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CN110172618A - Aluminum-silicon alloy partition plate, phosphating treatment method and compressor - Google Patents

Aluminum-silicon alloy partition plate, phosphating treatment method and compressor Download PDF

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Publication number
CN110172618A
CN110172618A CN201910390199.6A CN201910390199A CN110172618A CN 110172618 A CN110172618 A CN 110172618A CN 201910390199 A CN201910390199 A CN 201910390199A CN 110172618 A CN110172618 A CN 110172618A
Authority
CN
China
Prior art keywords
partition
compressor
phosphating
phosphating solution
alloy material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201910390199.6A
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Chinese (zh)
Other versions
CN110172618B (en
Inventor
郑慧芸
贾波
廖熠
沈慧
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gree Electric Appliances Inc of Zhuhai
Zhuhai Landa Compressor Co Ltd
Original Assignee
Gree Electric Appliances Inc of Zhuhai
Zhuhai Landa Compressor Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Gree Electric Appliances Inc of Zhuhai, Zhuhai Landa Compressor Co Ltd filed Critical Gree Electric Appliances Inc of Zhuhai
Priority to CN201910390199.6A priority Critical patent/CN110172618B/en
Publication of CN110172618A publication Critical patent/CN110172618A/en
Application granted granted Critical
Publication of CN110172618B publication Critical patent/CN110172618B/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/02Alloys based on aluminium with silicon as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C30/00Alloys containing less than 50% by weight of each constituent
    • C22C30/02Alloys containing less than 50% by weight of each constituent containing copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C30/00Alloys containing less than 50% by weight of each constituent
    • C22C30/06Alloys containing less than 50% by weight of each constituent containing zinc
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
    • C23C22/08Orthophosphates
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04CROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; ROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT PUMPS
    • F04C29/00Component parts, details or accessories of pumps or pumping installations, not provided for in groups F04C18/00 - F04C28/00
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04CROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; ROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT PUMPS
    • F04C29/00Component parts, details or accessories of pumps or pumping installations, not provided for in groups F04C18/00 - F04C28/00
    • F04C29/12Arrangements for admission or discharge of the working fluid, e.g. constructional features of the inlet or outlet

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Compressor (AREA)
  • Applications Or Details Of Rotary Compressors (AREA)

Abstract

The invention discloses an aluminum-silicon alloy partition plate, a phosphating treatment method and a compressor. The invention can obviously improve the wear resistance of the clapboard, meets the requirement on the wear resistance of the clapboard under the limit working condition of the compressor, and has lower process cost of the clapboard.

Description

Alusil alloy partition, parkerizing method and compressor
Technical field
The present invention relates to Compressor Technology field more particularly to alusil alloy partitions, parkerizing method and compressor.
Background technique
For conventional aluminum alloys compared with cast iron, intensity, hardness and wearability etc. are weaker, generally cannot directly apply to compression On the partition of machine.Existing solution is that aluminum alloy baffle plate is passivated to processing, oxidation processes or phosphatization, to improve partition Intensity and wearability.Although parkerized cost is more much lower than Passivation Treatment and oxidation processes, and generates after phosphorating treatment Phosphating coat wearability it is more preferable, but Passivation Treatment and oxidation processes are using at most in actual production, and phosphorating treatment is very rare, Main cause is in conventional aluminum alloys mainly based on aluminium, other alloying elements are generally lower than 1%, lead to only a small amount of gold Belong to ion (Zn 2+, Mn 2+), is not easy to react generation phosphating coat with phosphating solution, so that phosphatization effect is poor, phosphatization low efficiency.
Therefore, how to design wear-resisting property good partition is industry technical problem urgently to be resolved.
Summary of the invention
In order to solve the defect of existing partition wear-resisting property difference, the present invention proposes alusil alloy partition, parkerizing method And compressor.
The technical solution adopted by the present invention is that design partition uses alusil alloy material, the surface of partition is through phosphorating treatment After be coated with phosphating coat, phosphating coat with a thickness of 1 to 2 micron.
Preferably, the alusil alloy material of partition contains rare earth element.
Preferably, the alusil alloy material of partition is using aluminium as substrate, siliceous 17-32%, copper 5-10%, zinc 2-5%, manganese 0.6- 2%, magnesium 1-2%, iron 0.7-1.5%, rare earth element 0.1%.
The present invention also proposes the parkerizing method of partition, comprising: the partition of alusil alloy material is immersed in phosphating solution In, the surface of partition forms the phosphating coat of the grains formed with calcium phosphate precipitation object.
Preferably, phosphating solution phosphoric acid and dihydric phosphate.
Preferably, the total acidity 30-40 point of phosphating solution, the free acidity 5-10 point of phosphating solution.
Preferably, the temperature of phosphating solution is at 90 degree or more.
Preferably, before partition being immersed in phosphating solution, first the surface of partition is pre-processed, pretreatment include according to Oil removing, derusting and the neutralization of secondary progress.
The present invention also proposes compressor, including above-mentioned partition.
Preferably, compressor further include: upper cylinder, lower cylinder and crankshaft, partition are arranged between upper cylinder and lower cylinder, The center of partition is equipped with the through-hole passed through for crankshaft.
Preferably, suction hole is additionally provided on partition, upper cylinder is equipped with inlet channel, and suction hole is connected to inlet channel and lower gas The inner cavity of cylinder.
Preferably, the angle between air-breathing axially bored line and inlet channel axis is less than 90 degree.
Compared with prior art, the invention has the following advantages:
1, partition uses alusil alloy material, and the alloying component intensity is high and environment friendly and pollution-free, can also mitigate compressor weight, Reduce compressor cost;
2, partition carries out phosphorating treatment, and the phosphatization effect of silicon aluminum alloy material is good, and the phosphating coat wearability that baffle surface is formed is more It is excellent, meet the requirement under compressor limiting condition to partition wearability, and the process costs of partition are lower.
Detailed description of the invention
Below with reference to embodiment and attached drawing, the present invention is described in detail, in which:
Fig. 1 is the schematic diagram of internal structure of compressor in the preferred embodiment of the present invention.
Specific embodiment
The present invention proposes that partition uses alusil alloy material, and the surface of partition is coated with phosphating coat after phosphorating treatment.Every The alusil alloy material of plate contains 17-32%Si, 5-10%Cu, 2-5%Zn, 0.6-2%Mn, 1-2%Mg, 0.7-1.5%Fe, 0.1%RE, Remainder is Al.The alusil alloy material composition of partition has prevented adding for heavy metal antimony compared with general al alloy component Add, although the hardness and strength of alloy can be improved in heavy metal element, the element is toxic and price is higher, removes removing heavy metals On the one hand element can reduce cost, on the other hand can reduce the harm to environment and human body, keep material more environmentally-friendly.It is more excellent , the content of Zn and Mg are improved in the alusil alloy material of partition, effectively facilitate MgZn2 binary hardening constituent in alloying component It generates, MgZn2 content increases the intensity and hardness that partition can be improved.
More preferably, be also added into micro rare earth element in the alusil alloy material of partition, the addition of rare earth element so that Alloy flowability is improved, and the effect for refining phosphatization crystal grain is more preferable, the phosphating coat fine microstructures that partition phosphorating treatment obtains, phosphorus There are certain holes in change membrane tissue, can be reduced between partition and piston with oil storage in gap when compressor is run Frictional dissipation.Meanwhile using partition quality made of alusil alloy material being only the 1/3 of castiron partition quality, it can be with Effectively mitigate compressor weight, avoids moving component is overweight from causing that vibration of compressor is big, balance is poor.
Specifically, the parkerizing method of partition includes: that the partition of alusil alloy material is immersed in phosphating solution, every The surface of plate forms the phosphating coat of the grains formed with calcium phosphate precipitation object.Phosphating solution is by phosphoric acid, dihydric phosphate, promotor Or the composition such as oxidant, water, dihydric phosphate is containing Zn, Mn, Fe, Ni, Ca etc..The total acidity 30-40 point of phosphating solution, free acidity 5-10 point, the temperature of phosphating solution is at 90 degree or more.
The forming process of phosphating coat is as follows:
1, the multiple ionization of phosphoric acid
H3PO4→ H2PO4 -+ H+→ HPO4+2H+ →PO4 3-+3H+
Firstly, the etch of phosphoric acid makes the reduction of baffle surface H+ concentration, due to the H of baffle surface+Concentration sharply declines, and leads to phosphoric acid Root ionization at different levels carry out to the right, and final ionization is PO4 3-
2, calcium phosphate precipitation
As the PO that baffle surface dissociates4 3-With (metal interface) metal ion in solution: being mainly Zn2+、Mn2+、Fe 2+It reaches When to solubility product constant Ksp, calcium phosphate precipitation will be formed in metal surface.
3Zn2++2PO4 3-+4H2O→Zn3(PO4)2.4H2O
Zn2++Fe2++PO4 3-+H2O→Zn2Fe(PO4)2.4H2O
Or 3Mn2++2PO4 3-+4H2O→Mn3(PO4)2.4H2O
Mn2++Fe2++PO4 3-+H2O→Mn2Fe(PO4)2.4H2O
Calcium phosphate precipitation and hydrone are formed together phosphatization nucleus, and nucleus continues to grow up into phosphatization crystal grain, numerous crystal grain Combining closely finally can just integrate phosphating coat.The content that Mn, Zn element are improved in the alusil alloy material of partition, on the one hand makes Alloy strength, hardness raising are obtained, the Zn being precipitated in alloy is on the other hand improved2+、Mn2+Concentration, so that phosphatic forming amount It is more much higher than conventional aluminum alloys, eventually lead to better effect of the phosphorization film quality compared with conventional aluminum alloys, quality of forming film and resistance to Mill property is also 2 times of Conventional alloys or so.
In order to optimize parkerized effect, before partition is immersed in phosphating solution, first the surface of partition is carried out pre- Processing, pretreatment include oil removing, derusting and the neutralization successively carried out, and oil removing, derusting and neutralization technique are existing mature technologies, Its process is well known to those of ordinary skill in the industry, therefore not to repeat here.Compared with the pretreatment before traditional phosphating solutions processing, this hair Table tune technique is eliminated in bright middle preprocessing process, table tune technique is chiefly to facilitate the phosphatization that phosphatization forms the careful densification of crystal grain Film, this is because there is the addition phosphatization crystal grain of rare earth element to be refined, in matching for phosphatization liquid acidity and phosphatization temperature Under conjunction, gained phosphorization membrane is thin and careful, therefore does not need table tune technique and optimize processing to baffle surface.Of the invention is pre- Processing and phosphorating treatment whole process only need 20min or so, general 1-2 μm of the phosphating coat obtained after phosphatization, do not change substantially The size and surface roughness of alusil alloy partition, technical process are simple, at low cost.
As shown in Figure 1, in a preferred embodiment, the present invention also proposes that the compressor with aforementioned barriers, compressor also wrap Include: upper cylinder 1, lower cylinder 2 and crankshaft 3, partition 4 are arranged between upper cylinder 1 and lower cylinder 2, and the center of partition 4, which is equipped with, to be used for The through-hole that crankshaft passes through is additionally provided with suction hole 5 on partition 4, and upper cylinder 1 is equipped with inlet channel 6, and suction hole 5 is connected to inlet channel 6 With the inner cavity of lower cylinder 2, suction hole 5 is obliquely installed, and the angle between 6 axis of 5 axis of suction hole and inlet channel is less than 90 degree.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention Made any modifications, equivalent replacements, and improvements etc., should all be included in the protection scope of the present invention within mind and principle.

Claims (13)

1. a kind of partition, which is characterized in that the partition is alusil alloy material, and the surface of the partition is wrapped after phosphorating treatment It is covered with phosphating coat.
2. partition as described in claim 1, which is characterized in that the phosphating coat with a thickness of 1 to 2 micron.
3. partition as described in claim 1, which is characterized in that the alusil alloy material of the partition contains rare earth element.
4. partition as claimed in claim 3, which is characterized in that the alusil alloy material of the partition is siliceous using aluminium as substrate 17-32%, copper 5-10%, zinc 2-5%, manganese 0.6-2%, magnesium 1-2%, iron 0.7-1.5%, rare earth element 0.1%.
5. a kind of parkerizing method of partition characterized by comprising the partition of alusil alloy material is immersed in phosphating solution In, the surface of the partition forms the phosphating coat of the grains formed with calcium phosphate precipitation object.
6. parkerizing method as claimed in claim 5, which is characterized in that the phosphating solution phosphoric acid and dihydric phosphate.
7. parkerizing method as claimed in claim 5, which is characterized in that the total acidity 30-40 point of the phosphating solution, it is described The free acidity 5-10 point of phosphating solution.
8. parkerizing method as claimed in claim 5, which is characterized in that the temperature of the phosphating solution is at 90 degree or more.
9. parkerizing method as claimed in claim 5, which is characterized in that before the partition is immersed in phosphating solution, First the surface of partition is pre-processed, the pretreatment includes oil removing, derusting and the neutralization successively carried out.
10. a kind of compressor characterized by comprising such as the described in any item partitions of Claims 1-4.
11. compressor as claimed in claim 10, which is characterized in that further include: upper cylinder, lower cylinder and crankshaft, it is described every Plate is arranged between the upper cylinder and lower cylinder, and the center of the partition is equipped with the through-hole passed through for the crankshaft.
12. compressor as claimed in claim 11, which is characterized in that be additionally provided with suction hole, the upper cylinder on the partition Equipped with inlet channel, the suction hole is connected to the inner cavity of the inlet channel and the lower cylinder.
13. compressor as claimed in claim 12, which is characterized in that the air-breathing axially bored line and the inlet channel axis it Between angle less than 90 degree.
CN201910390199.6A 2019-05-10 2019-05-10 Aluminum-silicon alloy partition plate, phosphating treatment method and compressor Active CN110172618B (en)

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Application Number Priority Date Filing Date Title
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CN110172618B CN110172618B (en) 2020-06-16

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101812682A (en) * 2009-02-24 2010-08-25 中化化工科学技术研究总院 Zinc phosphating solution of aluminium and aluminium alloy
CN202203116U (en) * 2011-07-19 2012-04-25 珠海格力电器股份有限公司 Double-cylinder variable-capacity rotary compressor and air conditioning system thereof
CN106011559A (en) * 2016-07-06 2016-10-12 宁国市中泰汽车零部件有限公司 Bush inner core of automobile engine

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101812682A (en) * 2009-02-24 2010-08-25 中化化工科学技术研究总院 Zinc phosphating solution of aluminium and aluminium alloy
CN202203116U (en) * 2011-07-19 2012-04-25 珠海格力电器股份有限公司 Double-cylinder variable-capacity rotary compressor and air conditioning system thereof
CN106011559A (en) * 2016-07-06 2016-10-12 宁国市中泰汽车零部件有限公司 Bush inner core of automobile engine

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