CN118013154A - Geothermal gas absolute content calculation method and device, electronic equipment and storage medium - Google Patents
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Abstract
The application discloses a geothermal gas absolute content calculating method, a geothermal gas absolute content calculating device, electronic equipment and a storage medium, wherein the geothermal gas absolute content calculating method comprises the following steps: acquiring the relative content of geothermal gas; determining the partial pressure of the gas corresponding to the relative content; determining a henry constant corresponding to geothermal gas; the absolute geothermal gas content was calculated from the gas partial pressure and the henry constant. The application can calculate the absolute content of the geothermal gas according to the relative content of the geothermal gas, provides a data basis for researching the substance evolution and the energy evolution of the earth surface and the interior, can be applied to the fields of geothermal gas annual means and the like, and can be widely applied to the technical field of geothermal resources.
Description
Technical Field
The application relates to the technical field of geothermal resources, in particular to a geothermal gas absolute content calculation method, a geothermal gas absolute content calculation device, electronic equipment and a storage medium.
Background
Geothermal gas is an information window for knowing the evolution of substances and energy in the surface and the interior of the earth, and in the aspect of geothermal resource exploitation, the content of gas components and the isotope composition are less influenced by shallow processes and are often used as tracers, thermometers and annual means to reveal the heat source and the nature of a reservoir of a geothermal system, the source and the evolution of geothermal fluid and determine the deep thermal storage temperature, the geothermal water circulation depth and the geothermal water age. However, at present, in the process of collecting geothermal gas, a hot spring or a geothermal well is degassed on the near surface, and the content of the geothermal gas is measured to be relative volume percent (vol.%), namely, the relative content, and the absolute content (cm 3STP gH2O-1) of the geothermal gas is lacking by adopting a drainage gas collection method, so that the application of a geothermal gas annual determining means is limited.
Disclosure of Invention
The embodiment of the application mainly aims to provide a geothermal gas absolute content calculating method, a geothermal gas absolute content calculating device, electronic equipment and a storage medium, so as to obtain the absolute content of geothermal gas.
To achieve the above object, an aspect of the embodiments of the present application provides a geothermal gas absolute content calculating method, which includes:
acquiring the relative content of geothermal gas;
determining the partial pressure of the gas corresponding to the relative content;
determining a henry constant corresponding to the geothermal gas;
And calculating the absolute content of the geothermal gas according to the gas partial pressure and the Henry constant.
In some embodiments, the obtaining the relative content of geothermal gas comprises:
And determining the relative content of components of the sampled gas by using a mass spectrometer to obtain the relative content of the geothermal gas.
In some embodiments, the determining the partial pressure of the gas corresponding to the relative content comprises:
Multiplying the relative content by the total atmospheric pressure of the sampling point of the geothermal gas, and taking the multiplied result as the gas partial pressure.
In some embodiments, the determining the henry constant for the geothermal gas comprises:
Calculating the henry constant corresponding to the geothermal gas according to the Bensen coefficient;
The calculation formula of the henry constant is as follows:
Wherein H CP is the henry constant corresponding to geothermal gas, β is the bensen coefficient, R is the gas constant, and T 0 is the standard temperature under standard conditions;
the Bensen coefficient is calculated as:
lnβ=A1+A2(100/T)+A3 ln(T/100)+S‰[B1+B2(100/T)+B3 ln(T/100)2];
Wherein T is the temperature of geothermal water, S is the salinity of the geothermal water, and A 1、A2、A3、B1、B2、B3 is the constant for calculating the Bensen constant.
In some embodiments, said calculating the absolute content of said geothermal gas from said partial pressure of gas and said henry constant comprises:
Calculating the absolute content of the geothermal gas according to a gas absolute content calculation formula;
The absolute gas content calculation formula is as follows:
Wherein C is the absolute content of the geothermal gas, H CP is the henry constant corresponding to the geothermal gas, P i is the partial pressure of the gas, R is the gas constant, T 0 is the standard temperature under standard conditions, and P 0 is the standard pressure under standard conditions.
In some embodiments, the method further comprises:
acquiring groundwater reserves in a thermal reservoir; wherein the geothermal gas is collected from the thermal reservoir;
multiplying the groundwater reserve by the absolute content of the geothermal gas, the multiplication result being a geothermal associated gas resource quantity of the thermal reservoir.
In some embodiments, the acquiring groundwater reserves in the thermal reservoir comprises:
Multiplying the thickness of the thermal reservoir, geothermal zone area and porosity of the thermal reservoir rock, the result of the multiplication being the groundwater reserve in the thermal reservoir.
To achieve the above object, another aspect of the embodiments of the present application provides a geothermal gas absolute content calculating apparatus, the apparatus comprising:
the relative content acquisition unit is used for acquiring the relative content of geothermal gas;
a gas partial pressure determining unit for determining a gas partial pressure corresponding to the relative content;
a henry constant determination unit configured to determine a henry constant corresponding to the geothermal gas;
and an absolute content calculating unit for calculating the absolute content of the geothermal gas according to the gas partial pressure and the henry constant.
To achieve the above object, another aspect of the embodiments of the present application provides an electronic device, which includes a memory storing a computer program and a processor implementing the above method when executing the computer program.
To achieve the above object, another aspect of the embodiments of the present application proposes a computer-readable storage medium storing a computer program which, when executed by a processor, implements the above-mentioned method.
The embodiment of the application at least comprises the following beneficial effects:
The application obtains the relative content of geothermal gas; determining the partial pressure of the gas corresponding to the relative content; determining a henry constant corresponding to geothermal gas; the absolute geothermal gas content was calculated from the gas partial pressure and the henry constant. The application can calculate the absolute content of the geothermal gas according to the relative content of the geothermal gas, provides a data basis for researching the substance evolution and the energy evolution of the earth surface and the interior, and can be applied to the fields of geothermal gas annual determining means and the like.
Drawings
FIG. 1 is a schematic flow chart of a geothermal gas absolute content calculation method according to an embodiment of the present application;
FIG. 2 is a diagram illustrating a scenario for geothermal gas collection according to an embodiment of the present application;
FIG. 3 is a graph showing groundwater reserve distribution of a thermal reservoir according to an embodiment of the application;
FIG. 4 is a schematic structural diagram of a geothermal gas absolute content calculating device according to an embodiment of the present application;
Fig. 5 is a schematic diagram of a hardware structure of an electronic device according to an embodiment of the present application.
Detailed Description
The present application will be described in further detail with reference to the drawings and examples, in order to make the objects, technical solutions and advantages of the present application more apparent. It should be understood that the specific embodiments described herein are for purposes of illustration only and are not intended to limit the scope of the application. When the following description refers to the accompanying drawings, the same numbers in different drawings refer to the same or similar elements, unless otherwise indicated. The implementations described in the following exemplary embodiments do not represent all implementations consistent with embodiments of the application, but are merely examples of apparatuses and methods consistent with aspects of embodiments of the application as detailed in the accompanying claims.
It is to be understood that the terms "first," "second," and the like, as used herein, may be used to describe various concepts, but are not limited by these terms unless otherwise specified. These terms are only used to distinguish one concept from another. For example, the first information may also be referred to as second information, and similarly, the second information may also be referred to as first information, without departing from the scope of embodiments of the present application. The words "if", as used herein, may be interpreted as "at … …" or "at … …" or "in response to a determination", depending on the context.
The terms "at least one", "a plurality", "each", "any" and the like as used herein, at least one includes one, two or more, a plurality includes two or more, each means each of the corresponding plurality, and any one means any of the plurality.
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this application belongs. The terminology used herein is for the purpose of describing embodiments of the application only and is not intended to be limiting of the application.
Before describing the embodiments of the present application in detail, a part of related technologies related to the embodiments of the present application will be described below:
Geothermal gas is an information window for knowing the evolution of substances and energy in the earth surface and the interior, and in the aspect of geothermal resource exploitation, the content of gas components and the isotope composition are less influenced by shallow processes, and is often used as a tracer, a thermometer and a year-fixing means to reveal the heat source and the property of a reservoir of geothermal heat, the source and the evolution of geothermal fluid and determine the deep thermal storage temperature, the geothermal water circulation depth and the geothermal water age. However, at present, in the process of collecting geothermal gas, a hot spring or a geothermal well is degassed on the near surface, and the content of the geothermal gas is measured to be relative volume percent (vol.%), namely, the relative content, and the absolute content (cm 3STP gH2O-1) of the geothermal gas is lacking by adopting a drainage gas collection method, so that the application of a geothermal gas annual determining means is limited.
In view of the above, the embodiment of the application provides a geothermal gas absolute content calculating method, a geothermal gas absolute content calculating device, electronic equipment and a storage medium. The scheme is that the relative content of geothermal gas is obtained; determining the partial pressure of the gas corresponding to the relative content; determining a henry constant corresponding to geothermal gas; the absolute geothermal gas content was calculated from the gas partial pressure and the henry constant. The application can calculate the absolute content of the geothermal gas according to the relative content of the geothermal gas, provides a data basis for researching the substance evolution and the energy evolution of the earth surface and the interior, and can be applied to the fields of geothermal gas annual determining means and the like.
The embodiment of the application provides a geothermal gas absolute content calculation method, and relates to the technical field of geothermal resources. The geothermal gas absolute content calculating method provided by the embodiment of the application can be applied to a terminal, a server and software running in the terminal or the server. In some embodiments, the terminal may be, but is not limited to, a smart phone, a tablet computer, a notebook computer, a desktop computer, a smart speaker, a smart watch, a vehicle-mounted terminal, and the like; the server side can be configured as an independent physical server, a server cluster or a distributed system formed by a plurality of physical servers, and can be configured as a cloud server for providing cloud services, cloud databases, cloud computing, cloud functions, cloud storage, network services, cloud communication, middleware services, domain name services, security services, CDNs, basic cloud computing services such as big data and artificial intelligence platforms, and the server can also be a node server in a blockchain network; the software may be an application or the like for realizing the geothermal gas absolute content calculation method, but is not limited to the above form.
The application is operational with numerous general purpose or special purpose computer system environments or configurations. For example: personal computers, server computers, hand-held or portable devices, tablet devices, multiprocessor systems, microprocessor-based systems, set top boxes, programmable consumer electronics, network PCs, minicomputers, mainframe computers, distributed computing environments that include any of the above systems or devices, and the like. The application may be described in the general context of computer-executable instructions, such as program modules, being executed by a computer. Generally, program modules include routines, programs, objects, components, data structures, etc. that perform particular tasks or implement particular abstract data types. The application may also be practiced in distributed computing environments where tasks are performed by remote processing devices that are linked through a communications network. In a distributed computing environment, program modules may be located in both local and remote computer storage media including memory storage devices.
Referring to fig. 1, an embodiment of the present application provides a geothermal gas absolute content calculating method, which may include, but is not limited to, S100 to S130, specifically as follows:
S100: the relative content of geothermal gas is obtained.
First, this example describes an embodiment for collecting geothermal gas.
Performing geothermal fluid sample collection on geothermal well samples in a certain area: and a geothermal wellhead is connected with a plastic pipe made of HPDE material, and the wellhead is sequentially connected with a high-temperature-resistant hot water pipe, a copper pipe condenser, a silicone tube and a sharp glass tube. Initially a 50ml brine glass bottle was filled with geothermal water and immersed in a container filled with geothermal water. Placing a sharp glass tube in a container filled with geothermal water, after the whole sampling device is filled with geothermal fluid and the bubble quantity is stable, extending a silica gel tube with the sharp glass tube into a saline glass bottle, collecting geothermal gas by adopting a gas collecting and draining method, and collecting the geothermal gas, wherein an exemplary diagram of a scene is shown in fig. 2, after the saline glass bottle is filled with the gas, sealing the glass bottle by using a rubber plug, further sealing by using an aluminum cover by using a gland, and immersing the glass bottle mouth below the geothermal water surface in the container all the time in the whole process; and then the brine bottle is filled into a polyethylene bottle filled with correspondingly hot water to ensure no bubble residue, and the brine bottle is sealed by using sealing glue so as to avoid atmospheric pollution in the transportation process.
Then, a sample gas is collected from the collected geothermal water, and the relative content of the collected sample gas is measured.
Further, S100 may include:
The relative content of the sampled gas components is determined using a mass spectrometer to obtain the relative content of the geothermal gas.
S110: and determining the partial pressure of the gas corresponding to the relative content.
Specifically, the gas partial pressure of the collected geothermal gas at the relative content is determined.
Further, S110 may include:
Multiplying the relative content by the total atmospheric pressure of the sampling point of the geothermal gas, and taking the multiplied result as the gas partial pressure.
Specifically, the total atmospheric pressure at the sampling point refers to the atmospheric pressure of the environment in which the geothermal well is located.
S120: and determining the Henry constant corresponding to the geothermal gas.
Specifically, the geothermal gases have different henry constants, and as an alternative embodiment, S120 may further include:
Calculating the henry constant corresponding to the geothermal gas according to the Bensen coefficient;
The calculation formula of the henry constant is as follows:
Wherein H CP is the henry constant corresponding to geothermal gas, β is the bensen coefficient, R is the gas constant, and T 0 is the standard temperature under standard conditions;
the Bensen coefficient is calculated as:
lnβ=A1+A2(100/T)+A3 ln(T/100)+S‰[B1+B2(100/T)+B3 ln(T/100)2](2);
wherein T is the temperature of geothermal water, S is the salinity of the geothermal water, and A 1、A2、A3、B1、B2、B3 is the constant for calculating the Bensen constant. Alternatively, the embodiment can use an infrared thermometer to measure the geothermal water temperature of the water outlet, and use a multiparameter water quality analyzer to measure the salinity of the geothermal water.
Illustratively, the present embodiment may provide constants for use in bensen constant calculations for some optional gases, please refer to table 1.
TABLE 1 constants for Bensen constant calculation
A1 | A2 | A3 | B1 | B2 | B3 | |
He | -34.6261 | 43.0285 | 14.1391 | -0.04234 | 0.022624 | -0.003312 |
Ne | -39.1971 | 51.8013 | 15.7699 | -0.124695 | 0.078374 | -0.0127972 |
H2 | -47.8948 | 65.0368 | 20.1709 | -0.082225 | 0.049564 | -0.0078689 |
CO | -47.6148 | 69.5068 | 18.7397 | 0.045657 | -0.040721 | 0.00797 |
CH4 | -68.8862 | 101.4956 | 28.7314 | -0.076146 | 0.04397 | -0.0068672 |
S130: and calculating the absolute content of the geothermal gas according to the gas partial pressure and the Henry constant.
Specifically, when the gas is released from the geothermal water at the near-surface to form free gas, the phase transition is an equilibrium state, and the concentration (C; unit is cm 3STP gH2O-1) of dissolved gas in the geothermal water, that is, the absolute content, can be calculated according to the partial pressure of the gas (P i) and Henry Li Changshu (H CP).
Further, S130 may include:
Calculating the absolute content of the geothermal gas according to a gas absolute content calculation formula;
The absolute gas content calculation formula is as follows:
Wherein C is the absolute content of the geothermal gas, H CP is the henry constant corresponding to the geothermal gas, P i is the partial pressure of the gas, R is the gas constant, T 0 is the standard temperature under standard conditions, and P 0 is the standard pressure under standard conditions.
The calculation formula capable of being converted to obtain the absolute content of geothermal gas according to the above formulas is as follows:
Where x is the relative content of geothermal gas (unit: vol%), P s is the total atmospheric pressure of the sampling point of geothermal gas, and e is the natural base.
In addition, some components in geothermal gas are also important geothermal companion resources. Helium (He) in geothermal gas has the characteristics of chemical inertness and low boiling point, is an indispensable rare resource for the development of high and new technology industry, and has wide application in advanced technology and scientific research such as magnetic resonance imaging, semiconductor devices, optical fiber communication, space propulsion and the like. The hydrogen (H 2) in geothermal gas is the gas with highest energy content and no carbon at present, meets the global low-carbon or no-carbon energy development requirement, is considered as a 'future clean energy' for replacing fossil energy, and development and utilization of hydrogen are helpful for reducing greenhouse gas emission and relieving global warming, and are necessary choices for coping with climate change and adjusting energy structure for a long time. Whether geothermal resource cause research or geothermal associated gas resource development, it is necessary to know the absolute content of gas.
Therefore, the embodiment of the application can further comprise:
acquiring groundwater reserves in a thermal reservoir; wherein the geothermal gas is collected from the thermal reservoir;
multiplying the groundwater reserve by the absolute content of the geothermal gas, the multiplication result being a geothermal associated gas resource quantity of the thermal reservoir.
As a further embodiment, the step of obtaining the groundwater reserve in the thermal reservoir is more specifically:
Multiplying the thickness of the thermal reservoir, geothermal zone area and porosity of the thermal reservoir rock, the result of the multiplication being the groundwater reserve in the thermal reservoir.
Specifically, the geothermal associated gas resource amount (Q) may be obtained based on the groundwater reserve (R w) in the thermal reservoir in the geothermal system and the calculated absolute content (C) of the geothermal gas, the calculation formula being shown below; the groundwater reserve (R w) in the thermal reservoir is calculated from the thickness (H, unit: m) of the thermal reservoir, the distribution area (A, unit: m 2) of the geothermal zone, and the porosity (Φ) of the thermal reservoir rock, as follows:
Q=RW×C (5);
RW=AHΦ (6);
The distribution area of the geothermal zone can be obtained through on-site measurement, and the thickness of the thermal reservoir and the porosity of the thermal reservoir rock can be obtained through drilling data and a geophysical method. In consideration of uncertainty of parameters of the thermal reservoir, the method has a certain variation range, and follows a certain probability distribution, and the embodiment can adopt a Monte Carlo simulation calculation method in the process of calculating the groundwater reserve in the thermal reservoir. Alternatively, the Monte Carlo simulation calculation method is performed using Oracle Crystal Ball simulation software. And defining parameter distribution by adopting triangular probability density according to each parameter characteristic value of the Monte Carlo simulation calculation method, simulating and obtaining the groundwater reserve in the thermal reservoir.
The embodiment of the application can be based on the fact that when gas is separated from geothermal water on the near surface to form free gas (the phase state transition is an equilibrium state), the gas-liquid distribution of the geothermal gas between the liquid phase and the gas phase meets henry's law, the absolute content of the geothermal gas is obtained, and the reserve method is adopted for estimating the geothermal associated resource quantity.
The following describes and illustrates the embodiments of the present application in detail with reference to specific examples of application:
Illustratively, geothermal resources of a certain region are described as an example. In recent years, with exploitation and research of geothermal resources, it has been found that accompanying gas hydrogen and helium in geothermal gas in the region are abnormally high. When the helium concentration reaches 0.05-0.1vol.%, the method has industrial value, can be used as helium reservoir exploitation, and the hot water in the area can be accompanied with helium resources reaching 0.53vol.%, which exceeds the industrial value standard. In addition, the detected hydrogen is up to 12.45vol.%, far beyond other areas. However, due to the limitation of the existing sampling method, only the relative content of the gas can be obtained, and the absolute content of the helium and the hydrogen can not be obtained, so that the resource amount potential of the helium and the hydrogen can not be known for a long time. Therefore, according to the geothermal gas absolute content calculation method provided by the embodiment of the application, the absolute content of helium and hydrogen in geothermal gas of a geothermal system in the region is calculated, so that geothermal associated gas resource potential is obtained, and the method comprises the following steps:
The geothermal gas of 5 geothermal wells in the region is collected by a drainage gas collection method in the open air, the geothermal water temperature (T) is measured to be 60-89.5 ℃ by an infrared thermometer at a water outlet, the salinity (S) of the water body is measured to be 3.5-12.4 per mill by a multi-parameter water quality analyzer, the total atmospheric pressure of a sampling point is measured to be 0.9950-0.9974atm, and the measurement is carried out in a laboratory by a MAT 271 mass spectrometer, wherein the detection limit is 0.0001% and the relative standard error is less than 5%. The relative content of helium is measured to be 0.04-0.53 vol.% and the relative content of hydrogen is measured to be 2.38-12.45 vol.%.
The corresponding constants a 1,A2,A3,B1,B2,B3 in the absolute content calculation formula (4) of helium gas can be obtained by looking up table 1, and A1=-34.6261,A2=43.0285,A3=14.1391,B1=-0.04234,B2=0.022624,B3=-0.003312, is brought into the calculation formula (4) to obtain the calculation formula (7), and the absolute content of helium gas is obtained based on the calculation formula (7) to be 4.0x -6 to 5.3x -5cm3 STP g-1H2 O, and specific reference can be made to table 2.
Table 2 helium absolute content calculation parameters
The corresponding constants a 1,A2,A3,B1,B2,B3 in the equation (4) for the absolute content of hydrogen can be obtained by looking up table 1, and A1=-47.8948,A2=65.0368,A3=20.1709,B1=-0.082225,B2=0.049564,B3=-0.0078689, is brought into equation (4) to obtain equation (8), and the absolute content of hydrogen is 4.1X10 -4 to 2.1X10 -3cm3 STP g-1H2 O based on equation (8), for details, refer to table 3.
TABLE 3 calculation parameters of the absolute Hydrogen content
The geothermal reservoir in the area is mainly chalky Laiyang sandstone and Qingshan volcaniclastic rock, the area of the geothermal well concentrated distribution area in the micro-motion detection result is 160000m 2 thermal reservoir thickness distribution, the thermal reservoir thickness is 50-100m, and the porosity of the thermal reservoir is 10%. The embodiment can use Oracle Crystal Ball simulation software to perform Monte Carlo simulation calculation. According to the above-mentioned Monte Carlo simulation calculation method, the parameter characteristic values are defined by adopting triangular probability density, and the iteration times are 10000 times, and the simulation is performed, so that the groundwater reserve in the thermal reservoir is 8,000,000-16,000,000m 3, and the average value is 1.18×10 6m3, and the specific reference can be made to FIG. 3. According to the absolute content of helium of 4.0X10 -6 to 5.3X10 -5cm3 STP g-1H2 O, the geothermal associated helium resource amount of the geothermal well centralized production area is 5-63m 3 STP gH2O-1; the geothermal companion hydrogen resource amount is 487-2495m 3 STP gH2O-1 according to the absolute hydrogen content of 4.1X10 -4 to 2.1X10 -3cm3 STP g-1H2 O. For the whole medium-deep geothermal resource in the region, the whole area of the region is 113km 2, the top boundary of the thermal storage of the bedrock is 200m, the bottom boundary of the thermal storage is 2000m deep, the thickness of the thermal storage layer is 1800m, the porosity of the thermal storage rock is 3%, the underground water storage in the thermal storage layer is 6.1×10 9m3, and the resource amounts of helium and hydrogen are 7.8×10 6m3 STP gH2O-1 and 1.1×10 5m3 STP gH2O-1 respectively.
Referring to fig. 4, the embodiment of the application further provides a geothermal gas absolute content calculating device, which can implement the above geothermal gas absolute content calculating method, where the device includes:
the relative content acquisition unit is used for acquiring the relative content of geothermal gas;
a gas partial pressure determining unit for determining a gas partial pressure corresponding to the relative content;
a henry constant determination unit configured to determine a henry constant corresponding to the geothermal gas;
and an absolute content calculating unit for calculating the absolute content of the geothermal gas according to the gas partial pressure and the henry constant.
It can be understood that the content in the above method embodiment is applicable to the embodiment of the present device, and the specific functions implemented by the embodiment of the present device are the same as those of the embodiment of the above method, and the achieved beneficial effects are the same as those of the embodiment of the above method.
The embodiment of the application also provides electronic equipment, which comprises a memory and a processor, wherein the memory stores a computer program, and the processor realizes the geothermal gas absolute content calculating method when executing the computer program. The electronic equipment can be any intelligent terminal including a tablet personal computer, a vehicle-mounted computer and the like.
It can be understood that the content in the above method embodiment is applicable to the embodiment of the present apparatus, and the specific functions implemented by the embodiment of the present apparatus are the same as those of the embodiment of the above method, and the achieved beneficial effects are the same as those of the embodiment of the above method.
Referring to fig. 5, fig. 5 illustrates a hardware structure of an electronic device according to another embodiment, where the electronic device includes:
The processor 501 may be implemented by a general-purpose CPU (central processing unit), a microprocessor, an application-specific integrated circuit (ApplicationSpecificIntegratedCircuit, ASIC), or one or more integrated circuits, etc. for executing related programs to implement the technical solution provided by the embodiments of the present application;
Memory 502 may be implemented in the form of read-only memory (ReadOnlyMemory, ROM), static storage, dynamic storage, or random access memory (RandomAccessMemory, RAM). Memory 502 may store an operating system and other application programs, and when implementing the technical solutions provided in the embodiments of the present disclosure by software or firmware, relevant program codes are stored in memory 502, and the method for calculating the absolute geothermal gas content according to the embodiments of the present disclosure is invoked by processor 501;
an input/output interface 503 for implementing information input and output;
The communication interface 504 is configured to implement communication interaction between the device and other devices, and may implement communication in a wired manner (e.g. USB, network cable, etc.), or may implement communication in a wireless manner (e.g. mobile network, WIFI, bluetooth, etc.);
Bus 505 that transfers information between the various components of the device (e.g., processor 501, memory 502, input/output interface 503, and communication interface 504);
Wherein the processor 501, the memory 502, the input/output interface 503 and the communication interface 504 enable a communication connection between each other inside the device via the bus 505.
The embodiment of the application also provides a computer readable storage medium, wherein the computer readable storage medium stores a computer program which realizes the geothermal gas absolute content calculating method when being executed by a processor.
It can be understood that the content of the above method embodiment is applicable to the present storage medium embodiment, and the functions of the present storage medium embodiment are the same as those of the above method embodiment, and the achieved beneficial effects are the same as those of the above method embodiment.
The memory, as a non-transitory computer readable storage medium, may be used to store non-transitory software programs as well as non-transitory computer executable programs. In addition, the memory may include high-speed random access memory, and may also include non-transitory memory, such as at least one magnetic disk storage device, flash memory device, or other non-transitory solid state storage device. In some embodiments, the memory optionally includes memory remotely located relative to the processor, the remote memory being connectable to the processor through a network. Examples of such networks include, but are not limited to, the internet, intranets, local area networks, mobile communication networks, and combinations thereof.
The embodiments described in the embodiments of the present application are for more clearly describing the technical solutions of the embodiments of the present application, and do not constitute a limitation on the technical solutions provided by the embodiments of the present application, and those skilled in the art can know that, with the evolution of technology and the appearance of new application scenarios, the technical solutions provided by the embodiments of the present application are equally applicable to similar technical problems.
It will be appreciated by persons skilled in the art that the embodiments of the application are not limited by the illustrations, and that more or fewer steps than those shown may be included, or certain steps may be combined, or different steps may be included.
The above described apparatus embodiments are merely illustrative, wherein the units illustrated as separate components may or may not be physically separate, i.e. may be located in one place, or may be distributed over a plurality of network elements. Some or all of the modules may be selected according to actual needs to achieve the purpose of the solution of this embodiment.
Those of ordinary skill in the art will appreciate that all or some of the steps of the methods, systems, functional modules/units in the devices disclosed above may be implemented as software, firmware, hardware, and suitable combinations thereof.
The terms "first," "second," "third," "fourth," and the like in the description of the application and in the above figures, if any, are used for distinguishing between similar objects and not necessarily for describing a particular sequential or chronological order. It is to be understood that the data so used may be interchanged where appropriate such that the embodiments of the application described herein may be implemented in sequences other than those illustrated or otherwise described herein. Furthermore, the terms "comprises," "comprising," and "having," and any variations thereof, are intended to cover a non-exclusive inclusion, such that a process, method, system, article, or apparatus that comprises a list of steps or elements is not necessarily limited to those steps or elements expressly listed but may include other steps or elements not expressly listed or inherent to such process, method, article, or apparatus.
It should be understood that in the present application, "at least one (item)" means one or more, and "a plurality" means two or more. "and/or" for describing the association relationship of the association object, the representation may have three relationships, for example, "a and/or B" may represent: only a, only B and both a and B are present, wherein a, B may be singular or plural. The character "/" generally indicates that the context-dependent object is an "or" relationship. "at least one of" or the like means any combination of these items, including any combination of single item(s) or plural items(s). For example, at least one (one) of a, b or c may represent: a, b, c, "a and b", "a and c", "b and c", or "a and b and c", wherein a, b, c may be single or plural.
In the several embodiments provided by the present application, it should be understood that the disclosed apparatus and method may be implemented in other manners. For example, the above-described apparatus embodiments are merely illustrative, and for example, the above-described division of units is merely a logical function division, and there may be another division manner in actual implementation, for example, a plurality of units or components may be combined or may be integrated into another system, or some features may be omitted, or not performed. Alternatively, the coupling or direct coupling or communication connection shown or discussed with each other may be an indirect coupling or communication connection via some interfaces, devices or units, which may be in electrical, mechanical or other form.
The units described above as separate components may or may not be physically separate, and components shown as units may or may not be physical units, may be located in one place, or may be distributed over a plurality of network units. Some or all of the units may be selected according to actual needs to achieve the purpose of the solution of this embodiment.
In addition, each functional unit in the embodiments of the present application may be integrated in one processing unit, or each unit may exist alone physically, or two or more units may be integrated in one unit. The integrated units may be implemented in hardware or in software functional units.
The integrated units, if implemented in the form of software functional units and sold or used as stand-alone products, may be stored in a computer readable storage medium. Based on such understanding, the technical solution of the present application may be embodied in essence or a part contributing to the prior art or all or part of the technical solution in the form of a software product stored in a storage medium, including multiple instructions to cause a computer device (which may be a personal computer, a server, or a network device, etc.) to perform all or part of the steps of the method of the various embodiments of the present application. And the aforementioned storage medium includes: a U-disk, a removable hard disk, a Read-Only Memory (ROM), a random access Memory (Random Access Memory RAM), a magnetic disk, or an optical disk, or other various media capable of storing a program.
The preferred embodiments of the present application have been described above with reference to the accompanying drawings, and are not thereby limiting the scope of the claims of the embodiments of the present application. Any modifications, equivalent substitutions and improvements made by those skilled in the art without departing from the scope and spirit of the embodiments of the present application shall fall within the scope of the claims of the embodiments of the present application.
Claims (10)
1. A method for calculating absolute geothermal gas content, the method comprising:
acquiring the relative content of geothermal gas;
determining the partial pressure of the gas corresponding to the relative content;
determining a henry constant corresponding to the geothermal gas;
And calculating the absolute content of the geothermal gas according to the gas partial pressure and the Henry constant.
2. The method of claim 1, wherein the step of obtaining the relative geothermal gas content comprises:
And determining the relative content of components of the sampled gas by using a mass spectrometer to obtain the relative content of the geothermal gas.
3. The method of claim 1, wherein determining the partial pressure of the gas corresponding to the relative content comprises:
Multiplying the relative content by the total atmospheric pressure of the sampling point of the geothermal gas, and taking the multiplied result as the gas partial pressure.
4. The method for calculating the absolute content of geothermal gas according to claim 1, wherein the determining the henry constant corresponding to the geothermal gas comprises:
Calculating the henry constant corresponding to the geothermal gas according to the Bensen coefficient;
The calculation formula of the henry constant is as follows:
Wherein H CP is the henry constant corresponding to geothermal gas, β is the bensen coefficient, R is the gas constant, and T 0 is the standard temperature under standard conditions;
the Bensen coefficient is calculated as:
lnβ=A1+A2(100/T)+A3 ln(T/100)+S‰[B1+B2(100/T)+B3 ln(T/100)2];
Wherein T is the temperature of geothermal water, S is the salinity of the geothermal water, and A 1、A2、A3,、B1、B2、B3 is the constant for calculating the Bensen constant.
5. The method of claim 1, wherein said calculating the absolute content of the geothermal gas from the gas partial pressure and the henry constant comprises:
Calculating the absolute content of the geothermal gas according to a gas absolute content calculation formula;
The absolute gas content calculation formula is as follows:
Wherein C is the absolute content of the geothermal gas, H CP is the henry constant corresponding to the geothermal gas, P i is the partial pressure of the gas, R is the gas constant, T 0 is the standard temperature under standard conditions, and P 0 is the standard pressure under standard conditions.
6. The geothermal gas absolute content calculating method according to claim 1, further comprising:
acquiring groundwater reserves in a thermal reservoir; wherein the geothermal gas is collected from the thermal reservoir;
multiplying the groundwater reserve by the absolute content of the geothermal gas, the multiplication result being a geothermal associated gas resource quantity of the thermal reservoir.
7. The method of claim 6, wherein the step of obtaining the groundwater reserve in the thermal reservoir comprises:
Multiplying the thickness of the thermal reservoir, geothermal zone area and porosity of the thermal reservoir rock, the result of the multiplication being the groundwater reserve in the thermal reservoir.
8. A geothermal gas content computing device, the device comprising:
the relative content acquisition unit is used for acquiring the relative content of geothermal gas;
a gas partial pressure determining unit for determining a gas partial pressure corresponding to the relative content;
a henry constant determination unit configured to determine a henry constant corresponding to the geothermal gas;
and an absolute content calculating unit for calculating the absolute content of the geothermal gas according to the gas partial pressure and the henry constant.
9. An electronic device comprising a memory storing a computer program and a processor implementing the method of any of claims 1 to 7 when the computer program is executed by the processor.
10. A computer readable storage medium storing a computer program, characterized in that the computer program when executed by a processor implements the method according to any one of claims 1 to 7.
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20180080319A1 (en) * | 2015-11-28 | 2018-03-22 | IFP Energies Nouvelles | Method for exploitation and/or monitoring of an aquifer comprising at least one dissolved gas |
CN116109200A (en) * | 2023-02-27 | 2023-05-12 | 西安石油大学 | Helium resource amount calculation method, device and storage medium |
CN116733460A (en) * | 2023-06-13 | 2023-09-12 | 中核坤华能源发展有限公司 | Method for determining carbon dioxide content in geothermal reservoir |
CN117236526A (en) * | 2023-11-13 | 2023-12-15 | 北京师范大学 | River methane annual emission determining method, river methane annual emission determining device, electronic equipment and storage medium |
-
2024
- 2024-01-19 CN CN202410084838.7A patent/CN118013154A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20180080319A1 (en) * | 2015-11-28 | 2018-03-22 | IFP Energies Nouvelles | Method for exploitation and/or monitoring of an aquifer comprising at least one dissolved gas |
CN116109200A (en) * | 2023-02-27 | 2023-05-12 | 西安石油大学 | Helium resource amount calculation method, device and storage medium |
CN116733460A (en) * | 2023-06-13 | 2023-09-12 | 中核坤华能源发展有限公司 | Method for determining carbon dioxide content in geothermal reservoir |
CN117236526A (en) * | 2023-11-13 | 2023-12-15 | 北京师范大学 | River methane annual emission determining method, river methane annual emission determining device, electronic equipment and storage medium |
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