CN117797059B - Preparation method of soapberry fermentation liquor, composition and application thereof - Google Patents
Preparation method of soapberry fermentation liquor, composition and application thereof Download PDFInfo
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- CN117797059B CN117797059B CN202311403831.9A CN202311403831A CN117797059B CN 117797059 B CN117797059 B CN 117797059B CN 202311403831 A CN202311403831 A CN 202311403831A CN 117797059 B CN117797059 B CN 117797059B
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- soapberry
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- butanol
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- 240000003377 Shepherdia canadensis Species 0.000 title claims abstract description 66
- 235000018324 Shepherdia canadensis Nutrition 0.000 title claims abstract description 66
- 238000000855 fermentation Methods 0.000 title claims abstract description 43
- 230000004151 fermentation Effects 0.000 title claims abstract description 43
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000000203 mixture Substances 0.000 title claims description 18
- 239000000284 extract Substances 0.000 claims abstract description 37
- 239000000706 filtrate Substances 0.000 claims abstract description 37
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims abstract description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 31
- 238000002156 mixing Methods 0.000 claims abstract description 28
- 239000007788 liquid Substances 0.000 claims abstract description 25
- 239000000843 powder Substances 0.000 claims abstract description 19
- 239000001963 growth medium Substances 0.000 claims abstract description 16
- 238000005406 washing Methods 0.000 claims abstract description 14
- 238000003809 water extraction Methods 0.000 claims abstract description 13
- 239000012043 crude product Substances 0.000 claims abstract description 10
- 239000002244 precipitate Substances 0.000 claims abstract description 10
- 238000001035 drying Methods 0.000 claims abstract description 9
- 235000013399 edible fruits Nutrition 0.000 claims abstract description 9
- 238000000227 grinding Methods 0.000 claims abstract description 9
- 238000007873 sieving Methods 0.000 claims abstract description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000005457 ice water Substances 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims abstract description 8
- 230000009471 action Effects 0.000 claims abstract description 6
- 238000001704 evaporation Methods 0.000 claims abstract description 6
- 238000001556 precipitation Methods 0.000 claims description 16
- ZTOKUMPYMPKCFX-CZNUEWPDSA-N (E)-17-[(2R,3R,4S,5S,6R)-6-(acetyloxymethyl)-3-[(2S,3R,4S,5S,6R)-6-(acetyloxymethyl)-3,4,5-trihydroxyoxan-2-yl]oxy-4,5-dihydroxyoxan-2-yl]oxyoctadec-9-enoic acid Chemical compound OC(=O)CCCCCCC/C=C/CCCCCCC(C)O[C@@H]1O[C@H](COC(C)=O)[C@@H](O)[C@H](O)[C@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](COC(C)=O)O1 ZTOKUMPYMPKCFX-CZNUEWPDSA-N 0.000 claims description 11
- 239000002453 shampoo Substances 0.000 claims description 11
- 238000004140 cleaning Methods 0.000 claims description 9
- 241000228245 Aspergillus niger Species 0.000 claims description 7
- 241000186660 Lactobacillus Species 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 6
- 229940039696 lactobacillus Drugs 0.000 claims description 6
- 229920001817 Agar Polymers 0.000 claims description 5
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 5
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 5
- 239000008272 agar Substances 0.000 claims description 5
- 235000015278 beef Nutrition 0.000 claims description 5
- 229940041514 candida albicans extract Drugs 0.000 claims description 5
- 239000012153 distilled water Substances 0.000 claims description 5
- 229910052564 epsomite Inorganic materials 0.000 claims description 5
- 239000008103 glucose Substances 0.000 claims description 5
- 239000002054 inoculum Substances 0.000 claims description 5
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims description 5
- 229910000357 manganese(II) sulfate Inorganic materials 0.000 claims description 5
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 5
- 229920000053 polysorbate 80 Polymers 0.000 claims description 5
- 108010009004 proteose-peptone Proteins 0.000 claims description 5
- 239000001632 sodium acetate Substances 0.000 claims description 5
- 235000017281 sodium acetate Nutrition 0.000 claims description 5
- 239000004094 surface-active agent Substances 0.000 claims description 5
- YWYZEGXAUVWDED-UHFFFAOYSA-N triammonium citrate Chemical compound [NH4+].[NH4+].[NH4+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O YWYZEGXAUVWDED-UHFFFAOYSA-N 0.000 claims description 5
- 239000001393 triammonium citrate Substances 0.000 claims description 5
- 235000011046 triammonium citrate Nutrition 0.000 claims description 5
- 239000012138 yeast extract Substances 0.000 claims description 5
- 238000011081 inoculation Methods 0.000 claims description 4
- 239000012752 auxiliary agent Substances 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- 238000012360 testing method Methods 0.000 description 24
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 21
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 21
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 14
- POJWUDADGALRAB-UHFFFAOYSA-N allantoin Chemical compound NC(=O)NC1NC(=O)NC1=O POJWUDADGALRAB-UHFFFAOYSA-N 0.000 description 14
- 210000004761 scalp Anatomy 0.000 description 11
- -1 sesquiterpene glycosides Chemical class 0.000 description 9
- 108700004121 sarkosyl Proteins 0.000 description 8
- 229940045885 sodium lauroyl sarcosinate Drugs 0.000 description 8
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 7
- POJWUDADGALRAB-PVQJCKRUSA-N Allantoin Natural products NC(=O)N[C@@H]1NC(=O)NC1=O POJWUDADGALRAB-PVQJCKRUSA-N 0.000 description 7
- 229920001213 Polysorbate 20 Polymers 0.000 description 7
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 7
- 229960000458 allantoin Drugs 0.000 description 7
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 7
- 229940073507 cocamidopropyl betaine Drugs 0.000 description 7
- 229940071160 cocoate Drugs 0.000 description 7
- 229930182478 glucoside Natural products 0.000 description 7
- WCVRQHFDJLLWFE-UHFFFAOYSA-N pentane-1,2-diol Chemical compound CCCC(O)CO WCVRQHFDJLLWFE-UHFFFAOYSA-N 0.000 description 7
- 238000011056 performance test Methods 0.000 description 7
- 229960005323 phenoxyethanol Drugs 0.000 description 7
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 7
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 7
- 229940068977 polysorbate 20 Drugs 0.000 description 7
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 7
- 239000004299 sodium benzoate Substances 0.000 description 7
- 235000010234 sodium benzoate Nutrition 0.000 description 7
- 239000011780 sodium chloride Substances 0.000 description 7
- 230000001580 bacterial effect Effects 0.000 description 6
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 6
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 6
- 239000000523 sample Substances 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 5
- 229930182490 saponin Natural products 0.000 description 5
- 150000007949 saponins Chemical class 0.000 description 5
- 235000017709 saponins Nutrition 0.000 description 5
- 241000580955 Sapindus mukorossi Species 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 239000004519 grease Substances 0.000 description 3
- 244000005700 microbiome Species 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 241000235070 Saccharomyces Species 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 239000007853 buffer solution Substances 0.000 description 2
- 239000013068 control sample Substances 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 235000018102 proteins Nutrition 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 239000012488 sample solution Substances 0.000 description 2
- 150000003384 small molecules Chemical class 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- VFKZECOCJCGZQK-UHFFFAOYSA-M 3-hydroxypropyl(trimethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCCO VFKZECOCJCGZQK-UHFFFAOYSA-M 0.000 description 1
- 229920000832 Cutin Polymers 0.000 description 1
- 244000303965 Cyamopsis psoralioides Species 0.000 description 1
- 208000001840 Dandruff Diseases 0.000 description 1
- 206010061218 Inflammation Diseases 0.000 description 1
- 241000218652 Larix Species 0.000 description 1
- 235000005590 Larix decidua Nutrition 0.000 description 1
- 241000555676 Malassezia Species 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 206010039792 Seborrhoea Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000012869 ethanol precipitation Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000010685 fatty oil Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- 230000003779 hair growth Effects 0.000 description 1
- 230000003699 hair surface Effects 0.000 description 1
- 230000004054 inflammatory process Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 210000002752 melanocyte Anatomy 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910000402 monopotassium phosphate Inorganic materials 0.000 description 1
- 235000019796 monopotassium phosphate Nutrition 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- GNSKLFRGEWLPPA-UHFFFAOYSA-M potassium dihydrogen phosphate Chemical compound [K+].OP(O)([O-])=O GNSKLFRGEWLPPA-UHFFFAOYSA-M 0.000 description 1
- LWIHDJKSTIGBAC-UHFFFAOYSA-K potassium phosphate Substances [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000002633 protecting effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 229930004725 sesquiterpene Natural products 0.000 description 1
- 210000003491 skin Anatomy 0.000 description 1
- 229960003885 sodium benzoate Drugs 0.000 description 1
- 229940031688 sodium c14-16 olefin sulfonate Drugs 0.000 description 1
- 229960002668 sodium chloride Drugs 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229930182493 triterpene saponin Natural products 0.000 description 1
- 229910021642 ultra pure water Inorganic materials 0.000 description 1
- 239000012498 ultrapure water Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9789—Magnoliopsida [dicotyledons]
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/85—Products or compounds obtained by fermentation, e.g. yoghurt, beer, wine
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12R—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES C12C - C12Q, RELATING TO MICROORGANISMS
- C12R2001/00—Microorganisms ; Processes using microorganisms
- C12R2001/01—Bacteria or Actinomycetales ; using bacteria or Actinomycetales
- C12R2001/225—Lactobacillus
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12R—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES C12C - C12Q, RELATING TO MICROORGANISMS
- C12R2001/00—Microorganisms ; Processes using microorganisms
- C12R2001/645—Fungi ; Processes using fungi
- C12R2001/66—Aspergillus
- C12R2001/685—Aspergillus niger
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12R—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES C12C - C12Q, RELATING TO MICROORGANISMS
- C12R2001/00—Microorganisms ; Processes using microorganisms
- C12R2001/645—Fungi ; Processes using fungi
- C12R2001/85—Saccharomyces
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Dermatology (AREA)
- Engineering & Computer Science (AREA)
- Biotechnology (AREA)
- Botany (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Detergent Compositions (AREA)
Abstract
The invention provides a preparation method of soapberry fermentation liquor, which comprises the following steps: s01, washing soapberry fruits, drying, grinding, crushing and sieving to obtain powder; s02, extracting by adopting a water extraction mode to obtain a water extraction extract; s03, mixing the water extract with absolute ethyl alcohol with the same volume, and then stirring at a low speed under ice water bath to obtain a precipitate; removing the precipitate, and taking filtrate to be divided into 2 parts averagely; obtaining filtrate 1 and filtrate 2; s04, mixing the filtrate 1 prepared in the step S03 with a culture medium, and obtaining soapberry fermentation crude liquid under the action of strains; s05, mixing the filtrate 2 with n-butanol, taking n-butanol layer solution, and then rotationally evaporating n-butanol to obtain crude product 2; s06, mixing the crude product 2 with the soapberry fermentation crude liquid obtained in the step S04 to obtain the soapberry fermentation liquid.
Description
Technical Field
The invention relates to the technical field of daily chemicals, in particular to a preparation method, a composition and application of soapberry fermentation liquor.
Background
The scalp is effectively nursed, and the healthy growth of hair can be ensured. The daily scalp care mode comprises the steps of using scalp care essence, removing cutin periodically, preventing hair conditioner from contacting scalp, massaging scalp and the like. Moreover, hair is exposed to the environment for a long period of time, and in addition to being exposed to some dust and ultraviolet radiation, it is also necessary to deal with some sudden conditions of the scalp, such as hair oil, dandruff, etc. In addition, the shampoo products used on the market tend to pay more attention to cleaning, but do not pay much attention to hair repair and long-term care.
The soapberry saponin (Soapnut Saponin) is an extract of the pericarp of wild larch soapberry (Sapindus mukorossi gareth.) and mainly comprises triterpene saponins, sesquiterpene glycosides, fatty oil and protein, and is a natural nonionic surfactant and a pure natural product. The detergent has the function of reducing the surface tension, is used for cleaning skin and washing clothes, has good cleaning performance, effectively removes dirt and has no peculiar smell.
The soapberry extract is added into the shampoo, and the shampoo has the advantages of repairing scalp and hair, good absorption effect, fluffy washing and protecting effect and keeping fresh for a long time.
Disclosure of Invention
The invention aims to provide a preparation method of soapberry fermentation liquor, which comprises the following steps:
s01, washing soapberry fruits, drying, grinding, crushing and sieving to obtain powder;
S02, extracting by adopting a water extraction mode to obtain a water extraction extract;
S03, mixing the water extract with absolute ethyl alcohol with the same volume, and then stirring at a low speed under ice water bath to obtain a precipitate; removing the precipitate, and taking filtrate to be divided into 2 parts averagely; obtaining filtrate 1 and filtrate 2;
S04, mixing the filtrate 1 prepared in the step S03 with a culture medium, and obtaining soapberry fermentation crude liquid under the action of strains;
s05, mixing the filtrate 2 with n-butanol, taking n-butanol layer solution, and then rotationally evaporating n-butanol to obtain crude product 2;
s06, mixing the crude product 2 with the soapberry fermentation crude liquid obtained in the step S04 to obtain the soapberry fermentation liquid.
Preferably, in the step S01, the mixture is sieved with a 100-200 mesh sieve.
Preferably, the feed-liquid ratio is 1:10-20, the water extraction temperature is 90-95 ℃ and the time is 6h.
Preferably, the bacterial species is selected from one or more of Aspergillus niger, lactobacillus and Saccharomyces.
Preferably, the medium comprises the following components:
10.0g of casein peptone, 10.0g of beef extract powder, 5.0g of yeast extract powder, 20.0g of glucose, 1.0g of tween 80, 5.0g of sodium acetate, 2.0g of triammonium citrate, 0.05g of K 2HPO4 2.0g、MgSO4·7H2O 0.2g、MnSO4·H2 O, 15.0g of agar and 1000.0mL of distilled water.
Preferably, the fermentation condition is 27-31 ℃ and the fermentation is performed under aerobic condition for 6-48 hours.
The second aspect of the invention provides a soapberry fermentation broth, which is prepared from the soapberry fermentation broth.
In a third aspect, the present invention provides a cleaning composition comprising the soapberry fermentation broth described above.
Preferably, it comprises: solvent, surfactant, soapberry fermentation liquor, sophorolipid and auxiliary agent.
The fourth aspect of the invention provides the soapberry fermentation liquor which is applied to the field of daily chemicals.
By adopting the technical scheme, the invention has the following beneficial effects:
The cleaning composition disclosed by the application is durable and fresh after being used, can condition the scalp, has small irritation, effectively adjusts the grease balance, promotes the synthesis of melanocytes, reduces scalp inflammation and creates an ideal environment for hair growth.
Drawings
In order to more clearly illustrate the embodiments of the invention or the technical solutions in the prior art, the drawings which are required in the description of the embodiments or the prior art will be briefly described, it being obvious that the drawings in the description below are some embodiments of the invention and that other drawings may be obtained from these drawings without inventive effort for a person skilled in the art.
FIG. 1 shows the results of the control group test of the performance test 3 of the present invention.
FIG. 2 shows the test results of example 5 (30 min) of inventive performance test 3.
FIG. 3 shows the test results of example 5 (15 min) of the performance test 3 of the present invention.
FIG. 4 shows the test results of example 5 (5 min) of inventive performance test 3.
Detailed Description
The following description of the present invention will be made clearly and fully, and it is apparent that the embodiments described are some, but not all, of the embodiments of the present invention. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
The invention aims to provide a preparation method of soapberry fermentation liquor, which comprises the following steps:
S01, washing soapberry fruits, drying at normal temperature, grinding, crushing and sieving with a 100-200 mesh sieve to obtain powder;
s02, extracting for 6 hours in a water extraction mode at the temperature of 90-95 ℃ according to the feed-liquid ratio of 1:10-20 to obtain a water extraction extract;
s03, mixing the water extract with absolute ethyl alcohol with the same volume, then stirring at a low speed under ice water bath until precipitation occurs, and then standing until no precipitation occurs; filtering to remove precipitate, taking filtrate and equally dividing the filtrate into 2 parts; obtaining filtrate 1 and filtrate 2;
s04, mixing the filtrate 1 prepared in the step S03 with a culture medium, and fermenting under the action of a strain to obtain soapberry fermentation crude liquid; fermenting at 27-31deg.C under aerobic condition for 6-48 hr;
s05, mixing the filtrate 2 with n-butanol, taking n-butanol layer solution, and then rotationally evaporating n-butanol to obtain crude product 2;
s06, mixing the crude product 2 with the soapberry fermentation crude liquid obtained in the step S04 to obtain the soapberry fermentation liquid.
Preferably, the bacterial species is selected from one or more of Aspergillus niger, lactobacillus and Saccharomyces.
Preferably, the medium comprises the following components:
10.0g of casein peptone, 10.0g of beef extract powder, 5.0g of yeast extract powder, 20.0g of glucose, 1.0g of tween 80, 5.0g of sodium acetate, 2.0g of triammonium citrate, 0.05g of K 2HPO4 2.0g、MgSO4·7H2O 0.2g、MnSO4·H2 O, 15.0g of agar and 1000.0mL of distilled water.
The second aspect of the invention provides a soapberry fermentation broth, which is prepared from the soapberry fermentation broth.
In a third aspect, the present invention provides a cleaning composition comprising the soapberry fermentation broth described above.
Preferably, the shampoo composition comprises: solvent, surfactant, soapberry fermentation liquor, sophorolipid and auxiliary agent.
More preferably, the shampoo composition comprises: water, sodium lauroyl sarcosinate, soapberry fermentation broth, sodium C14-16 olefin sulfonate, cocamidopropyl betaine, polysorbate-20, phenoxyethanol, sodium chloride, sodium benzoate, bis (PPG-2 myristyl oleyl polyether-10) adipate, allantoin, PEG-7 glycerol cocoate, malto-oligosaccharide glucoside, butylene glycol, propylene glycol, 1, 2-pentanediol, sophorolipid.
More preferably, the cleaning composition comprises, in parts by mass: 80 parts of water, 5 parts of sodium lauroyl sarcosinate, 10 parts of soapberry fermentation broth, 1 part of C14-16 olefin sodium sulfonate, 3 parts of cocamidopropyl betaine, 0.5 part of polysorbate-20, 0.5 part of phenoxyethanol, 1 part of sodium chloride, 0.5 part of sodium benzoate, 0.1 part of bis (PPG-2 myristyl oleyl alcohol polyether-10) adipate, 0.1 part of allantoin, 1 part of PEG-7 glycerol cocoate, 2 parts of maltooligosaccharide glucoside, 0.1 part of butanediol, 0.5 part of propylene glycol, 0.5 part of 1, 2-pentanediol and 2 parts of sophorolipid.
The fourth aspect of the invention provides the soapberry fermentation liquor which is applied to the field of daily chemicals.
The soapberry fermentation filtrate provided by the invention has an excellent surfactant effect, and is not stimulated to scalp, and hair is not dry after washing. However, in order to realize the extraction of high-purity soapnut saponin, the process of ethanol precipitation is needed, and the proteins and polysaccharides in the system are often precipitated, so that the content of soapnut saponin in the system is increased; at the moment, the whole system can be found to have the phenomena of precipitation and the like, and the thickening agent or the surfactant can be added into the system to realize the stability in a short time; for extreme temperature storage or long-time storage, layering and other phenomena can occur; at the same time, for people with oily scalp, the foam can dissipate more quickly. According to the invention, part of soapberry water extract is fermented, soapberry saponin is partially decomposed to form small molecules, and then the small molecules are mixed with a precipitated system, so that the problem of precipitation can be solved, and the effect of foam stabilization can be realized.
The invention is further illustrated with reference to specific embodiments.
Aspergillus niger: purchased from China center for type culture Collection of microorganisms, with a strain number of CICC 40048.
Lactic acid bacteria: purchased from China center for Industrial microorganism culture Collection, with strain number CICC 21804
Yeast: purchased from China center for type culture Collection of microorganisms, with a strain number of CICC 32883.
Example 1:
The embodiment provides a soapberry extract, which is prepared by the following steps:
S01, washing soapberry fruits, drying, grinding, crushing and sieving with a 100-mesh sieve to obtain powder;
S02, extracting for 6 hours in a water extraction mode at the temperature of 95 ℃ according to the feed-liquid ratio of 1:15, so as to obtain a water extract.
Example 2:
The embodiment provides a soapberry extract, which is prepared by the following steps:
s01, washing soapberry fruits, drying at normal temperature, grinding, crushing and sieving with a 100-mesh sieve to obtain powder;
S02, extracting for 6 hours in a water extraction mode at the temperature of 95 ℃ according to the feed-liquid ratio of 1:15 to obtain a water extract;
S03, mixing the water extract with absolute ethyl alcohol with the same volume, then stirring at a low speed under ice water bath until precipitation occurs, and then standing until no precipitation occurs; filtering to remove precipitate, and collecting filtrate to obtain fructus Sapindi Mukouossi extract.
Example 3:
The embodiment provides a soapberry extract, which is prepared by the following steps:
s01, washing soapberry fruits, drying at normal temperature, grinding, crushing and sieving with a 100-mesh sieve to obtain powder;
S02, extracting for 6 hours in a water extraction mode at the temperature of 95 ℃ according to the feed-liquid ratio of 1:15 to obtain a water extract;
S03, mixing the water extract with absolute ethyl alcohol with the same volume, then stirring at a low speed under ice water bath until precipitation occurs, and then standing until no precipitation occurs; filtering to remove precipitate, and collecting filtrate;
S04, mixing the filtrate obtained in the step S03 with a culture medium, and fermenting under the action of a strain to obtain soapberry fermentation crude liquid; fermenting at 27-31deg.C under aerobic condition for 12 hr; the mass ratio of the filtrate to the culture medium is 1:5; the inoculation amount of the strain is 6wt% of the culture medium. The strains were Aspergillus niger (inoculum size 4%) and Lactobacillus (inoculum size 2%).
The culture medium comprises the following components:
10.0g of casein peptone, 10.0g of beef extract powder, 5.0g of yeast extract powder, 20.0g of glucose, 1.0g of tween 80, 5.0g of sodium acetate, 2.0g of triammonium citrate, 0.05g of K 2HPO4 2.0g、MgSO4·7H2O 0.2g、MnSO4·H2 O, 15.0g of agar and 1000.0mL of distilled water.
Example 4
The embodiment provides a soapberry extract, which is prepared by the following steps:
s01, washing soapberry fruits, drying at normal temperature, grinding, crushing and sieving with a 100-mesh sieve to obtain powder;
S02, extracting for 6 hours in a water extraction mode at the temperature of 95 ℃ according to the feed-liquid ratio of 1:15 to obtain a water extract;
S03, mixing the water extract with absolute ethyl alcohol with the same volume, then stirring at a low speed under ice water bath until precipitation occurs, and then standing until no precipitation occurs; filtering to remove precipitate, and collecting filtrate;
S04, mixing the filtrate with n-butanol, taking n-butanol layer solution, and then rotationally evaporating n-butanol to obtain soapberry extract.
Example 5:
the embodiment of the invention provides a preparation method of soapberry fermentation liquor, which comprises the following steps:
s01, washing soapberry fruits, drying at normal temperature, grinding, crushing and sieving with a 100-mesh sieve to obtain powder;
S02, extracting for 6 hours in a water extraction mode at the temperature of 95 ℃ according to the feed-liquid ratio of 1:15 to obtain a water extract;
s03, mixing the water extract with absolute ethyl alcohol with the same volume, then stirring at a low speed under ice water bath until precipitation occurs, and then standing until no precipitation occurs; filtering to remove precipitate, taking filtrate and equally dividing the filtrate into 2 parts; obtaining filtrate 1 and filtrate 2;
S04, mixing the filtrate 1 prepared in the step S03 with a culture medium, and fermenting under the action of a strain to obtain soapberry fermentation crude liquid; fermenting at 27-31deg.C under aerobic condition for 12 hr; the mass ratio of the filtrate to the culture medium is 1:5; the inoculation amount of the strain is 6wt% of the culture medium. The strains were Aspergillus niger (inoculum size 4%) and Lactobacillus (inoculum size 2%).
The culture medium comprises the following components:
10.0g of casein peptone, 10.0g of beef extract powder, 5.0g of yeast extract powder, 20.0g of glucose, 1.0g of tween 80, 5.0g of sodium acetate, 2.0g of triammonium citrate, 0.05g of K 2HPO4 2.0g、MgSO4·7H2O 0.2g、MnSO4·H2 O, 15.0g of agar and 1000.0mL of distilled water.
S05, mixing the filtrate 2 with n-butanol, taking n-butanol layer solution, and then rotationally evaporating n-butanol to obtain crude product 2;
s06, mixing the crude product 2 with the soapberry fermentation crude liquid obtained in the step S04 to obtain the soapberry fermentation liquid.
Example 6
This embodiment provides a shampoo composition comprising: 80 parts of water, 5 parts of sodium lauroyl sarcosinate, 10 parts of soapberry extract described in example 1,1 part of C14-16 olefin sodium sulfonate, 3 parts of cocamidopropyl betaine, 0.5 part of polysorbate-20, 0.5 part of phenoxyethanol, 1 part of sodium chloride, 0.5 part of sodium benzoate, 0.1 part of bis (PPG-2 myristyl oleate-10) adipate, 0.1 part of allantoin, 1 part of PEG-7 glycerol cocoate, 2 parts of maltooligosaccharide glucoside, 0.1 part of butanediol, 0.5 part of propylene glycol, 0.5 part of 1, 2-pentanediol and 2 parts of sophorolipid.
Example 7
This embodiment provides a shampoo composition comprising: 80 parts of water, 5 parts of sodium lauroyl sarcosinate, 10 parts of soapberry extract described in example 2, 1 part of C14-16 olefin sodium sulfonate, 3 parts of cocamidopropyl betaine, 0.5 part of polysorbate-20, 0.5 part of phenoxyethanol, 1 part of sodium chloride, 0.5 part of sodium benzoate, 0.1 part of bis (PPG-2 myristyl oleate-10) adipate, 0.1 part of allantoin, 1 part of PEG-7 glycerol cocoate, 2 parts of maltooligosaccharide glucoside, 0.1 part of butanediol, 0.5 part of propylene glycol, 0.5 part of 1, 2-pentanediol and 2 parts of sophorolipid.
Example 8
This embodiment provides a shampoo composition comprising: 80 parts of water, 5 parts of sodium lauroyl sarcosinate, 10 parts of soapberry extract described in example 3, 1 part of C14-16 olefin sodium sulfonate, 3 parts of cocamidopropyl betaine, 0.5 part of polysorbate-20, 0.5 part of phenoxyethanol, 1 part of sodium chloride, 0.5 part of sodium benzoate, 0.1 part of bis (PPG-2 myristyl oleate-10) adipate, 0.1 part of allantoin, 1 part of PEG-7 glycerol cocoate, 2 parts of maltooligosaccharide glucoside, 0.1 part of butanediol, 0.5 part of propylene glycol, 0.5 part of 1, 2-pentanediol and 2 parts of sophorolipid.
Example 9
This embodiment provides a shampoo composition comprising: 80 parts of water, 5 parts of sodium lauroyl sarcosinate, 10 parts of soapberry extract described in example 4, 1 part of C14-16 olefin sodium sulfonate, 3 parts of cocamidopropyl betaine, 0.5 part of polysorbate-20, 0.5 part of phenoxyethanol, 1 part of sodium chloride, 0.5 part of sodium benzoate, 0.1 part of bis (PPG-2 myristyl oleate-10) adipate, 0.1 part of allantoin, 1 part of PEG-7 glycerol cocoate, 2 parts of maltooligosaccharide glucoside, 0.1 part of butanediol, 0.5 part of propylene glycol, 0.5 part of 1, 2-pentanediol and 2 parts of sophorolipid.
Example 10
This embodiment provides a shampoo composition comprising: 80 parts of water, 5 parts of sodium lauroyl sarcosinate, 10 parts of soapberry extract described in example 5, 1 part of C14-16 olefin sodium sulfonate, 3 parts of cocamidopropyl betaine, 0.5 part of polysorbate-20, 0.5 part of phenoxyethanol, 1 part of sodium chloride, 0.5 part of sodium benzoate, 0.1 part of bis (PPG-2 myristyl oleate-10) adipate, 0.1 part of allantoin, 1 part of PEG-7 glycerol cocoate, 2 parts of maltooligosaccharide glucoside, 0.1 part of butanediol, 0.5 part of propylene glycol, 0.5 part of 1, 2-pentanediol and 2 parts of sophorolipid.
Example 11
This example provides a scalp lotion comprising 90 parts of water, 5 parts of sodium lauroyl sarcosinate, 0.5 part of guar hydroxypropyl trimethylammonium chloride, 1 part of citric acid, 10 parts of soapberry extract described in example 1, and 2 parts of sophorolipid.
Performance testing
Test 1: the compositions provided in examples 6-10 were allowed to stand at 5℃and 45℃for 90 days, and the traits were examined separately and divided into: stable, no obvious change; precipitating; layering; and (3) precipitation.
Test 2: and (3) testing the fluffiness: the products prepared in examples 6-10 were uniformly applied to the hair tresses of the sample group at a rate of 0.2g/g of hair, rubbed for 1min, rinsed with water at 37℃and a flow rate of 4L/min for 1min, rinsed with water every 20 seconds, dried under the comb 10 with narrow teeth, and then left to dry naturally under constant temperature and humidity. Test temperature: 21+ -1deg.C, humidity 50+ -10% RH. The tress area was measured using a VISIA-CR to calculate the bulk.
Pretreatment of sample group hair bundles before testing: moistening hair bundle at 37+ -2deg.C, spreading 1ml of 10% SLES, slightly kneading to enrich foam for 1min, removing greasy dirt on hair surface, washing at constant flow rate, washing, balancing in constant temperature and humidity, and naturally air drying. And (3) soaking in an artificial grease solution for 10min after airing, after soaking, stroking out excessive grease by fingers, combing 10 times on each of the two sides of the flat plate narrow-tooth comb, hanging the hair bundle in a constant temperature and humidity chamber for balancing, and airing naturally again.
Test 3: inhibition malassezia test: inoculating and subculturing with an inoculating loop under aseptic condition, wherein the 3 rd generation strain is used as a test strain. The test bacterial suspension is properly diluted by PBS liquid, and the required concentration is as follows: 0.1ml of the strain is dropped into 5.0ml of control solution PBS, and the recovery bacteria number is 1.0 x 10 4-9.0*104 CFU/ml.
5.0Ml of stock solution of the test sample is sucked and put into a sterilizing test tube, and after being put into a water bath with the temperature of 20+/-1 ℃ for 5min, 0.1ml of bacterial suspension for the test is respectively dripped, and the test sample is quickly and evenly mixed and immediately timed. After 5min, 15min and 30min, respectively sucking 0.5ml of mixed sample solution, adding into a sterilized PBS test tube containing 4.5ml, mixing thoroughly, standing for 10min, sucking 1ml of sample solution, placing into a plate, adding culture medium cooled to 40-45deg.C into the plate, and mixing thoroughly. Placing the solidified flat plate in a 30 ℃ incubator for inversion culture, observing and recording whether bacterial colony growth exists in each sample plate after 96 hours, counting viable bacteria bacterial colonies, and calculating the bacteriostasis rate according to the following formula:
Antibacterial ratio = (average colony count of control sample-average colony count of test sample)/average colony count of control sample × 100%
Control sample (PBS): 2.83g of anhydrous disodium hydrogen phosphate and 1.36g of monopotassium phosphate are weighed, 1000ml of ultrapure water is added for uniform mixing, the pH value is regulated to 7.2-7.4, PBS buffer solution with the concentration of 0.03mol/L is prepared, and the PBS buffer solution is sterilized at 121 ℃ for 20min for standby.
TABLE 1 test results of Performance test 1
| Examples | Test results |
| Example 6 | Stabilization |
| Example 7 | Precipitation of |
| Example 8 | Stable, without obvious change |
| Example 9 | Layering |
| Example 10 | Stable, without obvious change |
TABLE 2 test results of Performance test 2
Change rate = (post-treatment mean-pre-treatment mean)/post-treatment mean × 100%.
TABLE 3 test results of Performance test 3
| Examples | Antibacterial rate of% |
| Example 1 | >99.99 |
| Example 2 | >99.99 |
| Example 3 | >99.99 |
| Example 4 | >99.99 |
| Example 5 | >99.99 |
Finally, it should be noted that: the above embodiments are only for illustrating the technical solution of the present invention, and not for limiting the same; although the invention has been described in detail with reference to the foregoing embodiments, it will be understood by those of ordinary skill in the art that: the technical scheme described in the foregoing embodiments can be modified or some or all of the technical features thereof can be replaced by equivalents; such modifications and substitutions do not depart from the spirit of the invention.
Claims (5)
1. A preparation method of soapberry fermentation broth is characterized by comprising the following steps:
s01, washing soapberry fruits, drying, grinding, crushing and sieving with a 100-mesh sieve to obtain powder;
S02, extracting for 6 hours in a water extraction mode at the temperature of 95 ℃ according to the feed-liquid ratio of 1:15 to obtain a water extract;
S03, mixing the water extract with absolute ethyl alcohol with the same volume, then stirring at a low speed under ice water bath until precipitation occurs, and then standing until no precipitation occurs; filtering to remove precipitate, taking filtrate and equally dividing the filtrate into 2 parts; obtaining filtrate 1 and filtrate 2;
S04, mixing the filtrate 1 prepared in the step S03 with a culture medium, and fermenting under the action of a strain to obtain soapberry fermentation crude liquid; fermenting at 27-31deg.C under aerobic condition for 12 hr; the mass ratio of the filtrate to the culture medium is 1:5; the inoculation amount of the strain is 6wt% of the culture medium; the strain is Aspergillus niger and lactobacillus; the inoculum size of Aspergillus niger is 4%; the inoculation amount of the lactobacillus is 2%;
the culture medium comprises the following components: 10.0g of casein peptone, 10.0g of beef extract powder, 5.0g of yeast extract powder, 20.0 g g of glucose, 1.0g of tween 80, 5.0g of sodium acetate, 2.0g of triammonium citrate, 0.05g of K 2HPO4 2.0g、MgSO4·7H2O 0.2 g、MnSO4·H2 O, 15.0g of agar and 1000.0mL of distilled water;
s05, mixing the filtrate 2 with n-butanol, taking n-butanol layer solution, and then rotationally evaporating n-butanol to obtain crude product 2;
s06, mixing the crude product 2 with the soapberry fermentation crude liquid obtained in the step S04 to obtain the soapberry fermentation liquid.
2. A soapberry fermentation broth prepared by the preparation method of claim 1.
3. A cleaning composition comprising the soapberry fermentation broth of claim 2.
4. A cleaning composition according to claim 3, characterized in that it comprises: solvent, surfactant, soapberry fermentation liquor, sophorolipid and auxiliary agent.
5. Use of soapberry fermentation broth according to claim 2 for the preparation of a shampoo.
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| WO2006007741A1 (en) * | 2004-07-16 | 2006-01-26 | Thoeny Rolf | Liquid detergent based on saponin |
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