CN117417789B - Regenerated IBC ton bucket green cleaning solvent - Google Patents
Regenerated IBC ton bucket green cleaning solvent Download PDFInfo
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- CN117417789B CN117417789B CN202311355291.1A CN202311355291A CN117417789B CN 117417789 B CN117417789 B CN 117417789B CN 202311355291 A CN202311355291 A CN 202311355291A CN 117417789 B CN117417789 B CN 117417789B
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- ton barrel
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- 238000004140 cleaning Methods 0.000 title claims abstract description 46
- 239000002904 solvent Substances 0.000 title claims abstract description 34
- -1 trehalose ester Chemical class 0.000 claims abstract description 29
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 26
- 230000007797 corrosion Effects 0.000 claims abstract description 20
- 238000005260 corrosion Methods 0.000 claims abstract description 20
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 20
- 239000003112 inhibitor Substances 0.000 claims abstract description 20
- 229920002545 silicone oil Polymers 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229920001903 high density polyethylene Polymers 0.000 claims abstract description 19
- 239000004700 high-density polyethylene Substances 0.000 claims abstract description 19
- 150000007530 organic bases Chemical class 0.000 claims abstract description 19
- 239000012459 cleaning agent Substances 0.000 claims abstract description 16
- HDTRYLNUVZCQOY-UHFFFAOYSA-N α-D-glucopyranosyl-α-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)C(O)C(CO)O1 HDTRYLNUVZCQOY-UHFFFAOYSA-N 0.000 claims abstract description 15
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 claims abstract description 15
- HDTRYLNUVZCQOY-WSWWMNSNSA-N Trehalose Natural products O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-WSWWMNSNSA-N 0.000 claims abstract description 15
- 239000000176 sodium gluconate Substances 0.000 claims abstract description 15
- 229940005574 sodium gluconate Drugs 0.000 claims abstract description 15
- 235000012207 sodium gluconate Nutrition 0.000 claims abstract description 15
- 238000002360 preparation method Methods 0.000 claims abstract description 13
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 13
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 11
- 239000008367 deionised water Substances 0.000 claims abstract description 11
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 11
- 235000019795 sodium metasilicate Nutrition 0.000 claims abstract description 11
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 11
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 claims abstract description 10
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000001509 sodium citrate Substances 0.000 claims abstract description 10
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims abstract description 10
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid group Chemical group S(O)(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims description 18
- 229920001296 polysiloxane Polymers 0.000 claims description 11
- 238000002156 mixing Methods 0.000 claims description 9
- 235000017550 sodium carbonate Nutrition 0.000 claims description 9
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 8
- NECRQCBKTGZNMH-UHFFFAOYSA-N 3,5-dimethylhex-1-yn-3-ol Chemical group CC(C)CC(C)(O)C#C NECRQCBKTGZNMH-UHFFFAOYSA-N 0.000 claims description 4
- 229930006000 Sucrose Natural products 0.000 claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 4
- 239000000194 fatty acid Substances 0.000 claims description 4
- 229930195729 fatty acid Natural products 0.000 claims description 4
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 4
- 239000005720 sucrose Substances 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- HVCOBJNICQPDBP-UHFFFAOYSA-N 3-[3-[3,5-dihydroxy-6-methyl-4-(3,4,5-trihydroxy-6-methyloxan-2-yl)oxyoxan-2-yl]oxydecanoyloxy]decanoic acid;hydrate Chemical compound O.OC1C(OC(CC(=O)OC(CCCCCCC)CC(O)=O)CCCCCCC)OC(C)C(O)C1OC1C(O)C(O)C(O)C(C)O1 HVCOBJNICQPDBP-UHFFFAOYSA-N 0.000 claims description 2
- 229930186217 Glycolipid Natural products 0.000 claims description 2
- HDTRYLNUVZCQOY-LIZSDCNHSA-N alpha,alpha-trehalose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-LIZSDCNHSA-N 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 3
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 13
- 239000001593 sorbitan monooleate Substances 0.000 description 13
- 229940035049 sorbitan monooleate Drugs 0.000 description 13
- 235000011069 sorbitan monooleate Nutrition 0.000 description 13
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 10
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 9
- 239000007788 liquid Substances 0.000 description 7
- 229920000805 Polyaspartic acid Polymers 0.000 description 6
- 108010064470 polyaspartate Proteins 0.000 description 6
- 238000012360 testing method Methods 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- OWRXWSVBJIIORE-UHFFFAOYSA-N 3,7,11-trimethyldodec-1-yn-3-ol Chemical compound CC(C)CCCC(C)CCCC(C)(O)C#C OWRXWSVBJIIORE-UHFFFAOYSA-N 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000005429 filling process Methods 0.000 description 2
- 229960004793 sucrose Drugs 0.000 description 2
- 241001391944 Commicarpus scandens Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 229920006178 high molecular weight high density polyethylene Polymers 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 description 1
- 229910000342 sodium bisulfate Inorganic materials 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0073—Anticorrosion compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2027—Monohydric alcohols unsaturated
- C11D3/2031—Monohydric alcohols unsaturated fatty or with at least 8 carbon atoms in the alkenyl chain
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/221—Mono, di- or trisaccharides or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3719—Polyamides or polyimides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
The invention belongs to the field of ton bucket green cleaning agents, and particularly discloses a regenerated IBC ton bucket green cleaning solvent which comprises the following raw materials in parts by weight: 15-25 parts of sodium gluconate, 5-15 parts of sodium metasilicate, 4-8 parts of sodium carbonate, 3-6 parts of trehalose ester, 5-10 parts of sodium citrate, 6-12 parts of diethylene glycol monobutyl ether, 4-10 parts of an emulsifier, 3-8 parts of silicone oil, 2-5 parts of organic base, 2-4 parts of a corrosion inhibitor and 100 parts of deionized water. The cleaning agent disclosed by the invention is simple in preparation method, small in pollution, mild in cleaning condition and good in cleaning effect, and is especially suitable for cleaning sulfuric acid residues in the high-density polyethylene HDPE material ton barrel, and the damage to the HDPE ton barrel is small.
Description
Technical Field
The invention belongs to the field of ton bucket green cleaning agents, and particularly discloses a regenerated IBC ton bucket green cleaning solvent.
Background
IBC ton barrels refer to IBC intermediate bulk containers. Is a necessary tool for modern storage and transportation of liquid products. The packaging barrel is formed by combining an inner container and a metal frame, wherein the inner container is formed by blow molding high molecular weight high density polyethylene. The adoption of the container barrel for packaging can greatly reduce the production, storage, transportation and operation costs. Saving a great deal of manpower and material resources. Compared with the traditional package, the storage can save 35% of space, and the loading and unloading can be operated by using a forklift, so that a plurality of troubles of manual transportation are reduced. And (3) filling: 1 ton bucket = 5 200L barrels, the trouble of repeated operation many times has been reduced in the filling process, avoids simultaneously in the filling process to leak material, spill etc. extravagant. In summary, the container is convenient to use, economical and durable, and along with international development, the container gradually becomes a main stream product of liquid packaging. The liquid density of the liquid for containing the II type dangerous goods and the III type dangerous goods is 1.5g/cm < 3 > at the maximum, and the liquid density of the liquid for containing the II type dangerous goods and the III type dangerous goods is 1.8g/cm < 3 >. The product has reasonable structure, is firm and firm, can be directly loaded and unloaded by a forklift, and can be stacked and stored. The liquid discharge valve is arranged at the bottom of the product, so that the liquid discharge is convenient, rapid, thorough and safe, is convenient to clean, can be used in a circulating way for many times, saves energy and is beneficial to environmental protection.
The IBC ton barrel can be prepared by adopting PE reclaimed materials, is green and environment-friendly, but the reclaimed HDPE has the following defects of small hygroscopicity, easiness in melt fracture, easiness in decomposition after long-term contact with hot metal, large shrinkage range and shrinkage value, easiness in shrinkage cavity, dent and deformation. Therefore, the existing regenerated IBC ton barrel for storing 98% sulfuric acid is also required to be cleaned by a specific cleaning agent, so that the service life of the IBC ton barrel can be prolonged to the maximum extent, and the cleaning effect is improved.
Disclosure of Invention
In order to solve the problems, the invention discloses a green cleaning solvent for a regenerated IBC ton barrel, which has the advantages of simple preparation method, less pollution, mild cleaning condition and good cleaning effect.
The invention comprises the following technical scheme:
the regenerated IBC ton barrel green cleaning solvent comprises the following raw materials in parts by weight:
further, the regenerated IBC ton barrel green cleaning solvent is characterized in that the emulsifier is one of sorbitan monooleate, sorbitan monooleate or sucrose fatty acid ester.
Further, the regenerated IBC ton barrel green cleaning solvent is characterized in that the silicone oil is selected from polysiloxane or hydroxyl-terminated polysiloxane.
Further, the above-mentioned green cleaning solvent for a regenerated IBC ton barrel, wherein the organic base is selected from one of triethylamine, triethylenediamine or pyridine.
Further, the regenerated IBC ton barrel green cleaning solvent is characterized in that the corrosion inhibitor is selected from one of 3,7, 11-trimethyldodecyn-3-ol, polyaspartic acid or 3, 5-dimethyl-1-hexyn-3-ol.
Further, the regenerated IBC ton barrel is a high-density polyethylene ton barrel.
Further, the preparation method of the regenerated IBC ton barrel green cleaning solvent comprises the following steps:
Mixing sodium gluconate, sodium metasilicate, sodium carbonate, trehalose ester, sodium citrate, diethylene glycol monobutyl ether and deionized water to form a uniform solution system, stirring, and standing at room temperature;
(2) And adding an emulsifying agent, silicone oil, organic base and a corrosion inhibitor into the solution system, uniformly stirring, and standing to obtain the water-based cleaning agent.
Further, the use of the above-mentioned regenerated IBC ton barrel green cleaning solvent is characterized in that the green cleaning solvent is used for cleaning the IBC ton barrel storing 98% concentrated sulfuric acid.
Further, the use of the above recycled IBC ton bucket green cleaning solvent, the temperature during the cleaning process is kept at 20-30 ℃.
Compared with the prior art, the invention has the following beneficial effects:
The invention provides a regenerated IBC ton barrel green cleaning solvent, which is basically nontoxic or low in toxicity, small in environmental pollution, green and environment-friendly in raw materials, short in preparation process, low in cost and mild in preparation condition. The cleaning agent is designed specifically for a regenerated high-density polyethylene ton barrel, aims at the defects that a regenerated high-density polyethylene material is prone to melt fracture, is prone to decomposition after being contacted with hot metal for a long time, is large in shrinkage range and shrinkage value, is prone to shrinkage cavity, dent and deformation, sodium gluconate and trehalose glycolipid are added to protect the inner wall of the high-density polyethylene ton barrel, and meanwhile, organic alkali, sodium carbonate and other components are utilized to thoroughly neutralize and clean concentrated sulfuric acid remained in the ton barrel.
Drawings
FIG. 1 is a graph showing the residual rate of dirt in examples 1 to 3 and comparative examples 1 to 4 in the test examples;
FIG. 2 is the IBC ton barrel life (simulated accelerated aging test) days for examples 1-3 and comparative examples 1-4 in the test examples.
Detailed Description
The following description of the embodiments of the present invention will be made clearly and completely, and it is apparent that the described embodiments are only some embodiments of the present invention, but not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
The regenerated IBC ton barrel green cleaning solvent comprises the following raw materials in parts by weight:
The emulsifier is one of sorbitan monooleate, sorbitan monooleate or sucrose fatty acid ester;
the silicone oil is selected from polysiloxane or hydroxyl-terminated polysiloxane;
the organic base is selected from one of triethylamine, triethylene diamine or pyridine;
The corrosion inhibitor is selected from one of 3,7, 11-trimethyldodecyn-3-ol, polyaspartic acid or 3, 5-dimethyl-1-hexyn-3-ol;
the IBC ton barrel is a high-density polyethylene ton barrel;
The preparation method of the regenerated IBC ton barrel green cleaning solvent comprises the following steps:
Mixing sodium gluconate, sodium metasilicate, sodium carbonate, trehalose ester, sodium citrate, diethylene glycol monobutyl ether and deionized water to form a uniform solution system, stirring, and standing at room temperature;
(2) And adding an emulsifying agent, silicone oil, organic base and a corrosion inhibitor into the solution system, uniformly stirring, and standing to obtain the water-based cleaning agent.
Example 1
The regenerated IBC ton barrel green cleaning solvent comprises the following raw materials in parts by weight:
The emulsifier is sorbitan monooleate;
The silicone oil is polysiloxane;
the organic base is triethylamine;
The corrosion inhibitor is 3,7, 11-trimethyl dodecyn-3-ol;
the IBC ton barrel is a high-density polyethylene ton barrel;
The preparation method of the regenerated IBC ton barrel green cleaning solvent comprises the following steps:
Mixing sodium gluconate, sodium metasilicate, sodium carbonate, trehalose ester, sodium citrate, diethylene glycol monobutyl ether and deionized water to form a uniform solution system, stirring, and standing at room temperature;
(2) And adding an emulsifying agent, silicone oil, organic base and a corrosion inhibitor into the solution system, uniformly stirring, and standing to obtain the water-based cleaning agent.
Example 2
The regenerated IBC ton barrel green cleaning solvent comprises the following raw materials in parts by weight:
the emulsifier is sorbitan monooleate or sorbitan monooleate;
The silicone oil is hydroxyl-terminated polysiloxane;
The organic base is triethylene diamine;
The corrosion inhibitor is polyaspartic acid;
the IBC ton barrel is a high-density polyethylene ton barrel;
The preparation method of the regenerated IBC ton barrel green cleaning solvent comprises the following steps:
Mixing sodium gluconate, sodium metasilicate, sodium carbonate, trehalose ester, sodium citrate, diethylene glycol monobutyl ether and deionized water to form a uniform solution system, stirring, and standing at room temperature;
(2) And adding an emulsifying agent, silicone oil, organic base and a corrosion inhibitor into the solution system, uniformly stirring, and standing to obtain the water-based cleaning agent.
Example 3
The regenerated IBC ton barrel green cleaning solvent comprises the following raw materials in parts by weight:
the emulsifier is sucrose fatty acid ester;
The silicone oil is hydroxyl-terminated polysiloxane;
the organic base is pyridine;
the corrosion inhibitor is 3, 5-dimethyl-1-hexyn-3-ol;
the IBC ton barrel is a high-density polyethylene ton barrel;
The preparation method of the regenerated IBC ton barrel green cleaning solvent comprises the following steps:
Mixing sodium gluconate, sodium metasilicate, sodium carbonate, trehalose ester, sodium citrate, diethylene glycol monobutyl ether and deionized water to form a uniform solution system, stirring, and standing at room temperature;
(2) And adding an emulsifying agent, silicone oil, organic base and a corrosion inhibitor into the solution system, uniformly stirring, and standing to obtain the water-based cleaning agent.
Comparative example 1
The regenerated IBC ton barrel green cleaning solvent comprises the following raw materials in parts by weight:
the emulsifier is sorbitan monooleate or sorbitan monooleate;
The silicone oil is hydroxyl-terminated polysiloxane;
The organic base is triethylene diamine;
The corrosion inhibitor is polyaspartic acid;
the IBC ton barrel is a high-density polyethylene ton barrel;
The preparation method of the regenerated IBC ton barrel green cleaning solvent comprises the following steps:
Mixing sodium gluconate, sodium metasilicate, sodium carbonate, trehalose ester, sodium citrate, diethylene glycol monobutyl ether and deionized water to form a uniform solution system, stirring, and standing at room temperature;
(2) And adding an emulsifying agent, silicone oil, organic base and a corrosion inhibitor into the solution system, uniformly stirring, and standing to obtain the water-based cleaning agent.
Comparative example 1 was identical to example 2 except that 10 parts of sodium gluconate was not included.
Comparative example 2
The regenerated IBC ton barrel green cleaning solvent comprises the following raw materials in parts by weight:
the emulsifier is sorbitan monooleate or sorbitan monooleate;
The silicone oil is hydroxyl-terminated polysiloxane;
The organic base is triethylene diamine;
The corrosion inhibitor is polyaspartic acid;
the IBC ton barrel is a high-density polyethylene ton barrel;
The preparation method of the regenerated IBC ton barrel green cleaning solvent comprises the following steps:
Mixing sodium gluconate, sodium metasilicate, sodium carbonate, trehalose ester, sodium citrate, diethylene glycol monobutyl ether and deionized water to form a uniform solution system, stirring, and standing at room temperature;
(2) And adding an emulsifying agent, silicone oil, organic base and a corrosion inhibitor into the solution system, uniformly stirring, and standing to obtain the water-based cleaning agent.
This comparative example 1 was identical to example 2 except that 4.5 parts of trehalose lipid was not included.
Comparative example 3
The regenerated IBC ton barrel green cleaning solvent comprises the following raw materials in parts by weight:
the emulsifier is sorbitan monooleate or sorbitan monooleate;
The silicone oil is hydroxyl-terminated polysiloxane;
The organic base is triethylene diamine;
The corrosion inhibitor is polyaspartic acid;
the IBC ton barrel is a high-density polyethylene ton barrel;
The preparation method of the regenerated IBC ton barrel green cleaning solvent comprises the following steps:
Mixing sodium gluconate, sodium metasilicate, sodium carbonate, trehalose ester, sodium citrate, diethylene glycol monobutyl ether and deionized water to form a uniform solution system, stirring, and standing at room temperature;
(2) And adding an emulsifying agent, silicone oil, organic base and a corrosion inhibitor into the solution system, uniformly stirring, and standing to obtain the water-based cleaning agent.
This comparative example 1 was identical to example 2 except that 10 parts of sodium gluconate and 4.5 parts of trehalose lipid were not included.
Comparative example 4
Sodium bisulfate cleaning agents are commercially available.
Test case
Practical cleaning tests were performed on the cleaning solvents prepared in examples 1-3 and comparative examples 1-3 above, the green cleaning solvent being used to clean IBC ton barrels storing 98% concentrated sulfuric acid, the temperature being maintained at 20-30 ℃ during the cleaning process. The results are shown in table 1 and fig. 1 and 2.
Table 1 performance test
As can be seen from the table 1, the table 1 and the table 2, the cleaning agent is designed particularly for the regenerated high-density polyethylene ton barrel, aims at the defects that the regenerated high-density polyethylene material is easy to break, easy to decompose after being contacted with hot metal for a long time, large in shrinkage range and shrinkage value, easy to shrink, dent and deform, and sodium gluconate and trehalose lipid components are added to protect the inner wall of the high-density polyethylene ton barrel, and meanwhile, the components such as organic alkali, sodium carbonate and the like are utilized to thoroughly neutralize and clean the concentrated sulfuric acid remained in the ton barrel.
The foregoing examples are of a limited number of preferred embodiments of the invention, which are described in more detail and detail, but are not to be construed as limiting the scope of the invention. It should be noted that it will be apparent to those skilled in the art that several variations and modifications can be made without departing from the spirit of the invention, which are all within the scope of the invention.
Claims (1)
1. The use of a recycled IBC ton drum green cleaning solvent for cleaning IBC ton drums storing 98% concentrated sulfuric acid is characterized in that,
The cleaning solvent comprises the following raw materials in parts by weight:
25 parts of sodium gluconate
15 Parts of sodium metasilicate
Sodium carbonate 8 parts
Trehalose glycolipid 6 parts
10 Parts of sodium citrate
Diethylene glycol monobutyl ether 12 parts
10 Parts of emulsifying agent
8 Parts of silicone oil
5 Parts of organic base
Corrosion inhibitor 4 parts
100 Parts of deionized water;
the emulsifier is sucrose fatty acid ester;
The silicone oil is hydroxyl-terminated polysiloxane;
the organic base is pyridine;
the corrosion inhibitor is 3, 5-dimethyl-1-hexyn-3-ol;
the IBC ton barrel is a high-density polyethylene ton barrel;
The preparation method of the regenerated IBC ton barrel green cleaning solvent comprises the following steps:
Mixing sodium gluconate, sodium metasilicate, sodium carbonate, trehalose ester, sodium citrate, diethylene glycol monobutyl ether and deionized water to form a uniform solution system, stirring, and standing at room temperature;
(2) Adding an emulsifying agent, silicone oil, organic alkali and a corrosion inhibitor into the solution system, uniformly stirring, and standing to obtain a water-based cleaning agent;
the temperature is kept at 20-30 ℃ during the cleaning process.
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101597547A (en) * | 2009-05-21 | 2009-12-09 | 陈安友 | A kind of phosphate-free environment-friendly cleaning agent |
| CN115261150A (en) * | 2022-07-25 | 2022-11-01 | 北京国电富通科技发展有限责任公司 | Environment-friendly water-based cleaning agent based on insulating part and preparation method thereof |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007011045A1 (en) * | 2005-07-20 | 2007-01-25 | Kuraray Co., Ltd. | Purging agent |
| DE102011090030A1 (en) * | 2011-12-28 | 2013-07-04 | Evonik Industries Ag | Aqueous hair and skin cleansing compositions containing biosurfactants |
| CH712858A2 (en) * | 2016-08-29 | 2018-03-15 | Remo Richli | Mild preparations containing alkoxylated fatty acid amides and glycolipid biosurfactants. |
| CH712860A2 (en) * | 2016-08-29 | 2018-03-15 | Remo Richli | Agents with alkoxylated fatty acid amides and glycolipid biosurfactants. |
| EP3507352A1 (en) * | 2016-09-01 | 2019-07-10 | Symrise AG | Product comprising a plastic container and a substance composition |
| US20180332874A1 (en) * | 2017-05-18 | 2018-11-22 | Douglas Kelley | Method for cleaning and disinfection |
| US11136536B2 (en) * | 2017-12-01 | 2021-10-05 | Ecolab Usa Inc. | Cleaning compositions and methods for removing baked on grease from fryers and other hot surfaces |
| CN114561252B (en) * | 2022-03-02 | 2023-09-15 | 深圳市荣强科技有限公司 | Low-residue efficient cleaning agent and preparation method thereof |
| CN219399945U (en) * | 2022-12-15 | 2023-07-25 | 西安三浦化学试剂有限公司 | Ton bucket sodium carbonate solution preparation equipment |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101597547A (en) * | 2009-05-21 | 2009-12-09 | 陈安友 | A kind of phosphate-free environment-friendly cleaning agent |
| CN115261150A (en) * | 2022-07-25 | 2022-11-01 | 北京国电富通科技发展有限责任公司 | Environment-friendly water-based cleaning agent based on insulating part and preparation method thereof |
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