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CN116872397A - Waste plastic film forming and thermal cracking device and method - Google Patents

Waste plastic film forming and thermal cracking device and method Download PDF

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Publication number
CN116872397A
CN116872397A CN202311148258.1A CN202311148258A CN116872397A CN 116872397 A CN116872397 A CN 116872397A CN 202311148258 A CN202311148258 A CN 202311148258A CN 116872397 A CN116872397 A CN 116872397A
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CN
China
Prior art keywords
thermal cracking
equipment
spiral
pipe
film forming
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202311148258.1A
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Chinese (zh)
Inventor
王志平
许理想
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Huaxu Environmental Sanitation Technology Co ltd
Original Assignee
Jiangsu Huaxu Environmental Sanitation Technology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Huaxu Environmental Sanitation Technology Co ltd filed Critical Jiangsu Huaxu Environmental Sanitation Technology Co ltd
Priority to CN202311148258.1A priority Critical patent/CN116872397A/en
Publication of CN116872397A publication Critical patent/CN116872397A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B9/00Cleaning hollow articles by methods or apparatus specially adapted thereto 
    • B08B9/08Cleaning containers, e.g. tanks
    • B08B9/0804Cleaning containers having tubular shape, e.g. casks, barrels, drums
    • B08B9/0808Cleaning containers having tubular shape, e.g. casks, barrels, drums by methods involving the use of tools, e.g. by brushes, scrapers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/04Disintegrating plastics, e.g. by milling
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00Recovery or working-up of waste materials
    • C08J11/04Recovery or working-up of waste materials of polymers
    • C08J11/10Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
    • C08J11/12Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by dry-heat treatment only
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B2017/001Pretreating the materials before recovery
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B2017/001Pretreating the materials before recovery
    • B29B2017/0021Dividing in large parts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/04Disintegrating plastics, e.g. by milling
    • B29B2017/0424Specific disintegrating techniques; devices therefor
    • B29B2017/044Knives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/04Disintegrating plastics, e.g. by milling
    • B29B2017/0424Specific disintegrating techniques; devices therefor
    • B29B2017/0496Pyrolysing the materials

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Sustainable Development (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Thermal Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

The application discloses a waste plastic film forming and thermal cracking device and a method, wherein a horizontal film forming and thermal cracking device is arranged, and because a thermal cracking barrel of the horizontal film forming and thermal cracking device is horizontally arranged, waste plastic films can be uniformly attached to the inner side wall of the thermal cracking barrel, so that the films on the inner side wall of the thermal cracking barrel can be fully thermally cracked, and the edge of a spiral film forming blade is provided with an inclined plane, so that pasty waste plastic can be better and more smoothly scraped on the inner side wall of the thermal cracking barrel uniformly, and a spiral cleaning structure is arranged, so that carbon powder after thermal cracking on the inner side wall of the thermal cracking barrel is cleaned into a collecting bin by a cleaning steel brush, and the production efficiency is improved.

Description

Waste plastic film forming and thermal cracking device and method
Technical Field
The application relates to the technical field of waste plastic thermal cracking, in particular to a waste plastic film forming thermal cracking device and a waste plastic film forming thermal cracking method.
Background
Along with the global policy advocations of low-carbon development, circular economy and green packaging and the continuous enhancement of environmental protection consciousness of consumers, industry surge of packaging in the fields of fast-food, electronic commerce logistics and the like is increasingly pushed to greenization, circular cyclization, low carbonization and sustainability, and plastic packaging occupies the semi-wall Jiangshan of the packaging industry, and is a main source of white pollution due to large consumption and wide distribution, and is also a key point of circular economy.
The waste plastic raw material is characterized by solid property, low density, low garbage classification popularization rate, small number of single sources, complex sources and relatively dispersed geographical range, so that the form of a chemical recovery plant can be a large plant with annual output of hundreds of thousands of tons, and a small plant with several tens of thousands of tons, the product of the large plant is usually olefin monomer or polymer, and the product of the small plant is usually pyrolysis oil or wax oil, and the plastic pollution problem can be better solved.
The chemical recovery of waste plastics is a process of generating intermediate chemicals such as oil, gas, carbon and the like by a series of chemical reactions on plastic wastes, and the chemical recovery method of the thermal cracking method of the waste plastics is a chemical method of finally generating combustible gas, liquid oil and solid carbon by heating and decomposing solid organic matters under the condition of isolating oxygen; the waste plastic catalytic cracking method is to add a catalyst based on the thermal cracking method, and the chemical process is to combine thermal cracking and catalytic cracking, so that the reaction rate is high, the time is short, more isomerization and aromatization products are produced in oil products, the oil quality is high, and compared with the thermal cracking of waste plastic, the catalytic cracking method has the obvious advantages of high reaction rate, low reaction condition, high product value and the like. Under the condition of reaching the same conversion rate, the reaction temperature can be obviously reduced by adding the catalyst, and the reaction temperature can be further reduced along with the increase of the catalyst-oil ratio; the shape-selective action of the cracking catalyst can also improve the product distribution, so as to obtain a product with shorter carbon chain; the catalytic cracking reaction speed is also much faster than the thermal cracking reaction.
The centrifugal scraper film-forming thermal cracking reaction device has strong adaptability, can completely crack polymers such as gas oil, oil residue, waste plastics and the like, has no discharge of thick oily matters and wax-like coke residues in the cracking process, does not cause carbon formation in equipment, is fast in heat transfer, and has no secondary pollution, and the end product is dry chemical products, namely carbon black powder. The cracking of waste plastics is especially characterized by high oil conversion rate, 100% conversion into gasoline, diesel oil, paraffin wax and carbon black, more outstanding performance, and solves the problems of long reaction period, incomplete cracking reaction, serious carbon formation, sticky coking of end products, secondary pollution caused by difficult cleaning and the like of the existing domestic and foreign waste plastic treatment equipment, and the worldwide problem of harmless treatment of the waste plastics.
The thermal cracking equipment in the oil refining system for recycling waste plastics through catalytic cracking is generally vertical thermal cracking equipment, the rotary scraping plate in the vertical thermal cracking equipment scrapes waste plastics heated into paste into films on the inner side wall of the vertical thermal cracking equipment, so that the heating element on the outer side wall of the vertical thermal cracking equipment is convenient for carrying out thermal cracking on the waste plastics films, the situation that the waste plastics films attached to the inner side wall of the vertical thermal cracking equipment are thin upwards and thick downwards can occur due to the action of gravity, the situation that the lower films are insufficient in thermal cracking when the thermal cracking of the films on the upper part of the vertical thermal cracking equipment is completed can be caused when the thermal cracking is carried out, the situation that glue is formed on the lower part of the inner side wall of the vertical thermal cracking equipment can occur after a long time, and carbon powder after the inner side wall of the vertical thermal cracking equipment is difficult to clean, and the production efficiency is further influenced; and the reforming reaction equipment in the existing waste plastic catalytic cracking recovery oil refining system is usually arranged as a catalytic reforming path, and when overhauling, the whole production line is stopped for overhauling, so that the production progress is influenced, and the production efficiency is reduced.
Disclosure of Invention
Aiming at the defects of the prior art, the application aims to provide a waste plastic film forming and thermal cracking device so as to solve the problems in the prior art.
According to one aspect of the present application, a waste plastic film forming and thermal cracking apparatus comprises a crushing apparatus, a conveying apparatus, a melt extrusion apparatus, a horizontal film forming and thermal cracking apparatus, a buffer sedimentation apparatus, a reforming reaction apparatus, and a condensing apparatus, wherein a feed inlet above the crushing apparatus is used for placing waste plastic, a discharge outlet below the crushing apparatus is connected with a lower end input port of the conveying apparatus, an upper end output port of the conveying apparatus is arranged above the melt extrusion apparatus, a lower charging barrel is mounted above the feed inlet of the melt extrusion apparatus, an opening of the lower charging barrel is connected with an upper end output port of the conveying apparatus, a discharge outlet of the melt extrusion apparatus is connected with a feed inlet of the horizontal film forming and thermal cracking apparatus, an oil outlet pipe for discharging oil gas is arranged outside the horizontal film forming and thermal cracking apparatus, the oil outlet pipe of the horizontal film forming and thermal cracking apparatus is connected with an inlet of the buffer sedimentation apparatus, a support base is included inside the horizontal film forming and the horizontal thermal cracking apparatus, one end of the support base is fixedly provided with a speed reducing motor, an output shaft of the speed reducing motor is fixedly connected with the rotary shaft, the speed reducing motor is fixedly connected with the rotary shaft through a shaft coupling, one end of the rotary shaft is fixedly connected with the rotary shaft, a screw shaft is fixedly connected with a film forming and thermal cracking cutter, a sealing blade is fixedly connected with one end cap and a sealing structure is arranged at the two ends of the rotary shaft are respectively, and a sealing structure is arranged at the two ends of the rotary shaft are fixedly connected with the rotary shaft and a sealing blade, the thermal cracking tube is communicated with a slag discharging tube, the lower end of the slag discharging tube is connected with a collecting bin, an oil outlet tube is communicated with the upper portion of the sealing end cover and close to the reducing motor, a filter is fixedly connected to an outlet of the buffering sedimentation device, the filter is connected with the reforming reaction device, the reforming reaction device is connected with the condensing device, an oil storage tank is fixedly connected to the lower portion of the condensing device, and a waste gas treatment tank is fixedly connected to one side of the condensing device.
Further, the inside support base that is included of horizontal film formation thermal cracking equipment, support the one end fixed mounting of base has gear motor, gear motor's output shaft fixedly connected with pivot, gear motor passes through shaft coupling fixed connection with the pivot, pivot one end fixedly connected with connecting axle, the connecting axle outside fixedly connected with spiral film formation blade and spiral cleans the structure.
Further, the periphery side of spiral film forming blade and spiral cleaning structure is provided with the thermal cracking tube, thermal cracking tube fixed mounting is on supporting the base, the both ends of thermal cracking tube are all fixed and are equipped with the end cover, the both ends of connecting axle rotate sealing connection with the end cover middle part respectively, be equipped with heating element on the lateral wall of thermal cracking tube, the thermal cracking tube is close to the below fixedly connected with slag tap pipe of gear motor's one end, thermal cracking tube and slag tap pipe communicate each other, slag tap pipe lower extreme is connected with collects the storehouse.
Further, the edge of the spiral film forming blade is provided with an inclined plane, a gap between the edge of the spiral film forming blade and the inner side wall of the thermal cracking barrel is 0.3mm-1.5mm, the inside of the spiral cleaning structure comprises a spiral supporting sheet and a cleaning steel brush, the spiral supporting sheet is arranged on the connecting shaft, the spiral edge of the spiral supporting sheet is uniformly and tightly provided with the cleaning steel brush, and the cleaning steel brush is in close contact with the inner side wall of the thermal cracking barrel.
Further, the spiral film forming blades and the spiral cleaning structure are spirally and equidistantly staggered on the connecting shaft.
Further, the thermal cracking cylinder is an assembled structure and is formed by connecting a plurality of assembled sub cylinders, connecting flanges are fixedly arranged at two ends of the assembled sub cylinders, the assembled sub cylinders are fixedly connected with the connecting flanges through bolts, each assembled sub cylinder is arranged on the supporting base, each assembled sub cylinder is provided with a heating element on the outer side wall, the spiral film forming blade, the spiral cleaning structure and the connecting shaft are assembled, the connecting shaft is formed by connecting multiple shaft sections through bolts, one section of spiral film forming blade and the spiral cleaning structure are symmetrically arranged on each shaft section, and after the connecting shafts of the multiple shaft sections are connected, the multi-section spiral film forming blade and the spiral cleaning structure form a continuous spiral structure.
Further, the buffer sedimentation equipment exit linkage has the output tube, output tube tip respectively fixedly connected with two sets of flow pipes, every the shunt tubes all establish ties a plurality of filter and one reforming reaction equipment, every the filter core of different mesh numbers has all been placed in the filter, every reforming reaction equipment below all is connected with the discharging pipe, two discharging pipe one end is fixed and is linked together there is the collecting pipe, the collecting pipe other end with condensation equipment is connected, the output tube with two the shunt tubes junction is installed first control valve, collecting pipe and two the discharging pipe junction is equipped with the second control valve.
Further, condensation equipment liquid outlet end fixedly connected with connecting pipe, a plurality of condensation equipment passes through connecting pipe series connection, the center tube with the head end condensation equipment's top is linked together, former condensation equipment lower extreme one side with the latter condensation equipment top is linked together through the connecting pipe, and the tail end condensation equipment lower extreme one side with exhaust treatment jar is linked together through the outlet duct, every condensation equipment bottom all communicates and is equipped with one the oil storage tank.
Further, a driving motor is arranged above the blanking cylinder at the feeding port of the melt extrusion device, the output end of the driving motor is fixedly connected with a rotating shaft, a spiral blade is arranged on the rotating shaft, the lower end of the blanking cylinder and the spiral blade are both in conical structures, and the edge of the spiral blade is in sliding contact with the conical inner side wall of the blanking cylinder.
The application method of the waste plastic film forming and thermal cracking device specifically comprises the following steps:
step one, putting waste plastics into a feeding hole of crushing equipment, crushing the waste plastics into small blocks by the crushing equipment, dropping the small blocks of waste plastics into an input hole at the lower end of conveying equipment from a discharge hole of the crushing equipment, and dropping the small blocks of waste plastics into a blanking barrel at the feeding hole of melt extrusion equipment from an output hole at the upper end of the conveying equipment by conveying of the conveying equipment;
step two, small-block waste plastics falling into a blanking cylinder are driven by a driving motor to drive conical spiral blades so as to be blanked into a melt extrusion device, the waste plastics are heated into paste by the melt extrusion device, and the paste waste plastics are extruded into a horizontal film-forming thermal cracking device by a screw rod in the melt extrusion device;
step three, a gear motor in the horizontal film-forming thermal cracking equipment drives a rotating shaft to rotate, so as to drive a connecting shaft to rotate, so as to drive a spiral film-forming blade and a spiral cleaning structure on the connecting shaft to rotate, so that the inclined plane at the edge of the spiral film-forming blade uniformly scrapes the pasty waste plastics into a film of 0.3mm-1.5mm on the inner side wall of the thermal cracking barrel, and meanwhile, a heating element on the outer side wall of the thermal cracking barrel heats the thermal cracking barrel to 350-450 ℃ to enable the film on the inner side wall of the thermal cracking barrel to thermally crack and vaporize to generate oil gas, the generated oil gas enters a buffer sedimentation equipment through an oil outlet pipe, the film thermally cracks and becomes carbon powder to be attached to the inner side wall of the thermal cracking barrel, and the carbon powder is cleaned and collected into a collection bin through the spiral cleaning structure;
step four, oil gas entering the buffer sedimentation device flows through an output pipe and a shunt pipe after being filtered and purified, and enters the reforming reaction device for catalytic reforming after passing through a plurality of filters, the oil gas after catalytic reforming enters a centralized pipe through a discharging pipe, the catalytic reforming path in the step four is divided into two, and when one catalytic reforming path needs to be overhauled, the catalytic reforming path is switched to the other catalytic reforming path for catalytic reforming by controlling a first control valve and a second control valve, so that continuous production without shutdown overhauling is ensured;
and fifthly, enabling the catalytically reformed oil gas to enter condensing equipment through a centralized pipe, liquefying the oil gas through the condensing action of the condensing equipment to obtain heavy oil, collecting the heavy oil into an oil storage tank below, enabling the oil gas which is not condensed and liquefied to enter the next condensing equipment through a connecting pipe, condensing and liquefying the oil again to obtain heavy oil, collecting the heavy oil into the oil storage tank below, and discharging the finally generated waste gas into a waste gas treatment tank through an air outlet pipe until the heavy oil is completely condensed and liquefied.
The application has the beneficial effects that: according to the application, the horizontal film forming thermal cracking equipment is arranged, the spiral film forming blade is horizontally arranged in the horizontal film forming thermal cracking equipment and is driven by the connecting shaft driven by the speed reducing motor, so that the spiral film forming blade uniformly scrapes pasty waste plastics into films of 0.3-1.5 mm on the inner side wall of the thermal cracking cylinder; when one of the catalytic reforming paths needs to be overhauled, the first control valve and the second control valve are controlled to be switched to the other catalytic reforming path for catalytic reforming, so that continuous production without shutdown overhauling is ensured, and the production efficiency is improved.
Drawings
Fig. 1 is a schematic view showing a construction of a thermal cracking apparatus for forming a film of waste plastics according to an embodiment of the present application.
Fig. 2 is a schematic structural view of a horizontal type film formation thermal cracking apparatus of a waste plastic film formation thermal cracking apparatus according to an embodiment of the present application.
Fig. 3 is a partial sectional view of a horizontal type film formation thermal cracking apparatus of a waste plastic film formation thermal cracking apparatus according to an embodiment of the present application.
Fig. 4 is a front sectional view of a horizontal type film formation thermal cracking apparatus of a waste plastic film formation thermal cracking apparatus according to an embodiment of the present application.
Fig. 5 is a sectional view of an assembled cartridge of a thermal cracking apparatus for forming a film of waste plastics according to an embodiment of the present application.
Fig. 6 is a partial sectional view of a discharge cylinder of a thermal cracking apparatus for forming a film of waste plastics according to an embodiment of the present application.
Reference numerals: 1. a crushing device; 2. a conveying device; 3. a melt extrusion apparatus; 4. horizontal film-forming thermal cracking equipment; 41. a support base; 42. a speed reducing motor; 43. a heating element; 44. sealing the end cover; 45. a thermal cracking vessel; 451. assembling a separating cylinder; 452. a connecting flange; 46. a spiral film forming blade; 47. a spiral cleaning structure; 471. a spiral supporting sheet; 472. cleaning a steel brush; 48. a slag discharging pipe; 49. a connecting shaft; 5. buffer sedimentation equipment; 6. reforming reaction equipment; 7. a condensing device; 8. a blanking cylinder; 9. an oil outlet pipe; 10. a filter; 11. an oil storage tank; 12. a collecting bin; 13. an exhaust gas treatment tank; 14. an inclined plane; 15. an output pipe; 16. a shunt; 17. a discharge pipe; 18. a concentration tube; 19. a first control valve; 20. a second control valve; 21. a connecting pipe; 22. an air outlet pipe; 23. a driving motor; 24. a rotation shaft; 25. a helical blade; 26. a rotating shaft.
Detailed Description
The process according to the application is described in further detail below with reference to the accompanying drawings.
The following description of the embodiments of the present application will be made clearly and completely with reference to the accompanying drawings, in which it is apparent that the embodiments described are only some embodiments of the present application, but not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the application without making any inventive effort, are intended to be within the scope of the application.
In order to make the contents of the present application more clearly understood, the technical solutions in the embodiments of the present application will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present application. It should be noted that the words "front", "rear", "left", "right", "upper" and "lower" used in the following description refer to directions in fig. 1, and the words "inner" and "outer" refer to directions toward or away from, respectively, the geometric center of a particular component. Furthermore, the terms "first," "second," and the like are used for descriptive purposes only and are not to be construed as indicating or implying relative importance.
Example 1
As shown in fig. 1 and 6, a waste plastic film-forming thermal cracking device comprises a crushing device 1, a conveying device 2, a melt extrusion device 3, a horizontal film-forming thermal cracking device 4, a buffer sedimentation device 5, a reforming reaction device 6 and a condensation device 7, wherein the crushing device 1 is used for crushing waste plastics into small blocks, a feeding port above the crushing device 1 is used for placing the waste plastics, a crushing blade is arranged in the crushing device 1 and is driven by a motor, a discharging port below the crushing device 1 is connected with a lower end input port of the conveying device 2, an upper end output port of the conveying device 2 is arranged above the melt extrusion device 3, the conveying device 2 is a conveyor belt conveyor, a lower charging barrel 8 is arranged above the feeding port of the melt extrusion device 3, an opening of the lower charging barrel 8 is connected with an upper end output port of the conveying device 2, a driving motor 23 is arranged above the lower charging barrel 8, the driving motor 23 is connected with a vertically arranged rotating shaft 24 through a connecting component, spiral blade 25 is arranged on the rotating shaft 24, the lower end of the lower charging barrel 8 and the spiral blade 25 are both arranged into a conical structure, the edge of the spiral blade 25 is in sliding contact with the inner side wall of the lower charging barrel 8 so as to facilitate the melt extrusion device 3 to be arranged in the horizontal film-forming thermal cracking device, and the waste plastics is extruded into a paste form by the paste, and the paste is extruded by the melt extrusion device 3, and the waste plastics is driven into a heating device is arranged in the horizontal film-forming thermal cracking device, and is used for extruding and is driven by the melt extrusion device 3, and is arranged in the heating device, and is used for the heating and has a low-down device;
the discharge port of the melt extrusion device 3 is communicated with the feed port of the horizontal film forming thermal cracking device 4, the outer side of the horizontal film forming thermal cracking device 4 is also heated in an electric control electric heating mode, an oil outlet pipe 9 of the horizontal film forming thermal cracking device 4 is communicated with the inlet of the buffer sedimentation device 5, the outlet of the buffer sedimentation device 5 is connected with an output pipe 15, the end part of the output pipe 15 is respectively connected with two shunt pipes 16, each shunt pipe 16 is connected with a plurality of filters 10 and a reforming reaction device 6 in series, filter elements with different meshes are arranged in each filter 10, a discharge pipe 17 is connected below each reforming reaction device 6, the two discharge pipes 17 are connected with one end of the concentration pipe 18, oil gas entering the buffer sedimentation device 5 flows through the output pipe 15 and the shunt pipes 16 after buffer sedimentation purification, and enters the reforming reaction device 6 after passing through the filters 10 for catalytic reforming, the oil gas after catalytic reforming enters the concentration pipe 18 through the discharge pipe 17, and the catalytic reforming path is divided into two independent catalytic reforming paths in the process;
the other end of the concentration pipe 18 is connected with the condensation equipment 7, a first control valve 19 is arranged at the joint of the output pipe 15 and the two shunt pipes 16, a second control valve 20 is arranged at the joint of the concentration pipe 18 and the two discharge pipes 17, a plurality of condensation equipment 7 are connected in series through a connecting pipe 21, the concentration pipe 18 is communicated with the upper part of the condensation equipment 7 at the head end, one side of the lower end of the former condensation equipment 7 is communicated with the upper part of the latter condensation equipment 7 through the connecting pipe 21, one side of the lower end of the condensation equipment 7 at the tail end is communicated with the waste gas treatment tank 13 through an air outlet pipe 22, one oil storage tank 11 is communicated with the bottom end of each condensation equipment 7, the catalytically reformed oil gas enters the condensation equipment 7 through the concentration pipe 18, the oil gas is liquefied through the condensation of the condensation equipment 7 to obtain heavy oil, and is collected into the oil storage tank 11 below through the connecting pipe 21, the oil gas which is not condensed and liquefied is obtained again and is collected into the oil storage tank 11 below until the waste gas is completely condensed and liquefied into the heavy oil, the waste gas is discharged into the waste gas treatment tank 13 through the air outlet pipe 22, and the waste gas is discharged from the waste gas treatment tank 11.
In one embodiment, referring to fig. 2 to 5, the horizontal film-forming thermal cracking apparatus 4 includes a supporting base 41, a reducing motor 42, a rotating shaft 26, a sealing end cover 44, a thermal cracking cylinder 45, a spiral film-forming blade 46, a spiral cleaning structure 47, a slag discharging pipe 48 and a collecting bin 12, wherein the reducing motor 42 is fixedly installed at one end of the supporting base 41, an output shaft of the reducing motor 42 is fixedly connected with the rotating shaft 26, the rotating shaft 26 is fixedly connected with one end of a connecting shaft 49, the spiral film-forming blade 46 and the spiral cleaning structure 47 are symmetrically arranged on the connecting shaft 49, the thermal cracking cylinder 45 is arranged at the peripheral sides of the spiral film-forming blade 46 and the spiral cleaning structure 47, the thermal cracking cylinder 45 is fixedly installed on the supporting base 41, the sealing end covers 44 are fixedly arranged at two ends of the thermal cracking cylinder 45, the two ends of the connecting shaft 49 are respectively in rotary sealing connection with the middle parts of the sealing end covers 44 at two ends, a heating element 43 is arranged on the outer side wall of the thermal cracking cylinder 45, the heating element 43 can be heated by an electromagnetic coil, the heating temperature of 350 ℃ to 450 ℃, the lower part of one end of the thermal cracking cylinder 45, which is close to the reducing motor 42, is communicated with one end of the connecting pipe 48, the slag discharging pipe 48, the lower end of the thermal cracking pipe 48 is connected with the slag discharging pipe 12, the upper end cover 44 is fixedly connected with the sealing end cover 9, and communicated with the sealing end cover 9;
specifically, the edge of the spiral film forming blade 46 is set as an inclined plane 14, and the gap between the edge of the spiral film forming blade 46 and the inner side wall of the thermal cracking barrel 45 is 0.3mm-1.5mm, the spiral cleaning structure 47 comprises a spiral supporting sheet 471 and a cleaning steel brush 472, the spiral supporting sheet 471 is arranged on the connecting shaft 49, the cleaning steel brush 472 is uniformly and tightly arranged at the spiral edge of the spiral supporting sheet 471, and the cleaning steel brush 472 is tightly contacted with the inner side wall of the thermal cracking barrel 45;
specifically, the thermal cracking cylinder 45 is an assembled structure and is formed by connecting a plurality of assembled sub-cylinders 451 with each other, connecting flanges 452 are fixedly arranged at two ends of the assembled sub-cylinders 451, the assembled sub-cylinders 451 are connected together through the fixed connection of bolts and the connecting flanges 452, each assembled sub-cylinder 451 is arranged on the supporting base 41, a heating element 43 is arranged on the outer side wall of each assembled sub-cylinder 451, the spiral film forming blade 46, the spiral cleaning structure 47 and the connecting shaft 49 are all assembled structures, the connecting shaft 49 is formed by connecting multiple shaft sections through bolts, one section of spiral film forming blade 46 and the spiral cleaning structure 47 are symmetrically arranged on each shaft section, and after the connecting shaft 49 of the multiple shaft sections is connected, the multi-section spiral film forming blade 46 and the spiral cleaning structure 47 form a continuous spiral structure, so that the assembled structure is more convenient for equipment installation;
in the above design, through the arrangement of the horizontal film forming thermal cracking equipment 4, and then the spiral film forming blade 46 horizontally arranged in the horizontal film forming thermal cracking equipment 4 rotates under the drive of the gear motor 42 and the connecting shaft 49, and then the spiral film forming blade 46 uniformly scrapes the pasty waste plastics into the film of 0.3mm-1.5mm on the inner side wall of the thermal cracking cylinder 45, compared with the vertical thermal cracking equipment, because the thermal cracking cylinder 45 of the horizontal film forming thermal cracking equipment 4 is horizontally arranged, the waste plastics film can be uniformly attached on the inner side wall of the thermal cracking cylinder 45, and then the film on the inner side wall of the thermal cracking cylinder 45 can be fully thermally cracked, and the edge of the spiral film forming blade 46 is provided with the inclined plane 14, and then the pasty waste plastics can be better and smoothly scraped on the inner side wall of the thermal cracking cylinder 45, and the spiral cleaning structure 47 is arranged, so that the cleaning steel brush 472 can clean the thermally cracked carbon powder on the inner side wall of the thermal cracking cylinder 45 into the collecting bin 12, and further the better production efficiency is ensured.
Example two
The utility model provides a waste plastic film forming thermal cracking device, including crushing equipment 1, conveying equipment 2, melt extrusion equipment 3, horizontal film forming thermal cracking equipment 4, buffering subsidence equipment 5, reforming reaction equipment 6 and condensation equipment 7, crushing equipment 1 is used for breaking waste plastic into little cubic, the feed inlet of crushing equipment 1 top is used for putting into waste plastic, be provided with crushing blade in crushing equipment 1 and pass through motor drive, the discharge gate of crushing equipment 1 below links to each other with the lower extreme input port of conveying equipment 2, the upper end delivery outlet of conveying equipment 2 sets up above melt extrusion equipment 3, conveying equipment 2 is the conveyer belt conveyer, be equipped with down feed cylinder 8 above the feed inlet of melt extrusion equipment 3, down feed cylinder 8 opening links to each other with the upper end delivery outlet of conveying equipment 2, down feed cylinder 8 top is equipped with driving motor 23, driving motor 23 is connected with the rotation axis 24 of vertical setting through coupling assembling, be provided with helical blade 25 on rotation axis 24, down feed cylinder 8 lower extreme and helical blade 25 all set up to conical inside wall sliding contact with down feed cylinder 8, in order to carry little cubic to melt extrusion equipment 3, it is used for the melt extrusion equipment 3 to be provided with the paste like, the electric screw rod is used for the thermal cracking equipment is arranged in the melt extrusion equipment 3, the paste is used for the thermal cracking equipment is arranged in the heating paste form, the thermal cracking device is used for the thermal cracking equipment is used for the heating paste to be used for the extrusion equipment is arranged in the outside, and is heated by the thermal extrusion equipment;
the discharge port of the melt extrusion device 3 is communicated with the feed port of the horizontal film forming thermal cracking device 4, the outer side of the horizontal film forming thermal cracking device 4 is also heated in an electric control electric heating mode, an oil outlet pipe 9 of the horizontal film forming thermal cracking device 4 is communicated with the inlet of the buffer sedimentation device 5, the outlet of the buffer sedimentation device 5 is connected with an output pipe 15, the end part of the output pipe 15 is respectively connected with two shunt pipes 16, each shunt pipe 16 is connected with a plurality of filters 10 and a reforming reaction device 6 in series, filter elements with different meshes are arranged in each filter 10, a discharge pipe 17 is connected below each reforming reaction device 6, the two discharge pipes 17 are connected with one end of the concentration pipe 18, oil gas entering the buffer sedimentation device 5 flows through the output pipe 15 and the shunt pipes 16 after buffer sedimentation purification, and enters the reforming reaction device 6 after passing through the filters 10 for catalytic reforming, the oil gas after catalytic reforming enters the concentration pipe 18 through the discharge pipe 17, and the catalytic reforming path is divided into two independent catalytic reforming paths in the process;
the other end of the concentration pipe 18 is connected with the condensation equipment 7, a first control valve 19 is arranged at the joint of the output pipe 15 and the two shunt pipes 16, a second control valve 20 is arranged at the joint of the concentration pipe 18 and the two discharge pipes 17, a plurality of condensation equipment 7 are connected in series through a connecting pipe 21, the concentration pipe 18 is communicated with the upper part of the condensation equipment 7 at the head end, one side of the lower end of the former condensation equipment 7 is communicated with the upper part of the latter condensation equipment 7 through the connecting pipe 21, one side of the lower end of the condensation equipment 7 at the tail end is communicated with the waste gas treatment tank 13 through an air outlet pipe 22, one oil storage tank 11 is communicated with the bottom end of each condensation equipment 7, the catalytically reformed oil gas enters the condensation equipment 7 through the concentration pipe 18, the oil gas is liquefied through the condensation of the condensation equipment 7 to obtain heavy oil, and is collected into the oil storage tank 11 below through the connecting pipe 21, the oil gas which is not condensed and liquefied is obtained again and is collected into the oil storage tank 11 below until the waste gas is completely condensed and liquefied into the heavy oil, the waste gas is discharged into the waste gas treatment tank 13 through the air outlet pipe 22, and the waste gas is discharged from the waste gas treatment tank 11.
In the design, the brush hair structure in the horizontal film-forming thermal cracking equipment is removed, so that the cracking matters generated in the operation process of the whole can be stuck in the furnace wall, the whole cannot be sufficiently cleaned, and the waste materials in the furnace wall are accumulated for a long time, so that the whole cannot be cracked normally, a large amount of time is required for cleaning, and the whole cracking effect is delayed.
The application method of the waste plastic film forming and thermal cracking device specifically comprises the following steps:
step one, putting waste plastics into a feeding hole of crushing equipment 1, crushing the waste plastics into small blocks by the crushing equipment 1, dropping the small blocks of waste plastics into an input hole at the lower end of conveying equipment 2 from a discharge hole of the crushing equipment 1, and dropping the small blocks of waste plastics into a blanking barrel 8 at the feeding hole of melt extrusion equipment 3 from an output hole at the upper end of the conveying equipment 2;
step two, driving conical spiral blades 25 by a driving motor 23 to further discharge the small-block waste plastics into a melt extrusion device 3, heating the waste plastics into paste by the melt extrusion device 3, and extruding the paste waste plastics into a horizontal film-forming thermal cracking device 4 by a screw in the melt extrusion device 3;
step three, a speed reducing motor 42 in the horizontal film forming and thermal cracking equipment 4 drives a rotating shaft 26 to rotate, and then drives a connecting shaft 49 to rotate, and then drives a spiral film forming blade 46 and a spiral cleaning structure 47 on the connecting shaft 49 to rotate, and then an inclined plane 14 at the edge of the spiral film forming blade 46 uniformly scrapes pasty waste plastics into films of 0.3mm-1.5mm on the inner side wall of a thermal cracking cylinder 45, and meanwhile, a heating element 43 on the outer side wall of the thermal cracking cylinder 45 heats the thermal cracking cylinder 45 to 350-450 ℃ to enable the films on the inner side wall of the thermal cracking cylinder 45 to instantaneously crack and gasify to generate oil gas, the generated oil gas enters a buffer sedimentation equipment 5 through an oil outlet pipe 9, the films are thermally cracked and then become carbon powder to be attached to the inner side wall of the thermal cracking cylinder 45, and the cleaning and collecting bin 12 through the spiral cleaning structure 47;
step four, oil gas entering the buffer sedimentation device 5 flows through the output pipe 15 and the shunt pipe 16 after buffer sedimentation purification, and enters the reforming reaction device 6 for catalytic reforming after passing through the plurality of filters 10, and the oil gas after catalytic reforming enters the centralized pipe 18 through the discharging pipe 17;
step five, the oil gas after catalytic reforming enters the condensing equipment 7 through the collecting pipe 18, the oil gas is liquefied through the condensing action of the condensing equipment 7 to obtain heavy oil, the heavy oil is collected into the oil storage tank 11 below, the oil gas which is not condensed and liquefied enters the next condensing equipment 7 through the connecting pipe 21, the heavy oil is obtained through condensation and liquefaction again, the heavy oil is collected into the oil storage tank 11 below until the heavy oil is completely condensed and liquefied, and finally the generated waste gas is discharged into the waste gas treatment tank 13 through the gas outlet pipe 22.
The embodiments of the present application are all preferred embodiments of the present application, and are not intended to limit the scope of the present application in this way, therefore: all equivalent changes in structure, shape and principle of the application should be covered in the scope of protection of the application.

Claims (9)

1. The utility model provides a waste plastic film forming thermal cracking device, includes crushing equipment (1), conveying equipment (2), melt extrusion equipment (3), horizontal film forming thermal cracking equipment (4), buffering subsides equipment (5), reforming reaction equipment (6) and condensation equipment (7), its characterized in that: the device is characterized in that a feed inlet is formed in the upper part of the crushing equipment (1), a discharge outlet below the crushing equipment (1) is connected with a lower end input port of the conveying equipment (2), an upper end output port of the conveying equipment (2) is arranged above the melt extrusion equipment (3), a discharging barrel (8) is arranged above the feed inlet of the melt extrusion equipment (3), an opening of the discharging barrel (8) is connected with an upper end output port of the conveying equipment (2), a discharge outlet of the melt extrusion equipment (3) is communicated with a feed inlet of the horizontal film-forming thermal cracking equipment (4), an oil outlet pipe (9) is arranged outside the horizontal film-forming thermal cracking equipment (4), the oil outlet pipe (9) of the horizontal film-forming thermal cracking equipment (4) is communicated with an inlet of the buffer sedimentation equipment (5), a filter (10) is fixedly connected to an outlet of the buffer sedimentation equipment (5), the filter (10) is connected with the reforming reaction equipment (6), the reforming reaction equipment (6) is connected with the condensing equipment (7), and the condensing equipment (7) is fixedly connected with an oil storage tank (13) and one side of the condensing equipment (7).
The horizontal film forming thermal cracking equipment (4) comprises a supporting base (41), one end of the supporting base (41) is fixedly provided with a gear motor (42), an output shaft of the gear motor (42) is fixedly connected with a rotating shaft (26), the gear motor (42) is fixedly connected with the rotating shaft (26) through a coupler, one end of the rotating shaft (26) is fixedly connected with a connecting shaft (49), and the outer side of the connecting shaft (49) is fixedly connected with a spiral film forming blade (46) and a spiral cleaning structure (47).
2. The waste plastic film forming and thermal cracking device according to claim 1, wherein a thermal cracking tube (45) is arranged on the outer peripheral side of the spiral film forming blade (46) and the spiral cleaning structure (47), the thermal cracking tube (45) is fixedly arranged on the supporting base (41), sealing end covers (44) are fixedly arranged at two ends of the thermal cracking tube (45), two ends of the connecting shaft (49) are respectively and rotatably and hermetically connected with the middle part of the sealing end covers (44), a heating element (43) is arranged on the outer side wall of the thermal cracking tube (45), a slag discharging tube (48) is fixedly connected below one end of the thermal cracking tube (45) close to the reducing motor (42), the thermal cracking tube (45) is mutually communicated with the slag discharging tube (48), and a collecting bin (12) is connected to the lower end of the slag discharging tube (48).
3. The waste plastic film forming and thermal cracking device as claimed in claim 2, wherein an inclined plane (14) is arranged at the edge of the spiral film forming blade (46), a gap between the edge of the spiral film forming blade (46) and the inner side wall of the thermal cracking cylinder (45) is 0.3mm-1.5mm, a spiral supporting sheet (471) and a cleaning steel brush (472) are arranged inside the spiral cleaning structure (47), the spiral supporting sheet (471) is arranged on the connecting shaft (49), the cleaning steel brush (472) is uniformly arranged at the spiral edge of the spiral supporting sheet (471), and the cleaning steel brush (472) is in contact with the inner side wall of the thermal cracking cylinder (45).
4. A waste plastics film forming and thermal cracking apparatus as claimed in claim 3 wherein said spiral film forming blades (46) and said spiral cleaning structure (47) are spirally and equi-spaced staggered on a connecting shaft (49).
5. The waste plastic film forming and thermal cracking device as claimed in claim 4, wherein the thermal cracking barrel (45) is of an assembled structure and is formed by connecting a plurality of assembled sub-barrels (451), connecting flanges (452) are fixedly arranged at two ends of the assembled sub-barrels (451), the assembled sub-barrels (451) are fixedly connected with the connecting flanges (452) through bolts, each assembled sub-barrel (451) is arranged on the supporting base (41), a heating element (43) is arranged on the outer side wall of each assembled sub-barrel (451), the spiral film forming blades (46), the spiral cleaning structures (47) and the connecting shafts (49) are of an assembled structure, the connecting shafts (49) are formed by connecting multiple shaft sections through bolts, one section of spiral film forming blades (46) and the spiral cleaning structures (47) are symmetrically arranged on each shaft section, and after the connecting shafts (49) of the multiple shaft sections are connected, the multiple sections of spiral film forming blades (46) and the spiral cleaning structures (47) form a continuous spiral structure.
6. The waste plastic film forming and thermal cracking device according to claim 5, wherein an outlet of the buffer sedimentation device (5) is connected with an output pipe (15), two groups of flow pipes (16) are fixedly connected to the end parts of the output pipe (15), each flow pipe (16) is connected with a plurality of filters (10) and one reforming reaction device (6) in series, filter cores with different meshes are placed in each filter (10), a discharge pipe (17) is connected below each reforming reaction device (6), one end of each discharge pipe (17) is fixed and communicated with a concentration pipe (18), the other end of each concentration pipe (18) is connected with the condensation device (7), a first control valve (19) is installed at the joint of each output pipe (15) and each flow pipe (16), and a second control valve (20) is installed at the joint of each concentration pipe (18) and each discharge pipe (17).
7. The waste plastic film forming and thermal cracking device according to claim 6, wherein a connecting pipe (21) is fixedly connected to the liquid outlet end of the condensing equipment (7), a plurality of condensing equipment (7) are connected in series through the connecting pipe (21), the concentration pipe (18) is communicated with the upper part of the condensing equipment (7) at the head end, one side of the lower end of the former condensing equipment (7) is communicated with the upper part of the latter condensing equipment (7) through the connecting pipe (21), one side of the lower end of the tail condensing equipment (7) is communicated with the waste gas treatment tank (13) through an air outlet pipe (22), and one oil storage tank (11) is communicated with the bottom end of each condensing equipment (7).
8. The waste plastic film forming and thermal cracking device according to claim 7, wherein a driving motor (23) is installed above a discharging barrel (8) at a feeding hole of the melt extrusion equipment (3), an output end of the driving motor (23) is fixedly connected with a rotating shaft (24), a spiral blade (25) is arranged on the rotating shaft (24), the lower end of the discharging barrel (8) and the spiral blade (25) are both in conical structures, and the edge of the spiral blade (25) is in sliding contact with the conical inner side wall of the discharging barrel (8).
9. The method for using the waste plastic film forming and thermal cracking device according to claim 8, which is characterized by comprising the following steps:
step one, putting waste plastics into a feeding hole of crushing equipment (1), crushing the waste plastics into small blocks through the crushing equipment (1), dropping the small blocks of waste plastics into an input hole at the lower end of conveying equipment (2) from a discharge hole of the crushing equipment (1), and dropping the small blocks of waste plastics into a blanking cylinder (8) at the feeding hole of melt extrusion equipment (3) from an output hole at the upper end of the conveying equipment (2) through conveying of the conveying equipment (2);
step two, driving conical spiral blades (25) by a driving motor (23) to further discharge the small-block waste plastics into a melt extrusion device (3), heating the waste plastics into paste by the melt extrusion device (3), and extruding the paste waste plastics into a horizontal film-forming thermal cracking device (4) by a screw in the melt extrusion device (3);
step three, a reducing motor (42) in the horizontal film-forming thermal cracking equipment (4) drives a rotating shaft (26) to rotate, then drives a connecting shaft (49) to rotate, then drives a spiral film-forming blade (46) and a spiral cleaning structure (47) on the connecting shaft (49) to rotate, then an inclined plane (14) at the edge of the spiral film-forming blade (46) uniformly scrapes pasty waste plastics into films of 0.3mm-1.5mm on the inner side wall of a thermal cracking cylinder (45), and meanwhile a heating element (43) on the outer side wall of the thermal cracking cylinder (45) heats the thermal cracking cylinder (45) to 350-450 ℃ to enable the films on the inner side wall of the thermal cracking cylinder (45) to thermally crack and gasify to generate oil gas, the generated oil gas enters a buffer sedimentation equipment (5) through an oil outlet pipe (9), and the films are changed into carbon powder to be attached to the inner side wall of the thermal cracking cylinder (45) after being cleaned by the spiral cleaning structure (47) and collected into a collecting bin (12);
step four, oil gas entering the buffer sedimentation device (5) flows through an output pipe (15) and a shunt pipe (16) after being filtered and purified, and enters the reforming reaction device (6) to be subjected to catalytic reforming after passing through a plurality of filters (10), the oil gas after catalytic reforming enters a centralized pipe (18) through a discharging pipe (17), a catalytic reforming path is divided into two, and when one catalytic reforming path needs to be overhauled, the oil gas is switched into the other catalytic reforming path to be subjected to catalytic reforming through controlling a first control valve (19) and a second control valve (20);
step five, the oil gas after catalytic reforming enters a condensing device (7) through a collecting pipe (18), the oil gas is liquefied through the condensing action of the condensing device (7) to obtain heavy oil, the heavy oil is collected into an oil storage tank (11) below, the oil gas which is not completely condensed and liquefied enters the next condensing device (7) through a connecting pipe (21), the heavy oil is obtained through condensation and liquefaction again, the heavy oil is collected into the oil storage tank (11) below, the heavy oil is completely condensed and liquefied, and finally the generated waste gas is discharged into a waste gas treatment tank (13) through a gas outlet pipe (22).
CN202311148258.1A 2023-09-07 2023-09-07 Waste plastic film forming and thermal cracking device and method Pending CN116872397A (en)

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CN117270478B (en) * 2023-11-20 2024-01-23 江苏华旭环卫科技有限公司 Production control system for waste plastic film forming and thermal cracking device

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