CN116746585A - Sterilization composition containing pyraclostrobin - Google Patents
Sterilization composition containing pyraclostrobin Download PDFInfo
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- CN116746585A CN116746585A CN202310858919.3A CN202310858919A CN116746585A CN 116746585 A CN116746585 A CN 116746585A CN 202310858919 A CN202310858919 A CN 202310858919A CN 116746585 A CN116746585 A CN 116746585A
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- CN
- China
- Prior art keywords
- pyraclostrobin
- bactericidal composition
- late blight
- composition containing
- fluorothiazole
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000005869 Pyraclostrobin Substances 0.000 title claims abstract description 27
- HZRSNVGNWUDEFX-UHFFFAOYSA-N pyraclostrobin Chemical compound COC(=O)N(OC)C1=CC=CC=C1COC1=NN(C=2C=CC(Cl)=CC=2)C=C1 HZRSNVGNWUDEFX-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 239000000203 mixture Substances 0.000 title claims abstract description 20
- 230000001954 sterilising effect Effects 0.000 title claims abstract description 7
- 238000004659 sterilization and disinfection Methods 0.000 title claims abstract description 5
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 17
- 241000233622 Phytophthora infestans Species 0.000 claims abstract description 12
- 239000004480 active ingredient Substances 0.000 claims abstract description 7
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
- IAQLCKZJGNTRDO-UHFFFAOYSA-N 1-(4-{4-[5-(2,6-difluorophenyl)-4,5-dihydro-1,2-oxazol-3-yl]-1,3-thiazol-2-yl}piperidin-1-yl)-2-[5-methyl-3-(trifluoromethyl)-1H-pyrazol-1-yl]ethanone Chemical compound CC1=CC(C(F)(F)F)=NN1CC(=O)N1CCC(C=2SC=C(N=2)C=2CC(ON=2)C=2C(=CC=CC=2F)F)CC1 IAQLCKZJGNTRDO-UHFFFAOYSA-N 0.000 claims 1
- 239000005812 Oxathiapiprolin Substances 0.000 claims 1
- 239000000575 pesticide Substances 0.000 abstract description 3
- FDPIMTJIUBPUKL-UHFFFAOYSA-N pentan-3-one Chemical compound CCC(=O)CC FDPIMTJIUBPUKL-UHFFFAOYSA-N 0.000 abstract 4
- 238000012360 testing method Methods 0.000 description 11
- 230000001988 toxicity Effects 0.000 description 8
- 231100000419 toxicity Toxicity 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 239000003814 drug Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 5
- 230000002195 synergetic effect Effects 0.000 description 5
- 230000001580 bacterial effect Effects 0.000 description 4
- 239000003899 bactericide agent Substances 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- 201000010099 disease Diseases 0.000 description 3
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 3
- 230000002401 inhibitory effect Effects 0.000 description 3
- 241000233654 Oomycetes Species 0.000 description 2
- 244000061456 Solanum tuberosum Species 0.000 description 2
- 235000002595 Solanum tuberosum Nutrition 0.000 description 2
- 235000009754 Vitis X bourquina Nutrition 0.000 description 2
- 235000012333 Vitis X labruscana Nutrition 0.000 description 2
- 240000006365 Vitis vinifera Species 0.000 description 2
- 235000014787 Vitis vinifera Nutrition 0.000 description 2
- 244000052616 bacterial pathogen Species 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000009036 growth inhibition Effects 0.000 description 2
- 239000001963 growth medium Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 230000001018 virulence Effects 0.000 description 2
- PRYIJAGAEJZDBO-ZEQHCUNVSA-N 5,6alpha-epoxy-5alpha-cholestan-3beta-ol Chemical compound C([C@]12O[C@H]1C1)[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 PRYIJAGAEJZDBO-ZEQHCUNVSA-N 0.000 description 1
- 235000017060 Arachis glabrata Nutrition 0.000 description 1
- 244000105624 Arachis hypogaea Species 0.000 description 1
- 235000010777 Arachis hypogaea Nutrition 0.000 description 1
- 235000018262 Arachis monticola Nutrition 0.000 description 1
- 241000235349 Ascomycota Species 0.000 description 1
- 241000221198 Basidiomycota Species 0.000 description 1
- BOMXNVKTSSSTNJ-UHFFFAOYSA-N C1CC=NO1.C1CCN(CC1)c1nccs1 Chemical compound C1CC=NO1.C1CCN(CC1)c1nccs1 BOMXNVKTSSSTNJ-UHFFFAOYSA-N 0.000 description 1
- 102000014914 Carrier Proteins Human genes 0.000 description 1
- 235000009024 Ceanothus sanguineus Nutrition 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- ACTIUHUUMQJHFO-UHFFFAOYSA-N Coenzym Q10 Natural products COC1=C(OC)C(=O)C(CC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)C)=C(C)C1=O ACTIUHUUMQJHFO-UHFFFAOYSA-N 0.000 description 1
- 240000007154 Coffea arabica Species 0.000 description 1
- 244000241257 Cucumis melo Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- 102100030497 Cytochrome c Human genes 0.000 description 1
- 108010075031 Cytochromes c Proteins 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 101000992383 Homo sapiens Oxysterol-binding protein 1 Proteins 0.000 description 1
- 240000007049 Juglans regia Species 0.000 description 1
- 235000009496 Juglans regia Nutrition 0.000 description 1
- 240000003553 Leptospermum scoparium Species 0.000 description 1
- 235000015459 Lycium barbarum Nutrition 0.000 description 1
- 240000008790 Musa x paradisiaca Species 0.000 description 1
- 235000018290 Musa x paradisiaca Nutrition 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 102000004316 Oxidoreductases Human genes 0.000 description 1
- 108090000854 Oxidoreductases Proteins 0.000 description 1
- 102100032163 Oxysterol-binding protein 1 Human genes 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
- 241000233679 Peronosporaceae Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 108091008324 binding proteins Proteins 0.000 description 1
- -1 chieves Species 0.000 description 1
- 235000017471 coenzyme Q10 Nutrition 0.000 description 1
- ACTIUHUUMQJHFO-UPTCCGCDSA-N coenzyme Q10 Chemical compound COC1=C(OC)C(=O)C(C\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CCC=C(C)C)=C(C)C1=O ACTIUHUUMQJHFO-UPTCCGCDSA-N 0.000 description 1
- 235000016213 coffee Nutrition 0.000 description 1
- 235000013353 coffee beverage Nutrition 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 235000021186 dishes Nutrition 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 244000037666 field crops Species 0.000 description 1
- 244000053095 fungal pathogen Species 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- LVWZTYCIRDMTEY-UHFFFAOYSA-N metamizole Chemical compound O=C1C(N(CS(O)(=O)=O)C)=C(C)N(C)N1C1=CC=CC=C1 LVWZTYCIRDMTEY-UHFFFAOYSA-N 0.000 description 1
- 230000008811 mitochondrial respiratory chain Effects 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000008177 pharmaceutical agent Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- FGVVTMRZYROCTH-UHFFFAOYSA-N pyridine-2-thiol N-oxide Chemical compound [O-][N+]1=CC=CC=C1S FGVVTMRZYROCTH-UHFFFAOYSA-N 0.000 description 1
- 229960002026 pyrithione Drugs 0.000 description 1
- NPCOQXAVBJJZBQ-UHFFFAOYSA-N reduced coenzyme Q9 Natural products COC1=C(O)C(C)=C(CC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)C)C(O)=C1OC NPCOQXAVBJJZBQ-UHFFFAOYSA-N 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000004763 spore germination Effects 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229940035936 ubiquinone Drugs 0.000 description 1
- 235000020234 walnut Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P3/00—Fungicides
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to the technical field of pesticides, and provides a sterilization composition which contains active ingredients of oxathiapiprazole ethyl ketone and pyraclostrobin, wherein the weight percentage of the oxathiapiprazole ethyl ketone and the pyraclostrobin is 10:1-1:50. The invention also relates to the bactericidal composition for preventing and treating potato late blight and the like.
Description
Technical Field
The invention belongs to the technical field of pesticides, and relates to a bactericidal composition containing fluorothiazole pyraclostrobin and pyraclostrobin, which is used for preventing and treating potato late blight and the like.
Background
Fluothiapyr-diethyl ketone is the first piperidinyl thiazole isoxazoline bactericide developed by DuPont, has a unique action site on oomycete pathogenic bacteria, and achieves a bactericidal effect by inhibiting cholesterol oxide binding protein (OSBP). It has effects of preventing, treating and inhibiting spore production for pathogenic bacteria; it has no cross resistance with the existing bactericide, and has excellent prevention effect on downy mildew and epidemic diseases of crops such as melon, vegetable, potato, grape and the like. But the fluorothiazole has single action site, has medium and high level resistance risk and needs to be subjected to resistance management.
Pyraclostrobin is the most novel methoxy acrylic bactericide of Basiff company. Pyraclostrobin inhibits the activity of mitochondrial respiratory chain complex enzyme III (ubiquinone-cytochrome c oxidoreductase ) in pathogenic fungi, so that electrons cannot be transferred from ubiquinone to cytochrome c, and bacterial ATP cannot be normally synthesized, and finally the bacterial cells die due to energy deficiency. It can control most diseases of ascomycetes, basidiomycetes, semi-known fungus, oomycetes, etc. Has strong inhibiting effect on spore germination and mycelium growth in leaves, and has protective and therapeutic activities. Has permeability and local systemic activity, long lasting period and rain wash resistance. Is widely used for preventing and controlling diseases of wheat, rice, peanut, grape, vegetable, potato, banana, lemon, coffee, fruit tree, walnut, tea tree, tobacco, ornamental plant, lawn and other field crops. The compound is not only low in toxicity, safe to non-target organisms, but also safe and friendly to both the user and the environment, and has been classified by the U.S. EPA as a "risk-reducing candidate agent".
There is no report in the prior art about the combined use of fluorothiazole and pyraclostrobin.
Disclosure of Invention
The invention aims to provide a bactericidal composition which has obvious synergistic effect and can delay resistance and reduce the use amount.
In order to solve the problems, the invention adopts the following technical scheme:
the bactericidal composition containing the fluorothiazole and the pyraclostrobin comprises the active ingredients of the fluorothiazole and the pyraclostrobin, and the mass ratio of the fluorothiazole to the pyraclostrobin is 10:1-1:50. Preferably, the mass ratio of the oxathiapiprazole ethyl to the pyraclostrobin is 1:20-1:40. The mass ratio of the more preferable oxathiapiprazole ethyl to the pyraclostrobin is 1:30.
The weight percentage of the active ingredients in the bactericidal composition is 5-80%. The preferred weight percentage of active ingredient is 10-50%.
The bactericidal composition has remarkable effect on preventing and treating potato late blight, and the performance of the bactericidal composition is obviously better than that of a single dose.
The invention has the advantages that: the two components are compounded, the synergistic effect is obvious in a certain range, the dosage can be reduced, and the cost can be reduced; resistance can be delayed; high safety, environmental protection.
Description of the embodiments
The invention is illustrated by the following specific examples, but is by no means limited thereto, in order to make the objects, technical solutions and advantages of the invention more apparent. The percentages in the examples are by weight.
Embodiment 1: indoor toxicity determination test for potato late blight by compounding fluorothiazole pyrithione and pyraclostrobin
Test materials:
potato late blight germPhytophthora infestans) The method comprises the steps of carrying out a first treatment on the surface of the And (5) field collection and identification, and indoor living body culture preservation.
The testing method comprises the following steps:
referring to pesticide indoor biological test criterion bactericide, the inhibition rate of the single agent to be tested on potato late blight is measured by adopting a hypha growth rate method. Under the aseptic operation condition, a sterilized triangular flask (with the calibration quantity of 50 mL) which is calibrated accurately in advance is respectively added with liquid medicines with different concentrations of 2.0 mL by a liquid transfer device, then a culture medium which is melted and cooled to a proper temperature is added into the triangular flask to a calibrated scale mark of 50 mL, and the culture medium is poured into 4 culture dishes (phi 9 cm) in equal quantity after being shaken uniformly, so that a medicine-containing oat plate with corresponding concentration is prepared. Then, the potato late blight bacteria which are cultivated in advance are inoculated in the center of a medicine-containing flat plate by an inoculator by cutting a bacterial cake from the edge of a bacterial colony by a sterilization puncher with phi 5 mm under the aseptic condition, the mycelium surface is upward, a dish cover is covered, and the potato late blight bacteria are placed in a biochemical incubator with the relative humidity of 80% at 22+/-1 ℃ for dark cultivation, and the test result is observed. Stopping the test when the colony grows to the size of 2/3-4/5 of the diameter of the culture dish according to the control group treatment culture dish, measuring the colony growth diameter of the test bacteria by using a crisscross method, and calculating the hypha growth inhibition rate of each treatment concentration on the test strain according to the measurement result.
Hypha growth inhibition (%) = (control colony growth diameter-treated colony growth diameter)/control colony growth diameter×100
Then DPS data processing software is used for calculating test results, and respectively solving virulence regression equations, EC of single test medicament and mixed medicaments with different proportions 50 And EC (EC) 90 And comparing synergistic conditions, and calculating the co-toxicity coefficient (CTC) of the compound medicament mixture according to a grand cloud Pei method. The co-toxicity coefficient (CTC) is calculated as follows:
actual measurement of virulence index (ATI)= (EC of standard pharmaceutical agent 50 EC of test agent 50 ) × 100
Theoretical Toxicity Index (TTI) =toxicity index of agent a x percent of agent a in the mix + toxicity index of agent B x percent of agent B in the mix
Co-toxicity coefficient (CTC) = (ATI/TTI) ×100
According to the division standard of co-toxicity coefficient (CTC), CTC is less than or equal to 80 and is antagonism, CTC 80 is additive, CTC is greater than or equal to 120 and is synergistic.
Toxicity measurement results:
TABLE 1 results of indoor Combined toxicity measurements of Fluothiapyrad-ethyl and pyraclostrobin for potato late blight
| Medicament and proportion | Toxicity regression equation (Y=) | EC 50 （mg/L） | EC 90 （mg/L） | Co-toxicity coefficient (CTC) |
| Fluothiazole pyridone (A) | 1.7327x+10.6823 | 0.000525 | 0.002885 | - |
| Pyraclostrobin (B) | 1.6812x+5.5016 | 0.503105 | 2.910440 | - |
| A:B（10:1） | 1.61x+10.3633 | 0.000466 | 0.002916 | 123.92 |
| A:B（1:1） | 1.657x+10.0966 | 0.000840 | 0.004984 | 125.01 |
| A:B（1:10） | 1.6973x+8.9837 | 0.004498 | 0.025587 | 127.19 |
| A:B（1:20） | 1.5324x+8.205 | 0.008099 | 0.055560 | 133.46 |
| A:B（1:30） | 1.7683x+8.4338 | 0.011433 | 0.060657 | 138.15 |
| A:B（1:40） | 1.7242x+8.123 | 0.015442 | 0.085502 | 133.92 |
| A:B（1:50） | 1.6541x+7.8055 | 0.020131 | 0.119854 | 126.51 |
As can be seen from Table 1, when the fluzopyr-ethyl ketone and the pyraclostrobin are compounded within the range of 10:1-1:50, the co-toxicity coefficient (CTC) is more than 120, the synergistic effect is shown on potato late blight, and particularly when the mass ratio of the fluzopyr-ethyl ketone to the pyraclostrobin is 1:30, the compounding effect is optimal.
In conclusion, the sterilizing composition of the invention is compounded by the oxathiapiprazole and the pyraclostrobin, has remarkable synergism on potato late blight, expands a sterilizing spectrum, can delay resistance, is safe to crops, can reduce dosage, and is safe to environment.
Claims (6)
1. The bactericidal composition containing pyraclostrobin is characterized in that the active ingredients comprise fluorothiazole pyraclostrobin and pyraclostrobin, and the mass ratio of the fluorothiazole pyraclostrobin to the pyraclostrobin is 10:1-1:50.
2. The sterilization composition according to claim 1, wherein the mass ratio of the oxathiapiprazole ethyl to the pyraclostrobin is 1:20-1:40.
3. The bactericidal composition of claim 1, wherein the mass ratio of the oxathiapiprolin to the pyraclostrobin is 1:30.
4. A bactericidal composition according to any of claims 1-3, wherein the active ingredient is present in an amount of 5-80% by weight.
5. The bactericidal composition of claim 4, wherein the active ingredient is present in an amount of 10 to 50% by weight.
6. The bactericidal composition according to any one of claims 1 to 5 for controlling potato late blight and the like.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202310858919.3A CN116746585A (en) | 2023-07-13 | 2023-07-13 | Sterilization composition containing pyraclostrobin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202310858919.3A CN116746585A (en) | 2023-07-13 | 2023-07-13 | Sterilization composition containing pyraclostrobin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN116746585A true CN116746585A (en) | 2023-09-15 |
Family
ID=87957164
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202310858919.3A Pending CN116746585A (en) | 2023-07-13 | 2023-07-13 | Sterilization composition containing pyraclostrobin |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN116746585A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20120034315A1 (en) * | 2009-04-22 | 2012-02-09 | E.I. Du Pont De Nemours And Company | Solid forms of an azocyclic amide |
| CN104642360A (en) * | 2013-11-19 | 2015-05-27 | 陕西汤普森生物科技有限公司 | Sterilization composition containing fluorothiazole pyriethanone and methoxyl acrylate |
| CN104663674A (en) * | 2007-10-23 | 2015-06-03 | 杜邦公司 | Fungicidal Mixtures |
| CN108450471A (en) * | 2018-03-12 | 2018-08-28 | 佛山市盈辉作物科学有限公司 | A kind of seed coat agent containing fluorine azoles bacterium aniline, pyraclostrobin and fluorine thiazole pyrrole ethyl ketone |
-
2023
- 2023-07-13 CN CN202310858919.3A patent/CN116746585A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104663674A (en) * | 2007-10-23 | 2015-06-03 | 杜邦公司 | Fungicidal Mixtures |
| US20120034315A1 (en) * | 2009-04-22 | 2012-02-09 | E.I. Du Pont De Nemours And Company | Solid forms of an azocyclic amide |
| CN102459256A (en) * | 2009-04-22 | 2012-05-16 | 纳幕尔杜邦公司 | Solid forms of an azocyclic amide |
| CN104642360A (en) * | 2013-11-19 | 2015-05-27 | 陕西汤普森生物科技有限公司 | Sterilization composition containing fluorothiazole pyriethanone and methoxyl acrylate |
| CN107125247A (en) * | 2013-11-19 | 2017-09-05 | 陕西汤普森生物科技有限公司 | A kind of bactericidal composition of fluorine-containing thiazole pyrrole ethyl ketone and methoxy acrylic |
| CN108450471A (en) * | 2018-03-12 | 2018-08-28 | 佛山市盈辉作物科学有限公司 | A kind of seed coat agent containing fluorine azoles bacterium aniline, pyraclostrobin and fluorine thiazole pyrrole ethyl ketone |
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