CN116289241A - Functional leather and preparation method thereof - Google Patents
Functional leather and preparation method thereof Download PDFInfo
- Publication number
- CN116289241A CN116289241A CN202310111081.1A CN202310111081A CN116289241A CN 116289241 A CN116289241 A CN 116289241A CN 202310111081 A CN202310111081 A CN 202310111081A CN 116289241 A CN116289241 A CN 116289241A
- Authority
- CN
- China
- Prior art keywords
- leather
- surface modification
- parts
- resin layer
- expanded vermiculite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000010985 leather Substances 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title abstract description 7
- 239000011347 resin Substances 0.000 claims abstract description 42
- 229920005989 resin Polymers 0.000 claims abstract description 42
- 230000004048 modification Effects 0.000 claims abstract description 23
- 238000012986 modification Methods 0.000 claims abstract description 23
- 239000004744 fabric Substances 0.000 claims abstract description 19
- 239000010455 vermiculite Substances 0.000 claims abstract description 18
- 229910052902 vermiculite Inorganic materials 0.000 claims abstract description 18
- 235000019354 vermiculite Nutrition 0.000 claims abstract description 18
- 239000000843 powder Substances 0.000 claims abstract description 9
- 239000002002 slurry Substances 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 10
- 239000003381 stabilizer Substances 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 9
- 239000002270 dispersing agent Substances 0.000 claims description 6
- 239000000945 filler Substances 0.000 claims description 6
- 238000004140 cleaning Methods 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 238000006116 polymerization reaction Methods 0.000 claims description 4
- 238000005096 rolling process Methods 0.000 claims description 4
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical group [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 abstract description 16
- 229910052760 oxygen Inorganic materials 0.000 abstract description 16
- -1 oxygen ions Chemical class 0.000 abstract description 16
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 230000004071 biological effect Effects 0.000 abstract description 4
- 150000002500 ions Chemical class 0.000 abstract description 4
- 239000002649 leather substitute Substances 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 2
- 230000008499 blood brain barrier function Effects 0.000 abstract description 2
- 210000001218 blood-brain barrier Anatomy 0.000 abstract description 2
- 230000008014 freezing Effects 0.000 abstract description 2
- 238000007710 freezing Methods 0.000 abstract description 2
- 210000005260 human cell Anatomy 0.000 abstract description 2
- 238000009413 insulation Methods 0.000 abstract description 2
- 230000000694 effects Effects 0.000 description 3
- 150000001450 anions Chemical class 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000013441 quality evaluation Methods 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 238000004887 air purification Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical group [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000035790 physiological processes and functions Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0009—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using knitted fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/06—Properties of the materials having thermal properties
- D06N2209/065—Insulating
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/06—Properties of the materials having thermal properties
- D06N2209/067—Flame resistant, fire resistant
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/1671—Resistance to bacteria, mildew, mould, fungi
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
- D06N2211/28—Artificial leather
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2213/00—Others characteristics
- D06N2213/02—All layers being of the same kind of material, e.g. all layers being of polyolefins, all layers being of polyesters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
- Y02P70/62—Manufacturing or production processes characterised by the final manufactured product related technologies for production or treatment of textile or flexible materials or products thereof, including footwear
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Abstract
The invention discloses a functional leather and a preparation method thereof, belonging to the field of artificial leather production, wherein the leather sequentially comprises a base cloth layer, a resin layer and a surface modification layer from bottom to top, the surface modification layer with the function of generating negative oxygen ions is adopted, expanded vermiculite powder is adopted as a substance for generating the negative oxygen ions, water in the leather surface and air can be hydrolyzed to generate air negative ions, and the low-energy excited negative ions are OH ‑ (H 2 O) n The small-particle-size nano negative ions are mainly used, have good biological activity, are easy to penetrate through the blood brain barrier of the human body and enter human cells to exert biological effects, so that the leather provided by the invention has certain functionality and meets the requirements of modern high-quality life; the expanded vermiculite adopted by the invention has excellent properties such as heat insulation, freezing resistance, antibacterial property, fireproof property and the like, and the leather property is improved by adding the expanded vermiculite into the surface modification layer.
Description
Technical Field
The invention belongs to the field of artificial leather production, and particularly relates to functional leather and a preparation method thereof.
Background
The artificial leather has the advantages of soft touch and hand feeling, advanced appearance, large reformable space and the like, and gradually replaces the application of natural leather. Along with the continuous improvement of the living standard of people, higher requirements are also put on the functionality and the health of the artificial leather. Negative oxygen ions are the generic term for single gas molecules and hydrogen ion groups that are negatively charged. In the natural ecosystem, forests and wetlands are important places for generating negative oxygen ions, and have the effects of regulating the physiological functions of human bodies, eliminating fatigue, improving sleep, preventing diseases and the like, and also have the effects of regulating the air purification, the urban microclimate and the like. At present, the concentration level of negative oxygen ions is one of important indexes for air quality evaluation, and the concentration level of the negative oxygen ions is one of indexes for urban air quality evaluation. If negative oxygen ions are introduced into leather, the leather can be endowed with certain functionality and conditioning property, and can be used for manufacturing clothes, sofas, furniture and the like. At present, various problems exist in the process of introducing negative oxygen ions into leather, and the following aspects are mainly included: negative oxygen ions are mixed into leather, so that the negative oxygen ions are difficult to release in the use process; the large amount of the substance generating negative oxygen ions results in high manufacturing cost.
Disclosure of Invention
The invention provides a functional leather and a preparation method thereof, wherein natural vermiculite is adopted to generate negative oxygen ions, so that the production cost is reduced, and the functional leather is easy to disperse in the leather re-preparation process.
In order to achieve the above purpose, the invention adopts the following technical scheme:
a functional leather, which comprises a base cloth layer, a resin layer and a surface modification layer from bottom to top;
the base fabric is elastic knitted fabric;
the resin layer comprises the following components in parts by weight: 80-100 parts of PVC resin, 5-15 parts of filler and 1-1.5 parts of stabilizer; the PVC resin is PVC resin with polymerization degree of 1000-1500; the stabilizer is a calcium-zinc stabilizer;
the surface modification layer comprises the following components in parts by weight: 70-80 parts of PVC resin, 2-4 parts of expanded vermiculite powder and 0.2-0.5 part of dispersing agent, wherein the expanded vermiculite powder is silvery white expanded vermiculite.
A method for preparing functional leather, comprising the following steps:
step 1: and (3) base cloth treatment: cleaning the selected base cloth material for later use;
step 2: preparing a resin layer: uniformly mixing PVC resin, filler and stabilizer at 50-60 ℃ to obtain resin layer slurry, and rolling the resin layer slurry on the surface of the base cloth;
step 3: preparing a surface modification layer: uniformly mixing the expanded vermiculite, the PVC resin and the dispersing agent at 50-60 ℃ to obtain surface modification layer slurry; and (2) when the resin layer in the step (2) is in a semi-dry state, coating the surface modification layer slurry on the resin layer, and drying to obtain the functional leather.
In the steps, the dispersing time in the step 2 is 30-60min, and the mixing time in the step 3 is 4-6 hours.
The beneficial effects are that: the invention provides a functional leather and a preparation method thereof, wherein a surface modification layer with the function of generating negative oxygen ions is adopted, expanded vermiculite powder is adopted as a substance for generating the negative oxygen ions, the adopted silvery expanded vermiculite powder is a capacitor structure formed by highly insulating lamellar mica sheets, a large amount of charges in air can be adsorbed, after gradually accumulated charges touch water molecules, discharge ionization effect can be generated at the edge of the lamellar mica sheets, water in the leather surface and the air can be generated to generate air anions, and the anions excited by low energy are OH - (H 2 O) n The small-particle-size nano negative ions are mainly used, have good biological activity, are easy to penetrate through the blood brain barrier of the human body and enter human cells to exert biological effects, so that the leather provided by the invention has certain functionality and meets the requirements of modern high-quality life; the expanded vermiculite adopted by the invention has excellent properties such as heat insulation, freezing resistance, antibacterial property, fireproof property and the like, and the leather property is improved by adding the expanded vermiculite into the surface modification layer.
Detailed Description
The invention will be described in detail with reference to specific examples below:
example 1
A method for preparing functional leather, comprising the following steps:
step 1: and (3) base cloth treatment: cleaning the selected double-sided knitted elastic base cloth material for later use;
step 2: preparing a resin layer: mixing 100 parts by weight of PVC resin with the polymerization degree of 1500, 15 parts of filler and 1.5 parts of stabilizer at 60 ℃ for 60min to obtain resin layer slurry, and rolling the resin layer slurry on the surface of the base cloth;
step 3: preparing a surface modification layer: mixing 80 parts of PVC resin, 4 parts of silvery expanded vermiculite powder and 0.5 part of dispersing agent at 60 ℃ for 6 hours to obtain surface modification layer slurry; and (2) when the resin layer in the step (2) is in a semi-dry state, coating the surface modification layer slurry on the resin layer, and drying to obtain the functional leather.
The negative oxygen ion generation amount of the functional leather prepared by the method is 9435/cm 3 。
Example 2
A method for preparing functional leather, comprising the following steps:
step 1: and (3) base cloth treatment: cleaning the selected double-sided knitted elastic base cloth material for later use;
step 2: preparing a resin layer: mixing 80 parts by weight of PVC resin with the polymerization degree of 1500, 10 parts of filler and 1.5 parts of stabilizer at 60 ℃ for 60min to obtain resin layer slurry, and rolling the resin layer slurry on the surface of the base cloth;
step 3: preparing a surface modification layer: 70 parts of PVC resin, 3 parts of silvery expanded vermiculite powder and 0.5 part of dispersing agent are mixed for 6 hours at 60 ℃ to obtain surface modification layer slurry; and (2) when the resin layer in the step (2) is in a semi-dry state, coating the surface modification layer slurry on the resin layer, and drying to obtain the functional leather.
The negative oxygen ion generation amount of the functional leather prepared by the method is 8769/cm 3 。
Although the present invention has been described in detail with reference to the embodiments, it should be understood that the invention is not limited to the preferred embodiments, but is capable of modification and equivalents to some of the features described in the foregoing embodiments, but is intended to cover all modifications, equivalents, and alternatives falling within the spirit and principles of the invention.
Claims (7)
1. A functional leather is characterized in that a base cloth layer, a resin layer and a surface modification layer are sequentially arranged from bottom to top; the resin layer comprises the following components in parts by weight: 80-100 parts of PVC resin, 5-15 parts of filler and 1-1.5 parts of stabilizer; the surface modification layer comprises the following components in parts by weight: 70-80 parts of PVC resin, 2-4 parts of expanded vermiculite powder and 0.2-0.5 part of dispersing agent.
2. The functional leather of claim 1, wherein the base fabric is an elastic knitted fabric.
3. The functional leather of claim 1, wherein the PVC resin in the resin layer is a PVC resin having a degree of polymerization of 1000-1500; the stabilizer is calcium-zinc stabilizer.
4. The functional leather of claim 1, wherein the expanded vermiculite powder is silvery expanded vermiculite.
5. A method for preparing functional leather, which is characterized by comprising the following steps:
step 1: and (3) base cloth treatment: cleaning the selected base cloth material for later use;
step 2: preparing a resin layer: uniformly mixing PVC resin, filler and stabilizer at 50-60 ℃ to obtain resin layer slurry, and rolling the resin layer slurry on the surface of the base cloth;
step 3: preparing a surface modification layer: uniformly mixing the expanded vermiculite, the PVC resin and the dispersing agent at 50-60 ℃ to obtain surface modification layer slurry; and (2) when the resin layer in the step (2) is in a semi-dry state, coating the surface modification layer slurry on the resin layer, and drying to obtain the functional leather.
6. The method for preparing functional leather according to claim 5, wherein the dispersing time of step 2 is 30-60min.
7. The method for preparing functional leather according to claim 5, wherein the mixing time in step 3 is 4-6 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202310111081.1A CN116289241A (en) | 2023-02-13 | 2023-02-13 | Functional leather and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202310111081.1A CN116289241A (en) | 2023-02-13 | 2023-02-13 | Functional leather and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN116289241A true CN116289241A (en) | 2023-06-23 |
Family
ID=86793251
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202310111081.1A Pending CN116289241A (en) | 2023-02-13 | 2023-02-13 | Functional leather and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN116289241A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104928913A (en) * | 2014-03-19 | 2015-09-23 | 上海斯米克控股股份有限公司 | Textile fabric capable of releasing negative ions |
| CN105696360A (en) * | 2016-04-29 | 2016-06-22 | 储著国 | PVC artificial leather capable of efficiently releasing negative ions and preparation method thereof |
| CN107189138A (en) * | 2017-06-20 | 2017-09-22 | 合肥市淑芹美装饰工程有限公司 | A kind of rubber floor covering and preparation method thereof |
| CN107747232A (en) * | 2017-10-11 | 2018-03-02 | 容颖琳 | A kind of efficiently release anion PVC calendared artificial leathers and its manufacture method |
| CN112080942A (en) * | 2020-09-08 | 2020-12-15 | 清远市腾翔皮革有限公司 | Anti-cracking leather and production method thereof |
| CN114892411A (en) * | 2022-06-02 | 2022-08-12 | 浙江昶丰新材料有限公司 | Negative oxygen ion water-based bio-based sofa leather and preparation method thereof |
-
2023
- 2023-02-13 CN CN202310111081.1A patent/CN116289241A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104928913A (en) * | 2014-03-19 | 2015-09-23 | 上海斯米克控股股份有限公司 | Textile fabric capable of releasing negative ions |
| CN105696360A (en) * | 2016-04-29 | 2016-06-22 | 储著国 | PVC artificial leather capable of efficiently releasing negative ions and preparation method thereof |
| CN107189138A (en) * | 2017-06-20 | 2017-09-22 | 合肥市淑芹美装饰工程有限公司 | A kind of rubber floor covering and preparation method thereof |
| CN107747232A (en) * | 2017-10-11 | 2018-03-02 | 容颖琳 | A kind of efficiently release anion PVC calendared artificial leathers and its manufacture method |
| CN112080942A (en) * | 2020-09-08 | 2020-12-15 | 清远市腾翔皮革有限公司 | Anti-cracking leather and production method thereof |
| CN114892411A (en) * | 2022-06-02 | 2022-08-12 | 浙江昶丰新材料有限公司 | Negative oxygen ion water-based bio-based sofa leather and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104928826B (en) | A kind of radiation proof antibacterial and deodouring fabric and preparation method thereof | |
| CN111019359A (en) | High-temperature-resistant antibacterial silicone rubber and preparation method thereof | |
| CN105820642A (en) | Wall surface putty adsorbing formaldehyde and continuously releasing anions and preparation method thereof | |
| CN114835971B (en) | High-elasticity breathable Ai Caofen foaming composite material and preparation method and application thereof | |
| CN116289241A (en) | Functional leather and preparation method thereof | |
| WO2012148116A2 (en) | Naturally dyed functional latex foam and method for producing same | |
| CN1654739A (en) | Method for preparing PVC leatheroid and PU synthetic leather with high efficiency release of negative ions | |
| CN1036084C (en) | Far-infrared radiation fabric and its production method | |
| CN106703355A (en) | Production method of wall surface decoration materials capable of generating negative oxygen ions | |
| CN105769551A (en) | Acupuncture and moxibustion health-preserving tank | |
| CN104624214A (en) | Novel accelerant indoor air improver and production method | |
| CN104847064A (en) | Health-care ceramic tile and manufacturing method thereof | |
| CN109852167A (en) | It is a kind of that liquid occurring applied to the anion sprayed on object or material | |
| CN107990451A (en) | A kind of polymolecular air negative oxgyen ion generating means | |
| CN102417793B (en) | Electromagnetic wave shielding nanometer fragrant brightener capable of releasing trace element negative ions | |
| CN109577583B (en) | Wall surface soft package and construction method thereof | |
| CN113768320B (en) | Health-care mattress and preparation method thereof | |
| CN111172747A (en) | Anti-ultraviolet fabric and preparation method and application thereof | |
| CN2738756Y (en) | Warm potential therapy device | |
| KR200326158Y1 (en) | Beb using carbon molding panel | |
| CN101328323A (en) | Negative ion far infrared multifunctional ecological antibiotic inner wall emulsion paint and preparing process thereof | |
| CN104957921A (en) | Mattress with negative ion function and far infrared magnet therapy function | |
| CN110760105A (en) | Preparation method of tourmaline powder-based latex mattress | |
| KR101485370B1 (en) | A Far Infrared Rays Radiator And the Manufacturing Method Obtained by An Anodizing Treatment | |
| CN108527975A (en) | A kind of antistatic spontaneous heating quilt cover cloth |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |