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CN115997783A - Solid medicament for killing wood bees and preparation and use methods thereof - Google Patents

Solid medicament for killing wood bees and preparation and use methods thereof Download PDF

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Publication number
CN115997783A
CN115997783A CN202211735090.XA CN202211735090A CN115997783A CN 115997783 A CN115997783 A CN 115997783A CN 202211735090 A CN202211735090 A CN 202211735090A CN 115997783 A CN115997783 A CN 115997783A
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medicament
insecticide
solid
bees
organic solvent
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CN202211735090.XA
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Inventor
张斌
马星霞
张景朋
蒋明亮
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Research Institute of Wood Industry of Chinese Academy of Forestry
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Research Institute of Wood Industry of Chinese Academy of Forestry
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

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Abstract

The application provides a solid pesticide for preventing and treating wood bees and a preparation and use method thereof, wherein the solid pesticide comprises the following components in percentage by mass: 0.5-5% of organophosphorus insecticide, 0.5-2% of pyrethroid insecticide, 30-60% of organic solvent and the balance of curing agent; the active ingredients of the medicament are organophosphorus insecticide and pyrethroid insecticide, and the medicament has the combination of fumigation, contact killing and stomach poisoning effects when in use. When the wooden bee nest is used, the medicament is manufactured into a medicament strip with the diameter of about 8-10mm according to the characteristics of nest holes left when wooden bees endanger wood, and the medicament strip is directly put into the entrance of the wooden honeycomb nest or directly seals the entrance of the nest, can be further firmly adhered by an adhesive tape, and can kill the whole nest wooden bees through fumigation. The medicament obtained by the invention is simple to use, convenient to operate, free from polluting the surrounding environment and convenient for large-scale popularization and use.

Description

Solid medicament for killing wood bees and preparation and use methods thereof
Technical Field
The invention relates to the technical field of pest control, in particular to a solid medicament for killing wood bees and a preparation and application method thereof.
Background
Most of the traditional buildings in China contain wood structures, and wood is easily damaged by various insects due to the natural characteristics of the wood, such as termites, silverfish, longhornworm, wood bees and the like, so that the bearing capacity of the wood and the structural stability of the building are seriously threatened. The wood bees are punched and nest in the wood, the stability of the wood structure is seriously damaged, the wood bees bite through the palate, the nest with the diameter of about 1cm and the depth of up to more than 50cm is damaged on the wood product, the nest is internally and all around and is divided into 2-3 layers for spawning and overwintering. The wood bees are used to nest at higher places such as eaves and roof beams, the control effect of spraying insecticide is simple, and development of a proper insecticide is urgently needed. The Chinese pesticide information network is used for inquiring the key word of the wood bees, no registration information of the prevention and treatment agent is found, and other patent and technical documents are also not reported. In order to better protect the safety of traditional buildings in China, development of a suitable wood-killing bee medicament is urgently needed.
Disclosure of Invention
The invention aims at providing a solid pesticide for preventing and treating wood bees.
The second purpose of the invention is to provide a preparation method of the solid pesticide for controlling wood bees.
The invention also aims to provide a use method of the solid pesticide for preventing and treating the wood bees.
In order to achieve the above object, the present invention provides the following technical solutions:
the solid pesticide for preventing and controlling the wood bees comprises the following components in percentage by mass: 0.5-5% of organophosphorus insecticide, 0.5-2% of pyrethroid insecticide, 30-60% of organic solvent and the balance of curing agent;
the active ingredients of the medicament are organophosphorus insecticide and pyrethroid insecticide, and the medicament has the combination of fumigation, contact killing and stomach poisoning effects when in use.
The organic solvent is selected from the following substances with better solubility and low volatility: glycerol, propylene glycol, DMF, 150# solvent oil, n-butanol, methyl oleate, isopropanol, and ethanol.
The curing agent is selected from the following substances with higher melting points or stronger viscosity: 58# solid paraffin, microcrystalline wax, polyethylene glycol, carboxymethyl cellulose, stearic acid (sodium).
The curing agent comprises the following components in percentage by mass in the total medicament: 5-10% of 58# solid paraffin, 0.2-0.5% of carboxymethyl cellulose, 10-20% of polyethylene glycol (20 000) and 5-10% of sodium stearate.
The organophosphorus insecticide is selected from malathion, dichlorvos and methyl pyrifos, and the pyrethroid insecticide is selected from deltamethrin, cypermethrin and lambda-cyhalothrin.
The solid insecticide for controlling wood bees according to the above, wherein the agent is selected from one of the following components:
formulation 1: 5+/-1% of malathion, 2+/-1% of deltamethrin, 31.5+/-5% of a curing agent and the balance of an organic solvent, wherein the curing agent comprises 58# solid paraffin, polyethylene glycol (20 000) and sodium stearate, and the organic solvent comprises 150# solvent oil, n-butanol, glycerol and isopropanol;
formulation 2: 0.5+/-0.1% of dichlorvos, 0.5+/-0.1% of cypermethrin, 32+/-5% of curing agent and the balance of organic solvent, wherein the curing agent comprises microcrystalline wax, 58# solid paraffin, polyethylene glycol (20 000) and sodium stearate, and the organic solvent comprises methyl oleate, propylene glycol and isopropanol;
formulation 3: 2.5+/-0.5% of methyl pyrimidine phosphorus, 2+/-0.4% of lambda-cyhalothrin, 30+/-5% of curing agent and the balance of organic solvent, wherein the curing agent comprises carboxymethyl cellulose, 58# solid paraffin, polyethylene glycol (20 000) and sodium stearate, and the organic solvent comprises methyl oleate, DMF and ethanol.
A method for preparing the solid medicament for preventing and treating wood bees, wherein,
1. weighing organic solvent according to the components of the medicament, and placing the organic solvent in a container;
2. weighing a curing agent according to the components of the medicament, and adding the curing agent into the container;
3. heating the mixture of the organic solvent and the curing agent to 70-90 ℃, and electromagnetically stirring until the solid is melted to form homogeneous liquid;
4. the preparation method comprises the steps of weighing organophosphorus insecticide and pyrethroid insecticide which are active ingredients of the preparation according to the preparation ingredients, adding the organophosphorus insecticide and the pyrethroid insecticide into the container, stirring and dissolving uniformly, pouring the mixture into a mould for cooling and shaping, and obtaining the finished product of the preparation.
The application method of the solid medicament for preventing and treating wood bees comprises the following steps:
1. determining nest holes left when wood is damaged by the wood bees;
2. taking 2-4 g of solid medicament, and preparing the medicament into a medicament strip with the diameter of 8-10mm in a soft and plastic state which is easy to shape before the organic solvent is completely volatilized;
3. placing the medicinal strips into the inlets of the nest holes and/or blocking the inlets of the nest holes, and keeping for 3-7 days to kill all wood bees in the nest;
the method has the effects of fumigation, contact killing and stomach poisoning.
In the step 3, the medicine strip is further firmly adhered by using adhesive tape.
Is used for preventing and treating Huang Xiongmu bees, trichogramma, long wood bees, collar wood bees, and longhornet and larvae thereof.
Compared with the prior art, the invention has the beneficial effects that:
the solid wood bee killing agent is prepared by screening and shaping the pesticide with fumigating, contact killing and stomach poisoning effects, so that the pesticide is convenient to apply, the nest-formed wood bees can be killed, and the gap of high-efficiency wood bee control is filled.
The medicament of the invention has the following characteristics: the product is solid and non-flowable at room temperature, has soft texture, is wax-like and non-wax, can be shaped arbitrarily, has pungent smell, is insoluble in water, and has poor hydrophilicity. The product becomes hard when exposed to air for a long time, and the volume is slightly reduced.
The application method of the invention is simple, about 2-3g of solid insecticide is directly taken by using simple tools such as a spoon and the like to be blocked at the entrance of the wood honeycomb cavity, and the insecticide has self-adhesive property and can be adhered at the opening; the medicament has high content of active ingredients, not only has fumigating active ingredients, but also has contact killing and stomach poisoning active ingredients, can quickly kill the wood bees in the nest, and is an ideal medicament for preventing and treating the wood bees of the historic building wood structure.
The selected pesticide contains the organophosphorus pesticide with better fumigation effect and the pyrethroid pesticide with main effects of contact killing and stomach poisoning, and is prepared into a solid form, so that the pesticide is simple to use, convenient to operate, free from pollution to surrounding environment and convenient to popularize and use on a large scale.
Drawings
Fig. 1 is a photograph of wood chip spacing of wood larvae in a wood hive when the wood is compromised by the wood hive.
Detailed Description
The present invention will be described in detail with reference to the following examples.
The composition for preventing and treating trichogramma provided by the invention is prepared by taking organophosphorus insecticide and pyrethroid insecticide with fumigation effect as active ingredients and adding other auxiliary ingredients.
The solid pesticide for preventing and controlling the wood bees comprises the following components in percentage by mass: 0.5-5% of organophosphorus insecticide, 0.5-2% of pyrethroid insecticide, 30-60% of organic solvent and the balance of curing agent.
The organic solvent is a common solvent with good solubility and poor volatility, and comprises glycerol, propylene glycol, DMF, 150# solvent oil and the like.
And the curing agent is a substance with higher melting point or higher viscosity, and comprises solid paraffin, microcrystalline wax, polyethylene glycol, carboxymethyl cellulose, stearic acid (sodium) and the like.
In the curing agent, 5-10% of 58# solid paraffin, 0.5-1% of carboxymethyl cellulose and 10-20% of polyethylene glycol (20 000).
Specifically, the agent may be agent 1, agent 2, or agent 3.
The active ingredients of the medicament 1 and the mass percentages of the active ingredients in the medicament 1 are respectively 5+/-1% of malathion and 2+/-1% of deltamethrin.
The active ingredients of the medicament 2 and the mass percentages of the active ingredients in the medicament 2 are 0.5+/-0.1% of dichlorvos and 0.5+/-0.1% of cypermethrin respectively.
The active ingredients of the medicament 3 and the mass percentages of the active ingredients in the medicament 3 are 2.5 plus or minus 0.5 percent of methyl pyrimidine phosphorus and 2 plus or minus 0.4 percent of high-efficiency cyhalothrin respectively.
The medicament contains a solvent. The solvent is any mixture of methyl oleate, no. 150 solvent oil, glycerol, propylene glycol, DMF, no. 150 solvent oil and the like. The solvent is preferably any mixture of methyl oleate, dimethylformamide (DMF) and propylene glycol.
The medicament contains a solidifying agent. The curing agent is any mixture of microcrystalline wax, 58# solid paraffin, polyethylene glycol, carboxymethyl cellulose, stearic acid (sodium) and the like. The curing agent is preferably any mixture of 58# solid paraffin, polyethylene glycol and carboxymethyl cellulose.
Specifically, the medicament 1 comprises, by mass, 5% of malathion, 2% of deltamethrin, 10% of 58# solid paraffin, 15% of polyethylene glycol (20 000), 6.5% of sodium stearate, 20% of 150# solvent oil, 10% of n-butanol, 5% of glycerol and 26.5% of isopropanol.
The medicament 2 comprises, by mass, 0.5% of dichlorvos, 0.5% of cypermethrin, 2% of microcrystalline wax, 5% of 58# solid paraffin, 20% of polyethylene glycol (20 000), 5% of sodium stearate, 20% of methyl oleate, 15% of propylene glycol and 32% of isopropanol.
The medicament 3 comprises 2.5% of pyrimidyl phosphorus, 2% of lambda-cyhalothrin, 0.2% of carboxymethyl cellulose, 5% of 58# solid paraffin, 20% of polyethylene glycol (20 000), 5% of sodium stearate, 20% of methyl oleate, 5% of DMF and 32% of ethanol.
Further, the medicament 1 may be prepared according to a method comprising the steps of: 5.26g of 95% malathion crude drug and 2.04g of 98% deltamethrin crude drug are weighed, and in a 500mL beaker, 20g of 150# solvent oil, 10g of n-butanol, 5g of glycerol and 26.5g of isopropanol are respectively weighed and added, and the crude drugs are completely dissolved under electromagnetic stirring. Then, continuously adding 10g of 58# solid paraffin, 15g of polyethylene glycol (20 000) and 6.5g of sodium stearate, heating to 65 ℃, stirring and dissolving uniformly, pouring into a mould, cooling and shaping to obtain the medicament 1.
The medicament 2 may be prepared according to a method comprising the steps of: respectively weighing and adding 20g of methyl oleate, 15g of propylene glycol and 32g of isopropanol, continuously adding 2% of microcrystalline wax, 5% of 58# solid paraffin, 20% of polyethylene glycol (20 000) and 5% of sodium stearate into a 500mL round bottom flask, heating to reflux, stirring and dissolving uniformly, then weighing 0.53g of 95% dichlorvos and 0.53g of 95% cypermethrin, completely dissolving the raw materials under electromagnetic stirring, pouring into a mould, and cooling and shaping to obtain the medicament 2.
The medicament 3 may be prepared according to a method comprising the steps of: 2.63g of 95% methyl pyrimidine phosphorus crude drug and 2.04g of 98% high-efficiency cyhalothrin crude drug are weighed, 25g of 200# solvent oil, 15g of n-butyl alcohol, 10g of DMSO and 29.8g of propylene glycol are respectively weighed and added into a 500mL beaker, and the crude drugs are completely dissolved under electromagnetic stirring. Then, continuously adding 15g of 58# solid paraffin, 15g of polyethylene glycol (20 000) and 0.5g of chitosan, heating to 65 ℃, stirring and dissolving uniformly, pouring into a mould, cooling and shaping to obtain the medicament 3.
Wherein, 95% dichlorvos: shandong chemical Co., ltd.
95% of methyl pyrimidine phosphorus original drug: a Sail Biotechnology group Co., ltd.
98% lambda-cyhalothrin, 98% deltamethrin and 98% cypermethrin: jiangsu Yangnong chemical Co., ltd.
A preparation method of a solid pesticide for controlling wood bees comprises the following steps: heating and dissolving the curing agent in an organic solvent, adding the active ingredients, fully dissolving, uniformly mixing, pouring into a mould, cooling and shaping to obtain the finished product of the product.
The invention also provides a use method of the solid pesticide for controlling wood bees, which comprises the following steps:
taking about 2g of finished product, and plugging at the wood honeycomb cave entrance, wherein the solid medicament is softer before the organic solvent is completely volatilized, is easy to shape, and can well plug the wood honeycomb cave entrance. And killing all wood bees in the nest within 3-7 days.
In the invention, the harmful pests in the wood structure building are mainly different types of wood bees, such as Huang Xiongmu bees, trichogramma, longhorn bees and the like, and also can be longhorn beetles and larvae thereof. When the solid insecticide is used, the solid insecticide can be directly plugged into nest inlets of pests, and the pests in the whole nest can be killed through fumigation.
According to the characteristics of nest holes left when wood is damaged by wood bees, the medicament is manufactured into a medicament strip with the diameter of about 8-10mm, and the medicament is directly put into the entrance of the wood bees when in use, or directly seals the entrance of the nest, can be further firmly adhered by adhesive tapes, and can kill the whole nest wood bees through fumigation.
Biological Activity test
According to the method, the solid insecticide agent 1 is prepared, 100g of the solid insecticide agent 1 is prepared, about 3g of the solid insecticide agent 1 is taken in the evening of 29 days of 4 months of 2022, the solid insecticide agent 1 is directly plugged into the entrance of a wooden honeycomb hole, and after 5 days, the wooden honeycomb is planed to observe the survival state of the wooden honeycomb. 6 wood beehives are treated in total. Table 1 is statistics of survival status of wood bees after treatment.
TABLE 1 insecticidal Activity of solid insecticide blocking Apis cerana nest (5 days)
Figure BDA0004033476360000061
From table 1 it can be seen that the solid insecticide is fast and effective in killing wood wasp adults in the hives, the adult mortality rate of 6 hives is 100%, and only the outermost one of the larvae is killed. Analyzing the reason, the wood bee larvae have intervals formed by wood chips, and as shown in figure 1, the gas medicament is difficult to quickly permeate, so that the medicament has low activity of killing the larvae in a short time; moreover, the nest inlet is blocked, the adult tries to fly out of the nest inlet and is necessarily contacted with the solid insecticide, and the contact killing and stomach poisoning effects of the insecticide can also accelerate death of the adult. The solid insecticide is used for preventing and controlling the timing of taking the medicine, the wooden bees just end hibernation and do not lay eggs in the beginning of 3 months in winter every year, the habit of the wooden bees for homing in the evening can be utilized, and the solid insecticide is used for killing the adult wooden bees in a concentrated time.

Claims (10)

1. A solid insecticide for controlling wood bees, which is characterized in that: the solid pesticide comprises the following components in percentage by mass: 0.5-5% of organophosphorus insecticide, 0.5-2% of pyrethroid insecticide, 30-60% of organic solvent and the balance of curing agent;
the active ingredients of the medicament are organophosphorus insecticide and pyrethroid insecticide, and the medicament has the combination of fumigation, contact killing and stomach poisoning effects when in use.
2. A solid insecticide according to claim 1, wherein the organic solvent is selected from the group consisting of the following relatively soluble or less volatile substances: glycerol, propylene glycol, DMF, 150# solvent oil, n-butanol, methyl oleate, isopropanol, and ethanol.
3. A solid insecticide according to claim 1, wherein the solidifying agent is selected from the group consisting of the following higher melting or higher viscosity materials: 58# solid paraffin, microcrystalline wax, polyethylene glycol, carboxymethyl cellulose, stearic acid (sodium).
4. The solid insecticide for controlling wood bees according to claim 1, wherein the curing agent comprises the following components in percentage by mass based on the total amount of the insecticide: 5-10% of 58# solid paraffin, 0.2-0.5% of carboxymethyl cellulose, 10-20% of polyethylene glycol (20 000) and 5-10% of sodium stearate.
5. The solid insecticide for controlling wood bees of claim 1, wherein said organophosphorus insecticide is selected from one of malathion, dichlorvos and methyl pyrifos, and said pyrethroid insecticide is selected from one of deltamethrin, cypermethrin and lambda-cyhalothrin.
6. A solid insecticide for controlling wood bees as claimed in claim 1, wherein the agent is selected from one of the following ingredients:
formulation 1: 5+/-1% of malathion, 2+/-1% of deltamethrin, 31.5+/-5% of a curing agent and the balance of an organic solvent, wherein the curing agent comprises 58# solid paraffin, polyethylene glycol (20 000) and sodium stearate, and the organic solvent comprises 150# solvent oil, n-butanol, glycerol and isopropanol;
formulation 2: 0.5+/-0.1% of dichlorvos, 0.5+/-0.1% of cypermethrin, 32+/-5% of curing agent and the balance of organic solvent, wherein the curing agent comprises microcrystalline wax, 58# solid paraffin, polyethylene glycol (20 000) and sodium stearate, and the organic solvent comprises methyl oleate, propylene glycol and isopropanol;
formulation 3: 2.5+/-0.5% of methyl pyrimidine phosphorus, 2+/-0.4% of lambda-cyhalothrin, 30+/-5% of curing agent and the balance of organic solvent, wherein the curing agent comprises carboxymethyl cellulose, 58# solid paraffin, polyethylene glycol (20 000) and sodium stearate, and the organic solvent comprises methyl oleate, DMF and ethanol.
7. A method for preparing the solid medicament for controlling wood bees according to claim 1, wherein: the method comprises the following steps:
1. weighing organic solvent according to the components of the medicament, and placing the organic solvent in a container;
2. weighing a curing agent according to the components of the medicament, and adding the curing agent into the container;
3. heating the mixture of the organic solvent and the curing agent to 70-90 ℃, and electromagnetically stirring until the solid is melted to form homogeneous liquid;
4. the preparation method comprises the steps of weighing organophosphorus insecticide and pyrethroid insecticide which are active ingredients of the preparation according to the preparation ingredients, adding the organophosphorus insecticide and the pyrethroid insecticide into the container, stirring and dissolving uniformly, pouring the mixture into a mould for cooling and shaping, and obtaining the finished product of the preparation.
8. A method of using the solid medicament for controlling wood bees according to claim 1, comprising the steps of:
1. determining nest holes left when wood is damaged by the wood bees;
2. taking 2-4 g of solid medicament, and preparing the medicament into a medicament strip with the diameter of 8-10mm in a soft and plastic state which is easy to shape before the organic solvent is completely volatilized;
3. placing the medicinal strips into the inlets of the nest holes and/or blocking the inlets of the nest holes, and keeping for 3-7 days to kill all wood bees in the nest;
the method has the effects of fumigation, contact killing and stomach poisoning.
9. The method of using a solid medicament for controlling wood bees according to claim 8, wherein in the step 3, the medicinal strip is further adhered by an adhesive tape.
10. The method of claim 8, wherein the agent is used for controlling Huang Xiongmu bees, trichogramma, longhornet, collar bees, longhornet and larvae thereof.
CN202211735090.XA 2022-12-31 2022-12-31 Solid medicament for killing wood bees and preparation and use methods thereof Pending CN115997783A (en)

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