CN115887256A - Application of batyl alcohol in hair washing and caring products and hair washing and caring products containing batyl alcohol - Google Patents
Application of batyl alcohol in hair washing and caring products and hair washing and caring products containing batyl alcohol Download PDFInfo
- Publication number
- CN115887256A CN115887256A CN202211209519.1A CN202211209519A CN115887256A CN 115887256 A CN115887256 A CN 115887256A CN 202211209519 A CN202211209519 A CN 202211209519A CN 115887256 A CN115887256 A CN 115887256A
- Authority
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- China
- Prior art keywords
- hair
- shampoo
- hair washing
- children
- batyl alcohol
- Prior art date
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- Granted
Links
- 210000004209 hair Anatomy 0.000 title claims abstract description 144
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical compound CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 title claims abstract description 96
- 238000005406 washing Methods 0.000 title claims abstract description 73
- IWWCATWBROCMCW-UHFFFAOYSA-N batyl alcohol Natural products CCCCCCCCCCCCCCCCCCOC(O)CO IWWCATWBROCMCW-UHFFFAOYSA-N 0.000 title claims abstract description 48
- 239000002453 shampoo Substances 0.000 claims abstract description 71
- 206010015946 Eye irritation Diseases 0.000 claims abstract description 21
- 231100000013 eye irritation Toxicity 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000001035 drying Methods 0.000 claims abstract description 8
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 20
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 13
- JDRSMPFHFNXQRB-CMTNHCDUSA-N Decyl beta-D-threo-hexopyranoside Chemical compound CCCCCCCCCCO[C@@H]1O[C@H](CO)C(O)[C@H](O)C1O JDRSMPFHFNXQRB-CMTNHCDUSA-N 0.000 claims description 12
- LWZFANDGMFTDAV-BURFUSLBSA-N [(2r)-2-[(2r,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O LWZFANDGMFTDAV-BURFUSLBSA-N 0.000 claims description 12
- 229940073499 decyl glucoside Drugs 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- 229950006451 sorbitan laurate Drugs 0.000 claims description 12
- 235000011067 sorbitan monolaureate Nutrition 0.000 claims description 12
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 10
- MQFYRUGXOJAUQK-UHFFFAOYSA-N 2-[2-[2-(2-octadecanoyloxyethoxy)ethoxy]ethoxy]ethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOCCOCCOCCOC(=O)CCCCCCCCCCCCCCCCC MQFYRUGXOJAUQK-UHFFFAOYSA-N 0.000 claims description 10
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 10
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 claims description 10
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims description 10
- 229940073507 cocamidopropyl betaine Drugs 0.000 claims description 10
- 229920006037 cross link polymer Polymers 0.000 claims description 10
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims description 10
- 229960005323 phenoxyethanol Drugs 0.000 claims description 10
- 239000011780 sodium chloride Substances 0.000 claims description 10
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 claims description 9
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 9
- 229940081733 cetearyl alcohol Drugs 0.000 claims description 9
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 claims description 9
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 claims description 9
- 210000004087 cornea Anatomy 0.000 claims description 8
- 229920000642 polymer Polymers 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 8
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 claims description 7
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 7
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 206010019049 Hair texture abnormal Diseases 0.000 claims description 6
- 210000000795 conjunctiva Anatomy 0.000 claims description 6
- -1 dimethiconol Chemical compound 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 239000002243 precursor Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 229940047642 disodium cocoamphodiacetate Drugs 0.000 claims description 4
- 239000002304 perfume Substances 0.000 claims description 4
- 229960000541 cetyl alcohol Drugs 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000008236 heating water Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 230000002265 prevention Effects 0.000 claims description 2
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims 3
- 230000000694 effects Effects 0.000 abstract description 25
- 230000007794 irritation Effects 0.000 abstract description 17
- 238000012360 testing method Methods 0.000 description 18
- 239000000126 substance Substances 0.000 description 9
- 238000002474 experimental method Methods 0.000 description 8
- OVBJJZOQPCKUOR-UHFFFAOYSA-L EDTA disodium salt dihydrate Chemical compound O.O.[Na+].[Na+].[O-]C(=O)C[NH+](CC([O-])=O)CC[NH+](CC([O-])=O)CC([O-])=O OVBJJZOQPCKUOR-UHFFFAOYSA-L 0.000 description 6
- 230000003750 conditioning effect Effects 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 239000006260 foam Substances 0.000 description 6
- 238000005187 foaming Methods 0.000 description 6
- 230000002633 protecting effect Effects 0.000 description 6
- 210000004761 scalp Anatomy 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 5
- 239000013068 control sample Substances 0.000 description 5
- 210000000554 iris Anatomy 0.000 description 5
- 239000003945 anionic surfactant Substances 0.000 description 4
- 230000009286 beneficial effect Effects 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 150000003863 ammonium salts Chemical group 0.000 description 3
- 230000002708 enhancing effect Effects 0.000 description 3
- 230000004044 response Effects 0.000 description 3
- 230000000638 stimulation Effects 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- 230000001154 acute effect Effects 0.000 description 2
- 229940044197 ammonium sulfate Drugs 0.000 description 2
- 238000009960 carding Methods 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 231100000286 mucous membrane, eye irritation or corrosion testing Toxicity 0.000 description 2
- BOUCRWJEKAGKKG-UHFFFAOYSA-N n-[3-(diethylaminomethyl)-4-hydroxyphenyl]acetamide Chemical compound CCN(CC)CC1=CC(NC(C)=O)=CC=C1O BOUCRWJEKAGKKG-UHFFFAOYSA-N 0.000 description 2
- 210000003491 skin Anatomy 0.000 description 2
- 210000001519 tissue Anatomy 0.000 description 2
- 239000002888 zwitterionic surfactant Substances 0.000 description 2
- LXAHHHIGZXPRKQ-UHFFFAOYSA-N 5-fluoro-2-methylpyridine Chemical compound CC1=CC=C(F)C=N1 LXAHHHIGZXPRKQ-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000251730 Chondrichthyes Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 206010033546 Pallor Diseases 0.000 description 1
- 229920000289 Polyquaternium Polymers 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 229940082500 cetostearyl alcohol Drugs 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003026 cod liver oil Substances 0.000 description 1
- 235000012716 cod liver oil Nutrition 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 210000004907 gland Anatomy 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 231100000640 hair analysis Toxicity 0.000 description 1
- 230000037308 hair color Effects 0.000 description 1
- 210000003780 hair follicle Anatomy 0.000 description 1
- 230000003646 hair health Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 230000000474 nursing effect Effects 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Cosmetics (AREA)
Abstract
The invention provides an application of batyl alcohol in a hair washing and caring product and the hair washing and caring product containing batyl alcohol, wherein the application comprises the application of batyl alcohol in preparing the children hair washing and caring product with low eye irritation, improved hair smoothness and/or preventing hair from drying and knotting after hair washing. By adding batyl alcohol, the irritation of the shampoo to eyes can be effectively reduced, the hair washing effect of the shampoo is remarkably improved, the hair is more smooth, and the condition of withering and knotting after hair washing is reduced. The hair washing and caring product containing batyl alcohol has the characteristics of low eye irritation and excellent hair washing and caring effect, and can meet the requirements of children in the prior art. Moreover, the application of batyl alcohol in reducing the eye irritation of the hair washing water is convenient for combining the hair washing and caring product components which have good effect but may have irritation and are used by adults in the prior art, so that more hair washing and caring products suitable for children can be obtained.
Description
Technical Field
The invention relates to the technical field of washing and caring products, in particular to application of batyl alcohol in a washing and caring product and the washing and caring product containing batyl alcohol.
Background
The hair washing and caring products are a kind of nursing products for cleaning or protecting scalp and hair health, and can clean grease, sweat scale, external dust, microorganism and the like secreted by human bodies attached to the scalp and the hair, or provide good nourishment for the hair. In addition to the need for shampoo products for adults, there is in fact a need for use of shampoos which are smooth and condition hair for children over the age of 3, especially girls. However, the shampoo is more suitable for the requirements of adult shampoos, conditioning components often adopt cationic polyquaternium components with strong irritation, the conditioning components have strong irritation to eyes, and the formed shampoo is not suitable for children. According to national regulations, the test result of the eye irritation of the shampoo for children under 12 years old is not stimulated, so that the conventional common shampoo is not suitable for children and contradicts related regulations and product safety. Although some shampoo products for children do not contain shampoo components with good washing effect, the shampoo products are suitable for children, but the hair washing effect is weakened to some extent correspondingly. Therefore, it is very important to provide a substance, a scheme and the like which can eliminate the eye irritation of the shampoo to children and is beneficial to improving the hair washing effect.
Disclosure of Invention
The invention aims to overcome at least one defect of the prior art, and provides the application of the batyl alcohol in the hair washing and caring product and the hair washing and caring product containing the batyl alcohol.
It is an object of the present invention to provide the use of batyl alcohol in the preparation of a children's hair care product with low eye irritation, improved hair smoothness and/or prevention of hair drying and knotting after shampooing. In one or more embodiments of the present invention, it is found that the addition of batyl alcohol can effectively reduce the irritation of the hair washing and caring product to eyes, and after hair washing, the hair washing and caring product with batyl alcohol can make hair more flexible and easier to comb, and effectively reduce the dry and knotted condition of hair in wet or dry state.
Further, ocular sub-irritancy includes sub-irritancy to the cornea, iris, and/or conjunctiva. In one or more embodiments of the present invention, it was demonstrated by animal experiments that batyl alcohol has the effect of reducing eye irritation of components of hair wash and care products, and is embodied by the cornea, iris and conjunctiva in the process. Batyl alcohol was shown to be effective at reducing the irritation of wash and hair care products on the cornea, iris and conjunctiva of the eye at least.
Further, the children's hair washing and caring product contains the following components: quaternary ammonium salts and/or quaternary ammonium salt polymers. In more than one embodiment of the invention, for the shampoo containing the quaternary ammonium salt component, the adding of the batyl alcohol can effectively reduce the eye irritation of the corresponding shampoo, improve the softening function and reduce the drying and knotting after washing. The invention provides the application of batyl alcohol in reducing eye irritation in shampoo containing quaternary ammonium salt components, and is expected to solve the defect that the shampoo containing quaternary ammonium salt and polymer thereof in the prior art has good effect but cannot be suitable for children.
Further, the children's hair washing and caring product contains the following components: water, laureth ammonium sulfate, disodium cocoamphodiacetate, cocamidopropyl betaine, PEG-80 sorbitan laurate, dimethiconol, ethylene glycol distearate, decyl glucoside, phenoxyethanol, PEG-150 distearate, sodium chloride, cetearyl alcohol, acrylic acid/C10-30 alkanol acrylate crosspolymer, disodium EDTA, perfume, and polyquaternium-10. In more than one embodiment of the invention, the batyl alcohol is added into the hair washing and caring product containing the components, so that the hair washing and caring effects of the corresponding hair washing and caring product are obviously improved, including mildness, softening function and nourishing effect.
The invention also aims to provide the application of batyl alcohol in preparing products for reducing eye irritation of the hair washing and caring products, improving the softening function of the hair washing and caring products and/or reducing hair drying and knotting after the hair washing and caring products are washed. In addition to the presence of batyl alcohol itself as a component of a hair care product, it is also possible to prepare separate products based on batyl alcohol for use in combination with an agent for enhancing the cleansing and protecting effects of hair or for relieving eye irritation of a hair care product. Further, hair washing and caring products include children's shampoo.
Further, the hair washing and caring product contains the following components: quaternary ammonium salts and/or quaternary ammonium salt polymers. Further, the quaternary ammonium salt polymer is polyquaternium-10. Further, the hair washing and caring product contains the following components: water, laureth ammonium sulfate, disodium cocoamphodiacetate, cocamidopropyl betaine, PEG-80 sorbitan laurate, dimethiconol, ethylene glycol distearate, decyl glucoside, phenoxyethanol, PEG-150 distearate, sodium chloride, cetearyl alcohol, acrylic acid/C10-30 alkanol acrylate crosspolymer, disodium EDTA, perfume, and polyquaternium-10.
Still another object of the present invention is to provide a method for reducing eye irritation, improving the softening function and/or reducing dryness and knot of hair after washing hair by adding batyl alcohol to a hair washing and caring product.
The invention further aims to provide children shampoo which comprises the following components in parts by weight:
according to the children shampoo, the ammonium laureth sulfate is an anionic surfactant with excellent performances, and has excellent decontamination, emulsification and foaming performances, and the addition of the ammonium laureth sulfate is beneficial to improving the foaming effect of the shampoo and enhancing the cleaning effect. The cocoyl amphodiacetate disodium can further play roles in foaming and increasing foam, enables hair to be soft and easy to comb after the cocoyl amphodiacetate disodium is used, has antistatic property, is low in irritation to eyes, and is suitable for children.
Meanwhile, the coconut oil amido propyl betaine and the PEG-80 sorbitan laurate are also added into the shampoo, the coconut oil amido propyl betaine has sterilization and antibacterial effects to a certain extent, the performance is mild, and the softness, conditioning and low-temperature stability of the hair washing and caring product can be improved; the PEG-80 sorbitan laurate can improve the overall performance of the hair washing and caring product and improve the foamability, and the component also belongs to a mild component, has low irritation to eyes, and is safe and reliable when used on children shampoo; more importantly, the PEG-80 sorbitan laurate is matched with the cocamidopropyl betaine, so that the generation of bubbles can be obviously promoted, and the foam is converted into finer foam from a loose structure, so that the foam is fine and rich. And the two components can play a certain thickening role in coordination.
The sodium cocoyl amphohydroxypropyl sulfonate has good foaming power, can generate rich, fine and cream-like foam, enhances the foaming capability of a formula system, enables the skin to be soft and moist after cleaning, and prevents the skin and hair from being excessively degreased. The dimethiconol is added into a hair washing and caring product, can increase the smoothness of the washed hair, improves the luster, and has no greasy feeling. The ethylene glycol distearate has effects of moistening and conditioning hair, and enhancing hair nourishing and protecting effects. Decyl glucoside, a mild cleansing ingredient, has the ability to reduce surface tension, and does not cause discomfort to the scalp while removing scalp and hair follicle oil; and the decyl glucoside hydrophobic chain contains ten carbon atoms, the length of the carbon chain is just matched with that of most of anionic surfactants, and the decyl glucoside hydrophobic chain is easily inserted into a mixed micelle formed by the anionic surfactants and the zwitterionic surfactants, so that the efficiency of the anionic surfactants for reducing the surface tension is greatly improved, and the surface activity cleaning capability of the anions and the zwitterionic surfactants is more effectively exerted. The phenoxyethanol at least has the effect of a preservative, and is bacteriostatic and quality-guaranteeing. The PEG-150 distearate has the functions of conditioning and softening hair, and the addition of the component can effectively prevent hair from drying up and reduce the electrostatic effect between hair filaments. The sodium chloride can improve the ionization degree of the shampoo and the washing effect of the hair washing and caring product. The cetearyl alcohol is a surfactant, has foaming and defoaming effects, and can dissolve oil and fat which are difficult to clean in hair by solubilization; meanwhile, cetearyl alcohol can also relieve the condition of dry hair; due to hair dryness, the sebum gland oil secretion of scalp is insufficient, the scalp environment is too dry, and factors such as frequent high-temperature perm, medicament hair dyeing, reverse combing and the like cause damage to hair cuticular layer hair scales, and the cetostearyl alcohol can help smooth the raised edges of the hair cuticular layer hair scales, so that the hair color becomes gradually smooth and the hair texture is soft; in addition, cetearyl alcohol is used as an emulsifier, so that the adhesiveness and deposition of the hair conditioner on hair can be improved, the hair conditioner can be better released and expanded under a wet condition, and the hair conditioner has the effects of moisturizing the hair.
The acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer can provide a shampoo water-locking function and is beneficial to nourishing hair. The EDTA disodium is used as a chelating agent, so that the stability of a shampoo formula system can be promoted, and the overall shampoo effect can be improved. The polyquaternary ammonium salt has strong affinity to hair, can repair hair split, can form a transparent and continuous film when deposited on the hair, and enables the hair to be smooth and soft. The essence can provide a certain degree of fragrance of the shampoo, and the use experience is improved.
The batyl alcohol is used as a high-molecular auxiliary emulsified surfactant, can quickly form a layer of isolation at the cornea of eyes in the hair washing process, prevents small molecular substances in the shampoo from entering the internal tissues of the eyes, further prevents the shampoo from stimulating the eyes, and can effectively prevent hair from drying and knotting after being added into the shampoo, thereby remarkably improving the hair washing and protecting effects of the shampoo.
Further, the composition comprises the following components in parts by weight:
the invention further aims to provide a preparation method of the children shampoo, which comprises the following steps:
s1, heating water to 79-82 ℃, sequentially adding acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer, disodium EDTA, laureth ammonium sulfate, disodium cocoyl amphodiacetate, cocamidopropyl betaine, PEG-80 sorbitan laurate, decyl glucoside, PEG-150 distearate, cetyl alcohol, batyl alcohol and polyquaternium-10 in corresponding proportion, and uniformly mixing;
s2, after the mixture is uniformly mixed in the step S1, sequentially adding the dimethiconol and the ethylene glycol distearate in corresponding proportions, and slowly and uniformly stirring;
s3, adding sodium chloride in a corresponding proportion into the mixture obtained in the step S2 to adjust the viscosity of the liquid body, so as to obtain a liquid shampoo precursor solution;
and S4, cooling the shampoo precursor solution obtained in the step S3 to 45 ℃, adding essence and phenoxyethanol, and uniformly stirring to obtain the children shampoo.
The preparation method of the children shampoo is simple, high in preparation efficiency and convenient for industrial production. In addition, in the preparation process, complex chemical treatment is not needed, and the safety of the prepared children shampoo is guaranteed.
Compared with the prior art, the invention has the beneficial effects that: by adding batyl alcohol, the irritation of the shampoo to eyes can be effectively reduced, the hair washing effect of the shampoo is remarkably improved, the hair is more smooth, and the condition of dryness and knotting after hair washing is reduced. The batyl alcohol is used as a natural component of the cod liver oil in the shark liver, is natural in source, mild and safe, and is suitable for children; can be used as a polymer auxiliary emulsified surfactant to quickly form a layer of isolation on the cornea of eyes, thereby preventing small molecular substances in shampoo from entering the internal tissues of the eyes to cause eye irritation in the use process of the shampoo, and reducing the eye irritation of a hair washing and protecting product. Meanwhile, in more than one embodiment of the invention, the hair washing and caring product added with the batyl alcohol can improve the dryness, wetness, combing smoothness of hair, prevent the hair from being dried up and knotted, and has excellent hair cleaning, moistening and protecting effects. The shampoo and hair care product containing batyl alcohol has the characteristics of low eye irritation, excellent shampoo and hair care effect and the like, and can meet the requirements of shampoo and hair care products for children in the prior art. Moreover, the application of reducing the eye irritation of the shampoo through batyl alcohol is convenient for combining components of the shampoo which are good in effect and possibly have irritation and used by adults in the prior art, so that more shampoo products suitable for children are realized, and the requirement of the shampoo for children in the prior art is met. The addition of the batyl alcohol can improve the hair washing and caring effect of the hair washing and caring product, and the hair washing and caring product containing the batyl alcohol can bring excellent hair washing and caring experience to corresponding users.
Detailed Description
It should be noted that the following detailed description is exemplary and is intended to provide further explanation of the disclosure. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this application belongs.
It is noted that the terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of example embodiments according to the present application. As used herein, the singular forms "a", "an" and "the" are intended to include the plural forms as well, and it should be understood that when the terms "comprises" and/or "comprising" are used in this specification, they specify the presence of stated features, steps, operations, devices, components, and/or combinations thereof, unless the context clearly indicates otherwise.
The present invention will now be further described with reference to specific examples, which are intended to be illustrative only and not to be limiting. The test samples and test procedures used in the following examples include the following (generally, according to the conventional conditions or according to the conditions recommended by a reagent company if the specific conditions of the experiment not specified in the examples; reagents, consumables and the like used in the following examples are commercially available without specific description). And in the examples which follow, all parts and percentages are given by weight unless otherwise indicated.
Example 1
Various shampoo compositions were prepared according to the formulations given in table 1.
TABLE 1
The essence adopted in the embodiment is IFF essence FH3102914.
Preparation methods of schemes 1 to 3:
s1, heating water to 79-82 ℃, sequentially adding acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer, disodium EDTA, laureth ammonium sulfate, disodium cocoyl amphodiacetate, cocamidopropyl betaine, PEG-80 sorbitan laurate, decyl glucoside, PEG-150 distearate, cetyl alcohol, batyl alcohol and polyquaternium-10 in corresponding proportion, and uniformly mixing;
s2, after the mixture is uniformly mixed in the step S1, sequentially adding the dimethiconol and the ethylene glycol distearate in corresponding proportion, and slowly and uniformly stirring;
s3, adding sodium chloride in a corresponding proportion into the mixture obtained in the step S2 to adjust the viscosity of the liquid body, so as to obtain a liquid shampoo precursor solution;
and S4, cooling the shampoo precursor solution obtained in the step S3 to 45 ℃, adding essence and phenoxyethanol, and uniformly stirring to obtain the children shampoo.
The control sample was prepared in a similar manner to that described above, except that no batyl alcohol was added in step S1 and the other processing steps were the same.
The samples of schemes 1, 2, 3 and the control sample were obtained by the corresponding preparation methods.
Example 2
Testing the irritation of the shampoo with different batyl alcohol addition ratios to eyes; specifically, the test result proves whether the adding of batyl alcohol in the shampoo can effectively reduce the irritation of the shampoo on eyes.
Specifically, the eye irritation test is carried out according to an acute eye irritation/corrosivity experimental method of technical Specification for cosmetic safety.
Experiments were conducted using, as test substances, a plurality of protocol samples prepared in example 1 and control samples, and the highest integrated mean value and recovery time of the stimulation response at the observation point of 24, 48 or 72h, respectively, of the cornea, iris or conjunctiva of animals after administration of the test substances were evaluated, and the stimulation intensity of the test substances to eyes was judged in accordance with the eye stimulation response classification of table 2.
TABLE 2 grading of the eye irritation response of the products
Note: when the cornea, iris and conjunctiva are 0, it is judged to be non-irritant.
The results of the acute eye irritation test based on each of the samples of example 1 as the test substance are shown in table 3 below:
TABLE 3
| Scheme(s) | Scheme 1 | Scheme 2 | Scheme 3 | Control sample |
| Test results | Micro-stimulation property | Has no irritation | Has no irritation | Light irritation |
From the test results shown in table 3, it can be derived: the addition of batyl alcohol can effectively reduce the irritation of the shampoo to eyes.
Example 3
Evaluation of Dry and Wet combing after washing by consumers for protocols 1-3 and control samples prepared in example 1
30 female hair samples of 20-30cm length were prepared, shampooed, and evaluated for wet hair and combing after drying with a hair dryer.
Testing an instrument: hair combing tester, HM-01
The testing principle is as follows: the clips holding the hair tresses were mounted on a stainless steel stand on a Mettler-Torlitdo XS603S precision balance. The motor on the carding machine drives the screw rod to rotate, the rotating speed of the motor is 2800r/min, the guide metal plates are arranged on two sides of the screw rod, the comb is fixed on the screw rod, the comb is driven to slide up and down when the screw rod rotates, the comb can pass 20 cm in one second, and the speed of combing the hair is almost the same as that of a person at ordinary times, so that the real hair combing process can be simulated. In order to ensure that the starting position and the ending position of each test are the same to achieve the accuracy of the test, the starting position and the ending position are marked on the metal guide plate from the upper end to the bottom of the carding machine.
Pre-treatment of hair tresses: the selected hair bundle is real hair without chemical treatment such as blanching, dyeing and bleaching, each hair weighs about 10g, and the length is controlled to be about 35 cm. The 4-piece hair is clamped together by an iron clip, and the two sides are screwed tightly by screws to fix the hair for standby.
A hair washing step: in order to prevent the hair from being polluted by oil stain on the hands, a person who has been washed hair wears gloves during the whole process of washing hair; the specific steps of hair washing are as follows:
(1) The hair is first moistened with warm water of about 40 deg.C and then washed with 10% K12 solution, and the front and back sides are kneaded for half a minute to prevent the hair from being disordered. Then warm water is used for washing the front and back sides of the hair for half a minute respectively to remove foams;
(2) And (3) sucking 2mL of prepared shampoo by using a needle tube, washing hair according to the step (1), namely replacing K12 in the step (1) with the shampoo, and filtering water along the hair bundle direction by using two fingers after washing, wherein the water is to be measured.
Testing of combing property of shampoo: because the humidity of the air has certain influence on the hair combing property, in order to reduce the error of the experiment as much as possible, the experiment is carried out in a constant-temperature constant-humidity air-conditioning room.
TABLE 4 evaluation index and score for wet hair
TABLE 5 evaluation index and score of hair dryness
Under the above experimental methods and reference indices, the dry and wet combing evaluation results were obtained as shown in table 6 below:
TABLE 6
| Scheme(s) | Scheme 1 | Scheme 2 | Scheme 3 | Control sample |
| Wet comb evaluation average score | 3.9 | 4.2 | 4.5 | 3.7 |
| Dry comb evaluation average score | 3.7 | 4.1 | 4.2 | 3.5 |
That is, from the hair dry wet combing test results, it can be concluded: the addition of batyl alcohol can effectively improve the conditioning performance of the dry and wet hair combing of the shampoo and avoid the phenomena of dry hair and knotting of the hair.
Example 4
The shampoo compositions in the schemes 4 and 5 are prepared and obtained in the embodiment, specifically, the shampoo composition in the scheme 4 comprises the following components in parts by weight: 72.9 parts of water, 9 parts of laureth ammonium sulfate, 3 parts of disodium cocoyl amphodiacetate, 3 parts of cocamidopropyl betaine, 1 part of PEG-80 sorbitan laurate, 1 part of dimethiconol, 1 part of ethylene glycol distearate, 0.5 part of batyl alcohol, 0.5 part of decyl glucoside, 0.3 part of phenoxyethanol, 0.3 part of PEG-150 distearate, 0.3 part of sodium chloride, 0.3 part of cetearyl alcohol, 0.1 part of acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer, 0.05 part of disodium EDTA, 0.05 part of essence and 0.05 part of polyquaternary ammonium salt; the shampoo composition in the scheme 5 comprises the following components in parts by weight: 74.4 parts of water, 11 parts of laureth ammonium sulfate, 5 parts of disodium cocoyl amphodiacetate, 5 parts of cocamidopropyl betaine, 3 parts of PEG-80 sorbitan laurate, 1.4 parts of dimethiconol, 1.2 parts of ethylene glycol distearate, 2 parts of batyl alcohol, 1.5 parts of decyl glucoside, 0.7 part of phenoxyethanol, 0.7 part of PEG-150 distearate, 0.6 part of sodium chloride, 0.6 part of cetearyl alcohol, 0.5 part of acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer, 0.15 part of disodium EDTA, 0.15 part of essence and 0.15 part of polyquaternary ammonium salt. The same experiment as in example 2 and example 3 was performed, and in the ocular irritation test, protocol 4 performed and graded the same as protocol 1, and protocol 5 performed and graded the same as protocol 3; protocol 4 and protocol 5 also outperformed the control sample score in the wet and dry combing test. Namely, the effects of promoting the hair to be soft and preventing the hair from being dried and knotted after washing are also embodied in the scheme 4 and the scheme 5.
It should be understood that the above-mentioned embodiments of the present invention are only examples for clearly illustrating the technical solutions of the present invention, and are not intended to limit the specific embodiments of the present invention. Any modification, equivalent replacement, and improvement made within the spirit and principle of the present invention claims should be included in the protection scope of the present invention claims.
Claims (10)
1. Use of batyl alcohol for the preparation of a children's hair care product with low eye irritation, improved hair smoothness and/or prevention of hair drying and knotting after shampooing.
2. The use of claim 1, wherein ocular hypoirritation comprises hypoirritation to the cornea, iris and/or conjunctiva.
3. Use according to claim 1, characterized in that the children's hair care and washing products contain the components: quaternary ammonium salts and/or quaternary ammonium salt polymers.
4. Use according to claim 3, characterized in that the children's hair care and washing products contain the components: water, laureth sulfate ammonium, disodium cocoamphodiacetate, cocamidopropyl betaine, PEG-80 sorbitan laurate, dimethiconol, ethylene glycol distearate, decyl glucoside, phenoxyethanol, PEG-150 distearate, sodium chloride, cetearyl alcohol, acrylic acid/C10-30 alkanol acrylate crosspolymer, disodium EDTA, perfume, and polyquaternium-10.
5. The application of batyl alcohol in preparing products for reducing eye irritation of hair washing and caring products, improving softening function of the hair washing and caring products and/or reducing hair dryness and knotting of hair after hair washing of the hair washing and caring products.
6. Use according to claim 5, characterized in that the hair care and wash products contain the components: quaternary ammonium salts and/or quaternary ammonium salt polymers. Further, the quaternary ammonium salt polymer is polyquaternium-10. Further, the hair washing and caring product contains the following components: water, laureth sulfate ammonium, disodium cocoamphodiacetate, cocamidopropyl betaine, PEG-80 sorbitan laurate, dimethiconol, ethylene glycol distearate, decyl glucoside, phenoxyethanol, PEG-150 distearate, sodium chloride, cetearyl alcohol, acrylic acid/C10-30 alkanol acrylate crosspolymer, disodium EDTA, perfume, and polyquaternium-10.
7. An application method of reducing eye irritation, improving softening function and/or reducing hair dryness and knotting of a hair washing and caring product through batyl alcohol is characterized in that batyl alcohol is added into the hair washing and caring product.
8. The children shampoo is characterized by comprising the following components in parts by weight:
9. the shampoo for children as claimed in claim 8, wherein the shampoo for children comprises the following components in parts by weight:
10. method for preparing a shampoo for children according to any of claims 8 to 9, characterized in that it comprises the steps of:
s1, heating water to 79-82 ℃, sequentially adding acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer, disodium EDTA, laureth ammonium sulfate, disodium cocoyl amphodiacetate, cocamidopropyl betaine, PEG-80 sorbitan laurate, decyl glucoside, PEG-150 distearate, cetyl alcohol, batyl alcohol and polyquaternium-10 in corresponding proportion, and uniformly mixing;
s2, after the mixture is uniformly mixed in the step S1, sequentially adding the dimethiconol and the ethylene glycol distearate in corresponding proportions, and slowly and uniformly stirring;
s3, adding sodium chloride in a corresponding proportion into the mixture obtained in the step S2 to adjust the viscosity of the liquid body, so as to obtain a liquid shampoo precursor solution;
and S4, cooling the shampoo precursor solution obtained in the step S3 to 45 ℃, adding essence and phenoxyethanol, and uniformly stirring to obtain the children shampoo.
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Cited By (1)
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| WO2017127344A1 (en) | 2016-01-20 | 2017-07-27 | The Procter & Gamble Company | Hair conditioning composition comprising monoalkyl glyceryl ether |
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