CN1156564C - Production of anionic detergent particles - Google Patents
Production of anionic detergent particles Download PDFInfo
- Publication number
- CN1156564C CN1156564C CNB971940665A CN97194066A CN1156564C CN 1156564 C CN1156564 C CN 1156564C CN B971940665 A CNB971940665 A CN B971940665A CN 97194066 A CN97194066 A CN 97194066A CN 1156564 C CN1156564 C CN 1156564C
- Authority
- CN
- China
- Prior art keywords
- anion surfactant
- agent
- detergent
- detergent particles
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000002245 particle Substances 0.000 title claims abstract description 85
- 239000003599 detergent Substances 0.000 title claims abstract description 71
- 238000004519 manufacturing process Methods 0.000 title claims description 20
- 238000000034 method Methods 0.000 claims abstract description 50
- 238000001035 drying Methods 0.000 claims abstract description 49
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 41
- 238000001816 cooling Methods 0.000 claims abstract description 35
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000004094 surface-active agent Substances 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims description 45
- 239000002253 acid Substances 0.000 claims description 24
- 239000000126 substance Substances 0.000 claims description 24
- -1 alkylbenzene sulfonate Chemical class 0.000 claims description 23
- 235000011837 pasties Nutrition 0.000 claims description 18
- 238000013517 stratification Methods 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 17
- 230000003472 neutralizing effect Effects 0.000 claims description 13
- 238000003756 stirring Methods 0.000 claims description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 150000001450 anions Chemical class 0.000 claims description 2
- 238000007790 scraping Methods 0.000 claims description 2
- 230000008569 process Effects 0.000 abstract description 9
- 239000000843 powder Substances 0.000 description 29
- 239000013543 active substance Substances 0.000 description 25
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 20
- 150000001875 compounds Chemical class 0.000 description 15
- 238000005406 washing Methods 0.000 description 15
- 229910021536 Zeolite Inorganic materials 0.000 description 14
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 14
- 239000010457 zeolite Substances 0.000 description 14
- 238000010438 heat treatment Methods 0.000 description 11
- 239000002243 precursor Substances 0.000 description 11
- 229910000029 sodium carbonate Inorganic materials 0.000 description 10
- 235000017550 sodium carbonate Nutrition 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 125000000129 anionic group Chemical group 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- 239000000344 soap Substances 0.000 description 8
- 239000011159 matrix material Substances 0.000 description 7
- 239000002002 slurry Substances 0.000 description 7
- 150000007513 acids Chemical class 0.000 description 6
- 239000011149 active material Substances 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 238000001694 spray drying Methods 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
- 238000004061 bleaching Methods 0.000 description 5
- 239000008187 granular material Substances 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000007844 bleaching agent Substances 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 4
- 238000006386 neutralization reaction Methods 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000000112 cooling gas Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
- 238000001149 thermolysis Methods 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 239000011147 inorganic material Substances 0.000 description 2
- 229910017053 inorganic salt Inorganic materials 0.000 description 2
- 239000002563 ionic surfactant Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 235000012149 noodles Nutrition 0.000 description 2
- 235000019353 potassium silicate Nutrition 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000011343 solid material Substances 0.000 description 2
- 239000007790 solid phase Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- MLZGOXKPLYRFBZ-UHFFFAOYSA-N CC=C.O[PH2]=O Chemical compound CC=C.O[PH2]=O MLZGOXKPLYRFBZ-UHFFFAOYSA-N 0.000 description 1
- RKWGIWYCVPQPMF-UHFFFAOYSA-N Chloropropamide Chemical compound CCCNC(=O)NS(=O)(=O)C1=CC=C(Cl)C=C1 RKWGIWYCVPQPMF-UHFFFAOYSA-N 0.000 description 1
- RGHNJXZEOKUKBD-SQOUGZDYSA-M D-gluconate Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O RGHNJXZEOKUKBD-SQOUGZDYSA-M 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical class OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical group [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- ZUBJEHHGZYTRPH-KTKRTIGZSA-N [(z)-octadec-9-enyl] hydrogen sulfate Chemical compound CCCCCCCC\C=C/CCCCCCCCOS(O)(=O)=O ZUBJEHHGZYTRPH-KTKRTIGZSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
- 150000008041 alkali metal carbonates Chemical class 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052728 basic metal Inorganic materials 0.000 description 1
- 150000003818 basic metals Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- ZLVQSTSRGFIOEQ-UHFFFAOYSA-N carboxy 4-methylperoxy-4-oxobutanoate Chemical compound COOC(=O)CCC(=O)OC(O)=O ZLVQSTSRGFIOEQ-UHFFFAOYSA-N 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000007791 dehumidification Methods 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- MPFLRYZEEAQMLQ-UHFFFAOYSA-N dinicotinic acid Chemical class OC(=O)C1=CN=CC(C(O)=O)=C1 MPFLRYZEEAQMLQ-UHFFFAOYSA-N 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical class [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- KWKXNDCHNDYVRT-UHFFFAOYSA-N dodecylbenzene Chemical compound CCCCCCCCCCCCC1=CC=CC=C1 KWKXNDCHNDYVRT-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- AEDZKIACDBYJLQ-UHFFFAOYSA-N ethane-1,2-diol;hydrate Chemical compound O.OCCO AEDZKIACDBYJLQ-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 235000021050 feed intake Nutrition 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229940050410 gluconate Drugs 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910052816 inorganic phosphate Inorganic materials 0.000 description 1
- 150000008040 ionic compounds Chemical class 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 235000012204 lemonade/lime carbonate Nutrition 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 230000002366 lipolytic effect Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 230000002572 peristaltic effect Effects 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000002797 proteolythic effect Effects 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 239000006200 vaporizer Substances 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0082—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/04—Special methods for preparing compositions containing mixtures of detergents by chemical means, e.g. by sulfonating in the presence of other compounding ingredients followed by neutralising
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
In a process for producing detergent particles comprising an anionic surfactant, a paste comprising water and the surfactant is fed to a drying zone where it is heated. Subsequently, the paste is cooled in a cooling zone. A layering agent is introduced into the cooling zone to improve granularity.
Description
The present invention relates to anionic detergent particles, its production method and the composition that contains detergent particles.More particularly, the present invention relates to the production method of the high detergent particles of anionic surfactant concentration, this method is to contain the washing composition mashed prod drying of anion surfactant, and relates to the detergent particles that obtains thus.
Usually the detergent active compound that adopts in detergent composition comprises anion surfactant, as linear alkylbenzene sulfonate (LAS), straight chained alkyl ether sulfate (LES) and primary alkyl sulphates (PAS), and nonionogenic tenside such as ethoxylated alcohol.For improving the de-sludging performance, preferably supply with the powder of high-content detergent active material.
Usually, the high-content of the active substance that can mix is limited by the requirement of production method.The detergent composition that tap density is high, its typical production method are all components of said composition and/or the matrix powder that for example obtained by spray-drying process are mixed mutually or to granulate, and compare with the composition that tap density is low, and this brings very big benefit to the human consumer.
It is known that detergent active compound is joined in this liquid detergent compositions.But because ratio that must control liquid phase and solid phase is with the formation detergent particles, so the high-content of the detergent active material that can add like this is conditional.Also having known can be with anion surfactant, and for example LAS or PAS join in the detergent composition by the mode of solid auxiliary, are about to contain other composition of this tensio-active agent and said composition, as the particle adding of yellow soda ash and washing assistant.Up to now, owing to good flowability need be provided and reduce poly-group tendency, the amount of the anion surfactant in this auxiliary is restricted always.
EP-A-506 184 announces a kind of liquid acid precursor substance successive drying neutral method with anion surfactant.Can prepare the detergent particles that activated detergent content is 30-40% (weight) with this method.
A kind of method of producing Powdered anion surfactant of EP-A-572 957 announcements: the aqueous slurry that contains 60-80% solid tensio-active agent is delivered in the vaporizer, formed dry and concentrated these slurries of layer of surface promoting agent film and one side on the reactor wall, simultaneously from wall, it scraped.
DE-A-4304015 discloses the method for the lower tensio-active agent of a kind of production viscosity, being about to the introducing of tensio-active agent mashed prod contains in the fluidized bed plant of particulate matter, granulation simultaneously and dry adds particle stabilizers in the discharging air-flow of this device subsequently in fluidized-bed.Can prepare the detergent particles that contains activeconstituents 15-90% weight by this method.
What disclose in EP-A-572 957 also has: the reactor wall temperature is 50 to 140 ℃; The highest wall temperature of embodiment is 130 ℃.It is said that higher temperature can cause thermal destruction and tonal variation, is disadvantageous therefore.And document disclosure, the point of a knife speed of scraper preferably 2 arrives 20m/s in the reactor, and the highest point of a knife speed of embodiment is 10.5m/s.Disclosed tap density is up to about 0.5g/cm
3
Yet, opposite with above-mentioned saying, as described in the WO 96/06916 (not delivering before preferential day) in present patent application, the good detergent granules of tap density height, anionic surfactant concentration height and powder property can be with following method production: heating contains the mashed prod of this tensio-active agent in comparatively high temps first area uniformly, then the particle of such formation is cooled down.
In general, aforesaid method comprises: contain water (its amount generally greater than mashed prod weight 10%) and the mashed prod of anion surfactant send into drying zone, this pasty substance of heating then cools off in the cooling zone to form detergent particles to reduce water-content in drying zone.
The method of describing among the WO 96/06916 is particularly suitable for the anionic detergent component as detergent particles with PAS.Regrettably, the amount of PAS is many more in anionic group, and detergent particles just tends to form viscous surface more, and for the requirement that final production goes out the particulate product of uniform drying, this is very deleterious.
Have been found that now a stratification agent introducing cooling zone just can address this problem.
EP-A-390 251 discloses, and when producing detergent particles, available stratification agent is as the granulating auxiliary, and wherein all components are handled in homogenizer, keeps in moderate speed's stirrer then or enters deformation stage.
Therefore, a first aspect of the present invention is to propose the method that a kind of production contains the detergent particles of anion surfactant, this method comprises following step: the pasty substance that contains water and anion surfactant is delivered to drying zone (this district does not comprise fluidized-bed), the heating pasty substance is to reduce their moisture in drying zone, then the cooling pasty substance is characterized in that in cooling step the stratification agent being incorporated in the cooling zone to form detergent particles in the cooling zone.
Without the stratification agent, the pasty substance that adopts cooling gas to handle in the cooling zone also can reach same effect.Therefore, a second aspect of the present invention is to propose the method that a kind of production contains the detergent particles of anion surfactant, this method comprises following step: the pasty substance that contains water and anion surfactant is delivered to drying zone (this district does not comprise fluidized-bed), the heating pasty substance is to reduce their moisture in drying zone, then in the cooling zone, cool off pasty substance, to form detergent particles, it is characterized in that with the pasty substance in the cooling draught processing cooling zone.
Cooling gas needs drying in general, for example can be air or nitrogen, for example below 0 ℃.This cooling gas can the counter-current flow mode use.
But the present invention is not limited only to the composition that anionic group contains LAS or is made of LAS.Comprise the situation of other anionic group of PAS or LES for employing, the present invention also is very useful.
The stratification agent can be anyly can give the particle coating to improve the material of its granularity at cooling stages.For this reason, preferably inactive relatively material reaches this purpose, and particularly any has the inert material of good result in washing soln, for example, and silico-aluminate, silica mica and clay.Can use these mixtures of material.Hereinafter will narrate the example of silico-aluminate and silica in more detail.This material is not got rid of this material as the coating of finished particle and is existed in this particulate body yet.
The consumption of coated fertilizer is with respect to the ratio of the total amount of this other material of particulate in cooling stages, and preferably 1: 3 to 1: 20, further preferred 1: 9 to 1: 20.
Drying zone can be chosen wantonly under rough vacuum to help to remove moisture and volatile matter.Vacuum can be high to normal atmosphere from 100 Torr, and very big production method handiness is provided like this.But, cross 500 Torr and help when vacuum operating is provided, reducing investment to atmospheric vacuum.
Stirring material can ensure control and the increase output to residence time and granular size in drying zone and/or cooling zone.
This method is preferably carried out continuously, because this is convenient to carry continuously detergent particles.In continuous processing, the flow velocity of mashed prod with 10 to 25kg/m
2/ hr the order of magnitude is advisable, and preferred 17 to 22kg/m
2/ hr, for example 20kg/m
2/ hr.
Average retention time is to be advisable less than 5 minutes in drying zone.The preferred especially residence time is less than 4 minutes, and the most preferably short as far as possible residence time decomposes the possibility of (particularly PAS) and increases product production to greatest extent reducing.
In general, mashed prod will provide the inner net heat of mashed prod to shift in the stirring heating district, thereby help removing moisture.Stirring can reduce the duration of contact between pasty state particle and the drying zone wall, adds that effective heat shifts, and just can reduce " hot spot " that may cause decomposing and form possibility.In addition, drying process is improved, and this just can make, and residence time shortening/output increases in the drying zone.
For PAS, for avoiding thermolysis, preferred pasty substance heating is no more than 170 ℃.
Method of the present invention makes might form the tap density height, for example surpasses 550g/cm
3Particle.
At the cooling zone internal cooling, its service temperature that is fit to is no more than 50 ℃, preferably is no more than 40 ℃, as 30 ℃ paste-like material.Be preferably in have in the cooling zone stir so that wherein material effectively cool off.Compare with previous public technology, the employing particle initiatively cools off, and can reduce owing to particle is heated to comparatively high temps the pyrolysated possibility to occur, and can reduce particulate viscosity.This active cooling can be by (for example the using cooling jacket) of surrounding cooling zone cold water or realize through the circulation of refrigerative water (the ethylene glycol water about as-5 ℃) for example.
Preferred pasty substance contains the mixture of anion surfactant and water, though if having a mind to add or from upstream process, for example bring into also as impurity in the production of tensio-active agent and may have other component.Preferred pasty substance contains at least 60% (weight), and more preferably at least 65%, the especially preferred anion surfactant of at least 70% (weight).Correspondingly, mashed prod contains and is no more than 50% and preferably be no more than the water of 30% (weight).The temperature of pasty substance when being admitted to drying zone should be that available pump is smoked, and this may limit the maximum of the tensio-active agent that wherein exists.
When anionic agent contained PAS, correspondingly mashed prod should be sent into drying zone under 50 ℃ to 70 ℃ temperature, preferred 50 to 65 ℃.
Method of the present invention can be implemented in any suitable device.But preferably use the scraping surface moisture eliminator, particularly the quick response device.Suitable quick response device for example comprises the dehumidification system rapidly that can buy from VRVSPAProcessi Impianti Industriali company.The drying zone heat transfer area generally is 3: 1 to 1: 1 with the ratio of cooling zone heat transfer area, for example about 2: 1.
Can optionally before the cooling zone, select to adopt two or more drying zones when needing.Can adopt individual equipment as required with drying zone and cooling zone are provided, perhaps change a kind of method, also the equipment that can adopt moisture eliminator and cooling bed to separate.
Suitable drying zone cross section is circular substantially, and therefore, it is limited by columniform wall.Preferred above-mentioned wall heats with the heating jacket that can inject water, steam or oil.Described wall is inner preferably to keep at least 130 ℃, particularly at least 140 ℃.The vaporator rate of preferred drying zone is every m
2Heating surface per hour 3 arrives 25kg water, and particularly 5 to 20kg water.
Preferred cooling zone is limited by cylindrical wall.When production process is carried out continuously, be suitable for equipment drying zone and cooling zone horizontal aligument arrangement substantially, to help efficient drying, cooling and drying and cooling zone conveying material on the cardinal principle horizontal direction.
Correspondingly, drying zone and preferred cooling zone have stirring tool that the tensio-active agent mashed prod by aforementioned region and shaped particles are stirred and carry.Stirring tool is one group of blade and/or scraper that axially is installed in the circumferentially extending in the rotating shaft preferably.Blade and/or scraper preferably tilt with effective conveying material, and preferably the gap with inwall is not more than 10mm, for example 5mm.
We find that the present invention is specially adapted to produce the high-quality detergent granules that contains LAS, and this is that the previously known technology can not obtain.But anionic group also can be PAS, LES or any other anion surfactant, and the mixture of these components and LAS or do not contain the mixture of LAS.
The most common form with free acid of LAS is commercially available.Different with very unsettled PAS acid, LAS acid is very stable and the market sale of many manufacturers arranged, Petralab 550 (Petresa) for example, Deter (Deter), Marlican (Huls), Nalkylene 540L (Vista) and Isorchem L83 (Enichem).As a kind of viscous liquid, it is easy to handle, stores and processing.Under any circumstance, the liquid anion precursor substance of anion surfactant and neutralizing agent are sent into the inlet region of drying zone or drying zone and formed anion surfactant on the spot, just can in drying zone, form mashed prod.
The LAS acid that is neutralized is with Powdered commercially available.
The LAS powder mainly is a roller drying or spray-dired, has reasonable powder property during newborn output.But seldom preferably adopt, because they can absorb moisture and the intractable that becomes sticky from air, their flowability degenerates and becomes and lumps easily.The typical powder that can obtain (available from Huls) from market is Marlan ARL (80%LAS), Marlan A390 (90%LAS), Marlan A396 (96%LAS), or (available from Unger) Ufaryl DL90 (90%LAS), Ufaryl DL85 (85%LAS) and Ufaryl DL80 (80%LAS).
The PAS that buys on market at present is finely powdered or noodles shape.Fine powder generally is a dust-like, contains in a large number the particle less than 150 microns.Generally with the dry PAS of soap flakes shape through the extrusion production strip PAS that appears, it has very big particle size and very low porosity generally speaking, causes solubility property very poor.Be to increase the content of detergent active material in the detergent composition, the detergent particles that feeds intake after the what is called is arranged as everyone knows, can provide activity substance content high composition.
But, after being not suitable in general, finely powdered PAS and noodles shape PAS be dosed in the washing combination, particle size is different in general because composition grain is with the rearmounted particle that drops into, and it is very poor therefore to tend to segregation and outward appearance.The obtainable washing granule of the method according to this invention has high-load detergent active material, suitable porosity and particle size characteristic.
So, a third aspect of the present invention provides the anionic surfactant granules that contains particle weight 60% at least, preferably contain LAS or form by LAS, and containing the detergent particles that is no more than 5% water, this particle is coated with according to the present invention first or the stratification agent that obtains of the method for second aspect by bag.
According to a forth aspect of the invention, the detergent particles that contains anion surfactant is provided, preferably contain LAS or form by LAS, wherein linear alkylbenzene sulfonate accounts for 10% to 100% of anion surfactant gross weight, and preferably its amount is at least 60% of particle weight, wherein, this particle is coated with the stratification agent by bag, and containing porosity is 0% to 25% of particle volume, size-grade distribution is as follows: at least 80% particle size is at 180 to 1500 microns, preferred 250 to 1200 microns, and less than 10% and preferably less than 5% particle diameter less than 180 μ m.
In this detergent particles, the amount of suitable anion surfactant is at least 70% of a particle weight, particularly at least 75%, preferably at least 80%, preferably at least 85%.Preferably this particle also contains water, and its amount is no more than 10% of particle weight, and particularly 0% to 8%, preferred 0 to 4%.Water in the particle can improve particle integrity, thereby reduces fine grain amount.
Preferably the long-width ratio of detergent particles is no more than 2, more preferably totally is that spheric is emanated out to reduce from other particle of preparation said composition, and improves the profile directly perceived of powder.
Preferred LAS anion surfactant chain length is C
8To C
16, more preferably from C
9To C
15, most preferably from C
10To C
14Close limit.
If add PAS, this tensio-active agent chain length is C
10To C
22, preferred C
12To C
18, more preferably C
12To C
14Close limit, Coco PAS is especially desirable.
Detergent particles can contain PAS and other tensio-active agent and/or nonsurfactant mixture of ingredients on demand.
Other suitable tensio-active agent can comprise the straight chained alkyl ether sulfate, the oxo process alcohol sulfate.C for example
11To C
15And C
13To C
15Alcohol sulfate, secondary alcohol sulfate and sulfonate, unsaturated tensio-active agent is sodium oleate, oleyl sulfate, alkene sulfonate for example, or its mixture.
Especially preferably be rich in the detergent particles of LAS, promptly wherein the amount of LAS more preferably surpasses the total amount of all other tensio-active agents and nonsurfactant above the amount of any other tensio-active agent or nonsurfactant.
To adopt the sodium salt of tensio-active agent in general, but also may have the salt of K, Ca or Mg.Yet the inlet region before preferably the anion surfactant of sour form and neutralizing agent being sent into drying zone or be right after drying zone forms anion surfactant on the spot, to form this anionic group.
If generate anionic agent on the spot in drying zone, the neutralization heat of then emitting in drying zone can reduce the required of indirect heating drying zone, thereby is very beneficial for the method that adopts the tensio-active agent mashed prod to make raw material.
And, if precursor acids can liquid state rather than aqueous solution mode send into drying zone, and neutralizing agent can concentrate, that also is good.The total amount that enters the water of drying zone is compared and can be significantly reduced with the method that adopts the tensio-active agent mashed prod.Described mashed prod may need the water of at least 30% weight can be pumped fortune.
Also can before adding the stratification agent, directly form detergent particles from the precursor acid starting material, rather than two step method: generate tensio-active agent, then form mashed prod and dry, to form detergent particles.Its advantage is to avoid forming the tensio-active agent mashed prod, because it need carry and store this mashed prod, and gives the technical difficulty that causes.
Precursor acids, for example LAS or PAS acid are suitable for sending into drying zone with liquid phase.Because precursor acids may be heat-labile,, make to reduce to minimum, and preferably can avoid fully because caused this acid heat of the temperature that raises decomposes so preferred N-process should be enough fast, and react completely basically.
Precursor acids is suitable for being 40 to 60 ℃ in temperature carries down, is that liquid state is unlikely thermolysis again to guarantee it.Neutralizing agent can be at any temperature required drying zone of input down.
The neutralizing agent of introducing is suitable to the aqueous solution or slurries or solid material introducing.
The conventional neutralizing agent that can adopt comprises alkali-metal oxyhydroxide, for example sodium hydroxide and alkali-metal carbonate, and for example yellow soda ash preferably adds with solid material.
The amount of neutralizing agent is advisable with 25 to 55% of the aqueous solution or slurry weight, and preferred 30 to 50%.Neutralizing agent concentration height may cause undesirable crystallization effect, and concentration is low because the ratio of water is undesirable too greatly also.
For water-content in the control drying zone can change the concentration of neutralizing agent solution or slurries.So just can reach best viscosity characteristics, thus make material in the drying zone keep carrying/can be pumped the state of fortune.
Can adopt neutralizing agent with respect to precursor acids excessive amount on stoichiometric ratio.As the thermolysis of fruit part precursor acids, issuable acid, for example sulfuric acid can combine with excessive neutralizing agent.
Contain in advance the method for the mashed prod of neutral tensio-active agent with employing and compare, adopt neutralization on the spot can export product fast.
Precursor substance in the stirring heating district and neutralizing agent (hereinafter being referred to as raw material) can provide effective heat transfer in general and help removing moisture.Stir the duration of contact that reduces between raw material and the drying zone wall, add net heat and shift, just can reduce the possibility that causes pyrolysated " hot spot " to form.And, drying improve can shorten in the drying zone the residence time/raising output.
Other nonsurfactant component that can exist in the detergent particles comprises dispersion aids, preferred polymers dispersion aids, more preferably urea, sugar, polyalkylene oxide and hereinafter described washing assistant.
If necessary, this detergent particles can contain organic and/or inorganic salt, but as the salt of hydration.Suitable material in the salt, tri-polyphosphate, Citrate trianion, carbonate, vitriol, the muriate of preferred sodium.Also can comprise silico-aluminate, clay, silica and other inorganic materials.
This particle can contain one or more nonionogenic tensides, for example below about being mentioned with the matrix powder of this particle fusion those.
Also can comprise inorganic materials in same this particle, for example PEG and other polymkeric substance washing assistant or soap class, those as hereinafter mentioning.
When the anion surfactant component contains LAS, there is salt in preferred especially this particle.
The amount of salt can be up to 50% of this particle weight, and is preferably the highest by 30%.
This detergent particles is dosed in the resulting matrix powder of conventional washing composition production method after can be directly, ordinary method comprises the non-tower production method, wherein all components of detergent composition are pressed method mixing and the granulating of describing among the EP-A-367 339, and comprise spray-drying process (then can select rearmounted tower multiviscosisty).Because the detergent particles that the present invention produces can be dosed into later in this powder, so formulation flexibility is very big, and the amount of active substance can strengthen on demand in whole compositions formulated.Further advantage is to produce the matrix powder that is substantially free of the washing composition active material, and detergent active compound basically can be fully as after the particle that feeds intake add.
Therefore another aspect of the present invention provides the cleaning composition that contains described detergent particles in the present invention third and fourth aspect and matrix powder.
When the matrix powder was produced with spray-drying process, detergent active material content was particularly advantageous in the selection reduction matrix powder, thereby because the low high yield that can guarantee of detergent active compound content improves integral production efficient in spray-drying process.
Composition of the present invention also can contain detergent builder compound except detergent active compound, and appoints and to contain bleach and other activeconstituents to strengthen scourability.
Except after the detergent particles that feeds intake, detergent composition of the present invention can also contain one or more washing composition sensitization house things (tensio-active agent), these compounds can be selected from: the negatively charged ion of soap class and non-soap, positively charged ion, nonionic, both sexes and zwitterionic detergent active compound, and their mixture.Many suitable detergent active compounds all can be buied from market, and have a detailed description in the literature, for example, and in " tensio-active agent and washing composition " (volume I and II, Schwartz, Perry and Berch work) book.Preferred available detergent active compound is soap class and synthetic non-soap anionic and non-ionic compound.
Anion surfactant is that this area professional is known.Example comprises alkylbenzene sulfonate, and particularly alkyl chain length is C
8-C
15Linear alkylbenzene sulfonate; The second month in a season and primary alkyl sulphates, particularly C
12-C
15Primary alkyl sulphates; Sulfated alkyl ether; Alkene sulfonate; Alkylxylene sulfonate; Dialkyl sulfosuccinate amber salt; And fatty sulfonate.General preferred its sodium salt.
Operable ionic surfactant pack is drawn together the second month in a season and primary alcohol ethoxylate, the C that particularly every mol of alcohol and average 1 to 20 moles of ethylene oxide form
8-C
20Fatty alcohol ethoxylate, and the C of particularly every mol of alcohol and the formation of average 1 to 10 moles of ethylene oxide
10-C
15Primary aliphatic alcohols and secondary alcohol ethoxyl compound.The ionic surfactant pack of non-ethoxylated thing is drawn together alkylpolyglycosides, glycerol monoethers and poly-hydroxyl acid amides (glucamide).
The total amount of tensio-active agent is advisable to 40wt% with 5 in this detergent composition, though also can adopt the amount that exceeds this scope.
Detergent composition of the present invention also contains washing assistant in general.Its total amount suitable in composition is 10 to 80wt%, preferred 15 to 60%.Washing assistant can be the auxiliary that contains other component, perhaps if necessary, also can adopt the isolating separately lotion-aid particle that contains one or more washing assistants.
The inorganic builders that can provide comprises yellow soda ash, if necessary, can combine use with the lime carbonate crystal seed, as pointed among the GB-A-1 437 950; Crystalline state or amorphous silico-aluminate such as zeolite (open in GB-A-1 473 201); Amorphous silico-aluminate (open in GB-A-1 473 202); And crystalline state/non-crystalline state blended silico-aluminate (open in GB 1 470 250); And layered silicate (open in EP-B-164514) all can.Also can add inorganic phosphate builders, for example, the orthophosphoric acid salt of sodium, pyrophosphate salt and tri-polyphosphate, but be based on the environmental protection reason, no longer preferred these materials.
Silico-aluminate is regardless of being as the stratification agent and/or joining in the detergent particles body that its suitable total amount is 10 to 60wt%, preferred 15 to 50wt%.The zeolite that uses in most of commercialization granular detergent compositions is zeolite A.But advantageously, the high aluminium zeolite P (zeolite MAP) of description and patent protection also can use in EP-A-384070.Zeolite MAP is a kind of alkali metal aluminosilicate of P type, and the ratio of its sial is no more than 1.33, preferably is no more than 1.15 and more preferably no more than 1.07.
The organic washing-assisting detergent that can add comprises polycarboxylate polymer such as polyacrylate, vinylformic acid/maleic acid and propylene phosphinate; Monomer multi-carboxylate such as Citrate trianion, gluconate, oxygen connection succinate, glycerine list, two, three succinates, carboxyl methoxy succinate, carboxymethyloxymalo,ates, dinicotinic acid salt, hydroxyethyliminodia,etates, alkyl and thiazolinyl malonate and succinate; And sulfonated soap.The multipolymer of toxilic acid, vinylformic acid and vinyl acetate ester is particularly preferred, because it is biodegradable, thus compliance with environmental protection requirements.Herein not with above-named as limit.
Particularly preferred organic washing-assisting detergent is a Citrate trianion, and suitable consumption is from 5 to 30wt%, preferred 10 to 25wt%; And the polymerizing acrylic acid thing, the more preferably multipolymer of vinylformic acid/toxilic acid, suitable consumption be from 0.5 to 15wt%, and preferred 1 to 10wt%.Preferred washing assistant is an alkali metal salt, particularly sodium-salt form.
Suitable builder system contains the crystalline state layered silicate, and for example, available from the SKS-6 of Hoechst, zeolite is as zeolite A and optional alkali metal citrate.
Also can contain bleach system according to detergent composition of the present invention, peroxide bleaching compound preferably, for example, and inorganic persalt or organic peroxide acid, they can produce hydrogen peroxide in the aqueous solution.The peroxide bleaching compound can and bleach-activating agent (bleaching precursor substance) use together, to improve the bleaching action under the low wash temperature.Particularly preferred bleach system contains peroxide bleaching compound (preferred SPC-D, can use with bleach-activating agent arbitrarily), and transition metal bleach catalyzer (in EP 458 397A and EP-A-509 787 open and require patent protection).
Composition of the present invention can contain basic metal, and the carbonate of preferred sodium is to increase cleansing power and processing easily.The suitable amounts of yellow soda ash can be from 1 to 60wt%, and preferred 2 to 40wt%.But, contain on a small quantity or do not contain yellow soda ash composition also within the scope of the invention.
Add the small quantities of powder structural agent, for example, lipid acid (or fatty acid soaps class), sugar, acrylate or acrylate/maleate polymkeric substance, or water glass (its suitable amounts from 1 to 5wt%) can improve the flowability of powder.
The material that can add in the detergent composition of the present invention comprises water glass; Comprise the silicate corrosion inhibitor; Anti-redeposition agent is as cellulose polymer compound; Fluorescent agent; Inorganic salt are as sodium sulfate; Foaming control agent or short foaming agent (when suitable); Proteolytic ferment and lipolytic enzyme; Dyestuff; Color dot is sewed agent; Spices; Froth suppressor; With the fiber softening compound.Be not limited to above cited.
Substrate composition is fit to use spray drying method for preparation: compatible insensitive component slurries spraying drying hot in nature, be sprayed to then, be admixed to and/or after be dosed on the component that is not suitable for by the slurries processing.The detergent particles of producing according to the inventive method is dosed in the substrate composition after with ordinary method.
The preferred tap density of detergent composition of the present invention is at least 500g/l, more preferably 550g/l at least.
This powder can be used the rearmounted tower multiviscosisty method of spray-drying process, spray-dried powders, or all non-tower process such as dry mixed granulation prepare.For mixing herein, it is favourable adopting super mixer/Fitz chilsonator.Adopt the method for super mixer/Fitz chilsonator for example to exist, EP-A-340013, EP-A-367339 have disclosure among EP-A-390251 and the EP-A-420317.
Now explain the present invention in more detail with following non-limiting instance.
Technological process
Use 1.2m
2VRV equipment, three equal chuck sections are arranged.Liquid and powder charging opening are positioned at tight the place ahead of the first hot-zone section, in the end in two sections middle chuck layer charging opening are arranged.Adding the grain mouth by this is added to the mouth that boils in the last section.Electronic oil heater is given the first two chuck section heating, and the oil temperature of use is between 120 ℃ and 190 ℃.With chuck treated, that circulating waters 15 ℃ cool off last section.In the steam pumping extraction fan, open a bypass, the make-up gas current control by reactor 10 and 50m
3Between/the hr.All experiments are all made of the full speed electric motor, and its top speed is about 30m/sec.
One-way pump is calibrated the LAS acid with the room temperature that feeds intake, and a peristaltic pump is calibrated with 47% sodium hydroxide that feeds intake.Screw feeder is calibrated the zeolite A24 that uses with feed intake yellow soda ash and stratification.Yellow soda ash and liquid add in the tight the place ahead of the first hot pressing section, and the agent of zeolite stratification adds in the 3rd section that is cooled.Zeolite adds with minimum, leaves moisture eliminator to obtain free flowing powder.
In these examples, used following dummy suffix notation:
D (4,3)=weighted mean particle diameter;
DFR=kinetics flow velocity;
UCT=uncompacted compression testing.
Embodiment 1
LAS acid and sodium hydroxide
Experiment is carried out under different output and jacket temperature.Some device parameter and powder are listed in table 1.In following all examples, all need the agent of zeolite stratification.
Table 1
Specimen holder sleeving temperature estimated output tap density DFR %COMP UCT D (4,3)＜180＞1400
KG/HOUR micron micron micron
A 170℃ 37.9 621 142 4.1 0.0 845 1.58 8.2
B 178℃ 65.2 617 130 4.7 0.0 1116 3.32 33.2
C 178℃ 76.0 576 129 5.3 0.0 1351 1.11 49.82
D 178℃ 91.9 463 101 17.6 0.0 1522 0.0 78.81
E 178℃ 41.9 599 128 12.4 0.25 869 2.96 14.44
Sample A has fabulous powder property and rational average particle size particle size.Consider that these powder all contain the 90%LAS that has an appointment, its flowability is unusual.When output increased, all some reduced sample B to the flowability of D, and particle size increases simultaneously.The increase of particle size is because the interior residual moisture of particle is higher.When output reduced, mobile improvement and particle size reduced in E.
Just can not produce any of above-mentioned powder without the agent of zeolite stratification.
Embodiment 2
LAS acid and solid phase yellow soda ash
Experiment is to carry out under the different degree of neutralization of yellow soda ash.Some device parameter and powder property are listed in table 2.The agent of zeolite stratification all must be arranged in following all examples.
Table 2
Specimen holder sleeving temperature estimated output %NA
2CO
3Pile up DFR %COMP UCT D (4,3)＜180＞1400
KG/HOUR transforms density micron micron micron
A 145℃ 42.7 42 624 131 5.9 0.0 812 1.47 6.25
B 145℃ 57.6 63 594 140 7.6 0.0 946 0.3 6.57
C 145℃ 64.9 73 597 131 11.2 0.0 849 0.29 4.64
D 145℃ 72.2 83 601 141 7.1 0.0
Because do not add water, the moisture evaporation degree is very low in these experiments.Water is mainly from the Zhong Heshui of LAS acid.Like this, adopt 145 ℃ of lower chuck layer temperature.Adopt fixed powdered sodium carbonate flow, increase the LAS acid content simultaneously, so that consistent, as shown in table 3 with the degree of neutralization of 42% to 83% LAS acid.
The all powder of being produced all has excellent flowing performance and rational average particle size particle size.When in and degree when increasing, output also increases, powder property does not degenerate.
Just can not produce any of above-mentioned powder without the agent of zeolite stratification.
According to of the present invention open, together with the four corner of the present invention that claims limited, improving described embodiment and other embodiment is conspicuous to this area professional.
Claims (9)
1. a production contains the method for the detergent particles of anion surfactant, this method comprises the following steps: the pasty substance that contains water and anion surfactant is sent in the scraping surface moisture eliminator that comprises drying zone, pasty substance in the heat drying district is to reduce its water-content, it is characterized in that, after moisture eliminator, then in the cooling zone, cool off pasty substance, this cooling zone comprises stirring tool, to stir described material and in cooling stages, the stratification agent to be introduced in the cooling zone, to form detergent particles.
2. method according to claim 1, wherein anion surfactant contains linear alkylbenzene sulfonate.
3. method according to claim 2, wherein linear alkylbenzene sulfonate accounts for 10% to 100% of anion surfactant gross weight.
4. according to the described method of above-mentioned arbitrary claim, wherein pasty substance contains the water that is no more than 50wt%.
5. according to the described method of above-mentioned arbitrary claim, wherein the stratification agent comprises silico-aluminate, silica or its mixture.
6. according to the described method of above-mentioned arbitrary claim, wherein the stratification agent is by being to join the cooling zone in 1: 3 to 1: 20 with respect to final particle weight ratio.
7. according to the described method of above-mentioned arbitrary claim, wherein anion surfactant is that anion surfactant with free acid form mixes generation mutually with neutralizing agent.
8. according to the described method of above-mentioned arbitrary claim, wherein the gained particle contains at least 75 weight % anion surfactants and the water that is no more than 10 weight %.
9. according to the described method of above-mentioned arbitrary claim, wherein gained particle tool D (4,3) average particulate diameter is 180 to 1500 microns.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB9604000.1A GB9604000D0 (en) | 1996-02-26 | 1996-02-26 | Production of anionic detergent particles |
| GB9604000.1 | 1996-02-26 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1216578A CN1216578A (en) | 1999-05-12 |
| CN1156564C true CN1156564C (en) | 2004-07-07 |
Family
ID=10789393
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB971940665A Expired - Fee Related CN1156564C (en) | 1996-02-26 | 1997-02-08 | Production of anionic detergent particles |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | USRE36593E (en) |
| EP (1) | EP0883679B1 (en) |
| JP (1) | JP2000506193A (en) |
| CN (1) | CN1156564C (en) |
| AR (1) | AR005990A1 (en) |
| AU (1) | AU733689B2 (en) |
| BR (1) | BR9707741A (en) |
| DE (1) | DE69713488T2 (en) |
| EA (1) | EA001548B1 (en) |
| ES (1) | ES2177930T3 (en) |
| GB (1) | GB9604000D0 (en) |
| HU (1) | HUP9900652A3 (en) |
| ID (1) | ID16047A (en) |
| IN (1) | IN188392B (en) |
| PL (1) | PL188721B1 (en) |
| TR (1) | TR199801664T2 (en) |
| TW (1) | TW349122B (en) |
| WO (1) | WO1997032002A1 (en) |
| ZA (1) | ZA971457B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110785481A (en) * | 2017-06-20 | 2020-02-11 | 荷兰联合利华有限公司 | Granular detergent composition comprising perfume |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW397862B (en) * | 1996-09-06 | 2000-07-11 | Kao Corp | Detergent granules and method for producing the same, and high-bulk density detergent composition |
| WO1998054289A1 (en) | 1997-05-30 | 1998-12-03 | Unilever Plc | Free-flowing particulate detergent compositions |
| GB9711356D0 (en) | 1997-05-30 | 1997-07-30 | Unilever Plc | Particulate detergent composition |
| GB9711350D0 (en) * | 1997-05-30 | 1997-07-30 | Unilever Plc | Granular detergent compositions and their production |
| GB9711359D0 (en) | 1997-05-30 | 1997-07-30 | Unilever Plc | Detergent powder composition |
| GB9825558D0 (en) | 1998-11-20 | 1999-01-13 | Unilever Plc | Granular detergent components and particulate detergent compositions containing them |
| GB9825563D0 (en) | 1998-11-20 | 1999-01-13 | Unilever Plc | Particulate laundry detergent compositions containing anionic surfactant granules |
| GB9825560D0 (en) | 1998-11-20 | 1999-01-13 | Unilever Plc | Particulate laundry detergent compositons containing nonionic surfactant granules |
| GB9826097D0 (en) | 1998-11-27 | 1999-01-20 | Unilever Plc | Detergent compositions |
| US6407050B1 (en) | 2000-01-11 | 2002-06-18 | Huish Detergents, Inc. | α-sulfofatty acid methyl ester laundry detergent composition with reduced builder deposits |
| US6468956B1 (en) * | 2000-05-24 | 2002-10-22 | Huish Detergents, Inc. | Composition containing α-sulfofatty acid ester and hydrotrope and methods of making and using the same |
| GB0023487D0 (en) | 2000-09-25 | 2000-11-08 | Unilever Plc | Production of anionic surfactant granules by in situ neutralisation |
| GB0023488D0 (en) | 2000-09-25 | 2000-11-08 | Unilever Plc | Production of anionic surfactant granules by in situ neutralisation |
| GB0023489D0 (en) * | 2000-09-25 | 2000-11-08 | Unilever Plc | Production of anionic surfactant granules by in situ neutralisation |
| US6764989B1 (en) | 2000-10-02 | 2004-07-20 | Huish Detergents, Inc. | Liquid cleaning composition containing α-sulfofatty acid ester |
| GB0125653D0 (en) | 2001-10-25 | 2001-12-19 | Unilever Plc | Process for the production of detergent granules |
| BR0213432A (en) | 2001-10-25 | 2004-11-09 | Unilever Nv | Process for the preparation of detergent granules |
| DE10160319B4 (en) * | 2001-12-07 | 2008-05-15 | Henkel Kgaa | Surfactant granules and process for the preparation of surfactant granules |
| US7485613B2 (en) | 2004-12-01 | 2009-02-03 | Venus Laboratories, Inc. | Low foaming carpet-cleaning detergent concentrate comprised of ethylene oxide adduct and without phosphates |
| US7459420B2 (en) * | 2004-12-01 | 2008-12-02 | Vlahakis E Van | Automatic dishwashing detergent comprised of ethylene oxide adduct and without phosphates |
| EP2138565A1 (en) * | 2008-06-25 | 2009-12-30 | The Procter and Gamble Company | A spray-drying process |
| EP3022279B1 (en) | 2013-07-18 | 2019-03-27 | Galaxy Surfactants Ltd. | Free-flowing, solid, high active alkyl ether sulfates |
Family Cites Families (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH552977A (en) * | 1972-06-30 | 1974-08-30 | Decker Elektromaschinenbau | DRIVE UNIT FOR GLASS WASHING MACHINES. |
| GB1437950A (en) * | 1972-08-22 | 1976-06-03 | Unilever Ltd | Detergent compositions |
| AT330930B (en) * | 1973-04-13 | 1976-07-26 | Henkel & Cie Gmbh | PROCESS FOR THE PRODUCTION OF SOLID, SPILLABLE DETERGENTS OR CLEANING AGENTS WITH A CONTENT OF CALCIUM BINDING SUBSTANCES |
| DE2433485A1 (en) * | 1973-07-16 | 1975-02-06 | Procter & Gamble | ALUMINOSILICATE ION EXCHANGERS SUITABLE FOR USE IN DETERGENTS |
| US4534879A (en) * | 1983-06-29 | 1985-08-13 | The Procter & Gamble Company | Synthetic surfactant flakes and process for making them |
| JPS6072999A (en) * | 1983-09-30 | 1985-04-25 | 花王株式会社 | Manufacture of super concentrated powder detergent |
| DD228458A1 (en) * | 1983-12-21 | 1985-10-16 | Genthin Waschmittelwerk | METHOD FOR THE CONTINUOUS PREPARATION OF DETERGENT GRANULATE PRODUCTS |
| DE3413571A1 (en) * | 1984-04-11 | 1985-10-24 | Hoechst Ag, 6230 Frankfurt | USE OF CRYSTALLINE LAYERED SODIUM SILICATES FOR WATER SOFTENING AND METHOD FOR WATER SOFTENING |
| GB8810193D0 (en) * | 1988-04-29 | 1988-06-02 | Unilever Plc | Detergent compositions & process for preparing them |
| CA2001535C (en) * | 1988-11-02 | 1995-01-31 | Peter Willem Appel | Process for preparing a high bulk density granular detergent composition |
| GB8907187D0 (en) * | 1989-03-30 | 1989-05-10 | Unilever Plc | Detergent compositions and process for preparing them |
| GB8922018D0 (en) * | 1989-09-29 | 1989-11-15 | Unilever Plc | Detergent compositions and process for preparing them |
| DE69125310T2 (en) * | 1990-05-21 | 1997-07-03 | Unilever Nv | Bleach activation |
| KR0170424B1 (en) * | 1990-07-05 | 1999-01-15 | 호르스트 헤를레,요한 글라슬 | Process for making washing and cleaning active tensile granulates |
| DE4024657A1 (en) * | 1990-08-03 | 1992-02-06 | Henkel Kgaa | METHOD FOR DRYING AND GRANULATING WAESS-RATED PASTE WASH ACTIVE AGGREGATE MIXTURES |
| ES2118783T3 (en) * | 1991-03-28 | 1998-10-01 | Unilever Nv | DETERGENT COMPOSITIONS AND PROCEDURE FOR ITS PREPARATION. |
| DE4111827A1 (en) * | 1991-04-11 | 1992-10-15 | Basf Ag | METHOD FOR PRODUCING AND PURIFYING 1-AMINO-2-PHENOXY-4-HYDROXY-ANTHRACHINONE |
| GB9108136D0 (en) * | 1991-04-17 | 1991-06-05 | Unilever Plc | Concentrated detergent powder compositions |
| JPH04359100A (en) * | 1991-06-04 | 1992-12-11 | Lion Corp | Production of high-bulk density detergent composition |
| DE4134078A1 (en) * | 1991-10-15 | 1993-04-22 | Henkel Kgaa | CONCENTRATED AQUEOUS LIQUID DETERGENT |
| JP3179186B2 (en) * | 1992-06-01 | 2001-06-25 | 花王株式会社 | Method for producing anionic activator powder |
| CA2151746A1 (en) * | 1992-12-15 | 1994-06-23 | David Karl Schisla | Secondary alkyl sulphate/zeolite-containing surfactant composition |
| DE4304015A1 (en) * | 1993-02-11 | 1994-08-18 | Henkel Kgaa | Process for the production of granules |
| GB9313878D0 (en) * | 1993-07-05 | 1993-08-18 | Unilever Plc | Detergent composition or component containing anionic surfactant and process for its preparation |
| US5431857A (en) * | 1994-01-19 | 1995-07-11 | The Procter & Gamble Company | Process for producing a high density detergent composition having improved solubility by agglomeration of anionic surfactants and an agglomerating agent |
| US5565137A (en) * | 1994-05-20 | 1996-10-15 | The Proctor & Gamble Co. | Process for making a high density detergent composition from starting detergent ingredients |
| GB9417354D0 (en) * | 1994-08-26 | 1994-10-19 | Unilever Plc | Detergent particles and process for their production |
| GB9417356D0 (en) * | 1994-08-26 | 1994-10-19 | Unilever Plc | Detergent particles and process for their production |
| DE19707649C1 (en) * | 1997-02-26 | 1998-10-22 | Henkel Kgaa | Process for the production of detergent raw materials |
| DE19710152C2 (en) * | 1997-03-12 | 1999-04-22 | Henkel Kgaa | Process for the preparation of anionic surfactant granules |
-
1996
- 1996-02-26 GB GBGB9604000.1A patent/GB9604000D0/en active Pending
-
1997
- 1997-02-08 EP EP97902354A patent/EP0883679B1/en not_active Expired - Lifetime
- 1997-02-08 JP JP9530541A patent/JP2000506193A/en not_active Ceased
- 1997-02-08 BR BR9707741A patent/BR9707741A/en not_active IP Right Cessation
- 1997-02-08 PL PL97328458A patent/PL188721B1/en not_active IP Right Cessation
- 1997-02-08 DE DE69713488T patent/DE69713488T2/en not_active Expired - Fee Related
- 1997-02-08 ES ES97902354T patent/ES2177930T3/en not_active Expired - Lifetime
- 1997-02-08 EA EA199800766A patent/EA001548B1/en not_active IP Right Cessation
- 1997-02-08 HU HU9900652A patent/HUP9900652A3/en unknown
- 1997-02-08 WO PCT/EP1997/000591 patent/WO1997032002A1/en active IP Right Grant
- 1997-02-08 TR TR1998/01664T patent/TR199801664T2/en unknown
- 1997-02-08 CN CNB971940665A patent/CN1156564C/en not_active Expired - Fee Related
- 1997-02-08 AU AU16022/97A patent/AU733689B2/en not_active Ceased
- 1997-02-20 ZA ZA971457A patent/ZA971457B/en unknown
- 1997-02-21 IN IN108BO1997 patent/IN188392B/en unknown
- 1997-02-25 AR ARP970100750A patent/AR005990A1/en unknown
- 1997-02-25 ID IDP970563A patent/ID16047A/en unknown
- 1997-03-03 TW TW086102500A patent/TW349122B/en active
-
1999
- 1999-06-17 US US09/336,117 patent/USRE36593E/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110785481A (en) * | 2017-06-20 | 2020-02-11 | 荷兰联合利华有限公司 | Granular detergent composition comprising perfume |
| CN110785481B (en) * | 2017-06-20 | 2021-04-13 | 荷兰联合利华有限公司 | Granular detergent composition comprising perfume |
Also Published As
| Publication number | Publication date |
|---|---|
| AR005990A1 (en) | 1999-07-21 |
| EP0883679A1 (en) | 1998-12-16 |
| DE69713488D1 (en) | 2002-07-25 |
| PL328458A1 (en) | 1999-02-01 |
| WO1997032002A1 (en) | 1997-09-04 |
| HUP9900652A3 (en) | 2002-04-29 |
| GB9604000D0 (en) | 1996-04-24 |
| ZA971457B (en) | 1998-08-20 |
| EA001548B1 (en) | 2001-04-23 |
| CN1216578A (en) | 1999-05-12 |
| JP2000506193A (en) | 2000-05-23 |
| TR199801664T2 (en) | 1998-11-23 |
| BR9707741A (en) | 1999-07-27 |
| USRE36593E (en) | 2000-02-29 |
| IN188392B (en) | 2002-09-14 |
| EA199800766A1 (en) | 1999-02-25 |
| PL188721B1 (en) | 2005-04-29 |
| TW349122B (en) | 1999-01-01 |
| ES2177930T3 (en) | 2002-12-16 |
| HUP9900652A2 (en) | 1999-07-28 |
| EP0883679B1 (en) | 2002-06-19 |
| AU1602297A (en) | 1997-09-16 |
| ID16047A (en) | 1997-08-28 |
| DE69713488T2 (en) | 2003-01-16 |
| AU733689B2 (en) | 2001-05-24 |
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