CN115416382A - Hollow micro-nanofiber non-woven material with laminated structure and preparation method and application thereof - Google Patents
Hollow micro-nanofiber non-woven material with laminated structure and preparation method and application thereof Download PDFInfo
- Publication number
- CN115416382A CN115416382A CN202211073265.5A CN202211073265A CN115416382A CN 115416382 A CN115416382 A CN 115416382A CN 202211073265 A CN202211073265 A CN 202211073265A CN 115416382 A CN115416382 A CN 115416382A
- Authority
- CN
- China
- Prior art keywords
- laminated structure
- layer
- woven material
- fiber
- hollow micro
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002121 nanofiber Substances 0.000 title claims abstract description 68
- 239000000463 material Substances 0.000 title claims abstract description 50
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000000835 fiber Substances 0.000 claims abstract description 65
- 239000010410 layer Substances 0.000 claims abstract description 64
- 238000009987 spinning Methods 0.000 claims abstract description 43
- 239000000243 solution Substances 0.000 claims abstract description 35
- 229920002239 polyacrylonitrile Polymers 0.000 claims abstract description 31
- 238000000034 method Methods 0.000 claims abstract description 22
- 239000002105 nanoparticle Substances 0.000 claims abstract description 21
- 239000012792 core layer Substances 0.000 claims abstract description 18
- 239000000843 powder Substances 0.000 claims abstract description 16
- 239000007788 liquid Substances 0.000 claims abstract description 15
- 238000010041 electrostatic spinning Methods 0.000 claims abstract description 11
- 239000011259 mixed solution Substances 0.000 claims abstract description 9
- 238000005345 coagulation Methods 0.000 claims abstract description 8
- 230000015271 coagulation Effects 0.000 claims abstract description 8
- 239000002904 solvent Substances 0.000 claims abstract description 5
- 230000001105 regulatory effect Effects 0.000 claims abstract description 4
- 230000001276 controlling effect Effects 0.000 claims abstract description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 15
- 239000002344 surface layer Substances 0.000 claims description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 13
- 239000002041 carbon nanotube Substances 0.000 claims description 8
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 8
- 210000002615 epidermis Anatomy 0.000 claims description 8
- 230000010412 perfusion Effects 0.000 claims description 8
- 229920000642 polymer Polymers 0.000 claims description 8
- 229920001410 Microfiber Polymers 0.000 claims description 6
- 239000003658 microfiber Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 229910021389 graphene Inorganic materials 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical group O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 4
- 229940070527 tourmaline Drugs 0.000 claims description 4
- 229910052613 tourmaline Inorganic materials 0.000 claims description 4
- 239000011032 tourmaline Substances 0.000 claims description 4
- 238000007711 solidification Methods 0.000 claims description 3
- 230000008023 solidification Effects 0.000 claims description 3
- 238000007664 blowing Methods 0.000 claims description 2
- 239000000919 ceramic Substances 0.000 claims description 2
- 230000002787 reinforcement Effects 0.000 claims description 2
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 claims description 2
- 239000004753 textile Substances 0.000 abstract description 4
- 230000001681 protective effect Effects 0.000 abstract description 2
- 230000003014 reinforcing effect Effects 0.000 abstract 1
- 239000012510 hollow fiber Substances 0.000 description 13
- 230000007613 environmental effect Effects 0.000 description 10
- 238000009960 carding Methods 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 238000009413 insulation Methods 0.000 description 4
- 239000012774 insulation material Substances 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 238000004321 preservation Methods 0.000 description 3
- 230000003068 static effect Effects 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 208000024172 Cardiovascular disease Diseases 0.000 description 1
- 208000001034 Frostbite Diseases 0.000 description 1
- 239000005662 Paraffin oil Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 208000015606 cardiovascular system disease Diseases 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 230000001808 coupling effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000002526 effect on cardiovascular system Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 208000023504 respiratory system disease Diseases 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000001132 ultrasonic dispersion Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/022—Non-woven fabric
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/06—Thermally protective, e.g. insulating
- A41D31/065—Thermally protective, e.g. insulating using layered materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
- B32B5/265—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary characterised by one fibrous or filamentary layer being a non-woven fabric layer
- B32B5/266—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary characterised by one fibrous or filamentary layer being a non-woven fabric layer next to one or more non-woven fabric layers
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/0007—Electro-spinning
- D01D5/0015—Electro-spinning characterised by the initial state of the material
- D01D5/003—Electro-spinning characterised by the initial state of the material the material being a polymer solution or dispersion
- D01D5/0046—Electro-spinning characterised by the initial state of the material the material being a polymer solution or dispersion the fibre formed by coagulation, i.e. wet electro-spinning
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/24—Formation of filaments, threads, or the like with a hollow structure; Spinnerette packs therefor
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4282—Addition polymers
- D04H1/43—Acrylonitrile series
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4382—Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
- D04H1/43838—Ultrafine fibres, e.g. microfibres
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4391—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece characterised by the shape of the fibres
- D04H1/43914—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece characterised by the shape of the fibres hollow fibres
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
- D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
- D04H1/492—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres by fluid jet
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
- D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
- D04H1/498—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres entanglement of layered webs
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/03—3 layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/20—All layers being fibrous or filamentary
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0246—Acrylic resin fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/304—Insulating
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Nonwoven Fabrics (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Artificial Filaments (AREA)
Abstract
The invention relates to the technical field of functional textile materials, in particular to a hollow micro-nanofiber non-woven material with a laminated structure and a preparation method and application thereof, and the hollow micro-nanofiber non-woven material comprises the following steps: (1) Completely dissolving polyacrylonitrile powder in a solvent, and then adding far infrared nano particles and uniformly dispersing; (2) The method comprises the following steps of taking a polyacrylonitrile/far infrared nanoparticle mixed solution as a shell layer, taking temperature-controllable wet air as a core layer, spinning by using a coaxial electrostatic spinning method, receiving spun fibers by using a liquid coagulation tank, and preparing a laminated structure micro-nano fiber assembly with different fiber diameters and hollowness by regulating and controlling the properties of a spinning solution and spinning process parameters in a gradient manner; (3) And reinforcing the micro-nanofiber aggregate by a spunlace method to prepare the hollow micro-nanofiber non-woven material with the laminated structure. The laminated structure hollow micro-nanofiber non-woven material can be used for designing and developing high-performance cold-proof warm-keeping textile products and safety protective clothing.
Description
Technical Field
The invention relates to the technical field of functional textile materials, in particular to a hollow micro-nanofiber non-woven material with a laminated structure and a preparation method and application thereof.
Background
The cold environment at low temperature easily causes frostbite of human body, causes the immunity of the organism to be reduced, and causes cardiovascular and respiratory system diseases, thus seriously affecting the health and life safety of people. Therefore, it is necessary to wear cold-proof clothes having a warm-keeping function to resist the harm of the severe cold environment to the human body. At present, the common thermal filling materials for cold-proof thermal garments are mainly down fibers, which have good thermal properties, but face the disadvantages of low yield, high cost, complex processing and treatment processes, and the like, thereby greatly limiting the practical application thereof.
The hollow fiber contains a large amount of static air, so that the heat preservation performance of the fiber material can be effectively improved, and the hollow fiber is expected to become a good substitute of down fiber. At present, most researchers introduce hollow fibers into the yarn preparation process, add hollow short fibers into common solid fiber raw materials, further spin blended yarns containing the hollow fibers through the procedures of carding, drawing, roving, spinning and the like, and then weave the hollow fiber blended yarns into the thermal fabric containing the hollow fibers by using a weaving or knitting technology. However, the spinning and twisting action causes the hollow fibers to be closely arranged in the yarns, so that the structural advantages of the hollow fibers are limited, and the heat-insulating property of the material cannot be greatly improved. In addition, some researchers mix the hollow micro short fibers and the solid micro short fibers, and mix the hollow micro short fibers with the nano short fibers, and further prepare the three-dimensional hollow fiber thermal insulating flocculus (CN 111648025B) by carding, web forming, fiber web laminating and thermal bonding methods, but the nano effect of the nano short fibers causes the nano short fibers to be easily and electrostatically adsorbed on a mechanism in carding and web forming equipment in the carding process, so that the distribution uniformity of the nano fibers is difficult to control, the structure of the nano fibers is easily damaged in the carding process, and the structural forming and the thermal insulating performance of the flocculus material are not greatly improved. Recently, chinese patent CN114714693A reports a nanofiber thermal insulation material and a preparation method thereof, the light and thin nanofiber thermal insulation and moisture permeable fabric comprises an outer layer support fabric, a nanofiber far infrared waterproof moisture permeable layer, a nanofiber thermal insulation layer and a heating fabric, but paraffin oil is used as an inner core to prepare a polyurethane hollow nanofiber thermal insulation layer, and a paraffin inner core layer of polyurethane nanofibers needs to be removed by using an organic solvent soaking method subsequently, however, the structure with good nanofiber continuity leads to difficulty in completely removing the paraffin inner core layer inside, the preparation process is complex, and the production cost is high.
Therefore, the present application needs to provide a hollow micro-nanofiber nonwoven material with a laminated structure, and a preparation method and an application thereof, so as to solve the above related technical problems.
Disclosure of Invention
Aiming at the problems, the invention provides a hollow micro-nanofiber non-woven material with a laminated structure and a preparation method and application thereof.
In order to achieve the purpose, the technical scheme adopted by the invention is as follows:
the utility model provides a hollow micro-nanofiber non-woven material of laminated structure, includes upper epidermis, lower top layer and locates the intermediate level between upper epidermis and the lower top layer, upper epidermis and lower top layer are the fibre and pile up inseparable hollow nanofiber layer, the intermediate level is the fibre and piles up fluffy hollow microfiber layer, and the thickness of intermediate level is greater than the thickness on upper epidermis and lower top layer.
Preferably, in the upper surface layer and the lower surface layer, the fiber diameter is 0.2-1 μm, the hollowness is 20-40%, the thickness of the fiber layer is 0.5-2 mm, and the fiber bulk density is 10-15 mg/cm 3 (ii) a In the intermediate layer, the fiber diameter is 1-3 μm, the hollowness is 50-80%, the fiber layer thickness is 10-25 mm, and the fiber bulk density is 3-8 mg/cm 3 。
Preferably, the thermal conductivity of the laminated hollow micro-nanofiber non-woven material is 0.025-0.029W/(m.K).
The invention also provides a preparation method of the hollow micro-nanofiber non-woven material with the laminated structure, which comprises the following steps:
step 1, dissolving polyacrylonitrile powder in a solvent, then adding far infrared nano particles and uniformly dispersing to obtain a polyacrylonitrile/far infrared nano particle mixed solution;
step 2, taking a polyacrylonitrile/far infrared nanoparticle mixed solution as a shell layer, taking temperature-controllable wet air as a core layer, spinning by using a coaxial electrostatic spinning method, receiving spun fibers by using a liquid coagulation tank, and preparing a laminated structure micro-nano fiber aggregate with different fiber diameters and hollowness by regulating and controlling the properties of a spinning solution and spinning process parameters in a gradient manner;
and 3, carrying out spunlace reinforcement on the micro-nano fiber aggregate with the laminated structure obtained in the step 2, and then carrying out air blowing and drying to prepare the hollow micro-nano fiber non-woven material with the laminated structure.
Preferably, in step 1, the solvent is one or more of N, N-dimethylformamide, dimethyl sulfoxide and sulfolane; the far infrared nano-particles are one or more of carbon nano-tubes, graphene, tourmaline powder and ceramic nano-particles;
wherein, in the polyacrylonitrile/far infrared nano particle mixed solution, the mass concentration of the polyacrylonitrile is 5 to 35 weight percent, and the mass concentration of the far infrared nano particles is 0.1 to 5 weight percent.
Preferably, in the step 2, coaxial spinneret orifices for coaxial electrostatic spinning are arranged in an array manner, a shell layer of the coaxial spinneret orifices is filled with the polyacrylonitrile/far infrared nanoparticle mixed solution obtained in the step 1, and a medium filled in a core layer of the coaxial spinneret orifices is temperature-controllable wet air;
wherein the temperature of the temperature-controllable humid air is 30-40 ℃, and the humidity is 80-95%;
wherein the liquid contained in the solidification tank is deionized water;
wherein, the hollow micro-nanofiber in the fiber aggregate has continuity.
Preferably, in the step 2, the perfusion speed of the shell polymer solution of the coaxial spinneret orifice is 1-10 mL/h, the flow rate of the wet air of the nuclear layer is 1-20 m/s, the voltage is 10-50 kV, the distance between the spinneret orifice and the liquid level of the liquid coagulation pool is 10-50 cm, the ambient temperature is 15-30 ℃, and the ambient humidity is 30-70%.
The invention also provides application of the hollow micro-nanofiber non-woven material with the laminated structure in the field of cold protection and warm keeping.
Adopt above-mentioned technical scheme: the laminated structure mainly means that on the longitudinal section of the non-woven material, the upper surface layer and the lower surface layer are hollow nanofiber layers with smaller thickness, and the hollow nanofibers are tightly stacked, so that air convection in the non-woven material can be effectively reduced; the middle layer is a hollow micro-fiber layer, the larger diameter of the middle layer enables the middle layer to have larger bending rigidity, the longitudinal structures of the upper hollow nano-fiber layer and the lower hollow nano-fiber layer can be effectively supported, the hollow micro-fiber is stacked to be fluffy, and the static air content of the non-woven material can be effectively improved by the hollow structure of the micro-nanofiber and the multilayer laminated stacking structure; in addition, far infrared nano particles contained in the hollow fiber tube wall can effectively absorb and radiate far infrared rays, so that the hollow fiber tube has high-efficiency cold-proof and warm-keeping performance.
The invention has the beneficial effects that:
1. the invention adopts a coaxial electrostatic spinning method to prepare the hollow micro-nanofiber, which is different from the traditional core-shell electrostatic spinning method, the temperature-controllable wet air is loaded on the core layer, and the wet air with a certain temperature can promote the polyacrylonitrile/far infrared nanoparticle mixed spinning solution to generate rapid phase separation to form a stable hollow core layer, thereby effectively avoiding the collapse of a hollow structure; in addition, because the core layer uses the air medium, the subsequent process does not need to adopt an organic solvent soaking method to remove the hollow structure template medium of the core layer, the spinning speed of the hollow fiber can be effectively improved, the use of the organic solvent is reduced, and the production cost is reduced.
2. According to the invention, the electrostatic spinning hollow micro-nano fiber is received by adopting the coagulation bath, the mass concentration and the spinning process parameters of polyacrylonitrile and far infrared nano particles in a spinning solution are regulated and controlled in a gradient manner to prepare the micro-nano fiber aggregate with the laminated structure with different fiber diameters and hollowness, and the fiber aggregate is reinforced by a spunlace process, so that the upper hollow nano fiber layer and the lower hollow nano fiber layer of the prepared non-woven thermal insulation material have higher stacking density, the convection of air in the material can be reduced, the loosely stacked hollow micro-fiber intermediate layer has higher porosity, and the storage capacity of the non-woven material to static air can be effectively improved by the coupling effect of the non-woven thermal insulation material and the hollow fiber, thereby the thermal insulation performance of the material is improved.
3. Far infrared particles doped in the tube wall of the hollow micro-nanofiber non-woven material with the laminated structure can effectively absorb and radiate far infrared rays, so that the heat preservation performance of the non-woven material can be further improved, and the prepared material is expected to be applied to design and development of novel efficient cold-proof heat-preservation textiles and safety protective clothing.
Detailed Description
The technical solutions of the present invention are further illustrated and described below by specific embodiments, but the embodiments of the present invention are not limited thereto.
Example 1: a preparation method of a hollow micro-nanofiber non-woven material with a laminated structure comprises the following steps:
step 1, weighing polyacrylonitrile powder, dispersing the polyacrylonitrile powder in N, N-dimethylformamide, stirring the mixture at room temperature until the polyacrylonitrile powder is completely dissolved, then adding carbon nano tubes into the solution, and uniformly dispersing the carbon nano tubes by ultrasonic waves to obtain spinning solutions of upper-layer fibers and lower-layer fibers, wherein the mass concentration of polyacrylonitrile in the spinning solution is 8wt%, and the mass concentration of the carbon nano tubes is 0.5wt%; preparing a spinning solution of the middle layer fiber by the same method, wherein the mass concentration of polyacrylonitrile in the spinning solution is 33wt%, and the mass concentration of the carbon nano tube is 1wt%;
step 2, spinning the spinning solution obtained in the step 1 by adopting a coaxial electrostatic spinning technology, wherein the spun fiber is received in a square deionized water coagulation bath pool, when the fibers of the upper and lower surface layers are spun, the perfusion speed of the polymer solution of the shell layer of the coaxial spinning nozzle is 1mL/h, the voltage is 35kV, the distance between the spinning nozzle and the receiving liquid level is 15cm, the environmental temperature is 25 ℃, the environmental humidity is 35%, and the flow velocity of the air of the nuclear layer of the coaxial spinning nozzle is 2m/s; when the middle layer fiber is spun, the perfusion speed of the shell polymer solution of the coaxial spinneret orifice is 3mL/h, the voltage is 20kV, the distance between the spinneret orifice and the receiving liquid level is 25cm, the environmental temperature is 25 ℃, the environmental humidity is 70 percent, and the flow speed of the core layer air of the coaxial spinneret orifice is 18m/s; the temperature of the wet air of the nuclear layer is 35 ℃ and the humidity is 90 percent;
and 3, carrying out spunlace treatment on the hollow micro-nanofiber aggregate with the laminated structure obtained in the step 2, and then drying in a forced air oven to prepare the hollow micro-nanofiber non-woven material with the laminated structure. The average diameter of the hollow nanofibers in the upper and lower surface layers of the laminated nonwoven material was about 0.3 μm, the hollowness was about 23%, the thickness of the fiber layer was 2mm, and the bulk density was 14.5mg/cm 3 (ii) a The average diameter of hollow micro-fiber in the middle layer is about 2.5 μm, the hollowness is about 68%, the thickness of the fiber layer is 23mm, and the bulk density is 4mg/cm 3 (ii) a The prepared hollow micro-nanofiber non-woven material with the laminated structure has the thermal conductivity coefficient of 0.0253W/(m.K).
Example 2: a preparation method of a hollow micro-nanofiber non-woven material with a laminated structure comprises the following steps:
step 1, weighing polyacrylonitrile powder, dispersing the polyacrylonitrile powder in N, N-dimethylformamide, stirring the mixture at room temperature until the polyacrylonitrile powder is completely dissolved, then adding graphene into the solution, and performing ultrasonic dispersion to obtain spinning solutions of upper-layer fibers and lower-layer fibers, wherein the mass concentration of polyacrylonitrile in the spinning solution is 10wt%, and the mass concentration of graphene in the spinning solution is 1wt%; preparing a spinning solution of the intermediate layer fiber by the same method, wherein the mass concentration of polyacrylonitrile in the spinning solution is 30wt%, and the mass concentration of graphene is 1.5wt%;
step 2, spinning the spinning solution obtained in the step 1 by adopting a coaxial electrostatic spinning technology, wherein the spun fiber is received in a square deionized water coagulation bath pool, when the upper surface layer fiber and the lower surface layer fiber are spun, the perfusion speed of the shell layer polymer solution of a coaxial spinning nozzle is 2mL/h, the voltage is 35kV, the distance between the spinning nozzle and the receiving liquid level is 15cm, the environmental temperature is 25 ℃, the environmental humidity is 40%, and the flow velocity of the core layer air of the coaxial spinning nozzle is 5m/s; when the middle layer fiber is spun, the perfusion speed of the shell polymer solution of the coaxial spinneret orifice is 3mL/h, the voltage is 20kV, the distance between the spinneret orifice and the receiving liquid level is 27cm, the environmental temperature is 25 ℃, the environmental humidity is 65 percent, and the flow speed of the core layer air of the coaxial spinneret orifice is 15m/s; the temperature of the wet air of the nuclear layer is 35 ℃ and the humidity is 85 percent;
and 3, carrying out spunlace treatment on the hollow micro-nanofiber aggregate with the laminated structure obtained in the step 2, and then drying in a blast oven to prepare the hollow micro-nanofiber nonwoven material with the laminated structure. The average diameter of the hollow nano-fiber in the lower surface layer of the laminated non-woven material is about 390nm, the hollowness is about 26 percent, the thickness of the fiber layer is 1.5mm, and the bulk density is 14mg/cm 3 (ii) a The diameter of the hollow micron fiber in the middle layer is about 1.9 μm, the hollowness is about 59%, the thickness of the fiber layer is 20mm, and the bulk density is 5.3mg/cm 3 (ii) a The prepared hollow micro-nanofiber non-woven material with the laminated structure has a thermal conductivity coefficient of 0.0261W/(m.K).
Example 3: a preparation method of a hollow micro-nanofiber non-woven material with a laminated structure comprises the following steps:
step 1, weighing polyacrylonitrile powder, dispersing the polyacrylonitrile powder in N, N-dimethylformamide, stirring the mixture at room temperature until the polyacrylonitrile powder is completely dissolved, then adding carbon nanotubes into the solution, and uniformly dispersing the carbon nanotubes in the solution by ultrasonic waves to obtain spinning solutions of upper and lower surface layer fibers, wherein the mass concentration of polyacrylonitrile in the spinning solution is 13wt%, and the mass concentration of tourmaline powder is 1wt%; preparing a spinning solution of the middle layer fiber by the same method, wherein the mass concentration of polyacrylonitrile in the spinning solution is 25wt%, and the mass concentration of tourmaline powder is 2wt%;
step 2, spinning the spinning solution obtained in the step 1 by adopting a coaxial electrostatic spinning technology, wherein the spun fiber is received in a square deionized water coagulation bath pool, when the upper surface layer fiber and the lower surface layer fiber are spun, the perfusion speed of the shell layer polymer solution of a coaxial spinning nozzle is 2mL/h, the voltage is 35kV, the distance between the spinning nozzle and the receiving liquid level is 17cm, the environmental temperature is 25 ℃, the environmental humidity is 40%, and the flow velocity of the core layer air of the coaxial spinning nozzle is 4m/s; when the middle layer fiber is spun, the perfusion speed of the shell polymer solution of the coaxial spinneret orifice is 3mL/h, the voltage is 25kV, the distance between the spinneret orifice and the receiving liquid level is 25cm, the ambient temperature is 25 ℃, the ambient humidity is 65 percent, and the flow velocity of the core layer gas air of the coaxial spinneret orifice is 16m/s; the temperature and the humidity of the core layer wet air are both 30 ℃ and 80 percent;
and 3, carrying out spunlace treatment on the hollow micro-nanofiber aggregate with the laminated structure obtained in the step 2, and then drying in a forced air oven to prepare the hollow micro-nanofiber non-woven material with the laminated structure. The average diameter of the fibers of the upper and lower surface layers of the laminated nonwoven material was about 700nm, the degree of hollowness was about 32%, the thickness of the fiber layer was 1mm, and the bulk density was 10.5mg/cm 3 (ii) a The diameter of the hollow micron fiber in the middle layer is about 2.3 μm, the hollowness is about 53 percent, the thickness of the fiber layer is 15mm, and the bulk density is 7.5mg/cm 3 (ii) a The prepared hollow micro-nanofiber non-woven material with the laminated structure has the thermal conductivity coefficient of 0.0281W/(m.K).
The above examples are only for further illustrating the specific embodiments of the present invention, but the present invention is not limited to the above examples, and all equivalent changes and modifications made to the above examples according to the technical spirit of the present invention are included in the scope of the technical solution of the present invention.
Claims (8)
1. The utility model provides a hollow micro-nanofiber non-woven material of laminated structure which characterized in that, includes upper epidermis, lower top layer and locates the intermediate level between upper epidermis and the lower top layer, upper epidermis and lower top layer are the fibre and pile up inseparable hollow nanofiber layer, the intermediate level is the fibre and piles up fluffy hollow microfiber layer, and the thickness of intermediate level is greater than the thickness on upper epidermis and lower top layer.
2. The hollow micro-nanofiber non-woven material with the laminated structure according to claim 1, wherein in the upper surface layer and the lower surface layer, the fiber diameter is 0.2-1 μm, the hollowness is 20-40%, the thickness of the fiber layer is 0.5-2 mm, and the fiber bulk density is 10-15 mg/cm 3 (ii) a In the intermediate layer, the fiber diameter is 1-3 μm, the hollowness is 50-80%, the fiber layer thickness is 10-25 mm, and the fiber bulk density is 3-8 mg/cm 3 。
3. The laminated structure hollow micro-nanofiber nonwoven material as claimed in claim 2, wherein the thermal conductivity of the laminated structure hollow micro-nanofiber nonwoven material is 0.025-0.029W/(m-K).
4. The preparation method of the hollow micro-nanofiber non-woven material with the laminated structure according to claim 1, characterized by comprising the following steps:
step 1, dissolving polyacrylonitrile powder in a solvent, then adding far infrared nano particles and uniformly dispersing to obtain a polyacrylonitrile/far infrared nano particle mixed solution;
step 2, taking the polyacrylonitrile/far infrared nanoparticle mixed solution as a shell layer, taking temperature-controllable wet air as a core layer, spinning by using a coaxial electrostatic spinning method, receiving spun fibers by using a liquid solidification tank, and preparing a laminated structure micro-nano fiber aggregate with different fiber diameters and hollowness by regulating and controlling the properties of the spinning solution and spinning process parameters in a gradient manner;
and 3, carrying out spunlace reinforcement on the micro-nano fiber aggregate with the laminated structure obtained in the step 2, and then carrying out air blowing and drying to prepare the hollow micro-nano fiber non-woven material with the laminated structure.
5. The method for preparing the hollow micro-nanofiber non-woven material with the laminated structure according to claim 4, wherein in the step 1, the solvent is one or a mixture of N, N-dimethylformamide, dimethyl sulfoxide and sulfolane; the far infrared nano-particles are one or more of carbon nano-tubes, graphene, tourmaline powder and ceramic nano-particles;
in the polyacrylonitrile/far infrared nano-particle mixed solution, the mass concentration of polyacrylonitrile is 5-35 wt%, and the mass concentration of far infrared nano-particles is 0.1-5 wt%.
6. The method for preparing the hollow micro-nanofiber non-woven material with the laminated structure according to claim 4, wherein in the step 2, coaxial spinneret orifices for coaxial electrostatic spinning are arranged in an array manner, a shell layer of the coaxial spinneret orifices is filled with the polyacrylonitrile/far infrared nanoparticle mixed solution obtained in the step 1, and a medium filled in a core layer of the coaxial spinneret orifices is temperature-controllable wet air;
the temperature of the temperature-controllable wet air is 30-40 ℃, and the humidity is 80-95%;
the liquid contained in the solidification tank is deionized water;
the hollow micro-nanofibers in the fiber aggregate have continuity.
7. The method for preparing the hollow micro-nanofiber non-woven material with the laminated structure according to claim 4, wherein in the step 2, the perfusion speed of the polymer solution of the shell layer of the coaxial spinneret is 1-10 mL/h, the flow rate of the wet air of the core layer is 1-20 m/s, the voltage is 10-50 kV, the distance between the spinneret and the liquid surface of the liquid coagulation tank is 10-50 cm, the ambient temperature is 15-30 ℃, and the ambient humidity is 30-70%.
8. The application of the laminated structure hollow micro-nanofiber non-woven material in the field of cold protection and warm keeping.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211073265.5A CN115416382B (en) | 2022-09-02 | 2022-09-02 | Hollow micro-nanofiber non-woven material with laminated structure and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211073265.5A CN115416382B (en) | 2022-09-02 | 2022-09-02 | Hollow micro-nanofiber non-woven material with laminated structure and preparation method and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN115416382A true CN115416382A (en) | 2022-12-02 |
| CN115416382B CN115416382B (en) | 2024-03-29 |
Family
ID=84203007
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202211073265.5A Active CN115416382B (en) | 2022-09-02 | 2022-09-02 | Hollow micro-nanofiber non-woven material with laminated structure and preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN115416382B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117051538A (en) * | 2023-08-21 | 2023-11-14 | 波司登羽绒服装有限公司 | Nanofiber membrane thermal insulation material, preparation method thereof and down jacket |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103088442A (en) * | 2013-01-23 | 2013-05-08 | 上海交通大学 | Preparation method of hollow fiber in coaxial electrostatic spinning |
| CN107139553A (en) * | 2017-04-13 | 2017-09-08 | 深圳市和煦健康科技有限公司 | A kind of warming cold-resistant fabric structure |
| CN111455474A (en) * | 2020-03-23 | 2020-07-28 | 东华大学 | Wool-like crimped electrostatic spinning nanofiber and preparation method thereof |
| CN111485329A (en) * | 2020-03-23 | 2020-08-04 | 东华大学 | Nanofiber flocculus with sandwich structure and preparation method thereof |
| WO2020221286A1 (en) * | 2019-04-30 | 2020-11-05 | 西南石油大学 | β-FEOOH/POLYACRYLONITRILE COMPOSITE NANOFIBER MEMBRANE, PREPARATION METHOD THEREFOR AND USE THEREOF |
| WO2020232931A1 (en) * | 2019-05-21 | 2020-11-26 | 江西先材纳米纤维科技有限公司 | Preparation method for long continuous electrospun polyacrylonitrile nanofiber yarn, and application thereof |
| CN113529279A (en) * | 2021-07-08 | 2021-10-22 | 吉祥三宝高科纺织有限公司 | Humidity induced compact forming process for waterproof moisture permeable nanofiber membrane |
| CN114714693A (en) * | 2022-02-15 | 2022-07-08 | 昆承新材料科技(江苏)有限公司 | Nano-fiber thermal material and preparation method thereof |
| CN114892290A (en) * | 2022-05-09 | 2022-08-12 | 苏州中色德源环保科技有限公司 | Coreless liquid dry-wet hollow fiber membrane spinning process |
-
2022
- 2022-09-02 CN CN202211073265.5A patent/CN115416382B/en active Active
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103088442A (en) * | 2013-01-23 | 2013-05-08 | 上海交通大学 | Preparation method of hollow fiber in coaxial electrostatic spinning |
| CN107139553A (en) * | 2017-04-13 | 2017-09-08 | 深圳市和煦健康科技有限公司 | A kind of warming cold-resistant fabric structure |
| WO2020221286A1 (en) * | 2019-04-30 | 2020-11-05 | 西南石油大学 | β-FEOOH/POLYACRYLONITRILE COMPOSITE NANOFIBER MEMBRANE, PREPARATION METHOD THEREFOR AND USE THEREOF |
| WO2020232931A1 (en) * | 2019-05-21 | 2020-11-26 | 江西先材纳米纤维科技有限公司 | Preparation method for long continuous electrospun polyacrylonitrile nanofiber yarn, and application thereof |
| CN111455474A (en) * | 2020-03-23 | 2020-07-28 | 东华大学 | Wool-like crimped electrostatic spinning nanofiber and preparation method thereof |
| CN111485329A (en) * | 2020-03-23 | 2020-08-04 | 东华大学 | Nanofiber flocculus with sandwich structure and preparation method thereof |
| CN113529279A (en) * | 2021-07-08 | 2021-10-22 | 吉祥三宝高科纺织有限公司 | Humidity induced compact forming process for waterproof moisture permeable nanofiber membrane |
| CN114714693A (en) * | 2022-02-15 | 2022-07-08 | 昆承新材料科技(江苏)有限公司 | Nano-fiber thermal material and preparation method thereof |
| CN114892290A (en) * | 2022-05-09 | 2022-08-12 | 苏州中色德源环保科技有限公司 | Coreless liquid dry-wet hollow fiber membrane spinning process |
Non-Patent Citations (2)
| Title |
|---|
| 顾其胜等: "《海藻酸盐基生物医用材料与临床医学》", 上海科学技术出版社, pages: 134 - 135 * |
| 高宁;彭应杰;张爱英;叶霖;冯增国: "溶液参数对静电纺丝PAN@PS复合纳米纤维形貌及结构的影响", 合成树脂及塑料, vol. 36, no. 03, pages 12 - 17 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117051538A (en) * | 2023-08-21 | 2023-11-14 | 波司登羽绒服装有限公司 | Nanofiber membrane thermal insulation material, preparation method thereof and down jacket |
Also Published As
| Publication number | Publication date |
|---|---|
| CN115416382B (en) | 2024-03-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Liu et al. | Recent advances in novel aerogels through the hybrid aggregation of inorganic nanomaterials and polymeric fibers for thermal insulation | |
| Mazrouei-Sebdani et al. | Multiple assembly strategies for silica aerogel-fiber combinations–A review | |
| Zong et al. | Electrospun fibrous sponges: principle, fabrication, and applications | |
| CN105463603B (en) | A kind of SiO2The preparation method of/cellulose toughness airsetting glue fiber | |
| CN108840656A (en) | One kind being based on Static Spinning SiO2Nanofiber aerogel heat-insulating material and its preparation and application | |
| CN113416054B (en) | Preparation method of silica nanofiber/MXene composite aerogel with double protection performance | |
| CN102634870A (en) | Carbon-nanotube-reinforced cellulose-base carbon nanofiber and preparation method thereof | |
| Xue et al. | Double-network polyimide/silica aerogel fiber for thermal insulation under extremely hot and humid environment | |
| CN113308764B (en) | Silicon-based ceramic micro-nanofiber heat insulation felt and preparation method thereof | |
| CN106435841A (en) | Polyacrylonitrile porous carbon fiber preparation method | |
| CN115416382B (en) | Hollow micro-nanofiber non-woven material with laminated structure and preparation method and application thereof | |
| CN106350883A (en) | Preparation method of graphene oxide/polyacrylonitrile composite fiber | |
| Zhao et al. | Superelastic, lightweight, and flame-retardant 3D fibrous sponge fabricated by one-step electrospinning for heat retention | |
| CN113308754A (en) | Method for preparing high-orientation aramid fiber based on wet spinning | |
| CN108315877A (en) | A kind of graphene non-woven fabrics and its manufacturing process | |
| Zhang et al. | Large-scale solution blow spinning of flexible carbon nanofibers for the separation applications | |
| CN103350544A (en) | Fabric with warm-keeping and thermal insulation functions and preparation method thereof | |
| CN106626588A (en) | Micro-nano-scale regenerated fiber non-woven fabric with moisture conducting and rapid drying properties and preparation method of non-woven fabric | |
| CN105442093B (en) | A kind of standby continuous hollow SiO of coaxial spinning2The method of porous fibre | |
| CN108532128B (en) | One kind having polymer composite fibrous film of graphene-metal sulfide-layered and preparation method thereof | |
| CN105442099B (en) | A kind of toughness SiO post-processed with isocyanates2The preparation method of airsetting glue fiber | |
| CN113527752A (en) | Closed-cell aerogel microspheres, and preparation method and application thereof | |
| CN105442098B (en) | A kind of toughness SiO of PVP coatings2The preparation method of airsetting glue fiber | |
| CN110863349B (en) | Preparation method of centrifugal spinning nanofiber body material | |
| CN117051619A (en) | High-temperature-resistant high-strength composite felt and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |