CN115368086A - Foamed cement partition board and production method thereof - Google Patents
Foamed cement partition board and production method thereof Download PDFInfo
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- CN115368086A CN115368086A CN202211171246.6A CN202211171246A CN115368086A CN 115368086 A CN115368086 A CN 115368086A CN 202211171246 A CN202211171246 A CN 202211171246A CN 115368086 A CN115368086 A CN 115368086A
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- foamed cement
- partition board
- modified
- fiber
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- 239000004568 cement Substances 0.000 title claims abstract description 75
- 238000005192 partition Methods 0.000 title claims abstract description 50
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 17
- 239000000839 emulsion Substances 0.000 claims abstract description 68
- 229920000642 polymer Polymers 0.000 claims abstract description 34
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000008116 calcium stearate Substances 0.000 claims abstract description 22
- 235000013539 calcium stearate Nutrition 0.000 claims abstract description 22
- 229920002545 silicone oil Polymers 0.000 claims abstract description 22
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 22
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 22
- 239000003054 catalyst Substances 0.000 claims abstract description 12
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 10
- 239000010881 fly ash Substances 0.000 claims abstract description 10
- 229910021487 silica fume Inorganic materials 0.000 claims abstract description 9
- 239000006260 foam Substances 0.000 claims abstract description 8
- 230000000087 stabilizing effect Effects 0.000 claims abstract description 8
- 230000003014 reinforcing effect Effects 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 5
- 239000000835 fiber Substances 0.000 claims description 43
- 239000002002 slurry Substances 0.000 claims description 31
- 239000002131 composite material Substances 0.000 claims description 23
- 239000000843 powder Substances 0.000 claims description 23
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims description 18
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims description 18
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims description 18
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims description 18
- 229920005989 resin Polymers 0.000 claims description 18
- 239000011347 resin Substances 0.000 claims description 18
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 15
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 15
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 15
- 239000001110 calcium chloride Substances 0.000 claims description 15
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 15
- 238000002156 mixing Methods 0.000 claims description 15
- 229910052710 silicon Inorganic materials 0.000 claims description 15
- 239000010703 silicon Substances 0.000 claims description 15
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 15
- 235000011152 sodium sulphate Nutrition 0.000 claims description 15
- 238000005187 foaming Methods 0.000 claims description 14
- 229920000058 polyacrylate Polymers 0.000 claims description 14
- HIAAVKYLDRCDFQ-UHFFFAOYSA-L calcium;dodecanoate Chemical compound [Ca+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O HIAAVKYLDRCDFQ-UHFFFAOYSA-L 0.000 claims description 12
- 239000012783 reinforcing fiber Substances 0.000 claims description 10
- 239000007864 aqueous solution Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 5
- 239000004088 foaming agent Substances 0.000 claims description 5
- 239000007822 coupling agent Substances 0.000 claims description 4
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 4
- 238000002791 soaking Methods 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 claims description 2
- 229940082004 sodium laurate Drugs 0.000 claims description 2
- 238000000498 ball milling Methods 0.000 claims 1
- 238000004321 preservation Methods 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 description 34
- 230000000052 comparative effect Effects 0.000 description 29
- 239000012528 membrane Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 238000007711 solidification Methods 0.000 description 5
- 230000008023 solidification Effects 0.000 description 5
- 239000000203 mixture Substances 0.000 description 3
- 241001391944 Commicarpus scandens Species 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 230000009931 harmful effect Effects 0.000 description 2
- 238000009776 industrial production Methods 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical group O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 229920002050 silicone resin Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 208000034189 Sclerosis Diseases 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
- C04B18/18—Waste materials; Refuse organic
- C04B18/24—Vegetable refuse, e.g. rice husks, maize-ear refuse; Cellulosic materials, e.g. paper, cork
- C04B18/26—Wood, e.g. sawdust, wood shavings
- C04B18/265—Wood, e.g. sawdust, wood shavings from specific species, e.g. birch
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B22/00—Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
- C04B22/08—Acids or salts thereof
- C04B22/12—Acids or salts thereof containing halogen in the anion
- C04B22/124—Chlorides of ammonium or of the alkali or alkaline earth metals, e.g. calcium chloride
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B22/00—Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
- C04B22/08—Acids or salts thereof
- C04B22/14—Acids or salts thereof containing sulfur in the anion, e.g. sulfides
- C04B22/142—Sulfates
- C04B22/147—Alkali-metal sulfates; Ammonium sulfate
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/08—Fats; Fatty oils; Ester type waxes; Higher fatty acids, i.e. having at least seven carbon atoms in an unbroken chain bound to a carboxyl group; Oxidised oils or fats
- C04B24/085—Higher fatty acids
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/24—Macromolecular compounds
- C04B24/26—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B24/2641—Polyacrylates; Polymethacrylates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/24—Macromolecular compounds
- C04B24/38—Polysaccharides or derivatives thereof
- C04B24/383—Cellulose or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/40—Compounds containing silicon, titanium or zirconium or other organo-metallic compounds; Organo-clays; Organo-inorganic complexes
- C04B24/42—Organo-silicon compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/30—Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
- C04B2201/32—Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Civil Engineering (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The application relates to the field of fabricated buildings, and particularly discloses a foamed cement partition board and a production method thereof. The foamed cement partition board is prepared from the following raw materials in parts by weight: 110-130 parts of cement, 50-60 parts of silica fume, 30-50 parts of fly ash, 1.2-1.8 parts of a water reducing agent, 44-52 parts of water, 5.5-6.5 parts of hydrogen peroxide, 0.22-0.26 part of a catalyst, 4-7 parts of a foam stabilizing component and 6-12 parts of a reinforcing component, wherein the foam stabilizing component comprises vinyl silicone oil, modified polymer emulsion and calcium stearate, and the weight ratio of the vinyl silicone oil to the modified polymer emulsion to the calcium stearate is (2-4). The application of foamed cement partition plate can be used for assembly type building interior wall, and it has the advantage that heat preservation and compressive strength are high.
Description
Technical Field
The application relates to the field of assembly type buildings, in particular to a foamed cement partition board and a production method thereof.
Background
The prefabricated building mainly comprises a prefabricated concrete structure, a steel structure, a modern wood structure building and the like, and is a representative of a modern industrial production mode due to the adoption of standardized design, industrial production, assembly construction, informatization management and intelligent application.
Prefabricated inner partition boards can be adopted as the inner partition walls of the fabricated building, and the foaming cement partition boards are rapidly developed at present because the foaming cement has a plurality of excellent properties and advantages. The foaming method adopted by the foaming cement is generally chemical foaming, namely, a foaming agent is added into cement slurry to generate chemical reaction to release air bubbles, the air bubbles and the cement slurry are uniformly mixed, and the mixture is poured and molded to form a novel light heat-insulating material containing a large number of closed air holes through natural curing.
The common chemical foaming agent is hydrogen peroxide, so that hydrogen peroxide can be fully decomposed at the temperature of 20-30 ℃, a catalyst is usually added to promote hydrogen peroxide decomposition, and after the catalyst is added, the gas generation speed of hydrogen peroxide is too high, so that bubbles can escape from cement at an accelerated speed and cannot stably exist in cement slurry, and the compressive strength of the final foamed cement is reduced.
Disclosure of Invention
In order to improve the stability of bubble in the slurry, reduce and lead to the condition that foamed cement compressive strength descends because of the bubble is effusion with higher speed, the application provides a foamed cement partition plate and production method thereof.
A foamed cement partition board is prepared from the following raw materials in parts by weight: 110-130 parts of cement, 50-60 parts of silica fume, 30-50 parts of fly ash, 1.2-1.8 parts of a water reducing agent, 44-52 parts of water, 5.5-6.5 parts of hydrogen peroxide, 0.22-0.26 part of a catalyst, 4-7 parts of a foam stabilizing component and 6-12 parts of a reinforcing component, wherein the foam stabilizing component comprises vinyl silicone oil, modified polymer emulsion and calcium stearate, and the weight ratio of the vinyl silicone oil to the modified polymer emulsion to the modified calcium stearate is (2-4).
Through adopting above-mentioned technical scheme, at first improve vinyl silicone oil and modified polymer emulsion's compatibility with calcium stearate, thereby make vinyl silicone oil strengthen modified polymer emulsion, make holistic slurry viscosity increase, the difficult continuation increase of bubble is broken in the foaming process, calcium stearate exists the hydrophobicity that improves the bubble membrane on the bubble membrane simultaneously, further make the bubble membrane be difficult for receiving water erosion and break, effectively reduce the bubble loss, improve the stability of bubble in the slurry, and then reduce the harmful effects to foaming cement compressive strength.
Preferably, the modified calcium stearate is prepared by the following steps: the calcium stearate, the silica sol and the coupling agent are mixed, uniformly stirred and dried in an environment of 60 ℃, and then ball-milled to 2000 meshes to prepare the modified calcium stearate.
Preferably, the modified polymer emulsion comprises polyacrylate emulsion, hydroxypropyl methylcellulose and calcium laurate, and the weight ratio of the polyacrylate emulsion to the hydroxypropyl methylcellulose to the calcium laurate is 100.
By adopting the technical scheme, the hydroxypropyl methyl cellulose and the calcium laurate are added into the polyacrylate emulsion, so that the emulsifying degree and the viscosity degree of the polyacrylate emulsion are improved, the viscosity of the modified polymer emulsion to the cement paste is enhanced, the bubbles are not easy to grow and break, and the hydroxypropyl methyl cellulose and the calcium laurate further enable the vinyl silicone oil to be combined with the polyacrylate emulsion more easily to improve the strength of the bubble film and improve the stability of the bubbles in the paste.
Preferably, the modified polymer emulsion is prepared by dissolving hydroxypropyl methylcellulose with pure water to obtain a hydroxypropyl methylcellulose aqueous solution with the mass fraction of 2%, adding sodium laurate into the hydroxypropyl methylcellulose aqueous solution, uniformly stirring and mixing, and mixing with a polyacrylate emulsion to obtain the modified polymer emulsion.
By adopting the technical scheme, the calcium laurate is slightly soluble in water, so that the calcium laurate is more easily combined with polyacrylate emulsion by taking a hydroxypropyl methyl cellulose aqueous solution as an intermediate connecting component, the strength of the formed bubble film is effectively improved, and the bubbles are not easy to break.
Preferably, the reinforcing component comprises composite modified reinforcing fiber and a curing accelerator, and the weight ratio of the composite modified reinforcing fiber to the curing accelerator is 3-7.
Through adopting above-mentioned technical scheme to compound modified reinforcing fiber strengthens slurry strength, makes the bubble be difficult for expanding or overflowing in the slurry, and the solidification accelerator promotes the slurry solidification simultaneously and makes the bubble more difficult follow the slurry and overflow, effectively improves the stability of bubble in the slurry, reduces because of the influence of bubble overflow to foaming cement compressive strength.
Preferably, the composite modified reinforcing fiber comprises palm fiber, rubber powder and organic silicon resin emulsion, wherein the weight ratio of the palm fiber to the rubber powder to the organic silicon resin emulsion is 5.
Through adopting above-mentioned technical scheme, the organic silicon resin emulsion makes palm fiber and rubber powder combine, and palm fiber surface is modified by the rubber powder, and when palm fiber increased with the bonding strength of other components, the rubber powder on surface made palm fiber's tensile strength can further promote, and the cooperation solidification promoter makes the bubble more difficult to escape from the slurry simultaneously.
Preferably, the composite modified reinforced fiber is prepared by the steps of soaking palm fiber in organic silicon resin emulsion for 1 hour, taking out, spraying rubber powder on the palm fiber soaked by the organic silicon resin emulsion, and drying by hot air at 90 ℃ to prepare the composite modified reinforced fiber.
By adopting the technical scheme, the organic silicon resin emulsion is firstly soaked into the palm fiber, the organic silicon resin emulsion enables the rubber powder to be attached to the surface of the palm fiber in the subsequent process of being combined with the rubber powder, and the organic silicon resin emulsion is solidified after drying to enable the rubber powder to be fixed on the palm fiber, so that the composite modified reinforced fiber is formed.
Preferably, the curing accelerator comprises calcium chloride and sodium sulfate, and the weight ratio of the calcium chloride to the sodium sulfate is 1.
By adopting the technical scheme, the calcium chloride and the sodium sulfate can promote the cement to be solidified and hardened, so that the air bubbles are difficult to enlarge on one hand, and difficult to escape from the cement paste on the other hand, and the air bubbles are stably existed in the cement paste body.
In a second aspect, the present application provides a method for producing a foamed cement partition board, which adopts the following technical scheme: a production method of a foamed cement partition board comprises the following steps of mixing and stirring cement, silica fume, fly ash, a water reducing agent, a foam stabilizing component, a reinforcing component and water uniformly to prepare slurry, adding a foaming agent and a catalyst into the slurry, mixing uniformly, pouring the mixture into a mold for foaming, carrying out 5d initial curing and demolding, and curing in a natural environment for 10d to obtain the partition board.
By adopting the technical scheme, all the components are mixed, the foaming agent and the catalyst are added finally, the curing and demolding are carried out after foaming in the mold to achieve certain strength, and finally the curing is carried out in the natural environment, so that the operation is simple.
In summary, the present application has the following beneficial effects:
1. because this application adopts calcium stearate to improve vinyl silicone oil and modified polymer emulsion's the compatibility of the two, thereby make vinyl silicone oil strengthen the modified polymer emulsion, make holistic slurry viscosity increase, the bubble is difficult for continuing to increase and breaking among the foaming process, calcium stearate exists in the hydrophobicity that improves the bubble membrane on the bubble membrane simultaneously, further make the bubble membrane be difficult for receiving water erosion to break, effectively reduce the bubble loss, improve the stability of bubble in the slurry, and then reduce the harmful effects to foaming cement compressive strength.
2. In the organosilicon resin emulsion infiltration got into the palm fiber in this application, at the in-process that follow-up and rubber powder combine, the organosilicon resin emulsion makes the rubber powder attach to palm fiber surface, the solidification of stoving back organosilicon resin emulsion makes the rubber powder firm in on the palm fiber with other component's bonding strength increase in the time, the rubber powder on surface makes the fibrous tensile strength of palm can further promote, cooperate calcium chloride and sodium sulfate simultaneously can promote cement solidification sclerosis and make the bubble more difficult to escape from the slurry.
3. According to the preparation method, the raw materials are mixed and foamed, demoulding is carried out after certain strength is formed in the mould, and the product can be prepared by curing in a natural environment, and the preparation method is simple.
Detailed Description
The cement in the application is PO42.5; the fineness of the silica fume is 800 meshes; the fly ash is first-grade fly ash; the water reducing agent is a polycarboxylic acid water reducing agent; the concentration of hydrogen peroxide is 30 percent; the catalyst is manganese dioxide powder; the vinyl silicone oil is purchased from the market; polyacrylate emulsions were purchased from commercial sources; hydroxypropyl methylcellulose is purchased from the market; calcium laurate was purchased from commercial sources; calcium stearate is purchased from commercial sources; the silica sol is purchased from the market; the coupling agent is KH550 purchased from the market; the diameter of the palm fiber is 0.6mm, and the length of the palm fiber is 1-2 cm; the fineness of the rubber powder is 80 meshes; the organic silicon resin emulsion is purchased from the market; calcium chloride is purchased from the market; sodium sulfate was purchased from commercial sources.
The present application will be described in further detail with reference to examples.
Preparation example
Preparation example 1
The preparation example discloses a modified polymer emulsion, which is prepared by the following steps:
1kg of hydroxypropyl methyl cellulose is prepared into a hydroxypropyl methyl cellulose aqueous solution with the mass fraction of 2%, 10kg of calcium laurate is added, the mixture is stirred and mixed evenly, and finally 100kg of polyacrylate emulsion is added and mixed evenly to prepare the modified polymer emulsion.
Preparation example 2
The preparation example discloses a modified polymer emulsion, which is different from the preparation example 1 in that:
without addition of calcium laurate
Preparation example 3
The preparation example discloses a modified polymer emulsion, which is different from the preparation example 1 in that:
50kg of pure water was used in place of the 2% hydroxypropylmethylcellulose aqueous solution.
Preparation example 4
The preparation example discloses a composite modified reinforced fiber, which is prepared by the following steps:
soaking 5kg of palm fiber in 2kg of organic silicon resin emulsion for 1h, taking out, spraying 3kg of rubber powder on the palm fiber soaked by the organic silicon resin emulsion, and drying by hot air at 90 ℃ to obtain the composite modified reinforced fiber.
Preparation example 5
The preparation example discloses a composite modified reinforced fiber, which is different from the preparation example 4 in that:
no rubber powder was added.
Preparation example 6
The preparation example discloses a composite modified reinforced fiber, which is different from the preparation example 4 in that:
no silicone resin emulsion was added.
Preparation example 7
The preparation example discloses modified calcium stearate, which is prepared by the following steps: 30kg of calcium stearate, 15kg of silica sol and 1kg of coupling agent are mixed and stirred uniformly, dried at 60 ℃ and then ball-milled to 2000 meshes by using a ball mill, so that the modified calcium stearate is prepared.
Examples
Example 1
The embodiment discloses a foamed cement partition board, which is prepared by the following steps:
a cement slurry was prepared by mixing 110kg of cement, 50kg of silica fume, 30kg of fly ash, 1.2kg of a water reducing agent, 1kg of vinyl silicone oil, 1kg of calcium stearate prepared in production example 7, 1.5kg of the modified polymer emulsion prepared in production example 1, 3kg of the composite modified reinforcing fiber prepared in production example 4, 1.5kg of calcium chloride, 1.5kg of sodium sulfate and 44kg of water.
And adding 5.5kg of hydrogen peroxide and 0.22kg of catalyst into the cement paste, stirring and mixing, pouring into a mold, performing 5d initial curing and demolding, and curing in a natural environment for 10d to obtain the partition board.
Example 2
The embodiment discloses a foamed cement partition board, which is prepared by the following steps:
a cement slurry was prepared by mixing 120kg of cement, 55kg of silica fume, 40kg of fly ash, 1.5kg of a water reducing agent, 1.5kg of vinyl silicone oil, 2kg of calcium stearate prepared in production example 7, 2kg of the modified polymer emulsion prepared in production example 1, 5kg of the composite modified reinforcing fiber prepared in production example 4, 2kg of calcium chloride, 2kg of sodium sulfate and 48kg of water.
Adding 6kg of hydrogen peroxide and 0.24kg of catalyst into the cement paste, stirring and mixing, pouring into a mold, carrying out 5d of initial curing and demolding, and curing in a natural environment for 10d to obtain the partition board.
Example 3
The embodiment discloses a foamed cement partition board, which is prepared by the following steps:
a cement slurry was prepared by mixing 130kg of cement, 60kg of silica fume, 50kg of fly ash, 1.8kg of a water reducing agent, 2kg of vinyl silicone oil, 3kg of calcium stearate obtained in production example 7, 2.5kg of the modified polymer emulsion obtained in production example 1, 7kg of the composite modified reinforcing fiber obtained in production example 4, 2.5kg of calcium chloride, 2.5kg of sodium sulfate, and 52kg of water.
Adding 6.5kg of hydrogen peroxide and 0.26kg of catalyst into the cement paste, stirring and mixing, pouring into a mold, carrying out 5d of initial curing and demolding, and curing in a natural environment for 10d to obtain the partition board.
Example 4
The embodiment discloses a foamed cement partition board, which is different from embodiment 2 in that:
modified polymer emulsion prepared as in preparation example 2.
Example 5
The embodiment discloses a foamed cement partition board, which is different from embodiment 2 in that:
modified polymer emulsion prepared as in preparation example 3.
Example 6
The embodiment discloses a foamed cement partition board, which is different from embodiment 2 in that:
the composite modified reinforced fiber is prepared by the preparation example 5.
Example 7
The embodiment discloses a foamed cement partition board, which is different from embodiment 2 in that: the composite modified reinforcing fiber was prepared in preparation example 6.
Example 8
The embodiment discloses a foamed cement partition board, which is different from embodiment 2 in that: the amount of calcium chloride added was 4kg and the amount of sodium sulfate added was 0.
Example 9
The embodiment discloses a foamed cement partition board, which is different from embodiment 2 in that: the amount of calcium chloride added was 0 and the amount of sodium sulfate added was 4kg.
Example 10
The embodiment discloses a foamed cement partition board, which is different from embodiment 2 in that: palm fiber was used in place of the composite modified reinforcing fiber prepared in preparation example 4.
Comparative example
Comparative example 1
The present comparative example discloses a foamed cement partition board, which is different from example 2 in that: no vinyl silicone oil was added.
Comparative example 2
The comparative example discloses a foamed cement partition board, which is different from example 2 in that: no calcium stearate was added.
Comparative example 3
The present comparative example discloses a foamed cement partition board, which is different from example 2 in that: the modified polymer emulsion prepared in preparation example 1 was not added.
Comparative example 4
The present comparative example discloses a foamed cement partition board, which is different from example 2 in that: vinyl silicone oil and calcium stearate were not added.
Comparative example 5
The present comparative example discloses a foamed cement partition board, which is different from example 2 in that: vinyl silicone oil was not added and the modified polymer emulsion obtained in preparation example 1 was added.
Comparative example 6
The comparative example discloses a foamed cement partition board, which is different from example 2 in that: calcium stearate was not added and the modified polymer emulsion obtained in preparation example 1 was used.
Comparative example 7
The present comparative example discloses a foamed cement partition board, which is different from example 2 in that:
vinyl silicone oil, calcium stearate and the modified polymer emulsion obtained in preparation example 1 were not added.
Comparative example 8
The present comparative example discloses a foamed cement partition board, which is different from example 2 in that:
the composite modified fiber obtained in preparation example 4, calcium chloride and sodium sulfate were not added.
Comparative example 9
The comparative example discloses a foamed cement partition board, which is different from example 2 in that:
vinyl silicone oil, calcium stearate, the modified polymer emulsion obtained in preparation example 1, the composite modified fiber obtained in preparation example 4, calcium chloride, and sodium sulfate were not added.
Comparative example 10
The present comparative example discloses a foamed cement partition board, which is different from example 2 in that:
the modified polymer emulsion obtained in preparation example 1 was replaced with a polyacrylate emulsion.
EXAMPLES 1-9 AND COMPARATIVE EXAMPLES 1-9 raw material tables (kg)
Performance test the 28d compressive strength of the examples and the comparative examples was tested according to JG/T169-2016 technical requirements for light weight slat for building partition in general 7.4.3 compressive strength.
Relevant data are measured and the thermal conductivity coefficient is calculated for the examples and the comparative examples according to GB/T13475-2008 < determination calibration and protection hot box method for adiabatic steady state heat transfer properties >.
TABLE 2 tables of Performance data for examples and comparative examples
It can be seen by combining example 2 and comparative examples 1 to 7 and table 2 that the compatibility of vinyl silicone oil and modified polymer emulsion is improved by calcium stearate, so that the modified polymer emulsion is reinforced by the vinyl silicone oil, the viscosity of the whole slurry is increased, bubbles are not easy to increase and break in the foaming process, meanwhile, the calcium stearate exists on the bubble film to improve the hydrophobicity of the bubble film, further, the bubble film is not easy to be corroded and broken by water, the bubble loss is effectively reduced, the stability of the bubbles in the slurry is improved, and the adverse effects on the compressive strength and the heat conductivity of the partition board are reduced.
By combining example 2, example 4, example 5 and comparative example 10 and table 2, it can be seen that the calcium laurate is more easily combined with the polyacrylate emulsion by using the hydroxypropyl methyl cellulose aqueous solution as the intermediate connecting component, so that the strength of the formed bubble film of the bubble is effectively improved, the bubble is not easy to break, the stability of the bubble in the cement paste is improved, and the adverse effects of the bubble escape on the compressive strength and the thermal conductivity of the partition board are reduced.
Combining example 2, example 6, example 7 and example 10 and combining table 2, it can be seen that the silicone resin emulsion enables the palm fiber and the rubber powder to be combined, the surface of the palm fiber is modified by the rubber powder, the combination strength of the palm fiber and other components is increased, meanwhile, the rubber powder on the surface enables the tensile strength of the palm fiber to be further improved, and meanwhile, the curing accelerator is matched to make air bubbles more difficult to escape from the slurry.
It can be seen from the combination of example 2, comparative example 8 and comparative example 9 and from table 2 that calcium chloride and sodium sulfate promote the setting and hardening of cement, so that the bubbles are difficult to grow and escape from the cement slurry, and the bubbles are stably present in the cement slurry.
It can be seen from the combination of embodiment 2, embodiment 8 and embodiment 9 and table 2 that, on the one hand, the bubbles are strengthened to make the bubble membrane be difficult for breakage, improve bubble stability, on the other hand, improve the toughness of slurry, make the bubbles be difficult for grow or from the internal effusion of slurry, make the interior fine and stable bubble of formation of slurry, be favorable to compressive strength to promote and coefficient of thermal conductivity to descend.
The present embodiment is only for explaining the present application, and it is not limited to the present application, and those skilled in the art can make modifications of the present embodiment without inventive contribution as needed after reading the present specification, but all of them are protected by patent law within the scope of the claims of the present application.
Claims (9)
1. The foamed cement partition board is characterized by being prepared from the following raw materials in parts by weight:
110-130 parts of cement, 50-60 parts of silica fume, 30-50 parts of fly ash, 1.2-1.8 parts of a water reducing agent, 44-52 parts of water, 5.5-6.5 parts of hydrogen peroxide, 0.22-0.26 part of a catalyst, 4-7 parts of a foam stabilizing component and 6-12 parts of a reinforcing component, wherein the foam stabilizing component comprises vinyl silicone oil, a modified polymer emulsion and calcium stearate, and the weight ratio of the vinyl silicone oil to the modified polymer emulsion to the modified calcium stearate is (2-4).
2. The foamed cement partition board according to claim 1, wherein: the modified calcium stearate is prepared by the following steps: mixing calcium stearate, silica sol and a coupling agent, uniformly stirring, drying at 60 ℃, and ball-milling to 2000 meshes to obtain the modified calcium stearate.
3. The foamed cement partition board according to claim 1, wherein: the modified polymer emulsion comprises polyacrylate emulsion, hydroxypropyl methyl cellulose and calcium laurate, wherein the weight ratio of the polyacrylate emulsion to the hydroxypropyl methyl cellulose to the calcium laurate is 100.
4. The foamed cement partition board of claim 3, wherein: the modified polymer emulsion is prepared by dissolving hydroxypropyl methyl cellulose by using pure water to prepare a hydroxypropyl methyl cellulose aqueous solution with the mass fraction of 2%, adding sodium laurate into the hydroxypropyl methyl cellulose aqueous solution, stirring and mixing uniformly, and mixing with polyacrylate emulsion to prepare the modified polymer emulsion.
5. The foamed cement partition panel of claim 3, wherein: the reinforcing component comprises composite modified reinforcing fiber and a curing accelerator, wherein the weight ratio of the composite modified fiber to the curing accelerator is 3-7.
6. The foamed cement partition panel of claim 5, wherein: the composite modified reinforced fiber comprises palm fiber, rubber powder and organic silicon resin emulsion, wherein the weight ratio of the palm fiber to the rubber powder to the organic silicon resin emulsion is 5.
7. The foamed cement partition panel of claim 6, wherein: the composite modified reinforced fiber is prepared by the following steps of soaking palm fiber in organic silicon resin emulsion for 1h, taking out the palm fiber, spraying rubber powder on the palm fiber soaked in the organic silicon resin emulsion, and drying the palm fiber with hot air at 90 ℃ to obtain the composite modified reinforced fiber.
8. The foamed cement partition board of claim 3, wherein: the curing accelerator comprises calcium chloride and sodium sulfate, and the weight ratio of the calcium chloride to the sodium sulfate is 1.
9. The production process of the foamed cement partition board of any one of claims 1 to 8, characterized by comprising the steps of mixing and stirring cement, silica fume, fly ash, a water reducing agent, a foam stabilizing component, a reinforcing component and water uniformly to prepare a slurry, adding a foaming agent and a catalyst into the slurry, uniformly mixing and pouring the slurry into a mold for foaming, performing 5 days of initial curing and demolding, and curing in a natural environment for 10 days to obtain the partition board.
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| CN117865618A (en) * | 2024-01-23 | 2024-04-12 | 海南夏谊科技有限责任公司 | Light foamed cement partition board for building and production method thereof |
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