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CN115340890A - Heavy oil substituted diesel oil formula and using device thereof - Google Patents

Heavy oil substituted diesel oil formula and using device thereof Download PDF

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Publication number
CN115340890A
CN115340890A CN202210438800.6A CN202210438800A CN115340890A CN 115340890 A CN115340890 A CN 115340890A CN 202210438800 A CN202210438800 A CN 202210438800A CN 115340890 A CN115340890 A CN 115340890A
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China
Prior art keywords
diesel
oil
heavy oil
heavy
formula
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CN202210438800.6A
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Chinese (zh)
Inventor
陈进益
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Yangguang Lvneng Industrial Co ltd
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Yangguang Lvneng Industrial Co ltd
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/04Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/23Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites
    • C10L1/231Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites nitro compounds; nitrates; nitrites
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02DCONTROLLING COMBUSTION ENGINES
    • F02D19/00Controlling engines characterised by their use of non-liquid fuels, pluralities of fuels, or non-fuel substances added to the combustible mixtures
    • F02D19/06Controlling engines characterised by their use of non-liquid fuels, pluralities of fuels, or non-fuel substances added to the combustible mixtures peculiar to engines working with pluralities of fuels, e.g. alternatively with light and heavy fuel oil, other than engines indifferent to the fuel consumed
    • F02D19/0639Controlling engines characterised by their use of non-liquid fuels, pluralities of fuels, or non-fuel substances added to the combustible mixtures peculiar to engines working with pluralities of fuels, e.g. alternatively with light and heavy fuel oil, other than engines indifferent to the fuel consumed characterised by the type of fuels
    • F02D19/0649Liquid fuels having different boiling temperatures, volatilities, densities, viscosities, cetane or octane numbers
    • F02D19/0657Heavy or light fuel oils; Fuels characterised by their impurities such as sulfur content or differences in grade, e.g. for ships
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02DCONTROLLING COMBUSTION ENGINES
    • F02D19/00Controlling engines characterised by their use of non-liquid fuels, pluralities of fuels, or non-fuel substances added to the combustible mixtures
    • F02D19/06Controlling engines characterised by their use of non-liquid fuels, pluralities of fuels, or non-fuel substances added to the combustible mixtures peculiar to engines working with pluralities of fuels, e.g. alternatively with light and heavy fuel oil, other than engines indifferent to the fuel consumed
    • F02D19/08Controlling engines characterised by their use of non-liquid fuels, pluralities of fuels, or non-fuel substances added to the combustible mixtures peculiar to engines working with pluralities of fuels, e.g. alternatively with light and heavy fuel oil, other than engines indifferent to the fuel consumed simultaneously using pluralities of fuels
    • F02D19/081Adjusting the fuel composition or mixing ratio; Transitioning from one fuel to the other

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Lubrication Of Internal Combustion Engines (AREA)

Abstract

The invention discloses a formula of heavy oil replacing diesel oil, the operation mode of a general diesel engine is that the mixed gas of oil and air is compressed by 16-23 times to reach the ignition point of the diesel oil to detonate the diesel oil and generate power, however, the ignition point temperature of the diesel oil is not enough to detonate the heavy oil; therefore, by adding trace explosive in the heavy oil, the explosive can be detonated at the ignition temperature of the diesel oil, and then the heavy oil is detonated to generate power, so that the heavy oil can replace the diesel oil for use, and the oil cost is reduced; in addition, the invention also discloses a device for using the heavy oil instead of the diesel formula, so that the heavy oil instead of the diesel formula can be used in a diesel engine.

Description

Heavy oil substituted diesel oil formula and using device thereof
Technical Field
The application relates to a heavy oil-substituted diesel oil formula and a using device thereof, in particular to a heavy oil-substituted diesel oil formula capable of reducing oil cost and a using device thereof.
Background
In recent years, hybrid vehicles and electric vehicles having high fuel efficiency (fuel efficiency) have been gradually replacing conventional vehicles using gasoline engines, but vehicles using diesel engines have been increasing.
Heavy oil, also called fuel oil, is the residual heavy oil after extracting gasoline and diesel oil from crude oil, and is characterized by large molecular weight and high viscosity; heavy oil generally has a specific gravity of 0.82 to 0.95 and a calorific value of about 10,000 to 11,000kcal/kg, and mainly contains hydrocarbons, and further contains a part (about 0.1 to 4%) of sulfur and a trace amount of inorganic compounds.
The heavy oil can be used as the starting ignition fuel of a modern large coal-fired boiler, but the current research direction on the heavy oil is mainly the cracking of long-chain hydrocarbon, which aims to obtain light diesel oil or kerosene for use by cracking the heavy oil, but the heavy oil needs to be cracked at an extra cost and purified so as to be used on a common diesel engine, and only can be used as low-price fuel; moreover, the ignition point of the heavy oil is higher than that of diesel oil, so that the heavy oil is difficult to ignite when being used on a common diesel engine.
Therefore, it is necessary to provide a further solution to the above problems.
Disclosure of Invention
Aiming at the defects of the prior art, the problems to be solved by the application are mainly as follows:
(1) The common heavy oil has higher ignition point and cannot replace diesel oil as the fuel of a diesel engine.
(2) A typical diesel engine has only one tank in which diesel oil is placed, and has no other separately provided tank in which heavy oil can be placed.
In order to solve the above two main problems, the present application aims to provide a heavy oil-substituted diesel formulation and a device for using the same.
In order to achieve the above purpose, the embodiment of the present application adopts the following technical solutions: a heavy oil-in-place diesel formulation is provided, comprising:
adding trace explosive selected from Nitroglycerin (C) into heavy oil 3 H 5 N 3 O 9 ) Trinitrotoluene (C) 7 H 5 N 3 O 6 ) Hexanitrobenzene (C) 6 N 6 O 12 ) Trinitrobenzene (trinitrobenzzene, C) 6 H 3 N 3 O 6 ) Or trinitrophenol (C) 6 H 3 N 3 O 7 )。
The heavy oil replaces a diesel oil formula and forms oil drops after atomization, the oil drops are sprayed into a diesel engine, the atomized heavy oil replaces the mixed gas formed by mixing the oil drops of the diesel oil formula and air, the mixed gas is compressed, ignition is carried out in the compressed mixed gas, the temperature is raised to be more than 400 ℃, explosives are detonated, the heavy oil is detonated through chain reaction after the explosives are detonated, and then the heavy oil can be combusted and further used in the diesel engine.
Igniting the compressed mixed gas to detonate the explosive, taking trinitrotoluene as an example, the explosion chemical formula of the trinitrotoluene is as follows: 2C 7 H 5 N 3 O 6 →12CO+5H 2 +3N 2 The first stage of the trinitrotoluene explosion is to decompose into hundreds of times of gas, and the gas explodes heavy oil drops to form tens of thousands of smaller heavy oil drops, so that the contact area of the heavy oil drops and air is larger and the heavy oil drops are easier to burn; moreover, gases generated after explosion, such as carbon monoxide, hydrogen and the like, are inflammable gases, so that after the explosive is ignited and detonated, mixed gas formed by mixing heavy oil droplets and air can be easily detonated, and power is generated.
Wherein, the addition amount of the explosive is 0.001-1 wt% of the total weight of the heavy oil-substituted diesel formula, and the added explosive is very stable at normal temperature due to extremely low concentration, so that the explosive cannot explode even under shaking, shaking or impacting, and the safety in use is not concerned.
In addition, the detonation temperature of the explosive is related to the use concentration of the explosive, so that the proper explosive type and the use concentration thereof need to be selected according to the use occasion; furthermore, the explosive can be directly dissolved in heavy oil for use, or dissolved in an organic solvent to form a heavy oil additive, and then the oil additive is added into the heavy oil for use.
Wherein, the organic solvent can be toluene or ethanol.
On the other hand, in order to utilize the heavy oil to start the diesel engine, the technical scheme that this application embodiment adopted is: the utility model provides a heavy oil replaces use device of diesel oil prescription, includes:
a diesel engine;
the diesel tank is connected with the diesel engine, and an electromagnetic valve is arranged between the diesel tank and the diesel engine; and
a heavy oil-substituted diesel oil formulation tank connected with the diesel engine, and another electromagnetic valve arranged between the heavy oil-substituted diesel oil formulation tank and the diesel engine, wherein
The two electromagnetic valves can control the fuel oil input to the diesel engine to be diesel oil or the heavy oil to replace the diesel oil formula.
The operation principle of the using device for the heavy oil replacing diesel oil formula is that after the diesel engine is firstly started and preheated by supplying diesel oil from the diesel oil tank, the electromagnetic valve arranged between the diesel oil tank and the diesel engine is closed, the other electromagnetic valve arranged between the heavy oil replacing diesel oil formula oil tank and the diesel engine is opened, and the heavy oil replacing diesel oil formula oil tank supplies the heavy oil replacing diesel oil formula to the diesel engine for use.
Therefore, the using device of the heavy oil replacing diesel oil formula is that the diesel oil is firstly started by the diesel oil and then is switched to the heavy oil replacing diesel oil formula to provide the kinetic energy for the continuous operation of the diesel oil engine; therefore, the heavy oil can be used for a diesel engine, the utilization value of the heavy oil is improved, light diesel oil or kerosene is obtained for use without cracking the heavy oil, the use cost of the heavy oil is reduced, the environmental pollution caused by cracking the heavy oil can be reduced, and the effect of environmental protection is achieved.
The object of the present invention is not limited to the above-described technical problem, and those skilled in the art can clearly understand that the object is not mentioned or other objects through the following description.
Drawings
Fig. 1 is a schematic configuration diagram of a centralized supply system of a solid metal organic source according to the present invention.
Description of reference numerals:
1: a device for using heavy oil instead of diesel oil;
2: a diesel engine;
3: a diesel tank;
4: a heavy oil replacing diesel oil formula oil tank;
5: a diesel tank solenoid valve;
6: the heavy oil replaces the electromagnetic valve of the diesel oil formula oil tank.
Detailed Description
Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings. The advantages and features of the invention and the methods of accomplishing the same may be understood by reference to the drawings and the detailed description of the embodiments that follow. However, the present invention is not limited to the embodiments described below, and can be realized in various forms different from each other, and the embodiments are only for making the present invention fully disclosed so that those having ordinary knowledge in the art to which the present invention pertains can fully understand the scope of the present invention, and the scope of the present invention is defined by the claims of the present invention. Like reference numerals refer to like elements throughout the specification.
Unless otherwise defined, all terms (including technical and scientific terms) used in the present specification may be used with the meaning commonly understood by one having ordinary skill in the art to which the present invention belongs. Furthermore, terms commonly used in dictionaries have a definition and are not interpreted abnormally or excessively without explicit special definition.
Example 1
Detonation temperature test of different types of explosives and addition amounts thereof
Nitroglycerin (C) in an amount of 0.001 to 1wt% based on the total weight of the heavy oil is added to the heavy oil 3 H 5 N 3 O 9 ) Trinitrotoluene (C) 7 H 5 N 3 O 6 ) Hexanitrobenzene (C) 6 N 6 O 12 ) Trinitrobenzene (C) 6 H 3 N 3 O 6 ) Or trinitrophenol (C) 6 H 3 N 3 O 7 ) And (3) waiting for explosives to test the detonation temperature range of the heavy oil instead of diesel oil formulation.
The explosive can be directly added into heavy oil, or can be dissolved into an organic solvent to form a heavy oil additive, and then the heavy oil additive is added into the heavy oil to achieve the required addition amount, for example, 1 kg of toluene or ethanol can be dissolved into 1wt% of trinitrotoluene to form the heavy oil additive, and then the heavy oil additive is mixed with 99 kg of heavy oil, so that the heavy oil containing 0.01wt% of explosive can be formed to replace a diesel oil formula, or the explosive with 0.01wt% of the total weight of the heavy oil can be directly added into the heavy oil.
The results of adding different types of explosives and different addition amounts of detonation temperatures to heavy oil are shown in table 1 below:
TABLE 1
Figure BDA0003614157820000051
As can be seen from table 1, when the explosive is added in an amount of 1wt%, the detonation temperature is substantially the same as when the explosive is added in an amount of 0.1wt%, and the explosive is preferably added in an amount of 0.001 to 0.1wt% in consideration of cost and safety in use.
Example 2
Heavy oil replacing diesel oil formula using device
As shown in fig. 1, the present application provides an apparatus 1 for using heavy oil instead of diesel oil, comprising:
a diesel engine 2;
a diesel tank 3, the diesel tank 3 being connected to the diesel engine 2, and an electromagnetic valve (diesel tank electromagnetic valve 5) being provided between the diesel tank 3 and the diesel engine 2; and
a heavy oil replacing diesel oil formula oil tank 4, the heavy oil replacing diesel oil formula oil tank 4 is connected with the diesel engine 2, and another electromagnetic valve (a heavy oil replacing diesel oil formula oil tank electromagnetic valve 6) is arranged between the heavy oil replacing diesel oil formula oil tank 4 and the diesel engine 2, wherein
The diesel tank electromagnetic valve 5 and the heavy oil replacing diesel formula oil tank electromagnetic valve 6 can control the fuel oil input to the diesel engine 2 to be diesel or the heavy oil replacing diesel formula.
The operation principle of the using device 1 for heavy oil to replace diesel oil formula is that after the diesel engine 2 is firstly started and preheated by diesel oil supplied by the diesel oil tank 3, an electromagnetic valve (a diesel oil tank electromagnetic valve 5) arranged between the diesel oil tank 3 and the diesel engine 2 is closed, another electromagnetic valve (a heavy oil to replace diesel oil formula tank electromagnetic valve 6) arranged between the heavy oil to replace diesel oil formula tank 4 and the diesel engine 2 is opened, and the heavy oil to replace diesel oil formula supplied by the heavy oil to replace diesel oil formula tank 4 is supplied to the diesel engine 2 for use.
When the heavy oil-substituted diesel formulations containing different types of explosives and different amounts of heavy oil added to the heavy oil-substituted diesel formulation using apparatus 1 in table 1 of example 1 were applied, the diesel engine 2 was operated smoothly without safety concerns such as explosion or damage to the diesel engine 2.
In conclusion, the heavy oil is used for replacing diesel oil, and the using device thereof can ensure that the heavy oil replaces the diesel oil to ensure that the engine runs smoothly without cracking the heavy oil into the diesel oil, thereby improving the utilization value and wider applicability of the heavy oil and reducing the oil cost; in addition, the environmental pollution caused by cracking heavy oil can be reduced, and the effect of environmental protection is achieved.
It will be understood by those of ordinary skill in the art that various changes in form and details may be made therein without departing from the spirit and scope of the inventive concept as defined by the following claims. The exemplary embodiments should be considered in descriptive sense only and not for purposes of limitation. Therefore, the scope of the inventive concept is defined not by the detailed description of the exemplary embodiments but by the appended claims, and all differences within the scope will be construed as being included in the present inventive concept.

Claims (6)

1. A heavy oil can replace diesel oil, make the heavy oil replace the diesel oil, use in the diesel engine, characterized by that:
the heavy oil diesel oil substitute formula is characterized in that trace explosive is added into heavy oil, the explosive is selected from nitroglycerin, trinitrotoluene, hexanitrobenzene, trinitrobenzene or trinitrophenol, and the addition amount of the explosive is 0.001-1 wt% of the total weight of the heavy oil diesel oil substitute formula.
2. The heavy oil diesel-substitute formulation of claim 1, wherein said explosive is used as it is dissolved in heavy oil.
3. The heavy oil-substituted diesel formulation of claim 1, wherein the explosive is dissolved in an organic solvent to form a heavy oil additive, and the heavy oil additive is added to the heavy oil.
4. The heavy oil diesel-substitute formulation according to claim 3, wherein said organic solvent is toluene or ethanol.
5. Use unit of a heavy oil-in-place diesel formulation according to claims 1 to 4, characterized in that it comprises:
a diesel engine;
the diesel tank is connected with the diesel engine, and an electromagnetic valve is arranged between the diesel tank and the diesel engine; and
a heavy oil-substituted diesel oil formulation tank connected with the diesel engine, and another electromagnetic valve arranged between the heavy oil-substituted diesel oil formulation tank and the diesel engine, wherein
The two electromagnetic valves can control the fuel oil input to the diesel engine to be diesel oil or the heavy oil to replace the diesel oil formula.
6. The apparatus for using heavy oil in place of diesel fuel formulation as claimed in claim 5, wherein:
the diesel engine is started and preheated by supplying diesel oil from the diesel oil tank, the electromagnetic valve arranged between the diesel oil tank and the diesel engine is closed, the other electromagnetic valve arranged between the heavy oil replacing diesel oil formula oil tank and the diesel engine is opened, and the heavy oil replacing diesel oil formula oil tank supplies the heavy oil replacing diesel oil formula to the diesel engine for use.
CN202210438800.6A 2021-05-12 2022-04-25 Heavy oil substituted diesel oil formula and using device thereof Pending CN115340890A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
TW110117392 2021-05-12
TW110117392A TW202244257A (en) 2021-05-12 2021-05-12 The formula and device for heavy oil to replace diesel oil

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CN115340890A true CN115340890A (en) 2022-11-15

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101007970A (en) * 2006-01-26 2007-08-01 金柏林 Heavy oil modified fuel oil for substituting for heavy diesel oil and its production method
TW200823361A (en) * 2006-11-24 2008-06-01 Su-Qing Li Secon fuel-supplying system for an engine
CN102181310A (en) * 2011-04-11 2011-09-14 莫少剑 Novel gasoline, kerosene, diesel oil or heavy oil and preparation method thereof
TW202004006A (en) * 2018-05-22 2020-01-16 國立雲林科技大學 Method and device for pre-assisting combustion diesel engine using hydrogen
TW202126797A (en) * 2020-01-09 2021-07-16 陳進益 Fuel oil containing trace amount of explosives

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101007970A (en) * 2006-01-26 2007-08-01 金柏林 Heavy oil modified fuel oil for substituting for heavy diesel oil and its production method
TW200823361A (en) * 2006-11-24 2008-06-01 Su-Qing Li Secon fuel-supplying system for an engine
CN102181310A (en) * 2011-04-11 2011-09-14 莫少剑 Novel gasoline, kerosene, diesel oil or heavy oil and preparation method thereof
TW202004006A (en) * 2018-05-22 2020-01-16 國立雲林科技大學 Method and device for pre-assisting combustion diesel engine using hydrogen
TW202126797A (en) * 2020-01-09 2021-07-16 陳進益 Fuel oil containing trace amount of explosives

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