CN115323567A - Production process of medical antibacterial fabric - Google Patents
Production process of medical antibacterial fabric Download PDFInfo
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- CN115323567A CN115323567A CN202211112861.XA CN202211112861A CN115323567A CN 115323567 A CN115323567 A CN 115323567A CN 202211112861 A CN202211112861 A CN 202211112861A CN 115323567 A CN115323567 A CN 115323567A
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- 239000004744 fabric Substances 0.000 title claims abstract description 78
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 38
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 20
- 239000000835 fiber Substances 0.000 claims abstract description 94
- 229920000728 polyester Polymers 0.000 claims abstract description 44
- 229920000297 Rayon Polymers 0.000 claims abstract description 36
- 239000003242 anti bacterial agent Substances 0.000 claims abstract description 32
- 238000002156 mixing Methods 0.000 claims abstract description 19
- 238000009987 spinning Methods 0.000 claims abstract description 19
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 14
- 238000004043 dyeing Methods 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims description 20
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 15
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 15
- 238000004806 packaging method and process Methods 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 239000002994 raw material Substances 0.000 claims description 11
- 239000004952 Polyamide Substances 0.000 claims description 10
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 10
- 229920002647 polyamide Polymers 0.000 claims description 10
- -1 polytetrafluoroethylene Polymers 0.000 claims description 8
- 229920001661 Chitosan Polymers 0.000 claims description 5
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 5
- 229920002522 Wood fibre Polymers 0.000 claims description 5
- 239000003513 alkali Substances 0.000 claims description 5
- 229920002678 cellulose Polymers 0.000 claims description 5
- 239000001913 cellulose Substances 0.000 claims description 5
- 238000001311 chemical methods and process Methods 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 230000018044 dehydration Effects 0.000 claims description 5
- 238000006297 dehydration reaction Methods 0.000 claims description 5
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 5
- 229920006149 polyester-amide block copolymer Polymers 0.000 claims description 5
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 5
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 5
- 229920002994 synthetic fiber Polymers 0.000 claims description 5
- 239000012209 synthetic fiber Substances 0.000 claims description 5
- 238000002166 wet spinning Methods 0.000 claims description 5
- 239000002025 wood fiber Substances 0.000 claims description 5
- 239000012991 xanthate Substances 0.000 claims description 5
- 230000002378 acidificating effect Effects 0.000 claims 1
- 244000005700 microbiome Species 0.000 abstract description 15
- 210000002390 cell membrane structure Anatomy 0.000 abstract description 4
- 230000002209 hydrophobic effect Effects 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 4
- 238000007348 radical reaction Methods 0.000 abstract description 4
- 150000003254 radicals Chemical class 0.000 abstract description 4
- 238000012546 transfer Methods 0.000 abstract description 4
- 238000000034 method Methods 0.000 description 5
- 210000004027 cell Anatomy 0.000 description 4
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- 239000000975 dye Substances 0.000 description 4
- 230000000813 microbial effect Effects 0.000 description 4
- 230000009471 action Effects 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 229910021645 metal ion Inorganic materials 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 230000003204 osmotic effect Effects 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 235000011330 Armoracia rusticana Nutrition 0.000 description 1
- 240000003291 Armoracia rusticana Species 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 244000056139 Brassica cretica Species 0.000 description 1
- 235000003351 Brassica cretica Nutrition 0.000 description 1
- 235000003343 Brassica rupestris Nutrition 0.000 description 1
- 229920002101 Chitin Polymers 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- QKSKPIVNLNLAAV-UHFFFAOYSA-N bis(2-chloroethyl) sulfide Chemical compound ClCCSCCCl QKSKPIVNLNLAAV-UHFFFAOYSA-N 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
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- 238000012986 modification Methods 0.000 description 1
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- 229920001778 nylon Polymers 0.000 description 1
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- 238000006467 substitution reaction Methods 0.000 description 1
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Classifications
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D1/00—Woven fabrics designed to make specified articles
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
- D03D15/208—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based
- D03D15/225—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based artificial, e.g. viscose
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
- D03D15/283—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/30—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the fibres or filaments
- D03D15/33—Ultrafine fibres, e.g. microfibres or nanofibres
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/40—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
- D03D15/47—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads multicomponent, e.g. blended yarns or threads
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/22—Polymers or copolymers of halogenated mono-olefins
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/26—Polymers or copolymers of unsaturated carboxylic acids or derivatives thereof
- D06M2101/28—Acrylonitrile; Methacrylonitrile
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
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- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/20—Cellulose-derived artificial fibres
- D10B2201/22—Cellulose-derived artificial fibres made from cellulose solutions
- D10B2201/24—Viscose
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/04—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of halogenated hydrocarbons
- D10B2321/042—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of halogenated hydrocarbons polymers of fluorinated hydrocarbons, e.g. polytetrafluoroethene [PTFE]
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/10—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
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- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/13—Physical properties anti-allergenic or anti-bacterial
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- D10B2509/00—Medical; Hygiene
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Abstract
The invention discloses a production process of medical antibacterial fabric, which relates to the technical field of antibacterial fabric, is a mixed fabric formed by mixing and spinning the following fibers in parts by weight, and comprises 10-20 parts of polyester fibers, 10-20 parts of viscose fibers and 10-20 parts of superfine fibers, wherein the mixed fabric is formed by carrying out antibacterial agent padding treatment on the mixed fabric, and specifically comprises the following steps: s1, one-bath dyeing: putting 10-20 parts of polyester fiber, 10-20 parts of viscose fiber and 10-20 parts of superfine fiber into the same container, adding 1-3% of an antibacterial agent and adding a dye according to requirements, S2, padding: mixing and spinning 10-20 parts of polyester fiber, 10-20 parts of viscose fiber and 10-20 parts of superfine fiber by a spinning machine, adding an antibacterial agent, padding, and keeping the mangle ratio at 70-90%; according to the invention, the graphene is of a hydrophobic plane structure and a hydrophilic edge structure, and microorganisms stimulate free radical reaction through charge transfer after contacting the graphene material in the fabric, so that the cell membrane structure of the microorganisms is destroyed and the microorganisms die.
Description
Technical Field
The invention relates to the technical field of antibacterial fabrics, in particular to a production process of a medical antibacterial fabric.
Background
With the continuous development of scientific and technological technology and the continuous improvement of living standard of people, people gradually pursue comfortable and antibacterial fabrics, and in textile fabrics, because the fabrics belong to the chemical structure of high molecular polymers and the shape of porous objects, microorganisms have good habitats for survival and reproduction and attachment, but the microorganisms not only have harm to human bodies and pollute fiber fabrics, but also cannot be used in the medical field, so the antibacterial fabrics are widely concerned by people in the medical field.
The antibacterial fabric is a textile fabric consisting of fibers, the antibacterial fabric injection agent is fixed inside the nylon fibers and the polyester fibers at high temperature so as to protect the fibers from easily generating microorganisms, and the reason for the antibacterial fabric injection agent for resisting bacteria is that the osmotic pressure inside microbial cells is 20-30 times of the osmotic pressure outside the microbial cells, so that the microbial cells are broken to stop the metabolism of the microbial cells, thereby achieving the effects of sterilization, bacteriostasis and antibiosis.
The metal ions are added into the existing antibacterial fabric to achieve the antibacterial characteristic, so that the fabric has good heat resistance and durability besides the antibacterial effect, but the metal ions have the defects of large using area, easy color change and high cost, so that the metal ion antibacterial fabric cannot be widely used, and in addition, a natural antibacterial agent is added into the fabric, is extracted from natural plants such as chitin, mustard, castor oil, horseradish and the like, but has limited antibacterial capability and poor heat resistance, so that the using amount is small.
Disclosure of Invention
Technical problem to be solved
Aiming at the defects of the prior art, the invention provides a production process of a medical antibacterial fabric, wherein graphene is a hydrophobic plane structure and a hydrophilic edge structure, microorganisms stimulate free radical reaction through charge transfer after contacting graphene materials in the fabric, so that a microorganism cell membrane structure is damaged, the microorganisms die, the graphene takes natural corncobs as raw materials, the graphene is reproducible and cannot cause predatory development on resources, the polyester fibers, viscose fibers and superfine fibers are blended, and an antibacterial agent is added into the blended fabric, so that the antibacterial agent is uniformly distributed in the fabric, and the fiber strength, the heat resistance and the antistatic performance are effectively improved.
(II) technical scheme
In order to achieve the purpose, the invention provides the following technical scheme: a process for preparing medical antibacterial fabric, which is a mixed fabric formed by mixing and spinning the following fibers in parts by weight, comprises 10-20 parts of polyester fibers, 10-20 parts of viscose fibers and 10-20 parts of superfine fibers, and is formed by padding the mixed fabric with an antibacterial agent, and specifically comprises the following steps:
s1, one-bath dyeing: putting 10-20 parts of polyester fiber, 10-20 parts of viscose fiber and 10-20 parts of superfine fiber into the same container, adding 1-3% of an antibacterial agent and adding a dye according to requirements;
s2, padding: mixing and spinning 10-20 parts of polyester fiber, 10-20 parts of viscose fiber and 10-20 parts of superfine fiber by a spinning machine, adding an antibacterial agent, padding, and keeping the mangle ratio at 70-90%;
s3, dehydrating and packaging the fabric processed in the step two at the temperature of 80-110 ℃, drying the fabric at the temperature of 130-160 ℃, and packaging the fabric into a finished product by using a sterile packaging bag.
Preferably, the antibacterial agent comprises 40-60% of chitosan and 40-60% of graphene.
Preferably, the polyester fiber is obtained by slicing and crushing polyester through a high-speed crusher, mixing the polyester and 1,4 butanediol by using a mechanical stirrer, adding formaldehyde and water into a reaction container, adjusting the pH value to be alkalescent through triethanolamine, heating in a water bath for 60-90 minutes, adjusting the pH value to be alkalescent through 36% acetic acid, reacting 120, and curing at 130 ℃.
Preferably, the viscose is obtained by using wood fibers as raw materials, preparing the raw materials into soluble cellulose xanthate through a chemical process, preparing viscose by using alkali liquor, and performing wet spinning.
Preferably, the superfine fiber is superfine synthetic fiber, including polyester, polyamide, polyacrylonitrile, polytetrafluoroethylene, preferably one or two of polyester and polyamide.
Preferably, the mixed fabric comprises 10-20 parts of polyester fibers, 10-20 parts of viscose fibers and 10-20 parts of superfine fibers, and is formed by padding the mixed fabric with an antibacterial agent.
Preferably, the dehydration time is 3-5 minutes, and the drying time is 10-30 minutes.
(III) advantageous effects
The invention provides a production process of medical antibacterial fabric, which has the following beneficial effects:
(1) This medical antibacterial fabric is hydrophobic planar structure and hydrophilic edge structure through graphite alkene, and the transfer of microorganism through the electric charge stimulates the free radical reaction after the graphite alkene material contact in the surface fabric to destroy the microorganism cell membrane structure and make the microorganism die, graphite alkene uses natural corncob as raw and other materials, has the reproducibility, can not cause the predatory development to the resource.
(2) According to the medical antibacterial fabric, the polyester fibers, the viscose fibers and the superfine fibers are blended, and the antibacterial agent is added into the blended fabric, so that the antibacterial agent is uniformly distributed in the fabric, and the fiber strength, the heat resistance and the antistatic performance are effectively improved.
Detailed Description
All other embodiments, which can be obtained by a person skilled in the art without making any creative effort based on the embodiments in the present invention, belong to the protection scope of the present invention.
Example 1
The invention provides a technical scheme that: a production process of medical antibacterial fabric comprises the steps of mixing and spinning 10 parts of polyester fibers, 15 parts of viscose fibers and 20 parts of superfine fibers, padding the mixed fabric into a finished product through an antibacterial agent, and marking the finished product as the first antibacterial fabric, wherein the production process comprises the following specific steps:
s1, one-bath dyeing: putting 10 parts of polyester fiber, 15 parts of viscose fiber and 20 parts of superfine fiber into the same container, adding 1% of an antibacterial agent and adding a dye according to requirements;
s2, padding: mixing and spinning 10 parts of polyester fiber, 15 parts of viscose fiber and 20 parts of superfine fiber by a spinning machine, adding an antibacterial agent, padding, and keeping the mangling rate at 70%;
s3, dehydrating and packaging the fabric processed in the step two at 80 ℃, drying the fabric at 130 ℃, and packaging the fabric into a finished product by using a sterile packaging bag.
Wherein, the dehydration time is 3 minutes, and the drying time is 10 minutes.
The antibacterial agent comprises 40% of chitosan and 60% of graphene.
The polyester fiber is obtained by slicing and crushing polyester through a high-speed crusher, mixing the polyester and 1,4 butanediol by using a mechanical stirrer, adding formaldehyde and water into the mixture, putting the mixture into a reaction container, adjusting the pH value to be alkalescent through triethanolamine, heating the mixture in a water bath for 60 minutes, adjusting the pH value to be alkalescent through 36% acetic acid, reacting the mixture in a water bath for 90 minutes, and curing the mixture at 130 ℃.
The viscose fiber is prepared by using wood fiber as a raw material, preparing the raw material into soluble cellulose xanthate through a chemical process, preparing viscose through alkali liquor, and performing wet spinning on the viscose.
The superfine fiber is superfine synthetic fiber, which comprises polyester, polyamide, polyacrylonitrile and polytetrafluoroethylene, and preferably one or two of polyester and polyamide.
Example 2
The invention provides a technical scheme that: a production process of medical antibacterial fabric comprises the steps of mixing and spinning 15 parts of polyester fiber, 15 parts of viscose fiber and 15 parts of superfine fiber, wherein the mixed fabric is subjected to padding treatment by an antibacterial agent to form a finished product which is marked as an antibacterial fabric II, and the production process comprises the following specific steps:
s1, one-bath dyeing: putting 15 parts of polyester fiber, 15 parts of viscose fiber and 15 parts of superfine fiber into the same container, adding 1-3% of an antibacterial agent and adding a dyeing agent according to requirements;
s2, padding: mixing and spinning 15 parts of polyester fiber, 15 parts of viscose fiber and 15 parts of superfine fiber by a spinning machine, adding an antibacterial agent, padding, and keeping the mangling rate at 80%;
and S3, dehydrating and packaging the fabric processed in the step two at the temperature of 95 ℃, drying the fabric to 145 ℃, and packaging the fabric into a finished product by using a sterile packaging bag.
Wherein the dehydration time is 4 minutes, and the drying time is 20 minutes.
The antibacterial agent comprises 50% of chitosan and 50% of graphene.
The polyester fiber is obtained by slicing and crushing polyester through a high-speed crusher, mixing the polyester and 1,4 butanediol by using a mechanical stirrer, adding formaldehyde and water into the mixture, putting the mixture into a reaction container, adjusting the pH value to be alkalescent through triethanolamine, heating the mixture in a water bath for 75 minutes, adjusting the pH value to be alkalescent through 36% acetic acid, reacting the mixture for 100 minutes, and curing the mixture at 130 ℃.
The viscose fiber is prepared by using wood fiber as a raw material, preparing the raw material into soluble cellulose xanthate through a chemical process, preparing viscose through alkali liquor, and performing wet spinning on the viscose.
The superfine fiber is superfine synthetic fiber, which comprises polyester, polyamide, polyacrylonitrile and polytetrafluoroethylene, and preferably one or two of polyester and polyamide.
Example 3
The invention provides a technical scheme that: a production process of medical antibacterial fabric comprises the steps of mixing and spinning 20 parts of polyester fibers, 15 parts of viscose fibers and 10 parts of superfine fibers, padding the mixed fabric with an antibacterial agent to obtain a finished product, and marking the finished product as antibacterial fabric III, wherein the production process comprises the following specific steps:
s1, one-bath dyeing: putting 20 parts of polyester fiber, 15 parts of viscose fiber and 10 parts of superfine fiber into the same container, adding 3 percent of antibacterial agent and adding a dye according to the requirement;
s2, padding: mixing and spinning 20 parts of polyester fiber, 15 parts of viscose fiber and 10 parts of superfine fiber by a spinning machine, adding an antibacterial agent, padding, and ensuring that the mangle ratio is 90%;
and S3, dehydrating and packaging the fabric processed in the step two at 110 ℃, drying the fabric at 160 ℃, and packaging the fabric into a finished product by using a sterile packaging bag.
Wherein the dehydration time is 5 minutes, and the drying time is 30 minutes.
The antibacterial agent comprises 60% of chitosan and 40% of graphene.
The polyester fiber is obtained by slicing and crushing polyester through a high-speed crusher, mixing the polyester and 1,4 butanediol by using a mechanical stirrer, adding formaldehyde and water into the mixture, putting the mixture into a reaction container, adjusting the pH value to be alkalescent through triethanolamine, heating the mixture in a water bath for 90 minutes, adjusting the pH value to be alkalescent through 36% acetic acid, reacting the mixture in a water bath for 120 minutes, and curing the mixture at 130 ℃.
The viscose fiber is prepared by using wood fiber as a raw material, preparing the raw material into soluble cellulose xanthate through a chemical process, preparing viscose through alkali liquor, and performing wet spinning on the viscose.
The superfine fiber is superfine synthetic fiber, which comprises polyester, polyamide, polyacrylonitrile and polytetrafluoroethylene, and preferably one or two of polyester and polyamide.
Test for antibacterial Property
The test was performed by reference to the oscillation method in the FZ/T73023 standard, and the test results are shown in Table 1:
TABLE 1 detection of antibacterial effect of antibacterial and flame-retardant fabric
In summary, according to the production process of the medical antibacterial fabric, the graphene is of a hydrophobic plane structure and a hydrophilic edge structure, microorganisms stimulate free radical reaction through charge transfer after the graphene in the fabric is contacted, so that a microorganism cell membrane structure is damaged, the microorganisms die, the graphene takes natural corncobs as raw materials, the reproducibility is achieved, resource predatory development cannot be caused, blending is performed through polyester fibers, viscose fibers and superfine fibers, and an antibacterial agent is added into the blended fabric, so that the antibacterial agent is uniformly distributed in the fabric, and the fiber strength, the heat resistance and the antistatic performance are effectively improved.
It is noted that, herein, relational terms such as first and second, and the like may be used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Also, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (7)
1. A process for preparing medical antibacterial fabric is characterized by comprising the following steps: the blended fabric is formed by blending and spinning the following fibers in parts by weight, comprises 10-20 parts of polyester fibers, 10-20 parts of viscose fibers and 10-20 parts of superfine fibers, and is formed by padding the blended fabric with an antibacterial agent, and specifically comprises the following steps:
s1, one-bath dyeing: putting 10-20 parts of polyester fiber, 10-20 parts of viscose fiber and 10-20 parts of superfine fiber into the same container, adding 1-3% of an antibacterial agent and adding a dye according to requirements;
s2, padding: mixing and spinning 10-20 parts of polyester fiber, 10-20 parts of viscose fiber and 10-20 parts of superfine fiber by a spinning machine, adding an antibacterial agent, padding, and keeping the mangle ratio at 70-90%;
s3, dehydrating and packaging the fabric processed in the step two at the temperature of 80-110 ℃, drying the fabric at the temperature of 130-160 ℃, and packaging the fabric into a finished product by using a sterile packaging bag.
2. The production process of the medical antibacterial fabric according to claim 1, characterized by comprising the following steps: the antibacterial agent comprises 40-60% of chitosan and 40-60% of graphene.
3. The production process of the medical antibacterial fabric according to claim 1, characterized by comprising the following steps: the polyester fiber is obtained by slicing and crushing polyester through a high-speed crusher, mixing the polyester and 1,4 butanediol by using a mechanical stirrer, adding formaldehyde and water into the mixture, putting the mixture into a reaction container, adjusting the pH value to be alkalescent through triethanolamine, heating the mixture in a water bath for 60 to 90 minutes, adjusting the pH value to be weakly acidic through 36 percent acetic acid, reacting the mixture in a water bath for 120, and curing the mixture at 130 ℃.
4. The production process of the medical antibacterial fabric according to claim 1, characterized by comprising the following steps: the viscose fiber is prepared by using wood fiber as a raw material, preparing soluble cellulose xanthate through a chemical process, preparing viscose through alkali liquor, and performing wet spinning.
5. The production process of the medical antibacterial fabric according to claim 1, characterized by comprising the following steps: the superfine fiber is superfine synthetic fiber, which comprises polyester, polyamide, polyacrylonitrile and polytetrafluoroethylene, and preferably one or two of polyester and polyamide.
6. The medical antibacterial fabric according to any one of claims 1 to 5, characterized in that: the blended fabric is formed by blending and spinning the following fibers in parts by weight, and comprises 10-20 parts of polyester fibers, 10-20 parts of viscose fibers and 10-20 parts of superfine fibers, and is formed by padding the blended fabric with an antibacterial agent.
7. The production process of the medical antibacterial fabric according to claim 1, characterized by comprising the following steps: the dehydration time is 3-5 minutes, and the drying time is 10-30 minutes.
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