CN115155352B - Mixer for mixing ethylene and oxygen - Google Patents
Mixer for mixing ethylene and oxygen Download PDFInfo
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- CN115155352B CN115155352B CN202210655659.5A CN202210655659A CN115155352B CN 115155352 B CN115155352 B CN 115155352B CN 202210655659 A CN202210655659 A CN 202210655659A CN 115155352 B CN115155352 B CN 115155352B
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- oxygen
- outer cylinder
- distribution plate
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- 239000005977 Ethylene Substances 0.000 title claims abstract description 174
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims abstract description 170
- 239000001301 oxygen Substances 0.000 title claims abstract description 164
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 164
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 161
- 238000009826 distribution Methods 0.000 claims abstract description 74
- 239000007921 spray Substances 0.000 claims abstract description 35
- 238000002347 injection Methods 0.000 claims abstract description 24
- 239000007924 injection Substances 0.000 claims abstract description 24
- 238000005192 partition Methods 0.000 claims abstract description 13
- 239000006185 dispersion Substances 0.000 claims abstract description 12
- 239000007789 gas Substances 0.000 claims description 16
- 238000007789 sealing Methods 0.000 claims description 15
- 238000011144 upstream manufacturing Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 21
- 238000004880 explosion Methods 0.000 description 14
- 239000012530 fluid Substances 0.000 description 14
- 230000000694 effects Effects 0.000 description 13
- 230000008569 process Effects 0.000 description 9
- 230000003647 oxidation Effects 0.000 description 7
- 238000007254 oxidation reaction Methods 0.000 description 7
- 230000003068 static effect Effects 0.000 description 7
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
- 238000005507 spraying Methods 0.000 description 6
- 230000006872 improvement Effects 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- XENVCRGQTABGKY-ZHACJKMWSA-N chlorohydrin Chemical compound CC#CC#CC#CC#C\C=C\C(Cl)CO XENVCRGQTABGKY-ZHACJKMWSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
- 238000009776 industrial production Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 230000004323 axial length Effects 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000002360 explosive Substances 0.000 description 2
- 238000010907 mechanical stirring Methods 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- 230000007480 spreading Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- 241001391944 Commicarpus scandens Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000005465 channeling Effects 0.000 description 1
- OEYIOHPDSNJKLS-UHFFFAOYSA-N choline Chemical compound C[N+](C)(C)CCO OEYIOHPDSNJKLS-UHFFFAOYSA-N 0.000 description 1
- 229960001231 choline Drugs 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/10—Mixing gases with gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/20—Jet mixers, i.e. mixers using high-speed fluid streams
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/60—Safety arrangements
- B01F35/605—Safety devices concerning the operation of the mixer
- B01F35/6052—Safety devices concerning the operation of the mixer with locking, blocking or interlocking mechanisms for preventing operation of the actuation mechanism of the mixing device
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
Abstract
The invention discloses a mixer for mixing ethylene and oxygen, which comprises an outer cylinder body, a layered partition plate, a distribution plate, a spray ring, an ethylene inlet, an oxygen inlet and a dispersion cylinder; the spray ring is fixed on the distribution plate; a feeding area is formed between the distribution plate and the closed end of the outer cylinder, a distribution area is formed in the outer cylinder where the distribution plate and the spray ring are positioned, and a jet flow mixing area is formed between the spray ring and the open end of the outer cylinder; the layering partition plate divides the feeding zone into an ethylene feeding zone and an oxygen feeding zone, and is respectively connected with an ethylene inlet and an oxygen inlet; the distribution plate and the injection ring divide the distribution area into ethylene annular channels and oxygen annular channels which are alternately arranged from outside to inside; ethylene channel holes are formed in the distribution plate in the ethylene feeding area and correspond to the corresponding ethylene annular channels; an oxygen channel hole is formed in the distribution plate in the oxygen feeding area, and corresponding to the corresponding oxygen annular channel, an injection hole is formed in the wall of the dispersing cylinder. The invention can uniformly mix ethylene and oxygen, and is safe and reliable.
Description
Technical Field
The invention belongs to the technical field of mixing equipment, and particularly relates to a mixer for mixing ethylene and oxygen.
Background
Ethylene Oxide (EO) is an important chemical product of downstream derivatives of ethylene industry, is second to polyethylene, has wide application field, is mainly used for producing fine chemical products such as nonionic surfactants, ethanol adhesives, ethylene glycol vinegar, polymerase polyols, choline oxide, medicines and the like, and can also be used as a disinfectant for medical equipment such as foods, cosmetics, surgical equipment and the like. The downstream products of the ethylene oxide can reach 6000 or more, and the production has wide prospect.
The industrial production technology of ethylene oxide mainly comprises a chlorohydrin method and an ethylene direct oxidation method, wherein the chlorohydrin method is mainly used in the early stage, and because chlorine gas is used in the production process of the chlorohydrin method and a large amount of hydrogen chloride is generated, the corrosion damage to equipment, buildings and auxiliary facilities is serious, and in addition, waste water, waste gas and waste materials are difficult to treat, the chlorohydrin method is basically replaced by the ethylene direct oxidation method. The direct ethylene oxidation method can be divided into an air oxidation method and an oxygen oxidation method according to different oxidants, and the air oxidation method is usually low in operation cost, good in catalyst selectivity, high in investment and low in conversion rate, and the current mainstream production method is the oxygen oxidation method for synthesizing ethylene oxide through the reaction of ethylene and oxygen. At this time, the mixing of ethylene and oxygen is necessary to be completed before the reaction, but ethylene is inflammable and explosive, and has a wide explosion range, and if the explosion accident is extremely easy to occur due to improper control, the danger is extremely high, so that the mixing of ethylene and oxygen is a key process and equipment for producing ethylene oxide.
The mixing method commonly used in the current industrial production mainly comprises stirring mixing, static mixer mixing and jet flow mixing. The stirring and mixing mainly uses external mechanical energy such as mechanical stirring to strengthen macroscopic mixing of fluid, but because chemical products are easy to be inflammable and explosive, extremely toxic and easy to react when heated, the mechanical stirring is likely to provide spark and heat required by combustion, and moving parts are difficult to seal and easy to leak, the stirring and mixing is difficult to be used for mixing ethylene and oxygen. The static mixer is generally provided with structures such as a baffle plate in a mixer or a pipeline to disturb fluid flow, increase the speed gradient of laminar flow movement of the fluid or form turbulence to realize mixing of the fluid, but the mixing explosion range of ethylene and oxygen is wider, the mixing proportion of the static mixer is difficult to control, and precise mixing of the ethylene and the oxygen is difficult to realize, so that the static mixer is also difficult to be used for mixing the ethylene and the oxygen.
Jet mixing is the use of the high velocity jet entrainment effect by injecting a fast moving fluid (i.e., jet) into a slow flowing or stationary fluid (i.e., main fluid) to form a mixed layer at the jet boundary due to the velocity differential between the jet and main fluid. The mixing layer expands along the flow direction of the jet, and the main fluid enters the jet through entrainment and mixing, so that the two fluids are uniformly mixed. The mixing mode in industrial production is realized due to the advantages of simple structure, no rotating parts, reliable operation, intense mixing, high mass and heat transfer rate and the like.
The ethylene-oxygen mixer applied in industry at present is usually used as a mixing mode of main flow side feeding and jet flow as tubular feeding, and the jet flow is in single-point injection in general, so that the circumferential direction is uneven and the jet flow mixing effect is poor; the flow direction of the main flow is changed after the main flow enters the mixer laterally, the flow in the mixer is uneven, the impact on the tube array is large, the tube array is easy to break, the structural design is unreasonable, and continuous improvement is needed.
Patent CN 105214528A discloses a mixer of olefin and oxygen, which is mainly characterized in that a plurality of oxygen dispersing pipes are symmetrically arranged at the tail end of an oxygen pipeline, a plurality of oxygen dispersing holes are uniformly distributed on each oxygen dispersing pipe, and the oxygen pipeline is communicated with a mixing chamber through the oxygen dispersing holes. However, in the cross section of the olefin pipe, the oxygen-dispersed holes are denser at the center of the pipe and sparser near the wall surface. In the mixing process, the concentration of oxygen at the center of the main pipe is possibly higher than that near the wall surface, the mixing is uneven, the mixing effect is affected, and safety accidents are easily caused.
Patent CN 108310989B discloses a rapid mixing device for ethylene and oxygen, a plurality of oxygen spiral distributing pipes are arranged in a mixing chamber, the plane of each spiral distributing pipe is vertical to the flowing direction of ethylene, a plurality of oxygen nozzles are uniformly distributed on each spiral distributing pipe, the direction of each nozzle is consistent with the flowing direction of ethylene, ethylene entering from a main flow channel is rapidly mixed with oxygen sprayed from each spiral distributing pipe nozzle in the mixing region, and the mixing of ethylene and oxygen is better solved. However, as the oxygen feeding pipeline is divided into a plurality of distribution pipes at the main pipeline to enter the ethylene main pipeline, oxygen in each oxygen branch pipe may be different, so that the oxygen is unevenly mixed in the mixing area, the mixing effect is affected, and safety accidents are easily caused.
In summary, the mixing of ethylene and oxygen is an important production link, and the mixing process should traverse the explosion region, so that the risk is extremely high, and the ethylene and oxygen must be uniformly mixed and kept away from the explosion region during the mixing process. The current jet flow mixing technology has the technical problems of uneven mixing and easy safety accidents, and needs to be further improved.
Disclosure of Invention
In order to solve the technical problems of uneven mixing and easy safety accidents in the prior art, the invention provides a mixer for mixing ethylene and oxygen, which enables the ethylene and the oxygen to rapidly pass through an explosion interval in the mixing process, and the ethylene and the oxygen are uniformly mixed and then are far away from the explosion interval, so that the aim of safety is fulfilled.
The invention provides a mixer for mixing ethylene and oxygen, which comprises an outer cylinder body, a layered partition plate, a distribution plate, a spray ring, an ethylene inlet, an oxygen inlet and a dispersing cylinder; the outer cylinder body is cylindrical, one end of the outer cylinder body is closed, and the other end of the outer cylinder body is open; the spray ring is cylindrical with two open ends; the distribution plate is fixed in the outer cylinder, and one end of the spray ring is fixed on the distribution plate along the axis of the outer cylinder and is coaxially arranged with the outer cylinder; the space between the distribution plate and the closed end of the outer cylinder forms a feeding area, the space in the outer cylinder where the distribution plate and the spray ring are positioned forms a distribution area, and the space between the spray ring and the open end of the outer cylinder forms a jet mixing area; the layering partition plate is positioned in the feeding area, is vertically fixed on the distribution plate along the axis of the outer cylinder body, divides the feeding area into an ethylene feeding area and an oxygen feeding area, and is connected with the ethylene feeding area and the oxygen feeding area; the distribution plate and the injection ring divide the distribution area into annular channels with the diameters from large to small along the radial direction of the outer cylinder body, the annular channels are divided into ethylene annular channels and oxygen annular channels, and the ethylene annular channels and the oxygen annular channels are alternately arranged along the radial direction of the outer cylinder body from outside to inside; ethylene channel holes are formed in the distribution plate in the ethylene feeding area and correspond to the corresponding ethylene annular channels; oxygen channel holes are formed in the distribution plate in the oxygen feeding area and correspond to the corresponding oxygen annular channels; the dispersing cylinder is arranged in the jet flow mixing area and is coaxially arranged with the outer cylinder body, the upstream end of the dispersing cylinder is an open end of the dispersing cylinder, the downstream end of the dispersing cylinder is sealed by a sealing head to form a sealed end of the dispersing cylinder, and the cylinder wall of the dispersing cylinder is provided with an injection hole.
The specific number of the spray rings can be determined according to the actual working conditions, and is preferably 2-12, preferably 3-8. The large spray ring and the small spray ring are nested layer by layer along the radial direction of the outer cylinder body and are coaxially arranged with the outer cylinder body.
The outer cylinder body can be composed of a shell and a sealing head, and the closed end of the outer cylinder body can be sealed in the form of the sealing head or a flange cover; the open end of the outer cylinder body is used for allowing the mixed gas after mixing to enter a subsequent flow path; the outer cylinder is preferably a cylinder with a diameter of 200-3000 mm for the purpose of easy manufacture and uniform distribution.
The number of the layered separators can be determined according to actual working conditions, and is preferably 2-6, and more preferably 3-5. The layering partition plates and the distribution plates divide the feeding area of the outer cylinder into two types of ethylene feeding areas and oxygen feeding areas, the two types of feeding areas are alternately distributed along the circumferential direction of the outer cylinder, and each ethylene feeding area and each oxygen feeding area are closed areas; each closed area should be tightly sealed, and material channeling is forbidden; and a corresponding ethylene inlet or an oxygen inlet is arranged on the corresponding outer cylinder body of each closed area for external oxygen or ethylene to enter. The number of the layering partition plates is increased, the number of the ethylene feeding area and the oxygen feeding area can be increased, the rapid and uniform diffusion of ethylene and oxygen in the distribution area in the respective annular channels is promoted, the maximum distance of circumferential diffusion is reduced, the uniformity of ethylene and oxygen in the respective annular channels is increased, and the rectifying length and the jet ring length are shortened.
Because only ethylene channel holes corresponding to the ethylene annular channels are formed in the distribution plate of the ethylene feeding area, only oxygen channel holes corresponding to the oxygen annular channels are formed in the distribution plate of the oxygen feeding area, ethylene and oxygen enter the respective annular channels through the respective channel holes without being mixed with each other, and subsequent jet mixing is performed.
The sealing of the two sides of the spray ring and the distribution plate should be performed by reliable manners such as welding, bonding and the like, and the sealing of the mixing equipment must be performed due to the wide explosion range of ethylene and oxygen and extremely high risk. In general, the seal of the injection ring with the distribution plate should ensure that oxygen is only transported within the oxygen annular channel to the jet mixing zone, does not enter the ethylene annular channel, and must not diffuse into the ethylene region at the forward end of the ethylene annular channel; ethylene does not enter the oxygen annular channel, is only conveyed to the jet flow mixing zone in the ethylene annular channel, and cannot diffuse to the oxygen area at the front end of the oxygen annular channel, so that the intrinsic safety of the mixing equipment is ensured.
In order to ensure that the ethylene and the oxygen form jet flow mixing, the ethylene annular channels and the oxygen annular channels are alternately arranged, and the radial width of the ethylene annular channels is larger than that of the oxygen annular channels.
As a modification, the annular channel of the outermost ring of the distribution area is an ethylene annular channel.
The determination of the spray ring length may take into account the following two aspects:
on the one hand, after oxygen enters the oxygen annular channel from the oxygen channel holes on the distribution plate, the oxygen diffuses to the area in the oxygen annular channel, in which no oxygen directly enters, and then enters the jet flow mixing area after the oxygen is uniformly distributed in the oxygen annular channel. The oxygen annular channel plays roles in guiding oxygen and rectifying oxygen, and the oxygen is uniformly distributed in the annular direction in the oxygen annular channel, so that the injection ring is required to have a certain axial length;
on the other hand, after the ethylene enters the ethylene annular channel from the ethylene channel holes on the distribution plate, the ethylene is diffused in the ethylene annular channel to a region where the ethylene does not directly enter, and when the ethylene is uniformly distributed in the ethylene annular channel, the ethylene enters the jet mixing region. The injection ring is used for rectifying the ethylene in the circumferential direction, so that the ethylene is uniformly distributed in the ethylene annular channel in the circumferential direction, and therefore, the injection ring is required to have a certain axial length;
the final length of the spray ring takes the largest of the lengths determined by both and leaves a certain margin to provide greater operational flexibility.
As a further improvement, in order to shorten the rectifying length of the ethylene by the jet ring in the distribution area, promote the ethylene to diffuse to the ethylene annular channel area without direct feeding of ethylene, reduce the lengths of the jet ring and the mixing equipment, continuously or discontinuously set ethylene baffle plates on the inner wall of the ethylene annular channel corresponding to the ethylene channel holes, wherein the height of the ethylene baffle plates is smaller than the radial width of the ethylene annular channel, preferably smaller than 1/2 of the radial width of the ethylene annular channel, so as to increase the flow resistance of the ethylene after entering the ethylene annular channel, promote the ethylene to flow to the ethylene annular channel position without direct opening of the ethylene channel holes, and ensure that the ethylene is uniformly distributed in the annular channel in a shorter distance.
After ethylene and oxygen are rectified by the jet ring and distributed uniformly in the respective annular channels, the ethylene and the oxygen enter the jet mixing area. The total area of the cross section of the oxygen annular channel is smaller than the total area of the oxygen inlet, the conveying speed of oxygen in the oxygen annular channel is increased to 20-100 m/s, the fast moving oxygen fluid is injected into the relatively low-speed main fluid, namely ethylene flow, at the jet boundary, a mixed layer is formed due to the speed difference of the oxygen jet and the ethylene main fluid, and the mixed layer is expanded along the flow direction of the oxygen jet, and the main fluid ethylene enters the oxygen jet through entrainment and mixing, so that the purposes of fast passing through the explosion range and fast mixing are achieved. When the size of the annular channel, the position of the injection ring and the position of the ethylene channel hole are designed, oxygen injected from different oxygen annular channels must not cross and strike the wall surface within a certain distance, so as to realize the control of the mixing proportion of oxygen and ethylene, and avoid explosion. In the jet mixing zone, ethylene and oxygen are firstly jet mixed, the oxygen quickly passes through the explosion hazard zone, and after further mixing is completed through the dispersing cylinder, the oxygen is far away from the explosion range and leaves the mixing equipment.
The dispersing cylinder is preferably cylindrical, and the sealing head at the closed end of the dispersing cylinder can be flat, conical or spherical. The closed end seal head is not provided with holes, and the mixed gas entering the dispersing cylinder is completely separated from the spraying hole on the cylinder wall of the dispersing cylinder and is mixed with the gas which does not enter the dispersing cylinder in the annular area between the dispersing cylinder and the cylinder wall of the outer cylinder, so that the mixing effect can be greatly enhanced. Of course, the closed end can also adopt a local blocking mode, namely, an injection hole can be formed in the closed end sealing head, when the sealing head is provided with the injection hole, part of mixed gas entering the dispersing cylinder can be directly sprayed out from the sealing head, the mixing intensity of the gas in the jet flow mixing area can be weakened, the mixing effect can be reduced, and if the opening ratio of the sealing head is larger, the mixing effect is reduced more.
When the dispersing cylinder is cylindrical, the diameter is preferably 40% -80% of the diameter of the outer cylinder. The spraying holes on the wall of the dispersing cylinder and the sealing head are uniformly distributed along the circumferential direction of the tube wall, and can be round holes, slits or other shapes, from the angle of convenient processing, the spraying holes are preferably round holes, and the diameter of the round holes is 2-40 mm, preferably 4-30 mm. The mixed gas in the dispersing cylinder is sprayed out from the spraying holes to form staggered contact with the mixed gas in the ring flowing from front to back, and the mixed gas and the ring are fully mixed.
As a further proposal, in order to make the gas flow in the mixer smoother, the injection holes on the wall of the dispersing cylinder are preferably arranged along the gas flow direction from inside to outside, so that the gas in the cylinder is injected into the gas flow outside the cylinder, and the included angle between the opening direction and the axis of the dispersing cylinder is preferably 10-70 degrees, and is preferably 30-60 degrees.
As a further proposal, the hole opening ratio of the spray hole on the wall of the dispersion cylinder is gradually reduced from front to back along the axis of the cylinder wall, and the hole opening size is gradually reduced. Therefore, the pressure drop can be reduced on the basis of ensuring the mixing effect, most of the gas in the cylinder is sprayed out from the front end of the dispersing cylinder, the pressure drop is small, the contact time with the gas outside the dispersing cylinder is long, and the mixing effect is improved; the gas in the small part of cylinder is sprayed out from the rear end, the spraying speed is high, and the mixing effect is enhanced by the speed difference.
The dispersing cylinder is fixedly connected with the inner wall of the outer cylinder body through a supporting column. The fixed connection mode can adopt a detachable connection mode or a non-detachable connection mode. The detachable connection mode can be realized by adding bolts, threads, clamping grooves, clamping hoops or lantern rings and the like; the non-detachable connection mode can be realized by welding, riveting and the like. The number of the support columns may be set to one or two or more according to practical situations. If a detachable connection mode is adopted, the dispersing cylinder can be taken out of the mixer, inspected, cleaned or replaced in the shutdown maintenance process of the device; if a non-detachable connection mode is adopted, the installation mode is simpler. If the mixer diameter is small or the mixer operating temperature is not high, a non-detachable connection is recommended if the mixing medium is not easy to adhere to and block the dispersion cylinder and its injection hole.
As a further improvement, the mixer for mixing ethylene and oxygen can be provided with an electrostatic grounding device so as to eliminate the influence of static electricity on the mixing process, prevent static electricity accumulation, increase the safety of mixing equipment and increase the intrinsic safety.
As a further improvement, considering the extremely high risk of the mixing equipment, an explosion-proof wall can be arranged outside the mixer for mixing ethylene and oxygen, so that the loss of extreme accident conditions is minimized.
As a further improvement, considering the extremely high risk of the mixing equipment, the mixer for mixing ethylene and oxygen can be provided with an interlocking control system, and when the oxygen content of a measured point exceeds the standard, the oxygen supply is reduced or inert gases such as nitrogen are introduced from an oxygen inlet, so that the mixing process is far from the explosion limit.
The invention has the following beneficial effects:
1) By utilizing the spraying and entrainment of high-speed oxygen, ethylene and oxygen are quickly mixed through explosion limit and quick mixing, so that the physical domain and time domain of the mixing process are reduced, and the aim of safe mixing is fulfilled;
2) The diversion effect of the coaxially arranged multi-layer injection rings realizes that ethylene and oxygen enter the mixing equipment in the same direction, oxygen is uniformly and continuously sprayed from the oxygen annular channels with different diameters to the inner ring of the mixing equipment, the mixing is easy to be uniform, and the operation elasticity is high; the accurate mixing of ethylene and oxygen is realized by setting the flow velocity of the oxygen jet flow and the position of the jet flow;
3) By arranging the dispersing cylinder, the ethylene and the oxygen are mixed more fully in the jet flow mixing area, and the mixing effect is improved;
4) The safety of the mixing equipment is ensured by the static electricity eliminating device, the explosion-proof wall, the interlocking control system and the like.
Drawings
FIG. 1 is a schematic view of a construction of the present invention;
FIG. 2 is a schematic axial view of the feed zone when the layered separator of the present invention is two.
FIG. 3 is a schematic view of the spreading structure of the wall of the dispersing cylinder;
fig. 4 is a schematic structural view of the fixed connection of the dispersing cylinder.
In the figure: the device comprises an A-feeding area, a B-distribution area, a C-jet mixing area, a 1-outer cylinder, a 2-ethylene inlet, a 3-layering partition board, a 4-oxygen inlet, a 5-distribution board, a 6-oxygen passage hole, a 7-ethylene passage hole, an 8-ethylene baffle, a 9-jet ring, a 10-ethylene annular passage, a 11-oxygen annular passage, a 12-support column, a 13-dispersing cylinder and a 14-jet hole.
Detailed Description
The invention is further described below with reference to the accompanying drawings.
Fig. 1 is a schematic view of a construction of the present invention, as shown,
the mixer for mixing ethylene and oxygen comprises an outer cylinder body 1, a layered partition plate 3, a distribution plate 5, a spray ring 9, an ethylene inlet 2, an oxygen inlet 4 and a dispersing cylinder 13; the outer cylinder body 1 is cylindrical, the left end is closed, and the right end is open; the spray rings 9 are cylindrical with two open ends, and the number of the spray rings 9 is six; the distribution plate 5 is fixed on the inner wall of the outer cylinder 1, the left end of the spray ring 9 is welded on the distribution plate 5 along the axis of the outer cylinder 1 and is coaxially arranged with the outer cylinder 1, and the right end of the spray ring 9 is a free end; the space between the distribution plate 5 and the closed end, namely the left end, of the outer cylinder body 1 forms a feeding area A, the space between the distribution plate 5 and the inner space of the outer cylinder body 1 where the spray ring 9 is positioned forms a distribution area B, and the space between the spray ring 9 and the open end, namely the right end, of the outer cylinder body 1 forms a jet flow mixing area C; the layering partition plate 3 is positioned in the feeding area A, is vertically fixed on the distribution plate 5 along the axis of the outer cylinder body 1, divides the feeding area A into two types of ethylene feeding areas and oxygen feeding areas, wherein the ethylene inlet 2 is connected with the ethylene feeding areas, and the oxygen inlet 4 is connected with the oxygen feeding areas; the distribution plate 5 and the injection ring 9 divide the distribution area B into seven annular channels with diameters from large to small along the radial direction of the outer cylinder 1 from outside to inside, the seven annular channels comprise four ethylene annular channels 10 and three oxygen annular channels 11, and the ethylene annular channels 10 and the oxygen annular channels 11 are alternately arranged along the radial direction of the outer cylinder 1 from outside to inside; ethylene channel holes 7 are formed in the distribution plate in the ethylene feeding area and correspond to the corresponding ethylene annular channels 10; the distribution plate in the oxygen feeding area is provided with oxygen channel holes 6 which correspond to the corresponding oxygen annular channels 11; in the feeding zone A and the distribution zone B, ethylene and oxygen are not mixed; the dispersion cylinder 13 is arranged in the jet mixing area C, is fixed on the inner wall of the outer cylinder body 1 through the support column 12, the cylinder wall of the dispersion cylinder 13 is provided with an injection hole 14, the sealing head of the closed end of the dispersion cylinder 13 is conical, and the conical sealing head is not provided with an injection hole. Of course, the dispersing cylinder head can also be provided with an injection hole.
The ethylene baffle plate 8 is arranged on the inner wall of the ethylene annular channel 10, which corresponds to the ethylene channel hole 7, and the height of the ethylene baffle plate 8 is smaller than the radial width of the ethylene annular channel 10, so that the flow resistance of ethylene entering the ethylene annular channel 10 is increased, the ethylene is promoted to flow to the position of the ethylene annular channel which is not directly provided with the ethylene channel hole, and the ethylene is uniformly distributed in the annular channel in a shorter distance.
Fig. 2 is a schematic axial structure of a feeding area when the number of the layered separators is two, as shown in the drawing, the number of the layered separators 3 is two, the layered separators vertically intersect, the feeding area is divided into two ethylene feeding areas and two oxygen feeding areas, the two ethylene feeding areas correspond to the two ethylene inlets 2, the two oxygen feeding areas correspond to the two oxygen inlets 4, and the ethylene feeding areas and the oxygen feeding areas are alternately arranged along the circumferential direction of the distribution plate 5. The distribution plate 5 is a circular flat plate, and is provided with an oxygen passage hole 6 and an ethylene passage hole 7. The oxygen passage holes 6 are shown in the figure with circular arc-shaped shadows having a narrow radial width, and the ethylene passage holes 7 are shown in the figure with circular arc-shaped shadows having a wide radial width. The non-perforated areas on the distribution plate 5 are non-shaded areas.
Fig. 3 is a schematic view of the spreading structure of the dispersion cylinder wall, showing a distribution of the spray holes 14, which gradually decrease in aperture ratio from front to rear along the axis of the dispersion cylinder wall, and gradually decrease in aperture size.
Fig. 4 is a schematic structural view of the fixed connection of the dispersing cylinder, as can be seen from the figure, the dispersing cylinder 13 is fixedly connected to the inner wall of the outer cylinder body 1 through 3 supporting columns 12.
As shown in fig. 1 and 2, the present invention operates:
ethylene enters an ethylene feeding area from an ethylene inlet 2, enters an ethylene annular channel 10 through ethylene channel holes 7 on a distribution plate 5, diffuses in the ethylene annular channel 10 to an area where no ethylene directly enters, and enters a jet mixing area C after being uniformly distributed in the ethylene annular channel 10;
oxygen enters the oxygen feeding area from the oxygen inlet 4, enters the oxygen annular channel 11 through the oxygen channel holes 6 on the distribution plate 5, diffuses in the oxygen annular channel 11 to the area where no oxygen directly enters, and enters the jet mixing area C after being uniformly distributed in the oxygen annular channel 11;
in the jet mixing zone C, the ethylene and oxygen are jet mixed first and then further mixed by the dispersion cylinder 13 to achieve the desired mixing effect.
Claims (14)
1. A mixer for mixing ethylene with oxygen, characterized by: comprises an outer cylinder body, a layered partition plate, a distribution plate, a spray ring, an ethylene inlet, an oxygen inlet and a dispersion cylinder; the outer cylinder body is cylindrical, one end of the outer cylinder body is closed, and the other end of the outer cylinder body is open; the spray ring is cylindrical with two open ends; the distribution plate is fixed in the outer cylinder, and one end of the spray ring is fixed on the distribution plate along the axis of the outer cylinder and is coaxially arranged with the outer cylinder; the space between the distribution plate and the closed end of the outer cylinder forms a feeding area, the space in the outer cylinder where the distribution plate and the spray ring are positioned forms a distribution area, and the space between the spray ring and the open end of the outer cylinder forms a jet mixing area; the layering partition plate is positioned in the feeding area, is vertically fixed on the distribution plate along the axis of the outer cylinder body, divides the feeding area into an ethylene feeding area and an oxygen feeding area, and is connected with the ethylene feeding area and the oxygen feeding area; the distribution plate and the injection ring divide the distribution area into annular channels with the diameters from large to small along the radial direction of the outer cylinder body, the annular channels are divided into ethylene annular channels and oxygen annular channels, and the ethylene annular channels and the oxygen annular channels are alternately arranged along the radial direction of the outer cylinder body from outside to inside; ethylene channel holes are formed in the distribution plate in the ethylene feeding area and correspond to the corresponding ethylene annular channels; oxygen channel holes are formed in the distribution plate in the oxygen feeding area and correspond to the corresponding oxygen annular channels; the dispersing cylinder is arranged in the jet flow mixing area and is coaxially arranged with the outer cylinder body, the upstream end of the dispersing cylinder is an open end of the dispersing cylinder, the downstream end of the dispersing cylinder is sealed by a sealing head to form a sealed end of the dispersing cylinder, and the cylinder wall of the dispersing cylinder is provided with an injection hole.
2. The mixer according to claim 1, characterized in that: the number of the spray rings is 2-12.
3. The mixer according to claim 1, characterized in that: the number of the layered separators is 2-6.
4. The mixer according to claim 1, characterized in that: the ethylene feeding areas and the oxygen feeding areas are alternately distributed along the circumferential direction of the outer cylinder body.
5. The mixer according to claim 1, characterized in that: the radial width of the ethylene annular channel is greater than the radial width of the oxygen annular channel.
6. The mixer according to claim 1, characterized in that: and an ethylene baffle is arranged on the inner wall of the ethylene annular channel, which corresponds to the ethylene channel hole, and the height of the ethylene baffle is smaller than the radial width of the ethylene annular channel.
7. The mixer of claim 6, wherein: the height of the ethylene baffle is less than 1/2 of the radial width of the ethylene annular channel.
8. The mixer according to claim 1, characterized in that: the annular channel of the outermost ring of the distribution area is an ethylene annular channel.
9. The mixer according to claim 1, characterized in that: the jet hole on the wall of the dispersion cylinder is gradually reduced from front to back along the axis of the cylinder wall, and the size of the jet hole is gradually reduced.
10. The mixer according to claim 1, characterized in that: the jet holes on the wall of the dispersing cylinder are formed along the gas flowing direction from inside to outside.
11. The mixer according to any one of claims 1 to 10, characterized in that: and the device also comprises an electrostatic grounding device.
12. The mixer according to any one of claims 1 to 10, characterized in that: the mixer also comprises an explosion-proof wall arranged outside the mixer.
13. The mixer according to any one of claims 1 to 10, characterized in that: an interlock control system is also included.
14. A mixer for mixing ethylene with oxygen, characterized by: comprises an outer cylinder body, a layered partition plate, a distribution plate, a spray ring, an ethylene inlet, an oxygen inlet and a dispersion cylinder; the outer cylinder body is cylindrical, one end of the outer cylinder body is closed, and the other end of the outer cylinder body is open; the spray ring is cylindrical with two open ends; the distribution plate is fixed in the outer cylinder, and one end of the spray ring is fixed on the distribution plate along the axis of the outer cylinder and is coaxially arranged with the outer cylinder; the space between the distribution plate and the closed end of the outer cylinder forms a feeding area, the space in the outer cylinder where the distribution plate and the spray ring are positioned forms a distribution area, and the space between the spray ring and the open end of the outer cylinder forms a jet mixing area; the layering partition plate is positioned in the feeding area, is vertically fixed on the distribution plate along the axis of the outer cylinder body, divides the feeding area into an ethylene feeding area and an oxygen feeding area, and is connected with the ethylene feeding area and the oxygen feeding area; the distribution plate and the injection ring divide the distribution area into annular channels with the diameters from large to small along the radial direction of the outer cylinder body, the annular channels are divided into ethylene annular channels and oxygen annular channels, and the ethylene annular channels and the oxygen annular channels are alternately arranged along the radial direction of the outer cylinder body from outside to inside; ethylene channel holes are formed in the distribution plate in the ethylene feeding area and correspond to the corresponding ethylene annular channels; oxygen channel holes are formed in the distribution plate in the oxygen feeding area and correspond to the corresponding oxygen annular channels; the dispersing cylinder is arranged in the jet flow mixing area and is coaxially arranged with the outer cylinder body, the upstream end of the dispersing cylinder is an open end of the dispersing cylinder, the cylinder wall of the dispersing cylinder is provided with an injection hole, and the downstream end of the dispersing cylinder is partially blocked by a sealing head with the injection hole.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN202210655659.5A CN115155352B (en) | 2022-06-10 | 2022-06-10 | Mixer for mixing ethylene and oxygen |
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| CN202210655659.5A CN115155352B (en) | 2022-06-10 | 2022-06-10 | Mixer for mixing ethylene and oxygen |
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| CN115155352A (en) | 2022-10-11 |
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