CN114941047B - Rotary hearth furnace - Google Patents
Rotary hearth furnace Download PDFInfo
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- CN114941047B CN114941047B CN202210466714.6A CN202210466714A CN114941047B CN 114941047 B CN114941047 B CN 114941047B CN 202210466714 A CN202210466714 A CN 202210466714A CN 114941047 B CN114941047 B CN 114941047B
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- hydrogen
- rich gas
- rotary hearth
- hearth furnace
- furnace
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- 239000007789 gas Substances 0.000 claims abstract description 157
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 156
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 155
- 239000001257 hydrogen Substances 0.000 claims abstract description 155
- 239000008188 pellet Substances 0.000 claims abstract description 125
- 238000001816 cooling Methods 0.000 claims abstract description 119
- 239000007921 spray Substances 0.000 claims description 35
- 238000007599 discharging Methods 0.000 claims description 13
- 230000001105 regulatory effect Effects 0.000 claims description 13
- 238000002485 combustion reaction Methods 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 238000007790 scraping Methods 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 abstract description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 13
- 238000005265 energy consumption Methods 0.000 abstract description 7
- 238000001465 metallisation Methods 0.000 abstract description 7
- 238000011084 recovery Methods 0.000 abstract description 3
- 238000006722 reduction reaction Methods 0.000 description 81
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 20
- 229910052742 iron Inorganic materials 0.000 description 10
- 238000013461 design Methods 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 239000000428 dust Substances 0.000 description 8
- 238000002347 injection Methods 0.000 description 8
- 239000007924 injection Substances 0.000 description 8
- 238000011946 reduction process Methods 0.000 description 7
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 239000003546 flue gas Substances 0.000 description 5
- 238000012546 transfer Methods 0.000 description 5
- 238000003723 Smelting Methods 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- 239000000779 smoke Substances 0.000 description 4
- 229910052725 zinc Inorganic materials 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 230000001276 controlling effect Effects 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 239000003245 coal Substances 0.000 description 2
- 238000004939 coking Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical group [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 230000003009 desulfurizing effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/10—Making spongy iron or liquid steel, by direct processes in hearth-type furnaces
- C21B13/105—Rotary hearth-type furnaces
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/0073—Selection or treatment of the reducing gases
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
The invention discloses a rotary hearth furnace, belongs to the technical field of direct reduction of rotary hearth furnaces, and solves the problems of high direct reduction carbon emission, low product metallization rate and no recovery of high-temperature sensible heat of metallized pellets of the rotary hearth furnace. The rotary hearth furnace comprises a reduction section, a first cooling section and a discharge end which are sequentially communicated; the on-line cooling device is arranged above the first cooling section and comprises a hydrogen-rich gas generating unit and a hydrogen-rich gas conveying unit which are connected; the hydrogen-rich gas generating unit is used for providing hydrogen-rich gas; the hydrogen-rich gas conveying unit comprises a conveying pipeline which is arranged at the top of the rotary hearth furnace and is communicated with the first cooling section of the rotary hearth furnace; after being generated by the hydrogen-rich gas generating unit, the hydrogen-rich gas is conveyed to the first cooling section by the hydrogen-rich gas conveying unit, and the metallized pellets are cooled and deeply reduced by the hydrogen-rich gas in the first cooling section. The invention can reduce the reduction energy consumption of the rotary hearth furnace.
Description
Technical Field
The invention relates to a direct reduction iron-making device of a rotary hearth furnace, in particular to a rotary hearth furnace.
Background
The rotary hearth furnace direct reduction process is a new technology for non-coking coal iron making, and is mainly used for treating zinc-containing dust and special iron ore resources.
The rotary hearth furnace direct reduction process is a new technology for non-coking coal iron making, and is mainly used for treating zinc-containing dust and special iron ore resources. In the last 50 th century, the precursor Ross corporation of Midrex, U.S. invented a rotary hearth furnace direct reduction process for carbonaceous pellets, named Fastmet process, and conducted a 2t/h small scale thermal consolidation experiment. In 1974, international nickel group Canadian (Inmetco) began to study rotary hearth furnace treatment of stainless steel oxide dust waste, and metallized pellets pre-reduced by rotary hearth furnace were directly hot charged into an electric furnace for smelting, which was named as Inmetco process. At the end of the last century, the company of Japan Konja made steel and Midrex, USA, developed a new process for direct reduction of iron in rotary hearth furnaces, in which metallized pellets were reduced and melted in rotary hearth furnaces to form iron nuggets, while the iron slag was separated and named the third generation iron-making method (Itmk 3). The Itemk 3 process has been subjected to industrial tests and has commercial production capacity. The rotary hearth furnace process has been successful in treating zinc-containing dust in iron and steel enterprises, and is now increasingly being popularized and applied to the extraction of special iron ore resources.
In recent years, the rotary hearth furnace technology has been rapidly developed in China, and a plurality of rotary hearth furnace direct reduction production lines are built in succession in China. From the practical point of operation of the rotary hearth furnace, the smelting of the steel solid dust by the rotary hearth furnace has the characteristics of high resource utilization efficiency and high lead and zinc removal rate. Although the rotary hearth furnace technology has been successful in China and is gradually popularized for smelting some special iron ore resources, the rotary hearth furnace technology also has the problems of low product metallization rate, high smelting energy consumption and no recovery of sensible heat of metallized pellets.
Along with the implementation of 'carbon reaching peak and carbon neutralization' policies in China, the reduction of the direct reduction carbon consumption of the rotary hearth furnace becomes an important point of future rotary hearth furnace development. The first cooling section of the traditional rotary hearth furnace adopts water-cooled furnace top cooling, the cooling speed is low, and the cooled heat is not recovered.
Disclosure of Invention
In view of the analysis, the invention aims to provide an online cooling method for metallized pellets of a rotary hearth furnace, which solves the technical problems of low metallization rate, high carbon emission and no recovery of high-temperature sensible heat of the metallized pellets of a traditional direct reduction product of the rotary hearth furnace.
The aim of the invention is mainly realized by the following technical scheme:
the invention provides a rotary hearth furnace, which comprises an online cooling device, wherein the online cooling device is arranged on the top of the rotary hearth furnace; the rotary hearth furnace comprises a reduction section, a first cooling section and a discharge end which are sequentially communicated;
the on-line cooling device comprises a hydrogen-rich gas generating unit and a hydrogen-rich gas conveying unit which are connected; the hydrogen-rich gas generating unit is used for providing hydrogen-rich gas;
the hydrogen-rich gas conveying unit comprises a conveying pipeline which is arranged at the top of the rotary hearth furnace and is communicated with the first cooling section of the rotary hearth furnace;
after being generated by the hydrogen-rich gas generating unit, the hydrogen-rich gas is conveyed to the first cooling section by the hydrogen-rich gas conveying unit, and the metallized pellets are cooled and deeply reduced by the hydrogen-rich gas in the first cooling section.
In one possible design, the top of the reduction section is provided with a reduction section furnace top wall; the top of the first cooling section is provided with a cooling section furnace top wall, and the top of the discharging end is provided with a discharging end furnace top wall; the distances between the reduction section top wall, the cooling section top wall and the discharge end top wall and the bottom of the rotary hearth furnace are sequentially reduced.
In one possible design, a three-way head is arranged on the conveying pipeline, a first end of the three-way head is communicated with the hydrogen-rich gas generating unit, a second end of the three-way head is connected with a first main pipe, and a third end of the three-way head is connected with a second main pipe; the first main pipe and the second main pipe are vertically arranged;
the first main pipe is provided with a plurality of first conveying branch pipes which are arranged in parallel and perpendicular to the first main pipe; the second main pipe is provided with a plurality of second conveying branch pipes which are arranged in parallel and perpendicular to the second main pipe, and the first conveying branch pipes are arranged below the second conveying branch pipes and are staggered;
a plurality of first nozzles are arranged on the first conveying branch pipe; the second conveying branch pipe is provided with a second nozzle, and the first nozzle and the second nozzle penetrate through the furnace top wall of the cooling section.
In one possible design, the second nozzles are located at the gap between two adjacent first conveying branch pipes and are distributed at equal intervals with two adjacent first nozzles on the first conveying branch pipes;
the first nozzle and the second nozzle can both spray hydrogen-rich gas into the surface of the metallized pellets of the first cooling section.
In one possible design, the first nozzle and the second nozzle are hollow tubular nozzles, a hemispherical spray head is arranged at one end of the hollow tubular nozzle far away from the corresponding conveying branch pipe, a first spray hole and a second spray hole are arranged on the hemispherical spray head in a circumferential direction, the diameter of the first spray hole is 1.0-1.5 times that of the second spray hole, and the second spray hole is positioned at the top end of the hemispherical spray head.
In one possible design, the hydrogen-rich gas generating apparatus includes a hydrogen-rich gas tank, a pressurizing machine, a first hydrogen-rich gas flow meter, and a first flow regulating valve;
the hydrogen-rich gas tank is connected with a conveying pipeline, and the pressurizing machine, the first hydrogen-rich gas flowmeter and the first flow regulating valve are sequentially arranged on the conveying pipeline.
In one possible design, the discharge end is located at a distance of 5-20cm from the top wall to the bottom of the furnace.
In one possible design, the reduction stage has a top wall to bottom distance of 10 to 200cm.
In one possible design, the cooling section has a top wall to bottom distance of 5 to 50cm.
In one possible design, a screw discharger is provided at the discharge end of the rotary hearth furnace, the screw discharger being used to discharge cooled metallized pellets out of the rotary hearth furnace.
Compared with the prior art, the invention has at least one of the following beneficial effects:
(1) In the rotary hearth furnace provided by the invention, the water-cooling furnace wall of the first cooling section of the traditional rotary hearth furnace is changed into the hydrogen-rich gas which is directly sprayed on the surface of the metallized pellet, the temperature of the metallized pellet to the first cooling section is 1100-1350 ℃, the hydrogen-rich gas is sprayed on the surface of the metallized pellet, the metallized pellet can be further reduced, the reduction rate of the metallized pellet is improved, the pellet metallization rate can be improved to more than 90%, and the quality of the product directly reduced by the rotary hearth furnace is improved.
(2) In the rotary hearth furnace provided by the invention, the hydrogen-rich gas is directly sprayed onto the surface of the metallized pellets, so that the metallized pellets can be deeply reduced, the temperature of the metallized pellets can be reduced, the temperature of the metallized pellets is reduced from 1100-1350 ℃ to 700-1000 ℃, the discharging temperature of the pellets is reduced, and the service life of the spiral discharger is prolonged.
(3) In the rotary hearth furnace provided by the invention, the hydrogen-rich gas is directly sprayed onto the surface of the metallized pellets by utilizing the hydrogen-rich gas conveying unit, so that the temperature of the hydrogen-rich gas is increased while the temperature of the metallized pellets is reduced, the sensible heat of the high-temperature metallized pellets is recovered, the high-temperature hydrogen-rich gas enters the reduction section of the rotary hearth furnace to burn to provide heat for reduction of the carbon-containing pellets, the direct reduction energy consumption of the rotary hearth furnace is reduced, the carbon emission of the rotary hearth furnace is reduced, and the high-efficiency reduction of the pellets and the high-efficiency utilization of the hydrogen-rich gas are cooperatively utilized.
In the invention, the technical schemes can be mutually combined to realize more preferable combination schemes. Additional features and advantages of the invention will be set forth in the description which follows, and in part will be obvious from the description, or may be learned by practice of the invention. The objectives and other advantages of the invention may be realized and attained by the embodiments of the invention particularly pointed out in the written description and drawings.
Drawings
The drawings are only for purposes of illustrating particular embodiments and are not to be construed as limiting the invention, like reference numerals being used to refer to like parts throughout the several views.
FIG. 1 is a schematic view of a rotary hearth furnace 1;
FIG. 2 is a flow chart of a rotary hearth furnace hydrogen-rich reduction process;
FIG. 3 is a diagram showing the connection of a hydrogen-rich gas injection header and a branch pipe;
FIG. 4 is a schematic view of the structure of a first nozzle provided on a first delivery manifold;
FIG. 5 is a front view of the rotary hearth furnace;
fig. 6 is a schematic sectional view of a rotary hearth furnace.
Reference numerals:
1-a rotary hearth furnace bottom; 2-metallizing the pellets; 3-a reduction section furnace top wall; 4-cooling section furnace top wall; 5-a top wall of the discharging end furnace; 6-a first header; 7-a second header; 8-a first delivery manifold; 9-a second delivery manifold; 10-a first nozzle; 11-a second nozzle; 12-a conveying pipeline; 13-a first flow regulating valve; 14-a first hydrogen-rich gas flow meter; 15-a hydrogen-rich gas pressurizing machine; 16-a first nozzle; 17-a second nozzle; 18-a third manifold; 19-a second flow regulating valve; 20-a second hydrogen-rich gas flow meter; 21-a third delivery manifold; 22-a second cooling section; 23-a first cooling section; 24-spiral discharger; 25-cooling section; 26-a reduction section; 27-a pre-reduction stage; 28-a feed inlet; 29 tee joint.
Detailed Description
The following detailed description of preferred embodiments of the invention is made in connection with the accompanying drawings, which form a part hereof, and together with the description of the embodiments of the invention, are used to explain the principles of the invention and are not intended to limit the scope of the invention.
The invention provides a rotary hearth furnace, wherein an online cooling device is arranged on the rotary hearth furnace; the rotary hearth furnace comprises a feeding section (comprising a feeding port 28), a reduction section 26, a cooling section 25 (comprising a first cooling section 23) and a discharging end which are sequentially communicated; the on-line cooling device comprises a hydrogen-rich gas generating unit and a hydrogen-rich gas conveying unit which are connected; the hydrogen-rich gas generating unit is used for providing hydrogen-rich gas; the hydrogen-rich gas conveying unit comprises a conveying pipeline 12, wherein the conveying pipeline 12 is arranged at the top of the rotary hearth furnace and is communicated with a first cooling section 23 of the rotary hearth furnace; after being generated by the hydrogen-rich gas generating unit, the hydrogen-rich gas is conveyed to the first cooling section 23 by the hydrogen-rich gas conveying unit, and the hydrogen-rich gas cools and deeply reduces the metallized pellets in the first cooling section 23.
Specifically, as shown in fig. 1 to 6, the on-line cooling device is arranged on the top of the rotary hearth furnace, along the rotation direction of the bottom 1 of the rotary hearth furnace, the rotary hearth furnace comprises a feeding end, a reduction section 26 (the reduction section 27 is arranged before pre-reduction, the pre-reduction section 27 is arranged conventionally, the application is developed, and the description is provided), a first cooling section 23 and a discharging end, metallized pellets 2 enter the reduction section of the rotary hearth furnace through a feeder arranged at the feeding end, and after reduction in the reduction section, metallized pellets are formed and enter the first cooling section 23; the hydrogen-rich gas generated by the hydrogen-rich gas unit is conveyed to the first cooling section 23 through the hydrogen-rich gas conveying unit and is sprayed to the surface of the metallized pellets from the top of the first cooling section 23, after the hydrogen-rich gas exchanges heat with the metallized pellets, the temperature of the hydrogen-rich gas is increased, and the temperature of the metallized pellets is reduced, so that cooling is realized, the metallized pellets 2 after being sufficiently cooled by the hydrogen-rich gas are discharged out of the rotary hearth furnace through the discharge end, and online reduction and cooling of the metallized pellets 2 are realized.
The traditional rotary hearth furnace cooling section adopts water-cooled furnace top cooling, the cooling speed is low, and the cooled heat is not recovered; compared with the prior art, the invention provides the method for directly jetting the hydrogen-rich gas to the surface of the metallized pellet in the reduction section of the rotary hearth furnace, and on one hand, H in the hydrogen-rich gas is utilized 2 The high-temperature metallized pellets are quickly reduced, so that the metallization rate of the metallized pellets is further improved; on the other hand, the metallized pellets are cooled by utilizing the hydrogen-rich gas, and the cooled high-temperature hydrogen-rich gas provides heat for the reduction of the metallized pellets 2 in a reduction section in a combustion mode, so that the direct reduction energy consumption of the rotary hearth furnace is reduced.
In order to ensure that the hydrogen rich gas after heat exchange with the metallized pellets can enter a reduction section, the top of the reduction section is provided with a reduction section furnace top wall 3; the top of the first cooling section 23 is provided with a cooling section furnace top wall 4, and the top of the discharge end is provided with a discharge end furnace top wall 5; the distances from the reduction section furnace top wall 3, the cooling section furnace top wall 4 and the discharge end furnace top wall 5 to the rotary hearth furnace bottom 1 are sequentially reduced.
Specifically, as shown in fig. 1, the height of the top wall 3 of the reduction section from the furnace bottom is larger than the height of the top wall 4 of the cooling section from the furnace bottom, and the height of the top wall 4 of the cooling section from the furnace bottom is larger than the height of the top wall 5 of the discharge end from the furnace bottom, so that the hydrogen-rich gas after heat exchange with the metallized pellets completely enters the reduction section, and thus the hydrogen-rich gas is prevented from entering the discharge end; in addition, it should be noted that a flue is disposed on the top wall of the feeding section, a negative pressure fan is disposed outside the flue, and the negative pressure generated by the negative pressure fan can pump out the flue gas (the flue gas formed after the hydrogen-rich gas is further reduced and combusted) in the rotary hearth furnace, so as to ensure that the flow direction of the hydrogen-rich gas flows from the first cooling section 23 to the reducing section, and prevent the hydrogen-rich gas from entering the discharging end.
The rotary hearth furnace comprises a smoke treatment unit, wherein the smoke treatment unit is connected with the negative pressure fan, and smoke sucked by the negative pressure fan enters the smoke treatment unit. The flue gas treatment unit comprises a primary dust remover, a heat exchanger, a bag-type dust remover, a desulfurizing tower, a denitration tower, an induced draft fan and a chimney; the flue gas treatment unit can recycle sensible heat, volatilized valuable metals, oxides and dust in the flue gas.
In order to ensure that the hydrogen-rich gas sprayed onto the surface of the metallized pellets is more uniform, a three-way head 29 is arranged on the conveying pipeline 12, a first end of the three-way head 29 is communicated with a hydrogen-rich gas generating unit, a second end of the three-way head 29 is connected with a first main pipe 6, and a third end of the three-way head 29 is connected with a second main pipe 7; the first header pipe 6 is arranged vertically to the second header pipe 7; the first main pipe 6 is provided with a plurality of first conveying branch pipes 8 which are arranged in parallel and are vertical to the first main pipe 6; the second main pipe 7 is provided with a plurality of second conveying branch pipes 9 which are arranged in parallel and perpendicular to the second main pipe 7, and the first conveying branch pipes 8 are arranged below the second conveying branch pipes 9 in a staggered manner; the first conveying branch pipe 8 is provided with a plurality of first nozzles 10; the second conveying branch pipe 9 is provided with a second nozzle 11, and both the first nozzle 10 and the second nozzle 11 penetrate through the cooling section furnace top wall 4.
Specifically, as shown in fig. 3, the first main pipe 6 is provided with a plurality of first conveying branch pipes 8 arranged in parallel, the first conveying branch pipes 8 are arranged at equal intervals, one end of each first conveying branch pipe 8 is communicated with the first main pipe 6, and all the first conveying branch pipes 8 are arranged vertically to the first main pipe 6; in addition, when explanation is needed, as the first conveying branch pipe 8 is positioned below the second conveying branch pipe 9, a transfer pipe is arranged between the three-way head and the second main pipe 7, one end of the transfer pipe is connected with the third end of the three-way head, the other end of the transfer pipe is connected with the second main pipe 7, the transfer pipe is arranged in a vertical direction, the purpose of the transfer pipe is to ensure that the second main pipe 7 is positioned above the first main pipe 6 in a space position, so that the second conveying branch pipes 9 which are arranged on the second main pipe 7 at equal intervals are positioned above the first conveying branch pipes 8, and the first conveying branch pipes 8 and the second conveying branch pipes 9 are arranged in a staggered manner; because the first conveying branch pipe 8 is provided with a plurality of first nozzles 10, the second conveying branch pipe 9 is provided with a second nozzle 11, the first nozzles 10 and the second nozzles 11 penetrate through the cooling section furnace top wall 4, and finally, the first nozzles 10 and the second nozzles 11 are ensured to uniformly spray hydrogen-rich gas onto the surfaces of the metallized pellets.
Compared with the prior art, the invention can uniformly spray the hydrogen-rich gas onto the surface of the metallized pellet by arranging the first header pipe 6 and the second header pipe 7 vertically and arranging the plurality of first nozzles 10 on the first conveying branch pipe 8 and arranging the second nozzles 11 on the second conveying branch pipe 9, thereby realizing rapid online cooling of the metallized pellet.
In order to further uniformly spray the hydrogen-rich gas into the rotary hearth furnace, so that the hydrogen-rich gas is fully contacted with the metallized pellets for heat exchange, the second nozzles 11 are positioned at the gaps between two adjacent first conveying branch pipes 8 and are distributed at equal intervals with two adjacent first nozzles 10 on the first conveying branch pipes 8; the first nozzle 10 and the second nozzle 11 can spray hydrogen-rich gas onto the surface of the metallized pellets 2 in the first cooling section 23, the metallized pellets are cooled, the hydrogen-rich gas further reduces the metallized pellets, the hydrogen-rich gas after cooling the metallized pellets enters the reduction section, and the hydrogen-rich gas is combusted in the reduction section to provide heat for the reduction of the metallized pellets 2.
In order to further increase the uniformity of hydrogen-rich gas injection, the first nozzle 10 and the second nozzle 11 of the invention have the same structure and are hollow tubular nozzles, a hemispherical spray head is arranged at one end of the hollow tubular nozzle, which is far away from a corresponding conveying branch pipe, the hemispherical spray head is provided with first spray holes 16 which are circumferentially arranged and second spray holes 17 which are positioned at the top ends of the hemispherical spray heads, and the diameter of the first spray holes 16 is 1.0-1.5 times that of the second spray holes 17.
As shown in fig. 4, for example, the hydrogen-rich gas of the present invention enters the corresponding hemispherical spray head through the first delivery branch pipe 8 or the second delivery branch pipe 9, and the diameter of the first spray hole 16 is set to be 1.0-1.5 times the diameter of the second spray hole 17 for uniform spraying of the hydrogen-rich gas because the gas pressure at the top end of the hemispherical spray head is greater than the gas pressure at other positions of the hemispherical spray head.
The hydrogen-rich gas generating apparatus of the present invention includes a hydrogen-rich gas tank, a hydrogen-rich gas pressurizing machine 15, a first hydrogen-rich gas flow meter 14, and a first flow rate regulating valve 13; the hydrogen-rich gas tank is connected with the conveying pipeline 12, and the hydrogen-rich gas pressurizing machine 15, the first hydrogen-rich gas flowmeter 14 and the first flow regulating valve 13 are sequentially arranged on the conveying pipeline 12.
The metallized pellets cooled by the on-line cooling device of the present invention are discharged from the rotary hearth furnace through the screw discharger 24 provided at the discharge end of the rotary hearth furnace.
Compared with the prior art, the hydrogen-rich gas is directly sprayed to the surface of the metallized pellets by utilizing the online cooling device, so that the metallized pellets can be deeply reduced, the temperature of the metallized pellets can be reduced, the temperature of the metallized pellets is reduced from 1100-1350 ℃ to 700-1000 ℃, the discharging temperature of the pellets is reduced, and the service life of the spiral discharger 24 is prolonged.
In the present application, the distance between the reduction stage furnace top wall 3 and the furnace bottom is 10 to 200cm, and the distance is larger than the distance between the cooling stage furnace top wall 4 and the furnace bottom. The distance between the furnace top wall 3 and the furnace bottom of the reduction section is controlled within the range of 10-200cm, so that the hydrogen-rich gas after heat exchange with the metallized pellets can enter the reduction section.
It should be noted that the distance between the cooling section furnace top wall 4 and the furnace bottom is 5-50 cm. The laying height of the metallized pellets 2 is 3-5cm, and the distance between the furnace top wall 4 of the cooling section and the furnace bottom is controlled within the range of 5-50cm, so that the hydrogen rich gas sprayed by the first nozzle 10 and the second nozzle 11 can be directly sprayed onto the surface of the metallized pellets, and further, the sufficient cooling is realized.
It should be noted that the distance between the top wall and the bottom of the discharging end furnace in the invention is 5-20 cm. The distance between the furnace top wall 5 of the discharge end and the furnace bottom is controlled within the range of 5-20cm, so that the hydrogen-rich reducing gas after heat exchange with the metallized pellets can be prevented from entering the discharge end.
After the rotary hearth furnace is fed, in order to pave the mixed materials (comprising metallized pellets 2 and carbon), a scraping plate is arranged at the feeding section of the rotary hearth furnace, two ends of the scraping plate are respectively fixed on the inner side wall and the outer side wall of the rotary hearth furnace, and the scraping plate can scrape the mixed materials entering the rotary hearth furnace.
The annular retaining walls are arranged on the inner side and the outer side of the rotary hearth furnace, and the height of the annular retaining walls is equal to the laying height of the metallized pellets 2 on the bottom of the rotary hearth furnace. The region that the bottom of inboard annular barricade, outside annular barricade, rotary hearth furnace formed is the material and places the district, and inboard annular barricade and outside annular barricade are used for preventing the material to arrange outward, can improve the charge volume of material on the rotary hearth furnace bottom plate simultaneously.
In order to provide the processing capacity of the mixed materials and further improve the yield of metallized pellets of the rotary hearth furnace, a second cooling section 22 is arranged between the reduction section and the first cooling section 23; the inner side furnace wall and the outer side furnace wall of the second cooling section 22 are respectively provided with a plurality of third conveying branch pipes 21 which are arranged in parallel, the first ends of the third conveying branch pipes 21 are communicated with the conveying pipeline 12 of the hydrogen-rich gas through the third main pipe 18, the second ends of the third conveying branch pipes extend to the lower layer of the mixture layer in the rotary hearth furnace, the second ends of the third conveying branch pipes 21 are provided with 90-degree adapter connectors, and the hydrogen-rich gas is sprayed to the middle position of the lower layer of the mixture at a relatively high speed through the 90-degree adapter connectors, so that the deep reduction and full cooling of the lower layer of the mixture are realized.
In order to fully and deeply reduce and simultaneously cool the metal pellets at the lower layer in the mixture layer, the invention is provided with a second flow regulating valve 19 and a second hydrogen-rich gas flowmeter 20 on the third main pipe 18, the flow rate of hydrogen-rich gas in the third conveying branch pipe 21 is controlled to be 25-50m/s through the second flow regulating valve 19 and the second hydrogen-rich gas flowmeter 20, and the hydrogen-rich gas can deeply reduce and fully cool all materials (including the edge part and the central part) at the lower layer because of high flow rate.
It should be noted that, a plurality of combustion nozzles are disposed on the inner side furnace wall and the outer side furnace wall of the reduction section, oxygen is injected into the rotary hearth furnace through the combustion nozzles, so as to provide necessary conditions for the combustion of carbon in the mixture layer, and heat released by the combustion of unreacted hydrogen in the hydrogen-rich gas injected from the first cooling section 23 and the second cooling section 22 heats the mixture to a temperature required by the direct reduction reaction, and the related valuable metal oxides in the mixture layer and the carbon undergo the direct reduction reaction and are effectively recycled.
The invention also provides an online cooling method of the metallized pellet of the rotary hearth furnace, which adopts the rotary hearth furnace and comprises the following steps:
step 1, hydrogen-rich gas generated by a hydrogen-rich gas generating unit is firstly conveyed to a second cooling section 22 of a rotary hearth furnace through a third main pipe 18 and a third conveying branch pipe 21 of a hydrogen-rich gas conveying unit, metallized pellets reduced by a reduction section simultaneously enter the second cooling section 22, and the hydrogen-rich gas sprayed by the third conveying branch pipe 21 is sprayed into the pellets through the bottom layers of the multi-layer metallized pellets, so that the first deep reduction and cooling of the metallized pellets are realized;
step 2, the hydrogen-rich gas after heat exchange enters a reduction section, the metallized pellets after the first deep reduction and cooling enter a first cooling section 23 along with the rotation of a rotary hearth furnace, and at the moment, the hydrogen-rich gas is sprayed to the surfaces of the metallized pellets through a first nozzle 10 and a second nozzle 11 and is subjected to the second cooling and the deep reduction with the hydrogen-rich gas; the metallized pellets are discharged out of the rotary hearth furnace through a discharge end after being cooled twice and deeply reduced; and the hydrogen-rich gas after heat exchange with the metallized pellets enters a reduction section, is ignited by a combustion nozzle and burns to provide heat for the metallized pellets 2.
The traditional rotary hearth furnace cooling section adopts water-cooled furnace top cooling, the cooling speed is low, and the cooled heat is not recovered. Compared with the prior art, the invention can spray the hydrogen-rich gas to the surface of the metallized pellets in the furnace through the hydrogen-rich gas generating unit and the hydrogen-rich gas conveying unit, and can deeply reduce the metallized pellets while cooling the metallized pellets, thereby improving the metallization rate of the metallized pellets, and the hydrogen-rich gas after heat exchange is combusted in the reduction section, thereby improving the energy for the reduction process of the metallized pellets 2 and finally realizing the purpose of reducing the energy consumption of the rotary hearth furnace.
In the step 1, the injection amount of the hydrogen-rich gas in the rotary hearth furnace is 50-1000 m 3 And/t metallizing the pellets. The purpose of controlling the injection amount of the hydrogen-rich gas within this range is to: the temperature of the metallized pellets is ensured to be reduced from 1100-1350 ℃ to 700-1000 ℃, in addition, the hydrogen-rich gas can deeply reduce the metallized pellets, the reduction rate of the metallized pellets is improved, and the metallized pellets are subjected to the process of reducing the metallized pelletsThe reduction rate is improved to more than 95 percent, and the product quality of the rotary hearth furnace after direct reduction is improved. In addition, the service life of the screw discharger 24 can be improved due to the reduction of the discharge temperature of the metallized pellets.
In step 1, the hydrogen-rich gas comprises CO, H 2 And CH (CH) 4 、CO 2 And H 2 O, where CO 2 And H 2 The sum of the volume fractions of O is less than 5%.
Compared with the prior art, the invention uses CO 2 And H 2 The volume fraction of O is controlled in the above range, on one hand, the metallized pellets can be deeply reduced, and on the other hand, the hydrogen-rich gas after heat exchange enters a reduction section, if CO 2 And H 2 The sum of the volume fractions of O is greater than 5%, these gases affecting the reduction process on the metallized pellet 2.
In step 1 and step 2, the injection velocity of the hydrogen-rich gas in the third branch pipe 21 is larger than the injection velocity of the hydrogen-rich gas in the first branch pipe 8 and the second branch pipe 9.
Compared with the prior art, the hydrogen-rich gas is simultaneously introduced into the first cooling section 23 and the second cooling section 22, the injection speed of the hydrogen-rich gas in the first cooling section 23 is low, the contact time of the hydrogen-rich gas and the metallized pellets is long, and the full cooling and deep reduction are fully realized. In addition, the hydrogen-rich gas in the second cooling section 22 can be sprayed to the central position of the lower pellet of the metallized pellet through the right-angle adapter, so that the cooling and deep reduction of the metallized pellet at the lower layer are ensured.
In step 1 and step 2, the flow rates of the hydrogen-rich gas in the first delivery branch pipe 8 and the second delivery branch pipe 9 are each 1 to 5m/s by controlling the first flow rate adjusting valve 13.
Compared with the prior art, the flow rate of the hydrogen-rich gas in the first conveying branch pipe 8 and the second conveying branch pipe 9 is controlled to be 1-5m/s, so that the contact time of the hydrogen-rich gas and the metal pellets can be increased, the cooling effect of the high-temperature metallized pellets is improved, the sensible heat of the metallized pellets is recovered, and the gas consumption and the carbon emission of the rotary hearth furnace are reduced.
In step 2, the second flow rate regulating valve 19 and the second hydrogen-rich gas flow meter are provided on the third manifold 18, and the flow rate of the hydrogen-rich gas in the third delivery branch pipe 21 is 25 to 50m/s by controlling the second flow rate regulating valve 19.
Compared with the prior art, the flow rate of the hydrogen-rich gas in the third conveying branch pipe 21 is controlled to be 25-50m/s, so that the sprayed hydrogen-rich gas can reach the middle position of the lower pellet of the metallized pellet, and the deep reduction process and the cooling process of the lower pellet are promoted.
Example 1
The embodiment provides a rotary hearth furnace, which comprises an online cooling device of metallized pellets, wherein the online cooling device comprises a pressurizing machine, a first hydrogen-rich gas flowmeter 14, a first flow regulating valve 13, a conveying main pipe, conveying branch pipes and branch pipe nozzles, a cooling section furnace top wall 4, a reduction section furnace top wall 3 and a discharge end furnace top wall; the first conveying branch pipes 8 and the second conveying branch pipes 9 are uniformly and alternately distributed on the top wall 4 of the cooling section of the rotary hearth furnace, and a plurality of nozzles are distributed on each branch pipe, so that hydrogen-rich gas can be uniformly sprayed on the surface of the metallized pellets at the bottom of the furnace, and the metallized pellets are deeply reduced and cooled. The cooling section furnace top wall 4, the reduction section furnace top wall 3 and the discharge end furnace top wall are different in distance from the rotary hearth furnace bottom 1, the discharge end furnace top wall is small in distance from the rotary hearth furnace bottom, the reduction section furnace top wall 3 is large in distance from the rotary hearth furnace bottom, the reduction section has small resistance with the first cooling section, and hydrogen-rich gas can enter the reduction section from the first cooling section to provide heat for the reduction section.
The online cooling device for the metallized pellets of the rotary hearth furnace can uniformly spray hydrogen-rich gas onto the surfaces of the metallized pellets at high temperature, and can cool the metallized pellets while deeply reducing the metallized pellets, and the high-temperature hydrogen-rich gas after cooling the metallized pellets enters a reduction section to burn to provide heat, so that the direct reduction energy consumption of the rotary hearth furnace is reduced. The hydrogen-rich gas is pressurized to 2kPa by a pressurizer, enters a hydrogen-rich gas conveying pipeline 12 through a flowmeter and a first flow regulating valve 13, and has a hydrogen-rich gas injection quantity of 50m 3 The/t metallized pellet, the hydrogen-rich gas respectively enters the first main pipe 6 and the second main pipe 7 along the conveying pipeline 12, and then enters the first conveying branchAnd finally, the pipe 8 and the second conveying branch pipe 9 are sprayed into the surface of the metallized pellets 2 of the first cooling section of the rotary hearth furnace through a first nozzle 10 on the first conveying branch pipe 8 and a second nozzle 11 on the second conveying branch pipe 9, so that the deep reduction and cooling of the high-temperature metallized pellets are realized. The distance between the top wall 5 of the discharging end and the furnace bottom is 5cm, the distance between the top wall 4 of the cooling section and the furnace bottom is 10cm, and the distance between the top wall 3 of the reduction section and the furnace bottom is 200cm. After the metallized pellets are reduced and cooled by the hydrogen-rich gas in the first cooling section, the temperature reaches 800 ℃, the metallized pellets enter the reduction section, and the metallized pellets are burnt in the reduction section to provide heat for direct reduction of the carbon-containing pellets, so that the direct reduction energy consumption of the rotary hearth furnace is reduced. In the embodiment, the reduction degree of the metallized pellets is improved through hydrogen-rich reduction, and the metallization rate of the metallized pellets is more than 95%; the cooling effect of the high-temperature metallized pellets is improved, the sensible heat of the metallized pellets is recovered, the temperature of the metallized pellets is reduced from 1100-1350 ℃ to 700-1000 ℃, the temperature of the hydrogen-rich gas after heat exchange is increased, the hydrogen-rich gas can burn and release heat after entering the reduction section, the energy is improved for the reduction of the metallized pellets, and the gas consumption and the carbon emission of the rotary hearth furnace are further reduced.
The present invention is not limited to the above-mentioned embodiments, and any changes or substitutions that can be easily understood by those skilled in the art within the technical scope of the present invention are intended to be included in the scope of the present invention.
Claims (6)
1. The rotary hearth furnace is characterized by comprising an online cooling device for metallized pellets, wherein the online cooling device is arranged on the rotary hearth furnace; the rotary hearth furnace comprises a reduction section, a first cooling section and a discharge end which are sequentially communicated;
the online cooling device comprises a hydrogen-rich gas generating unit and a hydrogen-rich gas conveying unit which are connected; the hydrogen-rich gas generating unit is used for providing hydrogen-rich gas;
the hydrogen-rich gas conveying unit comprises a conveying pipeline which is arranged at the top of the rotary hearth furnace and is communicated with the first cooling section of the rotary hearth furnace;
after being generated by the hydrogen-rich gas generating unit, the hydrogen-rich gas is conveyed to the first cooling section by the hydrogen-rich gas conveying unit, and the hydrogen-rich gas cools and deeply reduces the metallized pellets in the first cooling section;
the top of the reduction section is provided with a reduction section furnace top wall; the top of the first cooling section is provided with a cooling section furnace top wall, and the top of the discharging end is provided with a discharging end furnace top wall; the distances between the reduction section furnace top wall, the cooling section furnace top wall and the discharge end furnace top wall and the bottom of the rotary hearth furnace are sequentially reduced;
the conveying pipeline is provided with a three-way head, a first end of the three-way head is communicated with the hydrogen-rich gas generating unit, a second end of the three-way head is connected with a first main pipe, and a third end of the three-way head is connected with a second main pipe; the first main pipe is arranged vertically to the second main pipe;
the first main pipe is provided with a plurality of first conveying branch pipes which are arranged in parallel and perpendicular to the first main pipe; the second main pipe is provided with a plurality of second conveying branch pipes which are arranged in parallel and perpendicular to the second main pipe, and the first conveying branch pipes are arranged below the second conveying branch pipes and are staggered;
a plurality of first nozzles are arranged on the first conveying branch pipe; the second conveying branch pipe is provided with a second nozzle, and the first nozzle and the second nozzle penetrate through the top wall of the cooling section;
the second nozzles are positioned at the gaps of two adjacent first conveying branch pipes and are distributed at equal intervals with the two adjacent first nozzles on the first conveying branch pipes;
the first nozzle and the second nozzle can spray hydrogen-rich gas onto the surface of the metallized pellet of the first cooling section;
a plurality of combustion nozzles are arranged on the inner side furnace wall and the outer side furnace wall of the reduction section, and oxygen is sprayed into the rotary hearth furnace through the combustion nozzles;
the first nozzle and the second nozzle are hollow tubular nozzles, a hemispherical spray head is arranged at one end of the hollow tubular nozzle, which is far away from the corresponding conveying branch pipe, the hemispherical spray head is provided with first spray holes which are arranged in a circumferential direction and second spray holes which are positioned at the top end of the hemispherical spray head, and the diameter of the first spray holes is 1.0-1.5 times that of the second spray holes;
a second cooling section is arranged between the reduction section and the first cooling section; a plurality of third conveying branch pipes which are arranged in parallel are arranged on the inner side furnace wall and the outer side furnace wall of the second cooling section, the first end of each third conveying branch pipe is communicated with a conveying pipeline of hydrogen-rich gas through a third main pipe, the second end of each third conveying branch pipe extends to the lower layer of a mixture layer in the rotary hearth furnace, and a 90-degree adapter is arranged on the second end of each third conveying branch pipe;
the feeding section of the rotary hearth furnace is provided with a scraping plate, two ends of the scraping plate are respectively fixed on the inner side wall and the outer side wall of the rotary hearth furnace, and the scraping plate is used for scraping and leveling mixed materials entering the rotary hearth furnace.
2. The rotary hearth furnace of claim 1, wherein the hydrogen-rich gas generating apparatus includes a hydrogen-rich gas tank, a pressurizer, a first hydrogen-rich gas flow meter, and a first flow regulator valve;
the hydrogen-rich gas tank is connected with the conveying pipeline, and the pressurizing machine, the first hydrogen-rich gas flowmeter and the first flow regulating valve are sequentially arranged on the conveying pipeline.
3. The rotary hearth furnace of claim 1, wherein the discharge end roof wall is 5-20cm from the hearth.
4. A rotary hearth furnace according to claim 3, wherein the reduction zone top wall is from 10 to 200cm from the hearth.
5. The rotary hearth furnace according to claim 4, wherein the cooling section has a top wall to bottom distance of 5 to 50cm.
6. The rotary hearth furnace according to any one of claims 2 to 5, wherein a screw discharger for discharging cooled metallized pellets out of the rotary hearth furnace is provided at a discharge end of the rotary hearth furnace.
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| US4268303A (en) * | 1978-04-10 | 1981-05-19 | Kobe Steel, Limited | Direct reduction process for producing reduced iron |
| CN106403595A (en) * | 2016-11-22 | 2017-02-15 | 江苏省冶金设计院有限公司 | Oxidation-reduction roasting integrated rotary hearth furnace |
| CN111926135A (en) * | 2020-07-14 | 2020-11-13 | 钢研晟华科技股份有限公司 | Hydrogen-based shaft furnace direct reduction system and reduction method |
| CN112159880A (en) * | 2020-09-30 | 2021-01-01 | 华北理工大学 | Method and device for making iron by hydrogen |
| CN215750254U (en) * | 2021-06-21 | 2022-02-08 | 湖北塑通科技有限公司 | Cooling device for plastic product forming die |
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2022
- 2022-04-29 CN CN202210466714.6A patent/CN114941047B/en active Active
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4268303A (en) * | 1978-04-10 | 1981-05-19 | Kobe Steel, Limited | Direct reduction process for producing reduced iron |
| CN106403595A (en) * | 2016-11-22 | 2017-02-15 | 江苏省冶金设计院有限公司 | Oxidation-reduction roasting integrated rotary hearth furnace |
| CN111926135A (en) * | 2020-07-14 | 2020-11-13 | 钢研晟华科技股份有限公司 | Hydrogen-based shaft furnace direct reduction system and reduction method |
| CN112159880A (en) * | 2020-09-30 | 2021-01-01 | 华北理工大学 | Method and device for making iron by hydrogen |
| CN215750254U (en) * | 2021-06-21 | 2022-02-08 | 湖北塑通科技有限公司 | Cooling device for plastic product forming die |
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