[go: up one dir, main page]
More Web Proxy on the site http://driver.im/

CN114672350A - 一种创新节约型尾气清洁剂及其制备方法 - Google Patents

一种创新节约型尾气清洁剂及其制备方法 Download PDF

Info

Publication number
CN114672350A
CN114672350A CN202110961821.1A CN202110961821A CN114672350A CN 114672350 A CN114672350 A CN 114672350A CN 202110961821 A CN202110961821 A CN 202110961821A CN 114672350 A CN114672350 A CN 114672350A
Authority
CN
China
Prior art keywords
parts
innovative
economical
tail gas
cleaning agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202110961821.1A
Other languages
English (en)
Inventor
朱子龙
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Sushoubao Network Technology Co ltd
Original Assignee
Anhui Sushoubao Network Technology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Sushoubao Network Technology Co ltd filed Critical Anhui Sushoubao Network Technology Co ltd
Priority to CN202110961821.1A priority Critical patent/CN114672350A/zh
Publication of CN114672350A publication Critical patent/CN114672350A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1208—Inorganic compounds elements
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1233—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
    • C10L1/125—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1857—Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C10L1/1886—Carboxylic acids; metal salts thereof naphthenic acid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • C10L1/1905—Esters ester radical containing compounds; ester ethers; carbonic acid esters of di- or polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • C10L1/1915—Esters ester radical containing compounds; ester ethers; carbonic acid esters complex esters (at least 3 ester bonds)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • C10L1/2225—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates hydroxy containing
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/08—Inhibitors
    • C10L2230/081—Anti-oxidants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/22—Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2270/00—Specifically adapted fuels
    • C10L2270/02—Specifically adapted fuels for internal combustion engines
    • C10L2270/023—Specifically adapted fuels for internal combustion engines for gasoline engines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/24—Mixing, stirring of fuel components

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Anti-Oxidant Or Stabilizer Compositions (AREA)

Abstract

本发明公开了一种创新节约型尾气清洁剂及其制备方法，包括以下重量份的原料：甲醇10‑20份、环烷酸铈5‑10份、多乙烯多胺2‑13份、三硬脂酸甘油酯6‑20份、纳米负载型活性炭2‑6份、抗氧稳定剂0.5‑1.5份、去离子水7‑25份、N‑甲基‑二乙醇胺3‑6份、2‑乙二氧基乙酸乙酯3‑8份、硝酸异丙酯3‑10份、二甲基酮3‑7份、二异丙醚6‑15份、丙二酸乙酯1.5‑3.5份。本发明使用时，受到抗氧化剂的稳定性，保证了其清洁剂的保存寿命，同时在使用过程中使油雾更精细，有助于增氧助燃。

Description

一种创新节约型尾气清洁剂及其制备方法
技术领域
本发明属于汽车能源技术领域，涉及一种液体燃料添加剂及其制备方法，更确切地说，是一种创新节约型尾气清洁剂及其制备方法。
背景技术
从2010年以来，随着国家经济的快速发展及人们生活水平的不断提高，汽车替代自行车、电动车、摩托车，成了人们的新的代步工具，与人们的生活息息相关，已经成为人们生活的一部分。
目前常见的汽车大多是依靠汽油来提供动力的，但汽油的燃烧往往不充分，造成汽车油路系统堵塞，发动机功率下降，在燃烧过程中产生大量的有害物质，外泄后产生大量的尾气排放，对大气环境造成了严重的污染，对人们的身心健康构成威胁。因此，本领域技术人员提供了一种创新节约型尾气清洁剂及其制备方法，以解决上述背景技术中提出的问题。
发明内容
本发明的目的在于提供一种创新节约型尾气清洁剂及其制备方法，以解决上述背景技术中提出的问题。
为实现上述目的，本发明提供如下技术方案：
一种创新节约型尾气清洁剂，包括以下重量份的原料：甲醇10-20份、环烷酸铈5-10 份、多乙烯多胺2-13份、三硬脂酸甘油酯6-20份、纳米负载型活性炭2-6份、抗氧稳定剂0.5-1.5份、去离子水7-25份、N-甲基-二乙醇胺3-6份、2-乙二氧基乙酸乙酯3-8份、硝酸异丙酯3-10份、二甲基酮3-7份、二异丙醚6-15份、丙二酸乙酯1.5-3.5份。
作为本发明进一步的方案：所述纳米负载型活性炭的制备方法为：20mL的钛酸正丁酯加入到40mL的无水乙醇中，升温至120℃搅拌均匀后，静置冷却至室温，加入5g的活性炭，再置于-9℃冰箱中冷却成凝胶状；-15℃超微粉碎得到粒径为40-45μm的纳米负载活性炭。
作为本发明再进一步的方案：所述抗氧稳定剂的制备方法为：将10g的4,4'-硫代双(6- 叔丁基-3-甲基苯酚)粗晶体加入到20g的C6烷烃和5g低级醇的复合溶剂混合，升温至 200℃溶解后，恒温搅拌十分钟，加入6g亚磷酸酯，继续搅拌十分钟，使亚磷酸酯对甲酚充分溶解后，静置冷却至室温。
作为本发明再进一步的方案：所述N-甲基-二乙醇胺的制备方法为：将甲酸加入反应锅内加热至沸，在搅拌下滴加甲醛和二乙醇胺的混合液，约1h滴完，温度维持在90-98℃，继续回流4h。然后进行减压蒸馏，收集120-130℃(0.53kPa)馏分，即得N-甲基二乙醇胺。
本发明还提供了一种创新节约型尾气清洁剂的制备方法，包括以下步骤：
S1：将2-乙二氧基乙酸乙酯份、三硬脂酸甘油酯份、硝酸异丙酯份、二甲基酮份、二异丙醚份、丙二酸乙酯份、纳米负载型活性炭份依次加入反应釜中，混合搅拌形成调和物；
S2：将甲醇份、环烷酸铈份、多乙烯多胺份加入反应釜中，60℃水浴加热2小时后，静置降温，再加入去离子水份、抗氧稳定剂份、N-甲基-二乙醇胺份浓缩至含水量小于2％，得到混合液；
S3：将调和物与混合液在常温下混合搅拌均匀，静置5-6h得到该清洁剂。
作为本发明再进一步的方案：所述S1，反应釜设置为常温,40℃和常压，搅拌时间为5小时。
作为本发明再进一步的方案：所述S2，釜内以0-60℃减压浓缩。
与现有技术相比，本发明的有益效果是：
1、本发明使用时，与汽油的混溶性好，制备方法简单，在汽油发动机高速高温运转的情况下能够稳定助燃，提高动力和汽油的燃烧率，节约了汽油使用量，大大提高了对汽油燃烧后产生的硫化物、氮氧化物、可吸入颗粒的吸附降解效率。
2、本发明使用时，纳米负载型活性炭采用常见的溶胶-凝胶法制备而成，以活性炭作为载体防止二氧化钛纳米的团聚，提高了纳米材料的稳定性，而且与纳米二氧化钛产生良好的协同效应，混入清洁剂后，活性炭和纳米二氧化钛均可对柴油燃烧产生的CO、CO2、NOX、可吸入颗粒进行大量的吸附，而且耐高温性能好，高温燃烧不会破坏该负载型活性炭的结构。
3、本发明使用时，受到抗氧化剂的稳定性，保证了其清洁剂的保存寿命，同时在使用过程中使油雾更精细，有助于增氧助燃。
具体实施方式
下面将对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
一种创新节约型尾气清洁剂，包括以下重量份的原料：甲醇10-20份、环烷酸铈5-10 份、多乙烯多胺2-13份、三硬脂酸甘油酯6-20份、纳米负载型活性炭2-6份、抗氧稳定剂0.5-1.5份、去离子水7-25份、N-甲基-二乙醇胺3-6份、2-乙二氧基乙酸乙酯3-8份、硝酸异丙酯3-10份、二甲基酮3-7份、二异丙醚6-15份、丙二酸乙酯1.5-3.5份。
实施例1
一种节能助燃汽车尾气汽油清洁剂，包括以下重量份的原料：甲醇10份、环烷酸铈7 份、多乙烯多胺5份、三硬脂酸甘油酯6份、纳米负载型活性炭2份、抗氧稳定剂1份、去离子水7份、N-甲基-二乙醇胺3份、2-乙二氧基乙酸乙酯5份、硝酸异丙酯7份、二甲基酮5份、二异丙醚6份、丙二酸乙酯1.5份。
其中，所述纳米负载型活性炭的制备方法为：20mL的钛酸正丁酯加入到40mL的无水乙醇中，升温至120℃搅拌均匀后，静置冷却至室温，加入5g的活性炭，再置于-9℃冰箱中冷却成凝胶状；-15℃超微粉碎得到粒径为40-45μm的纳米负载活性炭。
本实施例创新节约型尾气清洁剂的制备方法，包括以下步骤：
S1：将2-乙二氧基乙酸乙酯5份、三硬脂酸甘油酯6份、硝酸异丙酯7份、二甲基酮 5份、二异丙醚6份、丙二酸乙酯1.2份、纳米负载型活性炭2份依次加入反应釜中，混合搅拌形成调和物；
S2：将甲醇10份、环烷酸铈7份、多乙烯多胺5份加入反应釜中，60℃水浴加热2 小时后，静置降温，再加入去离子水7份、抗氧稳定剂1份、N-甲基-二乙醇胺3份浓缩至含水量小于2％，得到混合液；
S3：将调和物与混合液在常温下混合搅拌均匀，静置5-6h得到该清洁剂。
其中，步骤S1，反应釜设置为常温,40℃和常压，搅拌时间为5小时；所述步骤S2，釜内以0-60℃减压浓缩。
本发明的工作原理是：
实施例2
一种节能助燃汽车尾气汽油清洁剂，包括以下重量份的原料：甲醇15份、环烷酸铈10份、多乙烯多胺10份、三硬脂酸甘油酯18份、纳米负载型活性炭5份、抗氧稳定剂 1.5份、去离子水20份、N-甲基-二乙醇胺6份、2-乙二氧基乙酸乙酯8份、硝酸异丙酯 8份、二甲基酮5份、二异丙醚10份、丙二酸乙酯2份。
其中，所述纳米负载型活性炭的制备方法为：20mL的钛酸正丁酯加入到40mL的无水乙醇中，升温至120℃搅拌均匀后，静置冷却至室温，加入5g的活性炭，再置于-9℃冰箱中冷却成凝胶状；-15℃超微粉碎得到粒径为40-45μm的纳米负载活性炭。
本实施例创新节约型尾气清洁剂的制备方法，包括以下步骤：
S1：将2-乙二氧基乙酸乙酯8份、三硬脂酸甘油酯18份、硝酸异丙酯8份、二甲基酮5份、二异丙醚10份、丙二酸乙酯2份、纳米负载型活性炭份依次加入反应釜中，混合搅拌形成调和物；
S2：将甲醇15份、环烷酸铈10份、多乙烯多胺10份加入反应釜中，60℃水浴加热 2小时后，静置降温，再加入去离子水20份、抗氧稳定剂1.5份、N-甲基-二乙醇胺6份浓缩至含水量小于2％，得到混合液；
S3：将调和物与混合液在常温下混合搅拌均匀，静置5-6h得到该清洁剂。
其中，步骤S1，反应釜设置为常温,40℃和常压，搅拌时间为5小时；所述步骤S2，釜内以0-60℃减压浓缩。
本发明添加到汽油中混合使用，该种汽油清洁剂和汽油混合后燃烧过程中，够促进未燃烧充分的物质二次燃烧，提高燃料的利用率，也能够有效的降低油耗，提高汽油发动机的动力性能；同时降低燃油消耗气门表面积碳生成，降低二氧化碳的排放，减少大气污染。
以上所述，仅为本发明较佳的具体实施方式，但本发明的保护范围并不局限于此，任何熟悉本技术领域的技术人员在本发明揭露的技术范围内，根据本发明的技术方案及其发明构思加以等同替换或改变，都应涵盖在本发明的保护范围之内。

Claims (7)

1.一种创新节约型尾气清洁剂，其特征在于，包括以下重量份的原料：甲醇10-20份、环烷酸铈5-10份、多乙烯多胺2-13份、三硬脂酸甘油酯6-20份、纳米负载型活性炭2-6份、抗氧稳定剂0.5-1.5份、去离子水7-25份、N-甲基-二乙醇胺3-6份、2-乙二氧基乙酸乙酯3-8份、硝酸异丙酯3-10份、二甲基酮3-7份、二异丙醚6-15份、丙二酸乙酯1.5-3.5份。
2.根据权利要求1所述的一种创新节约型尾气清洁剂，其特征在于，所述纳米负载型活性炭的制备方法为：20mL的钛酸正丁酯加入到40mL的无水乙醇中，升温至120℃搅拌均匀后，静置冷却至室温，加入5g的活性炭，再置于-9℃冰箱中冷却成凝胶状；-15°C超微粉碎得到粒径为40-45μm的纳米负载活性炭。
3.根据权利要求1所述的一种创新节约型尾气清洁剂，其特征在于，所述抗氧稳定剂的制备方法为：将10g的4,4'-硫代双(6-叔丁基-3-甲基苯酚)粗晶体加入到20g的C6烷烃和5g低级醇的复合溶剂混合，升温至200℃溶解后，恒温搅拌十分钟，加入6g亚磷酸酯，继续搅拌十分钟，使亚磷酸酯对甲酚充分溶解后，静置冷却至室温。
4.根据权利要求1所述的一种创新节约型尾气清洁剂，其特征在于，所述N-甲基-二乙醇胺的制备方法为：将甲酸加入反应锅内加热至沸，在搅拌下滴加甲醛和二乙醇胺的混合液，约1h滴完，温度维持在90-98℃，继续回流4h。然后进行减压蒸馏，收集120-130℃(0.53kPa)馏分，即得N-甲基二乙醇胺。
5.一种创新节约型尾气清洁剂的制备方法，其特征在于，包括以下步骤：
S1：将2-乙二氧基乙酸乙酯份、三硬脂酸甘油酯份、硝酸异丙酯份、二甲基酮份、二异丙醚份、丙二酸乙酯份、纳米负载型活性炭份依次加入反应釜中，混合搅拌形成调和物；
S2：将甲醇份、环烷酸铈份、多乙烯多胺份加入反应釜中，60℃水浴加热2小时后，静置降温，再加入去离子水份、抗氧稳定剂份、N-甲基-二乙醇胺份浓缩至含水量小于2％，得到混合液；
S3：将调和物与混合液在常温下混合搅拌均匀，静置5-6h得到该清洁剂。
6.根据权利要求5所述的一种创新节约型尾气清洁剂的制备方法，其特征在于，所述步骤S1，反应釜设置为常温,40℃和常压，搅拌时间为5小时。
7.根据权利要求5所述的一种创新节约型尾气清洁剂的制备方法，其特征在于，所述步骤S2，釜内以0-60℃减压浓缩。
CN202110961821.1A 2021-08-20 2021-08-20 一种创新节约型尾气清洁剂及其制备方法 Pending CN114672350A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202110961821.1A CN114672350A (zh) 2021-08-20 2021-08-20 一种创新节约型尾气清洁剂及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202110961821.1A CN114672350A (zh) 2021-08-20 2021-08-20 一种创新节约型尾气清洁剂及其制备方法

Publications (1)

Publication Number Publication Date
CN114672350A true CN114672350A (zh) 2022-06-28

Family

ID=82069580

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202110961821.1A Pending CN114672350A (zh) 2021-08-20 2021-08-20 一种创新节约型尾气清洁剂及其制备方法

Country Status (1)

Country Link
CN (1) CN114672350A (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115651722A (zh) * 2022-10-20 2023-01-31 中再生新能源环保科技(新沂)有限公司 一种汽车尾气清洁剂及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB923190A (en) * 1961-04-11 1963-04-10 Ethyl Corp Antioxidant compositions
CN108949260A (zh) * 2018-07-24 2018-12-07 安徽绿色精灵新能源科技有限公司 一种节能助燃汽车尾气汽油清洁剂及其制备方法
CN109929614A (zh) * 2019-04-02 2019-06-25 刘云岭 一种尾气清洁剂的制备方法
CN110396441A (zh) * 2019-08-13 2019-11-01 吴爱林 一种尾气清洁剂

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB923190A (en) * 1961-04-11 1963-04-10 Ethyl Corp Antioxidant compositions
CN108949260A (zh) * 2018-07-24 2018-12-07 安徽绿色精灵新能源科技有限公司 一种节能助燃汽车尾气汽油清洁剂及其制备方法
CN109929614A (zh) * 2019-04-02 2019-06-25 刘云岭 一种尾气清洁剂的制备方法
CN110396441A (zh) * 2019-08-13 2019-11-01 吴爱林 一种尾气清洁剂

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
陈洛亮: "N-甲基二乙醇胺的合成研究" *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115651722A (zh) * 2022-10-20 2023-01-31 中再生新能源环保科技(新沂)有限公司 一种汽车尾气清洁剂及其制备方法

Similar Documents

Publication Publication Date Title
CN102527405A (zh) 一种高温合成气完全甲烷化催化剂及其制备方法
CN114672350A (zh) 一种创新节约型尾气清洁剂及其制备方法
CN107916147B (zh) 一种非金属汽油添加剂及其制备方法
CN107998824A (zh) 一种VOCs回收再利用处理工艺
CN104593106B (zh) 一种高清洁柴油添加剂及制备方法
CN106978224A (zh) 复合型柴油节能清净剂及其制备方法
CN101709234A (zh) 甲醇柴油复合添加剂及制备方法
CN110923024A (zh) 一种高清洁车用甲醇柴油
CN115232656B (zh) 一种醇基汽油燃料的制备方法
CN111471497B (zh) 一种用于压燃式发动机的清洁柴油
CN110373236B (zh) 一种稀土改性汽油添加剂及其制备方法
CN102093917B (zh) 一种可替代柴油的调和燃料油及其制备方法
CN108619907A (zh) 一种车用尿素还原剂溶液
CN105779042A (zh) 节油环保汽油品质提升剂及其制法和含其的汽油组合物
CN108395915A (zh) 一种基于非国标汽油组分的混合醚醇类清洁汽油
CN101220300A (zh) 一种甲醇柴油及其配制方法
CN110373235B (zh) 一种环保汽油添加剂及其制备方法
CN108395916A (zh) 一种基于国标柴油组分的混合醚酯类清洁柴油
CN108913232B (zh) 一种醇基燃料及其制备方法
CN112442397A (zh) 一种纳米金燃油添加剂及其制备方法
CN111472866B (zh) 一种抑制压燃式发动机内氮氧化物的抑制剂
CN109248698A (zh) 低温、抗硫型含磷铈铁锡复合脱硝催化剂及其制备方法
CN101220302B (zh) 一种甲醇汽油及其配制方法
CN116375494B (zh) 一种多孔陶瓷球材料及其制备方法和应用
CN109536217A (zh) 一种甲醇汽油及其制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20220628

WD01 Invention patent application deemed withdrawn after publication