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CN114669912B - Self-brazing composite alloy material for aluminum heat exchanger and intelligent preparation method thereof - Google Patents

Self-brazing composite alloy material for aluminum heat exchanger and intelligent preparation method thereof Download PDF

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CN114669912B
CN114669912B CN202210268295.5A CN202210268295A CN114669912B CN 114669912 B CN114669912 B CN 114669912B CN 202210268295 A CN202210268295 A CN 202210268295A CN 114669912 B CN114669912 B CN 114669912B
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CN114669912A (en
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姜之韬
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Jiangsu Grangis Heat Exchanger Co ltd
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Jiangsu Grangis Heat Exchanger Co ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/362Selection of compositions of fluxes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/40Making wire or rods for soldering or welding

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Abstract

The invention provides a self-brazing composite alloy material for an aluminum heat exchanger and an intelligent preparation method thereof, wherein the method comprises the following steps: a core material; the self-brazing alloy powder layer is positioned between the core material and the Al-Si alloy plate and/or between the Al-Si alloy plate and the Al-Si alloy plate, and comprises Al-Si alloy powder and Nocolok brazing flux powder; the core material, the self-brazing alloy powder layer and the Al-Si alloy plate are compounded into the self-brazing composite alloy material through hot rolling. According to the invention, the self-brazing alloy powder is distributed among the Al-Si alloy plates, and the Al-Si alloy plates, the self-brazing alloy powder and the core material are rolled and formed in one step by a hot rolling composite process, so that the self-brazing alloy powder is prevented from directly contacting with the roller to stick to the roller, the lubricating oil is not directly contacted with the self-brazing alloy powder, and the roller can be freely rolled in a lubricating state; and the Al-Si alloy plate can prevent the self-brazing alloy powder from being exposed in the air and being oxidized, and the subsequent rolling and brazing effects are influenced.

Description

Self-brazing composite alloy material for aluminum heat exchanger and intelligent preparation method thereof
Technical Field
The invention relates to the technical field of alloy plate brazing, in particular to a self-brazing composite alloy material for an aluminum heat exchanger and an intelligent preparation method thereof.
Background
The brazing is a welding process that a metal material with a melting point lower than that of a base metal is used as a brazing filler metal, the base metal is wetted by the liquid brazing filler metal, a gap between a workpiece interface is filled, and the brazing filler metal and the base metal are mutually diffused. Currently, the brazing filler metal used for aluminum alloy brazing is a noncorrosive brazing flux available under the trade name Nocolok. The brazing flux is a mixture of potassium fluoroaluminate with a general molecular formula of K1-3AlF4-6, and comprises the following components: 28-31% by weight of K, 16-18% by weight of Al, 49-53% by weight of F, 0.03% by weight of Fe, 0.02% by weight of Ca, 2.5% by weight of H2O; is white powder, the melting temperature is 560-570 ℃, the bulk density at 20 ℃ is 450-600 kg/m < 3 >, and the density is 2.8g/cm < 3 >.
In the aluminum alloy brazing process, the method of externally coating the brazing flux is divided into wet spraying and dry spraying according to the distribution range of the brazing flux particles, and the dosage of the brazing flux is generally 5-10 g/m < 2 >. When in use, the soldering flux is made into water suspension, then is sprayed on a workpiece, and is put into a furnace for brazing after being dried. The process is efficient and continuous, and has been widely applied to the brazing of various aluminum heat exchangers. However, with the continuous pursuit of high efficiency, low consumption, high quality and environmental friendliness in modern industrial production, the traditional external flux coating method has many problems, mainly including:
1) Before the brazing step, brazing flux is coated outside the surface of the workpiece, and then the workpiece is heated and dried, so that the process route is long;
2) The brazing flux particles are not uniform in size, so that the brazing flux sprayed on the surface of a weldment is not uniformly distributed, and the brazing quality is influenced;
3) In order to ensure that the brazing flux covers the whole heat exchanger, the brazing flux is generally coated excessively as much as possible, so that the brazing flux is wasted, and excessive brazing flux crystals exist on the surface of a brazed part, so that the appearance quality of a product is influenced, and the subsequent surface treatment of a weldment is also influenced;
4) After the soldering flux is sprayed, excessive soldering flux residues exist on the metal surface of the weldment, so that the service performance of a final product is influenced;
5) The flux is coated outside the surface mostly in a spraying mode, and powder and sewage in the production environment can cause environmental pollution and influence the physical and mental health of operators;
6) The process flow is long, so that the equipment investment is large, the production efficiency is reduced, and the final cost is increased.
Since the brazing method by coating flux has the above disadvantages, it is natural from the brazing method, that is, a method of previously placing flux in a brazing alloy. The piece is manufactured by spray forming, as described in patent CN 101674915A. The molten brazing aluminum alloy is sprayed and solidified with brazing flux under certain conditions to form a casting blank, then the casting blank is subjected to hot extrusion to form a plate, the plate is spliced and then subjected to hot rolling and composite rolling with a core material, and the subsequent processes are the same as those of the traditional composite material production method. As also described in EP0552567A1, a flux and Al-Si alloy powder are mixed together, the mixed powder is pressed into a blank of a certain shape at a very high temperature and pressure, then the blank is processed into a plate by hot extrusion, and then the plate is spliced and hot rolled with a core material, and the subsequent processes are the same as those of the conventional composite material production method. This method has the same problems as the above spray forming, and also has the defects of serious oxidation of Al-Si alloy powder, uneven distribution of flux, etc., and is difficult to be used for the production of actual products.
The technical problem can be solved if the self-brazing alloy powder and the core material can be directly subjected to one-step composite rolling forming. However, the direct one-step composite rolling forming of the self-brazing alloy powder and the core material by the conventional technology has the following technical difficulties:
1) During rolling, the self-brazing alloy powder can stick to a roller to cause rolling interruption;
2) If the roll is lubricated by lubricating oil, the lubricating oil can penetrate into the powder, so that the powder cannot be bonded, and the powder cannot be well deformed and bonded with the core material to form the composite plate.
Disclosure of Invention
The embodiment of the invention provides a self-brazing composite alloy material for an aluminum heat exchanger and an intelligent preparation method thereof, the production process flow is short, the investment is small, the cost is low, self-brazing alloy powder is directly compounded and rolled with a core material by taking an Al-Si alloy plate as a supporting carrier, the efficiency is high, the industrialization is easy, and the yield is high.
During rolling, the self-soldering alloy powder is isolated by the Al-Si alloy plate and cannot be in direct contact with the roller, so that the problem that the self-soldering alloy powder can stick to the roller to cause rolling interruption is solved, lubricating oil at the roller is isolated by the Al-Si alloy plate, the lubricating oil at the roller cannot directly flow to the self-soldering alloy powder, the self-soldering alloy powder layer is more stable, and the self-soldering alloy powder layer can be well deformed to be bonded with the core material to form the composite plate.
In a first aspect of embodiments of the present invention, there is provided a self-brazing composite alloy material for an aluminum heat exchanger, comprising:
a core material;
the self-brazing alloy powder layer is positioned between the core material and the Al-Si alloy plate and/or between the Al-Si alloy plate and the Al-Si alloy plate, and comprises Al-Si alloy powder and Nocolok brazing flux powder;
the core material, the self-brazing alloy powder layer and the Al-Si alloy plate are compounded into the self-brazing composite alloy material through hot rolling.
Optionally, in a possible implementation manner of the first aspect, the Nocolok flux powder content in the self-brazing alloy powder is 0.5 to 25% by mass, and the Nocolok flux powder is composed of the following raw materials by mass: k28-31%, al 16-18%, F49-53%, fe less than or equal to 0.03%, ca less than or equal to 0.02%, H 2 O≤2.5%。
Alternatively, in one possible implementation manner of the first aspect, the mass percentage of Si in each of the Al-Si alloy powder and the Al-Si alloy sheet is 4 to 13%.
In a second aspect of the embodiments of the present invention, there is provided an intelligent manufacturing method for manufacturing the self-brazing composite alloy material for an aluminum heat exchanger according to the first aspect, including:
acquiring scene data input by a user, wherein the scene data at least comprises heat exchange scene information, applicable temperature information and quality intensity information;
determining first quantity information and second quantity information of the Al-Si alloy plates hot-rolled at the upper surface and the lower surface of the core material based on the heat exchange scene information;
determining thickness information of the Al-Si alloy plates at the upper surface and the lower surface of the core material based on the applicable temperature information, and determining thickness information of a self-brazing alloy powder layer and proportion information of Si elements in the self-brazing alloy powder according to the thickness information of the Al-Si alloy plates;
correcting the first quantity information, the second quantity information, the thickness information of the Al-Si alloy plate, the thickness information of the self-brazing alloy powder layer and the proportion information of the Si element on the basis of the quality intensity information;
and selecting corresponding materials to generate the target self-brazing composite alloy material through hot rolling compounding based on the corrected first quantity information, second quantity information, thickness information of the Al-Si alloy plate, thickness information of the self-brazing alloy powder layer and proportion information of the Si element.
Optionally, in one possible implementation manner of the second aspect, determining the first quantity information and the second quantity information of the Al-si alloy sheets hot-rolled at the upper surface and the lower surface of the core material based on the heat exchange scenario information includes:
the heat exchange scene information comprises the property of a heat conduction medium, the heat exchange length and the heat exchange width which are respectively contacted with the upper surface and the lower surface of the alloy material, and the property of the heat conduction medium comprises any one of gas or liquid;
if the heat transfer medium of the upper surface and the lower surface is a gas, the first quantity information and the second quantity information are calculated by the following formula,
Figure GDA0004042605790000041
wherein s is 1 Is a first quantity of information, s 2 As second quantity information, k Qi (Qi) The weight value of the gas is set as the weight value of the gas,
Figure GDA0004042605790000042
first length weight value,/ 1 For the length of the heat exchange,/ Base (C) Length reference value->
Figure GDA0004042605790000043
Is a first width weight value, d 1 Is a first heat exchange width, d Base (C) Based on a width reference value>
Figure GDA0004042605790000044
Is a second length weight value>
Figure GDA0004042605790000045
A second width weight value;
if the heat transfer medium of the upper and lower surfaces is liquid, the first quantity information and the second quantity information are calculated by the following formulas,
Figure GDA0004042605790000051
wherein k is Liquid for treating urinary tract infection Is the liquid weight.
Optionally, in a possible implementation manner of the first aspect, the method further includes:
if the obtained first quantity information and/or second quantity information is not an integer, acquiring an integer which is larger than the first quantity information and/or second quantity information and is closest to the first quantity information and/or second quantity information as the adjusted first quantity information and/or second quantity information.
Optionally, in a possible implementation manner of the second aspect, the method further includes:
receiving third quantity information and/or fourth quantity information input by a user, wherein the third quantity information is the number of layers of the Al-Si alloy plate on the upper surface actually determined by the user, and the fourth quantity information is the number of layers of the Al-Si alloy plate on the lower surface actually determined by the user;
updating the gas weight value and/or the liquid weight value based on third quantity information and/or fourth quantity information input by a user;
the gas weight and/or liquid weight is updated by the following formula,
Figure GDA0004042605790000052
wherein, K Qi (Qi) To updated gas weight, K Liquid for treating urinary tract infection To updated liquid weight, b 1 As gas renewal coefficient, c 1 For gas update of weight, b 2 For updating the coefficient for the liquid, c 2 The weight is updated for the liquid.
Optionally, in one possible implementation manner of the second aspect, determining thickness information of al-si alloy plates at the upper surface and the lower surface of the core material based on the applicable temperature information, and determining thickness information of the self-brazing alloy powder layer and proportion information of the si element in the self-brazing alloy powder according to the thickness information of the al-si alloy plates includes:
determining thickness information of the Al-Si alloy plate based on the upper temperature limit value and the lower temperature limit value which are included in the applicable temperature information, and determining thickness information of a self-soldering alloy powder layer and proportion information of Si elements in the self-soldering alloy powder according to the thickness information of the Al-Si alloy plate;
the thickness information of the Al-Si alloy plate, the thickness information of the self-brazing alloy powder layer and the proportion information of the Si element are calculated by the following formulas,
Figure GDA0004042605790000061
wherein h is 1 Is thickness information of Al-Si alloy plate, u temperature weighted value, i is temperature conversion value, j 1 Is an upper limit value of temperature, j 2 The lower limit value of the temperature is,
Figure GDA0004042605790000062
is the base thickness value, h, of the Al-Si alloy sheet 2 For the thickness information of the self-brazing alloy powder layer, z is a preset proportion value>
Figure GDA0004042605790000063
The value is the basic thickness value of the self-brazing alloy powder layer, R is the proportion information of the Si element in the self-brazing alloy powder layer, and R is the preset proportion information of the Si element in the self-brazing alloy powder layer.
Optionally, in one possible implementation manner of the second aspect, the correcting the first quantity information, the second quantity information, the thickness information of the Al-si alloy plate, the thickness information of the self-brazing alloy powder layer, and the proportion information of the si element based on the mass strength information includes:
presetting a quality intensity comparison table, wherein the quality intensity comparison table comprises a plurality of intensity threshold intervals and an intensity coefficient corresponding to each intensity threshold interval;
traversing an intensity threshold interval in a quality intensity comparison table, and acquiring an intensity threshold interval corresponding to the quality intensity information and a corresponding intensity coefficient;
correcting the first quantity information, the second quantity information, the thickness information of the Al-Si alloy plate, the thickness information of the self-brazing alloy powder layer and the proportion information of the Si element on the basis of the strength coefficient;
the first quantity information, the second quantity information, the thickness information of the Al-Si alloy plate, the thickness information of the self-brazing alloy powder layer and the proportion information of the Si element are corrected by the following formulas,
Figure GDA0004042605790000071
wherein, y 1 For the corrected first quantity information, x 1 Is a first correction weight, X is an intensity coefficient, y 2 For the corrected second quantity information, x 2 Is the second modified weight, y 3 For the thickness information of the corrected Al-Si alloy plate, x 3 Is the third correction weight, y 4 For thickness information of the corrected self-brazing alloy powder layer, x 4 Is the fourth correction weight, y 5 For the corrected Si element ratio information, x 5 Is a fifth correction weight.
Optionally, in a possible implementation manner of the second aspect, the method further includes:
and generating a basic manufacturing table based on the corrected first quantity information, second quantity information, thickness information of the Al-Si alloy plate, thickness information of the self-brazing alloy powder layer and proportion information of the Si element, and displaying the basic manufacturing table.
A third aspect of the embodiments of the present invention provides a readable storage medium, in which a computer program is stored, and the computer program is used for implementing the method of the first aspect and various possible designs of the first aspect of the present invention when executed by a processor.
The invention provides a self-brazing composite alloy material for an aluminum heat exchanger and an intelligent preparation method thereof. The self-brazing alloy powder is distributed among the Al-Si alloy plates, and the Al-Si alloy plates, the self-brazing alloy powder and the core material are rolled and formed in one step through a hot rolling composite process, so that the self-brazing alloy powder is prevented from directly contacting with a roller to stick to the roller, lubricating oil is prevented from directly contacting with the self-brazing alloy powder, and the roller can be rolled freely in a lubricating state; and the Al-Si alloy plate can prevent the self-brazing alloy powder from being exposed in the air and being oxidized, and the subsequent rolling and brazing effects are influenced.
According to the technical scheme provided by the invention, the number of the Al-Si alloy plates hot-rolled on the upper surface and the lower surface of the core material can be obtained according to scene data input by a user, and is determined according to the property of the heat transfer medium respectively contacted with the upper surface and the lower surface of the alloy material, the heat exchange length and the heat exchange width, so that the number of the Al-Si alloy plates hot-rolled on the upper surface and the lower surface is suitable for the heat exchange scene of the material, and the stability of an aluminum heat exchanger made of the self-brazing composite alloy material in use is ensured. According to the technical scheme provided by the invention, different numbers of layer structures can be arranged according to different heat transfer media of the aluminum heat exchanger in the using process, so that the purpose and the effect of custom-producing the self-brazing composite alloy material according to an application scene are realized.
According to the technical scheme provided by the invention, the gas weight value and/or the liquid weight value can be updated according to the third quantity information and/or the fourth quantity information input by the user, so that the calculation formula and the algorithm provided by the invention can be continuously updated and iterated in an active learning manner, and the accuracy of the first quantity information and/or the second quantity information in the calculation process is further ensured.
According to the technical scheme provided by the invention, the thickness of the Al-Si alloy plate, the thickness of the self-brazing alloy powder layer and the proportion of the Si element can be determined according to different temperatures of a use scene, so that the self-brazing composite alloy material manufactured by the invention can ensure the stability at corresponding temperatures, the waste caused by excessive material use can be avoided on the premise of ensuring the stability of the aluminum heat exchanger manufactured by the invention, and the advantages and effects of energy conservation and emission reduction are achieved.
Drawings
FIG. 1A is a schematic layer structure diagram of a first embodiment of a self-brazing composite alloy material;
FIG. 1B is a cross-sectional view of the layer structure of the first embodiment of the self-brazing composite alloy material;
FIG. 1C is a schematic view of a layer structure of a second embodiment of a self-brazing composite alloy material;
FIG. 1D is a schematic layer structure diagram of a third embodiment of a self-brazing composite alloy material;
FIG. 1E is a schematic layer structure diagram of a fourth embodiment of a self-brazing composite alloy material;
FIG. 2A is a flow chart of a first embodiment of an intelligent manufacturing process;
FIG. 2B is a flow chart of a second embodiment of an intelligent manufacturing method.
Reference numerals:
1. a core material; 2. an Al-Si alloy plate; 3. self-brazing the alloy powder layer.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The terms "first," "second," "third," "fourth," and the like in the description and in the claims, as well as in the drawings, if any, are used for distinguishing between similar elements and not necessarily for describing a particular sequential or chronological order. It is to be understood that the data so used is interchangeable under appropriate circumstances such that the embodiments of the invention described herein are capable of operation in sequences other than those illustrated or described herein.
It should be understood that, in various embodiments of the present invention, the sequence numbers of the processes do not mean the execution sequence, and the execution sequence of the processes should be determined by the functions and the internal logic of the processes, and should not constitute any limitation on the implementation process of the embodiments of the present invention.
It should be understood that in the present application, "comprising" and "having" and any variations thereof, are intended to cover a non-exclusive inclusion, such that a process, method, system, article, or apparatus that comprises a list of steps or elements is not necessarily limited to those steps or elements expressly listed, but may include other steps or elements not expressly listed or inherent to such process, method, article, or apparatus.
It should be understood that, in the present invention, "a plurality" means two or more. "and/or" is merely an association describing an associated object, meaning that three relationships may exist, e.g., a and/or B, may mean: a exists alone, A and B exist simultaneously, and B exists alone. The character "/" generally indicates that the former and latter associated objects are in an "or" relationship. "comprising a, B and C", "comprising a, B, C" means that all three of a, B, C are comprised, "comprising a, B or C" means comprising one of a, B, C, "comprising a, B and/or C" means comprising any 1 or any 2 or 3 of a, B, C.
It should be understood that in the present invention, "B corresponding to a", "a corresponds to B", or "B corresponds to a" means that B is associated with a, and B can be determined from a. Determining B from a does not mean determining B from a alone, but may also be determined from a and/or other information. And the matching of A and B means that the similarity of A and B is greater than or equal to a preset threshold value.
As used herein, "if" may be interpreted as "at \8230; \8230when" or "when 8230; \8230when" or "in response to a determination" or "in response to a detection", depending on the context.
The technical solution of the present invention will be described in detail below with specific examples. These several specific embodiments may be combined with each other below, and details of the same or similar concepts or processes may not be repeated in some embodiments.
The present invention provides a self-brazing composite alloy material for an aluminum heat exchanger, as shown in fig. 1A and 1B, comprising:
a core material;
the self-brazing alloy powder layer is positioned between the core material and the Al-Si alloy plate and/or between the Al-Si alloy plate and the Al-Si alloy plate, and comprises Al-Si alloy powder and Nocolok brazing flux powder;
the core material, the self-brazing alloy powder layer and the Al-Si alloy plate are compounded into the self-brazing composite alloy material through hot rolling.
The technical scheme provided by the invention comprises a core material and a self-brazing alloy layer directly compounded and rolled on the upper surface and/or the lower surface of the core material, wherein the self-brazing alloy layer comprises an Al-Si alloy plate and self-brazing alloy powder uniformly distributed between two adjacent Al-Si alloy plates, and the self-brazing alloy powder consists of Al-Si alloy powder and Nocolok brazing flux powder. The self-brazing composite alloy material is formed by directly hot rolling and compounding a self-brazing alloy layer and a core material.
Fig. 1 and 1B are only the first embodiment of the technical solution provided by the present invention in the implementation process.
In one possible embodiment, the Nocolok brazing flux powder in the self-brazing alloy powder is 0.5-25% by mass, and consists of the following raw materials in percentage by mass: 28 to 31 percent of K,16 to 18 percent of Al,49 to 53 percent of F, less than or equal to 0.03 percent of Fe, less than or equal to 0.02 percent of Ca, and H 2 O≤2.5%。
In one possible embodiment, the mass percentage of Si in both the Al-Si alloy powder and the Al-Si alloy sheet is 4 to 13%.
According to the invention, the self-brazing alloy powder is distributed in the middle of the Al-Si alloy plate, the self-brazing alloy powder and the core material are rolled and formed in one step by a hot rolling composite process, the self-brazing alloy powder is isolated from the roller by the Al-Si alloy plate, so that the self-brazing alloy powder is prevented from directly contacting with the roller to stick to the roller, lubricating oil is prevented from directly contacting with the self-brazing alloy powder, the roller can be rolled freely in a lubricating state, and the normal and continuous operation of a rolling process is ensured; and the Al-Si alloy plate can prevent the self-brazing alloy powder from being exposed in the air and being oxidized, and the subsequent rolling and brazing effects are influenced.
The total amount of flux, the total content of Si element in the self-brazing alloy powder is determined according to the final product thickness and the use conditions. (in the following examples, products with different thickness requirements in different occasions need to be exemplified) when the total thickness required by the self-brazing alloy powder is larger, the self-brazing alloy powder is divided into a plurality of layers according to the principle that the thickness of each layer of self-brazing alloy powder does not exceed 20mm, and the layers are separated by Al-Si alloy plates with the thickness of not more than 10mm, so that the aim of one-step rolling forming is fulfilled.
The method of the invention completely omits the procedures of external coating of brazing flux and drying in the traditional brazing process, overcomes a series of technical defects of the traditional brazing process, reduces the equipment investment, greatly reduces the production cost, simultaneously improves the production efficiency and the brazing quality and improves the production environment of products by a short-flow composite rolling processing process. In addition, the invention omits a plurality of complex procedures of the traditional process, has high yield and is easy for industrialization.
Generally, the aluminum heat exchanger comprises a radiator, an oil cooler, a condenser, an evaporator, a intercooler and the like, and can ensure brazing connection in inert gas or vacuum atmosphere without adding brazing flux additionally; the composite alloy material can be simultaneously suitable for vacuum brazing and protective gas atmosphere brazing, and the flexibility and the uniformity of the use of the material are improved; the self-brazing alloy with a multilayer structure is adopted, so that the content of the brazing flux can be conveniently and flexibly adjusted in the manufacturing process, the brazing flux which is uniformly distributed in a proper amount can be fully utilized, the quality of a weldment is more reliable and stable, the brazing qualification rate is high, the surface of the weldment is bright and smooth, and the subsequent surface treatment is easy.
In general, the manufacture of the self-brazing composite alloy material provided by the present invention requires two steps, including:
step (1), preparing a self-brazing alloy layer:
weighing Al-Si alloy powder and Nocolok brazing flux powder according to a formula, fully and uniformly mixing to obtain self-brazing alloy powder, and uniformly paving the self-brazing alloy powder between two adjacent layers of Al-Si alloy plates at normal temperature to obtain a brazing alloy layer;
step (2), hot rolling and compounding:
and (2) combining or welding and fixing the self-brazing alloy layer obtained in the step (1) with the core material ingot according to the single-sided or double-sided process requirements, then feeding the self-brazing alloy layer and the core material ingot into a heating furnace for heating, discharging the self-brazing alloy layer from the furnace after heating to a certain temperature, directly performing hot rolling and compounding, and finally rolling the self-brazing alloy layer and the core material ingot into a hot rolled coil with a certain thickness.
And (2) rolling the self-brazing alloy powder in the step (1) in a mould in advance to obtain a self-brazing alloy powder cake with a specified thickness, and placing the self-brazing alloy powder cake between two adjacent layers of Al-Si alloy plates.
In a second embodiment of the self-brazing composite alloy material, the structure may be as shown in FIG. 1C.
(1) Preparing self-brazing alloy powder:
the Nocolok brazing flux powder consists of the following raw materials in percentage by mass: 28% K,17% Al,53% F ≦ 0.03 ≦ 0.02 ≦ Ca, the balance H 2 O; and fully and uniformly mixing 0.5 mass percent of Nocolok brazing flux powder and 99.5 mass percent of Al-Si alloy powder containing 4 mass percent of Si to obtain self-brazing alloy powder 3.
Wherein the Al-Si alloy powder comprises the following components in percentage by mass:
Al Si Fe Cu Mn Mg Ti Zn
95.779 4 0.15 0.003 0.05 0.001 0.002 0.015
(2) Preparing a self-brazing alloy layer:
flatly paving the self-brazing alloy powder 3 obtained in the step (1) between three layers of Al-Si alloy plates 2 in two layers, wherein the thickness of each layer of self-brazing alloy powder 3 is 20mm; the thickness of each layer of Al-Si alloy plate 2 is 10mm, and a self-brazing alloy layer is obtained;
(3) Casting the core material 1 by DC cast metal, in the embodiment, AA3003 series alloy is selected as the core material 1, and the alloy components can be adjusted correspondingly according to the final requirements of the product; compounding the self-brazing alloy layer obtained in the step (2) with one surface of a core material 1 cast ingot with the thickness of 350mm, feeding the composite into a furnace, heating to 490 ℃, and preserving heat for 2 hours;
(4) Hot rolling and compounding: the thickness of the hot-rolled blank is 8mm;
(5) Cold rolling: cold rolling to 2.5mm by 3 passes;
(6) Annealing of a finished product: the annealing temperature of the finished product is 380 ℃, the heat preservation time is 1.5 hours, the single-side composite self-brazing composite alloy material is obtained, and the single-side composite self-brazing composite alloy material is respectively brazed in vacuum brazing and nitrogen protective atmosphere, so that the brazing joint is full, and the surface is smooth and bright.
In a second embodiment of the self-brazing composite alloy material, the structure may be as shown in FIG. 1D.
(1) Preparing self-brazing alloy powder:
the Nocolok brazing flux powder consists of the following raw materials in percentage by mass: 31% K,18% Al,49% F, less than or equal to 0.03% Fe, less than or equal to 0.02% Ca, the balance H 2 O; and fully and uniformly mixing 10 mass percent of Nocolok brazing flux powder and 90 mass percent of Al-Si alloy powder containing 10.5 mass percent of Si to obtain self-brazing alloy powder 3.
Wherein the Al-Si alloy powder comprises the following components in percentage by mass:
Al Si Fe Cu Mn Mg Ti Zn
89.279 10.5 0.15 0.003 0.05 0.001 0.002 0.015
(2) Preparing a self-brazing alloy layer:
flatly paving the self-brazing alloy powder 3 obtained in the step (1) among four layers of Al-Si alloy plates 2 in three layers, wherein the thickness of each layer of self-brazing alloy powder 3 is 15mm; the thickness of each layer of Al-Si alloy plate 2 is 5mm, and a self-brazing alloy layer is obtained;
(3) Casting the core material 1 by using a DC cast metal method, wherein in the embodiment, AA3003 series alloy is selected as the core material 1, and the alloy components can be correspondingly adjusted according to the final requirements of products; compounding the self-brazing alloy layer obtained in the step (2) with one surface of a core material 1 cast ingot with the thickness of 440mm, feeding the composite ingot into a furnace, heating the composite ingot to 500 ℃, and preserving heat for 2 hours;
(4) Hot rolling and compounding: the thickness of the hot-rolled blank is 8mm;
(5) Cold rolling: cold rolling to 0.2mm after 7 passes;
(6) Annealing of a finished product: the annealing temperature of the finished product is 400 ℃, the heat preservation time is 1.5 hours, the single-side composite self-brazing composite alloy material is obtained, and the single-side composite self-brazing composite alloy material is respectively brazed in vacuum brazing and nitrogen protective atmosphere, so that the brazing joint is full, and the surface is smooth and bright.
In a second embodiment of the self-brazing composite alloy material, the structure may be as shown in FIG. 1E.
(1) Preparing self-brazing alloy powder:
the Nocolok brazing flux powder consists of the following raw materials in percentage by mass: 30% K,18% Al,50% F ≦ 0.03% Fe ≦ 0.02% Ca, the balance H 2 O; and fully and uniformly mixing 25 mass percent of Nocolok brazing flux powder and 75 mass percent of Al-Si alloy powder containing 13 mass percent of Si, and pressing the mixture into a powder cake in a mould to obtain the self-brazing alloy powder cake 3.
Wherein the Al-Si alloy powder comprises the following components in percentage by mass:
Al Si Fe Cu Mn Mg Ti Zn
86.842 13 0.11 0.003 0.03 0.001 0.002 0.012
(2) Preparing a self-brazing alloy layer:
placing the self-brazing alloy powder cake 3 obtained in the step (1) between two layers of Al-Si alloy plates 2, wherein the thickness of the self-brazing alloy powder cake 3 is 10mm; the thickness of each layer of Al-Si alloy plate 2 is 6mm, and a self-brazing alloy layer is obtained;
(3) Casting the core material 1 by using a DC cast metal method, wherein in the embodiment, AA3003 series alloy is selected as the core material 1, and the alloy components can be correspondingly adjusted according to the final requirements of products; compounding the self-brazing alloy layer obtained in the step (2) with two surfaces of a core material 1 cast ingot with the thickness of 440mm, feeding the composite ingot into a furnace, heating the composite ingot to 500 ℃, and preserving heat for 2 hours;
(4) Hot rolling and compounding: the thickness of the hot-rolled blank is 8mm;
(5) Cold rolling: cold rolling to 0.6mm through 5 passes;
(6) Annealing of a finished product: the annealing temperature of the finished product is 380 ℃, the heat preservation time is 1.5 hours, the self-brazing composite alloy material with double composite surfaces is obtained, and the self-brazing composite alloy material is respectively brazed in vacuum brazing and nitrogen protective atmosphere, so that the brazing joint is full, and the surface is smooth and bright.
The technical solution provided by the present invention further provides an intelligent preparation method, for preparing the self-brazing composite alloy material for an aluminum heat exchanger, as shown in fig. 2A, including:
step S110, scene data input by a user are obtained, and the scene data at least comprise heat exchange scene information, applicable temperature information and quality intensity information. According to the technical scheme provided by the invention, a user can input corresponding scene data according to the actual use scene of the aluminum heat exchanger prepared according to the requirement.
Generally, in an aluminum heat exchanger, a heat exchange medium is generally in a liquid or gaseous state, and several forms of heat exchange may occur, such as liquid-to-liquid, gas-to-gas, gas-to-liquid, and the like. In the use process of different aluminum heat exchangers, the different scenes of the aluminum heat exchangers cause different applicable temperature information, for example, the temperature of the aluminum heat exchanger in an air conditioner is generally below 100 ℃. However, in the scenario of flue gas heat recovery and the like, the temperature of the flue gas may be hundreds of degrees, so that the use temperature may be different in different use scenarios, and the possible uses of the heat exchanger are different, and when the heat exchanger is used as a home, the heat exchanger may be required to reach the national standard.
Therefore, the invention can receive the heat exchange scene information, the applicable temperature information and the quality intensity information which are actively input by the user through the interactive interface.
Step S120, determining first quantity information and second quantity information of the Al-Si alloy plates hot-rolled at the upper surface and the lower surface of the core material based on the heat exchange scene information. According to the technical scheme provided by the invention, the first quantity information and the second quantity information of the hot-rolled Al-Si alloy plate can be obtained according to the heat exchange scene information, the first quantity information and the second quantity information can be 0 or a plurality of information, and when the first quantity information and the second quantity information are larger, the more Al-Si alloy plates on the upper surface and the lower surface of the core material are proved, generally, the more Al-Si alloy plates are, the more stable self-brazing composite alloy material is, and the less damage is caused, but the corresponding material cost and manufacturing cost are also correspondingly improved.
In the technical solution provided by the present invention, step S120 specifically includes:
the heat exchange scene information includes heat conduction medium properties, a heat exchange length and a heat exchange width, which are respectively contacted with the upper surface and the lower surface of the alloy material, and the heat conduction medium properties include any one of gas or liquid. For example, when industrial flue gas is subjected to heat recovery, the properties of the heat transfer media respectively contacting the upper surface and the lower surface of the heat exchange scene information at the time are respectively gas and liquid, that is, the upper surface of an aluminum heat exchanger made of a brazing composite alloy material contacts with the flue gas, and the lower surface of the aluminum heat exchanger contacts with heat transfer oil, generally speaking, the corrosivity of the flue gas is higher than that of the heat transfer oil. The heat exchange length and the heat exchange width can be determined according to the volume of the aluminum heat exchanger, and different industrial scales can have different specifications of the aluminum heat exchanger, so the heat exchange length and the heat exchange width are determined according to practical situations, and generally speaking, when the volume of the aluminum heat exchanger is larger, the force applied to the aluminum heat exchanger is larger, and the aluminum heat exchanger is relatively unstable.
If the heat transfer medium of the upper surface and the lower surface is a gas, the first quantity information and the second quantity information are calculated by the following formula,
Figure GDA0004042605790000161
wherein s is 1 Is a first quantity of information, s 2 As second quantity information, k Qi (Qi) The weight value of the gas is set as the weight value of the gas,
Figure GDA0004042605790000162
first length weight value,/ 1 For the length of the heat exchange,/ Base of Length reference value->
Figure GDA0004042605790000163
Is a first width weight value, d 1 Is a first heat exchange width, d Base of Is a width reference value>
Figure GDA0004042605790000164
Is a second length weight value>
Figure GDA0004042605790000165
A second width weight value;
if the heat transfer medium of the upper surface and the lower surface is liquid, the first quantity information and the second quantity information are calculated by the following formula,
Figure GDA0004042605790000166
wherein k is Liquid for treating urinary tract infection Is the liquid weight.
According to the technical scheme provided by the invention, when the first quantity information and the second quantity information of the upper surface and the lower surface are calculated, different calculation formulas and algorithms are adopted according to different heat transfer media, and the gas weight value is generally greater than the liquid weight value because the corrosivity of gas is higher than that of liquid. Taking the heat transfer medium on the upper and lower surfaces as a gas as an example, the longer the length of the aluminum heat exchanger
Figure GDA0004042605790000167
The larger and->
Figure GDA0004042605790000168
The larger, the greater the width of the aluminum heat exchanger>
Figure GDA0004042605790000169
And->
Figure GDA00040426057900001610
The larger. First length weight value/>
Figure GDA00040426057900001611
Is typically greater than a second length weight value>
Figure GDA00040426057900001612
The first width weight->
Figure GDA00040426057900001613
Is generally greater than the second width weight value>
Figure GDA00040426057900001614
Since the aluminum heat exchanger is likely to be manufactured as a cylinder during the manufacturing process, the upper surface forms the outer surface of the cylinder, the lower surface forms the inner surface of the cylinder, the contact area of the outer surface is larger, and the extension requirement of the outer surface is higher during the manufacturing process, the corresponding weight needs to be increased to increase the corresponding first quantity information.
The technical scheme provided by the invention further comprises the following steps:
if the obtained first quantity information and/or the obtained second quantity information are not integers, the integers which are larger than the first quantity information and/or the second quantity information and are closest to the first quantity information and/or the second quantity information are obtained to be used as the adjusted first quantity information and/or the adjusted second quantity information. When the first quantity information and the second quantity information are calculated, the first quantity information and/or the second quantity information may not be integers, so that the invention selects an integer which is larger than the first quantity information and/or the second quantity information and is closest to the first quantity information and/or the second quantity information as the adjusted first quantity information and/or second quantity information, for example, if the first quantity information is 1.7, the adjusted first quantity information is 2. In this case, 2 Al-Si alloy sheets are present.
The technical scheme provided by the invention further comprises the following steps:
receiving third quantity information and/or fourth quantity information input by a user, wherein the third quantity information is the number of layers of the Al-Si alloy plate on the upper surface actually determined by the user, and the fourth quantity information is the number of layers of the Al-Si alloy plate on the lower surface actually determined by the user.
Updating the gas weight value and/or the liquid weight value based on third quantity information and/or fourth quantity information input by a user. According to the technical scheme provided by the invention, the first quantity information and/or the second quantity information of the upper surface and the lower surface are/is displayed through the display device, if the user thinks that the first quantity information and/or the second quantity information output at the moment are/is not suitable for the current scene, the user can actively input corresponding third quantity information and/or fourth quantity information at the moment, and the gas weight value and/or the liquid weight value are/is updated according to the relation between the corresponding third quantity information and/or fourth quantity information and the first quantity information and/or the second quantity information which are/is actively input by the user, so that the gas weight value and/or the liquid weight value which are/is more suitable for the current scene are/is obtained.
The gas weight and/or liquid weight is updated by the following equations,
Figure GDA0004042605790000181
wherein, K Qi (Qi) To updated gas weight, K Liquid for medical purpose To updated liquid weight, b 1 As gas renewal coefficient, c 1 For gas update of weight, b 2 For the liquid update coefficient, c 2 The weight is updated for the liquid.
The technical scheme provided by the invention s 1 -s 3 、s 2 -s 4 The larger the difference between the first quantity information/the second quantity information calculated by the invention and the first quantity information/the second quantity information input by the user is, the larger the difference is, so the updated gas weight value K at the moment Qi (Qi) Weight k compared to gas before update Qi (Qi) The greater the change. Same principle s 1 -s 3 、s 2 -s 4 The larger the liquid weight value K is, the more updated the liquid weight value K is Liquid for medical purpose Weight value K compared with liquid before update Liquid for treating urinary tract infection The greater the change. Wherein, qiThe volume update weight and the liquid update weight are preferably odd numbers, such that
Figure GDA0004042605790000182
And &>
Figure GDA0004042605790000183
And &>
Figure GDA0004042605790000184
And
Figure GDA0004042605790000185
the positive and negative values between the two are the same. And further, the purpose of updating the gas weight value and the liquid weight value according to the quantity relation between the first quantity information/the second quantity information and the third quantity information/the fourth quantity information is achieved.
And S130, determining the thickness information of the Al-Si alloy plates at the upper surface and the lower surface of the core material based on the applicable temperature information, and determining the thickness information of the self-soldering alloy powder layer and the proportion information of the Si element in the self-soldering alloy powder according to the thickness information of the Al-Si alloy plates. According to the technical scheme provided by the invention, the thickness information of the Al-Si alloy plate at the upper surface and the lower surface of the core material is determined according to the using temperature information of the aluminum heat exchanger, the numerical value corresponding to the thickness information of the Al-Si alloy plate is larger when the using temperature information of the aluminum heat exchanger is higher, and the numerical value corresponding to the thickness information of the Al-Si alloy plate is smaller when the using temperature information of the aluminum heat exchanger is lower. The thickness information of the self-brazing alloy powder layer can be determined according to the thickness information of the Al-Si alloy plate, and when the thickness information of the Al-Si alloy plate is thicker, the required adhesive force between the Al-Si alloy plate and the core material, and between the Al-Si alloy plate and the Al-Si alloy plate is larger, and the thickness corresponding to the thickness information of the self-brazing alloy powder layer is thicker. The proportion of the Si element in the self-brazing alloy powder can reflect the adhesive force from the brazing alloy powder layer, and the larger the proportion of the Si element, the larger the adhesive force from the brazing alloy powder layer.
The thickness information of the Al — Si alloy plate at the upper surface and the lower surface of the core material can be determined from the applied temperature information, and generally, the higher the temperature, the higher the corrosiveness and the oxidizability of the flue gas and the liquid, the thicker the thickness corresponding to the thickness information of the Al — Si alloy plate should be. When the thickness information of the Al-Si alloy plate is thicker, the required fixing force and the required adhesive force are larger, so that the thickness information of the corresponding self-brazing alloy powder layer and the proportion information of the Si element in the self-brazing alloy powder are larger, and the thickness of the Al-Si alloy plate, the thickness of the self-brazing alloy powder layer and the proportion of the Si element can be determined according to different temperature use scenes.
In the technical solution provided by the present invention, step S130 specifically includes:
and determining thickness information of the Al-Si alloy plate based on the upper temperature limit value and the lower temperature limit value which are included in the applicable temperature information, and determining thickness information of the self-brazing alloy powder layer and proportion information of Si elements in the self-brazing alloy powder according to the thickness information of the Al-Si alloy plate. For example, the self-brazing composite alloy material is suitable for a heat exchange scene of flue gas and heat conduction oil, when heat exchange is carried out, the highest temperature of the flue gas is 280 ℃, the lowest temperature of the heat conduction oil is 200 ℃, the upper limit value of the temperature is 280 ℃, and the lower limit value of the temperature is 200 ℃.
The thickness information of the Al-Si alloy plate, the thickness information of the self-brazing alloy powder layer and the proportion information of the Si element are calculated by the following formulas,
Figure GDA0004042605790000201
wherein h is 1 Is thickness information of Al-Si alloy plate, u temperature weighted value, i is temperature conversion value, j 1 Is an upper limit value of temperature, j 2 The lower limit value of the temperature is,
Figure GDA0004042605790000202
is the base thickness value, h, of the Al-Si alloy sheet 2 For self-soldering the thickness of the alloy powder layerInformation, z preset ratio value, <' >>
Figure GDA0004042605790000203
The method comprises the following steps of obtaining a basic thickness value of a self-brazing alloy powder layer, obtaining R proportion information of the Si element in the self-brazing alloy powder layer, and obtaining R preset proportion information of the Si element in the self-brazing alloy powder layer.
By passing
Figure GDA0004042605790000204
An average temperature value between an upper temperature limit value and a lower temperature limit value can be obtained, a temperature conversion value i is used for converting the average temperature value, so that the converted value can be used for calculating the thickness, and a temperature weight value can be preset and is based on the value of the temperature>
Figure GDA0004042605790000205
Can be a preset constant value when->
Figure GDA0004042605790000206
The larger the thickness information of the Al-Si alloy plate is, the larger the thickness information is. Since the thickness information of the self-brazing alloy powder layer is positively correlated with the thickness information of the Al-Si alloy plate, the thickness information of the self-brazing alloy powder layer increases as the thickness information of the Al-Si alloy plate increases, and the base thickness value ^ based on the thickness information of the self-brazing alloy powder layer>
Figure GDA0004042605790000207
Can be preset, base thickness value +>
Figure GDA0004042605790000208
May be a minimum base value and the temperature weight value may be a value less than 1. By>
Figure GDA0004042605790000209
The thickness information of the corresponding self-brazing alloy powder layer can be obtained, and the larger the thickness information of the self-brazing alloy powder layer is, the larger the corresponding annual requirement of the user is, so that at the momentThe ratio of the si element in the self-brazing alloy powder layer needs to be increased, and the preset ratio information r of the si element can be the lowest ratio of the si element in the self-brazing alloy powder layer.
Through the technical scheme, the calculation can be sequentially carried out
According to the technical scheme provided by the invention, the thickness information of the Al-Si alloy plate, the thickness information of the self-brazing alloy powder layer and the proportion information of the Si element provide customized manufacture of the self-brazing composite alloy material for a user according to the use scene of the aluminum heat exchanger, and the material and manufacturing cost is reduced while the stability is ensured.
And S140, correcting the first quantity information, the second quantity information, the thickness information of the Al-Si alloy plate, the thickness information of the self-brazing alloy powder layer and the proportion information of the Si element based on the quality intensity information.
In the technical solution provided by the present invention, as shown in fig. 2B, step S140 specifically includes:
step S1401, a quality intensity comparison table is preset, and the quality intensity comparison table includes a plurality of intensity threshold intervals and an intensity coefficient corresponding to each intensity threshold interval. The invention can preset a quality intensity comparison table, and stores the relation between the intensity threshold interval and the intensity coefficient through the quality intensity comparison table. For example, in the quality intensity comparison table, the intensity threshold interval is 2 to 3, and the intensity coefficient corresponding to the intensity threshold interval is 1.2. The granularity of the intensity threshold interval can be set as required.
Step S1402, traversing the intensity threshold interval in the quality intensity comparison table, and acquiring the intensity threshold interval corresponding to the quality intensity information and the corresponding intensity coefficient. After receiving the quality intensity information input by the user, the intensity threshold interval in which the quality intensity information is located is determined, for example, if the quality intensity information input by the user is 2.1, the intensity threshold interval corresponding to the quality intensity information is 2 to 3, and the intensity coefficient is 1.2.
Step S1403, the first quantity information, the second quantity information, the thickness information of the Al-Si alloy plate, the thickness information of the self-brazing alloy powder layer, and the proportion information of the Si element are corrected based on the strength coefficient. After the strength coefficient is determined, the first quantity information, the second quantity information, the thickness information of the Al-Si alloy plate, the thickness information of the self-brazing alloy powder layer and the proportion information of the Si element are corrected according to the strength coefficient, and the larger the strength coefficient is, the higher the redundancy strength requirement of a user on the aluminum heat exchanger is, and the redundancy strength can be understood as strength beyond the use scene of the aluminum heat exchanger.
The first quantity information, the second quantity information, the thickness information of the Al-Si alloy plate, the thickness information of the self-soldering alloy powder layer and the proportion information of the Si element are corrected through the following formulas,
Figure GDA0004042605790000221
wherein, y 1 For the corrected first quantity information, x 1 Is the first correction weight, X is the intensity coefficient, y 2 For the corrected second quantity information, x 2 Is the second modified weight, y 3 For the thickness information of the corrected Al-Si alloy plate, x 3 Is the third correction weight, y 4 For thickness information of the corrected self-brazing alloy powder layer, x 4 Is the fourth correction weight, y 5 As corrected Si element ratio information, x 5 Is a fifth correction weight. According to the invention, the first quantity information, the second quantity information, the thickness information of the Al-Si alloy plate, the thickness information of the self-soldering alloy powder layer and the proportion information of the Si element are corrected uniformly through the strength coefficient, and because the first quantity information, the second quantity information, the thickness information of the Al-Si alloy plate, the thickness information of the self-soldering alloy powder layer and the proportion information of the Si element have different units, the first quantity information, the second quantity information, the thickness information of the Al-Si alloy plate, the thickness information of the self-soldering alloy powder layer and the proportion information of the Si element respectively have correction weights suitable for the first quantity information, the second quantity information, the thickness information of the Al-Si alloy plate and the proportion information of the Si element, and the correction weights can be preset.
Through the technical scheme, the first quantity information, the second quantity information, the thickness information of the Al-Si alloy plate, the thickness information of the self-brazing alloy powder layer and the proportion information of the Si element can be corrected, so that a user has appropriate indexes and data when manufacturing the self-brazing composite alloy material.
And S150, selecting corresponding materials to generate the target self-soldering composite alloy material through hot rolling compounding based on the corrected first quantity information, second quantity information, thickness information of the Al-Si alloy plate, thickness information of the self-soldering alloy powder layer and proportion information of the Si element.
In one possible embodiment, the method further comprises:
and generating a basic manufacturing table based on the corrected first quantity information, second quantity information, thickness information of the Al-Si alloy plate, thickness information of the self-brazing alloy powder layer and proportion information of the Si element, and displaying the basic manufacturing table.
The user can select corresponding materials to manufacture the self-brazing composite alloy material according to the basic manufacturing table, or select corresponding materials to manufacture the self-brazing composite alloy material in a production line mode, and the specific selection and manufacturing process is not limited in the invention.
The readable storage medium may be a computer storage medium or a communication medium. Communication media includes any medium that facilitates transfer of a computer program from one place to another. Computer storage media can be any available media that can be accessed by a general purpose or special purpose computer. For example, a readable storage medium is coupled to the processor such that the processor can read information from, and write information to, the readable storage medium. Of course, the readable storage medium may also be an integral part of the processor. The processor and the readable storage medium may reside in an Application Specific Integrated Circuits (ASIC). Additionally, the ASIC may reside in user equipment. Of course, the processor and the readable storage medium may also reside as discrete components in a communication device. The readable storage medium may be a read-only memory (ROM), a random-access memory (RAM), a CD-ROM, a magnetic tape, a floppy disk, an optical data storage device, and the like.
The present invention also provides a program product comprising executable instructions stored on a readable storage medium. The at least one processor of the device may read the execution instructions from the readable storage medium, and the execution of the execution instructions by the at least one processor causes the device to implement the methods provided by the various embodiments described above.
In the above embodiments of the terminal or the server, it should be understood that the Processor may be a Central Processing Unit (CPU), other general-purpose processors, a Digital Signal Processor (DSP), an Application Specific Integrated Circuit (ASIC), etc. A general purpose processor may be a microprocessor or the processor may be any conventional processor or the like. The steps of a method disclosed in connection with the present invention may be embodied directly in a hardware processor, or in a combination of the hardware and software modules within the processor.
Finally, it should be noted that: the above embodiments are only used to illustrate the technical solution of the present invention, and not to limit the same; while the invention has been described in detail and with reference to the foregoing embodiments, it will be understood by those skilled in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some or all of the technical features may be equivalently replaced; and these modifications or substitutions do not depart from the spirit of the corresponding technical solutions of the embodiments of the present invention.

Claims (3)

1. An intelligent preparation method for preparing a self-brazing composite alloy material for an aluminum heat exchanger is characterized in that,
a self-brazing composite alloy material for an aluminum heat exchanger, comprising:
a core material;
the self-brazing alloy powder layer is positioned between the core material and the Al-Si alloy plate and/or between the Al-Si alloy plate and the Al-Si alloy plate, and comprises Al-Si alloy powder and Nocolok brazing flux powder;
the core material, the self-brazing alloy powder layer and the Al-Si alloy plate are compounded into a self-brazing composite alloy material through hot rolling;
the content of the Nocolok brazing flux powder in the self-brazing alloy powder is 0.5-25% by mass, and the Nocolok brazing flux powder consists of the following raw materials by mass: k28-31%, al 16-18%, F49-53%, fe less than or equal to 0.03%, ca less than or equal to 0.02%, H 2 O≤2.5%;
The mass percent of Si in the Al-Si alloy powder and the Al-Si alloy plate is 4-13%;
the intelligent preparation method comprises the following steps:
acquiring scene data input by a user, wherein the scene data at least comprises heat exchange scene information, applicable temperature information and quality intensity information;
determining first quantity information and second quantity information of the Al-Si alloy plates hot-rolled at the upper surface and the lower surface of the core material based on the heat exchange scene information;
determining thickness information of the Al-Si alloy plate at the upper surface and the lower surface of the core material based on the applicable temperature information, and determining thickness information of a self-brazing alloy powder layer and proportion information of Si elements in the self-brazing alloy powder according to the thickness information of the Al-Si alloy plate;
correcting the first quantity information, the second quantity information, the thickness information of the Al-Si alloy plate, the thickness information of the self-brazing alloy powder layer and the proportion information of the Si element on the basis of the quality intensity information;
selecting corresponding materials to generate a target self-brazing composite alloy material through hot rolling compounding based on the corrected first quantity information, second quantity information, thickness information of the Al-Si alloy plate, thickness information of the self-brazing alloy powder layer and proportion information of the Si element;
determining first quantity information and second quantity information of the Al-Si alloy plates hot-rolled at the upper surface and the lower surface of the core material based on the heat exchange scenario information includes:
the heat exchange scene information comprises the property of a heat conduction medium, the heat exchange length and the heat exchange width which are respectively contacted with the upper surface and the lower surface of the alloy material, and the property of the heat conduction medium comprises any one of gas or liquid;
if the heat transfer medium of the upper surface and the lower surface is a gas, the first quantity information and the second quantity information are calculated by the following formula,
Figure QLYQS_1
wherein,
Figure QLYQS_3
is the first quantity information, is greater or less>
Figure QLYQS_7
Is the second quantity information->
Figure QLYQS_10
Is a gas weight value>
Figure QLYQS_4
A first length weight value, <' > greater or lesser>
Figure QLYQS_6
For the length of the heat exchange>
Figure QLYQS_9
Length reference value->
Figure QLYQS_12
Is a first width weight value>
Figure QLYQS_2
For a first heat exchange width>
Figure QLYQS_5
Is a width reference value>
Figure QLYQS_8
Is a second length weight value>
Figure QLYQS_11
A second width weight value;
if the heat transfer medium of the upper and lower surfaces is liquid, the first quantity information and the second quantity information are calculated by the following formulas,
Figure QLYQS_13
wherein,
Figure QLYQS_14
the weight value of the liquid is;
further comprising:
receiving third quantity information and/or fourth quantity information input by a user, wherein the third quantity information is the number of layers of the Al-Si alloy plate on the upper surface actually determined by the user, and the fourth quantity information is the number of layers of the Al-Si alloy plate on the lower surface actually determined by the user;
updating the gas weight value and/or the liquid weight value based on third quantity information and/or fourth quantity information input by a user;
the gas weight and/or liquid weight is updated by the following equations,
Figure QLYQS_15
wherein,
Figure QLYQS_16
for updated gas weight values>
Figure QLYQS_17
For an updated liquid weight value, <' > based on the status of the liquid>
Figure QLYQS_18
In order to update the coefficient of the gas,
Figure QLYQS_19
update the weight for gas>
Figure QLYQS_20
Update the coefficient for liquid>
Figure QLYQS_21
Updating the weight for the liquid;
determining thickness information of the Al-Si alloy plates on the upper surface and the lower surface of the core material based on the applicable temperature information, and determining thickness information of the self-brazing alloy powder layer and proportion information of Si elements in the self-brazing alloy powder according to the thickness information of the Al-Si alloy plates comprises the following steps:
determining thickness information of the Al-Si alloy plate based on the upper temperature limit value and the lower temperature limit value included in the applicable temperature information, and determining thickness information of the self-brazing alloy powder layer and proportion information of Si elements in the self-brazing alloy powder according to the thickness information of the Al-Si alloy plate;
the thickness information of the Al-Si alloy plate, the thickness information of the self-brazing alloy powder layer and the proportion information of the Si element are calculated by the following formulas,
Figure QLYQS_22
wherein,
Figure QLYQS_25
is the thickness information of the Al-Si alloy plate>
Figure QLYQS_28
A temperature weight value->
Figure QLYQS_31
For temperature conversion value, in conjunction with a temperature sensor>
Figure QLYQS_24
Is an upper temperature limit value>
Figure QLYQS_27
Is a lower temperature limit value>
Figure QLYQS_30
Is the base thickness value of the Al-Si alloy plate>
Figure QLYQS_33
As thickness information of the self-brazing alloy powder layer,
Figure QLYQS_23
preset ratio value,>
Figure QLYQS_26
is the base thickness value of the self-brazing alloy powder layer>
Figure QLYQS_29
Is the proportion information of Si element in the self-brazing alloy powder layer>
Figure QLYQS_32
The preset proportion information of Si element in the self-brazing alloy powder layer;
correcting the first quantity information, the second quantity information, the thickness information of the Al-Si alloy plate, the thickness information of the self-brazing alloy powder layer, and the proportion information of the Si element based on the mass intensity information includes:
presetting a quality intensity comparison table, wherein the quality intensity comparison table comprises a plurality of intensity threshold intervals and intensity coefficients corresponding to the intensity threshold intervals;
traversing an intensity threshold interval in a quality intensity comparison table, and acquiring an intensity threshold interval corresponding to the quality intensity information and a corresponding intensity coefficient;
correcting the first quantity information, the second quantity information, the thickness information of the Al-Si alloy plate, the thickness information of the self-brazing alloy powder layer and the proportion information of the Si element on the basis of the strength coefficient;
the first quantity information, the second quantity information, the thickness information of the Al-Si alloy plate, the thickness information of the self-brazing alloy powder layer and the proportion information of the Si element are corrected by the following formulas,
Figure QLYQS_34
wherein,
Figure QLYQS_36
for the corrected first quantity information, ->
Figure QLYQS_38
For the first correction weight, <' >>
Figure QLYQS_41
For an intensity coefficient, <' > based on>
Figure QLYQS_37
For the corrected second quantity information, ->
Figure QLYQS_40
For the second correction weight>
Figure QLYQS_43
For the corrected thickness information of the Al-Si alloy plate, based on the thickness information of the Al-Si alloy plate>
Figure QLYQS_45
For the third correction weight, <' >>
Figure QLYQS_35
For the corrected thickness information of the self-brazing alloy powder layer, the thickness of the powder layer is corrected>
Figure QLYQS_39
For the fourth correction weight, <' >>
Figure QLYQS_42
For the corrected ratio information of the Si element, is compared>
Figure QLYQS_44
Is a fifth modified weight.
2. The intelligent preparation method according to claim 1, further comprising:
if the obtained first quantity information and/or second quantity information is not an integer, acquiring an integer which is larger than the first quantity information and/or second quantity information and is closest to the first quantity information and/or second quantity information as the adjusted first quantity information and/or second quantity information.
3. The intelligent preparation method of claim 1, further comprising:
and generating a basic manufacturing table based on the corrected first quantity information, second quantity information, thickness information of the Al-Si alloy plate, thickness information of the self-brazing alloy powder layer and proportion information of the Si element, and displaying the basic manufacturing table.
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