[go: up one dir, main page]
More Web Proxy on the site http://driver.im/

CN114474899A - 一种高物性玻纤加强的人造革及其制备方法 - Google Patents

一种高物性玻纤加强的人造革及其制备方法 Download PDF

Info

Publication number
CN114474899A
CN114474899A CN202210000984.8A CN202210000984A CN114474899A CN 114474899 A CN114474899 A CN 114474899A CN 202210000984 A CN202210000984 A CN 202210000984A CN 114474899 A CN114474899 A CN 114474899A
Authority
CN
China
Prior art keywords
glass fiber
artificial leather
layer
physical
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202210000984.8A
Other languages
English (en)
Inventor
宗政宇
蒋泽
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuxi Manyouli New Composite Materials Co ltd
Original Assignee
Wuxi Manyouli New Composite Materials Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuxi Manyouli New Composite Materials Co ltd filed Critical Wuxi Manyouli New Composite Materials Co ltd
Priority to CN202210000984.8A priority Critical patent/CN114474899A/zh
Publication of CN114474899A publication Critical patent/CN114474899A/zh
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/16—Drying; Softening; Cleaning
    • B32B38/164—Drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/028—Net structure, e.g. spaced apart filaments bonded at the crossing points
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0011—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using non-woven fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • D06N3/0022—Glass fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/045—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyolefin or polystyrene (co-)polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/24—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
    • B32B2037/243—Coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/20—All layers being fibrous or filamentary
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/02—Coating on the layer surface on fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/26—Polymeric coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/51—Elastic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/72—Density
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/06—Properties of the materials having thermal properties
    • D06N2209/067—Flame resistant, fire resistant
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D06N2209/1635—Elasticity
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D06N2209/1642—Hardnes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/12—Decorative or sun protection articles
    • D06N2211/28—Artificial leather

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)

Abstract

本发明公开了一种高物性玻纤加强的人造革及其制备方法，属于合成皮革技术领域，制备得到的人造革从下至上依次为基布层、PU树脂层、玻纤层、TPO层；PU树脂层采用水性聚氨酯树脂，环保无污染，采用玻璃纤维网格布作为增强层，表层采用TPO树脂层，具有密度小，高弹性，使人造革具有优良的柔软度及低温性能；并使用玻璃纤维作为填充料，进一步增强了人造革的耐高温耐低温性能，并且弹性系数高，刚性佳。

Description

一种高物性玻纤加强的人造革及其制备方法
技术领域
本发明属于合成皮革技术领域，尤其涉及一种高物性玻纤加强的人造革及其制备方法。
背景技术
随着时代的进步发展，对于皮具的需要已经不仅仅局限于真皮。各种仿真产品已经可以替代部分的真皮制品。自人造革产品面试以来，市场上出现了各种纹路、规格的产品，功用也呈多元化发展，对不同场景中应用的合成革也有了不同的要求。而且随着环保要求的提供，对人造革是否有异味产生的要求越来越高，由于人造革面料生产中使用有高分子化合物助剂，所以或多或少都会产生一定的化学品异味逸出，直接使用时有逸出的学品异味。虽然通过时效处理，产品中高分子化合物中逸出的学品异味会逐步减少，直到不在有异味逸出，但这一时间往往较长，而生产供货和使用是不可能等到这个时候。所以在保证人造革一定的物理性能的前提下，使制备过程更环保是研究的重点。
发明内容
本发明提供了一种高物性玻纤加强的人造革及其制备方法，制备得到的人造革具有高物性，且制备过程环保。
为实现以上目的，本发明采用以下技术方案：
一种高物性玻纤加强的人造革，从下至上依次为基布层、PU树脂层、玻纤层、TPO层；
所述PU树脂层包括以下质量份数组分：水性聚氨酯树脂50-80份、抗氧化剂0.5-1份、防霉剂0.3-0.8份；所述PU树脂层厚度为0.5-1.5mm；
所述TPO层包括以下质量份数组分：TPO树脂70-80份、填充料5-15份、抗氧化剂0.5-1份、紫外光吸收剂0.5-1份；所述填充料为短玻璃纤维，直径为20-80um；所述TPO层厚度为0.5-1.5mm；
所述玻纤层为玻璃纤维网格布，为玻璃纤维编织而成，厚度为0.5-0.8mm。
一种高物性玻纤加强的人造革的制备方法，包括以下步骤：
步骤1：取质量份组分水性聚氨酯树脂50-80份、抗氧化剂0.5-1份、防霉剂0.3-0.8份，混合均匀得到树脂层浆料；
步骤2：将步骤1得到的树脂层浆料均匀涂覆一定厚度于基布表面；
步骤3：将玻璃纤维编织的玻璃纤维网格布平整贴合于步骤2树脂层表面，烘干；
步骤4：将TPO树脂70-80份、填充料5-15份、抗氧化剂0.5-1份、紫外光吸收剂0.5-1份混合均匀，均匀涂覆一定厚度于步骤3玻璃纤维网格布表面，烘干。
以上所述步骤中，步骤1和步骤4树脂浆料在45-55℃下混合均匀。
有益效果：本发明提供一种高物性玻纤加强的人造革及其制备方法，制备得到的人造革从下至上依次为基布层、PU树脂层、玻纤层、TPO层；PU树脂层采用水性聚氨酯树脂，环保无污染，采用玻璃纤维网格布作为增强层，表层采用TPO树脂层，具有密度小，高弹性，使人造革具有优良的柔软度及低温性能；并使用玻璃纤维作为填充料，进一步增强了人造革的耐高温耐低温性能，并且弹性系数高，刚性佳。
具体实施方式
下面结合具体实施例对本发明进行详细说明：
实施例1
一种高物性玻纤加强的人造革的制备方法，包括以下步骤：
步骤1：取质量份组分水性聚氨酯树脂50份、抗氧化剂0.5份、防霉剂0.3份，在45℃混合均匀得到树脂层浆料；
步骤2：将步骤1得到的树脂层浆料均匀涂覆1mm于无纺布基布表面；
步骤3：将玻璃纤维编织的0.5mm厚的玻璃纤维网格布平整贴合于步骤2树脂层表面，70℃烘干；
步骤4：将TPO树脂70-80份、填充料短玻璃纤维5-15份、抗氧化剂1份、紫外光吸收剂1份混合均匀，均匀涂覆0.8mm于步骤3玻璃纤维网格布表面，70℃烘干得到成品人造革。
实施例2
一种高物性玻纤加强的人造革的制备方法，包括以下步骤：
步骤1：取质量份组分水性聚氨酯树脂80份、抗氧化剂1份、防霉剂0.8份，在45℃混合均匀得到树脂层浆料；
步骤2：将步骤1得到的树脂层浆料均匀涂覆0.8mm于无纺布基布表面；
步骤3：将玻璃纤维编织的0.5mm厚的玻璃纤维网格布平整贴合于步骤2树脂层表面，70℃烘干；
步骤4：将TPO树脂80份、填充料短玻璃纤维15份、抗氧化剂1份、紫外光吸收剂1份混合均匀，均匀涂覆1mm于步骤3玻璃纤维网格布表面，70℃烘干得到成品人造革。
对比例1
现有技术中常用的PU人造革。
将实施例1-2和对比例1制备的皮革取相同大小和厚度进行性能测试，采用0096Z-SEC-A000测试方法，检测结果如表1所示：
表1 实施例和对比例产品的性能测试结果
Figure DEST_PATH_IMAGE002
以上仅为本发明的优选实施例而已，并不用于限制本发明，尽管参照实施例对本发明进行了详细的说明，对于本领域的技术人员来说，其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分技术特征进行等同替换，但是凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。

Claims (10)

1.一种高物性玻纤加强的人造革，其特征在于，从下至上依次为基布层、PU树脂层、玻纤层、TPO层。
2.根据权利要求1所述的高物性玻纤加强的人造革，其特征在于，所述PU树脂层厚度为0.5-1.5mm。
3.根据权利要求1或2所述的高物性玻纤加强的人造革，其特征在于，所述PU树脂层包括以下质量份数组分：水性聚氨酯树脂50-80份、抗氧化剂0.5-1份、防霉剂0.3-0.8份。
4.根据权利要求1所述的高物性玻纤加强的人造革，其特征在于，所述TPO层厚度为0.5-1.5mm。
5.根据权利要求1或4所述的高物性玻纤加强的人造革，其特征在于，所述TPO层包括以下质量份数组分：TPO树脂70-80份、填充料5-15份、抗氧化剂0.5-1份、紫外光吸收剂0.5-1份。
6.根据权利要求5所述的高物性玻纤加强的人造革，其特征在于，所述填充料为短玻璃纤维。
7.根据权利要求1所述的高物性玻纤加强的人造革，其特征在于，所述玻纤层厚度为0.5-0.8mm。
8.根据权利要求1或7所述的高物性玻纤加强的人造革，其特征在于，所述玻纤层为玻璃纤维编织而成的玻璃纤维网格布。
9.一种高物性玻纤加强的人造革的制备方法，其特征在于，包括以下步骤：
步骤1：取质量份组分水性聚氨酯树脂50-80份、抗氧化剂0.5-1份、防霉剂0.3-0.8份，混合均匀得到树脂层浆料；
步骤2：将步骤1得到的树脂层浆料均匀涂覆一定厚度于基布表面；
步骤3：将玻璃纤维编织的玻璃纤维网格布平整贴合于步骤2树脂层表面，烘干；
步骤4：将TPO树脂70-80份、填充料5-15份、抗氧化剂0.5-1份、紫外光吸收剂0.5-1份混合均匀，均匀涂覆一定厚度于步骤3玻璃纤维网格布表面，烘干。
10.根据权利要求9所述的高物性玻纤加强的人造革的制备方法，其特征在于，步骤1和步骤4树脂浆料在45-55℃下混合均匀。
CN202210000984.8A 2022-01-04 2022-01-04 一种高物性玻纤加强的人造革及其制备方法 Pending CN114474899A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202210000984.8A CN114474899A (zh) 2022-01-04 2022-01-04 一种高物性玻纤加强的人造革及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202210000984.8A CN114474899A (zh) 2022-01-04 2022-01-04 一种高物性玻纤加强的人造革及其制备方法

Publications (1)

Publication Number Publication Date
CN114474899A true CN114474899A (zh) 2022-05-13

Family

ID=81509384

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202210000984.8A Pending CN114474899A (zh) 2022-01-04 2022-01-04 一种高物性玻纤加强的人造革及其制备方法

Country Status (1)

Country Link
CN (1) CN114474899A (zh)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1827906A (zh) * 2005-02-28 2006-09-06 刘彦伯 聚烯烃人造革及其制造工艺
CN103889707A (zh) * 2011-10-31 2014-06-25 南部工业联合股份公司 由多层复合材料制成的制品及其制备方法
US20150290913A1 (en) * 2014-04-14 2015-10-15 Jowat Se Laminating process employing grid-like adhesive application
US20160273159A1 (en) * 2015-03-18 2016-09-22 San Fang Chemical Industry Co., Ltd. Thermoplastic artificial leather, method for manufacturing the same and thermoplastic composite laminate
CN112895668A (zh) * 2019-11-19 2021-06-04 贝内克-长顺汽车内饰材料（张家港）有限公司 一种无胶水的tpo人造革及其制造方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1827906A (zh) * 2005-02-28 2006-09-06 刘彦伯 聚烯烃人造革及其制造工艺
CN103889707A (zh) * 2011-10-31 2014-06-25 南部工业联合股份公司 由多层复合材料制成的制品及其制备方法
US20150290913A1 (en) * 2014-04-14 2015-10-15 Jowat Se Laminating process employing grid-like adhesive application
US20160273159A1 (en) * 2015-03-18 2016-09-22 San Fang Chemical Industry Co., Ltd. Thermoplastic artificial leather, method for manufacturing the same and thermoplastic composite laminate
CN112895668A (zh) * 2019-11-19 2021-06-04 贝内克-长顺汽车内饰材料（张家港）有限公司 一种无胶水的tpo人造革及其制造方法

Similar Documents

Publication Publication Date Title
CN108384222B (zh) 一种水性聚氨酯涂层手套及其制备方法
CN103469577A (zh) 一种用于牛仔服饰压皱整理的硬挺剂
CN108411651A (zh) 一种烫金用浆料及其制备方法和用途
CN112760992B (zh) 一种耐磨篮球革及其制备方法
CN110644252A (zh) 一种弹性面料及其制备方法
CN110273302A (zh) 一种多功能超细纤维合成革的制备方法
CN110527465B (zh) 一种纺织用植绒胶及其制备方法
CN114474899A (zh) 一种高物性玻纤加强的人造革及其制备方法
CN102605622A (zh) 一种用于降低竹纤维面料缩水率的后整理工艺及床品
CN109853225A (zh) 一种夜光拒水涤纶面料的后整理工艺
CN105644125A (zh) 一种麂皮绒复合聚氨酯沙发布的制备方法
CN113045729A (zh) 抗菌罩杯及其生产工艺
CN112482031A (zh) 一种涤纶用蓬松弹性硅油及其制备方法
CN112376284A (zh) 一种沙发用水性超细纤维绒面合成革
CN112961307B (zh) 一种无溶剂型聚氨酯树脂、含浸浆料及其制备方法和应用
CN107761404B (zh) 一种高耐磨pu合成革面料的制备方法
CN114164675A (zh) 一种天然乳胶超细纤维合成革的制备方法
CN109385914A (zh) 一种鞋底用透气吸水性pu树脂的制备方法
CN110528293B (zh) 一种阻燃防污合成革及其制备方法
CN109371659B (zh) 一种基于数码印花的厚重型蚕丝织物的制备方法
CN105951444A (zh) 一种绿色环保织物硬挺剂
CN113561579A (zh) 一种玄武岩网布复合材料及其制备方法
CN115613375B (zh) 一种合成纤维及混纺织物的涂料印花工艺
CN108468225B (zh) 良好吸湿、透气性和透水汽性的聚氨酯合成革的制备方法
CN111335051A (zh) 环保仿皮革绒感光变色印花浆及其制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20220513

RJ01 Rejection of invention patent application after publication