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CN103996602B - A kind of method using bilateral wall technique to form ultralow size figure - Google Patents

A kind of method using bilateral wall technique to form ultralow size figure Download PDF

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Publication number
CN103996602B
CN103996602B CN201410253213.5A CN201410253213A CN103996602B CN 103996602 B CN103996602 B CN 103996602B CN 201410253213 A CN201410253213 A CN 201410253213A CN 103996602 B CN103996602 B CN 103996602B
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CN103996602A (en
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桑宁波
雷通
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Shanghai Huali Microelectronics Corp
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/027Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34
    • H01L21/033Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising inorganic layers
    • H01L21/0334Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising inorganic layers characterised by their size, orientation, disposition, behaviour, shape, in horizontal or vertical plane
    • H01L21/0338Process specially adapted to improve the resolution of the mask
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/28Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
    • H01L21/28008Making conductor-insulator-semiconductor electrodes
    • H01L21/28017Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon

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  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Drying Of Semiconductors (AREA)

Abstract

A kind of method using bilateral wall technique to form ultralow size figure, including: form the figure with fisrt feature size;Then depositing thin film material layer on this figure, form the conforma layer of uniform fold mask graph, on side wall, the thickness of thin film is the first thickness;Carry out second time photoetching and develop, defining the first device area;Carrying out second time on this figure to deposit, deposit thin film material layer, deposit thickness is the second thickness, and now the first device area covers the thickness of material is the sum that the first thickness adds the second thickness, and the thickness of the second device area is the second thickness;Anisotropically etch thin-film material, the thin-film material of mask layer top and bottom is removed, leaves behind the thin-film material on sidewall;Cineration technics optionally removes hard mask, leaves behind the side wall that thin-film material is formed;Utilize thin-film material to perform etching as the new mask of etching, form the hyperfine figure of two kinds of sizes with the first thickness by deposition thin film and the decision of the second thickness.

Description

A kind of method using bilateral wall technique to form ultralow size figure
Technical field
The present invention relates to field of semiconductor manufacture, more particularly to a kind of self aligned formation hyperfine feature chi The method of very little figure.Bilateral wall technique is used to form ultralow dimensional drawing it is more particularly related to a kind of The method of shape.
Background technology
The characteristic size of super large-scale integration according to the development of Moore's Law, have evolved to 20 nanometers and Following characteristic size, in order to increase the capacity of semiconductor device on less area and reduce cost, is formed There is better performance, the semiconductor device of lower power consumption.The contraction of the characteristic size of each device needs More complicated technology.Photoetching process is the conventional method transferring on substrate by device and circuit pattern, line Width and spacing are two parameters the most key in photoetching process.Spacing is defined as the phase of two adjacent lines With the distance between putting.Due to various factors, such as the physical restriction such as wavelength of optics and light, existing photoetching Technology has minimum spacing can not meet the demand of integrated circuit below 20 nanometers, less than this specific photoetching The figure of the characteristic size of technological limit can not be formed by existing photoetching technique.Therefore, one is found The method that can meet again characteristic size demand while of utilizing existing photoetching technique is the most extremely important.
Self aligned secondary graphical method is to be widely studied in recent years and the figure of very likely large-scale production Transfer techniques, with it, disclosure satisfy that the figure transfer demand of below 20 nanometers, not by photoetching work The physics of skill and the restriction of the equipment limit.
But the width of the spacer that self aligned secondary graphical method obtains (thickness of conforma layer) is unique , the size of the figure so obtained also is unique, but in actual Application of integrated circuit, especially It is in logic circuit, SRAM circuit, it is desirable to have the active area of different characteristic size, different characteristic size Grid etc..
Summary of the invention
The technical problem to be solved is for there is drawbacks described above in prior art, it is provided that Yi Zhongneng Enough use the method that bilateral wall technique forms ultralow size figure.
In order to realize above-mentioned technical purpose, according to the present invention, it is provided that a kind of employing bilateral wall technique is formed super First the method for low dimensional figure, comprising: carry out photoetching for the first time etch mask layer by a layer mask version Form the figure with fisrt feature size;Then on this figure, deposit thin film material layer, formed uniformly The conforma layer of coverage mask figure, on side wall, the thickness of thin film is the first thickness;Carry out second time photoetching and show Shadow, is defined as the first device area with a part of thin-film material covered by photoresist, will be as the second device The thin-film material of the expose portion in region is removed;Removing photoresist, the most only first device area is by thin film Material covers;Then carrying out second time on this figure to deposit, deposit thin film material layer, deposit thickness is Second thickness, now the first device area covers the thickness of material is the sum that the first thickness adds the second thickness, the Two device areas thickness be the second thickness;Anisotropically etch thin-film material, by mask layer top and The thin-film material of bottom is removed, and leaves behind the thin-film material on sidewall;Cineration technics is optionally removed and is firmly covered Mould, leaves behind the side wall that thin-film material is formed;Thin-film material is utilized to perform etching as the new mask of etching, Forming the hyperfine figure with two kinds of sizes, two kinds of sizes are by the first thickness and the second thickness depositing thin film Determine.
In one embodiment, first photoetching for the first time etch mask layer (amorphous are carried out by a layer mask version Carbon sacrifice layer) form the figure with fisrt feature size (this is closely sized to the physics limit of photoetching);Connect Deposition thin film material layer on this figure, form the side wall of uniform fold mask graph, thin film on side wall Thickness be the first thickness;Carrying out second time photoetching developing, photoresist covers a part of material and is defined as the One device area, removes the thin-film material of the part (the second device area) exposed;Remove photoresist, The first device area is now only had to have material one covering;Then on this figure, carry out second time deposit, deposition Thin film material layer 1, deposit thickness is the second thickness, and now the first device area covers the thickness of material is the One thickness adds the sum of the second thickness, the second device area thickness be the second thickness;Anisotropic etching Thin-film material 1, removes the thin-film material of mask layer top and bottom, leaves behind the thin film on sidewall;Ashing The removal hard mask (sacrifice layer) of process selectivity, leaves behind the side wall that material 1 is formed;Material is as etching New mask perform etching, formed and there is the hyperfine figure of two kinds of sizes.And the size of size close to First thickness of side wall and the second thickness, the second thickness is the second size of the second requirement on devices, the first thickness With the second thickness and the first size that is the first requirement on devices.
In one embodiment, the method for the shallow trench forming patterning in a silicon substrate includes: at silicon substrate Upper formation silicon nitride, and form mask layer (sacrifice layer) on silicon nitride, and use photoetching process formation to have The mask graph of fisrt feature size;The method further includes at covering layer of silicon dioxide on above-mentioned figure Conforma layer, forms the side wall of uniform fold mask graph, and on side wall, the thickness of thin film is the first thickness;Immediately Row second time photoetching is also developed, and photoresist covers a part of silicon dioxide conforma layer, by being total to of the part of exposure Shape layer is removed clean, and definition overlay area is the first device area, and expose portion is the second device area;Go Except photoresist and carry out second time and deposit silicon dioxide conforma layer, form the side wall of uniform fold mask graph, Deposit thickness is the second thickness, and now to be that the first thickness adds the second thick for the thickness of the first device area silicon dioxide Degree sum, the second device area thickness be the second thickness;Anisotropic etching silicon dioxide, by sacrificial The silicon dioxide of domestic animal layer top and bottom is removed, and leaves behind the silicon dioxide on sidewall;Use oxygen ash chemical industry Skill removes the mask layer (sacrifice layer) being exposed to surface;Dry etching is used to etch the conforma layer carried over, And as hard mask etch silicon nitride and silicon substrate, form shallow trench, having of the shallow trench finally obtained isolation The size of source region has two kinds, and the second thickness is the second size of the second requirement on devices, the first thickness and the second thickness First size that is that spend and that be the first requirement on devices.
The method of the polysilicon gate forming patterning in another embodiment on substrate includes: form titanium dioxide Silicon oxide gate dielectric layer, forms polysilicon gate, and forms mask layer (sacrifice layer) on polysilicon gate, and use light Carving technology forms the mask graph with fisrt feature size;The method further includes at above-mentioned figure overlying Lid layer of silicon dioxide conforma layer, forms the side wall of uniform fold mask graph, and on side wall, the thickness of thin film is First thickness;Immediately row second time photoetching developing, photoresist covers a part of silicon dioxide conforma layer, will The conforma layer of the part exposed is removed clean, and definition overlay area is the first device area, and expose portion is the Two device areas;Remove photoresist and carry out depositing for the second time silicon dioxide, forming uniform fold mask graph Side wall, deposit thickness is the second thickness, now first device area cover silicon dioxide thickness is first Thickness adds the sum of the second thickness, the second device area thickness be the second thickness;Anisotropic etching two Silicon oxide, removes the silicon dioxide of sacrifice layer top and bottom, leaves behind the thin film on sidewall;Use oxygen Gas cineration technics removes the mask layer (sacrifice layer) being exposed to surface;Dry etching etching is used to carry over Conforma layer, and as hard mask etches polycrystalline Si-gate and gate dielectric layer, form grid structure, finally obtain The size of grid structure has two kinds, and the second thickness is the second size of the second requirement on devices, the first thickness and Two thickness and the first size that is the first requirement on devices.
By the invention it is possible to be once lithographically formed the spacer with two kinds of thickness by increasing;And, By this method, the figure of two kinds of characteristic sizes can disposably be etched, it might even be possible to unrestrictedly increase Photoetching number of times forms the spacer spacer of various thickness, obtains the figure of more different characteristic size, full The actual demand of foot integrated circuit, significant to the large-scale application of SADP.
Accompanying drawing explanation
In conjunction with accompanying drawing, and by with reference to detailed description below, it will more easily the present invention is had more complete Understand and its adjoint advantage and feature is more easily understood, wherein:
Fig. 1 to Figure 11 schematically show employing bilateral wall technique according to the preferred embodiment of the invention Form sectional view or the top view of each step of the method for ultralow size figure.
It should be noted that accompanying drawing is used for illustrating the present invention, and the unrestricted present invention.Note, represent structure Accompanying drawing may be not necessarily drawn to scale.Further, in accompanying drawing, same or like element indicate identical or The label that person is similar to.
Detailed description of the invention
In order to make present disclosure more clear and understandable, below in conjunction with specific embodiments and the drawings to this Bright content is described in detail.
Fig. 1 to Figure 11 schematically show employing bilateral wall technique according to the preferred embodiment of the invention Form sectional view or the top view of each step of the method for ultralow size figure.
As shown in Figure 1 to 11, bilateral wall technique is used to form ultralow chi according to the preferred embodiment of the invention The method of very little figure includes:
Silicon substrate 1 is formed silicon nitride (not shown), and forms amorphous carbon layer (mask layer) on silicon nitride 2 (as shown in Figure 1), and use photoetching process formation to have the mask graph of fisrt feature size (such as Fig. 2 Sectional view shown in);Wherein fisrt feature size is formed at or close high-resolution photomask etching system The limit of optical resolution, the size at the resolution limit of present stage state-of-the-art immersed photoetching machine is 20-28 nanometer.
Aforementioned mask figure covers layer of silicon dioxide conforma layer 3 (such as the top view of Fig. 3 and cutting of Fig. 4 Shown in the figure of face), after this conforma layer 3, extended meeting forms the side wall (sectional view such as Fig. 5 of uniform fold mask graph Shown in), on side wall, the thickness of thin film is the first thickness;
Immediately carrying out second time photoetching and develop, photoresist 4 covers a part of silicon dioxide conforma layer, covers Part is defined as the first device area (as illustrated in the top plan view of fig. 6), is removed by the conforma layer of the part exposed Totally (as shown in Figure 7), expose portion is defined as the second device area;
Remove photoresist (as shown in Figure 8) and carry out depositing for the second time silicon dioxide conforma layer 5, being formed uniformly The side wall of coverage mask figure, deposit thickness is the second thickness, and now the first device area covers silicon dioxide Thickness be the sum that the first thickness adds the second thickness, the second device area thickness be that the second thickness is (such as Fig. 9 Sectional view and Figure 10 top view shown in);
Anisotropic etching silicon dioxide, removes the silicon dioxide of mask layer top and bottom, leaves behind Silica membrane (as shown in figure 11) on sidewall;
Oxygen ashing process is used to remove the amorphous carbon layer (mask layer) being exposed to surface;
Dry etching is used to etch the silicon dioxide conforma layer carried over, and as hard mask etch silicon nitride And silicon substrate, forming shallow trench, the size of the active area of the shallow trench finally obtained isolation has two kinds, and second Thickness be the second size of the second requirement on devices, the first thickness and the second thickness and be the first requirement on devices First size.
In the present invention, the size of the figure obtained as silicon dioxide or the silicon nitride of final etching mask Having two kinds, two kinds of sizes are not limited by the physics limit of photoetching, are only determined by the thickness of side wall.
Using bilateral wall technique to form the method for ultralow size figure according to the preferred embodiment of the invention can be favourable Apply in 20 nanometers and following IC manufacturing lithographic etch process.Such as, said method can conduct The method forming the polysilicon gate of patterning on substrate.
<concrete technology example>
Describe concrete technology example according to embodiments of the present invention below, can perform following step successively:
Use thermal oxidation method to form the silicon dioxide layer of 3 to 5 nanometers on a silicon substrate, adopt at silicon dioxide layer The silicon nitride layer of 50-80 nano thickness is formed with LPCVD;
With the amorphous carbon layer of the method deposition 50-200 nano thickness of PECVD on silicon nitride layer, by decomposing C2H2, forms amorphous carbon, and technique initialization is: the flow of C2H2 is 1500sccm, and temperature is 400C, buffering Gas He flow is 300-1500sccm, radio frequency be 13.56Mhz power be 800-1200W, pressure is 10 Torr;
Photoetching also etches amorphous carbon layer and is formed and have the figure of fisrt feature size, and the size of this example is 80 nanometers;
The method using ald (ALD) on above-mentioned figure forms silicon dioxide conforma layer, and technique sets Be set to: 2Nte flow is 1mgm, power be the flow of 2000-3000W, O2 be 3000-4000sccm, The flow of Ar is 1000-2000sccm;The thickness of conforma layer is 10-20 nanometer, and step coverage is 100%;
Carry out second time photoetching: spin coating gel method forms one layer of positive photoresist, carries out the second device area Development, retains the first device area photoresist, and this example is that the drop-down metal-oxide-semiconductor region in 6T-SRAM region is carried out Development, retains the photoresist in transmission metal-oxide-semiconductor region;
The conforma layer using the dry etching Pull-down metal-oxide-semiconductor region to coming out is removed;
Use cineration technics to get rid of all photoresists, carry out the method shape of second time ald (ALD) Becoming silicon dioxide conforma layer, technique initialization is: 2Nte flow is 1mgm, and power is 2000-3000W, O2's Flow be the flow of 3000-4000sccm, Ar be 1000-2000sccm;The thickness of conforma layer is that 15-20 receives Rice, step coverage is 100%;
The anisotropic silicon dioxide getting rid of amorphous carbon top and bottom of using plasma etching is conformal Layer, only leaves the silicon dioxide on side wall;
Using oxygen ashing process to remove amorphous carbon sacrifice layer, technique initialization is: the flow of O2 is 500-1500sccm, temperature is 200 degree, and power is 300W;
For hard mask, substrate is carried out dry etching with the silicon dioxide conforma layer of residual, form shallow trench isolation Active area, the size of this active area is the thickness of conforma layer, the first device area (transmission metal-oxide-semiconductor) A size of 25-40 nanometer;The size of the second device area (drop-down metal-oxide-semiconductor) is 10-20 nanometer.
The present invention uses advanced photoetching process to form the figure with fisrt feature size, and fisrt feature size connects It is bordering on the physics limit of photoetching, the physics of photoetching can be limited by the method using double isolation double patterning molding System is broken, and forms the figure much smaller than fisrt feature size, obtains two kinds of ultralow sizes by Twi-lithography Figure, meets the figure transfer demand of 20 nanometers and following integrated circuit technology.
Furthermore, it is necessary to explanation, unless stated otherwise or point out, the otherwise term in description " the One " each assembly during, the description such as " second ", " the 3rd " is used only for differentiation description, element, step Deng rather than for representing the logical relation between each assembly, element, step or ordering relation etc..
Although it is understood that the present invention discloses as above with preferred embodiment, but above-described embodiment is also It is not used to limit the present invention.For any those of ordinary skill in the art, without departing from skill of the present invention In the case of art aspects, technical solution of the present invention is made many by the technology contents that all may utilize the disclosure above Possible variation and modification, or it is revised as the Equivalent embodiments of equivalent variations.Therefore, every without departing from this The content of bright technical scheme, according to the present invention technical spirit to any simple modification made for any of the above embodiments, Equivalent variations and modification, all still fall within the range of technical solution of the present invention protection.

Claims (6)

1. one kind uses the method that bilateral wall technique forms ultralow size figure, it is characterised in that including: first The mask layer carried out in photoetching for the first time etched substrate by a layer mask version has fisrt feature size to be formed Figure;Then on this figure, deposit thin film material layer, form the conforma layer of uniform fold mask graph, On side wall, the thickness of thin film is the first thickness;Carry out second time photoetching developing, with photoresist is covered one Part thin-film material is defined as the first device area, using the thin film material of the expose portion as the second device area Material is removed;Removing photoresist, the most only first device area is covered by thin-film material;Then at this figure On carry out second time deposit, deposit thin film material layer, deposit thickness is the second thickness, now the first device The thickness of region overlay material is the sum that the first thickness adds the second thickness, the second device area thickness be Two thickness;Anisotropically etch thin-film material, the thin-film material of mask layer top and bottom is removed, only Leave the thin-film material on sidewall;Cineration technics optionally removes mask layer, leaves behind thin-film material and is formed Side wall;Utilize thin-film material to perform etching as the new mask of etching, form the superfinishing with two kinds of sizes Thin figure, two kinds of sizes are determined by the first thickness and the second thickness depositing thin film.
The method that employing bilateral wall technique the most according to claim 1 forms ultralow size figure, it is special Levying and be, mask layer is amorphous carbon film.
The method that employing bilateral wall technique the most according to claim 1 and 2 forms ultralow size figure, It is characterized in that, fisrt feature size is equal to the pole of the optical resolution of high-resolution photomask etching system Limit.
The method that employing bilateral wall technique the most according to claim 1 and 2 forms ultralow size figure, It is characterized in that, thin-film material is silicon dioxide or silicon nitride.
The method that employing bilateral wall technique the most according to claim 1 and 2 forms ultralow size figure, It is characterized in that, the size of the second device area is less than the size of the first device area.
6. one kind uses the method that bilateral wall technique forms ultralow size figure, it is characterised in that including: formed Silicon dioxide gate dielectric layer, forms polysilicon gate, and forms mask layer on polysilicon gate, and use photoetching Technique forms the mask graph with fisrt feature size;Mask graph covers layer of silicon dioxide conformal Layer, forms the side wall of uniform fold mask graph, and on side wall, the thickness of thin film is the first thickness;Perform subsequently Photoetching for the second time is also developed, and photoresist covers a part of silicon dioxide conforma layer, part conformal that will expose Layer is removed clean, and definition overlay area is the first device area, and expose portion is the second device area;Remove Photoresist also carries out depositing for the second time silicon dioxide, forms the side wall of uniform fold mask graph, deposit thickness Being the second thickness, now the first device area covers the thickness of silicon dioxide is that the first thickness adds the second thickness With, the second device area thickness be the second thickness;Anisotropic etching silicon dioxide, by mask layer The silicon dioxide of top and bottom is removed, and leaves behind the thin film on sidewall;Oxygen ashing process is used to remove sudden and violent It is exposed at the mask layer on surface;Use dry etching to etch the conforma layer carried over, and etch as hard mask Polysilicon gate and gate dielectric layer, form grid structure, and the size of the grid structure finally obtained has two kinds, the Two thickness be the second size of the second requirement on devices, the first thickness and the second thickness and be the first requirement on devices First size.
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CN110739210B (en) * 2018-07-18 2022-04-12 中芯国际集成电路制造(北京)有限公司 Semiconductor structure and forming method thereof

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