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CN103981008A - High-performance environment-friendly water-based honing working fluid - Google Patents

High-performance environment-friendly water-based honing working fluid Download PDF

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Publication number
CN103981008A
CN103981008A CN201410219549.XA CN201410219549A CN103981008A CN 103981008 A CN103981008 A CN 103981008A CN 201410219549 A CN201410219549 A CN 201410219549A CN 103981008 A CN103981008 A CN 103981008A
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CN
China
Prior art keywords
working fluid
performance environment
friendly type
water base
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Application number
CN201410219549.XA
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Chinese (zh)
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CN103981008B (en
Inventor
林丽静
阿部聪
常建忠
俞威
茅晓华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
QIDONG YOUXILU CHEMICAL INDUSTRY Co Ltd
Shanghai Yushiro Chemical Industry Co Ltd
Original Assignee
QIDONG YOUXILU CHEMICAL INDUSTRY Co Ltd
Shanghai Yushiro Chemical Industry Co Ltd
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Priority to CN201410219549.XA priority Critical patent/CN103981008B/en
Publication of CN103981008A publication Critical patent/CN103981008A/en
Application granted granted Critical
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Abstract

The invention discloses a high-performance environment-friendly water-based honing working fluid. The high-performance environment-friendly water-based honing working fluid is composed of an organic acid, an organic amine, a synthetic lubricant, a novel surface active agent, a corrosion inhibitor, water and a defoaming agent. The high-performance environment-friendly water-based honing working fluid has excellent lubricating property, foaming property, abrasive dust separating and settling property and penetrating quality.

Description

The water base honing working fluid of high-performance environment-friendly type
Technical field
The present invention relates to a kind of water base honing working fluid.
Background technology
Honing is a kind of under low cutting speed operating mode, and the polishing processing to workpiece surface its objective is in order effectively to improve dimensional precision, the geometrical precision of workpiece, reduces the surfaceness of workpiece.For obtaining good lubricant effect, for a long time, the honing working fluid of supporting application, all adopts that to take the mineral oil of deep refining be base oil substantially, adds multiple auxiliary agent agent blending and forms.Because oil-base fluid exists potential safety hazard (smolder, mist of oil, easily catch fire) and workpiece not easy cleaning, less economical etc. outstanding drawback, so be cooled just gradually at present that cleaning performance is good, security and better economy water base fluid substitute.But commercially available honing water base fluid also exists some problems to fail to solve at present.The one, oilness undesirable (during 3% concentration, coefficientoffrictionμ > 0.15), causes workpiece dimensional precision, geometrical precision poor, and surfaceness is high; The 2nd, foaming properties, abrasive dust settleability are poor, and 10000 revs/min of foam time >=30s(high-speed stirring stop after stirring 5min), abrasive dust settling time >=40s (adding 1%200 order iron powders in 3% diluent); The 3rd, poor permeability (3% concentration, 100 order iron particle sizes, penetration time >=25s), the 4th, contains the toxic substances such as Sodium Nitrite in formula constituent, be detrimental to health.
Summary of the invention
The object of the present invention is to provide a kind of easily manufactured, the water base honing working fluid of high-performance environment-friendly type of excellent performance.
Technical solution of the present invention is:
The water base honing working fluid of high-performance environment-friendly type, is characterized in that: the one-tenth by following weight percent is grouped into:
Organic acid 5-15%
Organic amine 10-20%
Synthetic lubricant 10-20%
Novel surfactant 1-10%
Inhibiter 1-3%
Water 30-50%
Defoamer 0-3%; .
Above-mentioned each amounts of components sum is 100%.
Organic acid is C 6-C 14straight chain diatomic acid, C 8-C 10one or more in lipid acid, p-tert-butyl benzoic acid, p-nitrobenzoic acid or sulfamic acid compound.
Organic amine is Monoethanolamine MEA BASF, monoisopropanolamine, diisopropanolamine (DIPA), tri-isopropanolamine, N, and N-bis-polyoxyethylene N-encircle one or more in amine, the amino 2-methylpropanol of 2-, 2-(2-amino ethoxy) ethanol.
Inhibiter is benzotriazole, methyl benzotriazazole tiger 2-mercaptobenzothiazole.
Synthetic lubricant is one or more in Macrogol 4000, polyethylene glycol 6000, polypropylene glycol 2000, polypropylene glycol 4000, modified fatty acid ester.
Novel surfactant is one or more in polyoxyethylene polyoxypropylene block polyether, glycerin polyoxyethylene polyethenoxy ether, polyvinylamine, isomery alcohol ether.
Defoamer is one or more in silicone emulsion, methyl-silicone oil, dimethyl silicone oil.
Advantage of the present invention is:
1, this product has excellent lubricity.Select new type water-solubility synthetic lubricant, make product 3% concentration dilution liquid frictional coefficient≤0.03.
2, this product has excellent foaming properties and abrasive dust settling property.Select novel high polymer tensio-active agent, make product 3% concentration dilution liquid, 10000 revs/min of foam time≤6s(high-speed stirring, stop after stirring 5min), in abrasive dust separate and subside time≤20s(2% diluent, add 1%200 order iron powders).
3, this product has excellent penetrating quality, selects novel surfactant, makes penetration time≤5s(100 order iron particle size of product 3% concentration dilution liquid).
4, this product has reliable safety and sanitation performance.Formula for a product raw material is not used and jeopardizes HUMAN HEALTH and environmental safety objectionable impurities.The biological Lethal Dose 50 LD50(mg/kg of product)>=5000, toxic limit medium dose LC50(mg/m 3)>=5000, respiratory mucosa stimulates≤1 grade.
Below in conjunction with embodiment, the invention will be further described.
Embodiment
Embodiment 1:
Component mix and blend by following weight percent, obtains product:
Chinese cassia tree diacid 3%
Sebacic acid 3%
Sad 4%
N-nonanoic acid 3%
The amino 2-methylpropanol 7% of 2-
2-(2-amino ethoxy) ethanol 6%
Polypropylene glycol 2,000 8%
Polyoxyethylene polyoxypropylene block polyether 15%
Polyvinylamine 2%
Isomery alcohol ether 2%
Methyl benzotriazazole 0.5%
Silicone emulsion 0.5%
Water 46%.
This product has excellent lubricity.Select new type water-solubility synthetic lubricant, make product 3% concentration dilution liquid frictional coefficient≤0.03.This product has excellent foaming properties and abrasive dust settling property.Select novel high polymer tensio-active agent, make product 3% concentration dilution liquid, 10000 revs/min of foam time≤6s(high-speed stirring, stop after stirring 5min), in abrasive dust separate and subside time≤20s(2% diluent, add 1%200 order iron powders).This product has excellent penetrating quality, selects novel surfactant, makes penetration time≤5s(100 order iron particle size of product 3% concentration dilution liquid).This product has reliable safety and sanitation performance.Formula for a product raw material is not used and jeopardizes HUMAN HEALTH and environmental safety objectionable impurities.The biological Lethal Dose 50 LD50(mg/kg of product)>=5000, toxic limit medium dose LC50(mg/m 3)>=5000, respiratory mucosa stimulates≤1 grade.
Embodiment 2:
The water base honing working fluid of high-performance environment-friendly type, is grouped into by the one-tenth of following weight percent:
Organic acid 5-15%(example 5%, 10%, 15%)
Organic amine 10-20%(example 10%, 15%, 20%)
Synthetic lubricant 10-20%(example 10%, 15%, 20%)
Novel surfactant 1-10%(example 1%, 5%, 10%)
Inhibiter 1-3%(example 1%, 2%, 3%)
Water 30-50%(example 30%, 40%, 50%)
Defoamer 0-3%(example 1%, 2%, 3%); .
Above-mentioned each amounts of components sum is 100%.
Organic acid is C 6-C 14straight chain diatomic acid, C 8-C 10one or more in lipid acid, p-tert-butyl benzoic acid, p-nitrobenzoic acid or sulfamic acid compound.
Organic amine is Monoethanolamine MEA BASF, monoisopropanolamine, diisopropanolamine (DIPA), tri-isopropanolamine, N, and N-bis-polyoxyethylene N-encircle one or more in amine, the amino 2-methylpropanol of 2-, 2-(2-amino ethoxy) ethanol.
Inhibiter is benzotriazole, methyl benzotriazazole tiger 2-mercaptobenzothiazole.
Synthetic lubricant is one or more in Macrogol 4000, polyethylene glycol 6000, polypropylene glycol 2000, polypropylene glycol 4000, modified fatty acid ester.
Novel surfactant is one or more in polyoxyethylene polyoxypropylene block polyether, glycerin polyoxyethylene polyethenoxy ether, polyvinylamine, isomery alcohol ether.
Defoamer is one or more in silicone emulsion, methyl-silicone oil, dimethyl silicone oil.

Claims (7)

1. the water base honing working fluid of high-performance environment-friendly type, is characterized in that: the one-tenth by following weight percent is grouped into:
Organic acid 5-15%
Organic amine 10-20%
Synthetic lubricant 10-20%
Novel surfactant 1-10%
Inhibiter 1-3%
Water 30-50%
Defoamer 0-3%; .
Above-mentioned each amounts of components sum is 100%.
2. the water base honing working fluid of high-performance environment-friendly type according to claim 1, is characterized in that: organic acid is C 6-C 14straight chain diatomic acid, C 8-C 10one or more in lipid acid, p-tert-butyl benzoic acid, p-nitrobenzoic acid or sulfamic acid compound.
3. the water base honing working fluid of high-performance environment-friendly type according to claim 1 and 2, it is characterized in that: organic amine is Monoethanolamine MEA BASF, monoisopropanolamine, diisopropanolamine (DIPA), tri-isopropanolamine, N, N-bis-polyoxyethylene N-encircle one or more in amine, the amino 2-methylpropanol of 2-, 2-(2-amino ethoxy) ethanol.
4. the water base honing working fluid of high-performance environment-friendly type according to claim 1, is characterized in that: inhibiter is benzotriazole, methyl benzotriazazole tiger 2-mercaptobenzothiazole.
5. the water base honing working fluid of high-performance environment-friendly type according to claim 1, is characterized in that: synthetic lubricant is one or more in Macrogol 4000, polyethylene glycol 6000, polypropylene glycol 2000, polypropylene glycol 4000, modified fatty acid ester.
6. the water base honing working fluid of high-performance environment-friendly type according to claim 1, is characterized in that: novel surfactant is one or more in polyoxyethylene polyoxypropylene block polyether, glycerin polyoxyethylene polyethenoxy ether, polyvinylamine, isomery alcohol ether.
7. the water base honing working fluid of high-performance environment-friendly type according to claim 1, is characterized in that: defoamer is one or more in silicone emulsion, methyl-silicone oil, dimethyl silicone oil.
CN201410219549.XA 2014-05-23 2014-05-23 The water base Honing process liquid of high-performance environment-friendly type Active CN103981008B (en)

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104388956A (en) * 2014-10-14 2015-03-04 东莞市四辉表面处理科技有限公司 Plane grinding detergent
CN104818100A (en) * 2015-03-18 2015-08-05 启东尤希路化学工业有限公司 Environment-friendly and low-cost special grinding fluid for steel ball hard grinding
CN104830285A (en) * 2015-04-23 2015-08-12 东莞市博奥润滑油有限公司 High-frequency welded tube processing liquid
CN104911015A (en) * 2015-06-30 2015-09-16 陕西航宇化工有限公司 Honing solution and preparation method thereof
CN105802581A (en) * 2016-03-28 2016-07-27 启东尤希路化学工业有限公司 Waterborne grinding fluid for sapphire wafer processing
CN106367188A (en) * 2016-08-12 2017-02-01 浙江模德石化有限公司 Water-soluble processing solution for slicing of hard and brittle material and preparation method thereof
CN106381209A (en) * 2016-08-23 2017-02-08 蚌埠精科机床制造有限公司 A preparing method of a water-based cutting fluid specially used for honing
CN106675751A (en) * 2016-12-20 2017-05-17 广东山之风环保科技有限公司 Glass cutting fluid
CN107987942A (en) * 2017-11-24 2018-05-04 重庆信人科技发展有限公司 A kind of water base high molecular grinding fluid
CN109913310A (en) * 2019-04-24 2019-06-21 上海尤希路化学工业有限公司 The miniature iron shot hard grind special-purpose water-based milling liquid of diameter 0.5mm-2.0mm
CN114317075A (en) * 2021-12-03 2022-04-12 广东红日星实业有限公司 Cutting fluid and preparation method and application thereof
CN115340900A (en) * 2021-12-31 2022-11-15 福建嘉富顿环保科技有限公司 Environment-friendly water-based honing fluid and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050245403A1 (en) * 2004-05-03 2005-11-03 Harris Charles P Gear cutting oil
CN103045341A (en) * 2013-01-08 2013-04-17 启东尤希路化学工业有限公司 Grinding fluid for processing high-performance superhard alloy

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050245403A1 (en) * 2004-05-03 2005-11-03 Harris Charles P Gear cutting oil
CN103045341A (en) * 2013-01-08 2013-04-17 启东尤希路化学工业有限公司 Grinding fluid for processing high-performance superhard alloy

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104388956A (en) * 2014-10-14 2015-03-04 东莞市四辉表面处理科技有限公司 Plane grinding detergent
CN104818100A (en) * 2015-03-18 2015-08-05 启东尤希路化学工业有限公司 Environment-friendly and low-cost special grinding fluid for steel ball hard grinding
CN104830285A (en) * 2015-04-23 2015-08-12 东莞市博奥润滑油有限公司 High-frequency welded tube processing liquid
CN104911015B (en) * 2015-06-30 2018-05-29 陕西航宇化工有限公司 A kind of grinding fluid and preparation method thereof
CN104911015A (en) * 2015-06-30 2015-09-16 陕西航宇化工有限公司 Honing solution and preparation method thereof
CN105802581A (en) * 2016-03-28 2016-07-27 启东尤希路化学工业有限公司 Waterborne grinding fluid for sapphire wafer processing
CN106367188A (en) * 2016-08-12 2017-02-01 浙江模德石化有限公司 Water-soluble processing solution for slicing of hard and brittle material and preparation method thereof
CN106381209A (en) * 2016-08-23 2017-02-08 蚌埠精科机床制造有限公司 A preparing method of a water-based cutting fluid specially used for honing
CN106675751A (en) * 2016-12-20 2017-05-17 广东山之风环保科技有限公司 Glass cutting fluid
CN106675751B (en) * 2016-12-20 2020-04-10 广东山之风环保科技有限公司 Glass cutting fluid
CN107987942A (en) * 2017-11-24 2018-05-04 重庆信人科技发展有限公司 A kind of water base high molecular grinding fluid
CN109913310A (en) * 2019-04-24 2019-06-21 上海尤希路化学工业有限公司 The miniature iron shot hard grind special-purpose water-based milling liquid of diameter 0.5mm-2.0mm
CN114317075A (en) * 2021-12-03 2022-04-12 广东红日星实业有限公司 Cutting fluid and preparation method and application thereof
CN115340900A (en) * 2021-12-31 2022-11-15 福建嘉富顿环保科技有限公司 Environment-friendly water-based honing fluid and preparation method thereof
CN115340900B (en) * 2021-12-31 2024-02-13 福建嘉富顿环保科技有限公司 Environment-friendly water-based honing liquid and preparation method thereof

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