CN103883812A - Inside spin type high-temperature-resisting ultra-quiet drainage pipe and manufacturing method thereof - Google Patents
Inside spin type high-temperature-resisting ultra-quiet drainage pipe and manufacturing method thereof Download PDFInfo
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- CN103883812A CN103883812A CN201410089961.4A CN201410089961A CN103883812A CN 103883812 A CN103883812 A CN 103883812A CN 201410089961 A CN201410089961 A CN 201410089961A CN 103883812 A CN103883812 A CN 103883812A
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L9/00—Rigid pipes
- F16L9/21—Rigid pipes made of sound-absorbing materials or with sound-absorbing structure
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/02—Making granules by dividing preformed material
- B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/09—Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L11/00—Hoses, i.e. flexible pipes
- F16L11/04—Hoses, i.e. flexible pipes made of rubber or flexible plastics
- F16L11/12—Hoses, i.e. flexible pipes made of rubber or flexible plastics with arrangements for particular purposes, e.g. specially profiled, with protecting layer, heated, electrically conducting
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L11/00—Hoses, i.e. flexible pipes
- F16L11/26—Hoses, i.e. flexible pipes made of sound-absorbing materials or with sound-absorbing structure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/10—Polymers of propylene
- B29K2023/14—Copolymers of polypropylene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
Abstract
The invention discloses an inside spin type high-temperature-resisting ultra-quiet drainage pipe and a manufacturing method thereof to solve the problem that existing drainage pipes are high in noise, not resistant to high temperature and high in cost and relates to the technical field of drainage. The inside spin type high-temperature-resisting ultra-quiet drainage pipe comprises a denoising layer, wherein spiral ribs are arranged on the inner wall of the denoising layer, the denoising layer is manufactured from, by weight, 20-35 percent of block co-polypropylene, 5-10 percent of viscous elastic bodies, 50-70 percent of barium sulfate, 2-3 percent of dispersing agents, 1-2 percent of coupling reagents, and 1-2 percent of lubricants, and a high-temperature-resistant polypropylene resin layer is further arranged on the outer surface of the denoising layer. According to the spin type high-temperature-resisting ultra-quiet drainage pipe and the manufacturing method thereof, by means of the denoising layer and the spiral ribs on the inner wall of the denoising layer, water falling noise of a building plastic pipeline system can be reduced to a level below 35 decibel, the heat-resistance temperature of a pipeline can reach 90 DEG C, the manufacturing cost of the drainage pipe is 10% less than that of a flexible cast-iron pipe, the service life of the pipe can reach 50 years, and the drainage pipe is easy to install, low in cost, economical and practical.
Description
Technical field
The present invention relates to plumbing technical field, refer to especially the high temperature resistant super-silent waste pipe of a kind of polypropylene with internal spiral and manufacture method thereof.
Background technique
Along with present information and scientific and technological fast development, the development of construction industry is also very fast, and the height of building is higher, and its requirement to water discharge technology is larger.Building plastic waste pipe comes across the end of the eighties in last century the earliest, and using maximum is PVC＝polyvinyl chloride (PVC) solid wall pipe, but PVC＝polyvinyl chloride (PVC) solid wall pipe waterfall noise is large, reaches 76 decibels.In order to reduce noise, developed successively again hard polyethylene (UPVC) silencing drainage pipe in the nineties, hard polyethylene (UPVC) silencing drainage pipe belongs to mould the energy-conserving product of Dai Gang, UPVC silencing drainage pipe for building be mould for soundproof effect in product made from steel good, but, these effects that reduce noise are limited, the noise that only reduces 5-7 decibel than common PVC solid wall pipe, drainage noise is more than 60 decibels, still very large, the noise of pipe-line system is still higher than cast iron tube, and resistance to high temperature is poor, aging fast, shock resistance is poor, and the life-span is short.
Modern society's commercialize housing development is very fast, provide hot-water supply system compared with big city commercial housing, apartment, office building, restaurant, hotel, physical culture place and recreation center more, even if the house that does not adopt Central Domestic Hot Water to supply with is also all designed with independent heat supply water piping system, conventionally waste discharge temperature is below 40 ℃, but there is considerable possibility chance exhaust temperature at 50-60 ℃, the heat resisting temperature of UPVC silencing drainage pipe is 50 ℃, if be heated for a long time intensity and the working life that can cause tubing heat ageing and reduce tubing.
Along with improving constantly of living standard, people are also more and more higher to building human settlement's requirement, and noise pollution becomes the pollution after atmospheric pollution, human lives being had the greatest impact.During due to high-rise building draining, the underwater sound is seriously polluted, and used UPVC silencing drainage pipe pipeline soundproof effect is poor, heatproof not again, and many developers select flexible iron drain-pipe to replace UPVC silencing drainage pipe at tall building; But although flexible iron drain-pipe soundproof effect is good, perishable, working life is short, not only tubing cost is high, and mounting process complexity, and tubing itself is heavy, and transportation installation cost is high, in addition perishable, installation and maintenance expense is high, and Integrated using cost than the high 3-4 of UPVC silencing drainage pipe doubly.
Summary of the invention
The present invention proposes the high temperature resistant super-silent waste pipe of a kind of internal spiral and manufacture method thereof, has solved in prior art in use large, the non-refractory of noise and the high problem of cost of waste pipe.
Technological scheme of the present invention is achieved in that the high temperature resistant super-silent waste pipe of internal spiral of the present invention, comprise noise reduction layer, described noise reduction layer inwall is provided with screw rib, described noise reduction layer is quiet material layer, and described quiet material layer is made up of the raw material of following weight portion: block copolymerization polypropylene 20-35%, viscous elastomer 5-10%, barium sulphate 50-70%, dispersing agent 2-3%, coupling agent 1-2%, oiling agent 1-2%.
The present invention, by the setting of noise reduction layer and internal spiral, has further been reduced to the waterfall noise of construction drainage plastic duct system below 35 decibels, and the heat resisting temperature of waste pipe reaches 90 ℃.Noise reduction layer as carrier, and plays adhesive effect by block copolymerization polypropylene material; Barium sulphate is as a kind of important rigid inorganic sound absorbing material, and because the structure of molecule of barium sulphate has silencing function, the density of barium sulphate is large simultaneously, has improved the density of tubing, thereby absorbs sound wave, reduces noise; The interpolation of viscous elastomer is mainly the toughness in order to increase material, meanwhile, also reaches the effect of further noise reduction, improves the impact resistance of tubing; The effect of dispersing agent is to make block copolymerization polypropylene, barium sulphate and viscous elastomer etc. carry out fully disperseing it is mixed, and improves the homogeneity of material; Strengthen the interface performance between inorganic material barium sulphate and organic material block copolymerization polypropylene etc. by coupling agent, make barium sulphate and block copolymerization polypropylene etc. carry out combination better; The effect of oiling agent is the friction reducing between material and material, reduces the friction of material and machinery equipment, improves the processibility of raw material.The cost of this waste pipe has reduced by 10% than flexible cast iron tube, and reach 50 years the working life of waste pipe pipeline, is easy to install, and cost is low.
As the preferred embodiment of one, described dispersing agent is one or both in zine stearate and Tissuemat E; Described oiling agent is one or both in stearic acid and white oil.Zine stearate and Tissuemat E are as two kinds of conventional dispersing agents, and its dispersion effect is good, cheap, easily obtain, and can combine together with acrylic resin, quiet stuffing better; Equally, adopt stearic acid and white oil as oiling agent, its lubrication effect is obvious, is convenient to store, easy to use.
As the preferred embodiment of one, the quantity of described screw rib is 3-12 bar.Screw rib is located on the internal surface of noise reduction layer, and protrusion is surperficial upper therein, and its sectional area is triangular in shape, and its helix angle is 25-80 °.In the process of draining, current, along the spiral whereabouts of screw rib of waste pipe inwall, have reduced the impact force of current to pipe material inner wall and tubing connection corner, reach the object that reduces noise; The current that rotation is fallen simultaneously have to pipe material inner wall the self-cleaning function of washing away, thereby make tubing also have self-cleaning function in reducing noise, make tubing be difficult for stopping up, and have reduced maintenance cost; The quantity of screw rib and angle can be carried out appropriateness adjustment according to the diameter of tubing.
As the preferred embodiment of one, described noise reduction layer outer surface is provided with one deck skin, and described skin is block copolymerization polypropylene resin layer.At the outer surface of noise reduction layer, fire resistant polypropylene protection is set outer, this fire resistant polypropylene resin layer has high temperature resistant, shock proof characteristic, can protect noise reduction layer better, strengthens the combination property of waste pipe.
Another kind of internal spiral of the present invention is high temperature resistant super-silent waste pipe, comprise internal layer, noise reduction layer and skin, described internal layer inwall is provided with screw rib, described internal layer is the one in block copolymerization polypropylene resin layer or quiet material layer, described noise reduction layer is quiet material layer, and described skin is block copolymerization polypropylene resin; Described quiet material layer is made up of the raw material of following weight portion: block copolymerization polypropylene 20-35%, viscous elastomer 5-10%, barium sulphate 50-70%, dispersing agent 2-3%, coupling agent 1-2%, oiling agent 1-2%.
Waste pipe of the present invention can be three layers, and noise reduction layer is arranged between internal layer and skin, and internal layer adopts block copolymerization polypropylene resin or quiet material granule to make, and on the inwall of internal layer, spiral is set; Meanwhile, by the outer field protection of fire resistant polypropylene resin, effectively noise reduction layer is carried out to outer layer protection, improve the impact resistance of waste pipe outer surface.Under the effect of noise reduction layer, waterfall noise is reduced, and on the inwall of waste pipe internal layer, internal spiral is set, the existence of internal spiral, change overboard flow direction in waste pipe, reduce current and pipe material inner wall and tubing have been connected to the impact force of corner, thereby played the effect of further reduction noise; The waterfall noise of whole waste pipe has been dropped to below 35 decibels, and the heat resisting temperature of waste pipe reaches 90 ℃.
The manufacture method of the high temperature resistant super-silent waste pipe of internal spiral of the present invention, comprise the following steps: the block copolymerization polypropylene of 1) getting 20-35% weight portion, the viscous elastomer of 5-10% weight portion, the barium sulphate of 50-70% weight portion, the dispersing agent of 2-3% weight portion, the coupling agent of 1-2% weight portion, the oiling agent of 1-2% weight portion, carries out abundant Agitation and mixing, temperature 70-110 ℃ in batch mixer, in parallel dual-screw extruding machine extruding pelletization, make quiet material granule; 2) utilize a single screw extrusion machine to extrude by the extrusion die with rotatable threaded mandril step 1) gained particle, form the pipe with a noise reduction layer single layer structure; 3) by step 2) gained pipe is through vacuum sizing, cooling, traction, cutting upset, and be packaged into finished product.
Internal spiral of the present invention is high temperature resistant super-silent waste pipe, first utilize parallel dual-screw extruding machine that block copolymerization polypropylene and barium sulphate blending and modifying are made to PP Pipe Compound composite material granular---noise reduction layer PP Pipe Compound, recycle a single screw extrusion machine and extrude by the extrusion die with rotatable threaded mandril, thereby form the quiet tubing of individual layer with internal spiral; This noise reduction layer is with the quiet material barium sulphate of block copolymerization polypropylene load, the content of barium sulphate is higher, its muting function is better, simultaneously, the too high levels of barium sulphate also can cause the shock resistance of waste pipe to decline, the weight portion of the quiet material of barium sulphate is 50-70%, and this manufacture method is simple, easy to operate.
The manufacture method of the high temperature resistant super-silent waste pipe of another kind of internal spiral of the present invention, comprise the following steps: the block copolymerization polypropylene of 1) getting 20-35% weight portion, the viscous elastomer of 5-10% weight portion, the barium sulphate of 50-70% weight portion, the dispersing agent of 2-3% weight portion, the coupling agent of 1-2% weight portion, the oiling agent of 1-2% weight portion, carries out abundant Agitation and mixing, temperature 70-110 ℃ in batch mixer, in parallel dual-screw extruding machine extruding pelletization, make quiet material granule; 2) by step 1) gained particle and block copolymerization polypropylene raw material, utilize respectively two single screw extrusion machines to extrude by the two-layer compound co-extruding machine head mould with rotatable threaded mandril, formation has double-deck pipe, and pipe is followed successively by noise reduction layer and the block copolymerization polypropylene resin layer be made up of quiet material from inside to outside; 3) by step 2) gained pipe is through vacuum sizing, cooling, traction, cutting upset, and be packaged into finished product.
Another kind of internal spiral of the present invention is high temperature resistant, and super-silent waste pipe is the high temperature resistant super-silent waste pipe of double-deck internal spiral, and noise reduction layer is in the inner side of tube wall, and noise reduction layer inwall extruded screw rib by mould, and it is outer that noise reduction layer outer surface is provided with fire resistant polypropylene protection; Fire resistant polypropylene raw material and noise reduction layer PP Pipe Compound are extruded by two extruders and by the composite dies with rotatable threaded mandril respectively simultaneously, thereby form the high temperature resistant super-silent waste pipe of double-deck internal spiral.
The manufacture method of the high temperature resistant super-silent waste pipe of another internal spiral of the present invention, comprise the following steps: the block copolymerization polypropylene of 1) getting 20-35% weight portion, the viscous elastomer of 5-10% weight portion, the barium sulphate of 50-70% weight portion, the dispersing agent of 2-3% weight portion, the coupling agent of 1-2% weight portion, the oiling agent of 1-2% weight portion, carries out abundant Agitation and mixing, temperature 70-110 ℃ in batch mixer, in parallel dual-screw extruding machine extruding pelletization, make quiet material granule; 2) by step 1) gained particle and block copolymerization polypropylene raw material, utilize respectively two or three single screw extrusion machines to extrude by three layers of composite co-extruding extrusion die with rotatable threaded mandril, formation has the pipe of three-decker, and internal layer, noise reduction layer and the skin of pipe are followed successively by block copolymerization polypropylene resin layer, quiet material layer and block copolymerization polypropylene resin layer; Or internal layer, noise reduction layer and the skin of pipe are followed successively by quiet material layer, quiet material layer and block copolymerization polypropylene resin layer; 3) by step 2) gained pipe is through vacuum sizing, cooling, traction, cutting upset, and be packaged into finished product.
The present invention can also manufacture a kind of three layers of high temperature resistant super-silent waste pipe of internal spiral, these three layers of internal spirals are high temperature resistant, and super-silent waste pipe internal layer is fire resistant polypropylene resin layer or quiet material layer, on internal layer inwall, has extruded screw rib by the composite co-extruding mould with rotatable threaded mandril; Mesosphere is noise reduction layer, noise reduction layer is the quiet material layer being made up of the quiet material barium sulphate of block copolymerization polypropylene carrying inorganic, this noise reduction layer has resistance to high temperature, density is large, Young's modulus is large, microcaloire softening point is high, has good sound insulation value and high temperature resistant quiet performance; Skin is fire resistant polypropylene resin layer, by fire resistant polypropylene resin, noise reduction layer is carried out to skin protection; This manufacture method is simple, easy to operate.
As the preferred embodiment of one, described dispersing agent is one or both in zine stearate and Tissuemat E; Described oiling agent is one or both in stearic acid and white oil.In manufacture method, zine stearate and Tissuemat E are as two kinds of conventional dispersing agents, and its dispersion effect is good, cheap, easily obtain, and can be combined as a whole with acrylic resin, quiet stuffing better; Equally, adopt stearic acid and white oil as oiling agent, its lubrication effect is obvious, is convenient to store, easy to use.
As the preferred embodiment of one, described noise reduction layer inwall is provided with screw rib, and the quantity of described screw rib is 3-12 bar.Directly extrude internal spiral rib by adopting with the extrusion die of rotatable threaded mandril, according to the difference of waste pipe pipe diameter size, the quantity of screw rib can suitably increase and decrease, and evenly arranges.
Beneficial effect of the present invention: the present invention utilizes block copolymerization polypropylene and the quiet material of the quiet blending and modifying gained of barium sulphate to form noise reduction layer, and is provided with screw rib on noise reduction layer inwall; This waste pipe can further be reduced to the waterfall noise of construction drainage pipeline system below 35 decibels, the heat resisting temperature of waste pipe reaches 90 ℃, and the cost of waste pipe has reduced by 10% than flexible cast iron tube, and reach 50 years the working life of waste pipe, be easy to install, cost is low.When the existence of screw rib makes draining, current fall along waste pipe pipe wall screw, thereby make the pipe-line system of waste pipe have self-cleaning function, are difficult for stopping up, and reduce maintenance cost.
Accompanying drawing explanation
In order to be illustrated more clearly in the embodiment of the present invention or technological scheme of the prior art, to the accompanying drawing of required use in embodiment or description of the Prior Art be briefly described below, apparently, accompanying drawing in the following describes is only some embodiments of the present invention, for those of ordinary skills, do not paying under the prerequisite of creative work, can also obtain according to these accompanying drawings other accompanying drawing.
Fig. 1 is the perspective view of the embodiment of the present invention one;
Fig. 2 is the cross-sectional structure schematic diagram of Fig. 1;
Fig. 3 is the plane structure schematic diagram of Fig. 1;
Fig. 4 is the cross-sectional structure schematic diagram of the embodiment of the present invention two;
Fig. 5 is the cross-sectional structure schematic diagram of the embodiment of the present invention three;
In figure: 1-noise reduction layer; 2-screw rib; 3-the first resin layer; 4-the second resin layer.
Embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technological scheme in the embodiment of the present invention is clearly and completely described, obviously, described embodiment is only the present invention's part embodiment, rather than whole embodiments.Based on the embodiment in the present invention, those of ordinary skills, not making the every other embodiment who obtains under creative work prerequisite, belong to the scope of protection of the invention.
A kind of internal spiral of the present invention is high temperature resistant super-silent waste pipe, comprise noise reduction layer, described noise reduction layer inwall is provided with screw rib, described noise reduction layer is quiet material layer, and described quiet material layer is made up of the raw material of following weight portion: block copolymerization polypropylene 20-35%, viscous elastomer 5-10%, barium sulphate 50-70%, dispersing agent 2-3%, coupling agent 1-2%, oiling agent 1-2%.
Further, described dispersing agent is one or both in zine stearate and Tissuemat E; Described oiling agent is one or both in stearic acid and white oil.
Further, the quantity of described screw rib is 3-12 bar.
Another kind of internal spiral of the present invention is high temperature resistant super-silent waste pipe, described noise reduction layer outer surface is provided with one deck skin, and described skin is block copolymerization polypropylene resin layer.
Another internal spiral of the present invention is high temperature resistant super-silent waste pipe, comprise internal layer, noise reduction layer and skin, described internal layer inwall is provided with screw rib, described internal layer is the one in block copolymerization polypropylene resin layer or quiet material layer, described noise reduction layer is quiet material layer, and described skin is block copolymerization polypropylene resin layer; Described quiet material layer is made up of the raw material of following weight portion: block copolymerization polypropylene 20-35%, viscous elastomer 5-10%, barium sulphate 50-70%, dispersing agent 2-3%, coupling agent 1-2%, oiling agent 1-2%.
The manufacture method of the high temperature resistant super-silent waste pipe of a kind of internal spiral of the present invention, comprise the following steps: the block copolymerization polypropylene of 1) getting 20-35% weight portion, the viscous elastomer of 5-10% weight portion, the barium sulphate of 50-70% weight portion, the dispersing agent of 2-3% weight portion, the coupling agent of 1-2% weight portion, the oiling agent of 1-2% weight portion, carries out abundant Agitation and mixing, temperature 70-110 ℃ in batch mixer, in parallel dual-screw extruding machine extruding pelletization, make quiet material granule; 2) utilize a single screw extrusion machine to extrude by the extrusion die with rotatable threaded mandril step 1) gained particle, form the pipe with a noise reduction layer single layer structure; 3) by step 2) gained pipe is through vacuum sizing, cooling, traction, cutting upset, and be packaged into finished product.
The manufacture method of the high temperature resistant super-silent waste pipe of another kind of internal spiral of the present invention, comprise the following steps: the block copolymerization polypropylene of 1) getting 20-35% weight portion, the viscous elastomer of 5-10% weight portion, the barium sulphate of 50-70% weight portion, the dispersing agent of 2-3% weight portion, the coupling agent of 1-2% weight portion, the oiling agent of 1-2% weight portion, carries out abundant Agitation and mixing, temperature 70-110 ℃ in batch mixer, in parallel dual-screw extruding machine extruding pelletization, make quiet material granule; 2) by step 1) gained particle and block copolymerization polypropylene raw material, utilize respectively two single screw extrusion machines to extrude by the two-layer compound co-extruding machine head mould with rotatable threaded mandril, formation has double-deck pipe, and pipe is from inside to outside followed successively by noise reduction layer and the block copolymerization polypropylene resin layer be made up of quiet material; 3) by step 2) gained pipe is through vacuum sizing, cooling, traction, cutting upset, and be packaged into finished product.
The manufacture method of the high temperature resistant super-silent waste pipe of another internal spiral of the present invention, comprise the following steps: the block copolymerization polypropylene of 1) getting 20-35% weight portion, the viscous elastomer of 5-10% weight portion, the barium sulphate of 50-70% weight portion, the dispersing agent of 2-3% weight portion, the coupling agent of 1-2% weight portion, the oiling agent of 1-2% weight portion, carries out abundant Agitation and mixing, temperature 70-110 ℃ in batch mixer, in parallel dual-screw extruding machine extruding pelletization, make quiet material granule; 2) by step 1) gained particle and block copolymerization polypropylene raw material, utilize respectively two or three single screw extrusion machines to extrude by three layers of composite co-extruding extrusion die with rotatable threaded mandril, formation has the pipe of three-decker, and internal layer, noise reduction layer and the skin of pipe are followed successively by block copolymerization polypropylene resin layer, quiet material layer and block copolymerization polypropylene resin layer; Or internal layer, noise reduction layer and the skin of pipe are followed successively by quiet material layer, quiet material layer and block copolymerization polypropylene resin layer; 3) by step 2) gained pipe is through vacuum sizing, cooling, traction, cutting upset, and be packaged into finished product.
Further, described dispersing agent is one or both in zine stearate and Tissuemat E; Described oiling agent is one or both in stearic acid and white oil.
Further, described noise reduction layer inwall is provided with screw rib, and the quantity of described screw rib is 3-12 bar.
Embodiment one
Certainly, also can be by gained particle and block copolymerization polypropylene raw material, utilize respectively two single screw extrusion machines to extrude by the two-layer compound co-extruding machine head mould with rotatable threaded mandril, formation has double-deck pipe, and pipe is from inside to outside followed successively by noise reduction layer 1 and i.e. the first resin layer 3 of block copolymerization polypropylene resin layer be made up of quiet material; By gained pipe through vacuum sizing, cooling, traction, cutting upset, and be packaged into finished product, thereby obtain outside, for fire resistant polypropylene resin layer, the first resin layer 3, inner side are the high temperature resistant super-silent waste pipe of double-layer coextrusion internal spiral that noise reduction layer 1 and noise reduction layer 1 inwall have screw rib 2.
Equally, this formula gained particle can also form three-layer co-extruded waste pipe, by above-mentioned gained particle and block copolymerization polypropylene raw material, utilize respectively two or three single screw extrusion machines to extrude by three layers of composite co-extruding extrusion die with rotatable threaded mandril, formation has the pipe of three-decker, the internal layer of pipe, noise reduction layer 1 and skin are followed successively by i.e. the second resin layer 4 of block copolymerization polypropylene resin layer, quiet material layer and block copolymerization polypropylene resin layer i.e. the first resin layer 3, certainly, the internal layer of this pipe, noise reduction layer 1 and skin also can be followed successively by quiet material layer, quiet material layer and block copolymerization polypropylene resin layer i.e. the first resin layer 3, gained pipe, through vacuum sizing, cooling, traction, cutting upset, and is packaged into finished product, thereby obtains the high temperature resistant super-silent waste pipe of the three-layer co-extruded internal spiral with internal spiral rib 2.
Embodiment two
Consult the block copolymerization polypropylene (PP-B) of accompanying drawing 4,25% weight portions, 1,1,2 of 5% weight portion, 2-tetraphenyl ethylene (TPE), the BaSO of 64.5% weight portion
4, the dispersing agent of 2.5% weight portion, the coupling agent of 2% weight portion, the stearic acid of 1% weight portion, carries out abundant Agitation and mixing in Mixing roll, 90 ℃ of mixing temperatures; The material mixing, in parallel dual-screw extruding machine extruding pelletization, is made to quiet material granule; By gained particle and block copolymerization polypropylene raw material, utilize respectively two single screw extrusion machines to extrude by the composite co-extruding extrusion die with rotatable threaded mandril, formation has double-deck pipe, and pipe is from inside to outside followed successively by noise reduction layer 1 and i.e. the first resin layer 3 of block copolymerization polypropylene resin layer be made up of quiet material; Gained pipe, through vacuum sizing, cooling, traction, cutting upset, and is packaged into finished product.Thereby obtain having the high temperature resistant super-silent waste pipe of double-deck internal spiral of internal spiral rib 2, described screw rib 2 is 4, the helix angle of described screw rib 2 is 25-45 °, this internal spiral is high temperature resistant, and super-silent waste pipe comprises noise reduction layer 1 and the first resin layer 3, described the first resin layer 3 is fire resistant polypropylene resin layer, and described noise reduction layer 1 is by PP-B25%, TPE5%, BaSO
464.5%, dispersing agent 2.5%, coupling agent 2% and stearic acid 1% form; This internal spiral is high temperature resistant, and super-silent waste pipe can high temperature resistantly reach 90 ℃, and the waterfall noise of construction drainage pipe-line system is down to below 35bd.
Certainly, also gained particle directly can be utilized a single screw extrusion machine extrude by the extrusion die with rotatable threaded mandril, form the pipe with noise reduction layer 1 single layer structure; Gained pipe, through vacuum sizing, cooling, traction, cutting upset, and is packaged into finished product, thereby obtains individual layer and have the high temperature resistant super-silent waste pipe of internal spiral of screw rib 2, this internal spiral is high temperature resistant, and super-silent waste pipe only has one deck noise reduction layer 1.
Equally, this formula gained particle can also form three-layer co-extruded waste pipe, by above-mentioned gained particle and block copolymerization polypropylene raw material, utilize respectively three single screw extrusion machines to extrude by the composite co-extruding extrusion die with rotatable threaded mandril, form the pipe with three-decker, by gained pipe process vacuum sizing, cooling, traction, cutting upset, and be packaged into finished product, thereby obtain internal layer, noise reduction layer 1 and skin are followed successively by i.e. the second resin layer 4 of block copolymerization polypropylene resin layer, quiet material layer and block copolymerization polypropylene resin layer i.e. the high temperature resistant super-silent waste pipe of the three-layer co-extruded internal spiral with internal spiral rib 2 of the first resin layer 3, certainly, can obtain internal layer, noise reduction layer 1 and skin are followed successively by quiet material layer, quiet material layer and block copolymerization polypropylene resin layer i.e. the high temperature resistant super-silent waste pipe of the three-layer co-extruded internal spiral with internal spiral rib 2 of the first resin layer 3, the composition of raw materials of the quiet material layer of its internal layer and the quiet material layer of noise reduction layer 1 can be identical, can be not identical yet, the quiet material layer of internal layer and the quiet material layer of noise reduction layer 1 can configure different colors, certainly, it also can configure identical color.
Embodiment three
Consult the PP-B of accompanying drawing 5,20% weight portions, the thermoplastic elastomer (TPE) (POE) of 10% weight portion, the BaSO of 65% weight portion
4, the zine stearate of 2% weight portion and the mixture of Tissuemat E, the coupling agent of 1% weight portion, the white oil of 2% weight portion, carries out abundant Agitation and mixing in Mixing roll, 110 ℃ of mixing temperatures, the material mixing, in parallel dual-screw extruding machine extruding pelletization, is made to quiet material granule; By above-mentioned gained particle and block copolymerization polypropylene raw material, utilize respectively two single screw extrusion machines to extrude by three layers of composite co-extruding extrusion die with rotatable threaded mandril, form the pipe with internal layer, noise reduction layer 1 and outer three-decker; Gained pipe, through vacuum sizing, cooling, traction, cutting upset, and is packaged into finished product.Thereby obtain three layers of high temperature resistant super-silent waste pipe of internal spiral, this internal spiral is high temperature resistant, and super-silent waste pipe internal layer is i.e. the second resin layer 4 of block copolymerization polypropylene resin layer, internal layer inwall is provided with screw rib 2, the quantity of described screw rib 2 is 6, the helix angle of described screw rib 2 is 25-80 °, mesosphere is noise reduction layer 1, and noise reduction layer 1 is by PP-B20%, TPR10%, BaSO
465%, zine stearate and polyethylene wax mixture 2%, coupling agent 1% and white oil 2% form, skin is also i.e. the first resin layer 3 of block copolymerization polypropylene resin layer, this three-layer co-extruded drainage pipe can high temperature resistantly reach 90 ℃, and the waterfall noise of construction drainage pipe-line system is down to below 35bd.
Certainly, also can directly utilize a single screw extrusion machine to extrude by the extrusion die with rotatable threaded mandril above-mentioned gained particle, form the pipe with noise reduction layer 1 single layer structure; Gained pipe, through vacuum sizing, cooling, traction, cutting upset, and is packaged into finished product, has the high temperature resistant super-silent waste pipe of internal spiral thereby obtain individual layer, this internal spiral is high temperature resistant, and super-silent waste pipe only has one deck noise reduction layer 1.
Equally, also can be by above-mentioned gained particle and block copolymerization polypropylene raw material, utilize respectively two single screw extrusion machines to extrude by the two-layer compound co-extruding machine head mould with rotatable threaded mandril, form and there is double-deck pipe; By gained pipe through vacuum sizing, cooling, traction, cutting upset, and be packaged into finished product, thereby obtain outside for block copolymerization polypropylene resin layer be that the first resin layer 3, inner side are the high temperature resistant super-silent waste pipe of double-layer coextrusion internal spiral that the noise reduction layer 1 be made up of quiet material and noise reduction layer 1 inwall have internal spiral.
Embodiment four
The PP-B of 20% weight portion, the POE of 5% weight portion, the BaSO of 70% weight portion
4, the Tissuemat E of 3% weight portion, the coupling agent of 1% weight portion, the white oil of 1% weight portion, carries out abundant Agitation and mixing in Mixing roll, and 100 ℃ of mixing temperatures in parallel dual-screw extruding machine extruding pelletization, are made quiet material granule by the material mixing; Utilize a single screw extrusion machine to extrude by the extrusion die with rotatable threaded mandril gained particle, form and there is the pipe of noise reduction layer 1 single layer structure, gained pipe, through vacuum sizing, cooling, traction, cutting upset, and is packaged into finished product.Thereby obtain by PP-B20%, TPR5%, BaSO
4the high temperature resistant super-silent waste pipe of individual layer internal spiral of the noise reduction layer 1 that 70%, Tissuemat E 3%, coupling agent 1% and white oil 1% form, this individual layer internal spiral is high temperature resistant, and super-silent waste pipe is provided with screw rib 2 on noise reduction layer 1 inwall, the quantity of described screw rib 2 is 3, and the helix angle of described screw rib 2 is 45 °; This individual layer internal spiral is high temperature resistant, and super-silent drainage pipe can high temperature resistantly reach 90 ℃, and the waterfall noise of construction drainage pipe-line system is down to below 35bd.
Certainly, also can, by above-mentioned gained particle and block copolymerization polypropylene raw material, extrude by the two-layer compound co-extruding machine head mould with rotatable threaded mandril at two single screw extrusion machines respectively, form tubing; By gained tubing through vacuum sizing, cooling, traction, cutting upset, and be packaged into finished product, be that fire resistant polypropylene resin layer, inner side are the high temperature resistant super-silent waste pipe of double-layer coextrusion internal spiral that noise reduction layer 1 and noise reduction layer 1 inwall have spiral thereby obtain outside.
Equally, this formula gained particle can also form three-layer co-extruded waste pipe, first, according to identical method, by the PP-B of 33% weight portion, the POE of 9% weight portion, the BaSO of 51% weight portion
4the Tissuemat E of 3% weight portion, the coupling agent of 2% weight portion, the white oil of 2% weight portion, make quiet material two, by this quiet material two, above-mentioned gained particle and block copolymerization polypropylene raw material, utilize respectively three single screw extrusion machines to extrude by three layers of composite co-extruding extrusion die with rotatable threaded mandril, form the pipe with three-decker; By gained pipe through vacuum sizing, cooling, traction, cutting upset, and be packaged into finished product, be followed successively by the three-layer co-extruded with the high temperature resistant super-silent waste pipe of internal spiral of quiet material layer, quiet material layer and block copolymerization polypropylene resin layer thereby obtain internal layer, noise reduction layer 1 and skin.
Embodiment five
The PP-B of 30% weight portion, the TPE of 8% weight portion, the BaSO of 55% weight portion
4, the Tissuemat E of 3% weight portion, the coupling agent of 2% weight portion, the stearic acid of 2% weight portion and the mixture of white oil, carry out abundant Agitation and mixing in Mixing roll, 80 ℃ of mixing temperatures; The material mixing, in parallel dual-screw extruding machine extruding pelletization, is made to quiet material granule; By gained particle and block copolymerization polypropylene raw material, utilize respectively two single screw extrusion machines to extrude by the composite co-extruding extrusion die with rotatable threaded mandril, form and there is double-deck pipe; Gained pipe, through vacuum sizing, cooling, traction, cutting upset, and is packaged into finished product.Thereby obtain the high temperature resistant super-silent waste pipe of double-deck internal spiral, this internal spiral is high temperature resistant, and super-silent waste pipe comprises the first resin layer 3 of noise reduction layer 1 and noise reduction layer 1 outer surface, the first resin layer 3 is fire resistant polypropylene resin layer, and described noise reduction layer 1 is by PP-B30%, TPE8%, BaSO
455%, dispersing agent 3%, coupling agent 2% and stearic acid 2% form, and described noise reduction layer 1 inwall is provided with screw rib 2, and the quantity of described screw rib 2 is 12, and the helix angle of described screw rib 2 is 25 °; This internal spiral is high temperature resistant, and super-silent waste pipe can high temperature resistantly reach 90 ℃, and the waterfall noise of construction drainage pipe-line system is down to below 35bd.
Certainly, also can directly utilize a single screw extrusion machine to extrude by the extrusion die with rotatable threaded mandril above-mentioned gained particle, form the pipe with noise reduction layer 1 individual layer; Gained pipe, through vacuum sizing, cooling, traction, cutting upset, and is packaged into finished product, has the high temperature resistant super-silent waste pipe of internal spiral thereby obtain individual layer, this internal spiral is high temperature resistant, and super-silent waste pipe only has one deck is noise reduction layer 1.
Equally, this formula gained particle can also form three-layer co-extruded waste pipe, by above-mentioned gained particle and block copolymerization polypropylene raw material, utilize respectively three single screw extrusion machines to extrude by the composite co-extruding extrusion die with rotatable threaded mandril, form the pipe of the three-decker that is followed successively by from inside to outside block copolymerization polypropylene resin layer, noise reduction layer 1 and block copolymerization polypropylene resin layer; Gained pipe is through vacuum sizing, cooling, traction, cutting upset, and is packaged into finished product, obtains the high temperature resistant super-silent waste pipe of three-layer co-extruded internal spiral.
The foregoing is only preferred embodiment of the present invention, in order to limit the present invention, within the spirit and principles in the present invention not all, any modification of doing, be equal to replacement, improvement etc., within all should being included in protection scope of the present invention.
Claims (10)
1. the high temperature resistant super-silent waste pipe of internal spiral, comprises noise reduction layer, it is characterized in that, described noise reduction layer inwall is provided with screw rib, and described noise reduction layer is quiet material layer;
Described quiet material layer is made up of the raw material of following weight portion: block copolymerization polypropylene 20-35%, viscous elastomer 5-10%, barium sulphate 50-70%, dispersing agent 2-3%, coupling agent 1-2%, oiling agent 1-2%.
2. the high temperature resistant super-silent waste pipe of internal spiral according to claim 1, is characterized in that:
Described dispersing agent is one or both in zine stearate and Tissuemat E;
Described oiling agent is one or both in stearic acid and white oil.
3. the high temperature resistant super-silent waste pipe of internal spiral according to claim 1, is characterized in that:
The quantity of described screw rib is 3-12 bar.
4. the high temperature resistant super-silent waste pipe of internal spiral according to claim 1, is characterized in that:
Described noise reduction layer outer surface is provided with one deck skin, and described skin is block copolymerization polypropylene resin layer.
5. the high temperature resistant super-silent waste pipe of internal spiral, comprises internal layer, noise reduction layer and skin, it is characterized in that:
Described internal layer inwall is provided with screw rib, and described internal layer is the one in block copolymerization polypropylene resin layer or quiet material layer, and described noise reduction layer is quiet material layer, and described skin is block copolymerization polypropylene resin layer;
Described quiet material layer is made up of the raw material of following weight portion: block copolymerization polypropylene 20-35%, viscous elastomer 5-10%, barium sulphate 50-70%, dispersing agent 2-3%, coupling agent 1-2%, oiling agent 1-2%.
6. the manufacture method of the high temperature resistant super-silent waste pipe of internal spiral according to claim 1, is characterized in that, comprises the following steps:
1) get the block copolymerization polypropylene of 20-35% weight portion, the viscous elastomer of 5-10% weight portion, the barium sulphate of 50-70% weight portion, the dispersing agent of 2-3% weight portion, the coupling agent of 1-2% weight portion, the oiling agent of 1-2% weight portion, carry out abundant Agitation and mixing in batch mixer, temperature 70-110 ℃, in parallel dual-screw extruding machine extruding pelletization, makes quiet material granule;
2) utilize a single screw extrusion machine to extrude by the extrusion die with rotatable threaded mandril step 1) gained particle, form the pipe with a noise reduction layer single layer structure;
3) by step 2) gained pipe is through vacuum sizing, cooling, traction, cutting upset, and be packaged into finished product.
7. the manufacture method of the high temperature resistant super-silent waste pipe of internal spiral according to claim 4, is characterized in that, comprises the following steps:
1) get the block copolymerization polypropylene of 20-35% weight portion, the viscous elastomer of 5-10% weight portion, the barium sulphate of 50-70% weight portion, the dispersing agent of 2-3% weight portion, the coupling agent of 1-2% weight portion, the oiling agent of 1-2% weight portion, carry out abundant Agitation and mixing in batch mixer, temperature 70-110 ℃, in parallel dual-screw extruding machine extruding pelletization, makes quiet material granule;
2) by step 1) gained particle and block copolymerization polypropylene raw material, utilize respectively two single screw extrusion machines to extrude by the two-layer compound co-extruding machine head mould with rotatable threaded mandril, formation has double-deck pipe, and pipe is from inside to outside followed successively by noise reduction layer and the block copolymerization polypropylene resin layer be made up of quiet material granule;
3) by step 2) gained pipe is through vacuum sizing, cooling, traction, cutting upset, and be packaged into finished product.
8. the manufacture method of the high temperature resistant super-silent waste pipe of internal spiral according to claim 5, is characterized in that, comprises the following steps:
1) get the block copolymerization polypropylene of 20-35% weight portion, the viscous elastomer of 5-10% weight portion, the barium sulphate of 50-70% weight portion, the dispersing agent of 2-3% weight portion, the coupling agent of 1-2% weight portion, the oiling agent of 1-2% weight portion, carry out abundant Agitation and mixing in batch mixer, temperature 70-110 ℃, in parallel dual-screw extruding machine extruding pelletization, makes quiet material granule;
2) by step 1) gained particle and block copolymerization polypropylene raw material, utilize respectively two or three single screw extrusion machines to extrude by three layers of composite co-extruding extrusion die with rotatable threaded mandril, formation has the pipe of three-decker, and internal layer, noise reduction layer and the skin of pipe are followed successively by block copolymerization polypropylene resin layer, quiet material layer and block copolymerization polypropylene resin layer; Or internal layer, noise reduction layer and the skin of pipe are followed successively by quiet material layer, quiet material layer and block copolymerization polypropylene resin layer;
3) by step 2) gained pipe is through vacuum sizing, cooling, traction, cutting upset, and be packaged into finished product.
9. according to the manufacture method of the high temperature resistant super-silent waste pipe of internal spiral described in claim 6-8 any one, it is characterized in that:
Described dispersing agent is one or both in zine stearate and Tissuemat E;
Described oiling agent is one or both in stearic acid and white oil.
10. according to the manufacture method of the high temperature resistant super-silent waste pipe of internal spiral described in claim 6 or 7, it is characterized in that:
Described noise reduction layer inwall is provided with screw rib, and the quantity of described screw rib is 3-12 bar.
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| CN105237850A (en) * | 2015-10-23 | 2016-01-13 | 广西象州联壮化工有限公司 | Three-layer composite silencing plastic drain pipe core material and preparation method and application thereof |
| CN106432905A (en) * | 2016-09-16 | 2017-02-22 | 上海白蝶管业科技股份有限公司 | PP (polypropylene) internal spiral pipe for drainage and preparation method of PP internal spiral pipe |
| CN106931246A (en) * | 2017-03-27 | 2017-07-07 | 芜湖锐华暖通科技有限公司 | One kind protection low frequency noise water-drainage tube part |
| CN107297876A (en) * | 2017-05-04 | 2017-10-27 | 广东联塑科技实业有限公司 | A kind of new process of raising HDPE double-wall corrugated pipe productivity effects |
| CN110566727A (en) * | 2019-10-09 | 2019-12-13 | 广东胜达塑胶科技有限公司 | High-pressure-resistant and wear-resistant quick-connection solid-wall winding pipe |
| CN113085280A (en) * | 2021-04-19 | 2021-07-09 | 陕西联塑科技实业有限公司 | Three-layer co-extrusion mute drain pipe and preparation method and application thereof |
| CN113789021A (en) * | 2021-09-22 | 2021-12-14 | 青岛六水管道有限公司 | Reinforced flame-retardant mute peptized drainage pipeline |
| CN114658927A (en) * | 2022-03-31 | 2022-06-24 | 湖北大洋塑胶有限公司 | Polypropylene drainage riser |
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| CN113789021A (en) * | 2021-09-22 | 2021-12-14 | 青岛六水管道有限公司 | Reinforced flame-retardant mute peptized drainage pipeline |
| CN114658927A (en) * | 2022-03-31 | 2022-06-24 | 湖北大洋塑胶有限公司 | Polypropylene drainage riser |
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