CN103858552B - Build method and the application thereof of topsoil in coarse sand earth's surface with heavy metal polluted bed mud - Google Patents
Build method and the application thereof of topsoil in coarse sand earth's surface with heavy metal polluted bed mud Download PDFInfo
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Abstract
The invention discloses a kind of method building topsoil with heavy metal polluted bed mud in coarse sand earth's surface, comprise the steps: 1) will treat to loosen in regulation coarse sand earth's surface, ground grading; 2) heavy metal polluted bed mud is laid on coarse sand earth's surface; 3) stabilizing agent is spread on heavy metal polluted bed mud; 4) first time rotary tillage; 5) alternation of wetting and drying process 15 days, is exposed to the sun 7 days, carries out second time rotary tillage, and rotary tillage direction is contrary with second time; After rotary tillage, the mixture quality moisture content of bed mud, coarse sand, stabilizing agent is reduced to 25 ~ 30% naturally, carries out third time rotary tillage, and rotary tillage direction is vertical with second time; 6) plant leguminous green manure 1 batch after third time rotary tillage, carry out the 4th rotary tillage by green manure also field, after 2 months, obtain topsoil.The topsoil heavy metal stabilization successful that this method obtains, the vegetable crop content of beary metal of plantation meets national standard.
Description
Technical field
The invention belongs to land control engineering field, particularly a kind of method and application thereof building topsoil with heavy metal polluted bed mud in coarse sand earth's surface.
Background technology
Land control is to poor efficiency utilization, irrational utilization, does not utilize and the soil of production and construction activity and natural calamity damage is renovated, and improves the activity of land utilization efficiency; Also be efficiently using the available land, strengthen the important means of optimal and intensive land-use, in good time replenished cultivated land and lifting soil production capacity.High especially to the requirement of topsoil in wherein land control engineering, namely improve at least one grade by farmland quality after regulation than farmland quality before regulation.It is 15 ~ more than 20cm that specific targets renovate soil thickness exactly, and nutrient is complete, and organic abundant, granular structure is good, and soil environment is good, is suitable for carrying out long-term cultivation.In the land control engineering of present stage, the source of topsoil mainly contains following pattern: (1) unsoil layer backfills; (2) development construction item backfilling new soil; (3) topsoil applying fertilizer improvement etc. three kinds main in existing topsoil carrys out source module, but above-mentioned pattern is all based on the more rich area of soil resource in training works and can realizes, and partial mode causes economic technology cost higher by the reason of soil haul distance and can not realize.
Coarse sand soil is that soil structure medium silt and glutinous grain are run off gradually, and the land deterioration of sand appears in soil for a long time under artificial unreasonable plantation operation and natural precipitation Scouring Condition.Finally cause the topsoil in such soil to destroy, soil water-retaining water conservation is poor, and soil fertility is barren, and cannot carry out normal agricultural planting activity in production, the most serious occurred land resources completely loses.The problem solving topsoil in coarse sand district land control engineering is very important, and lacking soil is also the Main Economic technical factor that restriction coarse sand district land control engineering advances fast.
Bed mud is the important component part of water body, and primarily of clay mineral, organic matter, reactive metal oxides composition, this natural particle has huge specific surface area, plays an important role in water environment, and it is the Yuan Hehui of various pollutant in water.Sediment Dredging is the effective measures improving lake water quality, and dispose Dredged bed mud needs to reach safe, reasonable, economic requirement simultaneously.The recycling of bed mud more carrys out the concern the more obtaining people, in the Dredged bed mud recycling approach of light, intermediate pollution, Land_use change has the advantage that consumption is large, the simple and economical property of technology is good, the agricultural resources of Dredged bed mud utilizes, not only can turn waste into wealth, and decrease environmental pollution.
Owing to containing the abundant nutritive element such as organic matter, nitrogen, phosphorus in bottom mud in lake, the own focus through becoming current research of its recycling, but heavy metal element wherein exceeds standard, oneself becomes the key factor restricting its agricultural resources and utilize.Many scholars expand for how reducing and reduce heavy metal toxicity in Dredged bed mud study widely, but systematicness, economy and practicality also do not reach requirement.Therefore, how reasonable resource utilization carried out to bottom mud in lake and avoid heavy metal just to seem that tool is of great significance to the research that soil one botanical system pollutes.In addition, because bed mud CLAY MINERALS AND THEIR SIGNIFICANCE content is higher, cause the bed mud after dewatering easily to harden into lump, its physical arrangement is unsuitable for plant growth.Therefore also need to regulate, improve the physico chemical property that it builds soil while solving heavy metal pollution.
The research of utilization of river bottom mud, not only can solve bed mud problem of outlet, can produce certain economic benefit again.Bed mud resource technology mainly contains: brickmaking, potting grain, adsorbent, Land_use change etc.Much research shows, after bottom mud in lake Land_use change, total granular structure and water-stable granular structure increase; Also improve soil moisture content, field capacity and soil porosity and capillary porosity simultaneously.After the bed mud that the content of organic matter is high and rotten amount of cure is higher is used, the bulk density of soil can be made to reduce, and volume of soil soild phase reduces gradually, and liquid and gas volume increases gradually; But the higher and low bed mud become thoroughly decomposed of clay mineral content then may increase the bulk density of soil and cause and harden.Therefore, bed mud use the various physicochemical characters that obviously can improve soil, thus improve the ability of soil water-retaining, fertilizer conservation and water supply, fertilizer.Bed mud and the sediment particles fertilizer be mixed with thereof contain a certain amount of nutrient, higher than pig manure nutrient content, have certain fertilizer efficiency effect.After thus bed mud Land_use change being described, all can improve soil nutrient content level.Bed mud Land_use change can not only bring a large amount of organic and mineral nutrient into, and for the microorganism in soil provides nutrient, and bed mud itself is containing abundant microorganism, improves the quantity of edaphon.Meanwhile, use the population structure that municipal sludge can change edaphon, improve the ratio of soil nitrification bacterium, increase enzymic activity, improve the basic fertility of soil and the content of soil humus.Containing a large amount of nitrogen and phosphorus in bed mud, also containing trace elements such as potassium, calcium, iron, sulphur, magnesium, zinc, copper, manganese, boron, molybdenums, the nutrient needed for plant strain growth slowly can be supplied.
The risk that bed mud Land_use change exists simultaneously is mainly heavy metal pollution, and in bed mud, heavy metal is of a great variety, mainly contains Cu, Pb, Zn, Ni, Cr, Hg, Cd etc., is the key factor limiting its extensive Land_use change.At present more to the Pollution Study of heavy metal-polluted soil, mainly concentrate on the change of soil plough horizon heavy metal after bed mud Land_use change, crop each position Heavy Metal Accumulation amount, existing forms and impact thereof etc.Bed mud is the agricultural heavy metal pollution that can not cause soil and agricultural product rationally, but chronic administration can increase the content of heavy metal in soil.Therefore, chronic administration bottom mud in lake and fertilizer thereof need carry out necessary monitoring.Containing Some Organic Pollutants in bed mud, higher level can be reached in vivo by bioconcentration, thus produce stronger toxic action, also may be jeopardized the health of the mankind by food chain.
In addition, the bed mud quality very consolidation after natural-dehydration, unit weight is up to 1.89g/cm
3, porosity only has 23.8%.The soil porosity scope that applicable plant well grows is generally 55% ~ 65%.Very consolidation is hard for the low soil of porosity, affects growth and the breathing of root system of plant.Therefore, if do not carry out quality adjustment to Dredged bed mud, just can not become the medium of plant growth, affect it in a large number for soil.
Summary of the invention
Utilize the deficiency of technology for the technical deficiency of existing coarse sand district land forming, bed mud agricultural resources, the object of the present invention is to provide a kind of method building topsoil with heavy metal polluted bed mud in coarse sand earth's surface.
A kind of method building topsoil with heavy metal polluted bed mud in coarse sand earth's surface provided by the invention, comprises the steps:
1) will treat to loosen in regulation coarse sand earth's surface, ground grading;
2) heavy metal polluted bed mud is laid on the coarse sand earth's surface described in step 1);
3) stabilizing agent is spread on step 2) on described heavy metal polluted bed mud;
4) at completing steps 3) ground on carry out first time rotary tillage;
5) alternation of wetting and drying process 15 days, is exposed to the sun 7 days, carries out second time rotary tillage, and rotary tillage direction is contrary with second time; After rotary tillage, the mixture quality moisture content natural-dehydration of bed mud, coarse sand, stabilizing agent is reduced to 25 ~ 30%, carries out third time rotary tillage, and rotary tillage direction is vertical with second time;
6) plant leguminous green manure 1 batch after third time rotary tillage, carry out the 4th rotary tillage when green manure plant height reaches 30-35cm by green manure also field, after 2 months, obtain topsoil.
Wherein, the standard of ground grading described in step 1) is the ratio of slope≤3:1000.
Wherein, step 2) described in heavy metal polluted bed mud be heavy metal pollution river bottom mud and/or heavy metal pollution bottom mud in lake.
Wherein, step 2) thickness of described heavy metal polluted bed mud tiling is 24cm.
Wherein, the stabilizing agent described in step 3) is heavy metal process stabilizing agent, preferably comprises the stabilizing agent of following parts by weight ingredient: 5 parts, fused calcium magnesium phosphate, 5 parts, calcium oxide, light dolomite 1 ~ 3 part.
Wherein, the usage amount of the stabilizing agent described in step 3) is: every 100 weight portion bed mud stabilizing agent 0.8 ~ 1.2 weight portions, preferably every 100 weight portion bed mud stabilizing agent 1 weight portions.
Wherein, alternation of wetting and drying process described in step 5) 15 days, for water spray once makes the moistening rear airing of bed mud 5 days, carries out 3 times, totally 15 days repeatedly.
Wherein, the degree of depth of described first time rotary tillage is 24cm; The degree of depth of second time rotary tillage is 27cm; The degree of depth of third time rotary tillage is 30cm; The degree of depth of the 4th rotary tillage is 30cm; The rotary tillage mode of 4 times is rotary tillage of advancing in the shape of a spiral.
Wherein, described leguminous green manure, one or more in preferred khuskhus, French beans, sesbania.
The present invention also provides the application of method on Heavy Metal Pollution in Sediments is administered building topsoil with heavy metal polluted bed mud in coarse sand earth's surface.
The present invention also provides the application of topsoil in proportion of crop planting obtained in coarse sand earth's surface structure topsoil method with heavy metal polluted bed mud.
Compared with prior art, the present invention has the following advantages and effect:
The present invention with heavy-metal composite pollution river bottom mud for handling object, fused calcium magnesium phosphate, calcium oxide, light dolomite is adopted to be heavy metal stabilizer, with coarse sand, also field green manure for physicochemical property modifying agent, the bed mud heavy metal stablizing effect processed is good, composition can be leached reduce, be difficult to Crop, physicochemical property improved effect is obvious simultaneously, has good effect of increasing production.For the disposal of resources of contaminated river bottom mud provides outlet, for in coarse sand soil training works, the structure of topsoil proposes new method, what become that topsoil in China's bed mud disposal of resources, land control engineering builds complements each other and combination simultaneously.
The degree of depth of the present invention's first time rotary tillage is 24cm, guarantees that bed mud and stabilizing agent tentatively mix and contact; Alternation of wetting and drying process 15 days, second time rotary tillage afterwards in 7 days of being exposed to the sun, the degree of depth is 27cm, and rotary tillage direction and first time oppositely, guarantee that bed mud, stabilizing agent and part coarse sand fully mix; The mixture quality moisture content of bed mud, coarse sand, stabilizing agent carries out third time rotary tillage when being reduced to 25 ~ 30%, rotary tillage direction is vertical with second time rotary tillage, the degree of depth is 30cm, guarantee that bed mud and coarse sand mix by design proportion (volume 4:1), make constructed topsoil thickness meet the requirement of land control.The present invention realizes the consumption of bed mud and coarse sand and bed mud and coarse sand mixed proportion by the laying depth of on-the-spot bed mud and the rotary tillage degree of depth, has actual productive value and meaning.After first three rotary tillage soil body settlement stability, this topsoil thickness >=26cm.
The topsoil sediment particles diameter≤3cm obtained after method process of the present invention, bed mud and coarse sand mix.
The angle that inventor absorbs from heavy metal occurrence patterns and crops, by leaching test, the growing vegetables field experiment of heavy metal, heavy metal after the aspects such as rain fed crop field experiment demonstrate process in bed mud has good stablizing effect, prevents the secondary pollution problem of bed mud in agricultural resources utilizes and food-safety problem.Inventor regulates test from the acid-base value that bed mud builds soil after topsoil, soil fertility improvement and simulation experiments, soil mechanical composition regulate the aspects such as test demonstrate bed mud build topsoil can overall raising soil quality effect, for the further utilization of bed mud in agricultural resources is laid a good foundation.
Test through reality, bed mud after the method for the invention process, the stabilization effect of heavy metal Cr, Cu, Zn and Cd is obvious, content of beary metal in the water spinach of plantation and green soy bean all lower than regulation in " the GB2762-2012 national food safety standard-pollutants in food limitation " of up-to-date issue relevant limit value, and lower than regulation in " GB18406.1-2001 agricultural product security quality pollution-free vegetable safety requirements " relevant limit value.
Embodiment
Following examples for illustration of the present invention, but are not used for limiting the scope of the invention.
Embodiment 1 builds the method for topsoil in coarse sand earth's surface with heavy metal polluted bed mud
In November, 2012, in Xia Si village, Xin Po town, Longhua District, Haikou City, Hainan Province, will treat that earth's surface, regulation coarse sand ground is loose, smooth, the standard of ground grading is the ratio of slope≤3:1000.
Bed mud in the Haikou City Xin Po town river embankment dredged out is carried out natural-dehydration to pave after nature dries dehydration and be evenly laid in above coarse sand, bed mud laying depth is 24cm.
Evenly apply stabilizing agent on above-mentioned heavy metal polluted bed mud, described stabilizing agent comprises fused calcium magnesium phosphate, calcium oxide, light dolomite, and mass ratio corresponding to three is 5:5:2, every 100 weight portion bed mud stabilizing agent 1 weight portions.
First time rotary tillage is carried out with rotovator (rotary tillage service machine is below identical for Dongfanghong 1GQN-125 rotovator, China Yituo Group Co., Ltd) in the ground of spreading stabilizing agent; Alternation of wetting and drying process 15 days, is exposed to the sun 7 days, carries out second time rotary tillage, and rotary tillage direction is contrary with second time; After rotary tillage, the mixture quality moisture content of bed mud, coarse sand, stabilizing agent is reduced to 25 ~ 30% naturally, carries out third time rotary tillage, and rotary tillage direction is vertical with second time; Plant leguminous green manure 1 batch after third time rotary tillage, green manuring is khuskhus, carries out the 4th rotary tillage by green manure also field, obtain topsoil after 2 months after growing to plant height 30cm.Described alternation of wetting and drying process 15 days, for water spray once makes the moistening rear airing of bed mud 5 days, carries out 3 times, totally 15 days repeatedly.The degree of depth of described first time rotary tillage is 24cm; The degree of depth of second time rotary tillage is 27cm; The degree of depth of third time rotary tillage is 30cm; The degree of depth of the 4th rotary tillage is 30cm; The rotary tillage mode of 4 times is rotary tillage of advancing in the shape of a spiral.
After 4th rotary tillage 2 months, use the Method-1311 Toxicity Characteristic Leaching Procedure(TCLP of EPA) measure, 0.3% lime+0.3% fused calcium magnesium phosphate is set simultaneously and makees stabilizing agent as a comparison (100 weight portion bed muds add 0.3 weight portion lime and 0.3 weight portion fused calcium magnesium phosphate).Bed mud after described method process, TCLP leaching concentration obviously reduces.Wherein, the leaching concentration of Cr element decreases 46.91% than not stablizing group, decreases 32.56% relative to lime fused calcium magnesium phosphate processed group; The leaching concentration of Cu element decreases 72.22% than not stablizing group, decreases 45.07% relative to lime fused calcium magnesium phosphate processed group; The leaching concentration of Zn element decreases 26.14% than not stablizing group, decreases 24.07% relative to lime fused calcium magnesium phosphate processed group; The leaching concentration of Cd element decreases 40.55% than not stablizing group, decreases 30.41% relative to lime fused calcium magnesium phosphate processed group; In leachate, the concentration of Pb, As, Hg element is all lower than detection limit.
Result is specifically in table 1, and Leaching of Heavy Metals reduces, and stablizing effect is obvious.
Heavy metal concentration (unit: μ g/L) in bed mud TCLP leachate before and after table 1 is stable
| Process title | Cr | Cu | Zn | Cd | Pb | As | Hg |
| Do not stablize | 4.37 | 11.23 | 146.68 | 5.08 | ＜1.00 | ＜0.15 | ＜0.15 |
| Lime+fused calcium magnesium phosphate | 3.44 | 5.68 | 142.69 | 4.34 | ＜1.00 | ＜0.15 | ＜0.15 |
| Stabilizing agent of the present invention | 2.32 | 3.12 | 108.34 | 3.02 | ＜1.00 | ＜0.15 | ＜0.15 |
The application of topsoil on proportion of crop planting that embodiment 2 the present invention obtains
On the topsoil that bed mud obtains by method of the present invention in embodiment 1, plant water spinach (originating from Thailand respectively up to seed Co., Ltd and Beijing gold soil agrotechnique research institute), Dry crop green soy bean according to a conventional method.Simultaneously do the stable test topsoil of stabilizing agent to arrange 0.3% lime+0.3% fused calcium magnesium phosphate, be covered with do not stablize bed mud topsoil as a comparison.Record physical signs and growth indexes in process of crop growth, record output during results, and content of beary metal detection is carried out to vegetables and green soy bean.
Result is, the physical signs of the rear bed mud planting vegetable of process and growth indexes are all better than 0.3% lime+0.3% fused calcium magnesium phosphate and do the vegetables that stabilizing agent and untreated bed mud are planted, and output also does the soil of stabilizing agent and untreated bed mud soil apparently higher than 0.3% lime+0.3% fused calcium magnesium phosphate.On the bed mud of process front and back, the content of beary metal of planting vegetable is in table 2.
Content of beary metal (unit: mg/kg) before and after table 2 is stable in bed mud planting vegetable
After stabilization processes, the content of beary metal in water spinach all obviously reduces.Cr constituent content decreases 43.96% than not stablizing group, decreases 22.65% relative to lime fused calcium magnesium phosphate processed group; Cu constituent content decreases 39.14% than not stablizing group, decreases 23.03% relative to lime fused calcium magnesium phosphate processed group; Cd constituent content decreases 82.59% than not stablizing group, decreases 34.52% relative to lime fused calcium magnesium phosphate processed group; Pb constituent content not stable group expression detects a bit, but stabilizer treatment of the present invention and lime fused calcium magnesium phosphate process content are then lower than method detection limit; As constituent content is all lower than method detection limit.
After stabilization processes, the heavy metal of green soy bean (edible portion), each process of Pb, As element is all lower than method detection limit; Cr constituent content decreases 44.27% than not stablizing group, reduces 17.04% relative to lime fused calcium magnesium phosphate processed group; Cu constituent content decreases 50.14% than not stablizing group, reduces 20.21% relative to lime fused calcium magnesium phosphate processed group; Cd constituent content decreases 63.22% than not stablizing group, adds 48.39% relative to lime fused calcium magnesium phosphate processed group.
The topsoil acid-base value that embodiment 3 the present invention builds regulates application
Bed mud is by the present invention through stable constructed topsoil in embodiment 1, plants water spinach (originating from Thailand up to seed Co., Ltd) according to a conventional method.Simultaneously do the stable topsoil of stabilizing agent (but present treatment not green manuring process), with locality nature agricultural land soil as a comparison to arrange 0.3% lime+0.3% fused calcium magnesium phosphate.Soil mechanical composition regulating effect (table 3) and soil fertility condition effect (table 4) after monitoring different disposal soil planting crop.
Table 3 difference stable process topsoil mechanical composition regulating effect (unit: %)
Data are regulated to find out from the soil mechanical composition of table 3 field experiment, applying this invention technology can make the mechanical composition of constructed topsoil have larger regulating effect, constructed soil particle structure is had and obviously improves effect, improve the effect of soil water-retaining, report fertilizer.With natural farmland soil for contrast, this technology can make clay content promote nearly 4%, silt content also comparatively contrasts and can improve, sand grain content reduces, this has larger impact for soil structure, especially by the biological modification measure of green manure, constructed soil can be made not easily to occur situation about hardening.
Table 4 difference stable process topsoil fertility regulating effect (unit: %)
From table 4 field soil Fertility Monitoring test data, the soil of the more natural farmland of the soil organic matter after process of the present invention and other process has larger increase, and the amplitude of increase is more than 28%; Total nitrogen content process increases effect clearly, and present treatment adds 4.66 times, 1.04 times respectively than nature farmland and the process of lime fused calcium magnesium phosphate group, and this invention technology is remarkable to fertility regulating effect, is presented as that good production application is worth.
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the prerequisite not departing from the technology of the present invention principle; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (10)
1. build a method for topsoil with heavy metal polluted bed mud in coarse sand earth's surface, comprise the steps:
1) will treat to loosen in regulation coarse sand earth's surface, ground grading;
2) heavy metal polluted bed mud is laid in step 1) described in coarse sand earth's surface on;
3) stabilizing agent is spread on step 2) on described heavy metal polluted bed mud;
4) at completing steps 3) ground on carry out first time rotary tillage;
5) alternation of wetting and drying process 15 days, is exposed to the sun 7 days, carries out second time rotary tillage, and rotary tillage direction is contrary with first time; After rotary tillage, the mixture quality moisture content natural-dehydration of bed mud, coarse sand, stabilizing agent is reduced to 25 ~ 30%, carries out third time rotary tillage, and rotary tillage direction is vertical with second time;
6) plant leguminous green manure 1 batch after third time rotary tillage, carry out the 4th rotary tillage when green manure plant height reaches 30-35cm by green manure also field, after 2 months, obtain topsoil.
2. according to claim 1ly building the method for topsoil with heavy metal polluted bed mud in coarse sand earth's surface, it is characterized in that, step 1) standard of described ground grading is the ratio of slope≤3:1000.
3. according to claim 1ly build the method for topsoil with heavy metal polluted bed mud in coarse sand earth's surface, it is characterized in that, step 2) described in heavy metal polluted bed mud be heavy metal pollution river bottom mud and/or heavy metal pollution bottom mud in lake; The thickness of heavy metal polluted bed mud tiling is 24cm.
4. according to claim 1ly build the method for topsoil with heavy metal polluted bed mud in coarse sand earth's surface, it is characterized in that, step 3) described in stabilizing agent be heavy metal process stabilizing agent.
5. the method building topsoil with heavy metal polluted bed mud in coarse sand earth's surface according to claim 4, it is characterized in that, step 3) described in stabilizing agent comprise following parts by weight ingredient: 5 parts, fused calcium magnesium phosphate, 5 parts, calcium oxide, light dolomite 1 ~ 3 part.
6. according to claim 5ly build the method for topsoil with heavy metal polluted bed mud in coarse sand earth's surface, it is characterized in that, step 3) described in the usage amount of stabilizing agent be: every 100 weight portion bed mud stabilizing agent 1 weight portions.
7. the method building topsoil with heavy metal polluted bed mud in coarse sand earth's surface according to claim 1, it is characterized in that, step 5) described alternation of wetting and drying process 15 days, for water spray once makes the moistening rear airing of bed mud 5 days, repeatedly carry out 3 times, totally 15 days.
8. the method building topsoil with heavy metal polluted bed mud in coarse sand earth's surface according to claim 1, it is characterized in that, the degree of depth of described first time rotary tillage is 24cm; The degree of depth of second time rotary tillage is 27cm; The degree of depth of third time rotary tillage is 30cm; The degree of depth of the 4th rotary tillage is 30cm.
9. any one of claim 1-8 builds the application of method on Heavy Metal Pollution in Sediments is administered of topsoil in coarse sand earth's surface with heavy metal polluted bed mud.
10. any one of claim 1-8 to build with heavy metal polluted bed mud the application of topsoil in proportion of crop planting that topsoil method obtains in coarse sand earth's surface.
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| CN105254401A (en) * | 2015-09-23 | 2016-01-20 | 北京世纪阿姆斯生物工程有限公司 | Soil improvement agent, and preparation method thereof |
| CN106811201A (en) * | 2017-01-24 | 2017-06-09 | 东南大学 | A kind of magnesium oxide-based curing agent and its application process |
| CN108834460A (en) * | 2018-05-16 | 2018-11-20 | 美丽国土（北京）生态环境工程技术研究院有限公司 | Mud utilizes methods and applications |
| CN110216139A (en) * | 2019-05-24 | 2019-09-10 | 广州市华南自然资源科学技术研究院 | A kind of water transfer heavy metals in farmland of improving the soil removes the construction method of system |
| CN114568061B (en) * | 2022-01-26 | 2023-10-31 | 广西壮族自治区农业科学院 | Rapid reconstruction method of plough layer |
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