CN103830996B - Middle high-temperature dechlorinating agent removing HCl gas and preparation method thereof - Google Patents
Middle high-temperature dechlorinating agent removing HCl gas and preparation method thereof Download PDFInfo
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- CN103830996B CN103830996B CN201410054194.3A CN201410054194A CN103830996B CN 103830996 B CN103830996 B CN 103830996B CN 201410054194 A CN201410054194 A CN 201410054194A CN 103830996 B CN103830996 B CN 103830996B
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Abstract
The invention discloses a kind of middle high-temperature dechlorinating agent removing HCl gas and preparation method thereof, described antichlor is made up of active component, carrier and auxiliary agent, adhesive; Active component is by glucose and Ca (NO
3)
2, Mg (NO
3)
2, Zn (NO
3)
2, NaHCO
3in more than one fully mix formation; Carrier and auxiliary agent are ZSM-5 or molecular sieve, and adhesive is methylcellulose; Described preparation method, first mixed active composition, be then added drop-wise on pretreated carrier and auxiliary agent by the aqueous solution of active component, and through rotation, heating, drying, roasting, shaping, then granulation obtains antichlor.Obtained antichlor all can the HCl gas removed in flue gas of the efficient degree of depth in 423-1073K temperature range, penetrates chlorosity and reach more than 63%.
Description
Technical field
The present invention relates to antichlor of a kind of deep removal HCl gas under middle hot conditions and preparation method thereof, belong to gas cleaning processing technology field.
Background technology
The output of current China domestic waste has reached 1.6 hundred million tons every year, and still with annual 8 ~ 10% speed increase, that wherein can carry out harmless treatment accounts for 66%, nearly 1/3 rubbish can only carry out simple landfill, China clears disposal of refuse and spends nearly 30,000,000,000 yuan every year, city, 600, the whole nation has been stacked or all kinds of rubbish of landfill reaches 8,000,000,000 tons, and rubbish is stored up and added up to occupy 500,000,000 square metres of soils, and 2/3 city faces " garbage-surrounded city ".The process problem of house refuse is very urgent, burning disposal because having significant minimizing (decrement about 80%, subtracts appearance 90%), resource (recoverable energy be used for generating and heat supply) is widely used by U.S., day, method, moral, Yi Deng developed country.China starts late, and the First garbage incinerating power plant set up for 1988, garbage incinerating power plant has reached over thousands of seat so far.On April 29th, 2012, the General Office of the State Council has printed and distributed " planning of " 12 " national application of city life garbage harmless treatment Facilities Construction ", waste incineration project construction is proposed and quantizes to require: by 2015, whole nation application of city life garbage burning disposal facility ability, reach more than 35% of harmless treatment total capacity, its Middle Eastern reaches more than 48%.
Because component of refuse is quite complicated, in burning process, inevitably secondary pollution problem to be produced.And the problem of the HCl burnt away the refuse in the sour gas of generation more and more causes the extensive concern of international community.Different from fire coal, the abundant chlorinated organics (rubber, PVC etc.) contained in house refuse and inorganic matter (NaCl) can mainly be discharged with the form of HCl, up to hundreds of even several thousand PPm in burning process.The basic principle of, minimizing innoxious according to urban garbage disposal and resource, effectively must control these pollutants.
Chlorine is one of important element causing secondary pollution in consumer waste incineration, and its existence directly has influence on design, the operation and maintenance of incinerator; And chlorine can change into HCl and give off, atmospheric environment and CIU are worked the mischief.HCl in air may react at normal temperatures with water vapour: OH+HCl-Cl+H
2o, the Cl of generation can as catalyst breakage ozone layers in high stratosphere gas-bearing formation, and meeting and SO
2deng formation acid rain, animals and plants and building are worked the mischief.At refuse burning system, the burning facility body of HCl to incinerator causes strong corrosion, can cause the high temperature corrosion damage of furnace heating surface and the cold end corrosion of back-end surfaces, can cause the raising of steam parameter, cause the corrosion on heated exchanger surface, also can promote NO
xgeneration, the desulfurizing agent of the HCl gas in coal gas easily and in desulphurization system reacts and generates the chloride of volatile, desulfurized effect is deteriorated, and blocks pipe-line system.Chlorine also can affect migration and the distribution of heavy metal, and forms dioxin, particularly at 300 ~ 400 DEG C as one of element.Point out in the report " incinerator and human health " that United Nations Environment Programme announced 20 end of the centurys, waste incineration is the largest source of dioxin.Estimate that the dioxin given off by incinerator accounts for 10% ~ 40% of total release in the world.Therefore, removing HCl gas at middle high temperature is one of core missions of garbage incinerator tail gas process.
Current antichlor can be divided into by chemical constituent: modified aluminas system antichlor, copper system antichlor, calcium system antichlor and ferripotassium system antichlor.But the exploitation due to each antichlor is targetedly, different antichlors is suitable for different occasions.And most of antichlor be mainly applicable in, under cryogenic conditions, the chlorosity of antichlor is not high, under middle high temperature, the harm of HCl gas can not be avoided.Therefore in research and development, under high temperature, the degree of depth efficiently seems particularly important at the antichlor of HCl gas.
Summary of the invention
Goal of the invention: not high for the antichlor chlorosity existed at present, and adaptive temperature scope is wideless, the problem of HCl gas in efficient deep removal flue gas under high temperature in cannot realizing, the invention provides antichlor of a kind of deep removal HCl gas under middle hot conditions and preparation method thereof, this antichlor has high HCl content in wide temperature range.
Technical scheme: for achieving the above object, the technical solution used in the present invention is:
A kind of middle high-temperature dechlorinating agent removing HCl gas, this antichlor is made up of active component, carrier and auxiliary agent, adhesive, and the mass percent of active component is 65 ~ 84%, the mass percent of carrier and auxiliary agent is 15 ~ 33%, and the mass percent of adhesive is 1 ~ 4%.
Preferably, described active component is by glucose and Ca (NO
3)
2, Mg (NO
3)
2, Zn (NO
3)
2, NaHCO
3in more than one fully mix formation according to mass ratio 1:3 ~ 1:8.
Preferably, described carrier and auxiliary agent are the one in ZSM-5 or molecular sieve.
Preferably, described adhesive is methylcellulose.
Remove a preparation method for the middle high-temperature dechlorinating agent of HCl gas, comprise the steps:
(1) also fully mix than proportioning active component according to quality, then mixture is fully dissolved in deionized water; Wherein the temperature of deionized water is 328 ~ 353K, and the solid-liquid mass ratio of mixture and deionized water is 1:3 ~ 1:10;
(2) take carrier and auxiliary agent according to mass ratio, pre-heat carrier and auxiliary agent 2 ~ 4h, preheat temperature is 328K ~ 353K;
(3) according to mass ratio, the dissolution homogeneity that step (1) is prepared is added drop-wise in the carrier after preheating and auxiliary agent;
(4) product of step (3) is fully mixed with adhesive;
(5) product of step (4) is carried out dry adjoint stirring and obtain solid product; Wherein bake out temperature is 353 ~ 373K, and mixing speed is 50rpm ~ 100rpm;
(6) product of step (5) is placed in tube furnace be warming up to holding temperature and be incubated, takes out after cooling; Protective gas wherein in tube furnace is N
2, programming rate is 5K/min, and holding temperature is 773 ~ 873K, and insulation duration is 30min;
(7) solid product that step (6) obtains is carried out shaping, granulation and obtain described antichlor.
Beneficial effect: middle high-temperature dechlorinating agent removing HCl gas provided by the invention and preparation method thereof, compared to prior art, have following characteristic with a little:
1, antichlor of the present invention, all efficiently can remove to the degree of depth HCl gas in flue gas and the HCl gas in IGCC and MCFC system in 423 ~ 1073K temperature range;
2, antichlor of the present invention, after a series of processing process, glucose powder meeting pyrolysis, remaining carbon has the character of active carbon: on the one hand due to the release of gas in glucose pyrolytic process, antichlor is made to have comparatively bigger serface, carbon remaining on the other hand also has higher specific area and pore volume, effectively can improve the adsorption activity on antichlor surface;
3, the preparation method of antichlor of the present invention, by adopting preheating method to make the antichlor structure prepared more tend towards stability to carrier and auxiliary agent, and select suitable sintering temperature, ensure that obtained antichlor can obtain more complete antichlor crystalline form, thus the antichlor obtained by ensureing has higher chlorosity, has good adsorption activity.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further described.
Embodiment 1
Take 75g glucose powder, 575g Ca (NO
3)
2, the methylcellulose of 330g molecular sieve and 20g; First by glucose powder and Ca (NO
3)
2fully mix, then add the deionized water of the 333K of 3kg, then by molecular sieve at 350K preheating 4h, then by glucose powder and Ca (NO
3)
2mixed solution evenly drip on preheated molecular sieve, then mix with methylcellulose, the mixture obtained revolved speed in the stirring of 65rpm, and under 353K dry obtain solid.The solid obtained is placed in tube furnace with N
2for protection gas, be warmed up to 773K with 5K/min, stop 30min, then take out after cooling.The solid obtained is carried out shaping, granulation and obtain required antichlor.
The antichlor of preparation is carried out dechlorination experiment, and sorbent reactions device can be moving bed, fixed bed or fluidized-bed reactor etc.Dechlorination reaction condition is: the amount passing into flue gas is 40L/h, wherein chlorine-containing gas amount is 100 ~ 3000ppm, reaction temperature is within the scope of 423 ~ 1073K, and this antichlor can make the amount of contained HCl in exit gas be down to below 0.5ppm, and penetrating chlorosity is after tested 69.9%.
Embodiment 2:
Take 74g glucose powder, 460g Ca (NO
3)
2, 116g Mg (NO
3)
2, the methylcellulose of 310g ZSM-5 and 40g; First by glucose powder and Ca (NO
3)
2, Mg (NO
3)
2fully mix, then add the deionized water of the 353K of 4kg, then by ZSM-5 at 340K preheating 4h, then by glucose powder and Ca (NO
3)
2, Mg (NO
3)
2mixed solution evenly drip on preheated ZSM-5, then mix with methylcellulose, the mixture obtained revolved speed in the stirring of 80rpm, and under 353K dry obtain solid.The solid obtained is placed in tube furnace with N
2for protection gas, be warmed up to 800K with 5K/min, stop 30min, then take out after cooling.The solid obtained is carried out shaping, granulation and obtain required antichlor.
The antichlor of preparation is carried out dechlorination experiment, and sorbent reactions device can be moving bed, fixed bed or fluidized-bed reactor etc.Dechlorination reaction condition is: the amount passing into flue gas is 40L/h, wherein chlorine-containing gas amount is 100 ~ 3000ppm, reaction temperature is within the scope of 423 ~ 1073K, and this antichlor can make the amount of contained HCl in exit gas be down to below 0.5ppm, and penetrating chlorosity is after tested 68.7%.
Embodiment 3:
Take 187g glucose powder, 563g NaHCO
3, the methylcellulose of 240g ZSM-5 and 10g; First by glucose powder and NaHCO
3fully mix, then add the deionized water of the 340K of 4kg, then by ZSM-5 at 348K preheating 4h, then by glucose powder and NaHCO
3mixed solution evenly drip on preheated ZSM-5, then mix with methylcellulose, the mixture obtained revolved speed in the stirring of 80rpm, and under 363K dry obtain solid.The solid obtained is placed in tube furnace with N
2for protection gas, be warmed up to 800K with 5K/min, stop 30min, then take out after cooling.The solid obtained is carried out shaping, granulation and obtain required antichlor.
The antichlor of preparation is carried out dechlorination experiment, and sorbent reactions device can be moving bed, fixed bed or fluidized-bed reactor etc.Dechlorination reaction condition is: the amount passing into flue gas is 40L/h, wherein chlorine-containing gas amount is 100 ~ 3000ppm, reaction temperature is within the scope of 423 ~ 1073K, and this antichlor can make the amount of contained HCl in exit gas be down to below 0.5ppm, and penetrating chlorosity is after tested 63.3%.
Embodiment 4:
Take 130g glucose powder, 400g NaHCO
3, 250g Zn (NO
3)
2, the methylcellulose of 190g ZSM-5 and 30g; First by glucose powder and NaHCO
3, Zn (NO
3)
2fully mix, then add the deionized water of the 328K of 2.5kg, then by ZSM-5 at 353K preheating 3h, then by glucose powder and NaHCO
3, Zn (NO
3)
2mixed solution evenly drip on preheated ZSM-5, then mix with methylcellulose, the mixture obtained revolved speed in the stirring of 100rpm, and under 363K dry obtain solid.The solid obtained is placed in tube furnace with N
2for protection gas, be warmed up to 853K with 5K/min, stop 30min, then take out after cooling.The solid obtained is carried out shaping, granulation and obtain required antichlor.
The antichlor of preparation is carried out dechlorination experiment, and sorbent reactions device can be moving bed, fixed bed or fluidized-bed reactor etc.Dechlorination reaction condition is: the amount passing into flue gas is 40L/h, wherein chlorine-containing gas amount is 100 ~ 3000ppm, reaction temperature is within the scope of 423 ~ 1073K, and this antichlor can make the amount of contained HCl in exit gas be down to below 0.5ppm, and penetrating chlorosity is after tested 70.8%.
Embodiment 5:
Take 140g glucose powder, 640g Zn (NO
3)
2, the methylcellulose of 210g molecular sieve and 10g; First by glucose powder and Zn (NO
3)
2fully mix, then add the deionized water of the 340K of 3kg, then by molecular sieve at 328K preheating 3h, then by glucose powder and Zn (NO
3)
2mixed solution evenly drip on preheated molecular sieve, then mix with methylcellulose, the mixture obtained revolved speed in the stirring of 75rpm, and under 373K dry obtain solid.The solid obtained is placed in tube furnace with N
2for protection gas, be warmed up to 873K with 5K/min, stop 30min, then take out after cooling.The solid obtained is carried out shaping, granulation and obtain required antichlor.
The antichlor of preparation is carried out dechlorination experiment, and sorbent reactions device can be moving bed, fixed bed or fluidized-bed reactor etc.Dechlorination reaction condition is: the amount passing into flue gas is 40L/h, wherein chlorine-containing gas amount is 100 ~ 3000ppm, reaction temperature is within the scope of 423 ~ 1073K, and this antichlor can make the amount of contained HCl in exit gas be down to below 0.5ppm, and penetrating chlorosity is after tested 64.9%.
Embodiment 6:
Take 100g glucose powder, 550g Mg (NO
3)
2, the methylcellulose of 320g molecular sieve and 30g; First by glucose powder and Mg (NO
3)
2fully mix, then add the deionized water of the 353K of 5kg, then by molecular sieve at 328K preheating 2h, then by glucose powder and Mg (NO
3)
2mixed solution evenly drip on preheated molecular sieve, then mix with methylcellulose, the mixture obtained revolved speed in the stirring of 65rpm, and under 373K dry obtain solid.The solid obtained is placed in tube furnace with N
2for protection gas, be warmed up to 800K with 5K/min, stop 30min, then take out after cooling.The solid obtained is carried out shaping, granulation and obtain required antichlor.
The antichlor of preparation is carried out dechlorination experiment, and sorbent reactions device can be moving bed, fixed bed or fluidized-bed reactor etc.Dechlorination reaction condition is: the amount passing into flue gas is 40L/h, wherein chlorine-containing gas amount is 100 ~ 3000ppm, reaction temperature is within the scope of 423 ~ 1073K, and this antichlor can make the amount of contained HCl in exit gas be down to below 0.5ppm, and penetrating chlorosity is after tested 65.3%.
Embodiment 7:
Take 150g glucose powder, 325g Ca (NO
3)
2, 325g NaHCO
3, the methylcellulose of 180g ZSM-5 and 20g; First by glucose powder and Ca (NO
3)
2, NaHCO
3fully mix, then add the deionized water of the 353K of 6kg, then by ZSM-5 at 340K preheating 4h, then by glucose powder and Ca (NO
3)
2and NaHCO
3mixed solution evenly drip on preheated ZSM-5, then mix with methylcellulose, the mixture obtained revolved speed in the stirring of 80rpm, and under 373K dry obtain solid.The solid obtained is placed in tube furnace with N
2for protection gas, be warmed up to 800K with 5K/min, stop 30min, then take out after cooling.The solid obtained is carried out shaping, granulation and obtain required antichlor.
The antichlor of preparation is carried out dechlorination experiment, and sorbent reactions device can be moving bed, fixed bed or fluidized-bed reactor etc.Dechlorination reaction condition is: the amount passing into flue gas is 40L/h, wherein chlorine-containing gas amount is 100 ~ 3000ppm, reaction temperature is within the scope of 423 ~ 1073K, and this antichlor can make the amount of contained HCl in exit gas be down to below 0.5ppm, and penetrating chlorosity is after tested 72.9%.
Embodiment 8:
Take 120g glucose powder, 400g Ca (NO
3)
2, 200g Mg (NO
3)
2, the methylcellulose of 260g molecular sieve and 20g; First by glucose powder and Ca (NO
3)
2, Mg (NO
3)
2fully mix, then add the deionized water of the 353K of 5kg, then by molecular sieve at 340K preheating 3h, then by glucose powder and Ca (NO
3)
2, Mg (NO
3)
2mixed solution evenly drip on preheated molecular sieve, then mix with methylcellulose, the mixture obtained revolved speed in the stirring of 90rpm, and under 373K dry obtain solid.The solid obtained being placed in tube furnace take N2 as protection gas, is warmed up to 793K, stops 30min, then take out after cooling with 5K/min.The solid obtained is carried out shaping, granulation and obtain required antichlor.
The antichlor of preparation is carried out dechlorination experiment, and sorbent reactions device can be moving bed, fixed bed or fluidized-bed reactor etc.Dechlorination reaction condition is: the amount passing into flue gas is 40L/h, wherein chlorine-containing gas amount is 100 ~ 3000ppm, reaction temperature is within the scope of 423 ~ 1073K, and this antichlor can make the amount of contained HCl in exit gas be down to below 0.5ppm, and penetrating chlorosity is after tested 65.7%.
Embodiment 9:
Take 90g glucose powder, 450g Zn (NO
3)
2, 200g Mg (NO
3)
2, the methylcellulose of 250g molecular sieve and 10g; First by glucose powder and Zn (NO
3)
2, Mg (NO
3)
2fully mix, then add the deionized water of the 353K of 4.5kg, then by molecular sieve at 343K preheating 3h, then by glucose powder and Zn (NO
3)
2, Mg (NO
3)
2mixed solution evenly drip on preheated molecular sieve, then mix with methylcellulose, the mixture obtained revolved speed in the stirring of 100rpm, and under 363K dry obtain solid.The solid obtained is placed in tube furnace with N
2for protection gas, be warmed up to 873K with 5K/min, stop 30min, then take out after cooling.The solid obtained is carried out shaping, granulation and obtain required antichlor.
The antichlor of preparation is carried out dechlorination experiment, and sorbent reactions device can be moving bed, fixed bed or fluidized-bed reactor etc.Dechlorination reaction condition is: the amount passing into flue gas is 40L/h, wherein chlorine-containing gas amount is 100 ~ 3000ppm, reaction temperature is within the scope of 423 ~ 1073K, and this antichlor can make the amount of contained HCl in exit gas be down to below 0.5ppm, and penetrating chlorosity is after tested 70.1%.
Embodiment 10:
Take 120g glucose powder, 300g Ca (NO
3)
2, 200g Mg (NO
3)
2, 160g NaHCO
3, the methylcellulose of 200g molecular sieve and 20g; First by glucose powder and Ca (NO
3)
2, Mg (NO
3)
2, NaHCO
3fully mix, then add the deionized water of the 353K of 7kg, then by molecular sieve at 340K preheating 3h, then by glucose powder and Ca (NO
3)
2, Mg (NO
3)
2, NaHCO
3mixed solution evenly drip on preheated molecular sieve, then mix with methylcellulose, the mixture obtained revolved speed in the stirring of 90rpm, and under 373K dry obtain solid.The solid obtained is placed in tube furnace with N
2for protection gas, be warmed up to 793K with 5K/min, stop 30min, then take out after cooling.The solid obtained is carried out shaping, granulation and obtain required antichlor.
The antichlor of preparation is carried out dechlorination experiment, and sorbent reactions device can be moving bed, fixed bed or fluidized-bed reactor etc.Dechlorination reaction condition is: the amount passing into flue gas is 40L/h, wherein chlorine-containing gas amount is 100 ~ 3000ppm, reaction temperature is within the scope of 423 ~ 1073K, and this antichlor can make the amount of contained HCl in exit gas be down to below 0.5ppm, and penetrating chlorosity is after tested 69.6%.
Embodiment 11:
Take 150g glucose powder, 320g Ca (NO
3)
2, 140g Mg (NO
3)
2, 230g Zn (NO
3)
2, the methylcellulose of 150gZSM-5 and 10g; First by glucose powder and Ca (NO
3)
2, Mg (NO
3)
2, Zn (NO
3)
2fully mix, then add the deionized water of the 353K of 5kg, then by ZSM-5 at 353K preheating 4h, then by glucose powder and Ca (NO
3)
2, Mg (NO
3)
2, Zn (NO
3)
2mixed solution evenly drip on preheated ZSM-5, then mix with methylcellulose, the mixture obtained revolved speed in the stirring of 85rpm, and under 373K dry obtain solid.The solid obtained is placed in tube furnace with N
2for protection gas, be warmed up to 853K with 5K/min, stop 30min, then take out after cooling.The solid obtained is carried out shaping, granulation and obtain required antichlor.
The antichlor of preparation is carried out dechlorination experiment, and sorbent reactions device can be moving bed, fixed bed or fluidized-bed reactor etc.Dechlorination reaction condition is: the amount passing into flue gas is 40L/h, wherein chlorine-containing gas amount is 100 ~ 3000ppm, reaction temperature is within the scope of 423 ~ 1073K, and this antichlor can make the amount of contained HCl in exit gas be down to below 0.5ppm, and penetrating chlorosity is after tested 68%.
Embodiment 12:
Take 100g glucose powder, 280g Ca (NO
3)
2, 180g Mg (NO
3)
2, 160g NaHCO
3, 100gZn (NO
3)
2, the methylcellulose of 160g ZSM-5 and 20g; First by glucose powder and Ca (NO
3)
2, Mg (NO
3)
2, NaHCO
3, Zn (NO
3)
2fully mix, then add the deionized water of the 333K of 8kg, then by ZSM-5 at 353K preheating 4h, then by glucose powder and Ca (NO
3)
2, Mg (NO
3)
2, NaHCO
3, Zn (NO
3)
2mixed solution evenly drip on preheated ZSM-5, then mix with methylcellulose, the mixture obtained revolved speed in the stirring of 100rpm, and under 363K dry obtain solid.The solid obtained is placed in tube furnace with N
2for protection gas, be warmed up to 873K with 5K/min, stop 30min, then take out after cooling.The solid obtained is carried out shaping, granulation and obtain required antichlor.
The antichlor of preparation is carried out dechlorination experiment, and sorbent reactions device can be moving bed, fixed bed or fluidized-bed reactor etc.Dechlorination reaction condition is: the amount passing into flue gas is 40L/h, wherein chlorine-containing gas amount is 100 ~ 3000ppm, reaction temperature is within the scope of 423 ~ 1073K, and this antichlor can make the amount of contained HCl in exit gas be down to below 0.5ppm, and penetrating chlorosity is after tested 69.7%.
The above is only the preferred embodiment of the present invention; be noted that for those skilled in the art; under the premise without departing from the principles of the invention, can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (3)
1. one kind removes the middle high-temperature dechlorinating agent of HCl gas, it is characterized in that: this antichlor is made up of active component, carrier and auxiliary agent, adhesive, and the mass percent of active component is 65 ~ 84%, the mass percent of carrier and auxiliary agent is 15 ~ 33%, and the mass percent of adhesive is 1 ~ 4%; Described active component is by glucose and Ca (NO
3)
2, Mg (NO
3)
2, Zn (NO
3)
2, NaHCO
3in more than one fully mix formation according to mass ratio 1:3 ~ 1:8; Described carrier and auxiliary agent are the one in ZSM-5 or molecular sieve.
2. the middle high-temperature dechlorinating agent removing HCl gas according to claim 1, is characterized in that: described adhesive is methylcellulose.
3. the preparation method removing the middle high-temperature dechlorinating agent of HCl gas according to claim 1, is characterized in that: comprise the steps:
(1) also fully mix than proportioning active component according to quality, then mixture is fully dissolved in deionized water; Wherein the temperature of deionized water is 328 ~ 353K, and the solid-liquid mass ratio of mixture and deionized water is 1:3 ~ 1:10;
(2) take carrier and auxiliary agent according to mass ratio, pre-heat carrier and auxiliary agent 2 ~ 4h, preheat temperature is 328K ~ 353K;
(3) according to mass ratio, the dissolution homogeneity that step (1) is prepared is added drop-wise in the carrier after preheating and auxiliary agent;
(4) product of step (3) is fully mixed with adhesive;
(5) product of step (4) is carried out dry adjoint stirring and obtain solid product; Wherein bake out temperature is 353 ~ 373K, and mixing speed is 50rpm ~ 100rpm;
(6) product of step (5) is placed in tube furnace be warming up to holding temperature and be incubated, takes out after cooling; Protective gas wherein in tube furnace is N
2, programming rate is 5K/min, and holding temperature is 773 ~ 873K, and insulation duration is 30min;
(7) solid product that step (6) obtains is carried out shaping, granulation and obtain described antichlor.
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| GB201513836D0 (en) * | 2015-08-05 | 2015-09-16 | Johnson Matthey Plc | Chemical absorbent composition |
| CN108654567B (en) * | 2018-05-14 | 2020-02-07 | 东南大学 | Medium-high temperature dechlorinating agent for removing HCl gas in flue gas and preparation method thereof |
| CN110624382A (en) * | 2018-06-25 | 2019-12-31 | 沈阳三聚凯特催化剂有限公司 | High-temperature flue gas dechlorinating agent and preparation method thereof |
| CN109173978B (en) * | 2018-09-18 | 2021-06-08 | 东南大学 | Preparation method of nitrogen-doped hydrotalcite adsorbent |
| CN109173979A (en) * | 2018-09-18 | 2019-01-11 | 东南大学 | A kind of preparation method of the hydrotalcite dehydrochlorination adsorbent of carrying potassium oxide |
| CN114146558B (en) * | 2021-10-27 | 2024-09-24 | 东南大学 | Dioxin retarder for synergistic dechlorination and denitration and preparation method thereof |
| CN115353900A (en) * | 2022-05-18 | 2022-11-18 | 河海大学 | Resource utilization method of macroalgae |
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| CN1784259A (en) * | 2002-12-09 | 2006-06-07 | 应用材料有限公司 | Method and apparatus for the abatement of toxic gas components from a semiconductor manufacturing process effluent stream |
| CN101773768A (en) * | 2010-03-16 | 2010-07-14 | 长春惠工净化工业有限公司 | Dechlorinating agent used for removing HCl from gas by dry method and preparation method thereof |
| CN103447067A (en) * | 2012-07-12 | 2013-12-18 | 北京英麟科贸有限公司 | Composite type catalyst and preparation method thereof |
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