CN103695918B - A kind of water-soluble rust prevention during manufacture liquid and preparation method thereof - Google Patents
A kind of water-soluble rust prevention during manufacture liquid and preparation method thereof Download PDFInfo
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- CN103695918B CN103695918B CN201310617889.3A CN201310617889A CN103695918B CN 103695918 B CN103695918 B CN 103695918B CN 201310617889 A CN201310617889 A CN 201310617889A CN 103695918 B CN103695918 B CN 103695918B
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- water
- during manufacture
- rust prevention
- prevention during
- titanium oxide
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- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 title claims abstract description 22
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
- 230000002265 prevention Effects 0.000 title claims abstract description 15
- 239000007788 liquid Substances 0.000 title claims abstract description 13
- 238000002360 preparation method Methods 0.000 title claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 8
- CCJAYIGMMRQRAO-UHFFFAOYSA-N 2-[4-[(2-hydroxyphenyl)methylideneamino]butyliminomethyl]phenol Chemical compound OC1=CC=CC=C1C=NCCCCN=CC1=CC=CC=C1O CCJAYIGMMRQRAO-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920000742 Cotton Polymers 0.000 claims abstract description 7
- 239000001293 FEMA 3089 Substances 0.000 claims abstract description 7
- SSOONFBDIYMPEU-UHFFFAOYSA-N [3-hydroxy-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propyl] prop-2-enoate Chemical compound OCC(CO)(CO)COCC(CO)(CO)COC(=O)C=C SSOONFBDIYMPEU-UHFFFAOYSA-N 0.000 claims abstract description 7
- 150000001336 alkenes Chemical class 0.000 claims abstract description 7
- 239000002270 dispersing agent Substances 0.000 claims abstract description 7
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 102000004160 Phosphoric Monoester Hydrolases Human genes 0.000 claims abstract description 4
- 108090000608 Phosphoric Monoester Hydrolases Proteins 0.000 claims abstract description 4
- GLDOVTGHNKAZLK-UHFFFAOYSA-N n-octadecyl alcohol Natural products CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims abstract description 4
- DYUWTXWIYMHBQS-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine Chemical compound C=CCNCC=C DYUWTXWIYMHBQS-UHFFFAOYSA-N 0.000 claims abstract description 4
- -1 octadecanol ester Chemical class 0.000 claims abstract description 4
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims abstract description 4
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 6
- 239000012467 final product Substances 0.000 claims description 6
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 3
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- 235000006040 Prunus persica var persica Nutrition 0.000 claims description 3
- 239000004115 Sodium Silicate Substances 0.000 claims description 3
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 3
- 229940043237 diethanolamine Drugs 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 3
- 240000006413 Prunus persica var. persica Species 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 abstract description 5
- 239000002184 metal Substances 0.000 abstract description 5
- 230000003064 anti-oxidating effect Effects 0.000 abstract description 2
- 239000002738 chelating agent Substances 0.000 abstract description 2
- 238000005202 decontamination Methods 0.000 abstract description 2
- 230000003588 decontaminative effect Effects 0.000 abstract description 2
- 239000006185 dispersion Substances 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 239000000178 monomer Substances 0.000 abstract description 2
- 229920000642 polymer Polymers 0.000 abstract description 2
- 239000003921 oil Substances 0.000 description 8
- 230000003449 preventive effect Effects 0.000 description 3
- 244000144730 Amygdalus persica Species 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 206010007269 Carcinogenicity Diseases 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007670 carcinogenicity Effects 0.000 description 1
- 231100000260 carcinogenicity Toxicity 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 231100000957 no side effect Toxicity 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000003405 preventing effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
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Abstract
The invention discloses a kind of water-soluble rust prevention during manufacture liquid, made by the raw material of following weight portion: sulfurized olefin cotton oil 4-6, turpentine oil 4-5, two octadecanol ester 1-2, diallylamine 1-2, nano titanium oxide 0.5-1, PVP 6-9, phosphatase 11-2, N hydroxymethyl acrylamide 10-15, dipentaerythritol acrylate 8-15, the smooth monostearate 1-2 of sorb, Dispersant MF 1-2, EDETATE SODIUM 1-2, auxiliary agent 4-5, water 300. The present invention uses multiple organic high molecular polymer monomer and chelating agent, can form film in metal surface, plays isolated air, anti-oxidation effect; By using nano titanium oxide, make antirust solution good dispersion, easily application, not stratified; Antirust solution film easy-clear of the present invention, is applicable to the rust prevention during manufacture that metal is processed, easy and simple to handle, can decontamination eliminate rust simultaneously, lubricated, facilitates next step operation to carry out.
Description
Technical field
The present invention relates to antirust technology field, relate in particular to a kind of water-soluble rust prevention during manufacture liquid and preparation method thereof.
Background technology
Metal surface is antirust is the important topic in industrial production, and traditional antirust solution, antirust oil has advantage also to have shortcoming. In common aqueous rust preventive, containing a large amount of natrium nitrosums, there is carcinogenicity, be unfavorable for environmental protection and person health, and adopt NMF to extend the life-span of aqueous rust preventive, bring again the disadvantage of touching with one's hand, being covered with dust, and can not be antirust for a long time; Although it is antirust for a long time that general hard film rust preventive oil is applicable to, film forming is also transparent attractive in appearance, and water white resin kind is less, and unstable also easy oxidation discoloration, also needs organic solvent dissolution, brings inflammable and explosive danger to be also unfavorable for environmental protection and health; General antirust oil uses mineral oil, difficult degradation, and also can bring the problem of oil removing difficulty when antirust for short-term. Therefore, comprehensive study performance is more excellent, and the antirust product being more applicable to for different occasion research is new direction and trend.
Summary of the invention
The object of the present invention is to provide a kind of water-soluble rust prevention during manufacture liquid and preparation method thereof, this antirust solution has the feature of favorable rust preventing effect, easy and simple to handle, easy cleaning.
Technical scheme of the present invention is as follows:
A kind of water-soluble rust prevention during manufacture liquid, is characterized in that being made up of the raw material of following weight portion: sulfurized olefin cotton oil 4-6, turpentine oil 4-5, two octadecanol ester 1-2, diallylamine 1-2, nano titanium oxide 0.5-1, PVP 6-9, phosphatase 11-2, N hydroxymethyl acrylamide 10-15, dipentaerythritol acrylate 8-15, the smooth monostearate 1-2 of sorb, Dispersant MF 1-2, EDETATE SODIUM 1-2, auxiliary agent 4-5, water 300. Described auxiliary agent is made up of the raw material of following weight portion: Tween-81 2-3, nano titanium oxide 0.1-0.2, sodium acid carbonate 1-2, diethanol amine 2-3, carboxymethyl cellulose 2-3, polyvinyl alcohol 1-2, peach gum 1-2, sodium metasilicate 1-2, urea 3-4, ammonium persulfate 1-2, water 20-24; Preparation method be ammonium persulfate is water-soluble after, then add other leftover materials, stir 10-15 minute, be heated to 70-80 DEG C, stirring reaction 1-2 hour, to obtain final product.
The preparation method of described water-soluble rust prevention during manufacture liquid, is characterized in that comprising the following steps: water, the smooth monostearate of sorb, Dispersant MF are mixed, be heated to 40-50 DEG C; Add sulfurized olefin cotton oil, turpentine oil, N hydroxymethyl acrylamide, dipentaerythritol acrylate, PVP, continue to be heated to 85-90 DEG C, stir 10-15 minute; Add other residual components, continue to stir 15-20 minute, to obtain final product.
Beneficial effect of the present invention
The present invention uses multiple organic high molecular polymer monomer and chelating agent, can form film in metal surface, plays isolated air, anti-oxidation effect; By using nano titanium oxide, make antirust solution good dispersion, easily application, not stratified; Antirust solution film easy-clear of the present invention, washing is fallen, and has no side effect, and is applicable to the rust prevention during manufacture of metal processing, easy and simple to handle, saves time, and can decontamination eliminate rust simultaneously, lubricated, facilitates next step operation to carry out.
Detailed description of the invention
A kind of water-soluble rust prevention during manufacture liquid, by following weight portion (kilogram) raw material make: sulfurized olefin cotton oil 5, turpentine oil 4.5, two octadecanol ester 1.5, diallylamine 1.5, nano titanium oxide 0.7, PVP 7, phosphatase 11 .5, N hydroxymethyl acrylamide 13, dipentaerythritol acrylate 12, the smooth monostearate 1.5 of sorb, Dispersant MF 1.5, EDETATE SODIUM 1.5, auxiliary agent 4.5, water 300. Described auxiliary agent by following weight portion (kilogram) raw material make: Tween-81 2, nano titanium oxide 0.1, sodium acid carbonate 2, diethanol amine 2, carboxymethyl cellulose 3, polyvinyl alcohol 2, peach gum 1, sodium metasilicate 2, urea 3, ammonium persulfate 1, water 20; Preparation method be ammonium persulfate is water-soluble after, then add other leftover materials, stir 10-15 minute, be heated to 70-80 DEG C, stirring reaction 1-2 hour, to obtain final product.
The preparation method of described water-soluble rust prevention during manufacture liquid, comprises the following steps: water, the smooth monostearate of sorb, Dispersant MF are mixed, be heated to 45 DEG C; Add sulfurized olefin cotton oil, turpentine oil, N hydroxymethyl acrylamide, dipentaerythritol acrylate, PVP, continue to be heated to 88 DEG C, stir 13 minutes; Add other residual components, continue to stir 17 minutes, to obtain final product.
The water-soluble rust prevention during manufacture liquid that this embodiment obtains detects by national standard, and damp heat test * (1) is qualified; Salt water immersion test * (1): qualified; Corrosion test * (2): qualified; Rust removability (inferior) < 6. Prepared water-soluble rust prevention during manufacture liquid is brushed on the steel matrix surface of being newly processed into and there is no greasy dirt, be placed in and within indoor 20 days, have no obvious iron mold.
Claims (2)
1. a water-soluble rust prevention during manufacture liquid, is characterized in that being made up of the raw material of following weight portion: sulfurized olefin cotton oil 4-6, turpentine oil 4-5, two octadecanol ester 1-2, diallylamine 1-2, nano titanium oxide 0.5-1, PVP 6-9, phosphatase 11-2, N hydroxymethyl acrylamide 10-15, dipentaerythritol acrylate 8-15, the smooth monostearate 1-2 of sorb, Dispersant MF 1-2, EDETATE SODIUM 1-2, auxiliary agent 4-5, water 300; Described auxiliary agent is made up of the raw material of following weight portion: Tween-81 2-3, nano titanium oxide 0.1-0.2, sodium acid carbonate 1-2, diethanol amine 2-3, carboxymethyl cellulose 2-3, polyvinyl alcohol 1-2, peach gum 1-2, sodium metasilicate 1-2, urea 3-4, ammonium persulfate 1-2, water 20-24; The preparation method of auxiliary agent be ammonium persulfate is water-soluble after, then add other leftover materials, stir 10-15 minute, be heated to 70-80 DEG C, stirring reaction 1-2 hour, to obtain final product.
2. the preparation method of water-soluble rust prevention during manufacture liquid according to claim 1, is characterized in that comprising the following steps: water, the smooth monostearate of sorb, Dispersant MF are mixed, be heated to 40-50 DEG C; Add sulfurized olefin cotton oil, turpentine oil, N hydroxymethyl acrylamide, dipentaerythritol acrylate, PVP, continue to be heated to 85-90 DEG C, stir 10-15 minute; Add other residual components, continue to stir 15-20 minute, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310617889.3A CN103695918B (en) | 2013-11-29 | 2013-11-29 | A kind of water-soluble rust prevention during manufacture liquid and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310617889.3A CN103695918B (en) | 2013-11-29 | 2013-11-29 | A kind of water-soluble rust prevention during manufacture liquid and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103695918A CN103695918A (en) | 2014-04-02 |
| CN103695918B true CN103695918B (en) | 2016-05-04 |
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| CN201310617889.3A Active CN103695918B (en) | 2013-11-29 | 2013-11-29 | A kind of water-soluble rust prevention during manufacture liquid and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110201870A (en) * | 2019-07-10 | 2019-09-06 | 陕西宝光真空电器股份有限公司 | A kind of electromagnetic pure iron part and preparation method thereof with transparent water-soluble protecting film |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4216032A (en) * | 1978-09-27 | 1980-08-05 | Stephen Gradowski | Oil composition and method for treating phosphated metal surfaces |
| CN1232079A (en) * | 1998-04-16 | 1999-10-20 | 北京百利威科技发展中心 | Internal cleaning agent for engine of car |
| CN103215594A (en) * | 2013-02-04 | 2013-07-24 | 安徽省繁昌县皖南阀门铸造有限公司 | Metal rust-preventive oil comprising coconut oil fatty acid diethanolamide |
| CN103215595B (en) * | 2013-02-04 | 2016-03-02 | 安徽省繁昌县皖南阀门铸造有限公司 | A kind of rust-proof oil containing sorbitan monooleate |
| CN103215596A (en) * | 2013-02-04 | 2013-07-24 | 安徽省繁昌县皖南阀门铸造有限公司 | Metal rust-preventive oil comprising chlorobutanol |
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Effective date of registration: 20240522 Address after: No. 98 Qicang Road, Mingguang City, Chuzhou City, Anhui Province, 239000 Patentee after: Mingguang Jiuzhi Intellectual Property Management Co.,Ltd. Country or region after: China Address before: 239400 No. 72, Liuwan Road, Mingguang Industrial Park, Chuzhou City, Anhui Province Patentee before: MINGGUANG CITY LIUXIANG PUMP INDUSTRY Co.,Ltd. Country or region before: China |