CN103694868A - Heat-resistant and flame-retardant anti-ultraviolet aging paint - Google Patents

Abstract

The invention relates to paint, and particularly relates to heat-resistant and flame-retardant anti-ultraviolet aging paint. The paint disclosed by the invention is prepared from the following raw materials in parts by weight: 20-24 parts of long oil alkyd resin, 20-24 parts of amino resin, 3-4 parts of sodium hexametaphosphate, 3-5 parts of 2,2,4-trimethyl-1,3-pentanediolmono(2-methylpropanoate), 1-2 parts of triethanolamine, 3-5 parts of aluminium tripolyphosphate, 3-5 parts of titanium dioxide, 1-2 parts of barium metaborate, 1-2 parts of 2,2-dibromo-3-nitrilopionamide, 2-3 parts of sodium tetraborate, 2-3 parts of sodium thiocyanate, 2-6 parts of hexabromocyclododecane, 3-4 parts of diethylene glycol monobutyl ether, 8-10 parts of propylene glycol methyl ether acetate, 1-2 parts of accelerant Na-22, 12-14 parts of nanosilicon dioxide, 2-3 parts of epoxy flaxseed oil, 3-4 parts of cobalt naphthenate, 1-2 parts of tributyl tin chloride, 5-6 parts of assistant, 10-12 parts of xylene and 10-12 parts of butyl acetate. The paint film of the paint disclosed by the invention is high in drying speed, bright and full in color and luster, lasting in color retaining property, good in thermal denaturation, heat-resistant and flame-retardant, weatherproof and anti-ageing, and ultraviolet irradiation resistant, and can be applied to beautiful protection of articles in various environments.

Description

A kind of heatproof flame-retardant anti-ultraviolet ageing paint

Technical field

The present invention relates to a kind of paint, be specifically related to a kind of heatproof flame-retardant anti-ultraviolet ageing paint and preparation technology thereof.

Background technology

Paint is seen everywhere in schedule life; it has been mainly the effect of protection and decoration, and according to different environments for use, the kind of paint is also varied; traditional paint ubiquity smell weighs, easily comes off, perishable; the problems such as inadequate environmental protection, can not meet the service requirements of human consumer to paint, therefore; need to improve the formula of original paint; the practicality and the weather resistance that increase paint, reduce its harm to environment and human body, and can adapt to various environment for use conditions.

Summary of the invention

The object of the invention is to, a kind of heatproof flame-retardant anti-ultraviolet ageing paint is provided, to achieve these goals, the technical solution used in the present invention is as follows:

A kind of heatproof flame-retardant anti-ultraviolet ageing paint, it is characterized in that, material of the present invention is made by the raw material of following weight part: long oil alkyd 20-24, aminoresin 20-24, Sodium hexametaphosphate 99 3-4, alcohol ester 12 3-5, trolamine 1-2, aluminium triphosphate 3-5, titanium dioxide 3-5, barium metaborate 1-2, 2, the bromo-3-nitrilo of 2-bis-propionic acid amide 1-2, sodium tetraborate 2-3, Sodium Thiocyanate 99 2-3, hexabromocyclododecane 2-6, Diethylene Glycol butyl ether 3-4, 1-Methoxy-2-propyl acetate 8-10, accelerant N a-221-2, nano silicon 12-14, epoxy Toenol 1140 2-3, cobalt naphthenate 3-4, tributyl tin trichloride 1-2, auxiliary agent 5-6, dimethylbenzene 10-12, butylacetate 10-12.

Described auxiliary agent is made by the raw material of following weight part: loess 1-2, polytetrafluoroethylene powder 4-5, altax 1-2, Silane coupling agent KH550 3-4, sodium laurate 1-2, jade 1-2, Whitfield's ointment 2-3, phthalic ester 35-40, Tenox PG 3-4, coix seed oil 2-3, vanadium diboride 1-2, l-Epicatechol 2-3; Preparation method sends into loess, jade in calcining furnace and calcine 2-3 hour at 720-740 ℃, then takes out, and sends in the hydrochloric acid soln of 10-15% and soaks 2-3 hour, filters, and obtains filter residue, with clear water, cleans, and dries, grinds to form 400-600 order powder; Gained powder mixes with other remaining component, is heated to 60-70 ℃, and stirring reaction 40-50 minute is cooling, grinds to form slurry, obtains.

Described a kind of heatproof flame-retardant anti-ultraviolet ageing paint, its preparation technology is:

(1) Sodium hexametaphosphate 99, barium metaborate, 1-Methoxy-2-propyl acetate, auxiliary agent are mixed, join in dimethylbenzene, butyl acetate solvent, be heated to 120-130 ℃, reaction 3-4 hour;

(2) material of step (1) is cooled to 70-85 ℃, adds hexabromocyclododecane, Diethylene Glycol butyl ether, epoxy Toenol 1140, stirring reaction 3-4 hour;

(3) material of step (2) is cooled to 50-65 ℃, adds other leftover materials, after stirring reaction 40-60 minute, be cooled to room temperature, grind to form 20-60 μ m slurry, obtain.

Compared with prior art, the present invention's paint possesses following advantage: drying varniss speed is fast, and bright in color is full, protects look lasting, temperature-change resistance, long service life, safe and reliable, fire resistant flame retardant, weather-proof aging, UV resistant irradiation, the article protection attractive in appearance can be used in multiple environment is used.

Embodiment

Embodiment

The present embodiment paint is made by following weight part raw material: long oil alkyd 24, aminoresin 24, Sodium hexametaphosphate 99 4, alcohol ester 12, trolamine 2, aluminium triphosphate 5, titanium dioxide 5, barium metaborate 2, DBNPA 2, sodium tetraborate 3, Sodium Thiocyanate 99 3, hexabromocyclododecane 4, Diethylene Glycol butyl ether 4,1-Methoxy-2-propyl acetate 10, accelerant N a-222, nano silicon 14, epoxy Toenol 1140 3, cobalt naphthenate 4, tributyl tin trichloride 2, auxiliary agent 6, dimethylbenzene 12, butylacetate 12.

Described auxiliary agent is made by the raw material of following weight part: loess 2, polytetrafluoroethylene powder 5, altax 2, Silane coupling agent KH550 4, sodium laurate 2, jade 2, Whitfield's ointment 3, phthalic ester 40, Tenox PG 4, coix seed oil 3, vanadium diboride 2, l-Epicatechol 3; Preparation method sends into loess, jade in calcining furnace and at 720-740 ℃, calcines 3 hours, then takes out, and sends in 15% hydrochloric acid soln and soaks 3 hours, filters, and obtains filter residue, with clear water, cleans, and dries, grinds to form 600 order powders; Gained powder mixes with other remaining component, is heated to 60-70 ℃, and stirring reaction 50 minutes is cooling, grinds to form slurry, obtains.

Described a kind of heatproof flame-retardant anti-ultraviolet ageing paint, its preparation technology is:

(1) Sodium hexametaphosphate 99, barium metaborate, 1-Methoxy-2-propyl acetate, auxiliary agent are mixed, join in dimethylbenzene, butyl acetate solvent, be heated to 120-130 ℃, react 4 hours;

(2) material of step (1) is cooled to 70-85 ℃, adds hexabromocyclododecane, Diethylene Glycol butyl ether, epoxy Toenol 1140, stirring reaction 4 hours;

(3) material of step (2) is cooled to 50-65 ℃, adds other leftover materials, stirring reaction, after 60 minutes, is cooled to room temperature, grinds to form 60 μ m slurries, obtains.

The performance test results of the present invention's paint is:

Above-mentioned test is all followed relevant criterion and is carried out.

Claims (2)

1. a heatproof flame-retardant anti-ultraviolet ageing paints, it is characterized in that, this paint is made by the raw material of following weight part: long oil alkyd 20-24, aminoresin 20-24, Sodium hexametaphosphate 99 3-4, alcohol ester 12 3-5, trolamine 1-2, aluminium triphosphate 3-5, titanium dioxide 3-5, barium metaborate 1-2, 2, the bromo-3-nitrilo of 2-bis-propionic acid amide 1-2, sodium tetraborate 2-3, Sodium Thiocyanate 99 2-3, hexabromocyclododecane 2-6, Diethylene Glycol butyl ether 3-4, 1-Methoxy-2-propyl acetate 8-10, accelerant N a-22 1-2, nano silicon 12-14, epoxy Toenol 1140 2-3, cobalt naphthenate 3-4, tributyl tin trichloride 1-2, auxiliary agent 5-6, dimethylbenzene 10-12, butylacetate 10-12,

Described auxiliary agent is made by the raw material of following weight part: loess 1-2, polytetrafluoroethylene powder 4-5, altax 1-2, Silane coupling agent KH550 3-4, sodium laurate 1-2, jade 1-2, Whitfield's ointment 2-3, phthalic ester 35-40, Tenox PG 3-4, coix seed oil 2-3, vanadium diboride 1-2, l-Epicatechol 2-3; Preparation method sends into loess, jade in calcining furnace and calcine 2-3 hour at 720-740 ℃, then takes out, and sends in the hydrochloric acid soln of 10-15% and soaks 2-3 hour, filters, and obtains filter residue, with clear water, cleans, and dries, grinds to form 400-600 order powder; Gained powder mixes with other remaining component, is heated to 60-70 ℃, and stirring reaction 40-50 minute is cooling, grinds to form slurry, obtains.

2. a kind of heatproof flame-retardant anti-ultraviolet ageing as claimed in claim 1 paints, and its manufacture craft is:

(1) Sodium hexametaphosphate 99, barium metaborate, 1-Methoxy-2-propyl acetate, auxiliary agent are mixed, join in dimethylbenzene, butyl acetate solvent, be heated to 120-130 ℃, reaction 3-4 hour;

(2) material of step (1) is cooled to 70-85 ℃, adds hexabromocyclododecane, Diethylene Glycol butyl ether, epoxy Toenol 1140, stirring reaction 3-4 hour;

(3) material of step (2) is cooled to 50-65 ℃, adds other leftover materials, after stirring reaction 40-60 minute, be cooled to room temperature, grind to form 20-60 μ m slurry, obtain.