CN103666061A - Liquid photosensitive corrosion-resistant printing ink and preparation method thereof - Google Patents
Liquid photosensitive corrosion-resistant printing ink and preparation method thereof Download PDFInfo
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- CN103666061A CN103666061A CN201310601762.2A CN201310601762A CN103666061A CN 103666061 A CN103666061 A CN 103666061A CN 201310601762 A CN201310601762 A CN 201310601762A CN 103666061 A CN103666061 A CN 103666061A
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Abstract
The invention discloses a liquid photosensitive corrosion-resistant printing ink which is characterized by being prepared from the following raw materials in parts by weight: 1-3 parts of an organic pigment, 10-12 parts of petroleum resin C5, 5-8 parts of allyl glycidyl ether, 1-2 parts of aluminium sulphate, 2-3 parts of 2-ethylhexyl dihydrogen phosphate, 10-12 parts of ethyl acrylate, 14-17 parts of 2-methyl methacrylate, 13-16 parts of ethylene-glycol, 20-30 parts of vermiculite, 1-2 parts of titanate coupling agent TMC-TTS, 26-29 parts of epoxidized triglyceride, 40-45 parts of bisphenol A epoxy acrylate, 10-12 parts of tripropylene glycol diacrylate, 7-9 parts of a photoinitiator 2959, and 4-5 parts of an additive. The additive improves the tenacity of the printing ink, enables the printing ink to disperse uniformly and maintains the stability of the printing ink. Moreover, the printing ink has the advantages of ultraviolet imaging, capability of developing in alkali water, and acid, alkali and neutral etching liquid resistance, and can be used for manufacturing high-definition patterns.
Description
Technical field
The present invention relates to a kind of ink and preparation method thereof, particularly anticorrosive ink of a kind of liquid photosensitive and preparation method thereof.
Background technology
Liquid photosensitive type resist is a kind of product growing up on the basis of photo-resist, and it is to make for solving a kind of ink that fine wire figure is developed, and is commonly called as wet film.Liquid photosensitive type resist is by photosensitive resin, sensitizer, filler, auxiliary agent, pigment and solvent composition, can be used for high-precision artwork, openworking template, the making of bat printing intaglio plate, also can be used for the making of multi-ply wood internal layer fine wire, because using epoxy resin, it makes thermosetting composition, so its chemical proofing, resistance to gold-plated, moisture-proof, heat-resisting and electric insulating quality is all fine.In view of this, when producing high-accuracy circuit card and multilayer circuit board, all used liquid photosensitive resist both at home and abroad.
At present, domestic have many producers to study and produce liquid photosensitive type etching resisting ink, but these products Shortcomings all aspect the comprehensive resistance to neutral etching solution of acid-fast alkali-proof and resistance to electroplate liquid generally can only adapt to the requirement of acidproof resistance to neutral etching solution and resistance to electroplate liquid; In addition, currently available products is difficult to the resolution that reaches higher, generally can only make the figure that minimum feature is 0.1 millimeter (mm).
Summary of the invention
The object of this invention is to provide anticorrosive ink of a kind of liquid photosensitive and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
The anticorrosive ink of liquid photosensitive, is made by the raw material of following weight part: pigment dyestuff 1-3, C5 petroleum resin 10-12, propenyl glycidyl ether 5-8, Tai-Ace S 150 1-2, ethylhexyl dihydrogen phosphate 2-3, ethyl propenoate 10-12,2-methyl methacrylate 14-17, ethylene glycol 13-16, vermiculite 20-30, titanate coupling agent TMC-TTS 1-2, epoxidation tri-glyceride 26-29, bisphenol A epoxy acrylate 40-45, tri (propylene glycol) diacrylate 10-12, light trigger 2959 7-9, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, morpholine 1-2, neopentyl glycol 3-4, oxidation inhibitor 1035 1-2, linking agent TAC2-3, tri (propylene glycol) diacrylate 10-12,1-Methoxy-2-propyl acetate 5-10, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
The anticorrosive ink of liquid photosensitive of the present invention, by following concrete steps, made: first add pigment dyestuff, C5 petroleum resin, propenyl glycidyl ether, Tai-Ace S 150, ethylhexyl dihydrogen phosphate, ethyl propenoate, 2-methyl methacrylate, ethylene glycol, vermiculite, titanate coupling agent TMC-TTS stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except light trigger 2959, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add light trigger 2959, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
The invention has the beneficial effects as follows: auxiliary agent of the present invention has improved the toughness of ink, make distributes ink even, and maintained the stability of ink; The anticorrosive ink of liquid photosensitive of the present invention have advantages of ultraviolet light imaging, can liquid alkali developing, the resistance to neutral etching solution of acid-fast alkali-proof, resistance to various electroplate liquids, can make fine figure.
Specific embodiments
Below by specific examples, the present invention is described in detail.
The anticorrosive ink of liquid photosensitive, by following weight part (kilogram) raw material make: pigment dyestuff 1, C5 petroleum resin 10, propenyl glycidyl ether 5, Tai-Ace S 150 1, ethylhexyl dihydrogen phosphate 2, ethyl propenoate 10,2-methyl methacrylate 14, ethylene glycol 13, vermiculite 20, titanate coupling agent TMC-TTS 1, epoxidation tri-glyceride 26, bisphenol A epoxy acrylate 40, tri (propylene glycol) diacrylate 10, light trigger 2,959 7, auxiliary agent 4;
Described auxiliary agent by following weight part (kilogram) raw material be prepared from: nano diatomite powder 0.2, nano mica powder 0.2, silane resin acceptor kh-550 2, morpholine 1, neopentyl glycol 3, oxidation inhibitor 1,035 1, linking agent TAC2, tri (propylene glycol) diacrylate 10,1-Methoxy-2-propyl acetate 5, Tenox PG 2, coix seed oil 1; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
The anticorrosive ink of liquid photosensitive of the present invention, by following concrete steps, made: first add pigment dyestuff, C5 petroleum resin, propenyl glycidyl ether, Tai-Ace S 150, ethylhexyl dihydrogen phosphate, ethyl propenoate, 2-methyl methacrylate, ethylene glycol, vermiculite, titanate coupling agent TMC-TTS stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except light trigger 2959, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add light trigger 2959, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
The ink of gained, is used cross-hatching ox-hide tape stripping, draws compartment apart from 1mm, and 100% adheres to; Spirituous cotton balls is soaked in use, and 300 grams of pressure wipings 50 times, are as good as shape; Be soaked in salad oil (normal temperature) 8 hours, be as good as shape; Use is soaked with the cotton balls of salt solution, and 300 grams of pressure wipings 50 times, are as good as shape.
Claims (2)
1. the anticorrosive ink of liquid photosensitive, it is characterized in that, by the raw material of following weight part, made: pigment dyestuff 1-3, C5 petroleum resin 10-12, propenyl glycidyl ether 5-8, Tai-Ace S 150 1-2, ethylhexyl dihydrogen phosphate 2-3, ethyl propenoate 10-12,2-methyl methacrylate 14-17, ethylene glycol 13-16, vermiculite 20-30, titanate coupling agent TMC-TTS 1-2, epoxidation tri-glyceride 26-29, bisphenol A epoxy acrylate 40-45, tri (propylene glycol) diacrylate 10-12, light trigger 2959 7-9, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, morpholine 1-2, neopentyl glycol 3-4, oxidation inhibitor 1035 1-2, linking agent TAC2-3, tri (propylene glycol) diacrylate 10-12,1-Methoxy-2-propyl acetate 5-10, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
2. the anticorrosive ink of liquid photosensitive according to claim 1, it is characterized in that, by following concrete steps, made: first add pigment dyestuff, C5 petroleum resin, propenyl glycidyl ether, Tai-Ace S 150, ethylhexyl dihydrogen phosphate, ethyl propenoate, 2-methyl methacrylate, ethylene glycol, vermiculite, titanate coupling agent TMC-TTS stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except light trigger 2959, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add light trigger 2959, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310601762.2A CN103666061B (en) | 2013-11-25 | 2013-11-25 | Anticorrosive ink of a kind of liquid photosensitive and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310601762.2A CN103666061B (en) | 2013-11-25 | 2013-11-25 | Anticorrosive ink of a kind of liquid photosensitive and preparation method thereof |
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| CN103666061A true CN103666061A (en) | 2014-03-26 |
| CN103666061B CN103666061B (en) | 2016-03-23 |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1884401A (en) * | 2005-06-24 | 2006-12-27 | 上海华明高技术（集团）有限公司 | Ultraviolet light cured printing ink |
| CN102643577A (en) * | 2012-05-03 | 2012-08-22 | 中钞油墨有限公司 | Environment-friendly printing ink suitable for high speed rotary printing |
| CN102850848A (en) * | 2012-03-20 | 2013-01-02 | 杭华油墨化学有限公司 | UV gravure RFID printing ink and preparation method thereof |
| CN103045011A (en) * | 2013-01-17 | 2013-04-17 | 佛山科学技术学院 | Blue ceramic ink-jet printing ink composition and preparation method thereof |
| CN103045015A (en) * | 2013-01-25 | 2013-04-17 | 深圳市万佳原丝印器材有限公司 | Liquid photo-imageable alkali developable and anodizing resistant ink and preparation method thereof |
| CN103319950A (en) * | 2013-06-19 | 2013-09-25 | 苏州凹凸彩印厂 | Carbon series electrically conductive ink |
-
2013
- 2013-11-25 CN CN201310601762.2A patent/CN103666061B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1884401A (en) * | 2005-06-24 | 2006-12-27 | 上海华明高技术（集团）有限公司 | Ultraviolet light cured printing ink |
| CN102850848A (en) * | 2012-03-20 | 2013-01-02 | 杭华油墨化学有限公司 | UV gravure RFID printing ink and preparation method thereof |
| CN102643577A (en) * | 2012-05-03 | 2012-08-22 | 中钞油墨有限公司 | Environment-friendly printing ink suitable for high speed rotary printing |
| CN103045011A (en) * | 2013-01-17 | 2013-04-17 | 佛山科学技术学院 | Blue ceramic ink-jet printing ink composition and preparation method thereof |
| CN103045015A (en) * | 2013-01-25 | 2013-04-17 | 深圳市万佳原丝印器材有限公司 | Liquid photo-imageable alkali developable and anodizing resistant ink and preparation method thereof |
| CN103319950A (en) * | 2013-06-19 | 2013-09-25 | 苏州凹凸彩印厂 | Carbon series electrically conductive ink |
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| CN103666061B (en) | 2016-03-23 |
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