CN103651513B - Missible oil containing flonicamid and Biphenthrin and application - Google Patents
Missible oil containing flonicamid and Biphenthrin and application Download PDFInfo
- Publication number
- CN103651513B CN103651513B CN201310672224.2A CN201310672224A CN103651513B CN 103651513 B CN103651513 B CN 103651513B CN 201310672224 A CN201310672224 A CN 201310672224A CN 103651513 B CN103651513 B CN 103651513B
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- CN
- China
- Prior art keywords
- biphenthrin
- flonicamid
- missible oil
- spotted spider
- spider mite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- RLQJEEJISHYWON-UHFFFAOYSA-N flonicamid Chemical compound FC(F)(F)C1=CC=NC=C1C(=O)NCC#N RLQJEEJISHYWON-UHFFFAOYSA-N 0.000 title claims abstract description 43
- 239000005900 Flonicamid Substances 0.000 title claims abstract description 42
- OMFRMAHOUUJSGP-IRHGGOMRSA-N bifenthrin Chemical compound C1=CC=C(C=2C=CC=CC=2)C(C)=C1COC(=O)[C@@H]1[C@H](\C=C(/Cl)C(F)(F)F)C1(C)C OMFRMAHOUUJSGP-IRHGGOMRSA-N 0.000 title claims abstract description 42
- 241001454293 Tetranychus urticae Species 0.000 claims abstract description 13
- 239000004480 active ingredient Substances 0.000 claims abstract description 5
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 27
- 239000003921 oil Substances 0.000 claims description 14
- 235000019198 oils Nutrition 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 9
- 235000019482 Palm oil Nutrition 0.000 claims description 7
- 229930006000 Sucrose Natural products 0.000 claims description 7
- 239000002540 palm oil Substances 0.000 claims description 7
- 239000005720 sucrose Substances 0.000 claims description 7
- 241000488581 Panonychus citri Species 0.000 claims description 3
- 235000002597 Solanum melongena Nutrition 0.000 claims description 3
- 244000061458 Solanum melongena Species 0.000 claims description 3
- 230000002195 synergetic effect Effects 0.000 abstract description 6
- 239000002917 insecticide Substances 0.000 abstract description 4
- 239000003905 agrochemical Substances 0.000 abstract description 3
- 239000002131 composite material Substances 0.000 abstract description 3
- 239000003814 drug Substances 0.000 description 14
- 241000238631 Hexapoda Species 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 241000607479 Yersinia pestis Species 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 239000000375 suspending agent Substances 0.000 description 3
- 231100000419 toxicity Toxicity 0.000 description 3
- 230000001988 toxicity Effects 0.000 description 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 231100000460 acute oral toxicity Toxicity 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- 241000272525 Anas platyrhynchos Species 0.000 description 1
- 241001124076 Aphididae Species 0.000 description 1
- 241000271566 Aves Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- DFPAKSUCGFBDDF-UHFFFAOYSA-N Nicotinamide Chemical compound NC(=O)C1=CC=CN=C1 DFPAKSUCGFBDDF-UHFFFAOYSA-N 0.000 description 1
- 241000283973 Oryctolagus cuniculus Species 0.000 description 1
- 241000286209 Phasianidae Species 0.000 description 1
- 208000031320 Teratogenesis Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 231100000293 acute skin toxicity Toxicity 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- -1 carrene Chemical compound 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000002703 mutagenesis Methods 0.000 description 1
- 231100000350 mutagenesis Toxicity 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- 239000011708 vitamin B3 Substances 0.000 description 1
- 235000019160 vitamin B3 Nutrition 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to the technical field that agricultural chemical insecticide is composite, be specially a kind of missible oil and the application that contain flonicamid and Biphenthrin.Active ingredient is flonicamid and Biphenthrin, wherein the weight ratio of flonicamid and Biphenthrin is, Biphenthrin: flonicamid=20:1-1:1, especially good to control two-spotted spider mite, mainly by the result of the synergistic function between each component.
Description
Technical field
The invention belongs to the technical field that agricultural chemical insecticide is composite, be specially a kind of missible oil and the application that contain flonicamid and Biphenthrin.
Background technology
Biphenthrin
Medium to person poultry toxicity, very high to fish toxicity.Be 54.5mg/kg to rat acute Oral toxicity LD50; 2000mg/kg is greater than to rabbit acute dermal toxicity LD50.Skin and eyes are had no stimulation, without teratogenesis, carcinogenic, mutagenesis.To birds low toxicity, be 1800mg/kg to quail acute oral toxicity LD50,4450mg/kg is greater than to wild duck.
Density relative density (d25) 1.21.
Stability is stablized light, also more stable in acid medium, store at normal temperatures 1 year still more stable, but to decompose in alkaline medium.
Physico-chemical property: sterling is white solid, in water, solvability is 0.1mg/l, is dissolved in acetone, chloroform, carrene, ether, toluene, heptane.Be slightly soluble in pentane, methyl alcohol, former medicine stablizes more than 1 year at 25 DEG C, stores at normal temperatures, and stability is greater than 1 year.21 days are stablized, DT50-65-125 days in soil at PH5-9 (21 DEG C).
But its action effect is also very single, after large-scale application, resistance risk is also very high.
Flonicamid
CA accession number: 158062-67-0.
Chemical name is N-cyanogen methyl .(trifluoromethyl) vitamin PP.
This product outward appearance is white tasteless pressed powder, fusing point 157.5 DEG C, vapour pressure (20 DEG C) 2.55x10-6pa, and solvability (g/L, 20 DEG C): water 5.2, acetone 157.1, methyl alcohol 89.0, to thermally-stabilised.
This agent of biologically active is effective to various sucking pest, and has good osmosis.It can from root to stem, the infiltration of leaf portion, but relatively weak to stem, root osmosis by leaf portion.This medicament causes effect by hindering insect act of sucking.Insect is taken in after medicament and stops very soon sucking, last hungry and dead.Insect according to electronics sucks behavior (EM III) and resolves, and this agent can make the lancet tissue of the sucking property insects such as aphid insert plant tissue and to cause effect.
But abuse makes insect generally produce very strong pesticide resistance to such medicament, and preventive effect is not equal to before.
Summary of the invention
The object of the present invention is to provide a kind of missible oil and the application that contain flonicamid and Biphenthrin, active ingredient is flonicamid and Biphenthrin, wherein the weight ratio of flonicamid and Biphenthrin is, Biphenthrin: flonicamid=20:1-1:1, especially good to control two-spotted spider mite, mainly by the result of the synergistic function between each component.
Technical scheme of the present invention is:
Contain a missible oil for flonicamid and Biphenthrin, active ingredient is flonicamid and Biphenthrin, and wherein the weight ratio of flonicamid and Biphenthrin is, Biphenthrin: flonicamid=20:1-1:1.
As preferably, the weight ratio of flonicamid and Biphenthrin is, Biphenthrin: flonicamid=10:1-7:1.
The missible oil of flonicamid of the present invention and Biphenthrin, it consists of following component by weight percentage:
Biphenthrin 1-75%,
Flonicamid 1-10%,
Sucrose glyceride 2-10%,
Methyl alcohol 1-15%,
Palm oil 1-5%.
As preferably, the missible oil of flonicamid of the present invention and Biphenthrin, it consists of following component by weight percentage:
Biphenthrin 70-75%,
Flonicamid 5-10%,
Sucrose glyceride 2-10%,
Methyl alcohol 1-15%,
Palm oil 1-5%.
Wherein, the total weight percentage of described active ingredient is 75 ~ 80%.
As preferred further, the missible oil of flonicamid of the present invention and Biphenthrin, it consists of following component by weight percentage:
Biphenthrin 70%,
Flonicamid 10%,
Sucrose glyceride 10%
Methyl alcohol 5%
Palm oil 5%.
The missible oil of flonicamid of the present invention and Biphenthrin, for preventing and treating citrus red mite, two-spotted spider mite, eggplant two spotted spider mite, is particularly useful for preventing and treating two-spotted spider mite.
Beneficial effect of the present invention is:
Said composition is compounded cream composition, compared with single product, there is the feature of binary composition, significantly enhance effect, delay the generation of pest resistance to insecticide, and expand effective active control spectrum, have speed fast, the lasting period is long, consumption is low, eco-friendly feature, the more important thing is, this compounded combination has effectively resisted the problem that pest resistance produces, farthest alleviate the problem of current pest resistance to insecticide, thus decrease the consumption of agricultural chemicals, also alleviate the impact for environment, meet the trend of future society environmental protection.The control efficiency of composition of the present invention is especially good to control two-spotted spider mite, mainly by the result of the synergistic function between each component.
Study the compound synergic of composition of the present invention, test adopts two-spotted spider mite to be used for test.
Concrete grammar is: the toxicity index and the mixed co-toxicity coefficient (CTC value) that calculate medicament according to the abundant method of Sun Yun.
Table 1 different ratio relation is to the toxicity test result of two-spotted spider mite
As can be seen from Table 1, flonicamid and Biphenthrin composite, has very high synergistic effect, especially Biphenthrin: during flonicamid=10:1-7:1, synergistic effect is more obvious.
Embodiment
Below by specific embodiment, technical scheme of the present invention is described in detail.
Embodiment 1
The composition of 80% flonicamid and Biphenthrin
Biphenthrin 70%,
Flonicamid 10%,
Sucrose glyceride 10%
Methyl alcohol 5%
Palm oil 5%.
Preparation method is the conventional method of this area.
This embodiment medicament is applied to control two-spotted spider mite:
Co-toxicity coefficient is: 320.8;
By 6000 times of thin up sprayings, after medicine, 7 days control efficiency are that 98.3%, 10% flonicamid suspending agent dilutes 600 times and 70% Biphenthrin missible oil dilutes 5000 times, use with same method respectively, after medicine 7 days, control efficiency was respectively 70.2% and 74.5%, significant difference.
Embodiment 2
The composition of 77% flonicamid and Biphenthrin
Flonicamid 70%,
Biphenthrin 7%,
Sucrose glyceride 7%
Methyl alcohol 15%
Palm oil 1%.
Preparation method is the conventional method of this area.
This embodiment medicament is applied to control citrus red mite:
Co-toxicity coefficient is: 326.7;
By 6000 times of thin up sprayings, after medicine, 7 days control efficiency are that 99.6%, 70% flonicamid suspending agent dilutes 5000 times and 7% Biphenthrin missible oil dilutes 500 times, use with same method respectively, after medicine 7 days, control efficiency was respectively 75.6% and 74.1%, significant difference.
Embodiment 3
The composition of 80% flonicamid and Biphenthrin
Flonicamid 75%,
Biphenthrin 5%,
Sucrose glyceride 8%
Methyl alcohol 8%
Palm oil 4%.
Preparation method is the conventional method of this area.
This embodiment medicament is applied to control eggplant two spotted spider mite:
Co-toxicity coefficient is: 224.1;
By 6000 times of thin up sprayings, after medicine, 7 days control efficiency are that 97.8%, 75% flonicamid suspending agent dilutes 5000 times and 5% Biphenthrin missible oil dilutes 400 times, use with same method respectively, after medicine 7 days, control efficiency was respectively 70.5% and 68.2%, significant difference.
Claims (3)
1. contain a missible oil for flonicamid and Biphenthrin, active ingredient is flonicamid and Biphenthrin, it is characterized in that, it consists of following component by weight percentage:
The composition of 80% flonicamid and Biphenthrin
Biphenthrin 70%,
Flonicamid 10%,
Sucrose glyceride 10%
Methyl alcohol 5%
Palm oil 5%.
2. the missible oil containing flonicamid and Biphenthrin according to claim 1 is for preventing and treating citrus red mite, two-spotted spider mite, eggplant two spotted spider mite.
3. the missible oil containing flonicamid and Biphenthrin according to claim 1 is for preventing and treating two-spotted spider mite.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310672224.2A CN103651513B (en) | 2013-12-10 | 2013-12-10 | Missible oil containing flonicamid and Biphenthrin and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310672224.2A CN103651513B (en) | 2013-12-10 | 2013-12-10 | Missible oil containing flonicamid and Biphenthrin and application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103651513A CN103651513A (en) | 2014-03-26 |
| CN103651513B true CN103651513B (en) | 2015-07-29 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310672224.2A Active CN103651513B (en) | 2013-12-10 | 2013-12-10 | Missible oil containing flonicamid and Biphenthrin and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103651513B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106719748B (en) * | 2016-11-25 | 2019-01-18 | 江西正邦作物保护有限公司 | A kind of composition pesticide containing Bifenazate and flonicamid |
| CN113826627A (en) * | 2020-06-23 | 2021-12-24 | 江苏功成生物科技有限公司 | Insecticidal composition containing flonicamid and pyrethroids and application |
| CN114642209A (en) * | 2021-03-26 | 2022-06-21 | 山东统防生物科技有限公司 | Flonicamid-bifenthrin pesticide preparation as well as preparation method and application thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002037964A1 (en) * | 2000-11-10 | 2002-05-16 | Syngenta Participations Ag | Synergistic pesticidal compositions comprising n-cyanomethyl-4-(trifluoromethyl)nicotinamide |
| CN101700036A (en) * | 2009-08-01 | 2010-05-05 | 深圳诺普信农化股份有限公司 | Pesticide composition and application thereof |
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| CN103651513A (en) | 2014-03-26 |
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| PB01 | Publication | ||
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| ASS | Succession or assignment of patent right |
Owner name: XU MAOHANG Free format text: FORMER OWNER: JINAN CAVIN BIOTECHNOLOGY CO., LTD. Effective date: 20150616 |
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| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20150616 Address after: Licang District of Shandong province 266000 fo Lu Zheng Qingdao City No. 17 Applicant after: Xu Maohang Address before: 250199, building 389, Huaxin Road, Licheng District, Shandong, Ji'nan 401 Applicant before: JINAN CAVIN BIOTECHNOLOGY CO., LTD. |
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Effective date of registration: 20190924 Address after: 233000 Xianghe Home Floor No.9, Xinhuai Road, Dongsheng Street, Longzihu District, Bengbu City, Anhui Province Patentee after: Bengbu Qibang Science and Technology Information Consulting Co., Ltd. Address before: Licang District of Shandong province 266000 fo Lu Zheng Qingdao City No. 17 Patentee before: Xu Mao Hang |
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Effective date of registration: 20200421 Address after: Han Miao Zhen Ji'nan plant protection science and Technology Industrial Park, Shanghe County, Jinan City, Shandong Province Patentee after: SHANDONG HUIMIN VANDA BIOLOGICAL TECHNOLOGY Co.,Ltd. Address before: 233000 Xianghe Home Floor No.9, Xinhuai Road, Dongsheng Street, Longzihu District, Bengbu City, Anhui Province Patentee before: Bengbu Qibang Science and Technology Information Consulting Co., Ltd. |