CN103641324A - Method for preparing sintering-free geopolymer foam glass - Google Patents
Method for preparing sintering-free geopolymer foam glass Download PDFInfo
- Publication number
- CN103641324A CN103641324A CN201310635571.8A CN201310635571A CN103641324A CN 103641324 A CN103641324 A CN 103641324A CN 201310635571 A CN201310635571 A CN 201310635571A CN 103641324 A CN103641324 A CN 103641324A
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- China
- Prior art keywords
- glass
- foam glass
- powder
- geopolymer foam
- geopolymer
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229920000876 geopolymer Polymers 0.000 title claims abstract description 18
- 238000000034 method Methods 0.000 title abstract description 12
- 239000011494 foam glass Substances 0.000 title abstract 7
- 239000011521 glass Substances 0.000 claims abstract description 39
- 239000000843 powder Substances 0.000 claims abstract description 20
- 238000003756 stirring Methods 0.000 claims abstract description 13
- 238000002360 preparation method Methods 0.000 claims abstract description 12
- 239000012190 activator Substances 0.000 claims abstract description 10
- 238000000227 grinding Methods 0.000 claims abstract description 7
- 238000012423 maintenance Methods 0.000 claims description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 239000006063 cullet Substances 0.000 claims description 13
- 235000019353 potassium silicate Nutrition 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 239000002002 slurry Substances 0.000 claims description 8
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 5
- 239000004111 Potassium silicate Substances 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 239000004411 aluminium Substances 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 claims description 5
- 229910052913 potassium silicate Inorganic materials 0.000 claims description 5
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 5
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 8
- 239000002994 raw material Substances 0.000 abstract description 7
- 239000003513 alkali Substances 0.000 abstract description 4
- 230000008569 process Effects 0.000 abstract description 4
- 239000002699 waste material Substances 0.000 abstract description 4
- 229910052799 carbon Inorganic materials 0.000 abstract description 3
- 238000005265 energy consumption Methods 0.000 abstract description 3
- 239000002910 solid waste Substances 0.000 abstract description 3
- 230000003213 activating effect Effects 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 7
- 230000006835 compression Effects 0.000 description 4
- 238000007906 compression Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- 241001274660 Modulus Species 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000005284 excitation Effects 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 239000011147 inorganic material Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000010451 perlite Substances 0.000 description 2
- 235000019362 perlite Nutrition 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- KMWBBMXGHHLDKL-UHFFFAOYSA-N [AlH3].[Si] Chemical compound [AlH3].[Si] KMWBBMXGHHLDKL-UHFFFAOYSA-N 0.000 description 1
- CQBLUJRVOKGWCF-UHFFFAOYSA-N [O].[AlH3] Chemical compound [O].[AlH3] CQBLUJRVOKGWCF-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 229920000592 inorganic polymer Polymers 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 239000008204 material by function Substances 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
Landscapes
- Processing Of Solid Wastes (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention discloses a method for preparing sintering-free geopolymer foam glass. The method comprises the steps of firstly grinding reclaimed waste glass in powder, then, uniformly mixing and stirring 100 parts by weight of glass powder, 30-60 parts by weight of alkaline activator and 1-5 parts by weight of foamer, pouring a mixture into a mold, curing for 24 hours in a curing box at the temperature of 60 DEG C, then, demolding, and continuously curing for 28 days, thereby obtaining the sintering-free geopolymer foam glass. According to the method disclosed by the invention, a high-temperature (750-900 DEG C) and high-energy-consumption process required by the general foam glass preparation processes is not required, so that the method is energy-saving, low-carbon and environmental-friendly; the waste glass serves as a raw material, so that the utilization ratio of solid wastes is high, other natural materials are not required to be consumed, and the raw material cost is reduced; the geopolymer foam glass is prepared by adopting an alkali activating principle, and the interior of the geopolymer foam glass contains a great deal of amorphous three-dimensional reticular structures, so that the geopolymer foam glass has good mechanical properties, low coefficient of heat conductivity and good stability and is a green, energy-saving and environment-friendly material.
Description
?
Technical field
The present invention relates to a kind of heat-insulating and sound-proof material, a kind of preparation method of burning free type geopolymer multicellular glass specifically, it is to utilize alkali exciting method to make the technology of multicellular glass after cullet is clayed into power.
Background technology
Multicellular glass is the heat-insulating and sound-proof material that a kind of over-all properties is very excellent.It has the good characteristics such as density is little, thermal conductivity is low, water-intake rate is low, acid-alkali-corrosive-resisting, compare with other building materials there is heat insulating, waterproof and dampproof, fire prevention, density is little, physical strength is high and a series of high-performances such as sound absorption, being widely used in industry and civil area, is 21 century one of the most rising functional materials.
At present, the production of multicellular glass is general adopts that to take perlite, float stone, mica, volcanic ash etc. be main raw material, through batching, enter mold forming, burn till the technological processs such as (foaming), annealing, excision forming and manufacture.But traditional method has not only consumed the natural materials that contains in a large number glassy phase, and in preparation technology, need the high temperature of 750 ~ 900 ℃ of firing process needs, the energy and Mineral resources consumption are all very large, are not a kind of preparation technologies of Sustainable development of environmental protection.
Cullet is as a kind of common solid waste, present stage China discarded glass reclaim after, generally first add some mineral material high-temperature fusion, the glass of plastotype Cheng Xin again, this recycling mode needs high temperature energy consumption very large, under current China energy-intensive situation, the environmental friendliness recycling mode of developing a kind of new low-carbon (LC) seems particularly important.
Geopolymer is the inorganic polymer material that a class has amorphous three-dimensional netted silicon-oxy tetrahedron and aluminum-oxygen tetrahedron structure, has the part advantage of inorganic materials and organic polymer concurrently.This material is having the excellent properties such as physical strength is high, acidproof, high temperature resistant, fire prevention, corrosion-resistant, weather resistance is strong because of its special structure.On the other hand, due to silicon-aluminium component that cullet contains some amount, can be used as in theory preparing the starting material of geopolymer.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of preparation method of burning free type geopolymer multicellular glass, and the method be take waste ceramic as raw material, does not add other natural materialss, has reduced cost, has saved resource, has improved the recovery utilization rate of waste ceramic.
The preparation method of a kind of burning free type geopolymer multicellular glass of the present invention, it comprises the following steps:
1), by common scrap glass sheet grinding 20 ~ 30 minutes in ball mill, levigate cullet powder can be crossed 100 mesh sieve can;
2) by scrap glass powder 100 weight parts, alkali-activator 30 ~ 60 weight parts, whipping agent 1 ~ 5 weight part, adds in concrete-agitating pot and stirs;
3) slurry stirring is poured in mould, then put into 60 ± 5 ℃, maintenance in the concrete curing box of relative humidity 99%, the demoulding after 24 hours.And then put into maintaining box maintenance certain hour and can obtain multicellular glass.
Step 2) described alkali-activator is a kind of in water glass, potassium silicate, sodium hydroxide, potassium hydroxide solution, and described water glass and the modulus of potassium silicate are between 1.0 ~ 2.0, and sodium hydroxide and potassium hydroxide solution concentration are 5 ~ 15mol/L.Whipping agent is aluminium powder or hydrogen peroxide.
Step 3) maintenance certain hour specifically refers to 28 days.
Preparation technology's main technological route of the present invention is: take cullet powder as main raw material, under the alkali excitation mechanism of alkali-activator, be prepared into geopolymer slurry, introduce whipping agent foaming at the uniform hole of the inner generation of geopolymer simultaneously.This slurry is entered to mold forming, and at 60 ℃, in the maintaining box of relative humidity 99%, maintenance is 28 days, can obtain that intensity is high, light weight, multicellular glass that thermal conductivity is low.
It is main fabricating technology that the present invention adopts alkali excitation principle, does not need the high-temperature technology of 750 ~ 900 ℃, reduces energy consumption; And take cullet as raw material, do not add other natural pit woods, reduce costs and economize on resources, improve the recovery utilization rate of cullet.Material of the present invention is inorganic materials, has overcome organic insulation material easy firing, inflammable critical defect.A large amount of unformed 3 D stereo reticulated structures are contained in its inside, have that thermal conductivity is low, heat-proof quality good, fire performance is good, a feature such as long service life, ageing-resistant performance are good.Raw material has replaced other natural matters such as perlite, float stone, mica with cullet, reduce resource consumption, has reduced production cost, has promoted the comprehensive utilization of solid waste.
embodiment:
Below embodiments of the invention are elaborated, the present embodiment is implemented take technical solution of the present invention under prerequisite, provided detailed embodiment and concrete operating process, but protection scope of the present invention is not limited to following embodiment.
Example 1:
The implementation case comprises the following steps:
(1), by common scrap glass sheet grinding 20 ~ 30 minutes in ball mill, levigate cullet powder can be crossed 100 mesh sieve can;
(2) by scrap glass powder 100 weight parts, water glass 55 weight parts of alkali-activator 1.2 moduluses, aluminium powder whipping agent 1.5 weight parts, add in concrete-agitating pot and stir;
(3) slurry stirring is poured in 4 ╳ 4 ╳ 16 3 gang mould tools, then put into 60 ± 5 ℃, maintenance in the concrete curing box of relative humidity 99%, the demoulding after 24 hours.And then put into maintaining box maintenance to 28 day and can obtain multicellular glass;
(4) maintenance is after 28 days, and the density that records prepared multicellular glass is 526kg/m3, ultimate compression strength 12.67MPa, folding strength 2.7MPa.
Example 2:
The implementation case comprises the following steps:
(1), by common scrap glass sheet grinding 20 ~ 30 minutes in ball mill, levigate cullet powder can be crossed 100 mesh sieve can;
(2) by scrap glass powder 100 weight parts, potassium silicate 60 weight parts of alkali-activator 2.0 moduluses, aluminium powder whipping agent 2 weight parts, add in concrete-agitating pot and stir;
(3) slurry stirring is poured in 4 ╳ 4 ╳ 16 3 gang mould tools, then put into 60 ± 5 ℃, maintenance in the concrete curing box of relative humidity 99%, the demoulding after 24 hours.And then put into maintaining box maintenance to 28 day and can obtain multicellular glass.
(4) maintenance, after 28 days, records the density 621kg/m of prepared multicellular glass
3, ultimate compression strength 13.737MPa, folding strength 3.27MPa.
Example 3:
The implementation case comprises the following steps:
(1), by common scrap glass sheet grinding 20 ~ 30 minutes in ball mill, levigate cullet powder can be crossed 100 mesh sieve can;
(2) by scrap glass powder 100 weight parts, alkali-activator 10mol/L sodium hydroxide solution 30 weight parts, hydrogen peroxide whipping agent 1 weight part, adds in concrete-agitating pot and stirs;
(3) slurry stirring is poured in 4 ╳ 4 ╳ 16 3 gang mould tools, then put into 60 ± 5 ℃, maintenance in the concrete curing box of relative humidity 99%, the demoulding after 24 hours.And then put into maintaining box maintenance to 28 day and can obtain multicellular glass.
(4) maintenance, after 28 days, records the density 214kg/m of prepared multicellular glass
3, ultimate compression strength 8.367MPa, folding strength 1.27MPa.
Example 4:
The implementation case comprises the following steps:
(1), by common scrap glass sheet grinding 20 ~ 30 minutes in ball mill, levigate cullet powder can be crossed 100 mesh sieve can;
(2) by scrap glass powder 100 weight parts, alkali-activator 10mol/L potassium hydroxide solution 60 weight parts, aluminium powder whipping agent 5 weight parts, add in concrete-agitating pot and stir;
(3) slurry stirring is poured in 4 ╳ 4 ╳ 16 3 gang mould tools, then put into 60 ± 5 ℃, maintenance in the concrete curing box of relative humidity 99%, the demoulding after 24 hours.And then put into maintaining box maintenance to 28 day and can obtain multicellular glass.
(4) record prepared multicellular glass after 28 days, density 386kg/m
3, ultimate compression strength 11.39MPa, folding strength 3.07MPa.
Claims (4)
1. a preparation method for burning free type geopolymer multicellular glass, is characterized in that comprising the following steps:
1), by common scrap glass sheet grinding 20 ~ 30 minutes in ball mill, levigate cullet powder can be crossed 100 mesh sieve can;
2) by scrap glass powder 100 weight parts, alkali-activator 30 ~ 60 weight parts, whipping agent 1 ~ 5 weight part, adds in concrete-agitating pot and stirs;
3) slurry stirring is poured in mould, then put into 60 ± 5 ℃, maintenance in the concrete curing box of relative humidity 99%, the demoulding after 24 hours, and then put into maintaining box maintenance certain hour and can obtain multicellular glass.
2. the preparation method of burning free type geopolymer multicellular glass according to claim 1, it is characterized in that step 2) described alkali-activator is a kind of in water glass, potassium silicate, sodium hydroxide, potassium hydroxide solution, described water glass and the modulus of potassium silicate are between 1.0 ~ 2.0, and sodium hydroxide and potassium hydroxide solution concentration are 5 ~ 15mol/L.
3. the preparation method of burning free type geopolymer multicellular glass according to claim 1 and 2, is characterized in that step 2) described whipping agent is aluminium powder or hydrogen peroxide.
4. the preparation method of burning free type geopolymer multicellular glass according to claim 1 and 2, is characterized in that step 3) maintenance certain hour is 28 days.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310635571.8A CN103641324A (en) | 2013-12-03 | 2013-12-03 | Method for preparing sintering-free geopolymer foam glass |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310635571.8A CN103641324A (en) | 2013-12-03 | 2013-12-03 | Method for preparing sintering-free geopolymer foam glass |
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| Publication Number | Publication Date |
|---|---|
| CN103641324A true CN103641324A (en) | 2014-03-19 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310635571.8A Pending CN103641324A (en) | 2013-12-03 | 2013-12-03 | Method for preparing sintering-free geopolymer foam glass |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105016640A (en) * | 2015-07-21 | 2015-11-04 | 桂林理工大学 | Preparation method of concrete doped with waste glass as concrete fine aggregate |
| CN107814497A (en) * | 2016-09-13 | 2018-03-20 | 黄忠信 | Binder, method for producing cured mortar, and cured mortar produced by the method |
| US10315954B2 (en) * | 2013-12-20 | 2019-06-11 | Universidade Estadual De Ponta Grossa | Geopolymer cement produced from recycled glass and method for producing same |
| CN111977976A (en) * | 2020-08-31 | 2020-11-24 | 武汉佳宝华节能科技有限公司 | Environment-friendly foam glass insulation board and production process thereof |
| CN112723911A (en) * | 2021-01-19 | 2021-04-30 | 河北工业大学 | Regenerated powder-based inorganic cementing material toughening and crack reducing foaming agent and application thereof |
| CN114133193A (en) * | 2021-12-09 | 2022-03-04 | 江苏银辉生态科技有限公司 | Baking-free foam glass insulation board and preparation method thereof |
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| CN102584323A (en) * | 2012-02-06 | 2012-07-18 | 广西大学 | Geopolymeric light porous material and preparation method thereof |
| CN102633449A (en) * | 2012-05-03 | 2012-08-15 | 南京大学 | High-strength glass base polymer and preparation method thereof |
| CN103241968A (en) * | 2013-05-24 | 2013-08-14 | 杭州电子科技大学 | Method for preparing low-lead-glass-based polymer |
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2013
- 2013-12-03 CN CN201310635571.8A patent/CN103641324A/en active Pending
Patent Citations (5)
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| JP2011219281A (en) * | 2010-04-05 | 2011-11-04 | Furukawa Electric Co Ltd:The | Water-absorbable geopolymer stock, water-absorbable porous building material using the same, and method for producing the water-absorbable geopolymer stock and the water-absorbable porous building material |
| CN101891498A (en) * | 2010-06-23 | 2010-11-24 | 南京大学 | Method for preparing fly ash-based geopolymer aerated concrete |
| CN102584323A (en) * | 2012-02-06 | 2012-07-18 | 广西大学 | Geopolymeric light porous material and preparation method thereof |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10315954B2 (en) * | 2013-12-20 | 2019-06-11 | Universidade Estadual De Ponta Grossa | Geopolymer cement produced from recycled glass and method for producing same |
| CN105016640A (en) * | 2015-07-21 | 2015-11-04 | 桂林理工大学 | Preparation method of concrete doped with waste glass as concrete fine aggregate |
| CN107814497A (en) * | 2016-09-13 | 2018-03-20 | 黄忠信 | Binder, method for producing cured mortar, and cured mortar produced by the method |
| CN111977976A (en) * | 2020-08-31 | 2020-11-24 | 武汉佳宝华节能科技有限公司 | Environment-friendly foam glass insulation board and production process thereof |
| CN111977976B (en) * | 2020-08-31 | 2023-02-24 | 武汉佳宝华节能科技有限公司 | Environment-friendly foam glass insulation board and production process thereof |
| CN112723911A (en) * | 2021-01-19 | 2021-04-30 | 河北工业大学 | Regenerated powder-based inorganic cementing material toughening and crack reducing foaming agent and application thereof |
| CN112723911B (en) * | 2021-01-19 | 2021-07-27 | 河北工业大学 | Regenerated powder-based inorganic cementing material toughening and crack reducing foaming agent and application thereof |
| CN114133193A (en) * | 2021-12-09 | 2022-03-04 | 江苏银辉生态科技有限公司 | Baking-free foam glass insulation board and preparation method thereof |
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Application publication date: 20140319 |