CN103636660A - Environmental-friendly particulate agent for controlling sugarcane pests - Google Patents
Environmental-friendly particulate agent for controlling sugarcane pests Download PDFInfo
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Abstract
The invention discloses an environmental-friendly particulate agent for controlling sugarcane pests. The particulate agent comprises the following components in percentage by weight: 0.1 to 10% of effective active component, 5% to 20% of auxiliary agent, and the balance being filling material; wherein the effective active component is one or two components selected from the following components: clothianidin, phoxim, high efficient cyhalothrin, abamectin, chlorpyrifos and bifenthrin; and the filling material is the residue of plants which have been extracted for essential oil. In this preparation method, the residue of plants, which have been extracted for essential plants, is taken as the pesticide absorption carrier; because the plant residue has a good absorbing performance, and the residual essential oil has a certain expellant and killing effect on pests at the same time, the effect of more efficiently controlling the sugarcane pests is achieved; moreover the plant residue is mainly composed of lignin, which is easy to decompose in the environment and is pollution-free; furthermore, the plant residue carrier has a lower cost than those of other carriers, is more environment-friendly and safer, and does not be restricted by the resources.
Description
Technical field:
The present invention relates to control of insect technical field, be specifically related to a kind of for preventing and treating the Environmental-protection particle agent of Sugarcane Pests.
Background technology:
Sugarcane Pests is of a great variety, and sugarcane production different times is threatened by different insect pests, and sugarcane yield and quality are all had a significant impact.The insect generally occurring on sugarcane has: sugarcane borer, cockchafer subclass, sugar cane cottony aphid, termite, Sugarcane Thrips, mealybug etc., gnaw rhizome and invasion growing point position, cause withered heart seedling, destroy sugarcane stem tissue, sugarcane sugar is reduced, and be prone to windbreak stem or spike top, reduce output, when serious, the underproduction is more than 20%.Granule is the upper conventional formulation of Sugarcane Pests control, but it is carrier that conventional granule is used a large amount of quartz sand, kaolin, imvite, diatomite, clay powder, attapulgite, carclazyte, precipitated calcium carbonate etc., both cause a large amount of wastings of resources, increased pesticide cost simultaneously.
Savage harm due to Sugarcane Pests, in spraying with fill with root and prevent and treat undesirable in the situation that, sugarcane has become research and development focus with granular insecticide, domestic more existing research institutions and enterprise are at research and production sugarcane granule, the patent No. is that 201210407726.8 denominations of invention are the fertilizer granules > > that mono-kind of < < prevents and treats sugarcane moth borer, disclose that a kind of to take the medicine that neonicotine pesticide clothianidin or imidaclothiz be the control sugarcane moth borer as insecticidal constituent fertile, carrier is kaolin, imvite, diatomite, clay powder, attapulgite, carclazyte, one or more combinations in precipitated calcium carbonate and talcum powder.Application number is that 201310014350.9 denominations of invention are: < < sugarcane insecticide fertilizer granular formulation and preparation method thereof > > discloses the fertile expenses for medicine granule of medicine that a kind of active ingredient is the control Sugarcane Pests of clothianidin and chlopyrifos, usings a kind of as excipient in starch, carboxymethyl cellulose, clay, diatomite, carclazyte, kaolin, bentonite or calcium carbonate.Application number is 201010515180.9, denomination of invention be < < containing the sugarcane insecticide > > of anabasine insecticide be utilize anabasine insecticide Diacloden, Imidacloprid or thiacloprid and organophosphorus insecticides composite, sugarcane cotten aphid, snout moth's larva, thrips and soil insect etc. are had to good preventive effect, but this product adopts quartz sand, montmorillonite etc. as carrier in a large number simultaneously, waste resource, also increased drug cost.Application number is that 201110293141.3 denominations of invention are: the Synergistic insecticidal compositions that < < contains clothianidin and Biphenthrin and application > > thereof disclose a kind of Pesticidal combination and application thereof that clothianidin and Biphenthrin be active ingredient of take, clothianidin and Biphenthrin composite rear to homoptera pest as trialeurodes vaporariorum, aphids etc. have synergistic effect, filler is white carbon, precipitated calcium carbonate, potter's clay, kaolin, diatomite, zeolite, one or more combinations of talcum powder etc.The patent No. is 201210286737.5, denomination of invention be the granule > > of < < clothianidin-containing to disclose active ingredient be the complex preparation granule of clothianidin, gamma cyhalothrin or Biphenthrin, but the carrier of using is white carbon, diatomite, active carbon kaolin, bentonite, calcium carbonate, urea, ammonium chloride etc.
China has abundant Aromatic Plant Resources, has more than 500 to plant volatile oil plant and be distributed widely in 20Duo Ge provinces and cities.2005, national essential oil output was 19.8 ten thousand tons, and the provinces such as Guangdong, Guangxi, Jiangxi are the important localities of the aromatic plants such as China Chinese anise, Chinese cassia tree, eucalyptus, fragrant citrus, camphor tree.Plants essential oil extracts the general methods such as distillation, squeezing, extraction that adopt from position extractions such as the branches and leaves of fragrant plant, bark, root, stem, flower, fruits, the low boiling, the volatile essential oil compounds that only extract as a rule, the recovery rate of essential oil is not high, when conventional steam distillation is processed essential oil raw material, extraction of essential oil rate is generally 0.1～0.5%, supercritical CO
2what extraction yield and solvent flashing extraction recovery rate had reaches 10%, produces a large amount of residues after extraction of essential oil, and residue also exists most valuable natural materials.Because plants essential oil aromatics plant itself has the insecticidal activity such as tag, walk quickly and keep away, in the residue after extraction of essential oil, also contain certain active substance, in peppermint residue, there is according to the literature sterol, phosphatide, organic acid, flavonoids, amino acids material.Clore basil, kind leaf, lavender, contain Natural Antioxidants vitamin E, flavonoids, sterol etc. in residue after the plants essential oils such as peppermint extract.Oleum Eucalypti extract residue can be used as growth regulator has good effect to the growth of multiple kinds of crops and the extermination of disease and insect pest, and do not pollute and residual toxicity, have very large application potential (referring to document: А. Б. С к в o р ц o в а, Л. К. Г у р и н o в и ч, kingdom's beam. the comprehensive utilization of waste material after essential oil Raw material processing---the natural products that scenting cosmetics industry is new. < < fragrance flavor and cosmetic > > 1992.02.).Although the residue after extraction of essential oil can extract other useful compound, because the factor availabilitys such as equipment requirement is high, processing cost is large are high, arbitrarily do not abandoned, can not get reasonable utilization, cause the wasting of resources and environmental pollution.
Utilize aromatic plant to extract the environment-protecting pesticide granule of the control Sugarcane Pests that the residue after essential oil is carrier, do not report at present.
Summary of the invention:
The object of this invention is to provide a kind of for preventing and treating the Environmental-protection particle agent of Sugarcane Pests.
The present invention is achieved by the following technical programs:
For preventing and treating an Environmental-protection particle agent for Sugarcane Pests, the component that contains following percentage by weight:
Effective active composition 0.1-10%,
Auxiliary agent 5%-20%,
All the other are filler, and filler supplies 100%;
Described effective active composition is selected from one or both in clothianidin, phoxim, gamma cyhalothrin, Avermectin, chlopyrifos, Biphenthrin;
Described filler is that aromatic plant extracts the residue after essential oil, is selected from the residue after one or more extraction essential oils in the aromatic plants such as Chinese cassia tree, camphor tree, eucalyptus, China fir, Chinese anise, clore basil, peppermint, lemongrass, Chinese ilex.
Described auxiliary agent is auxiliary agent conventional in agricultural chemicals, comprises cosolvent, emulsifier, dispersion moisture agent, bleeding agent, colouring agent, binding agent.
Described cosolvent is selected from least one in the soybean oil that methylates, biodiesel, turpentine oil, chloroform, methyl alcohol, ethanol, butanols, isoamyl alcohol, cyclohexanone, ethyl acetate, dimethyl sulfoxide (DMSO), methyl cellosolve.
Described emulsifier is selected from one or more in lauric acid APEO, oleic acid polyoxyethylene, fatty alcohol-polyoxyethylene ether, phenethyl phenol polyethenoxy polyethenoxy ether, tween, polyethylene glycol hard fatty acid ester, glycerine fatty acid, castor oil ethylene oxide adduct, alkylphenol polyoxyethylene formaldehyde condensation products, alkyl benzene calcium sulfonate, alkylnaphthalene sulfonate etc.Described emulsifier is 0.5～10%(percentage by weight), preferably 1%～8%.
Described dispersion moisture agent is selected from sodium lignin sulfonate, calcium lignosulfonate, alkylnaphthalene sulfonate formaldehyde condensation, lauryl alcohol polyethylene glycol oxide base ether sodium sulfate, Negel, naphthalene sulfonic acid-formaldehyde condensation product, methyl oleate, alkylphenol-polyethenoxy base ether formaldehyde condensation products, alkyl polyoxyethylene ether sulfonate, pull open in powder, the withered powder of tea, saponin, lauryl sodium sulfate, neopelex one or more.
Described bleeding agent is selected from the condensation product of fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, poly alkyl alcohol oxyalkyl ether or fatty alcohol and oxirane.
Described colouring agent is selected from that famille rose, rigidity are red, red, a kind of in Prussian blue, and consumption is 0.5%～2.0%(percentage by weight).
Described binding agent is selected from least one in starch, polyvinyl alcohol, carboxymethyl cellulose, clay, sucrose.
The Environmental-protection particle agent of the control Sugarcane Pests described in the present invention also provides is as the application of sugarcane insecticide.
The present invention has following beneficial effect:
The present invention utilizes aromatic plant to extract residue after essential oil after simple oven dry, pulverizing, as agricultural chemicals absorption carrier, utilize its good absorption property, utilize remaining essential oil in residue that insect is had and necessarily walked quickly and kept away and toxic action simultaneously, thereby reach the effect of preventing and treating more efficiently Sugarcane Pests, and the residue after extraction essential oil be take lignin as main, easily degraded in environment, pollution-free, with respect to other carrier costs not only cost significantly reduce, and more environmental protection, safety, be not subject to resource limitation.Other carriers are such as kaolin, silica flour, montmorillonite, diatomite etc. are non-renewable resources, and not only price is more expensive, and a large amount of exploitation, can cause environmental pollution, the wasting of resources.
Embodiment:
Below to further illustrate of the present invention, rather than limitation of the present invention.
After the aromatic plant processing such as Chinese cassia tree, camphor tree, eucalyptus, China fir, Chinese anise, camphor tree, clore basil, peppermint, lemongrass, Chinese ilex, residue is all purchased from the Jishui County natural medicinal oil of health god refinery.
Described cosolvent is selected from least one in the soybean oil that methylates, biodiesel, turpentine oil, chloroform, methyl alcohol, ethanol, butanols, isoamyl alcohol, cyclohexanone, ethyl acetate, dimethyl sulfoxide (DMSO), methyl cellosolve;
Described emulsifier is selected from one or more in lauric acid APEO, oleic acid polyoxyethylene, fatty alcohol-polyoxyethylene ether, phenethyl phenol polyethenoxy polyethenoxy ether, tween, polyethylene glycol hard fatty acid ester, glycerine fatty acid, castor oil ethylene oxide adduct, alkylphenol polyoxyethylene formaldehyde condensation products, alkyl benzene calcium sulfonate, alkylnaphthalene sulfonate etc.Described emulsifier is 0.5～10%(percentage by weight), preferably 1%～8%
Described dispersion moisture agent is selected from sodium lignin sulfonate, calcium lignosulfonate, alkylnaphthalene sulfonate formaldehyde condensation, lauryl alcohol polyethylene glycol oxide base ether sodium sulfate, Negel, naphthalene sulfonic acid-formaldehyde condensation product, methyl oleate, alkylphenol-polyethenoxy base ether formaldehyde condensation products, alkyl polyoxyethylene ether sulfonate, pull open in powder, the withered powder of tea, saponin, lauryl sodium sulfate, neopelex one or more.
Described bleeding agent is selected from the condensation product of fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, poly alkyl alcohol oxyalkyl ether or fatty alcohol and oxirane.
Described colouring agent is selected from that famille rose, rigidity are red, red, a kind of in Prussian blue, and consumption is 0.5%～2.0%(percentage by weight).
Described binding agent is selected from least one in starch, polyvinyl alcohol, carboxymethyl cellulose, clay, sucrose.
Embodiment mono-: formulation Example
Formulation Example 11.0% clothianidin granule
Clothianidin 1.0%, amino-oligosaccharide 0.5%, cosolvent 5%, dispersion moisture agent 3%, disintegrant 2.0%, colouring agent 2.0%, binding agent 2%, eucalyptus slag supplies 100%.
Formulation Example 22.5% clothianidin granule
Clothianidin 2.5%, brassin lactones 0.01%, cosolvent 5%, dispersion moisture agent 3.0%, disintegrant 5.0%, colouring agent 2.0%, binding agent 2.5%, Chinese cassia tree, eucalyptus slag supply 100%.
Formulation Example 310% chlopyrifos granule
Chlopyrifos 10.0%, amino-oligosaccharide 0.5%, cosolvent 7%, dispersion moisture agent 3.5%, disintegrant 2.0%, colouring agent 2.0%, binding agent 2.5%, Chinese cassia tree slag supplies 100%.
Formulation Example 43.0% phoxim granule
Phoxim 3.0%, amino-oligosaccharide 0.5%, cosolvent 8%, dispersion moisture agent 4%, disintegrant 3.0%, colouring agent 0.5%, binding agent 2.5%, camphor tree slag supplies 100%.
Formulation Example 53.0% Biphenthrin clothianidin granule
Clothianidin 1.0%, Biphenthrin 2.0%, cosolvent 5%, amino-oligosaccharide 0.5%, dispersion moisture agent 5%, disintegrant 5.0%, colouring agent 0.5%, binding agent 2.5%, Chinese anise slag supply 100%.
Formulation Example 61.0% clothianidin gamma cyhalothrin granule
Clothianidin 0.5%, gamma cyhalothrin 0.5%, amino-oligosaccharide 0.5%, dispersant wetting agent 6%, cosolvent 5.0%, disintegrant 5%, colouring agent 1.0%, binding agent 3%, Chinese cassia tree slag supply 100%.
Formulation Example 73.0% clothianidin gamma cyhalothrin granule
Clothianidin 1.0%, gamma cyhalothrin 2.0%, brassin lactones 0.005%, dispersant wetting agent 4%, cosolvent 5.0%, disintegrant 3%, colouring agent 1.0%, binding agent 3%, Chinese cassia tree slag supply 100%.
Formulation Example 83.5% clothianidin chlopyrifos granule
Clothianidin 0.5%, chlopyrifos 3.0%, brassin lactones 0.001%, dispersant wetting agent 5%, cosolvent 5.0%, disintegrant 3%, colouring agent 1.0%, binding agent 5%, China fir, clore basil slag supply 100%.
Formulation Example 910.0% clothianidin chlopyrifos granule
Clothianidin 0.5%, chlopyrifos 9.5%, amino-oligosaccharide 1.0%, dispersant wetting agent 2%, cosolvent 5.0%, disintegrant 5%, colouring agent 1.0%, binding agent 5%, peppermint slag supply 100%.
Formulation Example 105.0% clothianidin Abamectin
Clothianidin 1.0%, Avermectin 4.0%, brassin lactones 0.001%, dispersion moisture agent 5%, cosolvent 5%, colouring agent 1.0%, disintegrant 8%, lemongrass slag supply 100%.
Formulation Example 114.0% clothianidin phoxim granule
Clothianidin 0.5%, phoxim 3.5%, brassin lactones 0.001%, dispersion moisture agent 5%, cosolvent 5.5%, colouring agent 1.0%, disintegrant 8%, Chinese ilex wood slag supply 100%.
Embodiment bis-, evaluating drug effect test
Evaluating drug effect embodiment 1: toxicity screening
After aromatic plant Raw material processing, residue is to the toxicity of tagging to termite, sugarcane tortoise
Pesticide-clay mixture method is measured the tag toxicity of the rear residue of aromatic plant processing to termite.According to the consumption of 5mg/g, mixing soil uses.Take the arid soil that 100g crosses 60 mesh sieves, admix residue after 0.5g aromatic plant Raw material processing, be placed in diameter and be in the culture dish of 9cm (20g/ ware), evenly mat formation.Then by 20 termites (work slave: soldier ant=9:1) put into the culture dish of processing, and put into the sugarcane of 3cm left and right, as the food source of termite, drip water and keep moistening.Similarity condition is established blank, and 3 repetitions are established in each processing, in dark surrounds, under room temperature, cultivate.Observed and recorded result of the test after processing 48h, 72h.During observation, with tweezers, touch polypide, nymph body and feeler are all reactionless, are judged to death.
The test of sugarcane tortoise contact toxicity is the same, puts into 10 cephalonts in each culture dish, observed and recorded result of the test after processing 48h, 72h.
Average mortality (%)=(borer population alive after processing for the total borer population one of examination)/for the total borer population * 100% of examination.
Check experiment is selected quartz sand, diatomite.
Result of the test is as shown in table 1, and after aromatic plant extracts essential oil, residue has certain contact toxicity to termite, and after Chinese cassia tree, Chinese anise, camphor tree residue treatment 72h, termite lethality is greater than 15%.After aromatic plant extracts essential oil, residue is poor to the contact toxicity of sugarcane tortoise, and Chinese cassia tree, lemongrass are processed rear 72h, and the lethality of sugarcane tortoise is 10%.Quartz sand and diatomite are processed, and the lethality of termite, sugarcane tortoise is 0.
The lethality of table 1 different disposal termite, sugarcane tortoise
Evaluating drug effect embodiment 2: field efficacy evaluation test:
Control, the test processing of with embodiment 1-4 products obtained therefrom, carrying out sugarcane moth borer, sugarcane tortoise arrange as follows:
Process 11.0% clothianidin granule
Process 22.5% clothianidin granule
Process 310% chlopyrifos granule
Process 43.0% phoxim granule
Contrast 150% clothianidin water dispersible granules
Contrast 215% chlopyrifos granule
Contrast 33% phoxim granule
Above-mentioned processing is used when sugarcane is sowed, admixing certain proportion sand or earth imposes in ditch, contrast 1 clothianidin water dispersible granules, after dilute with water, fill with root and use, while within after medicine 60 days, 90 days, carrying out respectively the investigation of sugarcane moth borer, sugarcane tortoise situation of the harm, sugarcane harvesting, carry out determination of yield, final statistics is as shown in table 2:
Table 2: Sugarcane Pests control and volume increase field test results statistical form
As known from Table 2: clothianidin, chlopyrifos, phoxim all have certain control efficiency to snout moth's larva, sugarcane tortoise, termite, utilize granule described in the embodiment of the present invention to be applied to sugarcane field, better to the control efficiency of Sugarcane Pests compared with the control, after medication after 90 days, sugarcane moth borer, sugarcane tortoise, termite preventive effect, more than 80%, are all greater than to contrast.Because wood chip suction-operated is strong, slow down active ingredient and discharge, drug effect is sustainable more than 90 days, and whole dispenser breeding time of sugarcane 1 time, saves labour cost greatly.
Control, the test processing of with the composite product of embodiment 5-11 gained, carrying out sugarcane aphid, scale insect thrips arrange as follows:
Process 13.0% Biphenthrin clothianidin granule (1:3)
Process 21.0% clothianidin gamma cyhalothrin granule (1:1)
Process 33.0% clothianidin gamma cyhalothrin granule (1:2)
Process 43.5% clothianidin chlopyrifos granule (1:6)
Process 510.0% clothianidin chlopyrifos granule (1:19)
Process 65.0% clothianidin Abamectin (1:4)
Process 74.0% clothianidin phoxim granule (1:7)
Contrast 13% carbofuran granule
Above-mentioned processing is used when sugarcane is sowed, and admixes certain proportion sand or earth and imposes in ditch, within after medicine 30 days, 60 days, carries out respectively sugarcane aphid, and the investigation of scale insect, thrips situation of the harm is carried out determination of yield, final statistics is as shown in table 3 during sugarcane harvesting:
Table 3: Sugarcane Pests control and volume increase field test results statistical form
As known from Table 3: utilize granule described in the embodiment of the present invention, be applied to sugarcane field, with contrast medicament and compare, to sugarcane aphid, scale insect thrips all has good preventive effect, 3.0% Biphenthrin clothianidin granule (1:3) wherein, 1.0% clothianidin gamma cyhalothrin granule (1:1), 3.5% clothianidin chlopyrifos granule (1:6), 4.0% clothianidin phoxim granule (1:7) reaches more than 90% the preventive effect of sugarcane aphid, 3.0% Biphenthrin clothianidin granule (1:3) is 96.7% to 30 days preventive effects of thrips, 60 days 90.89% all higher than contrast.Regulate sugarcane production, strengthen resistance, there is certain production-increasing function.
Claims (3)
1. for preventing and treating an Environmental-protection particle agent for Sugarcane Pests, it is characterized in that the component that contains following percentage by weight:
Effective active composition 0.1-10%,
Auxiliary agent 5%-20%,
All the other are filler, and filler supplies 100%;
Described effective active composition is selected from one or both in clothianidin, phoxim, gamma cyhalothrin, Avermectin, chlopyrifos, Biphenthrin; Described filler is that aromatic plant extracts the residue after essential oil.
2. according to claim 1ly for preventing and treating the Environmental-protection particle agent of Sugarcane Pests, it is characterized in that, described aromatic plant is selected from one or more in Chinese cassia tree, camphor tree, eucalyptus, China fir, Chinese anise, clore basil, peppermint, lemongrass, Chinese ilex.
3. the Environmental-protection particle agent of the control Sugarcane Pests described in claim 1 or 2 is as the application of sugarcane insecticide.
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| CN106577727A (en) * | 2016-12-15 | 2017-04-26 | 安徽常泰化工有限公司 | Sugarcane herbicide |
| CN107027820A (en) * | 2017-05-10 | 2017-08-11 | 南宁为辰科技有限公司 | A kind of pesticide synergistic composition of leaf essential oil containing camphor tree and phoxim |
| CN107212026A (en) * | 2017-05-10 | 2017-09-29 | 南宁为辰科技有限公司 | A kind of pesticide synergistic composition of leaf essential oil containing camphor tree and cyhalothrin |
| CN107410377A (en) * | 2017-05-10 | 2017-12-01 | 南宁为辰科技有限公司 | A kind of pesticide synergistic composition of leaf essential oil containing camphor tree and Biphenthrin |
| CN109645001A (en) * | 2019-01-09 | 2019-04-19 | 长江大学 | A kind of effervescent table as agricultural chemical and preparation method thereof |
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| CN111129447A (en) * | 2019-10-31 | 2020-05-08 | 浙江锋锂新能源科技有限公司 | Ternary positive electrode material for long-cycle-life lithium storage battery and preparation method thereof |
| CN111009641B (en) * | 2019-10-31 | 2022-02-22 | 浙江锋锂新能源科技有限公司 | Long-cycle-life mixed solid-liquid electrolyte lithium storage battery and preparation method thereof |
| CN111134146A (en) * | 2019-12-26 | 2020-05-12 | 山西奇星农药有限公司 | Synergistic granule and preparation method and application thereof |
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