CN103627307B - A kind ofly can play coating of tangerine line/ripple effect and preparation method thereof - Google Patents
A kind ofly can play coating of tangerine line/ripple effect and preparation method thereof Download PDFInfo
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- CN103627307B CN103627307B CN201310592765.4A CN201310592765A CN103627307B CN 103627307 B CN103627307 B CN 103627307B CN 201310592765 A CN201310592765 A CN 201310592765A CN 103627307 B CN103627307 B CN 103627307B
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Abstract
The invention discloses a kind of coating that can play tangerine line/wrinkle varnish effect, comprise the component of following weight part: resin 45 ~ 65 parts, conven-tional adjuvants 0 ~ 2 part, filler 10 ~ 20 parts, ripple auxiliary agent 0.2 ~ 2 part, pigment 5 ~ 30 parts, solvent 8 ~ 15 parts and anti-settling agent 2 ~ 10 parts.The invention also discloses the preparation method of this coating.This formulation for coating material is simple, tangerine line/ripple is obvious after film forming, and coatingsurface stereoscopic sensation is strong.
Description
Technical field
The present invention relates to a kind of solvent based coating, particularly relate to a kind of coating that can play tangerine line/ripple effect, the invention still further relates to the preparation method of this coating.
Background technology
Paint is a kind of generally acknowledged high efficiency, excellent film performance, ecological environment-friendly type, economical coating products, and twentieth century starts to enter China and obtains develop rapidly the nineties.Wrinkle varnish is the one in paint, and its coatingsurface forms the effect as tangerine line/ripple, strong adhesion, paint film quick-drying, and ripple stereoscopic sensation is strong, and decorative effect is better than other finish paint, can cover up general coarse ground.Ripple paint is that current domestic each mechanical producer uses many a kind of novel high-grade industry art paints, and oil resistant water resistance is excellent, is applicable to the equipment applications such as bin, punch press, plastics subsidiary engine, hydropress, machining center.
Summary of the invention
First object of the present invention is to provide a kind of coating that can play tangerine line/ripple effect, and this formulation for coating material is simple, tangerine line/ripple is obvious after film forming, and coatingsurface stereoscopic sensation is strong.
Second object of the present invention is to provide the preparation method of above-mentioned coating.
First object of the present invention is achieved through the following technical solutions: a kind of coating that can play tangerine line/wrinkle varnish effect, comprises the component of following weight part:
Resin 45 ~ 65 parts
Conven-tional adjuvants 0 ~ 2 part
Filler 10 ~ 20 parts
Ripple auxiliary agent 0.2 ~ 2 part
Pigment 5 ~ 30 parts
Solvent 8 ~ 15 parts
Anti-settling agent 2 ~ 10 parts.
Described resin is soybean oil modified alkyd, and the hydroxyl ranges of resin is between 125 ~ 135, and acid number is less than 10mgKOH/g, and color and luster is within No. 2 looks, and viscosity is at 40,000/25 DEG C ~ 5.5 ten thousand/25 DEG C (rotational viscosimeter), and resin oil content is 36.
Described conven-tional adjuvants is the mixture of one or more of the organotin siccative, the silicone antifoam agent that are suitable for coating, dispersion agent etc.
Described pigment is titanium dioxide, carbon black, permanent bordeaux, phthalocyanine blue, the mixture of one or more of phthalein viridescent etc.
Described filler is one or more mixtures of talcum powder, coarse whiting, barium sulfate etc.
Described ripple auxiliary agent is a kind of organosilicon compound of macromolecular structure.Be specially the polydimethyl siloxane fluid polymkeric substance of high molecular, by the surface tension of organosilicon auxiliary agent, low and diffusion is fast high and spread slowly with the surface tension of resin, form the strength of two different directions, make coating produce the phenomenon of mutually piling up, form the same effect of tangerine line.
Described solvent is the mixture of one or more of dimethylbenzene, toluene, ethyl ester and butyl ester etc.
Described anti-settling agent is the mixture of one or more of silicon-dioxide, polyesteramide and organobentonite etc.
Second object of the present invention is realized by following technical approach: a kind of preparation method that can play the coating of tangerine line/ripple effect, comprises the following steps:
(1) take resin, pigment, filler, solvent, part anti-settling agent according to the above ratio, be placed in compounding jar, fully mix;
(2) mixed material enters in horizontal sand mill and grinds;
(3) residue anti-settling agent blending dispersion is added;
(4) ripple auxiliary agent blending dispersion is added;
(5) add conven-tional adjuvants blending dispersion, obtain the coating that can play tangerine line/ripple effect.
In described step (2), each component mixes and the time of grinding is 1 hour, is as the criterion, is ground to particle about 35 μm particularly to be ground to designated particles fineness.
The coating process of coating provided by the invention is: be coated on metal base by the method for air compressing spraying, can hot setting, also can seasoning, its hot setting temperature is 120 ~ 130 DEG C, set time is 25 ~ 45 minutes, can adopt baking box or pipelining, the seasoning time is more than 24 hours.
The present invention compared with prior art has the following advantages:
1. coating provided by the invention has formula simply, use resin and the auxiliary agent of high sag prevention, the strength that two different aspects produce, coating is made to produce tangerine line, and auxiliary agent produces the phenomenon of sagging when controlling piling, filler supplements the gap of piling up coating, and the tangerine line that formation is piled up can not subside, and forms stereoscopic sensation obviously coating.Coating after solidification has the excellent feature such as physical and mechanical properties, chemical resistance.
Use powder coating of the present invention, the coating after spraying solidification has following characteristics character:
2. coating provided by the invention is in spraying process, can improve the thickness of paint film fast, in the middle of same spraying coating process, the thickness of tangerine line paint/ripple coating at least than plane paint height 10um, so the efficiency in coating process can be significantly improved.
Embodiment
Below by a part of embodiment, the present invention will be described, be necessary to herein means out be following specific embodiment only for the invention will be further described, do not represent limiting the scope of the invention.Some nonessential amendments that other people make according to the present invention and adjustment still belong to protection scope of the present invention.
The hydroxyl ranges of soybean oil modified alkyd is between 125 ~ 135, and acid number is less than 10mgKOH/g, and color and luster is within No. 2 looks, and viscosity is at 40,000/25 DEG C ~ 5.5 ten thousand/25 DEG C (rotational viscosimeter), and resin oil content is 36.
Conven-tional adjuvants is the mixture of one or more of the organotin siccative, the silicone antifoam agent that are suitable for coating, dispersion agent etc.
Pigment is titanium dioxide, carbon black, permanent bordeaux, phthalocyanine blue, the mixture of one or more of phthalein viridescent etc.
Filler is one or more mixtures of talcum powder, coarse whiting, barium sulfate etc.
Ripple auxiliary agent is a kind of organosilicon compound of macromolecular structure.Be specially the polydimethyl siloxane fluid polymkeric substance of high molecular, by the surface tension of organosilicon auxiliary agent, low and diffusion is fast high and spread slowly with the surface tension of resin, form the strength of two different directions, make coating produce the phenomenon of mutually piling up, form the same effect of tangerine line.
Solvent is the mixture of one or more in diformazan benzene,toluene,xylene, ethyl ester and butyl ester etc.
Anti-settling agent is the mixture of one or more in silicon-dioxide, polyesteramide and organobentonite etc.
Select the component in following scope all can realize object of the present invention in the present invention.
embodiment 1
Ripple whitewash, its component and weight are: (unit: part)
The soybean oil modified alkyd (hydroxyl value is 126) 48 of acid number 8mgKOH/g
Titanium dioxide 30
Organotin siccative T-120.2
Coarse whiting 10
Toluene 8
Silicon-dioxide 2
Ripple auxiliary agent 0.8
Organobentonite 1
embodiment 2
Linen wrinkle varnish coating, its component and weight are: (unit: part)
The carboxyl Synolac (hydroxyl value is 130) 55 of acid number 8mgKOH/g
Titanium dioxide 20
Carbon black 2
Organotin siccative T-120.3
Coarse whiting 10
Dimethylbenzene 9
Silicon-dioxide 2
Ripple auxiliary agent 0.7
Organobentonite 1
embodiment 3
Blue wrinkle varnish coating, its component and weight are: (unit: part)
The carboxyl Synolac (hydroxyl value is 135) 53 of acid number 8mgKOH/g
Titanium dioxide 15
Phthalocyanine blue 3
Organotin siccative T-120.3
Coarse whiting 15
Dimethylbenzene 10
Silicon-dioxide 2
Ripple auxiliary agent 0.7
Organic Peng Run soil 1
embodiment 4
Red wrinkle varnish coating, its component and weight are: (unit: part)
The carboxyl Synolac (hydroxyl value is 125) 65 of acid number 5mgKOH/g
Titanium dioxide 25
Permanent bordeaux 5
Organotin siccative T-122
Barium sulfate 20
Ethyl ester 15
Silicon-dioxide 6
Ripple auxiliary agent 1.5
Organic Peng Run soil 4
embodiment 5
Green wrinkle varnish coating, its component and weight are: (unit: part)
The carboxyl Synolac (hydroxyl value is 130) 45 of acid number 9mgKOH/g
Titanium dioxide 5
Phthalein viridescent 3
Organotin siccative T-121
Barium sulfate 5
Butyl ester 15
Silicon-dioxide 3
Ripple auxiliary agent 0.5
Organic Peng Run soil 1
The preparation method of above embodiment
:
(1) resin, pigment, filler is taken in proportion, solvent and organobentonite, blending dispersion.
(2) grind 1 hour after blending dispersion, to fineness≤35 μm.
(3) silicon-dioxide blending dispersion is added.
(4) ripple auxiliary agent blending dispersion is added, adjustment tangerine line effect.
(5) add conven-tional adjuvants blending dispersion, obtain the coating that can play tangerine line/ripple effect.
Film performance after the product painting spontaneous curing obtained by above-described embodiment is as follows:
Claims (6)
1. can play a coating for tangerine line/wrinkle varnish effect, it is characterized in that, comprise the component of following weight part:
Resin 45 ~ 65 parts
Conven-tional adjuvants 0 ~ 2 part
Filler 10 ~ 20 parts
Ripple auxiliary agent 0.2 ~ 2 part
Pigment 5 ~ 30 parts
Solvent 8 ~ 15 parts
Anti-settling agent 2 ~ 10 parts,
Described resin is soybean oil modified alkyd, and the hydroxyl ranges of resin is between 125 ~ 135, and acid number is less than 10mgKOH/g, and color and luster is within No. 2 looks, and viscosity is at 40,000/25 DEG C ~ 5.5 ten thousand/25 DEG C, and resin oil content is 36; Described ripple auxiliary agent is the polydimethyl siloxane fluid polymkeric substance of high molecular; Described anti-settling agent is the mixture of one or more in silicon-dioxide, polyesteramide and organobentonite; Described conven-tional adjuvants is the mixture of one or more in organotin siccative, silicone antifoam agent and dispersion agent.
2. the coating that can play tangerine line/wrinkle varnish effect according to claim 1, is characterized in that, described pigment is the mixture of one or more in titanium dioxide, carbon black, permanent bordeaux, phthalocyanine blue and phthalein viridescent.
3. the coating that can play tangerine line/wrinkle varnish effect according to claim 1, is characterized in that, described filler is the mixture of one or more in talcum powder, coarse whiting and barium sulfate.
4. the coating that can play tangerine line/wrinkle varnish effect according to claim 1, is characterized in that, described solvent is the mixture of one or more in dimethylbenzene, toluene, ethyl ester and butyl ester.
5. the preparation method that can play the coating of tangerine line/ripple effect described in any one of claim 1 ~ 4, is characterized in that, comprise the following steps:
(1) take resin, pigment, filler, solvent, part anti-settling agent according to the above ratio, be placed in compounding jar, fully mix;
(2) mixed material enters in horizontal sand mill and grinds;
(3) residue anti-settling agent blending dispersion is added;
(4) ripple auxiliary agent blending dispersion is added;
(5) add conven-tional adjuvants blending dispersion, obtain the coating that can play tangerine line/ripple effect.
6. the preparation method that can play the coating of tangerine line/ripple effect according to claim 5, is characterized in that, in described step (2), each component mixes and the time of grinding is 1 hour, and grain diameter is 35 μm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310592765.4A CN103627307B (en) | 2013-11-22 | 2013-11-22 | A kind ofly can play coating of tangerine line/ripple effect and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310592765.4A CN103627307B (en) | 2013-11-22 | 2013-11-22 | A kind ofly can play coating of tangerine line/ripple effect and preparation method thereof |
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| Publication Number | Publication Date |
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| CN103627307A CN103627307A (en) | 2014-03-12 |
| CN103627307B true CN103627307B (en) | 2016-04-06 |
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| CN201310592765.4A Active CN103627307B (en) | 2013-11-22 | 2013-11-22 | A kind ofly can play coating of tangerine line/ripple effect and preparation method thereof |
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Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104194595A (en) * | 2014-08-29 | 2014-12-10 | 苏州圣谱拉新材料科技有限公司 | Acrylic polyurethane alkyd resin orange peel coating |
| CN104312226A (en) * | 2014-08-29 | 2015-01-28 | 苏州圣谱拉新材料科技有限公司 | Self-drying acrylic acid orange peel paint |
| CN104356788A (en) * | 2014-11-20 | 2015-02-18 | 深圳市广田环保涂料有限公司 | Orange-peel-effect fluorocarbon paint, and preparation method and application method thereof |
| CN105694695B (en) * | 2016-03-15 | 2017-12-12 | 广东绿色大地化工有限公司 | A kind of water soluble acrylic acid wrinkle varnish and preparation method thereof |
| CN105602431A (en) * | 2016-03-15 | 2016-05-25 | 广东绿色大地化工有限公司 | Water-based acrylic orange-figured paint and construction technique thereof |
| CN105885659A (en) * | 2016-05-23 | 2016-08-24 | 清远市贝客音涂料有限公司 | Bicomponent water-borne paint with orange peel texture/ripple effect and preparation method thereof |
| CN105969173B (en) * | 2016-07-17 | 2018-02-06 | 广东三和化工科技有限公司 | A kind of high temperature resistant low toxicity mallear stria spray painting and preparation method thereof |
| CN110760241B (en) * | 2019-11-11 | 2023-07-21 | 河北晨阳工贸集团有限公司 | Orange-peel anti-slip coating and preparation method thereof |
| CN111440476A (en) * | 2020-05-24 | 2020-07-24 | 华月圆 | Orange-peel auxiliary and orange-peel paint |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1033189A (en) * | 1987-11-19 | 1989-05-31 | 湖南造漆厂 | The manufacture method of auto-drying, matt and tangerine-grained paint |
| CN101070376A (en) * | 2007-05-14 | 2007-11-14 | 江苏长江涂料有限公司 | Alcohol-acid type wrinkled resin and preparing method |
| CN102140305A (en) * | 2011-03-07 | 2011-08-03 | 中国海洋石油总公司 | Polyurethane orange-peel coating |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2671530B2 (en) * | 1989-12-04 | 1997-10-29 | 三菱マテリアル株式会社 | Peeled paint can |
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2013
- 2013-11-22 CN CN201310592765.4A patent/CN103627307B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1033189A (en) * | 1987-11-19 | 1989-05-31 | 湖南造漆厂 | The manufacture method of auto-drying, matt and tangerine-grained paint |
| CN101070376A (en) * | 2007-05-14 | 2007-11-14 | 江苏长江涂料有限公司 | Alcohol-acid type wrinkled resin and preparing method |
| CN102140305A (en) * | 2011-03-07 | 2011-08-03 | 中国海洋石油总公司 | Polyurethane orange-peel coating |
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Effective date of registration: 20191112 Address after: 513059 No.8, Jinnan 3rd road, fine chemical industry zone, Qingyuan overseas Chinese Industrial Park, Donghua Town, Yingde City, Qingyuan City, Guangdong Province Patentee after: Qingyuan Beikeyin Coating Co., Ltd. Address before: 511363, Guangdong, Guangzhou, Luogang District Jiulong Town, Guangzhou highway, and paragraph Patentee before: GUANGZHOU BEIKEYIN PAINT CO., LTD. |
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