CN103563900A - Composite insecticidal composition containing methoxyfenozide and spinosad and application thereof - Google Patents
Composite insecticidal composition containing methoxyfenozide and spinosad and application thereof Download PDFInfo
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- CN103563900A CN103563900A CN201210276435.XA CN201210276435A CN103563900A CN 103563900 A CN103563900 A CN 103563900A CN 201210276435 A CN201210276435 A CN 201210276435A CN 103563900 A CN103563900 A CN 103563900A
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- methoxyfenozide
- pleocidin
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Abstract
The invention discloses a composite insecticidal composition containing methoxyfenozide and spinosad and an application thereof. The insecticidal composition takes methoxyfenozide and spinosad as main active ingredients, wherein the weight ratio of methoxyfenozide to spinosad is (0.1-80):(0.5-80). The insecticidal composition can generate relatively high synergistic effect, overcomes and delays the drug resistance of insects, and realizes high insecticidal speed and long duration while the application cost is reduced and the prevention effect is obviously better than that of using a single agent. The insecticidal composition disclosed by the invention can prevent homoptera, lepidoptera, hemiptera, coleoptera, hymenoptera, orthoptera, diptera, thysanoptera and mite insects on crops and particularly realizes a special effect on the insects such as homoptera rice planthopper and aphid, lepidoptera plutella xylostella, cotton bollworm and beet armyworm, thysanoptera thrips and mites and the like, and the effect is obviously better than that of using a single agent.
Description
Technical field
The invention belongs to pesticide field, be specifically related to a kind of compound pesticide compositions containing methoxyfenozide and pleocidin and uses thereof.
Background technology
Methoxyfenozide, chemical name: the N-tert-butyl group-N'-(3-methoxyl group-2-methyl benzoyl)-3,5-dimethyl benzene formylhydrazine.Structural formula is:
Sterling is white powder, fusing point 202-205 ℃.Water solubility < 1mg/L in the time of 20 ℃.Solvability in other solvents: dimethyl sulfoxide (DMSO) 11g/L, cyclohexanone 9.9g/L, acetone 9g/L.Stable storage at 25 ℃, 25 ℃, PH=5,7,9 times hydrolysis.
Methoxyfenozide preparation low toxicity, rat acute LD50 of passing through mouth is 5000mg/kg, acute through skin LD50>2000mg/kg.
Methoxyfenozide is a kind of of insect growth regulator, IGR, is mainly that the normal growth of interference insect is grown, though insect molting and dead, and can suppress to ingest.This product is strong to controlling object selectivity, is mainly used in the control of lepidoptera pest.
It is a kind of macrolides Nuisanceless high-efficient biological insecticides that extract in thorn sugared many born of the same parents bacterium (Saccharopolyspora spinosa) zymotic fluid that pleocidin has another name called multiple killing teichomycin (Spinosad).
Former medicine is to female rats acute oral LD50>5000 mg/kg, and male is 3738 mg/kg, mouse >5000 mg/kg, and rabbit is acute through skin LD50>5000 mg/kg.Non-stimulated to skin, eyes are had to minimal irritation, in 2 days, can disappear.Pleocidin is degradable in environment, without enrichment, free from environmental pollution.
Insect is had and tagged fast and stomach poison function, blade is had to stronger osmosis, can kill subepidermal insect, the longevity of residure is longer, and some insects are had to certain ovicidal action.Without systemic action.Can effectively preventing Lepidoptera, diptera and thrips insect, also can well prevent and treat that in coleoptera and orthoptera, some takes food the pest species of blade in a large number, poor to the control efficiency of sucking pest and mite class.Safer to predatory natural enemy insect, unique because of insecticidal action mechanism, not yet find at present to have mutual drug-fast report with other insecticides.Safe without poisoning to plant.Be suitable for using on vegetables, fruit tree, gardening, crops.Insecticidal effect be subject to rain affect less.
But diamond-back moth, cotton bollworm and thrips are under the condition of current long-term prescription, and resistance increases gradually, and agricultural chemicals single dose declines gradually to the effect of control of insect.Inventor finds after deliberation, and the synergistic complex of agricultural chemicals is expanding prevention spectrum and the effective measures that improve preventive effect, not yet finds up to now the Pesticidal combination of relevant methoxyfenozide and pleocidin.
Summary of the invention
The object of this invention is to provide a kind of compound pesticide compositions containing methoxyfenozide and pleocidin, this Pesticidal combination is the multifunctional insecticide composition of preventing and treating any one or a few insect in resistance Homoptera, Lepidoptera, Semiptera, coleoptera, Hymenoptera, orthoptera, diptera, thrips and mite class.
Another object of the present invention is to provide this compound pesticide compositions and prevents and treats the application on the insecticidal materials of one or more insects in resistance Homoptera, Lepidoptera, Semiptera, coleoptera, Hymenoptera, orthoptera, diptera, thrips and mite class in preparation.The particularly application on the insecticidal materials of any one or a few insect in preparation control rice fulgorid, aphid, diamond-back moth, cotton bollworm, beet armyworm, thrips and mite class.
The object of the invention is to be achieved through the following technical solutions:
Containing a compound pesticide compositions for methoxyfenozide and pleocidin, it is main active ingredient that this Pesticidal combination be take methoxyfenozide and pleocidin, and wherein, the weight ratio of methoxyfenozide and pleocidin is 0.1 ~ 80:0.5 ~ 80.Be preferably 0.5 ~ 50:2 ~ 50, more preferably 0.5 ~ 10:4 ~ 30.In this Pesticidal combination, effective ingredient is present in composition with synergy effective dose.
In compound pesticide compositions of the present invention, the two weight percentage in this compound pesticide compositions of methoxyfenozide and pleocidin is 3% ~ 80%.Be preferably 5% ~ 55%, most preferably 10% ~ 40%.
Compound pesticide compositions of the present invention be take methoxyfenozide and pleocidin and is mixed with any one formulation allowing on agricultural chemicals, the preferred missible oil of described formulation, suspending agent, wetting powder, aqueous emulsion, microemulsion or water dispersible granules as main active ingredient and insecticides adjuvant and excipient.
Auxiliary agent can adopt calcium dodecyl benzene sulfonate, agriculture breast 600#, the rare block compound of polyoxyethylene polyoxy third (as agriculture breast 33
#), polyoxyethylene nonylphenol ether etc., excipient comprises cyclohexanone, solvent naphtha, solvent naphtha, water, antifreezing agent (as propane diols), deionized water etc.Above auxiliary agent, excipient and other auxiliary material can alone or and use.
Compound pesticide compositions containing methoxyfenozide and pleocidin of the present invention is prevented and treated the application on the insecticidal materials of any one or a few insect in resistance Homoptera, Lepidoptera, Semiptera, coleoptera, Hymenoptera, orthoptera, diptera, thrips and mite class in preparation.Especially in preparation control rice fulgorid, aphid, diamond-back moth, cotton bollworm, beet armyworm, thrips and mite class, the effect in the insecticidal materials of any one or various pests is the most remarkable.And suppress insect the pesticide resistance of unitary agent (pleocidin or methoxyfenozide are arbitrary) is produced.
Beneficial effect of the present invention compared with prior art:
(1) compare with single dose, said composition antagonism lepidoptera pest, as diamond-back moth and thrips insect thrips etc. has obvious synergistic function, overcomes and has delayed pest resistance to insecticide, expanding prevention spectrum, and desinsection speed is fast, has obviously improved control efficiency; (2) reduce control recruitment, drug cost; (3) alternative high-toxic pesticide; (4) have concurrently quick-acting and long-acting; (5) compare with pleocidin single dose with methoxyfenozide, produce and use cost reduction; (6) suppress lepidoptera pest, Homoptera, thrips and mite pest the resistance of agricultural chemicals is strengthened, its successful is used higher than its single dose.
Embodiment
Below in conjunction with embodiment, the invention will be further described:
Embodiment 1:
Taking methoxyfenozide, pleocidin adopts conventional formulation method to be mixed with by different proportion the methoxyfenozide pleocidin missible oil that main active ingredient weight percentage is 30%.Concrete ratio is in Table 1,2.
Adopt leaf dipping method to carry out indoor synergy biologicall test, selecting resistance diamond-back moth is target pest, and every processing repeats 3 times, and every concentration is processed 60, calculates toxicity regression equation and the lethal concentration of 50 LC of each medicament antagonism diamond-back moth by probability value method
50, use LC
50value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient, the results are shown in Table 1:
The toxicity test of table 1 methoxyfenozide and pleocidin compound and single dose antagonism diamond-back moth
As shown in Table 1, methoxyfenozide and pleocidin compound, co-toxicity coefficient is all greater than 120, shows good synergistic function.
Adopt leaf dipping method to carry out indoor synergy biologicall test, selection resistant bollworm is target pest, and every processing repeats 3 times, calculates toxicity regression equation and the lethal concentration of 50 LC of each medicament antagonism cotton bollworm by probability value method
50, use LC
50value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient, the results are shown in Table 2:
The toxicity test of table 2 methoxyfenozide and pleocidin compound and single dose antagonism cotton bollworm
As shown in Table 2, methoxyfenozide and pleocidin compound, be all greater than 120 to the co-toxicity coefficient of cotton bollworm, shows good synergistic function.
Embodiment 2:
Take 5g methoxyfenozide, 50g pleocidin, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33
#2g, agriculture breast 600# 1g, solvent naphtha 13g, adds water to 100g.The method of above raw material being prepared routinely to aqueous emulsion drops into the mixing of mixing kettle high speed, forms the methoxyfenozide pleocidin aqueous emulsion that main active ingredient weight percentage is 55%.
Embodiment 3:
Take 2g methoxyfenozide, 18g pleocidin, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33
#2g, agriculture breast 600# 1g, cyclohexanone 10g, adds water to 100g.The method that above raw material is prepared to microemulsion routinely drops in mixing kettle mixes, and forms the methoxyfenozide pleocidin microemulsion that main active ingredient weight percentage is 20%.
Embodiment 3 is prevented and treated to the vegetables diamond-back moth test of pesticide effectiveness, according to the consumption medication in form 3, every mu of ground medication 20g, 30g, contrast medicament is 40% pleocidin EC(missible oil) 30g/ mu and 15% methoxyfenozide EC 30g/ mu, with clear water, do blank, the result of looking into 3 days, 7 days, 14 days and 28 days after medicine, result is in Table 3:
Table 3: the field test results of methoxyfenozide pleocidin compound to vegetables diamond-back moth
Field efficacy result shows, methoxyfenozide pleocidin composition antagonism diamond-back moth has good control efficiency, and control efficiency is all better than the effect that single dose kind is better than direct each single product of while.
Embodiment 3 is prevented and treated to cotton cotton bollworm field medicine effect test, according to the consumption medication in form 4, every mu of ground medication 20g, 30g, contrast medicament is 40% pleocidin EC(missible oil) 30g/ mu and 15% methoxyfenozide EC 30g/ mu, with clear water, do blank, after medicine, look into 3 days, the result of 7 days, 14 days and 28 days, result is in Table 4:
Table 4: the field test results of methoxyfenozide pleocidin compound to cotton bollworm
Field efficacy result shows, methoxyfenozide pleocidin composition antagonism cotton bollworm has good control efficiency, and control efficiency is all better than the effect that single dose kind is better than direct each single product of while.
Embodiment 4:
Take 1g methoxyfenozide, 5g pleocidin, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, solvent naphtha to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the methoxyfenozide pleocidin missible oil that main active ingredient weight percentage is 6%.
Embodiment 5:
Take 50g methoxyfenozide, 20g pleocidin, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the methoxyfenozide pleocidin missible oil that main active ingredient weight percentage is 70%.
Embodiment 6:
Take 2g methoxyfenozide, 40g pleocidin, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the methoxyfenozide pleocidin missible oil that main active ingredient weight percentage is 42%.
Embodiment 7:
Take 0.2g methoxyfenozide, 50g pleocidin, calcium dodecyl benzene sulfonate 9g, phenethyl phenol polyethenoxy ether 8g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the methoxyfenozide pleocidin missible oil that main active ingredient weight percentage is 50.2%.
Embodiment 8:
Take 5g methoxyfenozide, 0.5g pleocidin, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the methoxyfenozide pleocidin missible oil that main active ingredient weight percentage is 5.5%.
Embodiment 9:
Take 5g methoxyfenozide, 30g pleocidin, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the methoxyfenozide pleocidin missible oil that main active ingredient weight percentage is 35%.
Embodiment 10:
Take 20g methoxyfenozide, 5g pleocidin, calcium dodecyl benzene sulfonate 7g, phenethyl phenol polyethenoxy ether 9g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the methoxyfenozide pleocidin missible oil that main active ingredient weight percentage is 25%.
Embodiment 11:
Take 30g methoxyfenozide, 12g pleocidin, sodium lignin sulfonate 2g, alkyl phenol (or fatty alcohol) polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, water complements to 100g, forms the methoxyfenozide pleocidin suspension that main active ingredient weight percentage is 42% under the effect of sand mill.
Embodiment 12:
Take 2g methoxyfenozide, 5g pleocidin, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, diatomite 21g, forms by water dispersible granular agent method the methoxyfenozide pleocidin water dispersible granules that main active ingredient weight percentage is 14% by above raw material.
Embodiment 13:
Take 50g methoxyfenozide, 3g pleocidin, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the methoxyfenozide pleocidin missible oil that main active ingredient weight percentage is 53%.
Embodiment 14:
Take 2g methoxyfenozide, 18g pleocidin, sodium lignin sulfonate 10g, Negel 2g, with diatomite, add to 100g, above raw material is mixed in micronizer, form the methoxyfenozide pleocidin wetting powder that main active ingredient weight percentage is 20%.
Embodiment 15:
Take 7g methoxyfenozide, 70g pleocidin, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the methoxyfenozide pleocidin missible oil that main active ingredient weight percentage is 77%.
Embodiment 16:
Take 60g methoxyfenozide, 5g pleocidin, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, kaolin 13g, forms by water dispersible granular agent method the methoxyfenozide pleocidin water dispersible granules that main active ingredient weight percentage is 65% by above raw material.
Claims (10)
1. containing a compound pesticide compositions for methoxyfenozide and pleocidin, it is characterized in that it is main active ingredient that this Pesticidal combination be take methoxyfenozide and pleocidin, wherein, the weight ratio of methoxyfenozide and pleocidin is 0.1 ~ 80:0.5 ~ 80.
2. the compound pesticide compositions containing methoxyfenozide and pleocidin according to claim 1, is characterized in that described methoxyfenozide and the weight ratio of pleocidin are 0.5 ~ 50:2 ~ 50.
3. the compound pesticide compositions containing methoxyfenozide and pleocidin according to claim 2, is characterized in that described methoxyfenozide and the weight ratio of pleocidin are 0.5 ~ 10:4 ~ 30.
4. the compound pesticide compositions containing methoxyfenozide and pleocidin according to claim 1, is characterized in that the two weight percentage in this compound pesticide compositions of methoxyfenozide and pleocidin is 3% ~ 80%.
5. the compound pesticide compositions containing methoxyfenozide and pleocidin according to claim 4, is characterized in that the two weight percentage in this compound pesticide compositions of methoxyfenozide and pleocidin is 5% ~ 55%.
6. the compound pesticide compositions containing methoxyfenozide and pleocidin according to claim 5, is characterized in that the two weight percentage in this compound pesticide compositions of methoxyfenozide and pleocidin is 10% ~ 40%.
7. the compound pesticide compositions containing methoxyfenozide and pleocidin according to claim 1, is characterized in that this compound pesticide compositions take methoxyfenozide and pleocidin and be mixed with any one formulation allowing on agricultural chemicals as main active ingredient and insecticides adjuvant, excipients.
8. the compound pesticide compositions containing methoxyfenozide and pleocidin according to claim 7, is characterized in that described formulation is missible oil, suspending agent, aqueous emulsion, wetting powder, microemulsion or water dispersible granules.
9. the compound pesticide compositions containing methoxyfenozide and pleocidin claimed in claim 1 is prevented and treated the application on the insecticidal materials of one or more insects in resistance Homoptera, Lepidoptera, Semiptera, coleoptera, Hymenoptera, orthoptera, diptera, thrips and mite class in preparation.
10. the application on the insecticidal materials that is applied as this compound pesticide compositions any one or a few insect in preparation control rice fulgorid, aphid, diamond-back moth, cotton bollworm, beet armyworm, thrips and mite class according to claim 9.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105454231A (en) * | 2015-12-24 | 2016-04-06 | 河北博嘉农业有限公司 | Insecticide and sterilization composition containing methoxyfenozide |
| CN107318857A (en) * | 2016-04-28 | 2017-11-07 | 江苏龙灯化学有限公司 | A kind of Pesticidal combination |
Citations (2)
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| JP2008143809A (en) * | 2006-12-07 | 2008-06-26 | Mitsui Chemicals Inc | Method for prophylaxis of disease and insect pest damage to paddy rice |
| CN101878766A (en) * | 2010-07-02 | 2010-11-10 | 陕西上格之路生物科学有限公司 | Pesticidal composition containing methoxyfenozide and biogenic pesticide |
-
2012
- 2012-08-05 CN CN201210276435.XA patent/CN103563900A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008143809A (en) * | 2006-12-07 | 2008-06-26 | Mitsui Chemicals Inc | Method for prophylaxis of disease and insect pest damage to paddy rice |
| CN101878766A (en) * | 2010-07-02 | 2010-11-10 | 陕西上格之路生物科学有限公司 | Pesticidal composition containing methoxyfenozide and biogenic pesticide |
Non-Patent Citations (1)
| Title |
|---|
| 兰亦全 等: "杀虫剂对斜纹夜蛾和家蚕的毒力选择性研究", 《中国农学通报》, vol. 25, no. 22, 31 December 2009 (2009-12-31), pages 249 - 252 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105454231A (en) * | 2015-12-24 | 2016-04-06 | 河北博嘉农业有限公司 | Insecticide and sterilization composition containing methoxyfenozide |
| CN107318857A (en) * | 2016-04-28 | 2017-11-07 | 江苏龙灯化学有限公司 | A kind of Pesticidal combination |
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Application publication date: 20140212 |