CN103541234A - Thin-film printing adhesive and preparation method thereof - Google Patents
Thin-film printing adhesive and preparation method thereof Download PDFInfo
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- CN103541234A CN103541234A CN201310501904.8A CN201310501904A CN103541234A CN 103541234 A CN103541234 A CN 103541234A CN 201310501904 A CN201310501904 A CN 201310501904A CN 103541234 A CN103541234 A CN 103541234A
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Abstract
The invention provides a thin-film printing adhesive. The thin-film printing adhesive is prepared from the following raw materials in parts by weight: 35-40 parts of polyurethane acrylate, 2-3 parts of polyacrylamide, 12-14 parts of ethyl acrylate, 1-2 parts of sodium dodecylbenzene sulfonate, 7-9 parts of acrylonitrile, 2-3 parts of emulsifier (OP-10), 10-12 parts of isopropyl alcohol, 4-5 parts of naphthenic dicarboxylic acid monoester, 2-3 parts of styrene, 1-2 parts of 1,4-diamino-2-nitrobenzene, 7-9 parts of ethyl acetate, 2-3 parts of urea, 4-5 parts of additive, 1-2 parts of ammonium persulfate and 70-75 parts of water. The thin-film printing adhesive can form a thin film with strong adhesive force on a fabric, so that the printed fabric has relatively good rubbing fastness and soft hand feel; the formed thin film is colorless and transparent, does not affect the color and luster of pigment, and is uniform in thickness and smooth, so that the color of the pigment is expressed well; the film formation speed of the thin-film printing adhesive is appropriate, and the thin-film printing adhesive is not sticky; the film strength is high, and the formed film is soft and has high resilience.
Description
Technical field
The invention belongs to textile auxiliary's technical field, relate in particular to a kind of film printing adhesive and preparation method thereof.
Background technology
So-called COAT PRINTING is the effect by adhesive, by water insoluble, to fabric, do not have compatibility and reactive pigment to anchor on fabric, thereby reach painted object.According to update introduction, the PRINTED FABRIC of nearly half output is COAT PRINTING in the world at present.Pigment printing binding agent is the main component of textile printing pigment, and the quality of COAT PRINTING end product quality is directly subject to the impact of printing adhesive performance.
The quality of printing adhesive differs at present, the stamp defect rate causing because of adhesive quality problems, more than 3%, has caused huge economic loss, and the quality of printing adhesive directly has influence on quality, the fineness of stamp, the class of fabric, therefore, need to research and develop the more adhesive of high-quality.
Summary of the invention
The object of the present invention is to provide a kind of film printing adhesive and preparation method thereof, this adhesive has that film forming is thin, fastness good, dustproof feature.
Technical scheme of the present invention is as follows:
A printing adhesive, is characterized in that being made by the raw material of following weight portion: urethane acrylate 35-40, polyacrylamide 2-3, ethyl acrylate 12-14, neopelex 1-2, the fine 7-9 of propylene, emulsifying agent (OP-10) 2-3, isopropyl alcohol 10-12, Cycloalkane dicarboxylic acid monoesters 4-5, styrene 2-3,2-nitro P-pHENYLENE dI AMINE 1-2, ethyl acetate 7-9, urea 2-3, auxiliary agent 4-5, ammonium persulfate 1-2, water 70-75; Described auxiliary agent is made by the raw material of following weight portion: Silane coupling reagent KH-570 2-3, crosslinking agent TAC1-2, styrene 3-4, inositol hexaphosphate 9-12,2-amino-2-methyl-1-propyl alcohol 1-2, neopentyl glycol 3-4, antioxidant 1035 1-2, diethylene glycol (DEG) 7-9, ethanol 12-15; Preparation method mixes crosslinking agent TAC, styrene, 2-amino-2-methyl-1-propyl alcohol, neopentyl glycol, ethanol, be heated to 65-75 ℃, stirring reaction 45-60 minute, continues to be warming up to 85-95 ℃, add other residual components, stirring reaction 40-60 minute and get final product.
The preparation method of described film printing adhesive, it is characterized in that comprising the following steps: urethane acrylate, polyacrylamide, ethyl acrylate, propylene is fine, isopropyl alcohol, Cycloalkane dicarboxylic acid monoesters, styrene, 2-nitro P-pHENYLENE dI AMINE, ethyl acetate mix, under 1200-1500 rev/min of stirring, with the speed of 7-9 ℃/minute, be heated to 60-70 ℃; Add emulsifying agent (OP-10), neopelex, then be heated to 80-90 ℃ with the speed of 5-7 ℃/minute, add the mixed liquor of ammonium persulfate, water and other residual componentss, continue stirring reaction 2-2.5 hour, obtain.
Beneficial effect of the present invention
Adhesive of the present invention can form the film that adhesion strength is strong on fabric, and PRINTED FABRIC has better crock fastness, soft; Film forming water white transparency, does not affect pigment color and luster, and even thickness, smooth, makes pigment form and aspect be able to good behaviour; Conjunctiva speed is suitable, is not clamminess; Film-strength is high, the soft high resilience of film forming.
The specific embodiment
A printing adhesive, by following weight portion (kilogram) raw material make: urethane acrylate 37, polyacrylamide 2.5, ethyl acrylate 13, neopelex 1.5, propylene are fine 8, emulsifying agent (OP-10) 2.5, isopropyl alcohol 11, Cycloalkane dicarboxylic acid monoesters 4.5, styrene 2.5,2-nitro P-pHENYLENE dI AMINE 1.5, ethyl acetate 8, urea 2.5, auxiliary agent 4.5, ammonium persulfate 1.5, water 73; Described auxiliary agent by following weight portion (kilogram) raw material make: Silane coupling reagent KH-570 3, crosslinking agent TAC1, styrene 3, inositol hexaphosphate 9,2-amino-2-methyl-1-propyl alcohol 2, neopentyl glycol 4, antioxidant 1,035 1, diethylene glycol (DEG) 7, ethanol 12; Preparation method mixes crosslinking agent TAC, styrene, 2-amino-2-methyl-1-propyl alcohol, neopentyl glycol, ethanol, be heated to 65-75 ℃, stirring reaction 45-60 minute, continues to be warming up to 85-95 ℃, add other residual components, stirring reaction 40-60 minute and get final product.
The preparation method of described film printing adhesive, comprise the following steps: urethane acrylate, polyacrylamide, ethyl acrylate, propylene is fine, isopropyl alcohol, Cycloalkane dicarboxylic acid monoesters, styrene, 2-nitro P-pHENYLENE dI AMINE, ethyl acetate mix, under 1300 revs/min of stirrings, with the speed of 8 ℃/minute, be heated to 65 ℃; Add emulsifying agent (OP-10), neopelex, then be heated to 85 ℃ with the speed of 6 ℃/minute, add the mixed liquor of ammonium persulfate, water and other residual componentss, continue stirring reaction 2.3 hours, obtain.
This film printing adhesive, for stamp, is pressed GB standard detection, dry fastness 3-4 level, and fastness to wet rubbing is at 3 grades, and brushing fastness 3-4 level, glues COLOR FASTNESS 3-4 level, the fastness of fading after soaping 3-4 level.
Claims (2)
1. a film printing adhesive, is characterized in that being made by the raw material of following weight portion: urethane acrylate 35-40, polyacrylamide 2-3, ethyl acrylate 12-14, neopelex 1-2, the fine 7-9 of propylene, emulsifying agent (OP-10) 2-3, isopropyl alcohol 10-12, Cycloalkane dicarboxylic acid monoesters 4-5, styrene 2-3,2-nitro P-pHENYLENE dI AMINE 1-2, ethyl acetate 7-9, urea 2-3, auxiliary agent 4-5, ammonium persulfate 1-2, water 70-75; Described auxiliary agent is made by the raw material of following weight portion: Silane coupling reagent KH-570 2-3, crosslinking agent TAC1-2, styrene 3-4, inositol hexaphosphate 9-12,2-amino-2-methyl-1-propyl alcohol 1-2, neopentyl glycol 3-4, antioxidant 1035 1-2, diethylene glycol (DEG) 7-9, ethanol 12-15; Preparation method mixes crosslinking agent TAC, styrene, 2-amino-2-methyl-1-propyl alcohol, neopentyl glycol, ethanol, be heated to 65-75 ℃, stirring reaction 45-60 minute, continues to be warming up to 85-95 ℃, add other residual components, stirring reaction 40-60 minute and get final product.
2. the preparation method of film printing adhesive according to claim 1, it is characterized in that comprising the following steps: urethane acrylate, polyacrylamide, ethyl acrylate, propylene is fine, isopropyl alcohol, Cycloalkane dicarboxylic acid monoesters, styrene, 2-nitro P-pHENYLENE dI AMINE, ethyl acetate mix, under 1200-1500 rev/min of stirring, with the speed of 7-9 ℃/minute, be heated to 60-70 ℃; Add emulsifying agent (OP-10), neopelex, then be heated to 80-90 ℃ with the speed of 5-7 ℃/minute, add the mixed liquor of ammonium persulfate, water and other residual componentss, continue stirring reaction 2-2.5 hour, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310501904.8A CN103541234A (en) | 2013-10-23 | 2013-10-23 | Thin-film printing adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310501904.8A CN103541234A (en) | 2013-10-23 | 2013-10-23 | Thin-film printing adhesive and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
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| CN103541234A true CN103541234A (en) | 2014-01-29 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201310501904.8A Pending CN103541234A (en) | 2013-10-23 | 2013-10-23 | Thin-film printing adhesive and preparation method thereof |
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Citations (7)
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| US20060252329A1 (en) * | 2005-05-04 | 2006-11-09 | Shawmut Corporation | Halogen and plasticizer free permeable laminate |
| CN101467075A (en) * | 2006-06-13 | 2009-06-24 | 3M创新有限公司 | Fluoro(meth)acrylate polymer composition suitable for low index layer of antireflective film |
| CN102182080A (en) * | 2011-03-23 | 2011-09-14 | 成都德美精英化工有限公司 | Pigment printing binding agent and synthesizing method thereof |
| CN102619104A (en) * | 2012-04-07 | 2012-08-01 | 辽宁恒星精细化工有限公司 | Active coating imitating printing adhesive and preparation method thereof |
| CN102633954A (en) * | 2012-05-09 | 2012-08-15 | 南通纺织职业技术学院 | Environment-friendly emulsion modified acrylate pigment dyeing adhesive and manufacturing method thereof |
| CN102864658A (en) * | 2012-09-19 | 2013-01-09 | 吴江市意胜纺织有限公司 | Pigment printing binder |
| CN103214992A (en) * | 2013-05-04 | 2013-07-24 | 辽宁恒星精细化工有限公司 | Binding agent for conductive carbon black slurry and preparation method thereof |
-
2013
- 2013-10-23 CN CN201310501904.8A patent/CN103541234A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060252329A1 (en) * | 2005-05-04 | 2006-11-09 | Shawmut Corporation | Halogen and plasticizer free permeable laminate |
| CN101467075A (en) * | 2006-06-13 | 2009-06-24 | 3M创新有限公司 | Fluoro(meth)acrylate polymer composition suitable for low index layer of antireflective film |
| CN102182080A (en) * | 2011-03-23 | 2011-09-14 | 成都德美精英化工有限公司 | Pigment printing binding agent and synthesizing method thereof |
| CN102619104A (en) * | 2012-04-07 | 2012-08-01 | 辽宁恒星精细化工有限公司 | Active coating imitating printing adhesive and preparation method thereof |
| CN102633954A (en) * | 2012-05-09 | 2012-08-15 | 南通纺织职业技术学院 | Environment-friendly emulsion modified acrylate pigment dyeing adhesive and manufacturing method thereof |
| CN102864658A (en) * | 2012-09-19 | 2013-01-09 | 吴江市意胜纺织有限公司 | Pigment printing binder |
| CN103214992A (en) * | 2013-05-04 | 2013-07-24 | 辽宁恒星精细化工有限公司 | Binding agent for conductive carbon black slurry and preparation method thereof |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140129 |
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| RJ01 | Rejection of invention patent application after publication |