CN103526911B - A kind of preparation method of light-weight high-strength wood-plastic floor - Google Patents
A kind of preparation method of light-weight high-strength wood-plastic floor Download PDFInfo
- Publication number
- CN103526911B CN103526911B CN201310468657.6A CN201310468657A CN103526911B CN 103526911 B CN103526911 B CN 103526911B CN 201310468657 A CN201310468657 A CN 201310468657A CN 103526911 B CN103526911 B CN 103526911B
- Authority
- CN
- China
- Prior art keywords
- wood
- light
- plastic floor
- pvc
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Floor Finish (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
Abstract
The invention discloses a kind of preparation method of light-weight high-strength wood-plastic floor, comprise the following steps: 1) cover adhering process by hydrostatic(al) process and make decorative layer on PVC base layer surface; 2) with binding agent at decor surface bonding or spraying abrasion-proof layer, get product; Wherein: cover in hydrostatic(al) process the surface-active solvent used in adhering process and be made up of the raw material of following weight proportioning: cyclohexanone 4 ~ 10, dimethylbenzene 20 ~ 45, butyl acetate 0.5 ~ 3, methyl acetate 2 ~ 8, hexone 2 ~ 7, DEDB 1 ~ 3, butanone 2 ~ 8, isobutanol 1 ~ 6; Described binding agent is mixed by the component of following weight proportioning: melamine bonding adhesive 0.5 ~ 1.2, urea-formaldehyde resin adhesive 1 ~ 3, PVC bonding adhesive 0.2 ~ 1.5.Wood-plastic floor clear patterns obtained by this method, effect is true to nature and adhesive power good, and has good abrasion resistance, fire line, corrosion resistance and insulating properties, and light specific gravity.
Description
Technical field
The present invention relates to technical field of construction and decoration materials, be specifically related to a kind of preparation method of light-weight high-strength wood-plastic floor.
Background technology
Floor majority is in the market composite floor board, wooden floor, multi-layer solid wood floor, consolidated floor, Wood-plastic floor etc.
Wherein the water resistance of composite floor board, wooden floor and multi-layer solid wood floor is all poor, and after chance water, easily distortion, distortion, even ftractures, especially wooden floor and multi-layer solid wood floor, and all do not prevent fires.
Laminated flooring is that mat formation at the artificial substrate surface such as shaving board, high density fiberboard, the back side adds balance layer, and front adds wearing layer, through the floor of high temperature hot pressing with one or more layers dedicated paper through impregnated with thermoset amino resins.Its structure is divided into four layers, i.e. wearing layer, decorative layer, substrate layer, balance layer.
Last a kind of Wood-plastic floor is because of waterproof, indeformable and durable in use and be subject to liking of consumers in general.Weak point be exactly than great, materials are many, cost is higher, though fire-retardant, not resistance to cigarette end scalds, and anti-wear performance is not ideal enough.In addition, the lines technology on existing Wood-plastic floor surface is the pellet adopting different color, and the grain pattern obtained according to the principle of stream speed difference, therefore lines is more single, true to nature not, and the abrasion resistance of floor surface is also not ideal enough.The applicant is in the patent of invention of CN102827387A at the publication number applied for before, disclose a kind of for the active solvent in wood plastic product surface pattern formation process, it is made up of the raw material of following weight proportioning: carrene 4 ~ 10, butyl acetate 10 ~ 15, methyl acetate 12 ~ 20, hexone 3 ~ 8, isobutanol 2 ~ 5, dioctyl ester 2 ~ 5, cyclohexanone 5 ~ 10, dibutyl ethylene glycol ether 2 ~ 5.Although adopt this active solvent in conjunction with hydrostatic(al) process disclosed in this application cover adhering process make lines method can wood plastic product surface obtain clear, effect is true to nature and the grain pattern that adhesive power is good, but when using it for the making of grain pattern in the PVC wood plastic floor with wearing layer, can not match and use by the alchlor abrasion-proof paper used with wearing layer, adhesive power is not ideal enough.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of preparation method of light-weight high-strength wood-plastic floor.Wood-plastic floor clear patterns obtained by this method, effect is true to nature and adhesive power good, and has good abrasion resistance, fire line, corrosion resistance and insulating properties, and light specific gravity.
The preparation method of light-weight high-strength wood-plastic floor of the present invention, comprises the following steps:
1) cover adhering process by hydrostatic(al) process and make decorative layer on PVC base layer surface;
2) with binding agent at decor surface bonding or spraying abrasion-proof layer, get product;
Unlike the prior art:
Step 1) in, cover in hydrostatic(al) process the surface-active solvent used in adhering process and be made up of the raw material of following weight proportioning:
Cyclohexanone 4 ~ 10, dimethylbenzene 20 ~ 45, butyl acetate 0.5 ~ 3, methyl acetate 2 ~ 8, hexone 2 ~ 7, DEDB 1 ~ 3, butanone 2 ~ 8, isobutanol 1 ~ 6;
Step 2) in, described binding agent is mixed by the component of following weight proportioning:
Melamine bonding adhesive 0.5 ~ 1.2, urea-formaldehyde resin adhesive 1 ~ 3, PVC bonding adhesive 0.2 ~ 1.5.
In technique scheme, in described surface-active solvent, the preferred weight proportion of each raw material is:
Cyclohexanone 5 ~ 8, dimethylbenzene 25 ~ 40, butyl acetate 1 ~ 3, methyl acetate 3 ~ 6, hexone 3 ~ 6, DEDB 1 ~ 3, butanone 3 ~ 6, isobutanol 2 ~ 5.
In technique scheme, in described binding agent, the weight proportion of each component is preferably:
Melamine bonding adhesive 0.8 ~ 1, urea-formaldehyde resin adhesive 1.5 ~ 2.5, PVC bonding adhesive 0.5 ~ 1.2.
In the application, the preparation method of described active solvent is: take each raw material by formula, mix.Specifically in use, the active solvent of the printed film sprinkling 110 ~ 130g of every square metre is normally pressed.The preparation method of described binding agent is: take the melamine glue adhesive agent of formula ratio, urea-formaldehyde resin adhesive and PVC bonding adhesive, mix, to obtain final product.During use, binding agent is coated on decor surface, coating thickness is generally 0.1 ~ 0.4mm.
In technique scheme, described wearing layer is alundum (Al2O3) abrasion-proof paper, or is formed by spraying liquid alchlor.When wearing layer selects alundum (Al2O3) abrasion-proof paper to make, the technique of employing is directly bonding at decor surface, the quantitative 45 ~ 46g/m of described alundum (Al2O3) abrasion-proof paper
2; When wearing layer selects liquid alundum (Al2O3) to spray making, the quantity for spray of liquid alchlor is generally 120 ~ 260g/m
2.
In technique scheme, described PVC base layer can directly commercially, also can make by existing conventional formulation and technique.In this application, preferably with PVC low foaming wood plastic composite materials through granulation, extrude, mold pressing, shaping process obtain.
Described PVC low foaming wood plastic composite materials generally includes the component of following weight proportion:
Wood powder or fiber powder 20 ~ 60, waste polyvinyl chloride (PVC) 40 ~ 100, calcium-zinc composite stabilizing agent 2 ~ 4.5, Tissuemat E 0.2 ~ 1.0, stearic acid 0.2 ~ 0.8, Celogen Az 0.2 ~ 1.0, NaOH 0.3 ~ 0.8, precipitated calcium carbonate 5 ~ 20, DEDB 1 ~ 3, foaming control agent (Zibo Huaxing Additives Co., Ltd.'s production) 2 ~ 8, ACR-401 (Zibo Huaxing Additives Co., Ltd.'s production) 2 ~ 8, blowing agent (production of Kunshan Mai Jisen composite material Co., Ltd) 0.2 ~ 0.8, oxine ketone mould inhibitor (production of Hubei giant dragon hall biotechnology Development Co., Ltd) 0.1 ~ 0.6, titanate coupling agent (production of dawn chemical plant, Nanjing) 0.5 ~ 3, chloromethoxy fatty acid ester (production of Suzhou Yi Gete Chemical Co., Ltd.) 0.5 ~ 4, antioxidant 0.1 ~ 0.5 (production of Anhua, Beijing three chemical products Co., Ltd).According to the demand of customer to color, can increase appropriate pigment in above-mentioned formula, can be specifically 0.01 ~ 0.5 weight portion.
Wood powder described in above-mentioned formula or fiber powder can be fine graineds wood chip, bamboo bits, shell, waste of flax, peanut shell, chestnut shell or bagasse etc. being carried out pulverizing, obtain after abrasive dust; Can also be the combination two or more arbitrarily in above-mentioned selection, the proportioning now between them can be any proportioning.Their granularity controls usually at 80 ~ 200 orders.Described foaming control agent selects foaming control agent ZB-530 usually.Described ACR-401 uses as plastic processing additives, and it is acrylic ester high molecular type copolymer, specifically can adopt Zibo Huaxing Additives Co., Ltd., Zibo Hai Hua Chemical Co., Ltd., Shangyu city near a river the company such as Chemical Co., Ltd. produce.The yellow blowing agent MSV558 of PVC selected usually by described blowing agent; Described titanate coupling agent selects titanate coupling agent NDZ-102 usually; Antioxidant KY-1010 selected usually by described antioxidant.
Described PVC low foaming wood plastic composite materials carried out granulation, extrude, mold pressing, the operation such as sizing be identical with existing common process.
Compared with prior art, the feature of the method for the invention is:
1, adopt a kind of new surface-active solvent, in conjunction with described in hydrostatic(al) process cover adhering process make Wood-plastic floor PVC base layer surface obtain clear, effect is true to nature and the grain pattern that adhesive power is good;
Between the wearing layer on the Wood-plastic floor surface 2, adopting the binding agent of special composition to make to obtain and PVC base layer, there is very strong bonding force, make grain pattern have stronger adhesive power simultaneously and decorative layer printed film can not be destroyed again, in addition, adding of wearing layer has good protective effect to grain pattern, thus make the floor surface obtained have true to nature ornamental of lines to have again very wear-resisting advantage, flooring can be widely used in and mat formation;
3, whole method is simple to operation, and cost of production is low, is easy to industrialization;
4, Wood-plastic floor obtained by this method is except the performance (waterproof, fire prevention etc.) with conventional Wood-plastic floor, also has density little, lightweight, the feature of easy to clean, and gained floor has well corrosion-resistant and insulating properties.
Detailed description of the invention
With detailed description of the invention, the invention will be further described below, but the present invention is not limited to these embodiments.
The making of embodiment 1:PVC substrate layer
1) each component is taken by following weight proportion, for subsequent use:
Wood powder 50 weight portion, old polyvinyl chloride 100 weight portion, calcium-zinc composite stabilizing agent 3.5 weight portion, Tissuemat E 0.4 weight portion, stearic acid 0.3 weight portion, Celogen Az 0.35 weight portion, NaOH 0.5 weight portion, precipitated calcium carbonate 15 weight portion, DEDB 2 weight portion, foaming control agent ZB-530 (Zibo Huaxing Additives Co., Ltd.'s production) 4 weight portions, ACR-401 (Zibo Huaxing Additives Co., Ltd.'s production) 4 weight portions, yellow blowing agent MSV558 (production of Kunshan Mai Jisen composite material Co., Ltd) 0.5 weight portion of PVC, copper 8-quinolinolate mould inhibitor (production of Hubei giant dragon hall biotechnology Development Co., Ltd) 0.2 weight portion, titanate coupling agent NDZ-102 (production of dawn chemical plant, Nanjing) 2 weight portions, chloromethoxy fatty acid ester (production of Suzhou Yi Gete Chemical Co., Ltd.) 2 weight portions, antioxidant KY-1010 (production of Anhua, Beijing three chemical products Co., Ltd) 0.1 weight portion, appropriate (yellow 0.016 weight portion of Japanese gorgeous beauty of toner, yellow 0.170 weight portion of light lattice, yellow 0.020 weight portion of dark lattice, yellow 0.090 weight portion of tangerine lattice, red 0.021 weight portion of Germany's sun-proof, carbon black 0.016 weight portion),
2) the above-mentioned each component taken is placed in high low speed batch mixer to carry out mixing (incorporation time is 8 ~ 10min about), treats that material temperature is down to and get final product discharge at 40 ~ 45 DEG C;
3) by step 2) material of discharging joins comminutor and carries out granulation, the temperature of comminutor controls (to require the pellet created at 130 ~ 140 DEG C, plasticizing evenly, can not have the core of thickener, particle that the phenomenon of fretting map can not be had to occur), obtain PVC low foaming wood-plastic pellet;
4) by step 3) the PVC low foaming wood-plastic pellet of gained is placed in the hopper of extruding production line, carry out extruding, mold pressing, cooling and shaping, the operation such as cutting, this stage process expressing technique method of operating is routinely carried out, wherein extrusion temperature preferably controls, at 140 ~ 175 DEG C, to obtain PVC base layer.This PVC base layer smooth surface, smooth, inner in microcellular structure.
Embodiment 2: make light-weight high-strength wood-plastic floor
1) PVC base layer is made:
With embodiment 1;
2) cover adhering process by hydrostatic(al) process and make decorative layer on PVC base layer surface:
A) purchase water-fast printed film (selecting the printed film of concrete grain pattern as required), be cut into some pieces that are a bit larger tham PVC base surface layer, for subsequent use;
B) cyclohexanone 8 weight portion, dimethylbenzene 40 weight portion, butyl acetate 2 weight portion, methyl acetate 6 weight portion, hexone 5 weight portion, DEDB 1.6 weight portion, butanone 6 weight portion and isobutanol 5 weight portion is taken, mix, obtain surface-active solvent;
C) by cut the water-fast printed film of having carried be laid in fill with water temperature be the water layer of the warm water tank of 25 ~ 30 DEG C on the surface, to face up dapple one during tiling, the decorative pattern face of water-fast printed film evenly sprays (spraying with kettle formula spray gun) surface-active solvent by the amount of every square metre of printed film being sprayed 130g surface-active solvent, after water-fast printed film is softened by active solvent (3min), just PVC base layer is laminated in water-fast printed film gently, and press, utilize the effect of hydraulic pressure, water-fast printed film is wrapped up in be affixed on PVC base layer to be pressed into simultaneously in warm water tank, wrap up in completely until the pattern in water-fast printed film and adhere to PVC base layer on the surface after (this process 3 ~ 5min), pulled out, be placed in clear water reserviors and clean and remove unnecessary water-fast printed film, take out, 10h is dried under 40 DEG C of conditions, namely the PVC base with grain pattern is obtained, now namely complete the making of decorative layer, grain pattern on PVC base layer is decorative layer,
3) use binding agent at the bonding wearing layer of decor surface:
A) melamine glue (production of Linyi Jin Nuo chemical industry Co., Ltd) 1 weight portion, urea-formaldehyde resin adhesive (production of Guangzhou Zhi Hong Chemical Industry Science Co., Ltd) 2 weight portions and PVC bonding adhesive (Dongguan Onechance New Material Technology Co., Ltd.'s production) 1 weight portion is taken, mix, obtain binding agent;
B) in step 2) what obtain is the binding agent of 0.1 ~ 0.4mm with roller coating in the PVC base of grain pattern (on decor surface roller coating) a layer thickness, will be then quantitatively 45 ~ 46g/m
2alundum (Al2O3) abrasion-proof paper be placed in decorative layer and coated on the face of binding agent, be then placed on hot press, temperature be 140 ~ 170 DEG C, pressure be the condition of 1.5 ~ 3.5MPa under compacting 10 ~ 20s, take out, obtain the floor blank that hot pressing is good;
4) floor blank good for hot pressing is divided into dimension, then carries out conventional post processing (as longitudinal mortise groove milling and horizontal mortise groove milling, chamfering are rolled and painted light etc.), obtain light-weight high-strength wood-plastic floor of the present invention.
Embodiment 3: make light-weight high-strength wood-plastic floor
1) PVC base layer is made:
With embodiment 1;
2) cover adhering process by hydrostatic(al) process and make decorative layer on PVC base layer surface:
Repeat embodiment 2, unlike, surface-active solvent is mixed by the raw material of following weight parts and obtains:
Cyclohexanone 4 weight portion, dimethylbenzene 35 weight portion, butyl acetate 3 weight portion, methyl acetate 3 weight portion, hexone 2 weight portion, DEDB 3 weight portion, butanone 8 weight portion and isobutanol 4 weight portion;
3) use binding agent at the bonding wearing layer of decor surface:
Repeat embodiment 2, unlike, binding agent is mixed by melamine glue 0.5 weight portion, urea-formaldehyde resin adhesive 3 weight portion and PVC bonding adhesive 1.2 weight portion and is obtained;
4) floor blank good for hot pressing is divided into dimension, then carries out conventional post processing, obtain light-weight high-strength wood-plastic floor of the present invention.
Embodiment 4: make light-weight high-strength wood-plastic floor
1) PVC base layer is made:
With embodiment 1;
2) cover adhering process by hydrostatic(al) process and make decorative layer on PVC base layer surface:
Repeat embodiment 2, unlike, surface-active solvent is mixed by the raw material of following weight parts and obtains:
Cyclohexanone 10 weight portion, dimethylbenzene 30 weight portion, butyl acetate 1 weight portion, methyl acetate 8 weight portion, hexone 6 weight portion, DEDB 2 weight portion, butanone 2 weight portion and isobutanol 1 weight portion;
3) use binding agent at the bonding wearing layer of decor surface:
Repeat embodiment 2, unlike, binding agent is mixed by melamine glue 1.2 weight portion, urea-formaldehyde resin adhesive 1 weight portion and PVC bonding adhesive 0.5 weight portion and is obtained;
4) floor blank good for hot pressing is divided into dimension, then carries out conventional post processing, obtain light-weight high-strength wood-plastic floor of the present invention.
Embodiment 5: make light-weight high-strength wood-plastic floor
1) PVC base layer is made:
Using the PVC substrate (purchased from Li Nai building materials Co., Ltd of Shenzhen) directly bought from the market PVC base layer as light-weight high-strength wood-plastic floor described in the application;
2) cover adhering process by hydrostatic(al) process and make decorative layer on PVC base layer surface:
Repeat embodiment 2, unlike, surface-active solvent is mixed by the raw material of following weight parts and obtains:
Cyclohexanone 5 weight portion, dimethylbenzene 45 weight portion, butyl acetate 2 weight portion, methyl acetate 5 weight portion, hexone 3 weight portion, DEDB 2.5 weight portion, butanone 3 weight portion and isobutanol 2 weight portion;
3) use binding agent at the bonding wearing layer of decor surface:
Repeat embodiment 2, unlike, binding agent is mixed by melamine glue 1 weight portion, urea-formaldehyde resin adhesive 1.5 weight portion and PVC bonding adhesive 0.8 weight portion and is obtained;
4) floor blank good for hot pressing is divided into dimension, then carries out conventional post processing, obtain light-weight high-strength wood-plastic floor of the present invention.
Test the physicochemical property of the light-weight high-strength wood-plastic floor that embodiment 2 ~ 5 obtains, result is (proportion of the density of existing conventional PVC material is between 1.4 ~ 1.6) as described in Table 1:
Table 1:
Claims (6)
1. a preparation method for light-weight high-strength wood-plastic floor, comprises the following steps:
1) cover adhering process by hydrostatic(al) process and make decorative layer on PVC base layer surface;
2) with binding agent at decor surface bonding or spraying abrasion-proof layer, get product;
It is characterized in that:
Step 1) in, cover in hydrostatic(al) process the surface-active solvent used in adhering process and be made up of the raw material of following weight proportioning:
Cyclohexanone 4 ~ 10, dimethylbenzene 20 ~ 45, butyl acetate 0.5 ~ 3, methyl acetate 2 ~ 8, hexone 2 ~ 7, DEDB 1 ~ 3, butanone 2 ~ 8, isobutanol 1 ~ 6;
Step 2) in, described binding agent is mixed by the component of following weight proportioning:
Melamine bonding adhesive 0.5 ~ 1.2, urea-formaldehyde resin adhesive 1 ~ 3, PVC bonding adhesive 0.2 ~ 1.5.
2. the preparation method of light-weight high-strength wood-plastic floor according to claim 1, is characterized in that: in described surface-active solvent, the weight proportion of each raw material is:
Cyclohexanone 5 ~ 8, dimethylbenzene 25 ~ 40, butyl acetate 1 ~ 3, methyl acetate 3 ~ 6, hexone 3 ~ 6, DEDB 1 ~ 3, butanone 3 ~ 6, isobutanol 2 ~ 5.
3. the preparation method of light-weight high-strength wood-plastic floor according to claim 1, is characterized in that: in described binding agent, the weight proportion of each component is:
Melamine bonding adhesive 0.8 ~ 1, urea-formaldehyde resin adhesive 1.5 ~ 2.5, PVC bonding adhesive 0.5 ~ 1.2.
4. the preparation method of the light-weight high-strength wood-plastic floor according to any one of claims 1 to 3, is characterized in that: described wearing layer is alundum (Al2O3) abrasion-proof paper, or is formed by spraying liquid alchlor.
5. the preparation method of the light-weight high-strength wood-plastic floor according to any one of claims 1 to 3, is characterized in that: described PVC base layer with PVC low foaming wood plastic composite materials through granulation, extrude, mold pressing, shaping process obtain.
6. the preparation method of light-weight high-strength wood-plastic floor according to claim 5, is characterized in that: described PVC low foaming wood plastic composite materials comprises the component of following weight proportion:
Wood powder or fiber powder 20 ~ 60, polyvinyl chloride 40 ~ 100, calcium-zinc composite stabilizing agent 2 ~ 4.5, Tissuemat E 0.2 ~ 1.0, stearic acid 0.2 ~ 0.8, Celogen Az 0.2 ~ 1.0, NaOH 0.3 ~ 0.8, precipitated calcium carbonate 5 ~ 20, DEDB 1 ~ 3, ZB-530 foaming control agent 2 ~ 8, ACR-401 is 2 ~ 8, blowing agent 0.2 ~ 0.8, mould inhibitor 0.1 ~ 0.6, titanate coupling agent 0.5 ~ 3, chloromethoxy fatty acid ester 0.5 ~ 4, antioxidant 0.1 ~ 0.5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310468657.6A CN103526911B (en) | 2013-10-09 | 2013-10-09 | A kind of preparation method of light-weight high-strength wood-plastic floor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310468657.6A CN103526911B (en) | 2013-10-09 | 2013-10-09 | A kind of preparation method of light-weight high-strength wood-plastic floor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103526911A CN103526911A (en) | 2014-01-22 |
| CN103526911B true CN103526911B (en) | 2015-08-26 |
Family
ID=49929231
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310468657.6A Expired - Fee Related CN103526911B (en) | 2013-10-09 | 2013-10-09 | A kind of preparation method of light-weight high-strength wood-plastic floor |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103526911B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104308944A (en) * | 2014-10-13 | 2015-01-28 | 苏州东邦家具有限公司 | Mildew-proof and bacterial light solid wood board furniture |
| CN106009018A (en) * | 2016-06-24 | 2016-10-12 | 桂林舒康建材有限公司 | Special active solvent for producing grain on surfaces of PE (polyethylene) wood-plastic products |
| CN106085296A (en) * | 2016-07-21 | 2016-11-09 | 柳州市五源科技有限公司 | Food-grade adhesive |
| CN106543926A (en) * | 2016-10-20 | 2017-03-29 | 曹美兰 | A kind of Wood-plastic floor decorative layer laying binding agent |
| CN107227034A (en) * | 2017-06-21 | 2017-10-03 | 东莞市佳乾新材料科技有限公司 | A kind of floor PVC base wood-plastic composite materials and preparation method thereof |
| US10335990B2 (en) | 2017-06-28 | 2019-07-02 | Zhejiang Kingdom Plastics Industry Co., Ltd. | Composite floor and manufacturing method thereof |
| CN107118472A (en) * | 2017-06-28 | 2017-09-01 | 浙江晶通塑胶有限公司 | Composite floor board and preparation method thereof |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55144121A (en) * | 1979-04-27 | 1980-11-10 | Matsushita Electric Works Ltd | Production of decorative material |
| CN2214979Y (en) * | 1995-04-08 | 1995-12-13 | 孙福民 | Built-up wood-plastic ornament board |
| US6453630B1 (en) * | 2000-03-03 | 2002-09-24 | Crane Plastics Company Llc | Deck plank cover |
| JP4225120B2 (en) * | 2003-05-30 | 2009-02-18 | 凸版印刷株式会社 | Exterior resin floor and manufacturing method thereof |
| CN1311024C (en) * | 2004-04-28 | 2007-04-18 | 桂林舒康建材有限公司 | Aromatic multi-texture microporous thermoplastic resin wood-imitating materials and wood texture forming process |
| CN201040911Y (en) * | 2007-02-15 | 2008-03-26 | 青岛联谊木业有限公司 | Wood integrated wood-plastic floor |
| DE102009008381B3 (en) * | 2009-02-11 | 2010-08-05 | Flooring Technologies Ltd. | Method for finishing wood-based material board i.e. high density fiber board, utilized as floor laminate, involves pressing layer structure, where ground coat, primer, sealing and decorative layer are dried before applying one after another |
| CN201411888Y (en) * | 2009-06-05 | 2010-02-24 | 成都山天远信高新材料有限公司 | Composite floor |
| CN201526145U (en) * | 2009-11-10 | 2010-07-14 | 浙江久盛地板有限公司 | Plastic composite wood floor |
| DE102010020962B4 (en) * | 2010-05-19 | 2018-08-16 | Fritz Egger Gmbh & Co. Og | Floor panel with a wear layer comprising a cork layer |
| CN201771155U (en) * | 2010-07-09 | 2011-03-23 | 邓云鹏 | Novel PVC wood-plastic flooring board |
| CN102827387B (en) * | 2012-09-11 | 2013-11-13 | 桂林舒康建材有限公司 | Active solvent for surface grain forming technology of wood products |
| CN102993760B (en) * | 2012-12-03 | 2015-08-12 | 汕头市欣源低碳木业有限公司 | The making method of a kind of high temperature resistant composite wood-plastic material and high temperature-resistant compound wood-plastic |
-
2013
- 2013-10-09 CN CN201310468657.6A patent/CN103526911B/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN103526911A (en) | 2014-01-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103526911B (en) | A kind of preparation method of light-weight high-strength wood-plastic floor | |
| CN103498547B (en) | Novel method for producing reinforced wood-plastic composite floor | |
| CN100462398C (en) | Wear resistant type plastic floor and its production technology | |
| CN101487336B (en) | Composite floor board and method for producing the same | |
| CN102020862B (en) | Light wood-plastic composite material and manufacturing method thereof | |
| CN102504557A (en) | Low-density wood-plastic composite shaving board and manufacture method thereof | |
| CN102070856A (en) | Stone-plastic wood floor and processing technology thereof | |
| CN103556796A (en) | Ground heating floor made of polymer alloy materials and preparation method thereof | |
| CN102758518B (en) | High-wear-resistant wood-plastic composite floor and preparation method thereof | |
| CN102092163A (en) | Glassfibre reinforced plastics and preparation method thereof | |
| CN109605770A (en) | A kind of production technology of cork stone plastic floor | |
| CN113860795A (en) | Whole body texture material and preparation method thereof | |
| CN103319818B (en) | A kind of polyvinyl chloride bamboo utilizing bamboo powder to produce moulds the preparation method of goods | |
| CN103192440B (en) | Production method of pure cork wood tongue and groove floor and lock catch floor | |
| CN102888061A (en) | Processing method of polyvinyl chloride wood-like ornamental plate | |
| CN101066599B (en) | Bamboo-plastic floorboard and its production process | |
| CN102673082B (en) | Process for manufacturing veneer by using calcium silicate as substrate | |
| CN106280119A (en) | A kind of environmental protection Wood-plastic floor material | |
| CN105619549A (en) | Process for repairing substrate | |
| CN102296712A (en) | Ultra-thin stone phenolic foam composite board | |
| CN113578713A (en) | Processing technology of antioxidant metal surface floor | |
| CN102259415A (en) | Extrusion method for faux wood sheet material | |
| CN102729555B (en) | Environment-friendly composite stone plate and preparation method thereof | |
| CN110092992A (en) | Floor Shi Jing and preparation method thereof | |
| CN102557522B (en) | Material for building decoration and artificial floor manufactured by material for building decoration |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150826 Termination date: 20191009 |