CN103524221B - 茄子专用缓控/释复混肥料及其制备方法 - Google Patents
茄子专用缓控/释复混肥料及其制备方法 Download PDFInfo
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- CN103524221B CN103524221B CN201310471098.4A CN201310471098A CN103524221B CN 103524221 B CN103524221 B CN 103524221B CN 201310471098 A CN201310471098 A CN 201310471098A CN 103524221 B CN103524221 B CN 103524221B
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- Prior art keywords
- eggplant
- fertilizer
- sulfate
- adopts
- slow control
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 128
- 244000061458 Solanum melongena Species 0.000 title claims abstract description 100
- 235000002597 Solanum melongena Nutrition 0.000 title claims abstract description 100
- 238000002360 preparation method Methods 0.000 title description 17
- 150000001875 compounds Chemical class 0.000 title description 12
- 210000003608 fece Anatomy 0.000 claims abstract description 23
- 239000010871 livestock manure Substances 0.000 claims abstract description 23
- 241000287828 Gallus gallus Species 0.000 claims abstract description 22
- 239000011575 calcium Substances 0.000 claims abstract description 5
- 239000011701 zinc Substances 0.000 claims abstract description 5
- 239000011777 magnesium Substances 0.000 claims abstract description 4
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 38
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 28
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 27
- 239000004202 carbamide Substances 0.000 claims description 27
- 235000019779 Rapeseed Meal Nutrition 0.000 claims description 21
- 239000004456 rapeseed meal Substances 0.000 claims description 21
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 19
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 19
- 239000002245 particle Substances 0.000 claims description 19
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 17
- 239000004327 boric acid Substances 0.000 claims description 17
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 17
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 17
- 235000011151 potassium sulphates Nutrition 0.000 claims description 17
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 17
- 229960001763 zinc sulfate Drugs 0.000 claims description 17
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 17
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 15
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims description 14
- 239000011609 ammonium molybdate Substances 0.000 claims description 14
- 235000018660 ammonium molybdate Nutrition 0.000 claims description 14
- 229940010552 ammonium molybdate Drugs 0.000 claims description 14
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 14
- 239000011790 ferrous sulphate Substances 0.000 claims description 14
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 14
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 14
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 14
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 13
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 claims description 13
- 235000019837 monoammonium phosphate Nutrition 0.000 claims description 13
- 239000006012 monoammonium phosphate Substances 0.000 claims description 13
- HEPPIYNOUFWEPP-UHFFFAOYSA-N n-diaminophosphinothioylbutan-1-amine Chemical compound CCCCNP(N)(N)=S HEPPIYNOUFWEPP-UHFFFAOYSA-N 0.000 claims description 11
- 241000195940 Bryophyta Species 0.000 claims description 9
- 239000003415 peat Substances 0.000 claims description 9
- 239000004927 clay Substances 0.000 claims description 6
- 239000000440 bentonite Substances 0.000 claims description 5
- 229910000278 bentonite Inorganic materials 0.000 claims description 5
- 239000002689 soil Substances 0.000 abstract description 43
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 14
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 9
- 230000000694 effects Effects 0.000 abstract description 8
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 8
- 238000002156 mixing Methods 0.000 abstract description 7
- 229910052700 potassium Inorganic materials 0.000 abstract description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 6
- 235000015097 nutrients Nutrition 0.000 abstract description 6
- 235000013619 trace mineral Nutrition 0.000 abstract description 6
- 239000011573 trace mineral Substances 0.000 abstract description 6
- 230000012010 growth Effects 0.000 abstract description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 3
- 239000011574 phosphorus Substances 0.000 abstract description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052796 boron Inorganic materials 0.000 abstract description 2
- 229910052791 calcium Inorganic materials 0.000 abstract description 2
- 229910052742 iron Inorganic materials 0.000 abstract description 2
- 239000011591 potassium Substances 0.000 abstract description 2
- 229910052725 zinc Inorganic materials 0.000 abstract description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 abstract 2
- 240000002791 Brassica napus Species 0.000 abstract 1
- 235000004977 Brassica sinapistrum Nutrition 0.000 abstract 1
- 244000025254 Cannabis sativa Species 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract 1
- 229940090496 Urease inhibitor Drugs 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 abstract 1
- 239000003112 inhibitor Substances 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011733 molybdenum Substances 0.000 abstract 1
- 229910052750 molybdenum Inorganic materials 0.000 abstract 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 abstract 1
- RYYWUUFWQRZTIU-UHFFFAOYSA-K thiophosphate Chemical compound [O-]P([O-])([O-])=S RYYWUUFWQRZTIU-UHFFFAOYSA-K 0.000 abstract 1
- 239000002601 urease inhibitor Substances 0.000 abstract 1
- 239000002131 composite material Substances 0.000 description 68
- 238000000034 method Methods 0.000 description 63
- 230000008569 process Effects 0.000 description 63
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 24
- 235000013399 edible fruits Nutrition 0.000 description 16
- 235000010338 boric acid Nutrition 0.000 description 13
- 239000000203 mixture Substances 0.000 description 13
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 12
- 229910002651 NO3 Inorganic materials 0.000 description 12
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 12
- 229910021529 ammonia Inorganic materials 0.000 description 12
- 229940031352 solanine Drugs 0.000 description 11
- 230000007423 decrease Effects 0.000 description 9
- 229910021432 inorganic complex Inorganic materials 0.000 description 9
- 239000000618 nitrogen fertilizer Substances 0.000 description 9
- IKGXIBQEEMLURG-NVPNHPEKSA-N rutin Chemical compound O[C@@H]1[C@H](O)[C@@H](O)[C@H](C)O[C@H]1OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@H](OC=2C(C3=C(O)C=C(O)C=C3OC=2C=2C=C(O)C(O)=CC=2)=O)O1 IKGXIBQEEMLURG-NVPNHPEKSA-N 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- 235000001014 amino acid Nutrition 0.000 description 8
- 150000001413 amino acids Chemical class 0.000 description 8
- 235000019154 vitamin C Nutrition 0.000 description 7
- 239000011718 vitamin C Substances 0.000 description 7
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 description 6
- 229930003268 Vitamin C Natural products 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 238000000354 decomposition reaction Methods 0.000 description 5
- 235000013311 vegetables Nutrition 0.000 description 5
- 239000004254 Ammonium phosphate Substances 0.000 description 4
- JVMRPSJZNHXORP-UHFFFAOYSA-N ON=O.ON=O.ON=O.N Chemical compound ON=O.ON=O.ON=O.N JVMRPSJZNHXORP-UHFFFAOYSA-N 0.000 description 4
- 238000009825 accumulation Methods 0.000 description 4
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 4
- 235000019289 ammonium phosphates Nutrition 0.000 description 4
- 239000000084 colloidal system Substances 0.000 description 4
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 4
- 244000005700 microbiome Species 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 3
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- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 2
- 244000046052 Phaseolus vulgaris Species 0.000 description 2
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 2
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 2
- PPBAJDRXASKAGH-UHFFFAOYSA-N azane;urea Chemical compound N.NC(N)=O PPBAJDRXASKAGH-UHFFFAOYSA-N 0.000 description 2
- 229960002645 boric acid Drugs 0.000 description 2
- 150000001720 carbohydrates Chemical class 0.000 description 2
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- 238000004040 coloring Methods 0.000 description 2
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- 239000010985 leather Substances 0.000 description 2
- 229960003390 magnesium sulfate Drugs 0.000 description 2
- 235000014786 phosphorus Nutrition 0.000 description 2
- 229940093914 potassium sulfate Drugs 0.000 description 2
- 235000018102 proteins Nutrition 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 230000002786 root growth Effects 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 208000032843 Hemorrhage Diseases 0.000 description 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
- 235000002634 Solanum Nutrition 0.000 description 1
- 241000207763 Solanum Species 0.000 description 1
- MMDJDBSEMBIJBB-UHFFFAOYSA-N [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] Chemical compound [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] MMDJDBSEMBIJBB-UHFFFAOYSA-N 0.000 description 1
- FHGSRYWNWPZLLH-UHFFFAOYSA-N [Zn].[Mg].[B].[Ca] Chemical compound [Zn].[Mg].[B].[Ca] FHGSRYWNWPZLLH-UHFFFAOYSA-N 0.000 description 1
- 229930013930 alkaloid Natural products 0.000 description 1
- 150000003797 alkaloid derivatives Chemical class 0.000 description 1
- RXVGBQCEAQZMLW-UHFFFAOYSA-N alpha-solanine Natural products CC1CCC2C(C)C3C(CC4C5CC=C6CC(CCC6(C)C5CCC34C)OC7OC(CO)C(O)C(OC8OC(CO)C(O)C(O)C8O)C7OC9OC(CO)C(O)C(O)C9O)N2C1 RXVGBQCEAQZMLW-UHFFFAOYSA-N 0.000 description 1
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- YYRMJZQKEFZXMX-UHFFFAOYSA-L calcium bis(dihydrogenphosphate) Chemical compound [Ca+2].OP(O)([O-])=O.OP(O)([O-])=O YYRMJZQKEFZXMX-UHFFFAOYSA-L 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 239000000496 cardiotonic agent Substances 0.000 description 1
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- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 239000012954 diazonium Substances 0.000 description 1
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- 230000001079 digestive effect Effects 0.000 description 1
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- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000002526 effect on cardiovascular system Effects 0.000 description 1
- 238000012851 eutrophication Methods 0.000 description 1
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- 235000012041 food component Nutrition 0.000 description 1
- 229930008677 glyco alkaloid Natural products 0.000 description 1
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- 238000002386 leaching Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
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- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 230000014075 nitrogen utilization Effects 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
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- 230000000050 nutritive effect Effects 0.000 description 1
- 239000003895 organic fertilizer Substances 0.000 description 1
- 210000004681 ovum Anatomy 0.000 description 1
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- ZGVSETXHNHBTRK-OTYSSXIJSA-N solanine Chemical compound O([C@H]1[C@@H](O)[C@@H](CO)O[C@H]([C@@H]1O[C@@H]1[C@@H]([C@H](O)[C@@H](O)[C@H](C)O1)O)O[C@@H]1CC2=CC[C@H]3[C@@H]4C[C@@H]5N6C[C@@H](C)CC[C@@H]6[C@H]([C@@H]5[C@@]4(C)CC[C@@H]3[C@@]2(C)CC1)C)[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O ZGVSETXHNHBTRK-OTYSSXIJSA-N 0.000 description 1
- 241000894007 species Species 0.000 description 1
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- ZJHHPAUQMCHPRB-UHFFFAOYSA-N urea urea Chemical compound NC(N)=O.NC(N)=O ZJHHPAUQMCHPRB-UHFFFAOYSA-N 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
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- 230000029663 wound healing Effects 0.000 description 1
- 235000016804 zinc Nutrition 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P60/00—Technologies relating to agriculture, livestock or agroalimentary industries
- Y02P60/20—Reduction of greenhouse gas [GHG] emissions in agriculture, e.g. CO2
- Y02P60/21—Dinitrogen oxide [N2O], e.g. using aquaponics, hydroponics or efficiency measures
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- Fertilizers (AREA)
Abstract
Description
Claims (6)
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Cited By (2)
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EP3567020A1 (en) * | 2018-05-11 | 2019-11-13 | Yara International ASA | Improved urea-based composition comprising elemental sulphur and method for the manufacture thereof |
EP3567019A1 (en) * | 2018-05-09 | 2019-11-13 | Yara International ASA | Improved urea-based blend composition and method for the manufacture thereof |
Families Citing this family (10)
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CN104311220A (zh) * | 2014-09-24 | 2015-01-28 | 林公传 | 一种茄子种植控释肥料及其制备方法 |
CN105085094B (zh) * | 2015-09-29 | 2019-04-26 | 武汉市农业科学研究所 | 一种茄子营养生长期和生殖生长期的专用肥及其施用方法 |
CN105254409A (zh) * | 2015-09-30 | 2016-01-20 | 天长市翔净蔬菜种植发展有限公司 | 一种低成本缓释茄子专用肥及其制备方法 |
CN105265140A (zh) * | 2015-09-30 | 2016-01-27 | 天长市翔净蔬菜种植发展有限公司 | 一种高产环保茄子的种植方法 |
WO2017168288A1 (en) * | 2016-04-01 | 2017-10-05 | Basf Se | Use of a cation source to prevent decomposition of (thio)phosphoric acid triamide urease inhibitors when a phosphorus-containing fertilizer is present |
EP3309137A1 (en) * | 2016-10-13 | 2018-04-18 | YARA International ASA | Improved urea-based composition comprising elemental sulphur and method for the manufacture thereof |
CN106748331A (zh) * | 2017-03-10 | 2017-05-31 | 四川好时吉化工有限公司 | 用于茄子的缓控释肥料 |
CN109716945B (zh) * | 2017-10-31 | 2021-10-29 | 曲周县金满园农业科技有限公司 | 一种可提高茄子品质的嫁接方法 |
EP3567018A1 (en) | 2018-05-07 | 2019-11-13 | Yara International ASA | Improved urea ammonium sulphate-based composition and method for the manufacture thereof |
CN109553502A (zh) * | 2018-11-23 | 2019-04-02 | 西南大学 | 大白菜专用肥料及其制备方法 |
Citations (5)
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CN1081432A (zh) * | 1992-07-24 | 1994-02-02 | 中国科学院沈阳应用生态研究所 | 茄果类蔬菜专用复合肥及生产方法 |
CN101734959A (zh) * | 2009-12-18 | 2010-06-16 | 山东光大肥业科技有限公司 | 茄果类有机蔬菜专用有机肥及其制备方法 |
CN102515968A (zh) * | 2012-01-04 | 2012-06-27 | 广西新方向化学工业有限公司 | 多功能增效氮肥及其制备方法 |
CN102531762A (zh) * | 2010-12-22 | 2012-07-04 | 施可丰化工股份有限公司 | 一种萝卜专用的长效复混肥料 |
CN102863285A (zh) * | 2012-09-27 | 2013-01-09 | 上海孚祥生物科技有限公司 | 一种以生物质颗粒炭为基质的茄子专用缓释肥料及其制备方法 |
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2013
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EP3567019A1 (en) * | 2018-05-09 | 2019-11-13 | Yara International ASA | Improved urea-based blend composition and method for the manufacture thereof |
EP3567020A1 (en) * | 2018-05-11 | 2019-11-13 | Yara International ASA | Improved urea-based composition comprising elemental sulphur and method for the manufacture thereof |
WO2019215325A1 (en) | 2018-05-11 | 2019-11-14 | Yara International Asa | Improved urea-based composition comprising elemental sulphur and method for the manufacture thereof |
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