CN103495380A - Modified activated carbon air adsorbent and its preparation method - Google Patents
Modified activated carbon air adsorbent and its preparation method Download PDFInfo
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- CN103495380A CN103495380A CN201310387306.2A CN201310387306A CN103495380A CN 103495380 A CN103495380 A CN 103495380A CN 201310387306 A CN201310387306 A CN 201310387306A CN 103495380 A CN103495380 A CN 103495380A
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Abstract
A modified activated carbon air adsorbent is prepared from the following raw materials: by weight, 100-200 parts of activated carbon, 20-23 parts of clay, 2-3 parts of polyvinyl alcohol, 4-5 parts of rice husk, 8-10 parts of modified attapulgite, a proper amount of 10-15% hydrochloric acid and a proper amount of water. According to the modified activated carbon air adsorbent, the clay, the rice husk and the polyvinyl alcohol are roasted and then used as carriers to improve adsorption activity, and the raw materials are safe and free of production of harmful substances, can absorb sulfides, viruses, formaldehyde and other harmful substances in the air, and is suitable for air purification and detoxification in daily life. The modified activated carbon air adsorbent has the advantages of easily obtained raw materials, simple process, low cost, suitability for industrial production, and good application prospects.
Description
Technical field
The present invention relates to a kind of method of modifying of nonmetallic ore, relate in particular to a kind of modified activated carbon air adsorption agent and preparation method thereof.
Background technology
Along with scientific and technological development, the progressively construction of modernization industry, various chemicals are exploited, and have brought facility to people's life, simultaneously because chemicals has produced environment and the harmful material of human body, the problem that has also become people to have to face.
Current airborne pollutant is mainly the toxic and harmful produced in the gas that produces of industrial fuel burning, vehicle exhaust, production.It is mainly to contain a large amount of noxious materials in the sewage of industrial production discharge that water pollutes, and also has the sewage in people's life to produce a lot of harmful substances.Also have and many times need to remove toxin in people life, such as air conditioning filter has a lot of bacteriums, toxin on the net, newly-decorated has the harmful substance such as formaldehyde, all needs to remove toxin.All remove at present toxin and often use adsorbent, mainly contain silica gel, activated alumina, active carbon, molecular sieve etc., the sorbing material of developing for certain compositional selecting absorption in addition in addition.But the most adsorption capacity of these adsorbents is limited, need to study different adsorbents for different requirements, bring into play best effect.Simultaneously, find new raw material, to strengthen adsorption effect, cost-saving.
Summary of the invention
The object of the present invention is to provide a kind of modified activated carbon air adsorption agent and preparation method thereof.
Technical scheme of the present invention is as follows:
The agent of a kind of modified activated carbon air adsorption is characterized in that being made by the raw material of following weight portion: active carbon 100-120, clay 20-23, polyvinyl alcohol 2-3, rice husk 4-5, attapulgite modified 8-10,10-15% hydrochloric acid is appropriate, water is appropriate; The described attapulgite modified raw material by following weight portion is made: live tropine 2-3, lanthana 1-2, chromium oxide 3-4, morpholine 1-2, water of attapulgite 120-130, jade powder 3-4, kaolin 8-10, crosslinking agent TAC1-2, aluminium hydroxide 8-10, zinc stearate 2-3, borax 1-2, titanium sulfate 14-18, crow is appropriate; The preparation method sends into attapulgite, jade powder, kaolin in calcining furnace, and under 870-890 ℃, calcining 2-3 hour, take out, spill crosslinking agent TAC, then put into suitable quantity of water and grind, regulating the lapping liquid pH value is 4-5, grind 1-2 hour, obtain 100-150 order slurry, then regulate the lapping liquid pH value for neutral, add other residual components, continue to grind, obtain 200-300 order slurry, spray-drying, obtain.
The preparation method of described modified activated carbon air adsorption agent is characterized in that comprising the following steps: polyvinyl alcohol is added in suitable quantity of water, be heated to 80-90 ℃ of dissolving, add again clay, rice husk, stir into pasty state, granulation, send into 900-1000 ℃ of roasting kiln roasting 2-3 hour, take out, pulverize, put into appropriate 10-15% hydrochloric acid, soak 3-4 hour, take out washing, drying, mix with other residual components, obtain.
Divide the beneficial effect of the invention
The present invention use clay, rice husk, polyvinyl alcohol through roasting as carrier, improved adsorption activity, and the materials safety unharmful substance produces, the harmful substances such as the sulfide in can absorbed air, virus, formaldehyde, be applicable to the daily life Air to purify detoxification; Raw material of the present invention is easy to get, technique is simple, cost is low, be applicable to suitability for industrialized production, and good application prospect is arranged.
The specific embodiment
The agent of a kind of modified activated carbon air adsorption, by the raw material of following weight portion (kilogram), made: active carbon 110, clay 21, polyvinyl alcohol 2, rice husk 4, attapulgite modified 9,11% hydrochloric acid is appropriate, water is appropriate;
The described attapulgite modified raw material by following weight portion (kilogram) is made: live tropine 2, lanthana 1, chromium oxide 3, morpholine 1, water of attapulgite 110, jade powder 3, kaolin 9, crosslinking agent TAC 1.5, aluminium hydroxide 9, zinc stearate 2, borax 1, titanium sulfate 16, crow is appropriate; The preparation method sends into attapulgite, jade powder, kaolin in calcining furnace, and under 880 ℃, calcining is 2 hours, takes out, spill crosslinking agent TAC, then put into suitable quantity of water and grind, regulating the lapping liquid pH value is 4, grind 1.5 hours, obtain 120 order slurries, then regulate the lapping liquid pH value for neutral, add other residual components, continue to grind, obtain 250 order slurries, spray-drying, obtain.
The preparation method of described modified activated carbon air adsorption agent is characterized in that comprising the following steps: polyvinyl alcohol is added in suitable quantity of water, be heated to 85 ℃ of dissolvings, add again clay, rice husk, stir into pasty state, granulation, send into 950 ℃ of roasting kiln roastings 2 hours, take out, pulverize, put into 11% appropriate hydrochloric acid, soak 3 hours, take out washing, drying, mix with other residual components, obtain.
After measured, its iodine number 1508mg/g, methylene blue adsorption value 26.7mL/0.1g.
Claims (2)
1. modified activated carbon air adsorption agent is characterized in that being made by the raw material of following weight portion: active carbon 100-120, clay 20-23, polyvinyl alcohol 2-3, rice husk 4-5, attapulgite modified 8-10,10-15% hydrochloric acid is appropriate, water is appropriate; The described attapulgite modified raw material by following weight portion is made: live tropine 2-3, lanthana 1-2, chromium oxide 3-4, morpholine 1-2, water of attapulgite 120-130, jade powder 3-4, kaolin 8-10, crosslinking agent TAC1-2, aluminium hydroxide 8-10, zinc stearate 2-3, borax 1-2, titanium sulfate 14-18, crow is appropriate; The preparation method sends into attapulgite, jade powder, kaolin in calcining furnace, and under 870-890 ℃, calcining 2-3 hour, take out, spill crosslinking agent TAC, then put into suitable quantity of water and grind, regulating the lapping liquid pH value is 4-5, grind 1-2 hour, obtain 100-150 order slurry, then regulate the lapping liquid pH value for neutral, add other residual components, continue to grind, obtain 200-300 order slurry, spray-drying, obtain.
2. the preparation method of modified activated carbon air adsorption agent according to claim 1, is characterized in that comprising the following steps: polyvinyl alcohol is added in suitable quantity of water, be heated to 80-90 ℃ of dissolving, add again clay, rice husk, stir into pasty state, granulation, send into 900-1000 ℃ of roasting kiln roasting 2-3 hour, take out, pulverize, put into appropriate 10-15% hydrochloric acid, soak 3-4 hour, take out washing, drying, mix with other residual components, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310387306.2A CN103495380A (en) | 2013-08-30 | 2013-08-30 | Modified activated carbon air adsorbent and its preparation method |
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| CN201310387306.2A CN103495380A (en) | 2013-08-30 | 2013-08-30 | Modified activated carbon air adsorbent and its preparation method |
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| CN103495380A true CN103495380A (en) | 2014-01-08 |
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| CN201310387306.2A Pending CN103495380A (en) | 2013-08-30 | 2013-08-30 | Modified activated carbon air adsorbent and its preparation method |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104311921A (en) * | 2014-10-27 | 2015-01-28 | 安徽锐视光电技术有限公司 | Cold-resistant, light-resistant and water-resistant synthetic rubber for color selector and preparation method of synthetic rubber |
| CN106345218A (en) * | 2016-08-30 | 2017-01-25 | 樊之雄 | Antibacterial air purifying material and preparing method thereof |
| CN106362481A (en) * | 2016-10-24 | 2017-02-01 | 马鞍山科宇环境工程有限公司 | Modifier for filter material fibers of bag filter for soot |
| CN109675520A (en) * | 2018-12-29 | 2019-04-26 | 安徽蓝鼎环保能源科技有限公司 | A kind of high activity powdered carbon exhaust-gas treatment material and preparation method thereof |
| CN112275039A (en) * | 2020-10-16 | 2021-01-29 | 安徽职业技术学院 | Purifying filter element and purifier comprising same |
| WO2023089633A1 (en) * | 2021-11-16 | 2023-05-25 | Manish Jain | Activated carbon beads with reduced dust spillage |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1039193A (en) * | 1989-04-11 | 1990-01-31 | 四川建筑材料工业学院 | The semidry method acid heat activation of attapulgite clay |
| CN1935313A (en) * | 2006-09-18 | 2007-03-28 | 周祎 | Gas phase-liquid phase fluid multifunctional filtering core and its manufacturing method |
| CN102527337A (en) * | 2012-03-08 | 2012-07-04 | 天津市嘉腾环保设备有限公司 | Compound adsorbent grain and production method thereof |
| US20130177620A1 (en) * | 2009-11-24 | 2013-07-11 | The Clorox Company | Non-visible activated carbon in absorbent materials |
-
2013
- 2013-08-30 CN CN201310387306.2A patent/CN103495380A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1039193A (en) * | 1989-04-11 | 1990-01-31 | 四川建筑材料工业学院 | The semidry method acid heat activation of attapulgite clay |
| CN1935313A (en) * | 2006-09-18 | 2007-03-28 | 周祎 | Gas phase-liquid phase fluid multifunctional filtering core and its manufacturing method |
| US20130177620A1 (en) * | 2009-11-24 | 2013-07-11 | The Clorox Company | Non-visible activated carbon in absorbent materials |
| CN102527337A (en) * | 2012-03-08 | 2012-07-04 | 天津市嘉腾环保设备有限公司 | Compound adsorbent grain and production method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104311921A (en) * | 2014-10-27 | 2015-01-28 | 安徽锐视光电技术有限公司 | Cold-resistant, light-resistant and water-resistant synthetic rubber for color selector and preparation method of synthetic rubber |
| CN106345218A (en) * | 2016-08-30 | 2017-01-25 | 樊之雄 | Antibacterial air purifying material and preparing method thereof |
| CN106362481A (en) * | 2016-10-24 | 2017-02-01 | 马鞍山科宇环境工程有限公司 | Modifier for filter material fibers of bag filter for soot |
| CN109675520A (en) * | 2018-12-29 | 2019-04-26 | 安徽蓝鼎环保能源科技有限公司 | A kind of high activity powdered carbon exhaust-gas treatment material and preparation method thereof |
| CN112275039A (en) * | 2020-10-16 | 2021-01-29 | 安徽职业技术学院 | Purifying filter element and purifier comprising same |
| WO2023089633A1 (en) * | 2021-11-16 | 2023-05-25 | Manish Jain | Activated carbon beads with reduced dust spillage |
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Application publication date: 20140108 |