CN103483095B - Special slow/controlled release compound fertilizer for capsicum, and preparation method thereof - Google Patents
Special slow/controlled release compound fertilizer for capsicum, and preparation method thereof Download PDFInfo
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- CN103483095B CN103483095B CN201310471100.8A CN201310471100A CN103483095B CN 103483095 B CN103483095 B CN 103483095B CN 201310471100 A CN201310471100 A CN 201310471100A CN 103483095 B CN103483095 B CN 103483095B
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 121
- 235000002566 Capsicum Nutrition 0.000 title claims abstract description 85
- 239000001390 capsicum minimum Substances 0.000 title claims abstract description 12
- 238000013270 controlled release Methods 0.000 title abstract description 7
- 240000008574 Capsicum frutescens Species 0.000 title abstract 2
- 150000001875 compounds Chemical class 0.000 title description 70
- 238000002360 preparation method Methods 0.000 title description 16
- 241000758706 Piperaceae Species 0.000 claims abstract description 41
- 241000287828 Gallus gallus Species 0.000 claims abstract description 21
- 210000003608 fece Anatomy 0.000 claims abstract description 21
- 239000010871 livestock manure Substances 0.000 claims abstract description 21
- 235000019779 Rapeseed Meal Nutrition 0.000 claims abstract description 20
- 239000004456 rapeseed meal Substances 0.000 claims abstract description 20
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims abstract description 18
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000011777 magnesium Substances 0.000 claims abstract description 3
- 239000011701 zinc Substances 0.000 claims abstract description 3
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 34
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 28
- 239000004202 carbamide Substances 0.000 claims description 28
- 239000002245 particle Substances 0.000 claims description 21
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 17
- 239000004327 boric acid Substances 0.000 claims description 17
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 17
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 17
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 17
- 235000011151 potassium sulphates Nutrition 0.000 claims description 17
- 239000000440 bentonite Substances 0.000 claims description 16
- 229910000278 bentonite Inorganic materials 0.000 claims description 16
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 16
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 16
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 16
- 229960001763 zinc sulfate Drugs 0.000 claims description 16
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 16
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 12
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 claims description 12
- 235000019837 monoammonium phosphate Nutrition 0.000 claims description 12
- 239000006012 monoammonium phosphate Substances 0.000 claims description 12
- 241000208293 Capsicum Species 0.000 claims description 10
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 4
- RYYWUUFWQRZTIU-UHFFFAOYSA-K thiophosphate Chemical compound [O-]P([O-])([O-])=S RYYWUUFWQRZTIU-UHFFFAOYSA-K 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims 1
- 235000011130 ammonium sulphate Nutrition 0.000 claims 1
- QVLTXCYWHPZMCA-UHFFFAOYSA-N po4-po4 Chemical compound OP(O)(O)=O.OP(O)(O)=O QVLTXCYWHPZMCA-UHFFFAOYSA-N 0.000 claims 1
- 239000002689 soil Substances 0.000 abstract description 39
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 24
- 230000000694 effects Effects 0.000 abstract description 14
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 14
- 235000015097 nutrients Nutrition 0.000 abstract description 10
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract description 9
- 239000011591 potassium Substances 0.000 abstract description 9
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 8
- 229910052700 potassium Inorganic materials 0.000 abstract description 8
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 6
- 230000012010 growth Effects 0.000 abstract description 6
- 239000011574 phosphorus Substances 0.000 abstract description 6
- 239000011573 trace mineral Substances 0.000 abstract description 6
- 235000013619 trace mineral Nutrition 0.000 abstract description 6
- LMZSPXZNYGLPAV-UHFFFAOYSA-N butoxy-dihydroxy-sulfanylidene-$l^{5}-phosphane Chemical compound CCCCOP(O)(O)=S LMZSPXZNYGLPAV-UHFFFAOYSA-N 0.000 abstract description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052796 boron Inorganic materials 0.000 abstract 1
- 239000003112 inhibitor Substances 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000002601 urease inhibitor Substances 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 239000006002 Pepper Substances 0.000 description 32
- 241000722363 Piper Species 0.000 description 32
- 235000016761 Piper aduncum Nutrition 0.000 description 32
- 235000017804 Piper guineense Nutrition 0.000 description 32
- 235000008184 Piper nigrum Nutrition 0.000 description 32
- 235000013399 edible fruits Nutrition 0.000 description 21
- YKPUWZUDDOIDPM-SOFGYWHQSA-N capsaicin Chemical compound COC1=CC(CNC(=O)CCCC\C=C\C(C)C)=CC=C1O YKPUWZUDDOIDPM-SOFGYWHQSA-N 0.000 description 20
- 229910002651 NO3 Inorganic materials 0.000 description 17
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 17
- 239000000203 mixture Substances 0.000 description 16
- 239000000618 nitrogen fertilizer Substances 0.000 description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 10
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 10
- 229960002504 capsaicin Drugs 0.000 description 10
- 235000017663 capsaicin Nutrition 0.000 description 10
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 9
- 150000002894 organic compounds Chemical class 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- 150000001413 amino acids Chemical class 0.000 description 8
- 238000004040 coloring Methods 0.000 description 7
- 239000002994 raw material Substances 0.000 description 7
- MMDJDBSEMBIJBB-UHFFFAOYSA-N [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] Chemical compound [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] MMDJDBSEMBIJBB-UHFFFAOYSA-N 0.000 description 6
- 235000013311 vegetables Nutrition 0.000 description 6
- 235000019154 vitamin C Nutrition 0.000 description 6
- 239000011718 vitamin C Substances 0.000 description 6
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 description 5
- 229930003268 Vitamin C Natural products 0.000 description 5
- 229910021529 ammonia Inorganic materials 0.000 description 5
- 150000002484 inorganic compounds Chemical class 0.000 description 5
- 229910010272 inorganic material Inorganic materials 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000004254 Ammonium phosphate Substances 0.000 description 4
- JVMRPSJZNHXORP-UHFFFAOYSA-N ON=O.ON=O.ON=O.N Chemical compound ON=O.ON=O.ON=O.N JVMRPSJZNHXORP-UHFFFAOYSA-N 0.000 description 4
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 4
- 235000019289 ammonium phosphates Nutrition 0.000 description 4
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical group [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 239000003570 air Substances 0.000 description 3
- 235000010338 boric acid Nutrition 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 230000018044 dehydration Effects 0.000 description 3
- 238000006297 dehydration reaction Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000004720 fertilization Effects 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 235000002568 Capsicum frutescens Nutrition 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- 235000019764 Soybean Meal Nutrition 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000001186 cumulative effect Effects 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 230000035558 fertility Effects 0.000 description 2
- 239000003673 groundwater Substances 0.000 description 2
- 238000003306 harvesting Methods 0.000 description 2
- 235000012054 meals Nutrition 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910052901 montmorillonite Inorganic materials 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 230000036632 reaction speed Effects 0.000 description 2
- 239000004455 soybean meal Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid group Chemical group S(O)(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 240000004160 Capsicum annuum Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical class O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 244000179853 Sideroxylon dulcificum Species 0.000 description 1
- 235000011341 Sideroxylon dulcificum Nutrition 0.000 description 1
- 241000208292 Solanaceae Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 230000036528 appetite Effects 0.000 description 1
- 235000019789 appetite Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- YYRMJZQKEFZXMX-UHFFFAOYSA-N calcium;phosphoric acid Chemical compound [Ca+2].OP(O)(O)=O.OP(O)(O)=O YYRMJZQKEFZXMX-UHFFFAOYSA-N 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 235000013409 condiments Nutrition 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000012851 eutrophication Methods 0.000 description 1
- 210000001035 gastrointestinal tract Anatomy 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229910021432 inorganic complex Inorganic materials 0.000 description 1
- 235000021109 kimchi Nutrition 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 210000005059 placental tissue Anatomy 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 235000015067 sauces Nutrition 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 235000019654 spicy taste Nutrition 0.000 description 1
- WQSRXNAKUYIVET-UHFFFAOYSA-N sulfuric acid;zinc Chemical compound [Zn].OS(O)(=O)=O WQSRXNAKUYIVET-UHFFFAOYSA-N 0.000 description 1
- 239000002426 superphosphate Substances 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
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- Fertilizers (AREA)
Abstract
本发明提供了一种辣椒专用缓/控释肥料,其特征在于包括正丁基硫代磷酸三胺或氢醌0.10%~0.15%、双氰胺0.25%~0.30%,以质量百分比计。本发明将氮、磷、钾、镁、硼、锌等大中微量元素肥料与优质、腐熟的菜籽粕、鸡粪等有机肥结合起来,并添加脲酶抑制剂、硝化抑制剂混合制备而成,能在土壤中具有缓释效果,富含辣椒生长所特需的各种营养元素,能长效的满足辣椒不同生长发育阶段对养分的需要,有效提高辣椒产量。The invention provides a special slow/controlled release fertilizer for capsicum, which is characterized by comprising 0.10%-0.15% of n-butyl thiophosphate triamine or hydroquinone and 0.25%-0.30% of dicyandiamide, calculated by mass percentage. The invention combines nitrogen, phosphorus, potassium, magnesium, boron, zinc and other large, medium and trace element fertilizers with high-quality, decomposed rapeseed meal, chicken manure and other organic fertilizers, and adds urease inhibitors and nitrification inhibitors to mix and prepare , can have a slow-release effect in the soil, rich in various nutrient elements required for the growth of peppers, can meet the nutrient needs of different growth and development stages of peppers for a long time, and effectively increase the yield of peppers.
Description
技术领域 technical field
本发明涉及复混肥料领域,特别涉及一种专用于辣椒的缓控缓释复混肥料及其制备方法。 The invention relates to the field of compound fertilizers, in particular to a slow-control slow-release compound fertilizer specially used for peppers and a preparation method thereof.
背景技术 Background technique
辣椒(Capsicum annum L.)是茄科辣椒属中能结辣辣味或甜味浆果的一年生或多年生草本植物,别名海椒(蜀)、辣子(陕)、辣角(黔)、番椒等。我国是世界上辣椒种植面积最大的国家,全国各地均有种植,每年的栽培面积达133万公顷,占我国蔬菜栽培面积的第2位。青熟果实可炒食、制作泡菜,老熟红果可盐腌制酱,或干燥后成干辣椒及制成辣椒粉,是人们喜食的鲜菜和调味品,特别是西南的四川、贵州、云南,西北甘肃、陕西,华中的湖南、江西等地的人们尤为爱好,每餐必备。此外,辣椒的果皮及胎座组织中,含有辣椒素(C18H27NO3)及维生素A、C等多种营养物质,并有芬芳的辛辣味,有促进食欲,帮助消化及医药等效用。 Pepper ( Capsicum annum L.) is an annual or perennial herbaceous plant that can bear spicy or sweet berries in the Capsicum genus of the Solanaceae family. my country is the country with the largest planting area of pepper in the world, and it is planted all over the country. The annual planting area reaches 1.33 million hectares, accounting for the second place in my country's vegetable planting area. Ripe green fruits can be fried and made into kimchi. Ripe red fruits can be salted and marinated in sauce, or dried into dried chili and made into chili powder. It is a fresh vegetable and condiment that people like to eat, especially in Sichuan, Guizhou, Southwest China. People in Yunnan, Gansu and Shaanxi in the northwest, and Hunan and Jiangxi in central China are especially fond of it, and it is a must for every meal. In addition, the peel and placental tissue of peppers contain capsaicin (C 18 H 27 NO 3 ) and vitamins A, C and other nutrients, and have a fragrant spicy taste, which can promote appetite, help digestion and medicine. .
目前市场上辣椒施用的肥料主要是传统肥料品种,如单质尿素、过磷酸钙、氯化钾以及氮磷钾三元复合肥料等,一般不含中、微量元素,不但肥料针对性较差,未能充分发挥肥料的增产效应,而且,由于辣椒生育期或收获期较长,需多次追肥,费时费工,也增加了生产成本。 At present, the fertilizers used on peppers in the market are mainly traditional fertilizer varieties, such as elemental urea, superphosphate, potassium chloride, and nitrogen, phosphorus, and potassium ternary compound fertilizers, etc., which generally do not contain medium and trace elements. The production-increasing effect of the fertilizer can be brought into full play. Moreover, since the growth period or the harvest period of the pepper is long, it needs to be topdressed many times, which is time-consuming and labor-intensive, and also increases the production cost.
另外,现在蔬菜施肥存在肥料用量过大,而肥料利用率又相对较低的问题。在辣椒生产上重氮现象十分普遍,而氮肥利用率不到30%,不被利用的氮肥或淋溶进入水体引起水体富营养化,或挥发导致空气污染,或沉积在土壤中,造成土壤硝酸盐、亚硝酸盐富集。过量施肥不但降低了农户的经济效应,带来了环境污染,而且长期食用含硝酸盐、亚硝酸盐高的食物,通过食物链会影响人体健康,严重者引起消化道癌变。 In addition, there is a problem that the amount of fertilizer used in vegetable fertilization is too large, and the utilization rate of fertilizer is relatively low. The heavy nitrogen phenomenon is very common in pepper production, and the utilization rate of nitrogen fertilizer is less than 30%. The unused nitrogen fertilizer or leaching into the water body causes eutrophication of the water body, or volatilizes to cause air pollution, or deposits in the soil, causing soil nitric acid Salt and nitrite enrichment. Excessive fertilization not only reduces the economic effect of farmers, but also brings environmental pollution, and long-term consumption of foods high in nitrate and nitrite will affect human health through the food chain, and in severe cases cause digestive tract cancer.
发明内容 Contents of the invention
本发明提供了一种利用率高、肥效时间长的辣椒专用缓控释肥料。 The invention provides a special slow-controlled release fertilizer for capsicum with high utilization rate and long fertilizer effect time.
本发明的目的是通过以下措施实现的: The object of the present invention is achieved by the following measures:
一种辣椒专用缓控释肥料,其特征在于包括正丁基硫代磷酸三胺(nBPT )或氢醌(HQ) 0.10%~0.15%、双氰胺(DCD)0.25%~0.30%,以质量百分比计。本发明对土壤和肥料中的营养元素具有有效的缓释效果,控制硝化反应速度,减少氮素的损失,提高氮肥的利用率,增加产量;还可降低土壤和蔬菜中硝酸盐和亚硝酸盐含量,提高农作物品质,同时减少施氮肥量过高时对土壤、地下水和空气的污染。 A special slow and controlled release fertilizer for peppers, characterized in that it contains 0.10% to 0.15% of n-butylthiophosphate triamine (nBPT) or hydroquinone (HQ), and 0.25% to 0.30% of dicyandiamide (DCD). percentage meter. The invention has an effective slow-release effect on the nutrient elements in the soil and fertilizer, controls the nitrification reaction speed, reduces the loss of nitrogen, improves the utilization rate of nitrogen fertilizer, and increases the yield; it can also reduce nitrate and nitrite in soil and vegetables content, improve the quality of crops, and at the same time reduce the pollution of soil, groundwater and air when the amount of nitrogen fertilizer is too high.
优选地,上述辣椒专用肥料,nBPT纯度≥ 97.0%、HQ纯度≥99%、DCD纯度 ≥ 99.5%。 Preferably, the above special fertilizer for peppers has nBPT purity ≥ 97.0%, HQ purity ≥ 99%, and DCD purity ≥ 99.5%.
上述辣椒专用缓控释肥料,还包括尿素24%~28%、磷酸一铵18%~20%、硫酸钾35%~38%、硫酸镁0.5%~1.0%、硼酸0.015%~0.020%、硫酸锌0.03~0.05%、菜籽粕8%~12%、鸡粪5%~8%,以质量百分比计。优选地,尿素25%、磷酸一铵18%、硫酸钾36%、硫酸镁0.7%、硼酸0.016%、硫酸锌0.044%、菜籽粕10.5%、鸡粪6.84%。与其他蔬菜相比较,辣椒需肥量大,对肥料依赖性也大,3/5的N、P和2/3的K来自肥料,只有2/5的N、P和1/3的K来自土壤。与粮食作物比较,辣椒喜钾,氮、钾的吸收比在1:1.2以上。此外,辣椒还对中微量元素有特别需求。本发明是化学肥料与绿色有机肥料的混合体,不仅能明显提高辣椒产量,改善辣椒品质,还能改良土质现状,提高土壤肥沃度,改善土壤微生物环境,促进植物根系生长,提高辣椒抗性。本发明所述肥料富含丰富的营养,既增加了土壤有机胶体,同时借助微生物的作用把许多有机物也分解转化成有机胶体,大大增加了土壤吸附表面,并且产生许多胶粘物质,使土壤颗粒胶结起来变成稳定的团粒结构,提高了土壤保水、保肥和透气的性能,以及调节土壤温度的能力。从而起到改良土壤物理、化学和生物特性,熟化土壤,培肥地力的功效。 The above special slow and controlled release fertilizer for peppers also includes urea 24%-28%, monoammonium phosphate 18%-20%, potassium sulfate 35%-38%, magnesium sulfate 0.5%-1.0%, boric acid 0.015%-0.020%, sulfuric acid Zinc 0.03~0.05%, rapeseed meal 8%~12%, chicken manure 5%~8%, calculated by mass percentage. Preferably, urea 25%, monoammonium phosphate 18%, potassium sulfate 36%, magnesium sulfate 0.7%, boric acid 0.016%, zinc sulfate 0.044%, rapeseed meal 10.5%, chicken manure 6.84%. Compared with other vegetables, pepper needs a lot of fertilizer and is also highly dependent on fertilizer. 3/5 of N, P and 2/3 of K come from fertilizers, and only 2/5 of N, P and 1/3 of K come from soil. Compared with food crops, pepper likes potassium, and the absorption ratio of nitrogen and potassium is more than 1:1.2. In addition, peppers also have special requirements for medium and trace elements. The invention is a mixture of chemical fertilizers and green organic fertilizers, which can not only significantly increase the yield of peppers and improve the quality of peppers, but also improve the status quo of soil quality, increase soil fertility, improve soil microbial environment, promote the growth of plant roots, and improve the resistance of peppers. The fertilizer of the present invention is rich in nutrients, which not only increases soil organic colloids, but also decomposes and converts many organic matter into organic colloids by virtue of the action of microorganisms, greatly increases the soil adsorption surface, and produces many sticky substances, making soil particles It is cemented into a stable aggregate structure, which improves the performance of soil water retention, fertilizer retention and air permeability, as well as the ability to regulate soil temperature. Thereby improving soil physical, chemical and biological properties, ripening soil, and fertilizing the soil.
上述辣椒专用肥料,还包括膨润土2%~3%,以质量百分比计。膨润土是以蒙脱石为主的含水粘土矿,蒙脱石含量在85%~90%。可使肥料具有强的吸湿性和膨胀性,使之具有良好的物理化学性能,能将肥料与土壤有机的结合起来,充分发挥肥料和土壤的肥力。 The above special fertilizer for pepper also includes 2% to 3% of bentonite, calculated by mass percentage. Bentonite is a hydrous clay mineral mainly composed of montmorillonite, and the content of montmorillonite is 85%~90%. It can make the fertilizer have strong hygroscopicity and expansibility, make it have good physical and chemical properties, combine the fertilizer with the soil organically, and give full play to the fertility of the fertilizer and the soil.
优选地,上述尿素采用含N≥46%等级的尿素,磷酸一铵采用含N≥10%、含P2O5≥40%等级的磷酸铵,硫酸钾采用含K2O≥50%的硫酸钾,硫酸镁采用含Mg≥9.5%的硫酸镁,硫酸锌采用含Zn≥21%的硫酸锌,硼酸采用含B≥17%的硼酸,均以重量百分含量计。 Preferably, the above urea is urea containing N≥46%, the monoammonium phosphate is ammonium phosphate containing N≥10% and P 2 O 5 ≥40%, and the potassium sulfate is sulfuric acid containing K 2 O≥50%. Potassium and magnesium sulfate adopt magnesium sulfate containing Mg≥9.5%, zinc sulfate adopts zinc sulfate containing Zn≥21%, and boric acid adopts boric acid containing B≥17%, all by weight percentage.
进一步,为了使肥料均衡的释放,达到缓释作用,优选地,上述菜籽粕颗粒≤0.4 mm、鸡粪颗粒≤0.4 mm、膨润土颗粒≤0.25 mm;更优选地,上述菜籽粕颗粒粒径为0.1~0.25 mm、鸡粪颗粒的粒径为0.1~0.25 mm、膨润土颗粒粒径为0.1 mm。 Further, in order to release the fertilizer in a balanced manner and achieve a slow release effect, preferably, the above-mentioned rapeseed meal particles are ≤0.4 mm, the chicken manure particles are ≤0.4 mm, and the bentonite particles are ≤0.25 mm; more preferably, the above-mentioned rapeseed meal particle size The particle size of chicken manure particles is 0.1-0.25 mm, and the particle size of bentonite particles is 0.1 mm.
本发明的另一目的在于提供上述辣椒专用缓控释肥料的制备方法。 Another object of the present invention is to provide a preparation method of the above-mentioned slow and controlled-release fertilizer for peppers.
上述辣椒专用缓控释肥料的制备方法,包括以下步骤: The preparation method of the above-mentioned special slow and controlled release fertilizer for peppers comprises the following steps:
a. 有机复合物的制备:将颗粒粒径均为0.3~0.4mm所述量的菜籽粕、鸡粪混合,加入1%~2%尿素,搅拌均匀,然后加入浓度为2~3mol/l的等体积的H2SO4、H3PO4和HNO3组成的快速分解剂,所述菜籽粕、鸡粪和尿素的有机混合物与所述分解剂质量比为1:0.4~0.5,充分搅拌均匀、反应,获得腐熟有机复合物; a. Preparation of organic compound: mix rapeseed meal and chicken manure with the particle size of 0.3-0.4mm, add 1%-2% urea, stir evenly, and then add 2-3mol/l A rapid decomposer composed of equal volumes of H 2 SO 4 , H 3 PO 4 and HNO 3 , the mass ratio of the organic mixture of rapeseed meal, chicken manure and urea to the decomposer is 1:0.4-0.5, fully Stir evenly and react to obtain a decomposed organic compound;
b.无机复合物的制备:取所述量的磷酸一铵、硫酸钾、硫酸镁、硼酸和硫酸锌混合,加入为所述混合物0.5~1倍量的水,在50~60℃下使其溶解,经冷却、脱水干燥,得到氮磷钾微量元素无机复合物; b. Preparation of inorganic composites: Mix the amount of monoammonium phosphate, potassium sulfate, magnesium sulfate, boric acid and zinc sulfate, add 0.5-1 times the amount of water as the mixture, and dissolve it at 50-60°C. After cooling, dehydration and drying, the nitrogen, phosphorus and potassium trace element inorganic compound is obtained;
c. 将步骤a制得的有机复合物、b步骤制得的无机复合物及余量尿素混合均匀、粉碎,加入颗粒粒径0.1~0.25mm膨润土,搅拌均匀、造粒,即得辣椒专用肥料。 c. Mix the organic compound prepared in step a, the inorganic compound prepared in step b and the remaining urea evenly, pulverize, add bentonite with a particle size of 0.1-0.25 mm, stir evenly, and granulate to obtain the special fertilizer for pepper .
有益效果Beneficial effect
1. 本发明将化肥与优质有机肥料结合起来,并能在土壤中具有缓释效果,富含辣椒生长所特需的各种营养元素,能长效的满足辣椒不同生长发育阶段对养分的需要,其中氮、磷、钾总养分≥38%,有机质≥10%,有效提高辣椒产量。 1. The present invention combines chemical fertilizers with high-quality organic fertilizers, and can have a slow-release effect in the soil. It is rich in various nutrient elements specially required for the growth of peppers, and can meet the nutrient needs of peppers in different growth and development stages for a long time. Among them, the total nutrients of nitrogen, phosphorus and potassium are more than 38%, and the organic matter is more than 10%, which can effectively increase the yield of pepper.
2. 本发明肥料利用率高,对氮肥的利用可达到59.7%~76.2%。肥效时间长,达到60~70天以上。配合辣椒的收获时间,能满足辣椒不同生长发育阶段对养分的需要,有效减少了肥料使用量与施肥次数、降低生产成本、减少环境污染。 2. The fertilizer utilization rate of the present invention is high, and the utilization rate of nitrogen fertilizer can reach 59.7%~76.2%. The fertilizer effect time is long, reaching more than 60~70 days. Cooperating with the harvest time of peppers, it can meet the nutrient needs of different growth and development stages of peppers, effectively reduce the amount of fertilizer used and the frequency of fertilization, reduce production costs, and reduce environmental pollution.
3. 本发明有效提高了辣椒产量,使用本专用缓控/释复混肥料处理后,辣椒产量为2852~3394 kg/667m2,比施常规复合肥的处理即对照(产量为2544 kg/667m2)增产12.1%~33.4%;同时提高辣椒品质,使用本专用缓控/释复混肥料处理后,辣椒Vc含量为33.45~39.44 mg/100g,比施常规复合肥的处理(Vc含量为31.80 mg/100g)增加了5.2%~24.0%;使用本专用缓控/释复混肥料处理后,辣椒氨基酸含量为967.9~1164.9 ug/100g,比施常规复合肥的处理(氨基酸含量为928.5 mg/100g)增加了4.2%~25.5%;使用本专用缓控/释复混肥料处理后,辣椒还原糖含量为0.366%~0.415%,比施常规复合肥的处理(还原性糖含量为0.359%)增加了2.0%~15.6%;使用本专用缓控/释复混肥料处理后,辣椒素含量为17.78~18.64 mg/100g,比施常规复合肥的处理(辣椒素含量为17.56 mg/100g)增加了1.23%~6.12%;使用本专用缓控/释复混肥料处理后,辣椒硝酸盐含量为229.7~274.1 mg/kg,比施常规复合肥的处理(硝酸盐含量为192.1 mg/kg)降低了19.6%~42.7%。成果果皮光洁亮丽,着色均匀,果型饱满,辣椒品质明显改善。 3. The present invention effectively improves the yield of peppers. After using this special slow-control/release compound fertilizer, the yield of peppers is 2852~3394 kg/667m 2 , which is the control compared with the treatment of conventional compound fertilizers (yield is 2544 kg/667m 2 ) Increase production by 12.1%~33.4%; improve pepper quality at the same time, after using this special slow-control/release compound fertilizer, the Vc content of pepper is 33.45~39.44 mg/100g, compared with the treatment of conventional compound fertilizer (Vc content is 31.80 mg/100g) increased by 5.2%~24.0%; after treatment with this special slow-control/release compound fertilizer, the amino acid content of pepper was 967.9~1164.9 ug/100g, which was higher than that of conventional compound fertilizer (amino acid content was 928.5 mg/100g) 100g) increased by 4.2%~25.5%; after treatment with this special slow-control/release compound fertilizer, the reducing sugar content of pepper was 0.366%~0.415%, which was higher than that of conventional compound fertilizer (reducing sugar content was 0.359%) Increased by 2.0%~15.6%; after using this special slow-control/release compound fertilizer treatment, the capsaicin content is 17.78~18.64 mg/100g, which is higher than the treatment of conventional compound fertilizer (capsaicin content is 17.56 mg/100g) After using this special slow-control/release compound fertilizer, the nitrate content of pepper was 229.7-274.1 mg/kg, which was lower than that of conventional compound fertilizer (nitrate content was 192.1 mg/kg). 19.6%~42.7%. The fruit peel is bright and clean, the coloring is uniform, the fruit shape is plump, and the quality of pepper is obviously improved.
4. 本发明原料来源广泛,产品制造工艺简单,设备投资较少。 4. The present invention has a wide range of sources of raw materials, simple product manufacturing process, and less investment in equipment.
5. 本发明对土壤中的氮素养分具有有效的缓释效果,控制硝化反应速度,减少氮素的损失,极大程度降低了土壤中硝酸盐和亚硝酸盐含量。使用本专用缓控/释复混肥料处理后,土壤中的硝态氮含量为29.7~45.1 mg/kg,低于土壤硝态氮临界标准(60 mg/kg),比施常规复合肥的处理(土壤硝态氮含量为67.1 mg/kg,含量大于临界值)减少了32.8%~55.7%;使用本专用缓控/释复混肥料处理后,土壤中的亚硝态氮含量为0.16~0.32 mg/kg,比施常规复合肥的处理(土壤亚硝态氮含量为0.59 mg/kg)减少了45.8%~72.9%。减少施氮肥量过高时对土壤、地下水和空气的污染,无公害,对环境友好。 5. The present invention has an effective slow-release effect on nitrogen nutrients in the soil, controls the nitrification reaction speed, reduces the loss of nitrogen, and greatly reduces the content of nitrate and nitrite in the soil. After using this special slow-control/release compound fertilizer, the nitrate nitrogen content in the soil is 29.7~45.1 mg/kg, which is lower than the critical standard of soil nitrate nitrogen (60 mg/kg), which is better than the treatment of conventional compound fertilizer (The soil nitrate nitrogen content is 67.1 mg/kg, the content is greater than the critical value) decreased by 32.8%~55.7%; after using this special slow-control/release compound fertilizer, the nitrite nitrogen content in the soil is 0.16~0.32 mg/kg, which was 45.8%~72.9% lower than that of conventional compound fertilizer (soil nitrite nitrogen content was 0.59 mg/kg). Reduce the pollution of soil, groundwater and air when the amount of nitrogen fertilizer is too high, no pollution, and friendly to the environment.
6. 本发明肥料在氨挥发培养过程中,大颗粒尿素的氨挥发速率为5.39 mg??kg-1??d-1,本发明肥料的氨挥发速率为4.15 mg??kg-1??d-1,第70 d测定的大颗粒尿素氨累积挥发量为72.71 mg??kg-1,辣椒专用缓释肥52.47氨累积挥发量为,比等氮量大颗粒尿素减少氨挥发24.84%。有效地降低了肥料的氨挥发速率。 6. During the ammonia volatilization cultivation process of the fertilizer of the present invention, the ammonia volatilization rate of the large granule urea is 5.39 mg ?? d -1 , the cumulative ammonia volatilization of large granular urea measured on the 70th day was 72.71 mg??kg -1 , and the cumulative ammonia volatilization of 52.47 for pepper special slow-release fertilizer was 24.84% less than that of equal nitrogen large granular urea. Effectively reduces the ammonia volatilization rate of fertilizers.
具体实施方式 Detailed ways
下面通过实施例对本发明进行具体的描述,有必要在此指出的是以下实施例只用于对本发明进行进一步说明,不能理解为对本发明保护范围的限制,该领域技术人员可以根据上述本发明内容对本发明作出一些非本质的改进和调整。 The present invention is specifically described below through the examples, it is necessary to point out that the following examples are only used to further illustrate the present invention, and can not be interpreted as limiting the protection scope of the present invention, those skilled in the art can according to the content of the present invention above Some non-essential improvements and adjustments are made to the present invention.
实施例1Example 1
一种辣椒缓控/释复混肥料的制备方法,以重量百分含量计的尿素24%~28%、磷酸一铵18%~20%、硫酸钾35%~38%、硫酸镁0.5%~1.0%、硼酸0.015%~0.020%、硫酸锌0.03~0.05%、菜籽粕8%~12%、鸡粪5%~8%、膨润土2%~3%、正丁基硫代磷酸三胺或氢醌 0.10%~0.15%、双氰胺0.25%~0.30%为原料,按以下步骤进行: A preparation method of pepper slow-control/release compound fertilizer, comprising 24% to 28% of urea, 18% to 20% of monoammonium phosphate, 35% to 38% of potassium sulfate, and 0.5% to magnesium sulfate in weight percent 1.0%, boric acid 0.015%~0.020%, zinc sulfate 0.03~0.05%, rapeseed meal 8%~12%, chicken manure 5%~8%, bentonite 2%~3%, n-butyl triamine thiophosphate or Hydroquinone 0.10% ~ 0.15%, dicyandiamide 0.25% ~ 0.30% as raw materials, according to the following steps:
a. 有机复合物的制备:将颗粒粒径均为0.3~0.4mm所述量的菜籽粕、鸡粪混合,加入1%~2%尿素,搅拌均匀,然后加入浓度为2~3mol/l的等体积的H2SO4、H3PO4和HNO3组成的快速分解剂,所述菜籽粕、鸡粪和尿素的有机混合物与所述分解剂质量比为1:0.4~0.5,充分搅拌均匀、反应,获得腐熟有机复合物; a. Preparation of organic compound: mix rapeseed meal and chicken manure with the particle size of 0.3-0.4mm, add 1%-2% urea, stir evenly, and then add 2-3mol/l A rapid decomposer composed of equal volumes of H 2 SO 4 , H 3 PO 4 and HNO 3 , the mass ratio of the organic mixture of rapeseed meal, chicken manure and urea to the decomposer is 1:0.4-0.5, fully Stir evenly and react to obtain a decomposed organic compound;
b.无机复合物的制备:取所述量的磷酸一铵、硫酸钾、硫酸镁、硼酸和硫酸锌混合,加入为所述混合物0.5~1倍量的水,在50~60℃下使其溶解,经冷却、脱水干燥,得到氮磷钾微量元素无机复合物; b. Preparation of inorganic composites: Mix the amount of monoammonium phosphate, potassium sulfate, magnesium sulfate, boric acid and zinc sulfate, add 0.5-1 times the amount of water as the mixture, and dissolve it at 50-60°C. After cooling, dehydration and drying, the nitrogen, phosphorus and potassium trace element inorganic compound is obtained;
c. 将步骤a制得的有机复合物、b步骤制得的无机复合物及余量尿素混合均匀、粉碎,加入颗粒粒径0.1~0.25mm膨润土,搅拌均匀、造粒,即得辣椒专用肥料。 c. Mix the organic compound prepared in step a, the inorganic compound prepared in step b and the remaining urea evenly, pulverize, add bentonite with a particle size of 0.1-0.25 mm, stir evenly, and granulate to obtain the special fertilizer for pepper .
使用本专用缓控/释复混肥料处理后,辣椒产量为2852~3394 kg/667m2,比施常规复合肥的处理即对照(产量为2544 kg/667m2)增产12.1%~33.4%。辣椒Vc含量为33.45~39.44 mg/100g,比施常规复合肥的处理(Vc含量为31.80 mg/100g)增加了5.2%~24.0%;使用本专用缓控/释复混肥料处理后,辣椒氨基酸含量为967.9~1164.9 ug/100g,比施常规复合肥的处理(氨基酸含量为928.5 mg/100g)增加了4.2%~25.5%;使用本专用缓控/释复混肥料处理后,辣椒还原糖含量为0.366%~0.415%,比施常规复合肥的处理(还原性糖含量为0.359%)增加了2.0%~15.6%;使用本专用缓控/释复混肥料处理后,辣椒素含量为17.78~18.64 mg/100g,比施常规复合肥的处理(辣椒素含量为17.56 mg/100g)增加了1.23%~6.12%;使用本专用缓控/释复混肥料处理后,辣椒硝酸盐含量为229.7~274.1 mg/kg,比施常规复合肥的处理(硝酸盐含量为192.1 mg/kg)降低了19.6%~42.7%。成果果皮光洁亮丽,着色均匀,果型饱满,辣椒品质明显改善。 After using this special slow-control/release compound fertilizer, the yield of pepper was 2852~3394 kg/667m 2 , which was 12.1%~33.4% higher than that of the control (yield 2544 kg/667m 2 ) with conventional compound fertilizer. The Vc content of pepper is 33.45~39.44 mg/100g, which is 5.2%~24.0% higher than that of conventional compound fertilizer (Vc content is 31.80 mg/100g); The content is 967.9~1164.9 ug/100g, which is 4.2%~25.5% higher than that of conventional compound fertilizer (the amino acid content is 928.5 mg/100g); after using this special slow-control/release compound fertilizer, the reducing sugar content of pepper It is 0.366%~0.415%, which is 2.0%~15.6% higher than that of conventional compound fertilizer (reducing sugar content is 0.359%); after using this special slow-control/release compound fertilizer, the capsaicin content is 17.78~ 18.64 mg/100g, which is 1.23%~6.12% higher than the treatment of conventional compound fertilizer (capsaicin content is 17.56 mg/100g); after using this special slow-control/release compound fertilizer, the nitrate content of pepper is 229.7~ 274.1 mg/kg, which is 19.6%~42.7% lower than that of conventional compound fertilizer (nitrate content is 192.1 mg/kg). The fruit peel is bright and clean, the coloring is uniform, the fruit shape is plump, and the quality of pepper is obviously improved.
使用本专用缓控/释复混肥料处理后,土壤中的硝态氮含量为29.7~45.1 mg/kg,低于土壤硝态氮临界标准(60 mg/kg),比施常规复合肥的处理(土壤硝态氮含量为67.1 mg/kg,含量大于临界值)减少了32.8%~55.7%;使用本专用缓控/释复混肥料处理后,土壤中的亚硝态氮含量为0.16~0.32 mg/kg,比施常规复合肥的处理(土壤亚硝态氮含量为0.59 mg/kg)减少了45.8%~72.9%。 After using this special slow-control/release compound fertilizer, the nitrate nitrogen content in the soil is 29.7~45.1 mg/kg, which is lower than the critical standard of soil nitrate nitrogen (60 mg/kg), which is better than the treatment of conventional compound fertilizer (The soil nitrate nitrogen content is 67.1 mg/kg, the content is greater than the critical value) decreased by 32.8%~55.7%; after using this special slow-control/release compound fertilizer, the nitrite nitrogen content in the soil is 0.16~0.32 mg/kg, which was 45.8%~72.9% lower than that of conventional compound fertilizer (soil nitrite nitrogen content was 0.59 mg/kg).
实施例2Example 2
一种辣椒缓控/释复混肥料的制备方法,以重量百分含量计的尿素28%、磷酸铵18%、硫酸钾35%、硫酸镁0.93%、硼酸0.02%、硫酸锌0.05%、菜籽粕10%、鸡粪5.05%、膨润土2.5%、氢醌0.15%、双氰胺0.30%为原料,按以下步骤进行: A preparation method of capsicum slow-control/release compound fertilizer, comprising 28% urea, 18% ammonium phosphate, 35% potassium sulfate, 0.93% magnesium sulfate, 0.02% boric acid, 0.05% zinc sulfate, vegetable 10% of seed meal, 5.05% of chicken manure, 2.5% of bentonite, 0.15% of hydroquinone, and 0.30% of dicyandiamide are used as raw materials, and the following steps are carried out:
a. 有机复合物的制备:将颗粒粒径均为0.1~0.25 mm所述量的菜籽粕、鸡粪、豆粕混合,加入1%~2%尿素,搅拌均匀,然后加入浓度为3mol/l的等体积的H2SO4、H3PO4和HNO3组成的快速分解剂,所述菜籽粕、鸡粪、豆粕和尿素的有机混合物与所述分解剂质量比为1:0.5,充分搅拌均匀,在50℃~60℃条件下作用72小时,获得腐熟有机复合物; a. Preparation of organic compound: mix rapeseed meal, chicken manure and soybean meal with particle size of 0.1-0.25 mm, add 1%-2% urea, stir evenly, and then add urea at a concentration of 3mol/l A rapid decomposer composed of equal volumes of H 2 SO 4 , H 3 PO 4 and HNO 3 , the mass ratio of the organic mixture of rapeseed meal, chicken manure, soybean meal and urea to the decomposer is 1:0.5, fully Stir evenly and act for 72 hours at 50°C-60°C to obtain a decomposed organic compound;
b.无机复合物的制备:取所述量的磷酸铵、硫酸钾、硫酸镁、硼酸和硫酸锌混合,加入为所述混合物1倍量的水,在50~60℃下使其溶解,经冷却、脱水干燥,得到氮磷钾微量元素无机复合物; b. Preparation of inorganic composites: Mix the amount of ammonium phosphate, potassium sulfate, magnesium sulfate, boric acid and zinc sulfate, add water that is twice the amount of the mixture, dissolve it at 50-60°C, cool, Dehydration and drying to obtain nitrogen, phosphorus and potassium trace element inorganic complexes;
c. 将步骤a制得的有机复合物、b步骤制得的无机复合物及余量尿素混合均匀、粉碎,加入颗粒粒径0.1mm膨润土,搅拌均匀、造粒,即得辣椒专用肥料。 c. Mix the organic compound prepared in step a, the inorganic compound prepared in step b and the remaining urea evenly, pulverize, add bentonite with a particle size of 0.1mm, stir evenly, and granulate to obtain the special fertilizer for pepper.
施用专用缓控/释复混肥料的辣椒产量为2877.2~3264.7 kg/667m2,增产13.10%~28.33%;施用专用缓控/释复混肥料的辣椒维生素C含量为34.31~37.73 mg/100g,提高了7.90%~18.65%;施用专用缓控/释复混肥料的辣椒氨基酸含量为972.2~1095.9 mg/100g,提高了4.71%~18.03%;施用专用缓控/释复混肥料的辣椒还原性糖含量为0.367%~0.403%,提高了2.11%~12.21%;使用本专用缓控/释复混肥料处理后,辣椒素含量为18.12~18.46 mg/100g,较对照提高了3.19%~5.12%;使用本专用缓控/释复混肥料处理后,辣椒果实内硝酸盐含量为232.9~264.0 mg/kg,较对照减少了21.2%~37.4%。成果果皮光洁亮丽,着色均匀,果型饱满。氮肥利用率为59.7%~68.3%,肥效时间达到70天以上,土壤残余硝酸盐和亚硝酸盐分别为31.3~43.8 mg/kg和0.23~0.32 mg/kg。 The yield of peppers applied with special slow-control/release compound fertilizers was 2877.2~3264.7 kg/667m 2 , an increase of 13.10%~28.33%; the vitamin C content of peppers applied with special slow-control/release compound fertilizers was 34.31~37.73 mg/100g, increased by 7.90%~18.65%; the amino acid content of peppers applied with special slow-control/release compound fertilizers was 972.2~1095.9 mg/100g, an increase of 4.71%~18.03%; The sugar content was 0.367%~0.403%, an increase of 2.11%~12.21%; after using this special slow-control/release compound fertilizer, the capsaicin content was 18.12~18.46 mg/100g, an increase of 3.19%~5.12% compared with the control ; After being treated with this special slow-control/release compound fertilizer, the nitrate content in pepper fruit was 232.9-264.0 mg/kg, which was 21.2%-37.4% lower than that of the control. The fruit peel is bright and clean, the coloring is even, and the fruit shape is plump. The utilization rate of nitrogen fertilizer was 59.7%~68.3%, the fertilizer effect time reached more than 70 days, and the residual nitrate and nitrite in the soil were 31.3~43.8 mg/kg and 0.23~0.32 mg/kg, respectively.
实施例3Example 3
一种辣椒缓控/释复混肥料,以重量百分含量计的尿素24%、磷酸一铵20%、硫酸钾38%、硫酸镁0.5%、硼酸0.015%、硫酸锌0.03%、菜籽粕9%、鸡粪6.105%、膨润土2%,正丁基硫代磷酸三胺0.10%、双氰胺0.25%为原料,按实施例1制备方法制得。 A pepper slow-control/release compound fertilizer, comprising 24% urea, 20% monoammonium phosphate, 38% potassium sulfate, 0.5% magnesium sulfate, 0.015% boric acid, 0.03% zinc sulfate, and rapeseed meal in weight percent 9%, chicken manure 6.105%, bentonite 2%, n-butyl triamine thiophosphate 0.10%, dicyandiamide 0.25% are raw materials, prepared by the preparation method of Example 1.
施用专用缓控/释复混肥料的辣椒产量为2879.3~3222.6 kg/667m2,增产13.18%~27.11%;施用专用缓控/释复混肥料的辣椒维生素C含量为34.31~35.03 mg/100g,较对照提高了7.90%~10.18%;施用专用缓控/释复混肥料的辣椒氨基酸含量为967.5~1071.6 mg/100g,较对照提高了4.2%~15.41%;施用专用缓控/释复混肥料的辣椒还原性糖含量为0.380%~0.397%,较对照提高了5.8%~10.5%;使用本专用缓控/释复混肥料处理后,辣椒素含量为17.94~18.31 mg/100g,较对照提高了2.15%~4.27%;使用本专用缓控/释复混肥料处理后,辣椒果实内硝酸盐含量为229.2~266.8 mg/kg,较对照减少了19.3%~38.9%。成果果皮光洁亮丽,着色均匀,果型饱满。氮肥利用率为59.7%~66.4%,肥效时间达到70天以上,土壤残余硝酸盐和亚硝酸盐分别为30.4~42.8 mg/kg和0.19~0.27 mg/kg。 The yield of peppers applied with special slow-control/release compound fertilizers was 2879.3~3222.6 kg/667m 2 , an increase of 13.18%~27.11%; the vitamin C content of peppers applied with special slow-control/release compound fertilizers was 34.31~35.03 mg/100g, Compared with the control, it increased by 7.90%~10.18%; the amino acid content of peppers using the special slow-control/release compound fertilizer was 967.5~1071.6 mg/100g, which was 4.2%~15.41% higher than the control; the application of the special slow-control/release compound fertilizer The reducing sugar content of capsicum is 0.380%~0.397%, which is 5.8%~10.5% higher than that of the control; after being treated with this special slow-control/release compound fertilizer, the capsaicin content is 17.94~18.31 mg/100g, which is higher than that of the control After using this special slow-control/release compound fertilizer, the nitrate content in pepper fruit was 229.2-266.8 mg/kg, which was 19.3%-38.9% lower than that of the control. The fruit peel is bright and clean, the coloring is even, and the fruit shape is plump. The utilization rate of nitrogen fertilizer was 59.7%~66.4%, the fertilizer effect time reached more than 70 days, and the residual nitrate and nitrite in the soil were 30.4~42.8 mg/kg and 0.19~0.27 mg/kg, respectively.
实施例4Example 4
一种辣椒缓控/释复混肥料,以重量百分含量计的尿素28%、磷酸一铵18%、硫酸钾35%、硫酸镁1%、硼酸0.02%、硫酸锌0.05%、菜籽粕8%、鸡粪6.48%、膨润土3%、氢醌0.15%、双氰胺0.30%为原料,按实施例1制备方法制得。 A pepper slow-control/release compound fertilizer, comprising 28% urea, 18% monoammonium phosphate, 35% potassium sulfate, 1% magnesium sulfate, 0.02% boric acid, 0.05% zinc sulfate, and rapeseed meal in weight percent 8%, chicken manure 6.48%, bentonite 3%, hydroquinone 0.15%, dicyandiamide 0.30% are raw materials, prepared by the preparation method of Example 1.
施用专用缓控/释复混肥料的辣椒产量为2906.1~3154.8 kg/667m2,增产14.23%~24.01%;施用专用缓控/释复混肥料的辣椒维生素C含量为34.46~35.84 mg/100g,提高了8.38%~12.69%;施用专用缓控/释复混肥料的辣椒氨基酸含量为967.7~1092.3 mg/100g,提高了4.22%~17.64%;施用专用缓控/释复混肥料的辣椒还原性糖含量为0.375%~0.402%,提高了4.54%~11.78%;使用本专用缓控/释复混肥料处理后,辣椒素含量为17.78~18.12 mg/100g,较对照提高了提高了1.23%~3.18%;使用本专用缓控/释复混肥料处理后,辣椒果实内硝酸盐含量为229.8~256.9 mg/kg,较对照减少了19.6%~33.7%。成果果皮光洁亮丽,着色均匀,果型饱满。氮肥利用率为63.4%~76.2%,肥效时间达到70天以上,土壤残余硝酸盐和亚硝酸盐分别为29.7~37.2 mg/kg和0.16~0.29 mg/kg。 The yield of peppers applied with special slow-control/release compound fertilizers was 2906.1~3154.8 kg/667m 2 , an increase of 14.23%~24.01%; the vitamin C content of peppers applied with special slow-control/release compound fertilizers was 34.46~35.84 mg/100g, Increased by 8.38%~12.69%; the amino acid content of peppers using special slow-control/release compound fertilizers was 967.7~1092.3 mg/100g, an increase of 4.22%~17.64%; the reduction of peppers using special slow-control/release compound fertilizers The sugar content is 0.375%~0.402%, an increase of 4.54%~11.78%; after using this special slow-control/release compound fertilizer, the capsaicin content is 17.78~18.12 mg/100g, which is an increase of 1.23%~ 3.18%; after being treated with this special slow-control/release compound fertilizer, the nitrate content in pepper fruit was 229.8-256.9 mg/kg, which was 19.6%-33.7% lower than that of the control. The fruit peel is bright and clean, the coloring is even, and the fruit shape is plump. The utilization rate of nitrogen fertilizer was 63.4%~76.2%, and the fertilizer effect time reached more than 70 days. The residual nitrate and nitrite in the soil were 29.7~37.2 mg/kg and 0.16~0.29 mg/kg, respectively.
实施例5Example 5
一种辣椒缓控/释复混肥料,以重量百分含量计的尿素25%、磷酸一铵18%、硫酸钾36%、硫酸镁0.7%、硼酸0.016%、硫酸锌0.044%、菜籽粕10.5%、鸡粪6.84%、膨润土2.5%、氢醌0.12%、双氰胺0.28%为原料,按实施例1制备方法制得。 A pepper slow-control/release compound fertilizer, comprising 25% urea, 18% monoammonium phosphate, 36% potassium sulfate, 0.7% magnesium sulfate, 0.016% boric acid, 0.044% zinc sulfate, and rapeseed meal in weight percent 10.5%, chicken manure 6.84%, bentonite 2.5%, hydroquinone 0.12%, dicyandiamide 0.28% are raw materials, prepared by the preparation method of Example 1.
施用专用缓控/释复混肥料的辣椒产量为2929.2~3137.4 kg/667m2,增产15.14%~23.33%;施用专用缓控/释复混肥料的辣椒维生素C含量为34.47~39.42 mg/100g,提高了8.41%~24.0%;施用专用缓控/释复混肥料的辣椒氨基酸含量为976.0~1165.4 mg/100g,提高了5.12%~25.50%;施用专用缓控/释复混肥料的辣椒还原性糖含量为0.380%~0.412%,提高了5.89%~14.65%;使用本专用缓控/释复混肥料处理后,辣椒素含量为17.95~18.49 mg/100g,较对照提高了2.21%~5.30%;使用本专用缓控/释复混肥料处理后,辣椒果实内硝酸盐含量为225.2~256.8 mg/kg,较对照减少了17.22%~33.59%。成果果皮光洁亮丽,着色均匀,果型饱满。氮肥利用率为59.9%~74.5%,肥效时间达到70天以上,土壤残余硝酸盐和亚硝酸盐分别为32.2~40.9 mg/kg和0.17~0.31 mg/kg。 The yield of peppers applied with special slow-control/release compound fertilizers was 2929.2~3137.4 kg/667m 2 , an increase of 15.14%~23.33%; the vitamin C content of peppers applied with special slow-control/release compound fertilizers was 34.47~39.42 mg/100g, Increased by 8.41%~24.0%; the amino acid content of peppers using special slow-control/release compound fertilizers was 976.0~1165.4 mg/100g, an increase of 5.12%~25.50%; the reduction of peppers using special slow-control/release compound fertilizers The sugar content is 0.380%~0.412%, an increase of 5.89%~14.65%; after using this special slow-control/release compound fertilizer, the capsaicin content is 17.95~18.49 mg/100g, an increase of 2.21%~5.30% compared with the control ; After being treated with this special slow-control/release compound fertilizer, the nitrate content in pepper fruit was 225.2-256.8 mg/kg, which was 17.22%-33.59% lower than that of the control. The fruit peel is bright and clean, the coloring is even, and the fruit shape is plump. The utilization rate of nitrogen fertilizer was 59.9%~74.5%, the fertilizer effect time reached more than 70 days, and the residual nitrate and nitrite in the soil were 32.2~40.9 mg/kg and 0.17~0.31 mg/kg, respectively.
实施例6Example 6
一种辣椒缓控/释复混肥料,以重量百分含量计的尿素25%、磷酸铵19%、硫酸钾36%、硫酸镁0.8%、硼酸0.018%、硫酸锌0.045%、菜籽粕8.117%、鸡粪8%、膨润土2.6%、正丁基硫代磷酸三胺0.14%、双氰胺0.28%为原料,按实施例1制备方法制得。 A slow-control/release compound fertilizer for peppers, comprising 25% urea, 19% ammonium phosphate, 36% potassium sulfate, 0.8% magnesium sulfate, 0.018% boric acid, 0.045% zinc sulfate, and 8.117% rapeseed meal in weight percent %, chicken manure 8%, bentonite 2.6%, n-butyl triamine thiophosphate 0.14%, dicyandiamide 0.28% as raw materials, prepared by the preparation method of Example 1.
施用专用缓控/释复混肥料的辣椒产量为2977.3~3112.0 kg/667m2,增产13.10%~22.34%;施用专用缓控/释复混肥料的辣椒维生素C含量为34.16~36.28mg/100g,提高了7.43%~14.11%;施用专用缓控/释复混肥料的辣椒氨基酸含量为973.2~1083.6 mg/100g,提高了4.81%~16.71%;施用专用缓控/释复混肥料的辣椒还原性糖含量为0.373%~0.394%,提高了3.79%~9.64%;使用本专用缓控/释复混肥料处理后,辣椒素含量为17.88~18.45 mg/100g,较对照提高了1.82%~5.07%;使用本专用缓控/释复混肥料处理后,辣椒果实内硝酸盐含量为236.5~256.4 mg/kg,较对照减少了23.1%~33.5%。成果果皮光洁亮丽,着色均匀,果型饱满。氮肥利用率为61.3%~70.1%,肥效时间达到70天以上,土壤残余硝酸盐和亚硝酸盐分别为29.8~40.5 mg/kg和0.21~0.30 mg/kg。 The yield of peppers applied with special slow-control/release compound fertilizers was 2977.3~3112.0 kg/667m 2 , an increase of 13.10%~22.34%; the vitamin C content of peppers applied with special slow-control/release compound fertilizers was 34.16~36.28mg/100g, Increased by 7.43%~14.11%; the amino acid content of peppers using special slow-control/release compound fertilizers was 973.2~1083.6 mg/100g, an increase of 4.81%~16.71%; the reduction of peppers using special slow-control/release compound fertilizers The sugar content is 0.373%~0.394%, an increase of 3.79%~9.64%; after using this special slow-control/release compound fertilizer, the capsaicin content is 17.88~18.45 mg/100g, an increase of 1.82%~5.07% compared with the control ; After being treated with this special slow-control/release compound fertilizer, the nitrate content in the pepper fruit was 236.5-256.4 mg/kg, which was 23.1%-33.5% lower than that of the control. The fruit peel is bright and clean, the coloring is even, and the fruit shape is plump. The utilization rate of nitrogen fertilizer was 61.3%~70.1%, the fertilizer effect time reached more than 70 days, and the residual nitrate and nitrite in the soil were 29.8~40.5 mg/kg and 0.21~0.30 mg/kg respectively.
本发明的对照的肥料是常规的辣椒复合肥。 The fertilizer of contrast of the present invention is conventional capsicum compound fertilizer.
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CN108821921A (en) * | 2018-08-27 | 2018-11-16 | 湖南农业大学 | A kind of capsicum specially imitates slow-release compound fertilizer and preparation method thereof |
CN115745702A (en) * | 2022-11-14 | 2023-03-07 | 衡阳县沛科生态科技有限责任公司 | Formula and preparation of special biological organic fertilizer for Huang Gongjiao |
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