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CN103469231A - Metal surface cleaning agent - Google Patents

Metal surface cleaning agent Download PDF

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Publication number
CN103469231A
CN103469231A CN2013104098381A CN201310409838A CN103469231A CN 103469231 A CN103469231 A CN 103469231A CN 2013104098381 A CN2013104098381 A CN 2013104098381A CN 201310409838 A CN201310409838 A CN 201310409838A CN 103469231 A CN103469231 A CN 103469231A
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CN
China
Prior art keywords
cleaning agent
parts
metal surface
surface cleaning
sodium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2013104098381A
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Chinese (zh)
Inventor
王刚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Taicang Weiguan Electromechanical Co Ltd
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Taicang Weiguan Electromechanical Co Ltd
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Priority to CN2013104098381A priority Critical patent/CN103469231A/en
Publication of CN103469231A publication Critical patent/CN103469231A/en
Pending legal-status Critical Current

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  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Abstract

The invention provides a metal surface cleaning agent. A metal material consists of the following components in parts by mass: 20-25 parts of an anionic surfactant, 35-40 parts of a nonionic surfactant, 3-5 parts of an inorganic base, 4-6 parts of a washing aid, 0.5-1.0 part of a corrosion inhibitor, 10-20 parts of ethanol and the balance of deionized water, wherein the anionic surfactant is at least one of lauryl polyoxyethylene ether sodium sulfate, lauryl sodium sulfate or alkyl aryl sodium sulfonate, and the nonionic surfactant is C8-C14 secondary alcohol alkoxylate. The metal surface cleaning agent provided by the invention does not contain phosphorus or APEO (alkylphenol ethoxylate) type surfactants, and an environment-friendly surfactant is adopted to ensure that the cleaning agent is generally environment-friendly and harmless, has strong dirt-removing power at a low temperature and normal temperature; therefore, the cleaning agent is a good metal surface cleaning agent.

Description

A kind of metal surface cleaning agent
Technical field
The present invention relates to a kind of metal surface cleaning agent.
Background technology
Metal surface cleaning agent is mainly used in the cleaning in component production, and in the surface treatments such as application, plating, degreasing is important technological process, and the degreasing degree on metallic article surface will directly have influence on the subsequent disposal quality of workpiece.Usually can add some phosphorous assistants and APEO class tensio-active agent in metal surface cleaning agent, these materials have very large harm to environment, therefore, need the metal surface cleaning agent of some environmental protection of exploitation.
Summary of the invention
goal of the invention: purpose of the present invention just is to provide a kind of metal surface cleaning agent.
technical scheme:for achieving the above object, the present invention has taked following technical scheme:
A kind of metal surface cleaning agent is characterized in that: described metallic substance is comprised of by mass parts following component:
Anion surfactant: 20-25 part;
Nonionogenic tenside: 35-40 part;
Mineral alkali: 3-5 part;
Washing assistant: 4-6 part;
Inhibiter: 0.5-1.0 part;
Ethanol: 10-20 part;
Deionized water: surplus;
Described anion surfactant is at least one in alkylpolyoxyethylene sodium sulfate, sodium lauryl sulphate or Seconary Alkane Sulphonate Sodium; Such tensio-active agent has good wetting, infiltration, emulsification, dispersion and soil removability in water, and alkali resistance is higher, and biodegradability is good, containing carcinogenic arylamine and heavy metal ion, not harmless to HUMAN HEALTH.
Described nonionogenic tenside is: C 8-C 14the secondary alcohol Soxylat A 25-7.The cold washing performance that such tensio-active agent tool is good and solubilising, dispersion, wettability, viscosity is low, and congealing point is low, almost the gel-free phenomenon, have the good big gun performance that disappears, and has good biological degradability, pungency to skin is low, is a kind of environmental protection, non-harmful nonionogenic tenside.
  
Described washing assistant is EDETATE SODIUM.
Described mineral alkali is at least one in sodium carbonate, salt of wormwood, sodium bicarbonate.The carbonate mineral alkali is compared to common sodium hydroxide, potassium hydroxide, and alkalescence is comparatively gentle, little to the pungency of skin.
Described inhibiter is lauryl amine.
beneficial effect:adopt the present invention of technique scheme to have the following advantages:
Metal surface cleaning agent of the present invention is not phosphorous, also not containing APEO class tensio-active agent, adopting the tensio-active agent of environment-friendly type to make clean-out system generally speaking green, environmentally friendly, have stronger soil removability under low temperature, normal temperature, is a kind of good metal surface cleaning agent.
Embodiment
Below by specific embodiment, the present invention is further set forth.
Embodiment 1:
According to a kind of metal surface cleaning agent of the present embodiment, described metal surface cleaning agent comprises following composition by weight: anion surfactant: 20 parts; Nonionogenic tenside: 35 parts; Mineral alkali sodium carbonate: 3 parts; Washing assistant EDETATE SODIUM: 4 parts; Inhibiter lauryl amine: 0.5 part; Ethanol: 15 parts; Deionized water: surplus;
Wherein anion surfactant is alkylpolyoxyethylene sodium sulfate, and nonionogenic tenside is C 8the secondary alcohol Soxylat A 25-7.
The preparation method of this metal surface cleaning agent is as follows:
By above-mentioned each component proportioning, add successively anion surfactant, nonionogenic tenside, washing assistant, inhibiter, ethanol and mineral alkali in deionized water, stir and get final product under normal temperature.
Embodiment 2:
According to a kind of metal surface cleaning agent of the present embodiment, described metal surface cleaning agent comprises following composition by weight: anion surfactant: 25 parts; Nonionogenic tenside: 35 parts; Mineral alkali salt of wormwood: 4 parts; Washing assistant EDETATE SODIUM: 5 parts; Inhibiter lauryl amine: 0.8 part; Ethanol: 10 parts; Deionized water: surplus;
Wherein anion surfactant is sodium lauryl sulphate, and nonionogenic tenside is C 9the secondary alcohol Soxylat A 25-7.
The preparation method of this metal surface cleaning agent is as follows:
By above-mentioned each component proportioning, add successively anion surfactant, nonionogenic tenside, washing assistant, inhibiter, ethanol and mineral alkali in deionized water, stir and get final product under normal temperature.
Embodiment 3:
According to a kind of metal surface cleaning agent of the present embodiment, described metal surface cleaning agent comprises following composition by weight: anion surfactant: 25 parts; Nonionogenic tenside: 40 parts; Mineral alkali sodium bicarbonate: 5 parts; Washing assistant EDETATE SODIUM: 6 parts; Inhibiter lauryl amine: 1.0 parts; Ethanol: 10 parts; Deionized water: surplus;
Wherein anion surfactant is Seconary Alkane Sulphonate Sodium, and nonionogenic tenside is C 10the secondary alcohol Soxylat A 25-7.
The preparation method of this metal surface cleaning agent is as follows:
By above-mentioned each component proportioning, add successively anion surfactant, nonionogenic tenside, washing assistant, inhibiter, ethanol and mineral alkali in deionized water, stir and get final product under normal temperature.
Embodiment 4:
According to a kind of metal surface cleaning agent of the present embodiment, described metal surface cleaning agent comprises following composition by weight: anion surfactant: 25 parts; Nonionogenic tenside: 35 parts; Mineral alkali sodium carbonate: 6 parts; Washing assistant EDETATE SODIUM: 5 parts; Inhibiter lauryl amine: 0.7 part; Ethanol: 15 parts; Deionized water: surplus;
Wherein anion surfactant is alkylpolyoxyethylene sodium sulfate, and nonionogenic tenside is C 11the secondary alcohol Soxylat A 25-7.
The preparation method of this metal surface cleaning agent is as follows:
By above-mentioned each component proportioning, add successively anion surfactant, nonionogenic tenside, washing assistant, inhibiter, ethanol and mineral alkali in deionized water, stir and get final product under normal temperature.
Embodiment 5:
According to a kind of metal surface cleaning agent of the present embodiment, described metal surface cleaning agent comprises following composition by weight: anion surfactant: 20 parts; Nonionogenic tenside: 35 parts; Mineral alkali salt of wormwood: 5 parts; Washing assistant EDETATE SODIUM: 6 parts; Inhibiter lauryl amine: 1.0 parts; Ethanol: 20 parts; Deionized water: surplus;
Wherein anion surfactant is alkylpolyoxyethylene sodium sulfate, and nonionogenic tenside is C 12the secondary alcohol Soxylat A 25-7.
The preparation method of this metal surface cleaning agent is as follows:
By above-mentioned each component proportioning, add successively anion surfactant, nonionogenic tenside, washing assistant, inhibiter, ethanol and mineral alkali in deionized water, stir and get final product under normal temperature.
Embodiment 6:
According to a kind of metal surface cleaning agent of the present embodiment, described metal surface cleaning agent comprises following composition by weight: anion surfactant: 20 parts; Nonionogenic tenside: 40 parts; Mineral alkali sodium bicarbonate: 5 parts; Washing assistant EDETATE SODIUM: 5 parts; Inhibiter lauryl amine: 1.0 parts; Ethanol: 10 parts; Deionized water: surplus;
Wherein anion surfactant is Seconary Alkane Sulphonate Sodium, and nonionogenic tenside is C 13the secondary alcohol Soxylat A 25-7.
The preparation method of this metal surface cleaning agent is as follows:
By above-mentioned each component proportioning, add successively anion surfactant, nonionogenic tenside, washing assistant, inhibiter, ethanol and mineral alkali in deionized water, stir and get final product under normal temperature.
Embodiment 7:
According to a kind of metal surface cleaning agent of the present embodiment, described metal surface cleaning agent comprises following composition by weight: anion surfactant alkylpolyoxyethylene sodium sulfate: 10 parts; Anion surfactant Seconary Alkane Sulphonate Sodium: 15 parts; Nonionogenic tenside: 35 parts; Mineral alkali sodium carbonate: 4 parts; Washing assistant EDETATE SODIUM: 5 parts; Inhibiter lauryl amine: 0.8 part; Ethanol: 10 parts; Deionized water: surplus;
Wherein nonionogenic tenside is C 14the secondary alcohol Soxylat A 25-7.
The preparation method of this metal surface cleaning agent is as follows:
By above-mentioned each component proportioning, add successively anion surfactant, nonionogenic tenside, washing assistant, inhibiter, ethanol and mineral alkali in deionized water, stir and get final product under normal temperature.
Embodiment 8:
According to a kind of metal surface cleaning agent of the present embodiment, described metal surface cleaning agent comprises following composition by weight: anion surfactant alkylpolyoxyethylene sodium sulfate: 10 parts; Anionic: 15 parts; Nonionogenic tenside: 40 parts; Mineral alkali sodium carbonate: 4 parts; Washing assistant EDETATE SODIUM: 5 parts; Inhibiter lauryl amine: 0.8 part; Ethanol: 10 parts; Deionized water: surplus;
Wherein nonionogenic tenside is C 12the secondary alcohol Soxylat A 25-7.
The preparation method of this metal surface cleaning agent is as follows:
By above-mentioned each component proportioning, add successively anion surfactant, nonionogenic tenside, washing assistant, inhibiter, ethanol and mineral alkali in deionized water, stir and get final product under normal temperature.
Embodiment 9:
According to a kind of metal surface cleaning agent of the present embodiment, described metal surface cleaning agent comprises following composition by weight: the anion surfactant Seconary Alkane Sulphonate Sodium: 10 parts; Anionic: 10 parts; Nonionogenic tenside: 35 parts; Mineral alkali sodium carbonate: 4 parts; Washing assistant EDETATE SODIUM: 5 parts; Inhibiter lauryl amine: 0.8 part; Ethanol: 10 parts; Deionized water: surplus;
Wherein nonionogenic tenside is C 12the secondary alcohol Soxylat A 25-7.
The preparation method of this metal surface cleaning agent is as follows:
By above-mentioned each component proportioning, add successively anion surfactant, nonionogenic tenside, washing assistant, inhibiter, ethanol and mineral alkali in deionized water, stir and get final product under normal temperature.
Metal surface cleaning agent of the present invention needs dilute with water 10-20 doubly in use, and the metallic element that then will clean is immersed in room temperature in washing lotion, also can be heated to 40-50 ℃, soak 30-50 minute, then clean, wash once again after cleaning, finally dry and get final product.
Metal surface cleaning agent of the present invention replaces APEO class tensio-active agent in the past with the tensio-active agent of environment-friendly type, and the washing assistant of use is also phosphorus-free adjuvant, and metal surface cleaning agent environmental protection of the present invention like this, pollution-free and cleansing power is strong.
It is only below several specific embodiment of the present invention; should understand these embodiment only is not used in and limits the scope of the invention for the present invention is described; after having read the present invention; those skilled in the art all fall within claims of the present invention to the modification of the various equivalent form of values of the present invention and limit, and protection scope of the present invention should be as the criterion with claim of the present invention.

Claims (4)

1. a metal surface cleaning agent, it is characterized in that: described metallic substance is comprised of by mass parts following component:
Anion surfactant: 20-25 part;
Nonionogenic tenside: 35-40 part;
Mineral alkali: 3-5 part;
Washing assistant: 4-6 part;
Inhibiter: 0.5-1.0 part;
Ethanol: 10-20 part;
Deionized water: surplus;
Described anion surfactant is at least one in alkylpolyoxyethylene sodium sulfate, sodium lauryl sulphate or Seconary Alkane Sulphonate Sodium;
Described nonionogenic tenside is: C 8-C 14the secondary alcohol Soxylat A 25-7.
2. metal surface cleaning agent according to claim 1, it is characterized in that: described washing assistant is EDETATE SODIUM.
3. metal surface cleaning agent according to claim 1, it is characterized in that: described mineral alkali is at least one in sodium carbonate, salt of wormwood, sodium bicarbonate.
4. metal surface cleaning agent according to claim 1, it is characterized in that: described inhibiter is lauryl amine.
CN2013104098381A 2013-09-11 2013-09-11 Metal surface cleaning agent Pending CN103469231A (en)

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Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104032254A (en) * 2014-05-16 2014-09-10 浙江欧耀机械有限公司 Spraying process for abrasion resistant layer of plunger contact surface
CN104278283A (en) * 2014-09-25 2015-01-14 巢湖广丰金属制品有限公司 Special water-based cleaning agent for aluminum magnesium alloy
CN104450264A (en) * 2014-12-25 2015-03-25 常熟市苏搪化工设备制造有限公司 Special cleaning agent for chemical equipment
CN105063636A (en) * 2015-09-09 2015-11-18 路伯润滑油(苏州)有限公司 Ultrasonic cleaning agent for aluminium alloy mobile phone shells and preparation method of ultrasonic cleaning agent
CN105543732A (en) * 2016-01-25 2016-05-04 长春工业大学 Preparation method of C(F)/Cu composite material for electric locomotive pantograph slide plate
CN107299356A (en) * 2017-06-05 2017-10-27 武汉理工大学 A kind of ferrous metal aqueous cleaning agent and preparation method thereof
CN108286052A (en) * 2018-03-26 2018-07-17 中轻日化科技有限公司 A kind of biodegradation aqua type metal cleaner and the preparation method and application thereof
CN109097786A (en) * 2018-09-28 2018-12-28 何治伟 A kind of preparation method of metal surface residual oil cleaning agent
CN110862879A (en) * 2019-11-20 2020-03-06 上海涤宝科技有限公司 Environment-friendly efficient degreasing industrial cleaning agent
CN111321419A (en) * 2020-04-13 2020-06-23 宿迁盾嘉生物科技有限公司 Degreasing agent used in tinplate process and using method
CN111850578A (en) * 2020-07-17 2020-10-30 广东致卓环保科技有限公司 Medium-low temperature phosphorus-free oil removing powder for surfaces of steel parts and preparation and use methods thereof
CN112921329A (en) * 2021-01-19 2021-06-08 宁波东达磁电有限公司 Alkaline cleaning solution for neodymium iron boron material and cleaning method of neodymium iron boron material
CN112981423A (en) * 2019-12-02 2021-06-18 娄底市鼎宏自动化科技有限公司 Surface oil stain treatment agent for mining machinery
CN116240553A (en) * 2022-12-28 2023-06-09 建新赵氏科技股份有限公司 A cleaning agent for zinc alloy parts
CN117626281A (en) * 2023-10-20 2024-03-01 东方蓝天钛金科技有限公司 Solution and method for removing oxidation color on surface of GH4169 alloy bolt

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Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104032254A (en) * 2014-05-16 2014-09-10 浙江欧耀机械有限公司 Spraying process for abrasion resistant layer of plunger contact surface
CN104278283A (en) * 2014-09-25 2015-01-14 巢湖广丰金属制品有限公司 Special water-based cleaning agent for aluminum magnesium alloy
CN104450264A (en) * 2014-12-25 2015-03-25 常熟市苏搪化工设备制造有限公司 Special cleaning agent for chemical equipment
CN105063636A (en) * 2015-09-09 2015-11-18 路伯润滑油(苏州)有限公司 Ultrasonic cleaning agent for aluminium alloy mobile phone shells and preparation method of ultrasonic cleaning agent
CN105543732A (en) * 2016-01-25 2016-05-04 长春工业大学 Preparation method of C(F)/Cu composite material for electric locomotive pantograph slide plate
CN107299356A (en) * 2017-06-05 2017-10-27 武汉理工大学 A kind of ferrous metal aqueous cleaning agent and preparation method thereof
CN108286052B (en) * 2018-03-26 2019-11-08 中轻日化科技有限公司 A kind of biodegrade aqua type metal cleaner and the preparation method and application thereof
CN108286052A (en) * 2018-03-26 2018-07-17 中轻日化科技有限公司 A kind of biodegradation aqua type metal cleaner and the preparation method and application thereof
CN109097786A (en) * 2018-09-28 2018-12-28 何治伟 A kind of preparation method of metal surface residual oil cleaning agent
CN110862879A (en) * 2019-11-20 2020-03-06 上海涤宝科技有限公司 Environment-friendly efficient degreasing industrial cleaning agent
CN112981423A (en) * 2019-12-02 2021-06-18 娄底市鼎宏自动化科技有限公司 Surface oil stain treatment agent for mining machinery
CN111321419A (en) * 2020-04-13 2020-06-23 宿迁盾嘉生物科技有限公司 Degreasing agent used in tinplate process and using method
CN111850578A (en) * 2020-07-17 2020-10-30 广东致卓环保科技有限公司 Medium-low temperature phosphorus-free oil removing powder for surfaces of steel parts and preparation and use methods thereof
CN112921329A (en) * 2021-01-19 2021-06-08 宁波东达磁电有限公司 Alkaline cleaning solution for neodymium iron boron material and cleaning method of neodymium iron boron material
CN116240553A (en) * 2022-12-28 2023-06-09 建新赵氏科技股份有限公司 A cleaning agent for zinc alloy parts
CN116240553B (en) * 2022-12-28 2024-11-22 建新赵氏科技股份有限公司 A zinc alloy parts cleaning agent
CN117626281A (en) * 2023-10-20 2024-03-01 东方蓝天钛金科技有限公司 Solution and method for removing oxidation color on surface of GH4169 alloy bolt

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Application publication date: 20131225