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CN103467697A - Environment-friendly waterborne polyurethane coating and wallpaper adopting coating - Google Patents

Environment-friendly waterborne polyurethane coating and wallpaper adopting coating Download PDF

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Publication number
CN103467697A
CN103467697A CN2013103660403A CN201310366040A CN103467697A CN 103467697 A CN103467697 A CN 103467697A CN 2013103660403 A CN2013103660403 A CN 2013103660403A CN 201310366040 A CN201310366040 A CN 201310366040A CN 103467697 A CN103467697 A CN 103467697A
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China
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parts
environment
polyurethane coating
based polyurethane
friendly water
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CN2013103660403A
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CN103467697B (en
Inventor
吴坤燊
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Zhejiang Venecia Decoration Materials Co ltd
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ZHEJIANG VENECIA DECORATIVE CO Ltd
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Abstract

The invention discloses an environment-friendly waterborne polyurethane coating and wallpaper adopting the coating. The coating includes the following components in part by weight: 30-40 parts of diisocyanate, 6-10 parts of epoxidized soybean oil, 8-13 parts of dyhydroxy methyl propionic acid, 10-15 parts of dipropylene glycol, 8-12 parts of neopentyl glycol, 5-8 parts of organobentonite, 3-6 parts of ethidene diamine, 5-8 parts of ethylene glycol amine, 3-6 parts of acetic acid, 4-7 parts of cross-linking agent and 2-4 parts of catalyst. The wallpaper adopting the coating includes the following layers from bottom to top sequentially: a backing paper layer, a bonding layer, a primary layer, the environment-friendly waterborne polyurethane coating and a static flocking layer. According to the invention, the environment-friendly waterborne polyurethane coating and the static flocking layer are adopted, the wallpaper has the advantages of alkali, ethyl alcohol, water and abrasion resistance, better glossiness and the like, and the static flocking layer enables the stereoscopic effect of the wallpaper to be more obvious, and improves the attractiveness of the wallpaper.

Description

A kind of environment-friendly water-based polyurethane coating and adopt the wallpaper of this kind of coating
[technical field]
The present invention relates to the technical field of the technical field of finishing material, particularly wallpaper.
[background technology]
Most domestic wallpaper material all adopts all kinds of SOLVENTS type chemical assistant at present, in process of production with a large amount of toluene, pimelinketone, acetone, gasoline and N-BUTYL ACETATE are solvent, and the auxiliary agent such as heavy metallic salt in addition, these organic solvents and auxiliary agent are being produced, after construction and film forming for a long time in, can constantly discharge the infringer somatic nerves to surrounding environment, mucous membrane, the material of skin and liver organ is as organic compound (VOC) and carcinogenic substance, environment is caused to severe contamination, the upholstery of China, 10 national standards of finishing material limits of harmful substances, own formal enforcement in 1 day January in 2002, from 1 day July in 2002, once find not meet the unacceptable product of national standard, firmly closed down.These measures have promoted to take the development of the low-contamination type coating that water-borne coatings is representative greatly.Some aqueous coatings have also appearred at present both at home and abroad, but these coatings existence more or less disadvantage such as alkali resistant, not anti-ethanol, non-water resistant, dry slow, low in glossiness not, and traditional wallpaper stereoeffect is poor, can't meet human consumer's aesthetic conceptions.
[summary of the invention]
Purpose of the present invention solves the problems of the prior art exactly, propose a kind of environment-friendly water-based polyurethane coating and adopt the wallpaper of this kind of coating, can make wallpaper there is the advantages such as alkali resistant, anti-ethanol, water resistant, glossiness be good, the static flocking layer makes the stereoeffect of wallpaper more obvious simultaneously, has improved the aesthetic property of wallpaper.
For achieving the above object, the present invention proposes a kind of environment-friendly water-based polyurethane coating, comprise that following component and each constituent mass ratio are: 30~40 parts of vulcabond, 6~10 parts of epoxy soybean oils, 8~13 parts of dihydroxyl methylpropanoic acids, 10~15 parts of dipropylene glycols, 8~12 parts of neopentyl glycol, 5~8 parts of organobentonites, 3~6 parts of quadrols, 5~8 parts of ethylene glycol amine, 3~6 parts of acetic acid, 4~7 parts of linking agents, 2~4 parts of catalyzer.
As preferably, described vulcabond is tolylene diisocyanate TDI, l, the mixture of hexamethylene-diisocyanate HDI, different Buddhist diketone vulcabond IPDI, l, the blending ratio of hexamethylene-diisocyanate HDI, different Buddhist diketone vulcabond IPDI and tolylene diisocyanate TDI is 2.5:1:1.
As preferably, described linking agent is one or both of polynary aziridine and epoxy silane.
As preferably, described polynary aziridine is the ternary aziridine.
As preferably, described catalyzer is the one or any several mixture in aliphatics amine catalyzer, alicyclic amine catalyzer, aromatic amine and alcohol compound catalyzer.
As preferably, described aliphatics amine catalyzer is N, the N-dimethylcyclohexylamine, and described alicyclic amine catalyzer is N-methylmorpholine, and described aromatic amine is pyridine, and described alcohol compound catalyzer is trolamine.
The invention allows for a kind of wallpaper that adopts environment-friendly water-based polyurethane coating, comprise basic unit, tack coat, ground paper layer, environment-friendly water-based polyurethane coating and static flocking layer, described tack coat is positioned at the lower surface of basic unit, ground paper layer is positioned at the lower surface of tack coat, described environment-friendly water-based polyurethane coating is coated on the upper surface of basic unit, and described static flocking layer is positioned at the upper surface of environment-friendly water-based polyurethane coating.
As preferably, described basic unit is specially nonwoven layer or nonwoven ply of paper.
As preferably, described ground paper layer is specially the silicone oil ply of paper.
As preferably, the thickness of described environment-friendly water-based polyurethane coating is 0.02~0.05mm, and coating is thinner, does not affect feel and the aesthetic property of wallpaper.
As preferably, the thickness of described static flocking layer is 0.05~1.00mm, has strengthened the stereoeffect of wallpaper.
Beneficial effect of the present invention: the aqueous polyurethane coating that the present invention adopts not only has good physical and mechanical properties, excellent winter hardiness, elasticity, high gloss, and soft durometer varies with temperature not too large, anti-solvent, and good permeability, hardness is high, wear-resistant, snappiness is good, strong adhesion, film-forming temperature is low, can be in self-vulcanizing, there is nontoxic odorless simultaneously, have no irritating odor, pollution-free, cost is low, easy damaged is not by coating surface, easy construction, be easy to cleaning, non-corrosiveness, the advantages such as safety in utilization is good, also there is the intrinsic high rigidity of solvent borne polyurethane coating, the wear-resistant excellent properties that waits, the static flocking layer makes the stereoeffect of wallpaper more obvious simultaneously, improved the aesthetic property of wallpaper.
Feature of the present invention and advantage will be elaborated by reference to the accompanying drawings by embodiment.
[accompanying drawing explanation]
Fig. 1 is a kind of main pseudosection that adopts the wallpaper of environment-friendly water-based polyurethane coating of the present invention.
In figure: 1-basic unit, 2-tack coat, 3-ground paper layer, the environment-friendly water-based polyurethane coating of 4-, 5-static flocking layer.
[embodiment]
A kind of environment-friendly water-based polyurethane coating of the present invention, comprise that following component and each constituent mass ratio are: 30~40 parts of vulcabond, 6~10 parts of epoxy soybean oils, 8~13 parts of dihydroxyl methylpropanoic acids, 10~15 parts of dipropylene glycols, 8~12 parts of neopentyl glycol, 5~8 parts of organobentonites, 3~6 parts of quadrols, 5~8 parts of ethylene glycol amine, 3~6 parts of acetic acid, 4~7 parts of linking agents, 2~4 parts of catalyzer, described vulcabond is tolylene diisocyanate TDI, l, hexamethylene-diisocyanate HDI, the mixture of different Buddhist diketone vulcabond IPDI, l, hexamethylene-diisocyanate HDI, the blending ratio of different Buddhist diketone vulcabond IPDI and tolylene diisocyanate TDI is 2.5:1:1, described linking agent is one or both of polynary aziridine and epoxy silane, described polynary aziridine is the ternary aziridine, described catalyzer is aliphatics amine catalyzer, alicyclic amine catalyzer, one or any several mixture in aromatic amine and alcohol compound catalyzer, described aliphatics amine catalyzer is N, the N-dimethylcyclohexylamine, described alicyclic amine catalyzer is N-methylmorpholine, described aromatic amine is pyridine, described alcohol compound catalyzer is trolamine.
Consult Fig. 1, a kind of wallpaper that adopts environment-friendly water-based polyurethane coating of the present invention, comprise basic unit 1, tack coat 2, ground paper layer 3, environment-friendly water-based polyurethane coating 4 and static flocking layer 5, described tack coat 2 is positioned at the lower surface of basic unit 1, ground paper layer 3 is positioned at the lower surface of tack coat 2, described environment-friendly water-based polyurethane coating 4 is coated on the upper surface of basic unit 1, described static flocking layer 5 is positioned at the upper surface of environment-friendly water-based polyurethane coating 4, described basic unit 1 is specially nonwoven layer or nonwoven ply of paper, described ground paper layer 3 is specially the silicone oil ply of paper, the thickness of described environment-friendly water-based polyurethane coating 4 is 0.02~0.05mm, the thickness of described static flocking layer 5 is 0.05~1.00mm.
A kind of wallpaper that adopts environment-friendly water-based polyurethane coating of the present invention, not only there is good physical and mechanical properties, excellent winter hardiness, elasticity, high gloss, and soft durometer varies with temperature not too large, anti-solvent, and good permeability, hardness is high, wear-resistant, snappiness is good, chemicals-resistant, strong adhesion, film-forming temperature is low, can be in self-vulcanizing, there is nontoxic odorless simultaneously, have no irritating odor, pollution-free, nonflammable, cost is low, easy damaged is not by coating surface, easy construction, be easy to cleaning, non-corrosiveness, the advantages such as safety in utilization is good, also there is the intrinsic high rigidity of solvent borne polyurethane coating, the wear-resistant excellent properties that waits, static flocking layer 5 makes the stereoeffect of wallpaper more obvious simultaneously, improved the aesthetic property of wallpaper.
Embodiment mono-:
A kind of environment-friendly water-based polyurethane coating comprises that following component and each constituent mass ratio are: 36 parts of vulcabond, 8 parts of epoxy soybean oils, 10 parts of dihydroxyl methylpropanoic acids, 12 parts of dipropylene glycols, 9 parts of neopentyl glycol, 5 parts of organobentonites, 4 parts of quadrols, 6 parts of ethylene glycol amine, 4 parts of acetic acid, 4 parts of ternary aziridine, N, 2 parts of N-dimethylcyclohexylamines, described vulcabond is tolylene diisocyanate TDI, l, hexamethylene-diisocyanate HDI, the mixture of different Buddhist diketone vulcabond IPDI, l, hexamethylene-diisocyanate HDI, the blending ratio of different Buddhist diketone vulcabond IPDI and tolylene diisocyanate TDI is 2.5:1:1.
A kind of wallpaper that adopts environment-friendly water-based polyurethane coating, comprise basic unit 1, tack coat 2, ground paper layer 3, environment-friendly water-based polyurethane coating 4 and static flocking layer 5, described tack coat 2 is positioned at the lower surface of basic unit 1, ground paper layer 3 is positioned at the lower surface of tack coat 2, described environment-friendly water-based polyurethane coating 4 is coated on the upper surface of basic unit 1, described static flocking layer 5 is positioned at the upper surface of environment-friendly water-based polyurethane coating 4, described basic unit 1 is specially nonwoven layer or nonwoven ply of paper, described ground paper layer 3 is specially the silicone oil ply of paper, the thickness of described environment-friendly water-based polyurethane coating 4 is 0.03mm, the thickness of described static flocking layer 5 is 0.06mm.
Embodiment bis-:
A kind of environment-friendly water-based polyurethane coating comprises that following component and each constituent mass ratio are: 34 parts of vulcabond, 7 parts of epoxy soybean oils, 9 parts of dihydroxyl methylpropanoic acids, 14 parts of dipropylene glycols, 10 parts of neopentyl glycol, 6 parts of organobentonites, 3 parts of quadrols, 6 parts of ethylene glycol amine, 3 parts of acetic acid, 2.5 parts of ternary aziridine, 2.5 parts of epoxy silanes, 1 part of trolamine, 2 parts of N-methylmorpholines, described vulcabond is tolylene diisocyanate TDI, l, hexamethylene-diisocyanate HDI, the mixture of different Buddhist diketone vulcabond IPDI, l, hexamethylene-diisocyanate HDI, the blending ratio of different Buddhist diketone vulcabond IPDI and tolylene diisocyanate TDI is 2.5:1:1.
A kind of wallpaper that adopts environment-friendly water-based polyurethane coating, comprise basic unit 1, tack coat 2, ground paper layer 3, environment-friendly water-based polyurethane coating 4 and static flocking layer 5, described tack coat 2 is positioned at the lower surface of basic unit 1, ground paper layer 3 is positioned at the lower surface of tack coat 2, described environment-friendly water-based polyurethane coating 4 is coated on the upper surface of basic unit 1, described static flocking layer 5 is positioned at the upper surface of environment-friendly water-based polyurethane coating 4, described basic unit 1 is specially nonwoven layer or nonwoven ply of paper, described ground paper layer 3 is specially the silicone oil ply of paper, the thickness of described environment-friendly water-based polyurethane coating 4 is 0.04mm, the thickness of described static flocking layer 5 is 0.08mm.
Embodiment tri-:
A kind of environment-friendly water-based polyurethane coating comprises that following component and each constituent mass ratio are: 37 parts of vulcabond, 6 parts of epoxy soybean oils, 8 parts of dihydroxyl methylpropanoic acids, 10 parts of dipropylene glycols, 9 parts of neopentyl glycol, 9 parts of organobentonites, 3 parts of quadrols, 5 parts of ethylene glycol amine, 3 parts of acetic acid, 3 parts of ternary aziridine, 3 parts of epoxy silanes, 1 part of trolamine, 2 parts of N-methylmorpholines, 1 part of pyridine, described vulcabond is tolylene diisocyanate TDI, l, hexamethylene-diisocyanate HDI, the mixture of different Buddhist diketone vulcabond IPDI, l, hexamethylene-diisocyanate HDI, the blending ratio of different Buddhist diketone vulcabond IPDI and tolylene diisocyanate TDI is 2.5:1:1.
A kind of wallpaper that adopts environment-friendly water-based polyurethane coating, comprise basic unit 1, tack coat 2, ground paper layer 3, environment-friendly water-based polyurethane coating 4 and static flocking layer 5, described tack coat 2 is positioned at the lower surface of basic unit 1, ground paper layer 3 is positioned at the lower surface of tack coat 2, described environment-friendly water-based polyurethane coating 4 is coated on the upper surface of basic unit 1, described static flocking layer 5 is positioned at the upper surface of environment-friendly water-based polyurethane coating 4, described basic unit 1 is specially nonwoven layer or nonwoven ply of paper, described ground paper layer 3 is specially the silicone oil ply of paper, the thickness of described environment-friendly water-based polyurethane coating 4 is 0.05mm, the thickness of described static flocking layer 5 is 0.10mm.
Above-described embodiment is to explanation of the present invention, is not limitation of the invention, any scheme after simple transformation of the present invention is all belonged to protection scope of the present invention.

Claims (10)

1. an environment-friendly water-based polyurethane coating, it is characterized in that: comprise that following component and each constituent mass ratio are: 30~40 parts of vulcabond, 6~10 parts of epoxy soybean oils, 8~13 parts of dihydroxyl methylpropanoic acids, 10~15 parts of dipropylene glycols, 8~12 parts of neopentyl glycol, 5~8 parts of organobentonites, 3~6 parts of quadrols, 5~8 parts of ethylene glycol amine, 3~6 parts of acetic acid, 4~7 parts of linking agents, 2~4 parts of catalyzer.
2. a kind of environment-friendly water-based polyurethane coating as claimed in claim 1, it is characterized in that: described vulcabond is tolylene diisocyanate TDI, l, the mixture of hexamethylene-diisocyanate HDI, different Buddhist diketone vulcabond IPDI, l, the blending ratio of hexamethylene-diisocyanate HDI, different Buddhist diketone vulcabond IPDI and tolylene diisocyanate TDI is 2.5:1:1.
3. a kind of environment-friendly water-based polyurethane coating as claimed in claim 1, it is characterized in that: described linking agent is one or both of polynary aziridine and epoxy silane.
4. a kind of environment-friendly water-based polyurethane coating as claimed in claim 3, it is characterized in that: described polynary aziridine is the ternary aziridine.
5. a kind of environment-friendly water-based polyurethane coating as claimed in claim 1, it is characterized in that: described catalyzer is the one or any several mixture in aliphatics amine catalyzer, alicyclic amine catalyzer, aromatic amine and alcohol compound catalyzer.
6. a kind of environment-friendly water-based polyurethane coating as claimed in claim 5, it is characterized in that: described aliphatics amine catalyzer is N, the N-dimethylcyclohexylamine, and described alicyclic amine catalyzer is N-methylmorpholine, described aromatic amine is pyridine, and described alcohol compound catalyzer is trolamine.
7. a wallpaper that adopts environment-friendly water-based polyurethane coating, it is characterized in that: comprise basic unit (1), tack coat (2), ground paper layer (3), environment-friendly water-based polyurethane coating (4) and static flocking layer (5), described tack coat (2) is positioned at the lower surface of basic unit (1), ground paper layer (3) is positioned at the lower surface of tack coat (2), described environment-friendly water-based polyurethane coating (4) is coated on the upper surface of basic unit (1), and described static flocking layer (5) is positioned at the upper surface of environment-friendly water-based polyurethane coating (4).
8. a kind of wallpaper that adopts environment-friendly water-based polyurethane coating as claimed in claim 7, it is characterized in that: described basic unit (1) is specially nonwoven layer or nonwoven ply of paper.
9. a kind of wallpaper that adopts environment-friendly water-based polyurethane coating as claimed in claim 7, it is characterized in that: described ground paper layer (3) is specially the silicone oil ply of paper.
10. a kind of wallpaper that adopts environment-friendly water-based polyurethane coating as claimed in claim 7, it is characterized in that: the thickness of described environment-friendly water-based polyurethane coating (4) is 0.02~0.05mm, the thickness of described static flocking layer (5) is 0.05~1.00mm.
CN201310366040.3A 2013-08-21 2013-08-21 A kind of environment-friendly water-based polyurethane coating and adopt the wallpaper of this kind of coating Expired - Fee Related CN103467697B (en)

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Cited By (8)

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CN104141231A (en) * 2014-08-02 2014-11-12 甄曰菊 Fabric coating slurry and preparing method thereof
CN105274855A (en) * 2015-11-25 2016-01-27 安徽索亚装饰材料有限公司 Refractory insulating wallpaper containing modified acrylic resin emulsion coating
CN105297438A (en) * 2015-11-25 2016-02-03 安徽索亚装饰材料有限公司 Attapulgite-polylactic acid porous fiber modified acrylic resin emulsion coating-containing wallpaper
CN105297463A (en) * 2015-11-25 2016-02-03 安徽索亚装饰材料有限公司 Nanometer manganese dioxide-polylactic acid porous fiber modified acrylic resin emulsion coating-containing wear resistant wallpaper
CN105421087A (en) * 2015-11-25 2016-03-23 安徽索亚装饰材料有限公司 Anti-static health-care wallpaper containing modified acrylic resin emulsion coating
CN105421086A (en) * 2015-11-25 2016-03-23 安徽索亚装饰材料有限公司 Wallpaper containing tea polyphenol-polylactic acid porous fiber modified acrylic resin emulsion coating
CN106609483A (en) * 2015-10-27 2017-05-03 戚炎思 Wear-resistant wallpaper
CN108612273A (en) * 2016-12-22 2018-10-02 福建省优雅环保壁纸有限公司 A kind of noise reduction antistatic wallpaper

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CN104141231A (en) * 2014-08-02 2014-11-12 甄曰菊 Fabric coating slurry and preparing method thereof
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CN105297438A (en) * 2015-11-25 2016-02-03 安徽索亚装饰材料有限公司 Attapulgite-polylactic acid porous fiber modified acrylic resin emulsion coating-containing wallpaper
CN105297463A (en) * 2015-11-25 2016-02-03 安徽索亚装饰材料有限公司 Nanometer manganese dioxide-polylactic acid porous fiber modified acrylic resin emulsion coating-containing wear resistant wallpaper
CN105421087A (en) * 2015-11-25 2016-03-23 安徽索亚装饰材料有限公司 Anti-static health-care wallpaper containing modified acrylic resin emulsion coating
CN105421086A (en) * 2015-11-25 2016-03-23 安徽索亚装饰材料有限公司 Wallpaper containing tea polyphenol-polylactic acid porous fiber modified acrylic resin emulsion coating
CN108612273A (en) * 2016-12-22 2018-10-02 福建省优雅环保壁纸有限公司 A kind of noise reduction antistatic wallpaper

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Granted publication date: 20150729