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CN103451949A - Ultraviolet-proof fabric as well as production method thereof, and ultraviolet-proof paint as well as preparation method thereof - Google Patents

Ultraviolet-proof fabric as well as production method thereof, and ultraviolet-proof paint as well as preparation method thereof Download PDF

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Publication number
CN103451949A
CN103451949A CN2013104000400A CN201310400040A CN103451949A CN 103451949 A CN103451949 A CN 103451949A CN 2013104000400 A CN2013104000400 A CN 2013104000400A CN 201310400040 A CN201310400040 A CN 201310400040A CN 103451949 A CN103451949 A CN 103451949A
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coating
fabric
ultraviolet
parts
titanium dioxide
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CN103451949B (en
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许斌
沈卫锋
徐丽亚
陈波
王成翔
沈叶明
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Zhejiang Taihua New Materials Group Co ltd
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ZHEJIANG TAIHUA NEW MATERIAL CO Ltd
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Priority to CN201310400040.0A priority patent/CN103451949B/en
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Abstract

The invention provides an ultraviolet-proof fabric, which is good and lasting in ultraviolet-proof effect, a production method of the ultraviolet-proof fabric, a paint for the ultraviolet-proof fabric, and a preparation method of the paint, aiming at the shortcomings of poor and unabiding ultraviolet-proof effect of the ultraviolet-proof fabric in the prior art. A coating is arranged on at least one surface of the fabric; the coating comprises 50-65 parts of silicone resin and 15-40 parts of titanium dioxide particles by mass, wherein the silicone resin is used for coating the FC-2433 produced by Taiwan Congxin Co., Ltd. The coating surface of the ultraviolet-proof fabric is dry, smooth, and stiff; the fabric has preferable ultraviolet-proof effect and ultraviolet-proof durability; the ultraviolet-proof capacity can be improved to 40-50UPF (Ultraviolet Protection factor) from 10-20UPF; the washing resistant times are increased to be over than 10 from normal 2-3.

Description

Uvr Protective Fabric and preparation method thereof, antiultraviolet coating and preparation method thereof
Technical field
The present invention relates to a kind of Uvr Protective Fabric and preparation method thereof and antiultraviolet coating and preparation method thereof.
Background technology
Along with the continuous progress and development of society, people's cognitive level also improves constantly, and for the safety of self, also more and more values.Protectiveness as " clothing, food, lodging and transportion--basic necessities of life " primary clothes is also more and more valued more.As everyone knows, especially in summer, ultraviolet irradiation intensity is the strongest at all seasons.In hot summer, if skin is exposed under strong sunshine for a long time, will be tanned severely by ultraviolet ray.Short irradiation can impel the synthetic increase of melanin.Can cause pigmentation, as blackspot, freckle, increasing of the various color spots such as chloasma, increase, and deepens, cutaneous attractive in appearance.If long-irradiated words, will make skin immune function controlling descend, can form cutaneum carcinoma or precancerous lesion, as light keratosis, squamous cell carcinoma, melanoma etc.Therefore, in order to prevent flat skin, by ultraviolet ray, tanned severely, at ordinary times, especially when summer, the antitan agent clothing of wearing an antiultraviolet is very important.
In the market as the fabric of sunproof clothes, be adopt when dyeing or add ultraviolet (UV) resistant agent during typing mostly, after finalizing the design by high-temperature hot-air, itself and cloth cover are followed, thereby produced certain uvioresistant effect.But current this processing mode also exists two large defects: 1. the preventing ultraviolet effect of the ultraviolet-resistant fabric produced by the method is poor, and the UPF value only has 10-20; 2. preventing ultraviolet effect is not lasting, and after 2-3 washing, the UPF value will drop to below 10, and fabric has not possessed preventing ultraviolet effect basically.
Summary of the invention
The objective of the invention is, poor for prior art Uvr Protective Fabric preventing ultraviolet effect, the unabiding deficiency of preventing ultraviolet effect, provide a kind of preventing ultraviolet effect good, and the preparation method of the lasting Uvr Protective Fabric of preventing ultraviolet effect and preparation method thereof and coating and this coating used.
The objective of the invention is to be achieved through the following technical solutions:
A kind of Uvr Protective Fabric, at least one surface at described fabric is provided with coating, described coating is by parts by mass, the titanium dioxide particle that is resin and 15-40 part by the silicon of 50 parts-65 parts forms, and described silicon is that resin is the FC-2433 gluing SiLiconeCoating that limited company is believed in Taiwan;
Described titanium dioxide is the titanium white nano powder.
A kind of antiultraviolet coating, described coating is that the bridging agent of resin, 2-5 part, the short matchmaker of 2-5 part and the titanium dioxide particle of 15-40 part are dissolved in solvent composition by parts by mass by the silicon of 50 parts-65 parts, and described silicon is that resin is the FC-2433 gluing SiLiconeCoating that limited company is believed in Taiwan;
Described titanium dioxide is the titanium white nano powder;
The solution viscosity of described coating is 15000cps-25000cps;
Bridging agent is the H-835 that limited company is believed in Taiwan, and described short matchmaker believes in the CAT-135 of limited company for Taiwan, and described solvent is toluene.
A kind of preparation method of antiultraviolet coating, adopt aforesaid coating, taking silicon coefficient fat puts in container, then first add bridging agent in container, slowly add again catalyst after stirring, then add the solvent of 10-20 parts by mass, finally add titanium dioxide, after standing 1-2 minute, treat that titanium dioxide is dissolved in solvent fully, is then stirred until form uniform coating solution.
A kind of preparation method of Uvr Protective Fabric, comprise the coating step, adopts aforesaid coating to carry out coating, and described coating amount is 2-10g/m 2, coating tension force is 25kg-50kg, the painting interval velocity is 20m/min-60m/min; Carry out the temperature-gradient method drying, dry initial temperature is 130 ℃-150 ℃, and the baking temperature of final stage is 160 ℃-180 ℃, is more than or equal to 40s total drying time;
Give fabric desizing before coating, during destarch, the pH value of slurries is 12-13;
Before described coating, fabric is carried out to HEAT SETTING, finishing agent proportioning during typing is: waterproofing agent 60-80g/L bridging agent 10-20g/L, bleeding agent 1-5g/L, citric acid 1-5g/L; Setting temperature is 160-170 ℃, typing speed 30-50m/min.
Antiultraviolet coating of the present invention, at silicon, it is mixed with titanium white powder in resin, the coat side that not only makes and scribble the Uvr Protective Fabric of coating of the present invention obtains dry and comfortable, smooth, well-pressed appearance effect, and can make fabric there is better preventing ultraviolet effect and better antiultraviolet persistence, ability and ultraviolet resistance can be brought up to 40-50UPF by 10-20UPF, washable number of times is from usual bringing up to for 2-3 time more than 10 times, more than 10 times, the ability and ultraviolet resistance of fabric only reduces 5%-10%, so preventing ultraviolet effect is more lasting.
Adopt method of the present invention to prepare antiultraviolet coating, first solvent benzol being joined to silicon is in resin, then adds the titanium dioxide particle, after standing 1-2 minute, is stirred again, so titanium dioxide dissolves more fully, is conducive to bring into play the preventing ultraviolet effect of coating;
Adopt the inventive method to prepare Uvr Protective Fabric, not only the preventing ultraviolet effect of fabric is good, and preventing ultraviolet effect is lasting.
The specific embodiment
Below in conjunction with the specific embodiment and embodiment, the present invention is further described:
Fabric of the present invention, it is resinous coat that silicon is set on fabric, the silicon adopted is that resin is the FC-2433 gluing SiLiconeCoating that limited company is believed in Taiwan, at this silicon, be in resin, to add nano level titanium dioxide particle, Taiwan to believe in the H-835 bridging agent of limited company and CAT-135 catalyst that limited company is believed in Taiwan obtains coating, by parts by mass, wherein silicon is that the content of resin is 50 parts-65 parts, nano level titanium dioxide particle 15-40 part, H-835 bridging agent 2-5 part, CAT-135 catalyst 2-5 part.Using titanium dioxide and silicon, be that the mixture of resin is as coating, not only make the fabric coating face obtain dry and comfortable, smooth, well-pressed appearance effect, and can make fabric there is better preventing ultraviolet effect and better antiultraviolet persistence, ability and ultraviolet resistance can be brought up to 40-50UPF by 10-20UPF, washable number of times is from usual bringing up to for 2-3 time more than 10 times, more than 10 times, the ability and ultraviolet resistance of fabric only reduces 5%-10%, so preventing ultraviolet effect is more lasting.Simultaneously, titanium dioxide add the sliding-frictional resistance that also can obviously reduce coat side, make coat side more smooth, wide.
Institutional framework, the fabric variety of Uvr Protective Fabric of the present invention to fabric itself, yarn variety etc. do not have special requirement.Fabric carries out coating with cold coating after destarch, dyeing, typing.The manufacture of this fabric does not all have special requirement for the destarch of fabric, dyeing, typing etc., also can adopt common coating process, in order to obtain better preventing ultraviolet effect, be preferably as follows coating process: select floating cutter formula dry coating machine, select the cutter type of 0.5#-2.5#, the stand out of cutter and base plate is adjusted to 2.0mm-5.0mm, and the difference in height of cutter and base plate is adjusted to 2.0mm-4.0mm, makes fabric weightening finish 2-10g/m after coating 2, coating tension force is 25kg-50kg, the painting interval velocity is 20m/min-60m/min; Preferably adopt stage by stage and dry, bake out temperature rises stage by stage, and bake out temperature rises to 180 ℃ stage by stage from 130 ℃, and the total time of oven dry is that 40s-60s is advisable.Take that to float cutter formula dry coating machine be example, preferred stoving process is, the first segment oven temperature is 130 ℃-150 ℃, the second section oven temperature is 150 ℃-170 ℃, the 3rd joint oven temperature is 160 ℃-170 ℃, the 4th joint oven temperature is 160 ℃-180 ℃, and the 5th joint oven temperature is 160 ℃-180 ℃, and the drying time of each baking oven is 10 ± 2s left and right.Higher bake out temperature is conducive to resin and cloth cover is followed, and the cross-linking reaction of resin itself.Certainly, the number of times of oven dry and temperature can be adjusted, preferably, the number of times of oven dry three times and more than, be conducive to like this improve the adhesive force between resin and cloth cover, strengthen the cross-linking reaction of resin itself, be conducive to improve anti-ultraviolet function and the washability of fabric.
In order to obtain better preventing ultraviolet effect, coating is allocated as follows: taking silicon by proportioning is resin, the silicon that first takes 50 parts-65 parts is resin, then add 2-5 part bridging agent to container, the catalyst that adds again 2-5 part, the solvent (toluene) that then adds 10-20 part, the nano level titanium dioxide particle that finally adds 15 parts-40 parts, after standing 1-2 minute, after nano level titanium dioxide particle is dissolved in solvent fully, start again to stir, can avoid like this dissolving insufficient because of titanium dioxide, form granular projection at fabric face after coating, affect quality and feel, affect the uvioresistant effect simultaneously.The viscosity of preferably final coating solution is 15000cps-25000cps.This resin and titanium dioxide are mixed and made into to coating, can bring into play more fully the preventing ultraviolet effect of titanium dioxide, give full play to the effect of its ultraviolet light screener, this coating can effectively prevent that coating from, because the preventing ultraviolet effect that washing causes descends, making preventing ultraviolet effect more lasting.Through this kind of processing, process, more than the antiultraviolet UPF value of fabric can reach 40+, and more than after 20 washings, the UPF value still can remain on 40+.
In order further to improve the then fastness of resin and cloth cover, improve the washability of coating, the pH value of desizing liquid is 12-13;
In order to obtain having the more fabric of durable water resistant effect, finishing agent proportioning during typing is: waterproofing agent 60-80g/L Bridge Erector 10-20g/L, bleeding agent 1-5g/L, citric acid 1-5g/L, setting temperature 160-170 ℃, speed 30-50m/min.
Fabric of the present invention, yarn is preferably selected nylon, the terylene of 10D-60D,
Coating preparation embodiment 1
By parts by mass, the silicon that takes 50 parts of parts is resin, and then add the toluene of 10 parts, the nano level titanium dioxide particle that finally adds 40 parts, after standing 1-2 minute, after nano level titanium dioxide particle is dissolved in solvent fully, then start to stir and stir, obtaining viscosity is 25000cps antiultraviolet coating.
Coating preparation embodiment 2
By parts by mass, the silicon that takes 65 parts is resin, and then add the toluene of 10 parts, the nano level titanium dioxide particle that finally adds 15 parts, after standing 1-2 minute, after nano level titanium dioxide particle is dissolved in solvent fully, then start to stir and stir, obtaining viscosity is 21000cps antiultraviolet coating.
Coating preparation embodiment 3
By parts by mass, the silicon that takes 55 parts is resin, and then add the toluene of 15 parts, the nano level titanium dioxide particle that finally adds 25 parts, after standing 1-2 minute, after nano level titanium dioxide particle is dissolved in solvent fully, then start to stir and stir, obtaining viscosity is 17000cps antiultraviolet coating.
Coating preparation embodiment 4
By parts by mass, the silicon that takes 60 parts is resin, and then add the toluene of 17 parts, the nano level titanium dioxide particle that finally adds 33 parts, after standing 1-2 minute, after nano level titanium dioxide particle is dissolved in solvent fully, then start to stir and stir, obtaining viscosity is 15000cps antiultraviolet coating.
The Uvr Protective Fabric Preparation Example: following to adopt common destarch, dyeing and setting process, it is example that coating apparatus adopts floating cutter formula dry coating machine, and the preparation method of Uvr Protective Fabric of the present invention is illustrated:
All select the cutter type of 0.5#-2.5# during coating, the stand out of cutter and base plate is adjusted to 2.0mm-5.0mm, the difference in height of cutter and base plate is adjusted to 2.0mm-4.0mm, makes fabric weightening finish 2-10g/m after coating 2:
Embodiment 11
Fabric adopts 10D nylon, adopts the coating of embodiment 1, and setting coating tension force is 25kg, and the painting interval velocity is 60m/min; Dry stage by stage, per stage dries 10 seconds, and the design temperature of first segment baking oven is 130 ℃, the design temperature of second section baking oven is 150 ℃, the design temperature of the 3rd joint baking oven is 160 ℃, 170 ℃ of the design temperatures of the 4th joint baking oven, 180 ℃ of the design temperatures of the 5th joint baking oven.
Embodiment 12
Adopt the coating of embodiment 2 preparations, fabric is the 60D terylene, and coating tension force is 50kg, and the painting interval velocity is 20m/min; The employing syllogic is dried, and every section drying time is 12S, and setting the first segment oven temperature is 150 ℃, and setting the second section oven temperature is 170 ℃, and setting the 3rd joint oven temperature is 180 ℃.
Embodiment 13
Adopt the coating of embodiment 3 preparations, fabric is the 30D terylene, and coating tension force is 40kg, and the painting interval velocity is 40m/min; The employing sectional type is dried, and every section drying time is 8S, and setting the first segment oven temperature is 140 ℃, and setting the second section oven temperature is 160 ℃, and setting the 3rd joint oven temperature is 170 ℃, sets 180 ℃ of the 4th joint oven temperatures, sets 170 ℃ of the 5th joint oven temperatures.
Embodiment 14
Adopt the coating of embodiment 4 preparations, fabric is the 50D terylene, and coating tension force is 50kg, and the painting interval velocity is 35m/min; The employing sectional type is dried, and every section drying time is 10S, and setting the first segment oven temperature is 135 ℃, setting the second section oven temperature is 155 ℃, setting the 3rd joint oven temperature is 160 ℃, sets 170 ℃ of the 4th joint oven temperatures, sets 180 ℃ of the 5th joint oven temperatures.
Embodiment 15
Fabric is 50D nylon, and during destarch, the pH value of desizing liquid is 12, and all the other are with embodiment 12.
Embodiment 16
Fabric is 30D nylon, and during destarch, the pH value of desizing liquid is 13, and all the other are with embodiment 13.
Embodiment 17
Finishing agent proportioning during typing is: waterproofing agent 60g/L, Bridge Erector 10g/L, bleeding agent 1g/L, citric acid 1/L, 160 ℃ of setting temperatures, speed 30m/min.All the other are with embodiment 11.
Embodiment 18
Finishing agent proportioning during typing is: waterproofing agent 80g/L, Bridge Erector 20g/L, bleeding agent 3g/L, citric acid 3g/L, 170 ℃ of setting temperatures, speed 50m/min.All the other are with embodiment 12.
Embodiment 19
Finishing agent proportioning during typing is: waterproofing agent 70g/L, Bridge Erector 15g/L, bleeding agent 5g/L, citric acid 5g/L, 165 ℃ of setting temperatures, speed 40m/min.All the other are with embodiment 13.
Embodiment 20
Finishing agent proportioning during typing is: waterproofing agent 70g/L, Bridge Erector 15g/L, bleeding agent 5g/L, citric acid 5g/L, 165 ℃ of setting temperatures, speed 40m/min.All the other are with embodiment 14.
Embodiment 21
Finishing agent proportioning during typing is: waterproofing agent 70g/L, Bridge Erector 15g/L, bleeding agent 5g/L, citric acid 5g/L, 165 ℃ of setting temperatures, speed 40m/min.All the other are with embodiment 15.
Embodiment 22
PH value during destarch is 12, and all the other are with embodiment 19.
Embodiment 23
PH value during destarch is 13, and all the other are with embodiment 16.
Embodiment 24
PH value during destarch is 14, and all the other are with embodiment 17.
Embodiment 25
PH value during destarch is 13, and all the other are with embodiment 18.
Coating solubility property prepared by table 1 the inventive method and conventional method and the contrast of the uniformity of titanium dioxide
Figure BDA0000377560400000071
Fabric property indices prepared by table 2, the inventive method and the ultraviolet resistance of the prepared fabric of commonsense method and wash durability comparison sheet
Figure BDA0000377560400000072

Claims (10)

1. a Uvr Protective Fabric, it is characterized in that, at least one surface at described fabric is provided with coating, described coating is by parts by mass, the titanium dioxide particle that is resin and 15-40 part by the silicon of 50 parts-65 parts forms, and described silicon is that resin is the FC-2433 gluing SiLiconeCoating that limited company is believed in Taiwan.
2. a kind of Uvr Protective Fabric as claimed in claim 1, is characterized in that, described titanium dioxide is the titanium white nano powder.
3. an antiultraviolet coating, it is characterized in that, described coating is that the bridging agent of resin, 2-5 part, the short matchmaker of 2-5 part and the titanium dioxide particle of 15-40 part are dissolved in solvent composition by parts by mass by the silicon of 50 parts-65 parts, and described silicon is that resin is the FC-2433 gluing SiLiconeCoating that limited company is believed in Taiwan.
4. antiultraviolet coating as claimed in claim 3, is characterized in that, described titanium dioxide is the titanium white nano powder.
5. antiultraviolet coating as claimed in claim 3, is characterized in that, the solution viscosity of described coating is 15000cps-25000cps.
6. antiultraviolet coating as described as claim 3-4, is characterized in that, bridging agent is the H-835 that limited company is believed in Taiwan, and described short matchmaker believes in the CAT-135 of limited company for Taiwan, and described solvent is toluene.
7. the preparation method of an antiultraviolet coating, it is characterized in that, adopt the described coating of claim 3-6, take silicon coefficient fat and put in container, then in container, first add bridging agent, slowly add again catalyst after stirring, the solvent that then adds the 10-20 parts by mass, finally add titanium dioxide, after standing 1-2 minute, treat that titanium dioxide is dissolved in solvent fully, is then stirred until form uniform coating solution.
8. the manufacture method of a Uvr Protective Fabric, is characterized in that, comprises the coating step, adopts coating claimed in claim 7 to carry out coating, and described coating amount is 2-10g/m 2, coating tension force is 25kg-50kg, the painting interval velocity is 20m/min-60m/min; Carry out the temperature-gradient method drying, dry initial temperature is 130 ℃-150 ℃, and the baking temperature of final stage is 160 ℃-180 ℃, is more than or equal to 40s total drying time.
9. the preparation method of Uvr Protective Fabric as claimed in claim 8, is characterized in that, gives fabric desizing before coating, and during destarch, the pH value of slurries is 12-13.
10. the preparation method of Uvr Protective Fabric as claimed in claim 8 or 9, it is characterized in that, before described coating, fabric is carried out to HEAT SETTING, finishing agent proportioning during typing is: waterproofing agent 60-80g/L bridging agent 10-20g/L, bleeding agent 1-5g/L, citric acid 1-5g/L; Setting temperature is 160-170 ℃, typing speed 30-50m/min.
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105778708A (en) * 2016-03-11 2016-07-20 山东永泰集团有限公司 Ultraviolet-proof paint and preparation method thereof
CN107048545A (en) * 2017-04-18 2017-08-18 苏州市兴丰强纺织科技有限公司 One kind does not bore suede 3D fabrics and preparation method
CN108867099A (en) * 2018-06-15 2018-11-23 合肥伊只门窗有限公司 A kind of antiultraviolet dyestuff and preparation method thereof for curtain
CN109109410A (en) * 2018-08-08 2019-01-01 康帝雅高档面料(苏州)有限公司 Waterproof Breathable corduroy is bonded fabric and its manufacturing process
CN109267323A (en) * 2018-08-31 2019-01-25 谭亚 A kind of preparation method of antiultraviolet umbrella cloth

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101880961A (en) * 2009-07-21 2010-11-10 上海工程技术大学 Series modified nano titanium dioxide photo-catalyst textile finishing agent and preparation method
CN102505488A (en) * 2011-11-08 2012-06-20 浙江台华新材料股份有限公司 Post-treatment method of chinlon superfine denier fiber fabric
CN103265882A (en) * 2013-05-08 2013-08-28 上海纳米技术及应用国家工程研究中心有限公司 High temperature resistance anti-ultraviolet hydrophobic coating material and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101880961A (en) * 2009-07-21 2010-11-10 上海工程技术大学 Series modified nano titanium dioxide photo-catalyst textile finishing agent and preparation method
CN102505488A (en) * 2011-11-08 2012-06-20 浙江台华新材料股份有限公司 Post-treatment method of chinlon superfine denier fiber fabric
CN103265882A (en) * 2013-05-08 2013-08-28 上海纳米技术及应用国家工程研究中心有限公司 High temperature resistance anti-ultraviolet hydrophobic coating material and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105778708A (en) * 2016-03-11 2016-07-20 山东永泰集团有限公司 Ultraviolet-proof paint and preparation method thereof
CN107048545A (en) * 2017-04-18 2017-08-18 苏州市兴丰强纺织科技有限公司 One kind does not bore suede 3D fabrics and preparation method
CN108867099A (en) * 2018-06-15 2018-11-23 合肥伊只门窗有限公司 A kind of antiultraviolet dyestuff and preparation method thereof for curtain
CN109109410A (en) * 2018-08-08 2019-01-01 康帝雅高档面料(苏州)有限公司 Waterproof Breathable corduroy is bonded fabric and its manufacturing process
CN109267323A (en) * 2018-08-31 2019-01-25 谭亚 A kind of preparation method of antiultraviolet umbrella cloth

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