[go: up one dir, main page]
More Web Proxy on the site http://driver.im/

CN103405991A - Energy-efficient comprehensive desulfurization and purification system and method for active coke of different flue gases - Google Patents

Energy-efficient comprehensive desulfurization and purification system and method for active coke of different flue gases Download PDF

Info

Publication number
CN103405991A
CN103405991A CN2013103713468A CN201310371346A CN103405991A CN 103405991 A CN103405991 A CN 103405991A CN 2013103713468 A CN2013103713468 A CN 2013103713468A CN 201310371346 A CN201310371346 A CN 201310371346A CN 103405991 A CN103405991 A CN 103405991A
Authority
CN
China
Prior art keywords
desulfurization
activated coke
adsorption tower
flue gases
conveyer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN2013103713468A
Other languages
Chinese (zh)
Other versions
CN103405991B (en
Inventor
翟尚鹏
何慕春
黄丽娜
傅月梅
刘强
翁淑容
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHANGHAI CLEAR ENVIRONMENTAL PROTECTION SCIENCE AND TECHNOLOGY Co Ltd
Original Assignee
SHANGHAI CLEAR ENVIRONMENTAL PROTECTION SCIENCE AND TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHANGHAI CLEAR ENVIRONMENTAL PROTECTION SCIENCE AND TECHNOLOGY Co Ltd filed Critical SHANGHAI CLEAR ENVIRONMENTAL PROTECTION SCIENCE AND TECHNOLOGY Co Ltd
Priority to CN201310371346.8A priority Critical patent/CN103405991B/en
Publication of CN103405991A publication Critical patent/CN103405991A/en
Application granted granted Critical
Publication of CN103405991B publication Critical patent/CN103405991B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Landscapes

  • Treating Waste Gases (AREA)

Abstract

The invention discloses an energy-efficient comprehensive desulfurization and purification system and method for active coke of different flue gases. The purification system comprises a first adsorption desulfurization section, a second adsorption desulfurization section, an active coke regeneration section and active coke conveying equipment. According to the purification method, the purification system is adopted to carry out desulfurization and purification on different flue gases, and the purification method comprises a smoke desulfurization step and active coke regenerating and circulating steps, which are synchronously carried out. According to the energy-efficient comprehensive desulfurization and purification system and method for active coke of different flue gases disclosed by the invention, the difference of the flue gas conditions of different flue gas components and the like is fully utilized; the flue gas suitable for the processing conditions is formed after mixing; the pretreatment procedure of the flue gas in independent treatment is reduced; the flow is simplified; energy conservation and consumption reduction are achieved; the characteristics of different flue gases can be fully utilized; comprehensive treatment is carried out; the operation cost is reduced; energy conservation and consumption reduction are achieved; efficient purification of pollutants is also achieved.

Description

The energy-efficient synthesis desulfurating cleaning system of activated coke and method for different flue gases
Technical field
The present invention relates to the technical field of flue gas desulfurization, relate in particular to the energy-efficient synthesis desulfurating cleaning system of a kind of activated coke for different flue gases and method.
Background technology
" strengthen sulfur dioxide and nitrogen oxide and reduce discharging dynamics, the reduction of discharging target of sulfur dioxide is that ratio in 2015 descended 8% in 2010, so the task of desulfurization is still more arduous in " national environmental protection " 12 " planning " (No. (2011) 42, promulgated by the State Council) proposition.
The active coke dry-method desulfuration technology be take the dry method resource desulfur technology that physics-chemisorbed principle is that gas cleaning is carried out on basis, the de-SO of the burnt absorption of trafficability characteristic 2, absorption SO 2After activated coke, by heating, regenerate, activated coke recycles, and obtains concentration and be 20~30% SO 2Gas, adopt ripe chemical process, can produce multiple Containing Sulfur chemical product, as sulfuric acid, ammonium sulfate, liquid SO 2Deng.
The active coke dry-method desulfuration technology is with its water saving, integrated purifying, non-secondary pollution, and the advantages such as recovery sulphur resource are applied in fields such as non-ferrous metal metallurgy, coal-burning boiler, sintering.
At present in the flue gas desulfurization course of industrial furnace, due to the production process difference, in same enterprise, have different temperatures, the flue gas of characteristic needs to process, flue gas as the existing industrial furnace of coloured smelting, the flue gas that the environment gas collection is also arranged, the flue gas of sulphuric acid plant, process separately respectively in addition, some needs cooling, some need to use steam humidifying and preservative treatment etc., and technological process is relatively complicated, and investment and operating cost are increased.The present invention aims to provide the energy-efficient synthesis desulfurating cleaning system of a kind of activated coke for different flue gases and method, takes full advantage of the characteristic of different flue gases, and integrated treatment reduces operating cost, energy-saving and cost-reducing and realize the high-efficient purification of pollutant.
Summary of the invention
Deficiency in view of above-mentioned prior art existence, the present invention proposes the energy-efficient synthesis desulfurating cleaning system of a kind of activated coke for different flue gases and method, can take full advantage of the characteristic of different flue gases, integrated treatment, reduce operating cost, energy-saving and cost-reducing and realize the high-efficient purification of pollutant.
The present invention is for achieving the above object, and the energy-efficient synthesis desulfurating cleaning system of a kind of activated coke for different flue gases provided by the invention, comprise the first adsorption desulfurize section, the second adsorption desulfurize section, activated coke regenerator section and activated coke conveying equipment.
Described the first adsorption desulfurize section comprises the first desulfurization adsorption tower purified for different flue gas desulfurization, for importing the first desulfurization fume pipeline of different flue gases and be used to importing the first tower top feed bin of activated coke, described the first desulfurization fume pipeline conducting is connected to the bottom of described the first desulfurization adsorption tower, and described the first tower top feed bin conducting is connected to the top of described the first desulfurization adsorption tower.
Described the second adsorption desulfurize section comprises the second desulfurization adsorption tower purified for different flue gas desulfurization, for importing the second desulfurization fume pipeline of different flue gases and be used to importing the second tower top feed bin of activated coke, described the second desulfurization fume pipeline conducting is connected to the bottom of described the second desulfurization adsorption tower, and described the second tower top feed bin conducting is connected to the top of described the second desulfurization adsorption tower.
Described activated coke regenerator section comprises the regeneration reactor for activated coke regeneration.
Described activated coke conveying equipment comprises be used to the screening plant that sieves activated coke, the first conveyer, second conveyor and the 3rd conveyer be used to transferring activated coke.
Described the first desulfurization adsorption tower bottom is connected in series successively for the first feed opening, described the first conveyer, described screening plant and the described second tower top feed bin of discharging the activated coke of reacting through the first desulfurization adsorption tower, described the second desulfurization adsorption tower bottom is connected to the activated coke charging aperture of described regeneration reactor for second feed opening of discharging the activated coke of reacting through the second desulfurization adsorption tower by described second conveyor, the activated coke discharging opening of described regeneration reactor is connected on described the first tower top feed bin by the 3rd conveyer.
As a further improvement on the present invention, also comprise and be used to system to add the batcher of fresh activated coke, described batcher is connected on described the first conveyer.
As a further improvement on the present invention, described the first desulfurization adsorption tower is cross-flow moving bed structure, and described the second desulfurization adsorption tower is the adverse current bed structure.
As a further improvement on the present invention, described the first desulfurization adsorption tower can be single or multiple desulfurization adsorption tower parallel-connection structures.
As a further improvement on the present invention, in described regeneration reactor, be provided with the thermal treatment zone, renewing zone and the cooling zone distributed from top to bottom; The described regeneration reactor outside also is provided with the one-way circulation closed-loop system be connected with the conducting of the described thermal treatment zone, described one-way circulation closed-loop system comprises circulating fan and thermal source, the input port conducting of described circulating fan is connected to the top of the described thermal treatment zone, and the delivery outlet of described circulating fan leads to and connects by the lower guide of described thermal source and the described thermal treatment zone.
As a further improvement on the present invention, described the first conveyer, second conveyor and the 3rd conveyer are bucket conveyor.
As a further improvement on the present invention, between described the 3rd conveyer and described the first tower top feed bin, be provided with the first charging unloader, between described the first feed opening and described the first conveyer, be provided with the first discharging unloader, between described screening plant and described the second tower top feed bin, be provided with the second charging unloader, between described the second feed opening and described second conveyor, be provided with the second discharging unloader, between described second conveyor and described regeneration reactor, be provided with the 3rd charging unloader, between described regeneration reactor and described the 3rd conveyer, be provided with the 3rd discharging unloader,
Described the first charging unloader, the first discharging unloader, the second charging unloader and the second discharging unloader are the star-like discharger of single spool, and described the 3rd charging unloader and the 3rd discharging unloader are the star-like discharger of double spool.
As a further improvement on the present invention, also comprise a chimney for flue gas after emission purification, described the first desulfurization adsorption tower is connected on described chimney by the first purifying smoke pipeline, described the second desulfurization adsorption tower is connected on described chimney by the second purifying smoke pipeline, is provided be used to controlling the air door of flue gas flow on described the first desulfurization fume pipeline, the second desulfurization fume pipeline, the first purifying smoke pipeline and described the second purifying smoke pipeline.
The present invention also proposes the energy-efficient synthesis desulfurating purification method of a kind of activated coke for different flue gases, adopt the energy-efficient synthesis desulfurating cleaning system of the above-mentioned activated coke for different flue gases to carry out the desulfurizing and purifying of different flue gases, comprise the flue gas desulfurization step and activated coke regeneration and the circulation step that synchronously carry out.
The flue gas desulfurization step: different flue gases are converged and import described the first desulfurization fume pipeline and/or described the second desulfurization fume pipeline, and different flue gases have reacted Dry FGD with activated coke in described the first desulfurization adsorption tower and/or described the second desulfurization adsorption tower.
Activated coke regeneration and circulation step: the fresh activated coke that the activated coke of discharging from the first feed opening of the first desulfurization adsorption tower and batcher add is sent into screening plant by the first conveyer and is sieved, and the activated coke that meets the desulfurization requirement enters the second tower top feed bin and then enters the second desulfurization adsorption tower and adsorb SO 2Activated coke after absorption is discharged from the second feed opening of the second desulfurization adsorption tower bottom, enter second conveyor, by second conveyor, sent in regeneration reactor, by the thermal treatment zone, renewing zone, cooling zone, activated coke is regenerated successively, activated coke after regeneration is discharged and is sent into the first tower top feed bin by the 3rd conveyer by the activated coke discharging opening, and activated coke enters the first desulfurization adsorption tower absorption SO 2, then discharged by the first feed opening of the first desulfurization adsorption tower, enter next time and recycle.
As a further improvement on the present invention, the flue-gas temperature that described the first desulfurization fume pipeline imports is 50-100 ℃, and the flue-gas temperature that described the second desulfurization fume pipeline imports is over 100 ℃.
The energy-efficient synthesis desulfurating cleaning system of activated coke for different flue gases of the present invention and method compared with prior art have following technique effect at least:
The first, take full advantage of the otherness of the flue gas conditions such as different flue gas compositions, after mixing, become the flue gas that is applicable to treatment conditions, while having reduced independent the processing, to the pretreatment process of flue gas, simple flow, realize energy-saving and cost-reducing.
The second, high-temperature flue gas enters the second adsorption desulfurize section, utilizes the activated coke of the first adsorption desulfurize section discharge, can improve the utilization rate of activated coke, improves simultaneously the activated coke temperature that enters regenerator section, reduces the energy consumption of regeneration heating.
Three, different workshop sections are mixed converges flue gas and can reduce SO under abnormal condition 2Instantaneous variation maximum, be conducive to system stable operation.
The the 4th. but the activated coke synchronizing regeneration of whole system recycles, and further improves the flue gas desulfurization purification efficiency, saves energy consumption, reduces operating cost.
The accompanying drawing explanation
Fig. 1 is the structural representation of the energy-efficient synthesis desulfurating cleaning system of the activated coke for different flue gases of the present invention.
Primary clustering symbol description in figure:
100. the first adsorption desulfurize section, 110. the first desulfurization adsorption tower, 111. the first feed opening, 120. the first desulfurization fume pipeline, 130. the first tower top feed bin, 200. the second adsorption desulfurize section, 210. the second desulfurization adsorption tower, 211 second feed openings, 220. the second desulfurization fume pipeline, 230. the second tower top feed bin, 300. activated coke regenerator section, 310. regeneration reactor, 311. activated coke charging aperture, 312 activated coke discharging openings, 313. the thermal treatment zone, 314. renewing zone, 315 cooling zones, 316. circulating fan, 317. thermal source, 318. cooling blower, 410. screening plant, 420. the first conveyer, 430. second conveyor, 440. the 3rd conveyer, 500. batcher, 610. the first charging unloader, 620. the first discharging unloader, 630. the second charging unloader, 640. the second discharging unloader, 650. the 3rd charging unloader, 660. the 3rd discharging unloader, 700. chimney, 800. the first purifying smoke pipeline, 900. the second purifying smoke pipeline.
The specific embodiment
In order to be illustrated more clearly in the embodiment of the present invention or technical scheme of the prior art, below will the accompanying drawing of required use in embodiment or description of the Prior Art be briefly described, apparently, accompanying drawing in the following describes is only some embodiments of the present invention, for those of ordinary skills, under the prerequisite of not paying creative work, can also obtain according to these accompanying drawings other accompanying drawing.
Embodiment mono-:
Fig. 1 is the structural representation of the energy-efficient synthesis desulfurating cleaning system of the activated coke for different flue gases of the present invention.As shown in Figure 1, the energy-efficient synthesis desulfurating cleaning system of a kind of activated coke for different flue gases that the present embodiment proposes, comprise the first adsorption desulfurize section 100, the second adsorption desulfurize section 200, activated coke regenerator section 300 and activated coke conveying equipment.
The first adsorption desulfurize section 100 comprises the first desulfurization adsorption tower 110 purified for different flue gas desulfurization, for importing the first desulfurization fume pipeline 120 of different flue gases and be used to importing the first tower top feed bin 130 of activated coke, the first desulfurization fume pipeline 120 conductings are connected to the bottom of the first desulfurization adsorption tower 110, and the first tower top feed bin 130 conductings are connected to the top of the first desulfurization adsorption tower 110.
The second adsorption desulfurize section 200 comprises the second desulfurization adsorption tower 210 purified for different flue gas desulfurization, for importing the second desulfurization fume pipeline 220 of different flue gases and be used to importing the second tower top feed bin 230 of activated coke, the second desulfurization fume pipeline 220 conductings are connected to the bottom of the second desulfurization adsorption tower 210, and the second tower top feed bin 230 conductings are connected to the top of the second desulfurization adsorption tower 210.
Activated coke regenerator section 300 comprises the regeneration reactor 310 for activated coke regeneration.
Described activated coke conveying equipment comprises be used to the screening plant 410 that sieves activated coke, the first conveyer 420, second conveyor 430 and the 3rd conveyer 440 be used to transferring activated coke.
The first desulfurization adsorption tower 110 bottoms are connected in series successively for the first feed opening 111, the first conveyer 420, screening plant 410 and the second tower top feed bin 230 of discharging the activated coke of reacting through the first desulfurization adsorption tower 110, the second desulfurization adsorption tower 210 bottoms are connected to the activated coke charging aperture 311 of regeneration reactor 310 for second feed opening 211 of discharging the activated coke of reacting through the second desulfurization adsorption tower 210 by second conveyor 430, the activated coke discharging opening 312 of regeneration reactor 310 is connected on the first tower top feed bin 130 by the 3rd conveyer 440.
Concrete, as shown in the figure, the present embodiment also comprises the batcher 500 that is used to the fresh activated coke of system interpolation, batcher 500 is connected on the first conveyer 420.
Concrete, the first desulfurization adsorption tower 110 is cross-flow moving bed structure, the second desulfurization adsorption tower 210 is the adverse current bed structure.Exemplary, as shown in the figure, the present embodiment only adopts cross-flow moving bed the first desulfurization adsorption tower 110 and the adverse current bed of being used as the second desulfurization adsorption tower 210, and cross-flow moving bed and adverse current bed is outsourcing piece commonly used, repeats no more herein.
Certainly, in other specific embodiments, can also adopt the first desulfurization adsorption tower and the second desulfurization adsorption tower of other versions, the first desulfurization adsorption tower and/or the second desulfurization adsorption tower can also be respectively a plurality of desulfurization adsorption tower parallel-connection structures simultaneously, repeat no more herein.
Exemplary, as shown in the figure, in regeneration reactor 310, be provided with the 314He cooling zone, 313, renewing zone, the thermal treatment zone 315 distributed from top to bottom; Regeneration reactor 310 outsides also are provided with the one-way circulation closed-loop system be connected with the thermal treatment zone 313 conductings, described one-way circulation closed-loop system comprises circulating fan 316 and thermal source 317, the input port conducting of circulating fan 316 is connected to 313De top, the thermal treatment zone, and the delivery outlet of circulating fan 316 leads to and connects with the lower guide of the thermal treatment zone 313 by thermal source 317.In addition, on cooling zone 315, conducting is provided with cooling blower 318, on renewing zone 314, is provided with the SO that contains that derives the regenerative process generation 2The outlets of desorption gas etc., those skilled in the art can select and arrange according to common practise or prior art, repeat no more herein.
Exemplary, first conveyer 420 of the present embodiment, second conveyor 430 and the 3rd conveyer 440 all adopt bucket conveyor.Between the 3rd conveyer 440 and the first tower top feed bin 130, be provided with the first charging unloader 610, between the first feed opening 111 and the first conveyer 420, be provided with the first discharging unloader 620, between screening plant 410 and the second tower top feed bin 230, be provided with the second charging unloader 630, between the second feed opening 211 and second conveyor 430, be provided with the second discharging unloader 640, between second conveyor 430 and regeneration reactor 310, be provided with the 3rd charging unloader 650, be provided with the 3rd discharging unloader 660 between regeneration reactor 310 and the 3rd conveyer 440.
The first charging unloader 610, the first discharging unloader 620, the second charging unloader 630 and the second discharging unloader 640 are the star-like discharger of single spool, and the 3rd charging unloader 650 and the 3rd discharging unloader 660 are the star-like discharger of double spool.
Certainly, in other specific embodiments, described the first conveyer, second conveyor and the 3rd conveyer, and described the first charging unloader, the first discharging unloader, the second charging unloader, the second discharging unloader, described the 3rd charging unloader and the 3rd discharging unloader, all can select other outsourcing pieces commonly used, repeat no more herein.
Concrete, as shown in the figure, the present embodiment also comprises a chimney for flue gas after emission purification 700, the first desulfurization adsorption tower 110 is connected on chimney 700 by the first purifying smoke pipeline 800, the second desulfurization adsorption tower 210 is connected on chimney 700 by the second purifying smoke pipeline 900, is provided with the air door (figure does not mark) for controlling flue gas flow on the first desulfurization fume pipeline 120, the second desulfurization fume pipeline 220, the first purifying smoke pipeline 800 and the second purifying smoke pipeline 900.
Certainly, in other specific embodiments, can also adopt flue gas after other mode emission purifications, the setting of air door also can optionally arrange as required.
The present embodiment has also proposed the energy-efficient synthesis desulfurating purification method of a kind of activated coke for different flue gases, the method is the desulfurizing and purifying of the different flue gases that adopt the energy-efficient synthesis desulfurating cleaning system of above-mentioned activated coke for different flue gases and carry out, wherein, comprise flue gas desulfurization step and activated coke regeneration and the circulation step synchronously carried out.Concrete steps are as follows:
The flue gas desulfurization step: different flue gases are converged and import the first desulfurization fume pipeline 120 and/or the second desulfurization fume pipeline 220, and different flue gases have reacted Dry FGD with activated coke in the first desulfurization adsorption tower 110 and/or the second desulfurization adsorption tower 210.
Activated coke regeneration and circulation step: the fresh activated coke that the activated coke of discharging from the first feed opening 111 of the first desulfurization adsorption tower 110 and batcher 500 add is sent into screening plant 410 by the first conveyer 420 and is sieved, and the activated coke that meets the desulfurization requirement enters the second tower top feed bin 230 and then enters the second desulfurization adsorption tower 210 and adsorb SO 2Activated coke after absorption is discharged from the second feed opening 211 of the second desulfurization adsorption tower 210 bottoms, enter second conveyor 430, by second conveyor 430, sent in regeneration reactor 310, by 315 pairs of 314, cooling zones, 313, renewing zone, thermal treatment zone activated coke, regenerate successively, activated coke after regeneration is discharged and is sent into the first tower top feed bin 130 by the 3rd conveyer 440 by activated coke discharging opening 312, and activated coke enters the first desulfurization adsorption tower 110 absorption SO 2, then discharged by the first feed opening 111 of the first desulfurization adsorption tower 110, enter next time and recycle.
Further, the flue-gas temperature that the first desulfurization fume pipeline 120 imports is 50-100 ℃, and the flue-gas temperature that the second desulfurization fume pipeline 220 imports is over 100 ℃.
Exemplary, will hang down and the very high flue gas of temperature from the temperature of different workshop sections, or SO 2After the flue gas that other flue gas conditions such as concentration and water content differ greatly fully mixes, obtain being applicable to the flue gas that converges that flue gas is processed working condition, select to import the first desulfurization fume pipeline 120 and the second desulfurization fume pipeline 220 according to the temperature of converging flue gas.The different flue gases of different workshop sections can be connected on the first desulfurization fume pipeline 120 or the second desulfurization fume pipeline 220 on side separately by its discharge duct, directly in the first desulfurization fume pipeline 120 or the second desulfurization fume pipeline 220, realize mixing to import in corresponding adsorption desulfurize tower carrying out SO 2Absorption.Meanwhile, activated coke regeneration and circulation step also carry out synchronizeing, and for the first desulfurization adsorption tower 110 and the second desulfurization adsorption tower 210 provide suitable activated coke, simultaneously the activated coke of discharging after its reaction are carried out processing and regenerating and recycle in real time.
Embodiment bis-:
The present embodiment is a concrete application of the present invention, is three kinds of situations that different flue gases are processed simultaneously that three different workshop sections are discharged.
The exhaust gas volumn of the first workshop section is 280000Nm 3/ h, SO 2Concentration is 2400mg/Nm 3, flue-gas temperature is 70 ℃.The exhaust gas volumn of the second workshop section is 110000Nm 3/ h, SO 2Concentration is 1500mg/Nm 3, flue-gas temperature is 75 ℃.The first workshop section and the second workshop section are mixed into the first desulfurization fume pipeline, and its exhaust gas volumn is 390000Nm 3/ h, SO 2Concentration is 2146mg/Nm 3, flue-gas temperature is 71.4 ℃, the first desulfurization fume pipeline enters the first desulfurization adsorption tower through air door and carries out SO 2Absorption, purifying smoke enters the first purifying smoke pipeline, SO 2Concentration is 120mg/Nm 3.The exhaust gas volumn 20000Nm of the 3rd workshop section 3/ h, SO 2Concentration is 2400mg/Nm 3, temperature is 130 ℃, directly imports the second desulfurization fume pipeline and enters the second desulfurization adsorption tower and carry out SO through air door 2Absorption, after purifying, flue gas enters the second purifying smoke pipeline, SO 2Concentration is 150mg/Nm 3, then, the flue gas in the first purifying smoke pipeline and the second purifying smoke pipeline jointly enters chimney and discharges.Wherein, the first desulfurization adsorption tower desulfuration efficiency is that 94.4%, the second desulfurization adsorption tower desulfuration efficiency is 93.7%, realizes SO 2Safety and efficient desorption.
The activated coke of discharging from the first discharging discharger of the first desulfurization adsorption tower below be arranged on the fresh activated coke that the batcher on the first conveyer adds and be delivered to screening plant by the first conveyer, activated coke enters the second tower top feed bin by the second charging discharger after screening, and then enter in the second desulfurization adsorption tower and carry out the high-temperature flue gas desulfurization, activated coke after desulfurization is discharged and is entered second conveyor through the second discharging discharger of the second desulfurization adsorption tower below, and deliver to regeneration reactor by second conveyor, successively through the thermal treatment zone, renewing zone, cooling zone completes regeneration, by the 3rd discharging discharger, enter the 3rd conveyer and enter the first tower top feed bin, realize recycling and efficient desorption of activated coke, save energy consumption, reduce operating cost.
Certainly the present invention also can be used for the above flue gas of three workshop sections, can extend enforcement according to the present embodiment, within all falling into protection scope of the present invention.
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.

Claims (10)

1. energy-efficient synthesis desulfurating cleaning system of the activated coke for different flue gases is characterized in that:
Comprise the first adsorption desulfurize section, the second adsorption desulfurize section, activated coke regenerator section and activated coke conveying equipment;
Described the first adsorption desulfurize section comprises the first desulfurization adsorption tower purified for different flue gas desulfurization, for importing the first desulfurization fume pipeline of different flue gases and be used to importing the first tower top feed bin of activated coke, described the first desulfurization fume pipeline conducting is connected to the bottom of described the first desulfurization adsorption tower, and described the first tower top feed bin conducting is connected to the top of described the first desulfurization adsorption tower;
Described the second adsorption desulfurize section comprises the second desulfurization adsorption tower purified for different flue gas desulfurization, for importing the second desulfurization fume pipeline of different flue gases and be used to importing the second tower top feed bin of activated coke, described the second desulfurization fume pipeline conducting is connected to the bottom of described the second desulfurization adsorption tower, and described the second tower top feed bin conducting is connected to the top of described the second desulfurization adsorption tower;
Described activated coke regenerator section comprises the regeneration reactor for activated coke regeneration;
Described activated coke conveying equipment comprises be used to the screening plant that sieves activated coke, the first conveyer, second conveyor and the 3rd conveyer be used to transferring activated coke;
Described the first desulfurization adsorption tower bottom is connected in series successively for the first feed opening, described the first conveyer, described screening plant and the described second tower top feed bin of discharging the activated coke of reacting through the first desulfurization adsorption tower, described the second desulfurization adsorption tower bottom is connected to the activated coke charging aperture of described regeneration reactor for second feed opening of discharging the activated coke of reacting through the second desulfurization adsorption tower by described second conveyor, the activated coke discharging opening of described regeneration reactor is connected on described the first tower top feed bin by the 3rd conveyer.
2. the energy-efficient synthesis desulfurating cleaning system of the activated coke for different flue gases as claimed in claim 1 is characterized in that: also comprise and be used to system to add the batcher of fresh activated coke, described batcher is connected on described the first conveyer.
3. the energy-efficient synthesis desulfurating cleaning system of the activated coke for different flue gases as claimed in claim 1, it is characterized in that: described the first desulfurization adsorption tower is cross-flow moving bed structure, described the second desulfurization adsorption tower is the adverse current bed structure.
4. the energy-efficient synthesis desulfurating cleaning system of the activated coke for different flue gases as claimed in claim 1, it is characterized in that: described the first desulfurization adsorption tower can be single or multiple desulfurization adsorption tower parallel-connection structures.
5. the energy-efficient synthesis desulfurating cleaning system of the activated coke for different flue gases as claimed in claim 1, is characterized in that: in described regeneration reactor, be provided with the thermal treatment zone, renewing zone and the cooling zone that distribute from top to bottom; The described regeneration reactor outside also is provided with the one-way circulation closed-loop system be connected with the conducting of the described thermal treatment zone, described one-way circulation closed-loop system comprises circulating fan and thermal source, the input port conducting of described circulating fan is connected to the top of the described thermal treatment zone, and the delivery outlet of described circulating fan leads to and connects by the lower guide of described thermal source and the described thermal treatment zone.
6. the energy-efficient synthesis desulfurating cleaning system of the activated coke for different flue gases as claimed in claim 1, it is characterized in that: described the first conveyer, second conveyor and/or the 3rd conveyer are bucket conveyor.
7. the energy-efficient synthesis desulfurating cleaning system of the activated coke for different flue gases as claimed in claim 1, it is characterized in that: be provided with the first charging unloader between described the 3rd conveyer and described the first tower top feed bin, between described the first feed opening and described the first conveyer, be provided with the first discharging unloader, between described screening plant and described the second tower top feed bin, be provided with the second charging unloader, between described the second feed opening and described second conveyor, be provided with the second discharging unloader, between described second conveyor and described regeneration reactor, be provided with the 3rd charging unloader, between described regeneration reactor and described the 3rd conveyer, be provided with the 3rd discharging unloader,
Described the first charging unloader, the first discharging unloader, the second charging unloader and the second discharging unloader are the star-like discharger of single spool, and described the 3rd charging unloader and the 3rd discharging unloader are the star-like discharger of double spool.
8. the energy-efficient synthesis desulfurating cleaning system of the activated coke for different flue gases as claimed in claim 1, it is characterized in that: also comprise a chimney for flue gas after emission purification, described the first desulfurization adsorption tower is connected on described chimney by the first purifying smoke pipeline, described the second desulfurization adsorption tower is connected on described chimney by the second purifying smoke pipeline, is provided be used to controlling the air door of flue gas flow on described the first desulfurization fume pipeline, the second desulfurization fume pipeline, the first purifying smoke pipeline and/or described the second purifying smoke pipeline.
9. energy-efficient synthesis desulfurating purification method of the activated coke for different flue gases is characterized in that:
Adopt the energy-efficient synthesis desulfurating cleaning system of the claim described activated coke for different flue gases of 1-8 any one to carry out the desulfurizing and purifying of different flue gases, comprise the flue gas desulfurization step and activated coke regeneration and the circulation step that synchronously carry out;
The flue gas desulfurization step: different flue gases are converged and import described the first desulfurization fume pipeline and/or described the second desulfurization fume pipeline, and different flue gases have reacted Dry FGD with activated coke in described the first desulfurization adsorption tower and/or described the second desulfurization adsorption tower;
Activated coke regeneration and circulation step: the fresh activated coke that the activated coke of discharging from the first feed opening of the first desulfurization adsorption tower and batcher add is sent into screening plant by the first conveyer and is sieved, and the activated coke that meets the desulfurization requirement enters the second tower top feed bin and then enters the second desulfurization adsorption tower and adsorb SO 2Activated coke after absorption is discharged from the second feed opening of the second desulfurization adsorption tower bottom, enter second conveyor, by second conveyor, sent in regeneration reactor, by the thermal treatment zone, renewing zone, cooling zone, activated coke is regenerated successively, activated coke after regeneration is discharged and is sent into the first tower top feed bin by the 3rd conveyer by the activated coke discharging opening, and activated coke enters the first desulfurization adsorption tower absorption SO 2, then discharged by the first feed opening of the first desulfurization adsorption tower, enter next time and recycle.
10. the energy-efficient synthesis desulfurating purification method of the activated coke for different flue gases as claimed in claim 9, it is characterized in that: the flue-gas temperature that described the first desulfurization fume pipeline imports is 50-100 ℃, and the flue-gas temperature that described the second desulfurization fume pipeline imports is over 100 ℃.
CN201310371346.8A 2013-08-22 2013-08-22 Energy-efficient comprehensive desulfurization and purification system and method for active coke of different flue gases Active CN103405991B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310371346.8A CN103405991B (en) 2013-08-22 2013-08-22 Energy-efficient comprehensive desulfurization and purification system and method for active coke of different flue gases

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310371346.8A CN103405991B (en) 2013-08-22 2013-08-22 Energy-efficient comprehensive desulfurization and purification system and method for active coke of different flue gases

Publications (2)

Publication Number Publication Date
CN103405991A true CN103405991A (en) 2013-11-27
CN103405991B CN103405991B (en) 2015-04-08

Family

ID=49599060

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310371346.8A Active CN103405991B (en) 2013-08-22 2013-08-22 Energy-efficient comprehensive desulfurization and purification system and method for active coke of different flue gases

Country Status (1)

Country Link
CN (1) CN103405991B (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106994287A (en) * 2017-05-11 2017-08-01 国电科学技术研究院 A kind of system and method for coal fired power plant flue gas dry desulfurizing denitration
CN107126811A (en) * 2017-06-27 2017-09-05 西安西热锅炉环保工程有限公司 Desulfurization system based on phase change active coke dry method
WO2018000888A1 (en) * 2016-06-30 2018-01-04 中冶长天国际工程有限责任公司 Flue gas desulfurization and denitrification method and device capable of preventing corrosion
CN110385029A (en) * 2018-04-20 2019-10-29 中国石化工程建设有限公司 Activated coke flue gas purification system and method
WO2019214272A1 (en) * 2018-05-10 2019-11-14 中冶长天国际工程有限责任公司 Centralized and independent multi-working condition flue gas purifying treatment system and control method therefor

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102886190A (en) * 2012-10-20 2013-01-23 福建鑫泽环保设备工程有限公司 Technique for desulfurizing flue gas by using activated cokes and device used in technique
CN203425681U (en) * 2013-08-22 2014-02-12 上海克硫环保科技股份有限公司 Efficient energy-conservation integrated activated coke desulfurization purification system for different flue gases

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102886190A (en) * 2012-10-20 2013-01-23 福建鑫泽环保设备工程有限公司 Technique for desulfurizing flue gas by using activated cokes and device used in technique
CN203425681U (en) * 2013-08-22 2014-02-12 上海克硫环保科技股份有限公司 Efficient energy-conservation integrated activated coke desulfurization purification system for different flue gases

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018000888A1 (en) * 2016-06-30 2018-01-04 中冶长天国际工程有限责任公司 Flue gas desulfurization and denitrification method and device capable of preventing corrosion
CN107551756A (en) * 2016-06-30 2018-01-09 中冶长天国际工程有限责任公司 Prevent the flue gas desulfurization and denitration method and device of corrosion
CN106994287A (en) * 2017-05-11 2017-08-01 国电科学技术研究院 A kind of system and method for coal fired power plant flue gas dry desulfurizing denitration
CN107126811A (en) * 2017-06-27 2017-09-05 西安西热锅炉环保工程有限公司 Desulfurization system based on phase change active coke dry method
CN110385029A (en) * 2018-04-20 2019-10-29 中国石化工程建设有限公司 Activated coke flue gas purification system and method
WO2019214272A1 (en) * 2018-05-10 2019-11-14 中冶长天国际工程有限责任公司 Centralized and independent multi-working condition flue gas purifying treatment system and control method therefor
KR20200066693A (en) * 2018-05-10 2020-06-10 종예 창티엔 인터내셔날 엔지니어링 컴퍼니 리미티드 Independent purification treatment system and control method for flue gas concentration under multiple working conditions
RU2753521C1 (en) * 2018-05-10 2021-08-17 Чжуне Чантянь Интернешнал Энджиниринг Ко., Лтд Centralized and autonomous waste gas treatment system for multiple work processes and how to manage it
KR102318354B1 (en) * 2018-05-10 2021-10-27 종예 창티엔 인터내셔날 엔지니어링 컴퍼니 리미티드 Flue gas concentration independent purification treatment system under multiple working conditions and control method thereof

Also Published As

Publication number Publication date
CN103405991B (en) 2015-04-08

Similar Documents

Publication Publication Date Title
CN109794146B (en) Grate-rotary kiln SNCR/SCR denitration and active coke desulfurization combined system and process
CN103349892B (en) A kind of cross-current type twin-stage moving-bed active coke waste gas integrated purification tower
CN104195326A (en) Sintering energy-saving technique and system capable of removing multiple pollutants
CN107596798B (en) Pre-dedusting, desulfurizing and denitrating integrated treatment device and method
CN105688566A (en) Desulfurization and denitrification device and method for sintering flue gas
CN103405991B (en) Energy-efficient comprehensive desulfurization and purification system and method for active coke of different flue gases
CN204365100U (en) A kind of regenerative system of desulphurization denitration activated coke
CN102008893A (en) Low temperature SCR moving bed flue gas denitration method for coal-fired boiler
CN213132673U (en) Grate-rotary kiln pelletizing flue gas classification denitrification facility
CN102728217A (en) Method and system for jointly desulfuration, denitration and demercuration by activated coke of moving bed
CN103007677A (en) Movable desorption and regeneration system and method for active coke
CN112268293A (en) Large-scale thermal power generating unit flue gas active coke purification system and method
CN102380295A (en) Waste rubber cracking gas purifying process and equipment thereof
CN107115775B (en) Iron ore sintering flue gas sectional enrichment self-heat exchange emission reduction SOxAnd NOxMethod of producing a composite material
CN104826489A (en) Activated carbon and low temperature catalyst-based combined desulfurization denitration fluidized bed device
CN205145970U (en) Charcoal base catalyst SOx/NOx control system
CN208177248U (en) It is a kind of based on active carbon/coke coke oven flue gas system for desulfuration and denitration
CN211659714U (en) Combined flue gas circulation, grading purification and waste heat utilization device for multiple sintering machines
CN112915724A (en) Integrated removal system and method for multiple pollutants in flue gas
CN210079219U (en) Active coke combined desulfurization and denitrification system
CN108870988A (en) A kind of sintering smoke purifying system and its purification method
CN203425681U (en) Efficient energy-conservation integrated activated coke desulfurization purification system for different flue gases
CN104707470B (en) Activated coke/soot desulfurization and desorbing integrated system
CN107930396B (en) Method for concentrated and efficient desulfurization and denitrification of sintering flue gas
CN210560242U (en) System for optimizing configuration and comprehensively treating coking tail gas

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant