CN103371176A - Glufosinate-ammonium-containing pesticide composition - Google Patents
Glufosinate-ammonium-containing pesticide composition Download PDFInfo
- Publication number
- CN103371176A CN103371176A CN2012101260948A CN201210126094A CN103371176A CN 103371176 A CN103371176 A CN 103371176A CN 2012101260948 A CN2012101260948 A CN 2012101260948A CN 201210126094 A CN201210126094 A CN 201210126094A CN 103371176 A CN103371176 A CN 103371176A
- Authority
- CN
- China
- Prior art keywords
- ammonium phosphine
- careless ammonium
- weeds
- weed
- mesotrione
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a glufosinate-ammonium-containing pesticide composition which is mainly characterized by containing 1-80% of effective component A glufosinate-ammonium and 1-60% of effective component B, wherein the effective component B is selected from any one of the following weedicides: pyraflufen-ethyl, diflufenican and mesotrione. The glufosinate-ammonium-containing pesticide composition is prepared into wettable powder, water-dispersible granules, aqueous emulsion, oil suspending agent or microemulsion. The pesticide composition provided by the invention is used for controlling pesticide.
Description
Technical field
The invention belongs to technical field of pesticide, be specifically related to a kind of composition pesticide that contains careless ammonium phosphine, be used for controlling weeds.
Background technology
The direction of pesticide developing was to embody efficient, low toxicity, low-residual and pollution-free in recent years.Be embodied in pursuit " three height ", namely (1) is safe, and this not only requires toxicity low, and is residual low, and nuisanceless; (2) biologically active is high; (3) selectivity is high.Therefore continue to improve the performance of present Pesticidal products, reach efficient, low toxicity, free of contamination requirement.So, select the agricultural chemicals of composite mixture just to become current first-selection and a kind of effective approach, be that the agricultural chemicals of performance complement obtains best synergistic effect by the proportioning of adjusting different agricultural chemicals.
Grass ammonium phosphine (glufosinate-ammonium) chemical name: (RS)-2-amino-4-(hydroxymethyl oxygen see base) butyric acid ammonium, molecular formula: C
5H
13N
2O
4P.Grass ammonium phosphine belongs to the acid herbicides of seeing, and is glutamine synthetase inhibitor, has the non-selective contact weedicide of part systemic action.In the short time, disorder is sunk in the ammonium metabolism in the plant corpus after the dispenser, and the cytotoxic agent ammonium ion is accumulated in plant corpus, and meanwhile, photosynthesis is reached the weeding purpose by severe inhibition.
Pyrrole grass ether (pyraflufen-ethyl) chemical name: 2-chloro-5-(4-chloro-5-difluoro-methoxy-1-methylpyrazole-3-yl)-4-fluorophenoxy ethyl acetate, molecular formula: C
15H
13C
12F
3N
2O
4This medicine is the phenylpyrazole class herbicide after seedling of tagging property, its mechanism of action is protoporphyrin 4 oxidase that suppress in the plant corpus, and utilize wheat and weeds to the metabolite of the different activities that difference produces of medicine absorption and deposition, reach the effect of optionally preventing and treating the wheatland weeds.
Diflufenican (diflufenican) chemical name: N-(2,4-difluorophenyl)-2-(3-4-trifluoromethylphenopendant)-3-pyridine anilide, molecular formula: C
19H
11F
5N
2O
2Diflufenican is used the medicine soil layer that can form at the soil table anti-leaching before and after weeds germinate, keep active whole vegetative period crop.When weed germination all can absorb medicament by medicine soil layer young shoot or root system, this agent has the carotenoid of inhibition biosynthesis effect, carotenoid content descends in the weeds plant of absorption medicament, cause chlorophyll destroyed, membranolysis, weeds then show as young shoot decolouring or white, and last whole strain is wilted dead.
Mesotrione (mesotrione) chemical name: 2-(2-nitro-4-mesyl benzene adds acyl) cyclohexane-1,3-diketone, molecular formula: C
14H
13NO
7S.Mesotrione suppresses the activity of PHPPA dioxygenase (HPPD), and HPPD can be converted into plastoquinone with amino acid Lip river propylhomoserin.Plastoquinone is the co-factor of phytoene desaturase, is the biosynthetic key enzyme of carotenoid.Use 3-5 days implants meristematic tissue of mesotrione the yellow symptom to occur and cause withered spot thereupon, spread all over whole strain plant behind the fortnight.
The chemical composition of each weed killer herbicide, formation and physic-chemical property all are distinguishing.Therefore, their herbicide ability and scope are also different.Some weed killer herbicide herbicide spectrum is narrower, but has one's own knack, and can eradicate the weeds that are difficult to eliminate with other weed killer herbicide.
Along with further developing of weed killer herbicide production and application, using with gradually between the weed killer herbicide grows up.China also comparatively payes attention to using with aspect the research of weed killer herbicide, extensively is recognized as one of important measures that weed killer herbicide rationally uses, and has worked out a series of Herbicidal compositions, has obtained greater advance.
My company also is devoted to the research and development of Herbicidal compositions.At present, have no report about careless ammonium phosphine with the relevant composite product of pyrrole grass ether, diflufenican, mesotrione.
Summary of the invention
The composition pesticide that the purpose of this invention is to provide careless ammonium phosphine of containing of a kind of controlling weeds.
Technical scheme of the present invention is:
A kind of composition pesticide that contains careless ammonium phosphine, composition pesticide contain effective constituents A grass ammonium phosphine 1%～80%, active ingredient B1%～60%, and wherein active ingredient B is selected from a kind of in pyrrole grass ether, diflufenican, the mesotrione.Composition pesticide preferably contains careless ammonium phosphine 5%～70%, and active ingredient B 1%～40%; Composition pesticide more preferably contains careless ammonium phosphine 10%～60%, pyrrole grass ether 1%～20%; Contain careless ammonium phosphine 10%～50%, diflufenican 5%～35%; Contain careless ammonium phosphine 10%～50%, mesotrione 5%～30%.
Described composition pesticide, composition is made any formulation of agricultural chemicals, be wetting powder, water dispersible granules, oil-suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspending agent more preferably, most preferably be wetting powder, water dispersible granules, aqueous emulsion, oil-suspending agent, microemulsion.
Described auxiliary agent and excipients comprise: dispersant, wetting agent, disintegrant, emulsifier, solvent, antifreeze, defoamer, thickener, filler, deionized water.
When making wetting powder, composition comprises following constituent content: active components A 1%～80%, active component B 1%～60%, dispersant 1%～12%, wetting agent 1%～8%, filler surplus.
When making water dispersible granules, composition comprises following constituent content: active components A 1%～80%, active component B 1%～60%, dispersant 1%～12%, wetting agent 1%～10%, disintegrant 1%～10%, binding agent 0～8%, filler surplus.
Comprise following constituent content when composition is made aqueous emulsion: active components A 1%～50%, active component B 1%～40%, solvent 0～30%, emulsifier 1%～15%, antifreeze 0～8%, thickener 0～2%, defoamer 0.01%～2%, deionized water add to 100%.
Comprise following constituent content when composition is made oil-suspending agent: active components A 1%～50%, active component B 1%～40%, dispersant 1%～10%, wetting agent 2%～10%, defoamer 0.01%～1%, thickener 0～2%, antifreeze 0～8%, solvent add to 100%.
Comprise following constituent content when composition is made microemulsion: active components A 1%～50%, active component B 1%～40%, solvent 0～30%, emulsifier 3%～25%, antifreeze 0～8%, thickener 0～2%, defoamer 0.01%～2%, stabilizing agent 0～4%, deionized water adds to 100%.
Comprise following constituent content when composition is made suspension emulsion: active components A 1%～50%, active component B 1%～40%, solvent 0～15%, emulsifier 1%～10%, dispersant 1%～10%, defoamer 0.01%～2%, thickener 0～2%, antifreeze 0～8%, stabilizing agent 0～3%, deionized water add to 100%.
When making microcapsule suspending agent, composition comprises following constituent content: active components A 1%～50%, active component B 1%～40%, macromolecule cyst material 2%～10%, dispersant 1%～10%, organic solvent 0～10%, emulsifier 1%～7%, pH adjusting agent 0.01%～5%, deionized water adds to 100%.
Composition comprises following constituent content when making microcapsule suspension-suspending agent: active components A 1%～50%, active component B1%～40%, macromolecule cyst material 2%～10%, dispersant 1%～12%, wetting agent 1%～8%, organic solvent 1%～15%, emulsifier 1%～6%, defoamer 0.01%～2%, thickener 0～2%, pH adjusting agent 0.01%～5%, deionized water add to 100%.
Wetting powder the key technical indexes of the present invention:
Water dispersible granules the key technical indexes of the present invention:
Aqueous emulsion the key technical indexes of the present invention:
Oil-suspending agent the key technical indexes of the present invention:
Microemulsion the key technical indexes of the present invention:
Suspension emulsion the key technical indexes of the present invention:
Microcapsule suspending agent the key technical indexes of the present invention:
Microcapsule suspension of the present invention-suspending agent the key technical indexes:
Composition pesticide of the present invention compared with prior art produces following beneficial effect:
Can enlarge herbicidal spectrum, improve herbicidal effect, prolong the optimum period for applying fertilizer, reduce poisoning, reduce residual activity, delay the drug-fast generation of weed killer herbicide and development by using with of weed killer herbicide, quick-acting is good, to succession crop safety.
Herbicidal combinations of the present invention is used for the multiple weeds of control uncultivated area, orchard, tea place, no-tillage field, sugarcane field, Cotton Fields, Spring Maize, sisal hemp garden, wooden land, mulberry field, forest.
Multiple weeds comprise: grassy weed, broad leaved weed, sedge weed, annual weed, perennial weed.
Embodiment
Below in conjunction with embodiment to further instruction of the present invention.
Implementation of an application example one:
Grass ammonium phosphine and active ingredient B are mixed to the active determination test report of weeds
Test objective: under the greenhouse pot culture condition, measured careless ammonium phosphine and active ingredient B and different blended combo thereof and closed herbicidal effect to the target weeds, and estimated its synergy, for formulation development and the agriculture chemical registration field control effectiveness test of Mixed Pharmacy provides scientific basis.
For trying target: grassy weed (Gramineous weeds); Broad leaved weed (Broadleaf weeds); Sedge weed (Cyperaceae secco weeds);
Test medicine: careless ammonium phosphine (glufosinate-ammonium) 95% former medicine; pyrrole grass ether (pyraflufen-ethyl) 95% former medicine; diflufenican (diflufenican) 98% former medicine; mesotrione (mesotrione) 94% former medicine provides by Shaanxi Welch Crop Protection Co., Ltd..
The medicament configuration:
Grass ammonium phosphine solution: accurately take by weighing 0.2141g 95% Glufosinate-ammonium, dissolve with 0.2mLDMF, add the clear water 400mL that contains the 0.1%TWEEN80 emulsifier, stir, be configured to careless ammonium phosphine 800g (a.i.)/ha solution, it is for subsequent use to be diluted to 500g (a.i.)/ha, 300g (a.i.)/ha, 100g (a.i.)/ha, 5g (a.i.)/ha concentration with clear water again.
Pyrrole grass ethereal solution: accurately take by weighing the former medicine of 0.0812g 95% pyrrole grass ether, dissolve with 0.2mLDMF, add the clear water 400mL that contains the 0.1%TWEEN80 emulsifier, stir, be configured to pyrrole grass ether 300g (a.i.)/ha solution, it is for subsequent use to be diluted to 50g (a.i.)/ha, 12g (a.i.)/ha, 10g (a.i.)/ha, 5g (a.i.)/ha concentration with clear water again.
Diflufenican solution: accurately take by weighing the former medicine of 0.0778g 98% diflufenican, dissolve with 0.2mLDMF, add the clear water 400mL that contains the 0.1%TWEEN80 emulsifier, stir, be configured to diflufenican 300g (a.i.)/ha solution, it is for subsequent use to be diluted to 250g (a.i.)/ha, 150g (a.i.)/ha, 125g (a.i.)/ha, 10g (a.i.)/ha concentration with clear water again.
Mesotrione solution: accurately take by weighing the former medicine of 0.0812g 94% mesotrione, dissolve with 0.2mLDMF, add the clear water 400mL that contains the 0.1%TWEEN80 emulsifier, stir, be configured to mesotrione 300g (a.i.)/ha solution, it is for subsequent use to be diluted to 150g (a.i.)/ha, 100g (a.i.)/ha, 25g (a.i.)/ha, 10g (a.i.)/ha concentration with clear water again.
Blank solution: 0.2mLDMF adds the water of 400mL 0.1%TWEEN80 emulsifier.
Test method: adopt potted plant cauline leaf facture (NY/T 1155.4-2006): at the in-built quantitative soil of the polypots of high 6cm, diameter 9cm, will be for 15～20 sowings of examination target weed seed in polypots, be placed on cultivation in the greenhouse after covering the thick fine earth of 0.5～1cm, treat that weeds grew to for 1～4 leaf phase and carry out cauline leaf spraying processing, every alms bowl spraying liquid 1mL, every processing repeats 4 times, and establishes the contrast that is treated to that does not contain medicament.Processing is placed in the greenhouse cultivates, the growing state of routine observation target weeds, and be injured symptom and growth inhibition situation of range estimation target behind the 15d, and claim acrial part fresh weight or strain fresh weight, estimate medicament to the toxicity action of target weeds with form fresh weight inhibiting rate.
Investigation method:
Range estimation target be injured symptom and growth inhibition situation are processed behind the 15d in test, and claim to calculate fresh weight inhibiting rate (%) by the acrial part fresh weight.
The synergy evaluation method:
Estimate weed killer herbicide mode of application (NY/T 1155.7-2006) according to the Gowing method, its formula is as follows:
E
0＝X+Y-XY/100
In the formula, X is careless ammonium phosphine fresh weight inhibiting rate to target weeds when alone with certain dosage; Y is active ingredient B fresh weight inhibiting rate to target weeds when alone with certain dosage; E
0During for careless ammonium phosphine and two kinds of pharmacy mix of active ingredient B to the theoretical value of target weeds fresh weight inhibiting rate; When E is careless ammonium phosphine and two kinds of pharmacy mix of active ingredient B to the measured value of target weeds fresh weight inhibiting rate.Active ingredient B is a kind of in pyrrole grass ether, diflufenican, the mesotrione.
Evaluation criterion: work as E-E
0Be expressed as synergistic effect in the time of＞10%, as-10%≤E-E
0Be expressed as summation action in the time of≤10%, work as E-E
0Be expressed as antagonism in the time of＜-10%.
Measurement result one
The careless ammonium phosphine of table 1 and pyrrole grass ether and the toxicity test result of combination to grassy weed that be mixed thereof
Evaluating drug effect: careless ammonium phosphine and pyrrole grass ether and the composition that is mixed thereof see Table 1 to the herbicidal effect measurement result of grassy weed.As seen, careless ammonium phosphine and pyrrole grass ether all shows synergistic effect with 5+50,5+300,250+10,450+10,450+12,450+16,650+12,650+16,650+50,650+300,800+10,800+16, the 800+50 composition that is mixed to grassy weed.
Measurement result two
The careless ammonium phosphine of table 2 and diflufenican and the toxicity test result of combination to broad leaved weed that be mixed thereof
Evaluating drug effect: careless ammonium phosphine and diflufenican and the composition that is mixed thereof see Table 2 to the herbicidal effect measurement result of broad leaved weed.As seen, careless ammonium phosphine and diflufenican all show synergistic effect to broad leaved weed with 5+10,5+50,5+300,100+10,100+250,300+50,300+150,500+50,500+150,800+10,800+50, the 800+150 composition that is mixed.
Measurement result three
The careless ammonium phosphine of table 3 and mesotrione and the toxicity test result of combination to sedge weed that be mixed thereof
Evaluating drug effect: careless ammonium phosphine and mesotrione and the composition that is mixed thereof see Table 3 to the herbicidal effect measurement result of sedge weed.As seen, careless ammonium phosphine and mesotrione all show synergistic effect to sedge weed with 5+100,5+300,100+10,100+25,300+10,300+25,500+25,500+100,800+10,800+100, the composition that is mixed.
Application Example two: the careless ammonium phosphine composite product embodiments (following content is and amounts to percentage composition) of being correlated with.
Embodiment 1～8 wetting powder
Careless ammonium phosphine, active ingredient B, dispersant, wetting agent, filler are mixed in mixed cylinder, mix after airslide disintegrating mill is pulverized again, namely can be made into careless ammonium phosphine active ingredient B wetting powder product, concrete prescription sees Table 4.
Table 4 embodiment 1～8 each component and weight portion
Pyrrole grass ether, diflufenican, mesotrione exchange in will showing, and can make novel formulation.
Embodiment 9～16 water dispersible granules
Careless ammonium phosphine, active ingredient B, dispersant, wetting agent, disintegrant, filler etc. are obtained the particle diameter that needs through air-flow crushing together, add again other auxiliary agents such as binding agent, obtain the materials of granulating.With item quantitatively send in the fluidized bed granulation dryer through granulation and drying after, make careless ammonium phosphine active ingredient B water dispersible granules product, concrete prescription sees Table 5.
Table 5 embodiment 9～16 each component and weight portions
Pyrrole grass ether, diflufenican, mesotrione exchange in will showing, and can make novel formulation.
Embodiment 17～24 aqueous emulsions
Careless ammonium phosphine, active component B, solvent, emulsifier are added together, make and be dissolved into even oil phase; Deionized water, antifreeze, thickener, defoamer are mixed, become the homogeneous water.Under high-speed stirred, water is added oil phase, surplus is supplied with deionized water; Can make aqueous emulsion product of the present invention, concrete prescription sees Table 6,7.
Table 6 embodiment 17～20 each component and weight portions
Table 7 embodiment 21～24 each component and weight portions
Pyrrole grass ether, diflufenican, mesotrione exchange in will showing, and can make novel formulation.
Embodiment 25～33 oil-suspending agents
Careless ammonium phosphine, active ingredient B, dispersant, wetting agent, defoamer, thickener, antifreeze are mixed through high speed shear, add former medicine, ball milling is 2～3 hours in ball mill, make diameter of particle all below 5 μ m, solvent is supplied surplus, make careless ammonium phosphine active ingredient B suspending agent product, concrete prescription sees Table 8.
Table 8 embodiment 25～29 each component and weight portions
Pyrrole grass ether, diflufenican, mesotrione exchange in will showing, and can make novel formulation.
Embodiment 34～37 microemulsions
Careless ammonium phosphine, active component B, solvent, emulsifier, antifreeze, thickener, defoamer fully are mixed into the oil phase of homogeneous transparent, under agitation slowly add deionized water, form WO emulsion, again through agitating heating, make it rapid phase inversion and become oil-in-water type, be chilled to room temperature and make it to reach balance, after filtration, surplus is supplied with deionized water; Can make microemulsion product of the present invention, specifically see Table 10.
Table 10 embodiment 34～37 each component and weight portions
Pyrrole grass ether, diflufenican, mesotrione exchange in will showing, and can make novel formulation.
Application Example three: careless ammonium phosphine and the active component B control uncultivated area weeds test of pesticide effectiveness
The control medicament: careless ammonium phosphine and pyrrole grass ether, diflufenican, mesotrione complex composition, produced by Shaanxi Welch Crop Protection Co., Ltd.'s research and development;
Contrast medicament: 18% careless ammonium phosphine soluble concentrate (commercial); 2% pyrrole grass ether suspending agent (commercial); 15% diflufenican suspending agent (autogamy); 9% mesotrione suspending agent (commercial).
If artificial weeding and clear water control treatment.
Using method: every mu be watered 35 liters after evenly cauline leaf sparge in each residential quarter
Spraying time: in the weeds in field 1-4 leaf phase, carry out cauline leaf spraying 1 time.
Investigation method and drug effect are calculated
Investigation weeds object is: grassy weed, broad leaved weed, sedge weed, 10 days, 30 days strain preventive effects to weeds behind the investigation medicine.
The visual test medicament occurs without poisoning crop.
The careless ammonium phosphine of the table 11 active component B built composition for preventing and controlling uncultivated area weeds test of pesticide effectiveness
Careless ammonium phosphine and active component B are composite as shown in Table 11 has good control efficiency to uncultivated area weeds such as grassy weed, broad leaved weed, sedge weeds, preventive effect is better than the single dose preventive effect, with contrast medicament, artificial weeding, remarkable with respect to the rate of growth difference of clear water control treatment, and have preferably quick-acting and lasting effect, in this experimental drug scope, to crop safety.
Application Example four: careless ammonium phosphine and the active component B control apple orchard weeds test of pesticide effectiveness
The control medicament: careless ammonium phosphine and pyrrole grass ether, diflufenican, mesotrione complex composition, produced by Shaanxi Welch Crop Protection Co., Ltd.'s research and development;
Contrast medicament: 18% careless ammonium phosphine soluble concentrate (commercial); 2% pyrrole grass ether suspending agent (commercial); 15% diflufenican suspending agent (autogamy); 9% mesotrione suspending agent (commercial).
If artificial weeding and clear water control treatment.
Using method: every mu be watered 35 liters after evenly cauline leaf sparge in each residential quarter
Spraying time: in the weeds in field 1-4 leaf phase, carry out cauline leaf spraying 1 time.
Investigation method and drug effect are calculated
Investigation weeds object is: annual weed, perennial weed, 10 days, 30 days strain preventive effects to weeds behind the investigation medicine.
The visual test medicament occurs without poisoning crop.
The careless ammonium phosphine of the table 12 active component B built composition for preventing and controlling apple orchard weeds test of pesticide effectiveness
Careless ammonium phosphine and active component B is composite that the apple orchard weeds such as annual weed, perennial weed are had good control efficiency as shown in Table 12, preventive effect is better than the single dose preventive effect, with contrast medicament, artificial weeding, remarkable with respect to the rate of growth difference of clear water control treatment, and have preferably quick-acting and lasting effect, in this experimental drug scope, to crop safety.
Application Example five: careless ammonium phosphine and active component B prevent and treat no-tillage Weed Control Efficacy
The control medicament: careless ammonium phosphine and pyrrole grass ether, diflufenican, mesotrione complex composition, produced by Shaanxi Welch Crop Protection Co., Ltd.'s research and development;
Contrast medicament: 18% careless ammonium phosphine soluble concentrate (commercial); 2% pyrrole grass ether suspending agent (commercial); 15% diflufenican suspending agent (autogamy); 9% mesotrione suspending agent (commercial).
If artificial weeding and clear water control treatment.
Using method: every mu be watered 35 liters after evenly cauline leaf sparge in each residential quarter
Spraying time: in the weeds in field 1-4 leaf phase, carry out cauline leaf spraying 1 time.
Investigation method and drug effect are calculated
Investigation weeds object is: grassy weed, broad leaved weed, sedge weed, 10 days, 30 days strain preventive effects to weeds behind the investigation medicine.
The visual test medicament occurs without poisoning crop.
The no-tillage Weed Control Efficacy of the careless ammonium phosphine of table 13 active component B built composition for preventing and controlling
Careless ammonium phosphine and active component B are composite as shown in Table 13 has good control efficiency to no-tillage field weeds such as grassy weed, broad leaved weed, sedge weeds, preventive effect is better than the single dose preventive effect, with contrast medicament, artificial weeding, remarkable with respect to the rate of growth difference of clear water control treatment, and have preferably quick-acting and lasting effect, in this experimental drug scope, to crop safety.
Application Example six: careless ammonium phosphine and the active component B control weed in tea garden test of pesticide effectiveness
The control medicament: careless ammonium phosphine and pyrrole grass ether, diflufenican, mesotrione complex composition, produced by Shaanxi Welch Crop Protection Co., Ltd.'s research and development;
Contrast medicament: 18% careless ammonium phosphine soluble concentrate (commercial); 2% pyrrole grass ether suspending agent (commercial); 15% diflufenican suspending agent (autogamy); 9% mesotrione suspending agent (commercial).
If artificial weeding and clear water control treatment.
Using method: every mu be watered 35 liters after evenly cauline leaf sparge in each residential quarter
Spraying time: in the weeds in field 1-4 leaf phase, carry out cauline leaf spraying 1 time.
Investigation method and drug effect are calculated
Investigation weeds object is: annual weed, perennial weed, 10 days, 30 days strain preventive effects to weeds behind the investigation medicine.
The visual test medicament occurs without poisoning crop.
The careless ammonium phosphine of the table 14 active component B built composition for preventing and controlling weed in tea garden test of pesticide effectiveness
Careless ammonium phosphine and active component B is composite that the weed in tea garden such as annual weed, perennial weed are had good control efficiency as shown in Table 14, preventive effect is better than the single dose preventive effect, with contrast medicament, artificial weeding, remarkable with respect to the rate of growth difference of clear water control treatment, and have preferably quick-acting and lasting effect, in this experimental drug scope, to crop safety.
After draw through different local throughout the country tests, the composite rear multiple weeds preventive effect to uncultivated area, orchard, tea place, no-tillage field, sugarcane field, Cotton Fields, Spring Maize, sisal hemp garden, wooden land, mulberry field, forest of the careless ether of grass ammonium phosphine and pyrrole, diflufenican, mesotrione is all more than 95%, be better than the single dose preventive effect, synergistic effect is obvious.
Claims (5)
1. composition pesticide that contains careless ammonium phosphine is characterized in that: composition pesticide contains effective constituents A grass ammonium phosphine 1%～80%, and active ingredient B1%～60%, active ingredient B are selected from a kind of in pyrrole grass ether, diflufenican, the mesotrione.
2. the composition pesticide that contains careless ammonium phosphine according to claim 1, it is characterized in that: composition pesticide contains careless ammonium phosphine 5%～70%, and active ingredient B 1%～40%.
3. the composition pesticide that contains careless ammonium phosphine according to claim 2, it is characterized in that: composition pesticide contains careless ammonium phosphine 10%～60%, pyrrole grass ether 1%～20%; Composition pesticide contains careless ammonium phosphine 10%～50%, diflufenican 5%～35%; Composition pesticide contains careless ammonium phosphine 10%～50%, mesotrione 5%～30%.
4. according to claim 1 to 3 each described composition pesticides that contain careless ammonium phosphine, it is characterized in that: composition pesticide is made wetting powder, water dispersible granules, aqueous emulsion, oil-suspending agent, microemulsion.
5. the composition pesticide that contains careless ammonium phosphine according to claim 4 is used for the application of controlling weeds.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101260948A CN103371176A (en) | 2012-04-26 | 2012-04-26 | Glufosinate-ammonium-containing pesticide composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101260948A CN103371176A (en) | 2012-04-26 | 2012-04-26 | Glufosinate-ammonium-containing pesticide composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103371176A true CN103371176A (en) | 2013-10-30 |
Family
ID=49457497
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012101260948A Pending CN103371176A (en) | 2012-04-26 | 2012-04-26 | Glufosinate-ammonium-containing pesticide composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103371176A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106689191A (en) * | 2015-07-14 | 2017-05-24 | 江苏扬农化工股份有限公司 | Compound weeding composition containing glufosinate-ammonium and application thereof |
| WO2021151739A1 (en) | 2020-01-31 | 2021-08-05 | Basf Se | Herbicide combinations comprising glufosinate and pyraflufen-ethyl |
| US11666052B2 (en) | 2017-08-09 | 2023-06-06 | Basf Se | Herbicidal mixtures comprising L-glufosinate or its salt and at least one bleacher herbicide |
| US12144351B2 (en) | 2017-08-09 | 2024-11-19 | Basf Se | Herbicidal mixtures comprising L-glufosinate and their use in corn cultures |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1312683A (en) * | 1998-08-13 | 2001-09-12 | 阿温提斯作物科学有限公司 | Herbicides for tolerant or resistant cereal cultures |
| CN1312682A (en) * | 1998-08-13 | 2001-09-12 | 阿温提斯作物科学有限公司 | Herbicides for tolerant or resistant corn cultures |
| US6720288B1 (en) * | 1999-08-23 | 2004-04-13 | Nihon Nohyaku Co., Ltd. | Herbicidal compositions and method of using the same |
-
2012
- 2012-04-26 CN CN2012101260948A patent/CN103371176A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1312683A (en) * | 1998-08-13 | 2001-09-12 | 阿温提斯作物科学有限公司 | Herbicides for tolerant or resistant cereal cultures |
| CN1312682A (en) * | 1998-08-13 | 2001-09-12 | 阿温提斯作物科学有限公司 | Herbicides for tolerant or resistant corn cultures |
| US6720288B1 (en) * | 1999-08-23 | 2004-04-13 | Nihon Nohyaku Co., Ltd. | Herbicidal compositions and method of using the same |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106689191A (en) * | 2015-07-14 | 2017-05-24 | 江苏扬农化工股份有限公司 | Compound weeding composition containing glufosinate-ammonium and application thereof |
| US11666052B2 (en) | 2017-08-09 | 2023-06-06 | Basf Se | Herbicidal mixtures comprising L-glufosinate or its salt and at least one bleacher herbicide |
| US12082585B2 (en) | 2017-08-09 | 2024-09-10 | Basf Se | Herbicidal mixtures comprising L-glufosinate or its salt and at least one bleacher herbicide |
| US12108763B2 (en) | 2017-08-09 | 2024-10-08 | Basf Se | Herbicidal mixtures comprising L-glufosinate or its salt and at least one bleacher herbicide |
| US12133531B2 (en) | 2017-08-09 | 2024-11-05 | Basf Se | Herbicidal mixtures comprising L-glufosinate or its salt and at least one bleacher herbicide |
| US12144351B2 (en) | 2017-08-09 | 2024-11-19 | Basf Se | Herbicidal mixtures comprising L-glufosinate and their use in corn cultures |
| WO2021151739A1 (en) | 2020-01-31 | 2021-08-05 | Basf Se | Herbicide combinations comprising glufosinate and pyraflufen-ethyl |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101999400B (en) | Cyhalofop-butyl-containing weeding composition | |
| CN103371175A (en) | Glufosinate-ammonium-containing weeding composition | |
| CN103371173A (en) | Weeding composition containing glufosinate-ammonium and sulfonylurea | |
| CN103314971A (en) | Weeding composition | |
| CN102860320A (en) | Weeding composite containing cyhalofop-butyl | |
| CN103271028A (en) | Compound herbicide | |
| CN103250722A (en) | Bromoxynil octanoate-containing pesticide composition | |
| CN103371176A (en) | Glufosinate-ammonium-containing pesticide composition | |
| CN102273476B (en) | Pesticide composition containing bispyribac-sodium | |
| CN104542663A (en) | Weeding composition containing halosulfuron-methyl and quinclorac as well as fluroxypyr | |
| CN103371174A (en) | Weeding composition containing glufosinate-ammonium and amides | |
| CN103371159A (en) | Weeding composition containing cyclosulfamuron and amides | |
| CN102326563B (en) | Weeding composition containing diflufenican and flumetsulam | |
| CN109362743A (en) | A kind of Herbicidal combinations and its application containing symetryne | |
| CN102326556A (en) | Weeding composition containing carfentrazone-ethyl and diflufenican | |
| CN102318608A (en) | A kind of Herbicidal combinations that contains diflufenican and pyrrole grass ether | |
| CN102027940B (en) | Herbicidal composition containing diflufenican and fenoxaprop-ethyl and application thereof | |
| CN103380786A (en) | Cyclosulfamuron-containing weeding composition | |
| CN105123707A (en) | Weeding composition | |
| CN103371158A (en) | Weeding composition containing cyclosulfamuron | |
| CN103371161A (en) | Cyclosulfamuron-containing weeding composition | |
| CN109287649A (en) | A kind of Herbicidal combinations and its application containing dichloro quinolinic acid | |
| CN102396463A (en) | Weeding composition containing pyraflufen-ethyl and diphenyl ether compound | |
| CN104082314B (en) | Weeding composition applied to paddy rice transplanting field | |
| CN103210934B (en) | Weeding composite |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20131030 |
|
| RJ01 | Rejection of invention patent application after publication |