CN1033597C - Far-infrared ceramic chemical fibre - Google Patents
Far-infrared ceramic chemical fibre Download PDFInfo
- Publication number
- CN1033597C CN1033597C CN 93104713 CN93104713A CN1033597C CN 1033597 C CN1033597 C CN 1033597C CN 93104713 CN93104713 CN 93104713 CN 93104713 A CN93104713 A CN 93104713A CN 1033597 C CN1033597 C CN 1033597C
- Authority
- CN
- China
- Prior art keywords
- far
- chemical fibre
- ceramic
- ceramic powder
- powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000919 ceramic Substances 0.000 title claims abstract description 37
- 239000000835 fiber Substances 0.000 title claims abstract description 34
- 239000000126 substance Substances 0.000 title claims abstract description 15
- 239000000843 powder Substances 0.000 claims abstract description 27
- 238000009987 spinning Methods 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 239000012744 reinforcing agent Substances 0.000 claims abstract description 6
- 229920000642 polymer Polymers 0.000 claims abstract description 5
- 238000002074 melt spinning Methods 0.000 claims abstract 2
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 6
- 239000004743 Polypropylene Substances 0.000 claims description 5
- 229920001155 polypropylene Polymers 0.000 claims description 5
- -1 polypropylene Polymers 0.000 claims description 4
- 238000009941 weaving Methods 0.000 claims description 4
- 239000004952 Polyamide Substances 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 229920002647 polyamide Polymers 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract description 4
- 239000008187 granular material Substances 0.000 abstract 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 abstract 2
- 230000002349 favourable effect Effects 0.000 abstract 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 230000005855 radiation Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- 230000000191 radiation effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229920001410 Microfiber Polymers 0.000 description 1
- 230000003187 abdominal effect Effects 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 230000003110 anti-inflammatory effect Effects 0.000 description 1
- 230000017531 blood circulation Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000004087 circulation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000036449 good health Effects 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 150000003754 zirconium Chemical class 0.000 description 1
Landscapes
- Artificial Filaments (AREA)
- Woven Fabrics (AREA)
Abstract
The present invention relates to belongs to a spinning field. Far infrared ceramic powder is adopted as raw materials for the spinning of chemical fibers; superfine powder of ZrO2, Fe2O3, MnO2 and a phase reinforcing agent, and a high molecular polymer are made into master granules (or slices); the master granules are made into far infrared ceramic chemical fibers through melt spinning. After proper treatment, the fibers have favorable elasticity and flexibility, and can be made into various clothes with healthcare functions.
Description
The invention belongs to field of textiles, in particular the making of far IR ceramic fiber and goods.
Fiber with far infrared radiation effect repeatedly proposes on the patent abroad, and Japanese clear 63-105107 proposes natural ceramic raw material and raw materials of chemical fibres dissolvings such as the grain soil, silica with 15～20wt%, then spinning process making chemical fibre routinely.The far infrared chemical fibre of introducing among the flat 1-162824 of Japan adopts in the grain soil and adds generation total radiation rates (500 ℃) such as zirconia, silica more than 0.4, the far-infrared ceramic of granularity 5 μ m dissolves weaving with after some disperses media to mix as ancillary additions and chemical fibre raw material.See that from above patent ceramic powders that they adopt is some natural ceramic raw materials that mix compositions, its far infrared spectrum is that ceramic raw material itself is intrinsic, can not with human-body biological frequency spectrum tight connecting.Moreover the granularity of natural ceramic raw material is too big, powder distribution inequality in fiber.The bulky grain ceramic powders is bigger to the wearing and tearing of textile machine, also is not suitable for making the chemical fibre of ultra-fine fiber number.In the clear 63-126971 of Japan, adopt the ceramic powder of aluminium, magnesium, zirconium series, the gained fiber is a kind of fiber product of core sheath structure, ceramic powders wherein is 0.65 in the radiance of 30 ℃ of environment temperatures, wavelength 4.5～30 μ m, this kind core contains ceramic powder, or fiber surface contains ceramic powder, and its sandwich construction certainly will influence fiber finer dawnization, and the multilayer mode that coats all has a significant impact elongation of fiber, resilience, flexibility etc.
The object of the present invention is to provide a kind of multiple performance that has, can satisfy the preparation and the corresponding articles of the far-infrared ceramic chemical fibre material of taking requirement simultaneously.
Major technique feature of the present invention is to adopt far-infrared ceramic powder to carry out the weaving of chemical fibre as raw material, far-infrared ceramic material is the superfines of particle mean size less than 0.5 μ m with reinforcing agent mutually, its radiance is 0.85-0.92, powder is made the chemical fibre spinning with ceramic with dry method or wet method, with high molecular polymers such as material and polypropylene, polyurethane, polyamide, polyester section melting spinning, the ceramic ultrafine powder end is 50-80wt%ZrO
2, 5-20wt%F
2O
310-30wt%MnO
2With reinforcing agent mutually is that 5-15wt% is a raw material.
The spinning technique that adopts also can be ceramic master batch and polymer chips melting and adds Masterbatch simultaneously and spin the look silk.And by changing special-shaped silk that spinneret component spins out different shape as triangle, three leaves, hollow etc., spun or yarn are made into fabric.
Technical solution of the present invention is as follows:
1. the prescription of far-infared ceramic powder
It is ZrO that the present invention adopts the composition of far-infrared ceramic powder
2, Fe
2O
3, MnO
2Increase agent mutually, wherein ZrO
2Be 50～80wt%, Fe
2O
3Be 5-20wt%; MnO
2Be 10-30wt% and reinforcing agent mutually.Its average material footpath is＜0.5 μ m, and it is at 20～50 ℃ of far infrareds that can radiate 2-25 μ m, radiation coefficient 0.85～0.92.
2. the making of far-infrared matrix:
With far-infrared ceramic powder and polypropylene; Polyurethane; Polyblend such as polyamide, polyester.Make section or master batch, wherein ceramic powder content is 30～70wt%.
3. spinning technique
With ceramic master batch (or section) and high molecular polymer section blend, or add the Masterbatch blend simultaneously.Master batch accounts for 10～70wt%.Melting at high temperature, the spray silk stretches, and reels, and gets as-spun fibre.After treatment, obtain the far infrared characterization fiber that every indexs such as temperature, modulus, percentage elongation all meet the demands.
The present invention can produce special-shaped silk such as hollow, triangle, three leaves by changing spinneret component.Because ultra-fine ceramic powder specific surface is big, in the spinning process of special-shaped silk, can appropriateness increase spinning speed.
4. the making of fabric
Precursor after the drawing-off or yarn suede are after treatment pressed different specifications, and difference is taken the clothing that the requirement group is produced various different purposes.
As: corselet, abdominal belt, Training wear, socks, sheet, clothes, trousers, drapery etc. and various health care clothings.
Adopt good effect of the present invention:, improved content and the uniformity of ceramic powder in fiber owing to use the method for making less than ultrafine ceramic powder end and the master batch of 0.5 μ m.The specific surface of the far infrared radiation in the fiber is increased, and radiation effect is good.Its far infrared radiation characteristic of the far IR fibre of co-blended spinning is not influenced by washing, and radiation effect is lasting.Simultaneously, its intensity of the fiber of weaving, retractility, flexibility etc. are all fine, have improved the performance indications of fiber itself greatly.
Embodiment:
Ceramic powder 60wt%ZrO
2, 18%Fe
2O
312wt%MnO
2With add 20wt% reinforcing agent mutually, its particle mean size＜0.5 μ m; They and the polypropene blended master batch of making of 30wt%.Again master batch was mixed congruent melting in knitting the fiber that is spun into different size on the frame with polypropylene by 100: 70.The fiber process adds post processings such as bullet, is spun into clothes, socks etc.The intensity of fiber was 5.2 gram/dawn, and extension at break is 38.6%, and boiling water is punctured into 3.1%, was the fiber of excellent performance.Be made into thing and have the good health care function.As the brassiere made from it.Have and stimulate circulation, play the effect that anti-inflammatory is invigorated blood circulation.
Claims (1)
1, a kind of preparation method of far-infrared ceramic chemical fibre adopts far-infrared ceramic powder to carry out the weaving of chemical fibre as raw material, it is characterized in that:
(1), the composition of far-infrared ceramic powder is 50-80wt%ZrO
2, 5-20wt%Fe
2O
3, 10～30wt%MnO
2With the 5-15wt% superfines of reinforcing agent mutually, its particle mean size is less than 0.5 μ m;
(2), the powder with above-mentioned 1 is made the ceramic master batch of chemical fibre spinning with dry method or wet method, ceramic powder content 30～70wt% in the master batch;
(3), with the female powder that contains ceramic powder in above-mentioned 2 and polypropylene, polyurethane, polyamide polyester, polymer melt spinning, wherein the ultrafine ceramic powder end accounts for 5～50wt%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93104713 CN1033597C (en) | 1993-05-07 | 1993-05-07 | Far-infrared ceramic chemical fibre |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93104713 CN1033597C (en) | 1993-05-07 | 1993-05-07 | Far-infrared ceramic chemical fibre |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1095118A CN1095118A (en) | 1994-11-16 |
| CN1033597C true CN1033597C (en) | 1996-12-18 |
Family
ID=4985309
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 93104713 Expired - Fee Related CN1033597C (en) | 1993-05-07 | 1993-05-07 | Far-infrared ceramic chemical fibre |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1033597C (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1091188C (en) * | 1996-03-25 | 2002-09-18 | 张宝玲 | Far infrared cloth and its production and use |
| SG138444A1 (en) * | 2002-12-04 | 2008-01-28 | Inventio Ag | Reinforced synthetic cable for lifts |
| CN100344804C (en) * | 2003-12-25 | 2007-10-24 | 纳米科技国际集团有限公司 | Biologically active nano fiber and products thereof |
| CN201055478Y (en) * | 2007-02-15 | 2008-05-07 | 深圳市月朗科技有限公司 | Far-infrared anion composite sanitary napkins and protecting pad |
| CN104480573B (en) * | 2014-12-23 | 2016-07-13 | 李淑兰 | Fire-resistant anti-bacterial fibre |
| CN106245127B (en) * | 2016-08-03 | 2018-09-14 | 三德亿顺商贸(深圳)有限公司 | A kind of natural nano-mineral mountain flour functional fibre and a kind of functional heat energy cotton |
| CN107151843B (en) * | 2017-05-23 | 2019-12-24 | 浙江亚特新材料股份有限公司 | Method for manufacturing far infrared negative ion nylon-ammonia coated yarn |
| CN109629035A (en) * | 2018-12-25 | 2019-04-16 | 南通东屹高新纤维科技有限公司 | A kind of manufacture craft of 56 fiber of biology base nylon with far-infrared functional |
| CN110629340A (en) * | 2019-08-26 | 2019-12-31 | 宁波大千纺织品有限公司 | Seaweed carbon fiber far infrared moisture absorption multifunctional fabric and preparation method thereof |
-
1993
- 1993-05-07 CN CN 93104713 patent/CN1033597C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1095118A (en) | 1994-11-16 |
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| CF01 | Termination of patent right due to non-payment of annual fee |