CN103341695A - Method for improving mechanical property of hardened and tempered low-alloy high-strength steel GMAW connector - Google Patents
Method for improving mechanical property of hardened and tempered low-alloy high-strength steel GMAW connector Download PDFInfo
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- 239000010959 steel Substances 0.000 title claims abstract description 43
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 32
- 239000000956 alloy Substances 0.000 title claims abstract description 32
- 238000000034 method Methods 0.000 title claims abstract description 26
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- 238000005496 tempering Methods 0.000 claims abstract description 12
- 238000010791 quenching Methods 0.000 claims abstract description 6
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- 210000001503 joint Anatomy 0.000 claims description 18
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- 238000004458 analytical method Methods 0.000 claims description 3
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- 239000002184 metal Substances 0.000 claims 5
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- 238000001816 cooling Methods 0.000 abstract description 5
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- 230000004927 fusion Effects 0.000 description 13
- 239000010953 base metal Substances 0.000 description 9
- 238000010586 diagram Methods 0.000 description 6
- 238000004364 calculation method Methods 0.000 description 5
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- 238000011160 research Methods 0.000 description 4
- 229910001563 bainite Inorganic materials 0.000 description 3
- 229910000734 martensite Inorganic materials 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
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- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
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Abstract
Description
【技术领域】【Technical field】
本发明属于材料加工技术领域,涉及一种改善调质低合金高强钢GMAW接头力学性能的方法。The invention belongs to the technical field of material processing and relates to a method for improving the mechanical properties of quenched and tempered low-alloy high-strength steel GMAW joints.
【背景技术】【Background technique】
低合金高强钢以其超高的强度、良好的塑韧性和较好的焊接性能广泛应用于工程机械、电力、压力容器、汽车等领域。低合金高强钢的种类可分为非调质钢和调质钢,调质态的低合金高强钢是近几十年来发展最迅速、最有活力的钢种之一,其屈服强度可达到880~1176MPa,由于其超高的强度,良好的塑韧性以及焊接性,除了在桥梁、建筑、船舶、高压容器、工程机械及车辆等领域被广泛应用,通常也用于强度要求很高的产品或部件,如火箭发动机外壳、飞机起落架等。Low-alloy high-strength steel is widely used in construction machinery, electric power, pressure vessels, automobiles and other fields due to its ultra-high strength, good ductility and good welding performance. The types of low-alloy high-strength steel can be divided into non-quenched and tempered steel and quenched and tempered steel. Quenched and tempered low-alloy high-strength steel is one of the fastest-growing and most dynamic steel types in recent decades, and its yield strength can reach 880 ~1176MPa, due to its ultra-high strength, good plastic toughness and weldability, it is not only widely used in bridges, buildings, ships, high-pressure vessels, construction machinery and vehicles, but also used in products with high strength requirements or Components, such as rocket motor casings, aircraft landing gear, etc.
由于性能优异和经济效益显著,调质低合金高强钢在工程焊接结构中的应用日益广泛,对如何获得性能优异的焊接结构件一直是研究者的重点研究目标。对于调质低合金高强钢而言,除了高强钢焊接的共性问题,焊接冷裂纹和焊接热影响区脆化,焊接接头的软化问题也是该钢种在焊接中所遇到的一个关键技术问题,这是因为调质低合金高强钢是在低碳钢的基础上加入提高淬透性的合金元素后经调质(淬火+回火)热处理来获得强度高、韧性好的低碳马氏体+下贝氏体混合组织,而焊接时,在焊接热循环作用下,接头热影响区被加热到超过调质回火温度的区域,将会出现强度、硬度低于母材的软化区,该软化区可能成为接头强度的薄弱区,即出现焊接接头的软化问题。焊后,如果在缓冷过程中马氏体得以自回火,可以缓解冷裂纹出现的情况;但如果冷却速度快,马氏体不能自回火,其冷裂倾向必然加大。研究表明,低合金高强钢在调质状态下焊接,裂纹和脆化可以通过预热和焊后保温等措施得以控制,而软化引起的问题在焊后无法解决,需要在焊接工艺上予以控制。例如,王莲芳等人对法国优基诺钢铁公司生产的DILLMAX965调质高强钢进行焊接研究,研究表明,只有通过严格控制热输入使t8/5<10s时,焊接接头中的热影响区才不存在软化现象。赵玉珍等人对SS400钢进行焊接研究,研究了其脉冲MAG(80%Ar+20%CO2)焊接接头粗晶区的精细结构,其研究表明采用高线能量焊接时,热影响区粗晶区含有大量的上贝氏体组织,而采用较低线能量焊接时,热影响区主要为韧性良好的下贝氏体组织,在热影响区未出现软化现象。总结以上方法,可知,尽量降低热输入是调质态高强钢焊接时避免热影响区软化的有效方式,但这种方法也给高强钢焊接方式带来了局限性和灵活性的缺失,因此,找到其他有效的解决调质低合金高强钢GMAW接头热影响区软化问题的方法是有很必要的。Due to its excellent performance and remarkable economic benefits, quenched and tempered low-alloy high-strength steel is widely used in engineering welded structures, and how to obtain welded structural parts with excellent performance has always been the key research goal of researchers. For quenched and tempered low-alloy high-strength steel, in addition to the common problems of high-strength steel welding, welding cold cracks and welding heat-affected zone embrittlement, the softening of welded joints is also a key technical problem encountered in welding of this steel type. This is because quenched and tempered low-alloy high-strength steel is based on low-carbon steel by adding alloying elements that improve hardenability and then undergoes quenching and tempering (quenching + tempering) heat treatment to obtain low-carbon martensite with high strength and good toughness+ The lower bainite mixed structure, while welding, under the action of welding heat cycle, the heat-affected zone of the joint is heated to the area exceeding the quenching and tempering temperature, and there will be a softening zone whose strength and hardness are lower than that of the base metal. The area may become the weak area of the joint strength, that is, the softening problem of the welded joint occurs. After welding, if the martensite can be self-tempered during the slow cooling process, the occurrence of cold cracks can be alleviated; but if the cooling rate is fast, the martensite cannot self-temper, and its tendency to cold cracks will inevitably increase. Studies have shown that when low-alloy high-strength steel is welded in the quenched and tempered state, cracks and embrittlement can be controlled by preheating and post-weld heat preservation, while problems caused by softening cannot be solved after welding and need to be controlled in the welding process. For example, Wang Lianfang and others conducted welding research on DILLMAX965 quenched and tempered high-strength steel produced by Ukino Steel Company in France. The research shows that only when the heat input is strictly controlled to make t 8/5 <10s, the heat-affected zone in the welded joint does not exist. softening phenomenon. Zhao Yuzhen and others conducted welding research on SS400 steel, and studied the fine structure of the coarse-grained zone of the pulsed MAG (80%Ar+20%CO2) welded joint. There is a large amount of upper bainite structure, and when welding with lower heat input energy, the heat-affected zone is mainly the lower bainite structure with good toughness, and there is no softening phenomenon in the heat-affected zone. Summarizing the above methods, it can be seen that reducing the heat input as much as possible is an effective way to avoid softening of the heat-affected zone during the welding of quenched and tempered high-strength steel, but this method also brings limitations and lack of flexibility to the high-strength steel welding method. Therefore, It is necessary to find other effective methods to solve the softening problem of heat-affected zone of quenched and tempered low-alloy high-strength steel GMAW joints.
【发明内容】【Content of invention】
针对调质低合金高强钢GMAW焊接时,焊接接头HAZ(热影响区)发生回火软化,使得接头强度下降的问题,本发明提供了一种改善调质低合金高强钢GMAW接头力学性能的方法。Aiming at the problem that tempering and softening of the HAZ (heat-affected zone) of the welded joint during GMAW welding of quenched and tempered low-alloy high-strength steel causes the joint strength to decrease, the present invention provides a method for improving the mechanical properties of the quenched and tempered low-alloy high-strength steel GMAW joint .
本发明是通过以下技术方案来实现:The present invention is realized through the following technical solutions:
一种改善调质低合金高强钢GMAW接头力学性能的方法,包括以下操作:A method for improving the mechanical properties of quenched and tempered low-alloy high-strength steel GMAW joints, comprising the following operations:
1)测量并标定焊接接头的焊缝、熔合线的位置,依据焊接热循环曲线的最高温度计算公式计算并标定焊接接头软化区的位置及宽度;1) Measure and calibrate the position of the weld seam and fusion line of the welded joint, calculate and calibrate the position and width of the softened zone of the welded joint according to the maximum temperature calculation formula of the welding thermal cycle curve;
2)采用激光对焊接接头的软化区进行重熔;2) Use laser to remelt the softened zone of the welded joint;
3)对激光重熔后的接头表面进行打磨处理。3) Grinding the joint surface after laser remelting.
所述的软化区是指焊接接头热影响区中发生抗拉强度低于母材抗拉强度的区域。The softening zone refers to the zone in the heat-affected zone of the welded joint where the tensile strength is lower than that of the base metal.
所述在对软化区进行重熔时,可采用单面或者双面激光重熔的方式达到对接头软化区的重熔。When remelting the softening zone, one-sided or double-sided laser remelting can be used to remelt the softening zone of the butt joint.
所述在测量标定焊接接头软化区之前还包括以下处理:Before measuring the softening zone of the calibration welded joint, the following processing is also included:
首先将待激光重熔的试样接头表面进行打磨抛光;First, the surface of the sample joint to be laser remelted is polished and polished;
然后对焊接接头采用腐蚀剂进行腐蚀,直至显现出接头焊缝、熔合线、热影响区以及母材的各个区域。The welded joint is then corroded with a corrosive agent until the joint weld, fusion line, heat-affected zone, and various areas of the base metal appear.
所述的腐蚀剂是指可用于金属金相腐蚀分析的腐蚀剂。The corrosive agent refers to the corrosive agent that can be used in metallographic corrosion analysis.
所述的GMAW接头为淬火+低温回火调质低合金高强钢薄板GMAW焊接所形成的焊接接头。The GMAW joint is a welded joint formed by GMAW welding of a quenched + low-temperature tempered low-alloy high-strength steel sheet.
所述的薄板是指厚度范围为0.2~6mm的钢板。The thin plate refers to a steel plate with a thickness ranging from 0.2 to 6 mm.
所述对接头软化区的重熔是指对接头软化区熔透性或者非熔透行重熔。The remelting of the joint softening zone refers to remelting the penetrating or non-penetrating softening zone of the joint.
所述焊接接头软化区的位置及宽度的计算为:The calculation of the position and width of the softened zone of the welded joint is:
依据焊接循环曲线的最高温度计算公式:The maximum temperature calculation formula based on the welding cycle curve:
式中:E为焊接热输入;T0为焊件初始温度;TM为母材熔点,d为离开熔合线的距离;δ为母材厚度;cv为材料定容比热;In the formula: E is the welding heat input; T 0 is the initial temperature of the weldment; T M is the melting point of the base metal, d is the distance from the fusion line; δ is the thickness of the base metal; c v is the specific heat of the material at constant volume;
导出接头HAZ中峰值温度Tmax位置离开熔合线距离为The distance from the position of the peak temperature T max in the derived joint HAZ to the fusion line is
则接头HAZ中软化区的宽度为:Then the width of the softening zone in the joint HAZ is:
式中b为HAZ软化区宽度;Th为材料控冷生产自回火温度;为HAZ中峰值温度为回火温度的位置与熔合线距离;为HAZ中峰值温度Ac1位置与熔合线距离。In the formula, b is the width of HAZ softening zone; T h is the self-tempering temperature of material controlled cooling production; is the distance between the position where the peak temperature is the tempering temperature and the fusion line in the HAZ; is the distance between the position of the peak temperature A c1 and the fusion line in the HAZ.
与现有技术相比,本发明具有以下有益的技术效果:Compared with the prior art, the present invention has the following beneficial technical effects:
本发明提供的改善调质低合金高强钢GMAW接头力学性能的方法,是一种基于激光重熔法改善淬火+低温回火调质低合金高强钢薄板GMAW接头软化区力学性能的方法,借助激光加热冷却速度快的热循环特点改善淬火+低温回火调质低合金高强钢薄板的GMAW接头HAZ软化区的组织;借助激光焊接深熔焊焊缝深、宽比高、热输入小热影响区小、焊接变形小的特点对淬火+低温回火调质低合金高强钢薄板的GMAW接头进行激光重熔可减小接头HAZ软化区宽度,以此可提高接头强韧性。The method for improving the mechanical properties of quenched and tempered low-alloy high-strength steel GMAW joints provided by the present invention is a method based on laser remelting to improve the mechanical properties of the softened zone of quenched and tempered low-alloy high-strength steel sheet GMAW joints. The thermal cycle characteristics of fast heating and cooling speed improve the structure of the HAZ softening zone of the GMAW joint of the quenched + low-temperature tempered low-alloy high-strength steel sheet; deep penetration welding with the help of laser welding has deep weld seam, high aspect ratio, and small heat input heat-affected zone Small and small welding deformation. Laser remelting of GMAW joints of quenched + low-temperature tempered low-alloy high-strength steel sheets can reduce the width of the HAZ softening zone of the joints, thereby improving the strength and toughness of the joints.
【附图说明】【Description of drawings】
图1为接头区域标定和软化区位置示意图;Figure 1 is a schematic diagram of the calibration of the joint area and the position of the softening area;
图2为接头激光重熔方案示意图;Figure 2 is a schematic diagram of the joint laser remelting scheme;
图3为接头激光重熔后宏观形貌示意图;Figure 3 is a schematic diagram of the macroscopic morphology of the joint after laser remelting;
图4实施例激光重熔后接头实物图;The physical picture of the joint after the laser remelting of the embodiment in Fig. 4;
图5为激光重熔前后接头拉伸试样应力—应变曲线。Figure 5 shows the stress-strain curves of the joint tensile specimen before and after laser remelting.
【具体实施方式】【Detailed ways】
下面结合具体的实施例对本发明做进一步的详细说明。The present invention will be further described in detail below in conjunction with specific embodiments.
本发明提供的一种改善调质低合金高强钢GMAW接头力学性能的方法,包括以下操作:A method for improving the mechanical properties of quenched and tempered low-alloy high-strength steel GMAW joints provided by the invention comprises the following operations:
1)测量并标定焊接接头的焊缝、熔合线的位置,依据焊接热循环曲线的最高温度计算公式计算并标定焊接接头软化区的位置及宽度;1) Measure and calibrate the position of the weld seam and fusion line of the welded joint, calculate and calibrate the position and width of the softened zone of the welded joint according to the maximum temperature calculation formula of the welding thermal cycle curve;
2)采用激光对焊接接头的软化区进行重熔;2) Use laser to remelt the softened zone of the welded joint;
3)对激光重熔后的接头表面进行打磨处理。3) Grinding the joint surface after laser remelting.
具体的,在测量标定焊接接头软化区之前还包括以下处理:Specifically, the following treatments are also included before measuring the softening zone of the calibration welded joint:
首先将待激光重熔的试样接头表面进行打磨抛光;First, the surface of the sample joint to be laser remelted is polished and polished;
然后对焊接接头采用腐蚀剂进行腐蚀,直至显现出接头焊缝、熔合线、热影响区以及母材的各个区域。所述的腐蚀剂是指可用于金属金相腐蚀分析的腐蚀剂。The welded joint is then corroded with a corrosive agent until the joint weld, fusion line, heat-affected zone, and various areas of the base metal appear. The corrosive agent refers to the corrosive agent that can be used in metallographic corrosion analysis.
所述的软化区是指焊接接头热影响区中发生抗拉强度低于母材抗拉强度的区域。而在在对软化区进行重熔时,可采用单面或者双面激光重熔的方式达到对接头软化区的重熔。所述对接头软化区的重熔是指对接头软化区熔透性或者非熔透行重熔。The softening zone refers to the zone in the heat-affected zone of the welded joint where the tensile strength is lower than that of the base metal. When remelting the softening zone, single-sided or double-sided laser remelting can be used to achieve remelting of the softened zone of the joint. The remelting of the joint softening zone refers to remelting the penetrating or non-penetrating softening zone of the joint.
下面给出具体的实施例来进行说明。Specific examples are given below for illustration.
本实施例采用JHM-1GXY-400X型Nd:YAG激光器对1.5mm厚1000MPa细晶粒高强钢20MnTiB GMAW接头HAZ软化区进行激光重熔。具体的实施步骤包括:In this example, a JHM-1GXY-400X Nd:YAG laser is used to remelt the HAZ softening zone of the 1.5mm thick 1000MPa fine-grained high-strength steel 20MnTiB GMAW joint. The specific implementation steps include:
(1)采用GMAW焊接20MnTiB对接接头,保护气体为富氩混合气体,线能量为9.5J/cm。采用线切割切取待激光重熔试样,具体尺寸为200mm×30mm×1.5mm。(1) GMAW is used to weld 20MnTiB butt joints, the shielding gas is argon-rich mixed gas, and the line energy is 9.5J/cm. The sample to be laser remelted is cut by wire cutting, and the specific size is 200mm×30mm×1.5mm.
(2)对待激光重熔的试样接头进行打磨抛光。(2) Grinding and polishing the sample joints to be laser remelted.
(3)对打磨抛光好的试样用4%的硝酸酒精溶液(体积分数)对20MnTiB GMAW焊接接头区域进行腐蚀,直至显现出接头焊缝、熔合线、热影响区以及母材的各个区域,(3) Corrode the 20MnTiB GMAW welded joint area with 4% nitric alcohol solution (volume fraction) on the polished sample until the joint weld, fusion line, heat-affected zone and various areas of the base metal appear,
(4)结合金相观察和,测量标定20MnTiB GMAW接头的焊缝、熔合线、热影响区,依据焊接热循环曲线的最高温度计算公式计算并标定焊接接头软化区的位置及宽度,具体步骤如下:(4) Combined with metallographic observation and calibration, measure and calibrate the weld seam, fusion line, and heat-affected zone of 20MnTiB GMAW joints, calculate and calibrate the position and width of the softening zone of the welded joint according to the maximum temperature calculation formula of the welding thermal cycle curve, the specific steps are as follows :
由焊接热循环曲线的最高温度计算公式:The formula for calculating the maximum temperature from the welding thermal cycle curve:
导出接头HAZ中峰值温度Tmax位置离开熔合线距离为The distance from the position of the peak temperature T max in the derived joint HAZ to the fusion line is
则接头HAZ中软化区宽度为Then the width of the softening zone in the joint HAZ is
实施例中:热输入E为8.2kJ/cm;焊件初始温度T0为20℃;20MnTiB熔点TM为1530℃;母材厚度δ为6mm;20MnTiB的定容比热cv为6.7J/(cm3℃);20MnTiB控冷生产回火温度Th为200℃;则由公式(2)可知,接头HAZ中峰值温度为回火温度的位置与熔合线距离dTmax=Th为4mm;接头HAZ中峰值温度Ac1位置与熔合线距离dTmax=Acl为2.5mm。示意图为图1。In the embodiment: the heat input E is 8.2kJ/cm; the initial temperature T 0 of the weldment is 20°C; the melting point T M of 20MnTiB is 1530°C; the thickness δ of the base metal is 6mm; the specific heat c v of 20MnTiB is 6.7J/ (cm 3 ℃); 20MnTiB controlled cooling production tempering temperature T h is 200 ℃; then it can be seen from the formula (2) that the distance between the position where the peak temperature in the joint HAZ is the tempering temperature and the fusion line d Tmax = Th is 4mm; The distance d Tmax =A cl between the position of the peak temperature A c1 and the fusion line in the joint HAZ is 2.5 mm. The schematic diagram is Figure 1.
(5)采用JHM-1GXY-400X型Nd:YAG激光器对标定好的20MnTiBGMAW接头HAZ软化区进行重熔;(5) Use JHM-1GXY-400X Nd:YAG laser to remelt the calibrated 20MnTiBGMAW joint HAZ softening zone;
具体的方案为:①采用脉冲激光对20MnTiB的GMAW接头软化区重熔,示意图为图2;The specific plan is: ① use pulsed laser to remelt the softened zone of the GMAW joint of 20MnTiB, the schematic diagram is shown in Figure 2;
②为减小热输入,避免产生较宽的激光热影响区和产生小的焊接变形,对20MnTiB的GMAW接头进行上下两道小热输入对焊的方式,达到对接头HAZ软化区的重熔,示意图为图3,图4为实施例实物图;②In order to reduce heat input, avoid wide laser heat-affected zone and small welding deformation, the GMAW joint of 20MnTiB is welded with two small heat input up and down, so as to achieve remelting of the HAZ softening zone of the joint, The schematic diagram is Fig. 3, and Fig. 4 is the physical figure of the embodiment;
(6)对激光重熔后的接头进行打磨处理。(6) Grinding the joints after laser remelting.
对实例试样进行力学性能检测,采取的检测方法是接头拉伸性能测试,图5为实施例接头拉伸试验所得到的应力—应变曲线,图中黑色曲线为未经过激光重熔软化区接头拉伸应力—应变曲线,曲线显示接头的抗拉强度为766MPa,图中红色的曲线为经过激光重熔软化区的接头拉伸应力—应变曲线,曲线显示接头的抗拉强度为906MPa,从两条曲线的对比可以看出激光重熔可以显著的改善20MnTiB的GMAW接头软化区的力学性能。The mechanical performance test of the example sample is carried out by the joint tensile performance test. Figure 5 is the stress-strain curve obtained by the joint tensile test of the example. The black curve in the figure is the joint that has not passed through the laser remelting softening zone Tensile stress-strain curve, the curve shows that the tensile strength of the joint is 766MPa, the red curve in the figure is the tensile stress-strain curve of the joint after the laser remelting softening zone, the curve shows that the tensile strength of the joint is 906MPa, from the two The comparison of the two curves shows that laser remelting can significantly improve the mechanical properties of the softened zone of the GMAW joint of 20MnTiB.
最后说明的是,本实施例仅用以说明本发明的技术方案而非限制,本领普通技术人员对本发明的技术方案所做的其他修改或者等同替换,只要不脱离本发明技术方案的精神范围,均应涵盖在本发明的权利要求范围中。Finally, it is noted that this embodiment is only used to illustrate the technical solution of the present invention without limitation. Other modifications or equivalent replacements made by those of ordinary skill in the art to the technical solution of the present invention, as long as they do not depart from the spirit of the technical solution of the present invention, All should be included in the scope of claims of the present invention.
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