CN103250732B - Synergistic pesticide composition for killing scale insects - Google Patents
Synergistic pesticide composition for killing scale insects Download PDFInfo
- Publication number
- CN103250732B CN103250732B CN201310158072.4A CN201310158072A CN103250732B CN 103250732 B CN103250732 B CN 103250732B CN 201310158072 A CN201310158072 A CN 201310158072A CN 103250732 B CN103250732 B CN 103250732B
- Authority
- CN
- China
- Prior art keywords
- pesticide composition
- red
- spotted lizard
- synergistic
- synergetic pesticide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 72
- 230000002195 synergetic effect Effects 0.000 title claims abstract description 55
- 239000000575 pesticide Substances 0.000 title claims abstract description 29
- 241000258937 Hemiptera Species 0.000 title abstract 4
- 239000005660 Abamectin Substances 0.000 claims abstract description 35
- 241000270322 Lepidosauria Species 0.000 claims description 37
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 claims description 26
- 241000607479 Yersinia pestis Species 0.000 claims description 24
- 240000000249 Morus alba Species 0.000 claims description 20
- 235000008708 Morus alba Nutrition 0.000 claims description 20
- 239000004530 micro-emulsion Substances 0.000 claims description 20
- 125000003545 alkoxy group Chemical group 0.000 claims description 14
- 239000007788 liquid Substances 0.000 claims description 8
- 235000013399 edible fruits Nutrition 0.000 claims description 5
- 241000196324 Embryophyta Species 0.000 claims description 4
- 244000046151 Acer negundo Species 0.000 claims description 3
- 235000004422 Acer negundo Nutrition 0.000 claims description 3
- 241000586568 Diaspidiotus perniciosus Species 0.000 claims description 3
- 241000586610 Parlatoria oleae Species 0.000 claims description 3
- 240000008866 Ziziphus nummularia Species 0.000 claims description 3
- 239000003814 drug Substances 0.000 abstract description 15
- 229920000056 polyoxyethylene ether Polymers 0.000 abstract description 14
- 229940051841 polyoxyethylene ether Drugs 0.000 abstract description 14
- IBSREHMXUMOFBB-JFUDTMANSA-N 5u8924t11h Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 IBSREHMXUMOFBB-JFUDTMANSA-N 0.000 abstract description 9
- 229950008167 abamectin Drugs 0.000 abstract description 9
- -1 alkoxy trisiloxane Chemical compound 0.000 abstract description 9
- 230000002265 prevention Effects 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 239000002420 orchard Substances 0.000 abstract description 3
- 229940079593 drug Drugs 0.000 abstract 1
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 54
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 42
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 42
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 26
- 238000002474 experimental method Methods 0.000 description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 19
- 231100000331 toxic Toxicity 0.000 description 16
- 230000002588 toxic effect Effects 0.000 description 16
- 238000009472 formulation Methods 0.000 description 15
- 238000002156 mixing Methods 0.000 description 15
- 239000000126 substance Substances 0.000 description 14
- 238000000034 method Methods 0.000 description 13
- 210000000481 breast Anatomy 0.000 description 11
- 239000004495 emulsifiable concentrate Substances 0.000 description 7
- 239000003995 emulsifying agent Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000000843 powder Substances 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 239000003921 oil Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 239000004480 active ingredient Substances 0.000 description 4
- 239000006184 cosolvent Substances 0.000 description 4
- 230000006378 damage Effects 0.000 description 4
- 238000011049 filling Methods 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 238000009736 wetting Methods 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 241000819999 Nymphes Species 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000007859 condensation product Substances 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 231100000225 lethality Toxicity 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- XXKHDSGLCLCFSC-UHFFFAOYSA-N 2,3-diphenylphenol Chemical compound C=1C=CC=CC=1C=1C(O)=CC=CC=1C1=CC=CC=C1 XXKHDSGLCLCFSC-UHFFFAOYSA-N 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000012466 permeate Substances 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- LWEAHXKXKDCSIE-UHFFFAOYSA-M 2,3-di(propan-2-yl)naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S([O-])(=O)=O)=C(C(C)C)C(C(C)C)=CC2=C1 LWEAHXKXKDCSIE-UHFFFAOYSA-M 0.000 description 1
- BYLSIPUARIZAHZ-UHFFFAOYSA-N 2,4,6-tris(1-phenylethyl)phenol Chemical compound C=1C(C(C)C=2C=CC=CC=2)=C(O)C(C(C)C=2C=CC=CC=2)=CC=1C(C)C1=CC=CC=C1 BYLSIPUARIZAHZ-UHFFFAOYSA-N 0.000 description 1
- CUFXMPWHOWYNSO-UHFFFAOYSA-N 2-[(4-methylphenoxy)methyl]oxirane Chemical compound C1=CC(C)=CC=C1OCC1OC1 CUFXMPWHOWYNSO-UHFFFAOYSA-N 0.000 description 1
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- FQYUMYWMJTYZTK-UHFFFAOYSA-N Phenyl glycidyl ether Chemical compound C1OC1COC1=CC=CC=C1 FQYUMYWMJTYZTK-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000004283 Sodium sorbate Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical group 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229960004050 aminobenzoic acid Drugs 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 231100000636 lethal dose Toxicity 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical class [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- CIBMHJPPKCXONB-UHFFFAOYSA-N propane-2,2-diol Chemical compound CC(C)(O)O CIBMHJPPKCXONB-UHFFFAOYSA-N 0.000 description 1
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 1
- 150000004040 pyrrolidinones Chemical class 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- LROWVYNUWKVTCU-STWYSWDKSA-M sodium sorbate Chemical compound [Na+].C\C=C\C=C\C([O-])=O LROWVYNUWKVTCU-STWYSWDKSA-M 0.000 description 1
- 235000019250 sodium sorbate Nutrition 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000011885 synergistic combination Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a synergistic pesticide composition for killing scale insects. The synergistic pesticide composition is prepared by taking abamectin and a synergist component as active components and combining the active components with aids, wherein the synergistic component is alkoxy trisiloxane or fatty alcohol-polyoxyethylene ether; and the weight ratio of the abamectin to the synergistic component is (1:1)-(1:5000). The pesticide composition has the advantages of having obvious synergistic effect, improving the effect for preventing scale insects and reducing drug dosage and has great significance to the protection of orchard ecological environment and green prevention and control of the scale insects.
Description
Technical field
The present invention relates to a kind of synergetic pesticide composition, be specially the composition pesticide killing a red-spotted lizard class pest containing Avermectin, and the application of this composition pesticide in agricultural, forestry.
Technical background
Mainly comprise white mulberry scale, san jose scale at the cause harm a red-spotted lizard class pest of fruit tree and forest of China, tell human relations ball hard a red-spotted lizard, jujube ball a red-spotted lizard, Parlatoria oleae, moire a red-spotted lizard, Acer negundo a red-spotted lizard, lose sharp a red-spotted lizard etc.A red-spotted lizard class pest is caused harm the woody plant such as fruit tree, forest usually, and cause tree vigo(u)r weak, branch is withered, and result reduces, production declining, the gently then underproduction, heavy then have no harvest, and also makes product qualitative change bad, commodity rate reduction simultaneously.Because a red-spotted lizard class pest has periostracum to protect in the middle and later periods of causing harm more, strong to autoprotection sexuality.In current production, the middle high-toxic pesticide containing organic phosphates insect killing substance that uses is used for control more.Because the agent permeates used is not strong, effective insect killing substance is difficult to contact protected a red-spotted lizard class pest polypide, and control efficiency is unsatisfactory, and larger to the environmental destruction in orchard.
Summary of the invention
The invention provides and a kind ofly prevent and treat agricultural and forestry a red-spotted lizard class pest has the composition pesticide of synergistic effect.This composition pesticide has obvious synergistic effect, overcomes the deficiency of existing Prevention Technique, improves the control efficiency to a red-spotted lizard class pest, reduces medicament usage amount, to protection orchard ecology and green prevention and control a red-spotted lizard class pest significant.
Adopt and a red-spotted lizard class pest is had to highly active insecticide and has the auxiliary agent that high synergy permeates by force and carry out composite, inventor is by a large amount of screening tests, after finding that Avermectin is mixed with alkoxyl trisiloxanes or fatty alcohol-polyoxyethylene ether, obvious synergistic effect is shown to a red-spotted lizard class pest, effectively can reduce the dosage of control a red-spotted lizard class pest, be particularly useful for the green high-efficient prevention and control of a red-spotted lizard class pest.
Kill a synergetic pesticide composition for a red-spotted lizard class pest, with Avermectin and synergistic component for active component, form with carrier and auxiliary combination, the ratio of weight and number of described Avermectin and synergistic component is 1:1-1:5000.
Described synergistic component is alkoxyl trisiloxanes or fatty alcohol-polyoxyethylene ether.Wherein alkoxyl trisiloxanes can be one or more of the organic silicon surfactants such as Greenwet3710, Greenwet BP, Silwet408, Silwet806, Silwet618, Silwet625, SilwetL-77.
The formulation that described synergetic pesticide composition can be made into is microemulsion, missible oil, wetting powder.
Described active component sum accounts for the 0.01-99% of synergetic pesticide composition gross weight.
Synergetic pesticide composition of the present invention is by apparatus spraying or manually smear liquid to process the habitat of the woody plant such as fruit tree, forest a red-spotted lizard class pest, for preventing and treating white mulberry scale, san jose scale, telling a red-spotted lizard class pests such as human relations ball hard a red-spotted lizard, the large ball a red-spotted lizard of jujube, Parlatoria oleae, moire a red-spotted lizard, Acer negundo a red-spotted lizard.
Present invention also offers the preparation method of the synergetic pesticide composition killing a red-spotted lizard class pest.
Described synergistic composition is the technical scheme one of microemulsion:
Solvent and cosolvent have the mixture of one or more in methyl alcohol, ethanol, butanols, ethylene glycol, propane diols, glycerine, polyethylene glycol, acetone, cyclohexanone, pyrrolidones, toluene, dimethylbenzene, ethyl acetate, dimethyl formamide (DMF), dimethyl alum (DMSO).
Emulsifier is alkylbenzene naphthalene sulfonate, alkylphenol polyoxyethylene phosphate, diphenyl phenol polyethenoxy polyethenoxy ether, styrenated phenol APEO, alkylphenol polyoxyethylene formaldehyde condensation products, diphenyl phenol polyethenoxy polyformaldehyde condensation product, castor oil ethylene oxide adduct and derivative thereof, such as agriculture breast 300, agriculture breast 500, agriculture breast 600, Nongru-700, agriculture breast Sorp1KS, OX2511, NNO, NP series etc., emulsifier can be one or more mixture.
Antifreezing agent has the mixture of one or more in ethylene glycol, propane diols, glycerine, polyethylene glycol, sorbierite.
Stabilizing agent can be the mixture of one or more in urea, methyl alcohol, soluble starch, sodium sorbate, pyrogallic acid, aminobenzoic acid, cresyl glycidyl ether, phenyl glycidyl ether.
The concrete production stage of microemulsion be first active ingredient Avermectin and alkoxyl trisiloxanes are added dissolve completely in cosolvent after add emulsifier, antifreezing agent, stabilizing agent become transparent and homogeneous oily liquids after stirring again, filling, i.e. the microemulsion formulation of obtained synergistic composition of the present invention.
Described synergistic composition is the technical scheme two of microemulsion:
The concrete production stage of microemulsion be first active ingredient Avermectin and fatty alcohol-polyoxyethylene ether are added dissolve completely in cosolvent after add emulsifier, antifreezing agent, stabilizing agent become transparent and homogeneous oily liquids after stirring again, filling, i.e. the microemulsion formulation of obtained synergistic composition of the present invention.
Described synergistic composition is the technical scheme one of missible oil:
Conventional emulsifier have Nongru-700, agriculture breast 401, agriculture breast 300, agriculture breast 600, agriculture breast 1602, agriculture breast 0203B, agriculture breast 0201B, agriculture breast OX2568,6201,2201 in one or more.
The concrete production stage of this missible oil be first active ingredient Avermectin and fatty alcohol-polyoxyethylene ether are added dissolve completely in cosolvent after add the oily liquids that emulsifier for mixing evenly becomes transparent and homogeneous afterwards again, filling, i.e. the cream preparation of obtained synergistic composition of the present invention.
Described synergistic composition is the technical scheme two of missible oil:
The concrete production stage of this missible oil be first active ingredient Avermectin and fatty alcohol-polyoxyethylene ether are added dissolve completely in solvent after add the oily liquids that emulsifier for mixing evenly becomes transparent and homogeneous afterwards again, filling, i.e. the cream preparation of obtained synergistic composition of the present invention.
Described synergistic composition is the technical scheme of wetting powder:
Dispersant is the sodium lignin sulfonate of lignosulfonates, alkylnaphthalene sulfonate formaldehyde condensation products, nekal, polyoxyethylene polyoxypropylene base ether charcoal down section copolymer, alkylphenol-polyethenoxy phosphoric acid ester and collapse in outstanding DK8 one or more.
Wetting agent is sodium alkyl benzene sulfonate, fatty acid sulfates, bay alcohol radical sulphate, alkylphenol polyoxyethylene, moistening penetrating agent JFC, the withered powder of tea, spaonin powder, the one pulled open in powder.
Filler is the mixture of one or more of atlapulgite, clay, talcum powder, bentonite, precipitated calcium carbonate, kaolin, montmorillonite, diatomite, attapulgite, white carbon etc.
Stabilizing agent is one or more in alkyl phosphate and alkoxide, fatty acid polyoxy alkane alkene ester, phosphate and radical derivative, polyethylene glycol, glycerine, Isopropanediol, tricresyl phosphate butyrite.
The concrete production stage of this wetting powder is above-mentioned each composition mixing, and uniform stirring in stirred tank, after airslide disintegrating mill mixes, namely can be made into the wetting powder of this bright described synergistic composition.
Embodiment
Inventor finds Avermectin and has synergistic effect as the alkoxyl trisiloxanes of synergist or fatty alcohol-polyoxyethylene ether mixture to control white mulberry scale, and the present invention is further illustrated in conjunction with the embodiments in the present invention, but the present invention is not limited thereto.
The synergy test of Avermectin and alkoxyl trisiloxanes or fatty alcohol-polyoxyethylene ether.
Prepared by medicament: dilute for high concentration mother liquor by former for Avermectin medicinal acetone or dimethyl sulfoxide (DMSO), and then with 0.05% Qu Latong x-100 solution as solvent, again according to the liquid that reagent agent dilution is Different Weight concentration by the method for geometric ratio or equal difference, and with 0.05% Qu Latong x-100 solution-treated in contrast, determine the lethal concentration of 50 LC50 of Avermectin to white mulberry scale.
Experimental Method in Laboratory: fetch the branch with white mulberry scale larva in field, after cleaning foreign material, soaks 5-10s in different liquid, every concentration repeats 4 times, and at indoor feeding, add up each process lethality after 2-4d, lethality and correcting controling effect are by following formulae discovery.Synergetic pesticide composition in indoor to the toxic action data of a red-spotted lizard class pest see table 1.
Field trial method: carry out pharmacy test for contrasting with clear water and 1.8% abamectin emulsifiable concentrate.White mulberry scale nymph is based on nymph at the beginning of 2 ages.Utilize knapsack hand sprayer to each process even spraying, until processed limb is all squirted.After medicine 4 days, 3 fruit trees were investigated in every community, gather the branch with white mulberry scale nymph, take back indoor statistics lethality and correcting controling effect.Synergetic pesticide composition in field to the toxic action data of a red-spotted lizard class pest see table 2.
Embodiment 1:
0.9g Avermectin, 0.9g alkoxyl trisiloxanes (Silwet408), 15g cyclohexanone, 4g dimethyl sulfoxide (DMSO), No. 0203B, 7g farm chemical emulgent, 4g ethylene glycol, 2g methyl alcohol, water supply 100g, give strong mixing and homogenize, obtain the microemulsion formulation of synergistic composition.Obtained medicament is diluted 4500 times, with clear water and 1.8% abamectin emulsifiable concentrate for contrast.Do synergism experiment according to above-mentioned Experimental Method in Laboratory to white mulberry scale, toxic action data are see table 1.
Embodiment 2:
0.01g Avermectin, 25g alkoxyl trisiloxanes (Silwet408), 15g cyclohexanone, 6g dimethyl sulfoxide (DMSO), No. 0203B, 15g farm chemical emulgent, 4g ethylene glycol, 2g methyl alcohol, water supply 100g, give strong mixing and homogenize, obtain the microemulsion formulation of synergistic composition.Obtained medicament is diluted 50 times, with clear water and 1.8% abamectin emulsifiable concentrate for contrast.Do synergism experiment according to above-mentioned Experimental Method in Laboratory to white mulberry scale, toxic action data are see table 1.
Embodiment 3:
0.01g Avermectin, 50g alkoxyl trisiloxanes (Silwet408), 15g cyclohexanone, 8g dimethyl sulfoxide (DMSO), No. 0203B, 20g farm chemical emulgent, 4g ethylene glycol, 2g methyl alcohol, water supply 100g, give strong mixing and homogenize, obtain the microemulsion formulation of synergistic composition.Obtained medicament is diluted 50 times, with clear water and 1.8% abamectin emulsifiable concentrate for contrast.Do synergism experiment according to above-mentioned Experimental Method in Laboratory to white mulberry scale, toxic action data are see table 1.
Embodiment 4:
0.1g Avermectin, 25g fatty alcohol-polyoxyethylene ether, 15g cyclohexanone, 8g dimethyl sulfoxide (DMSO), No. 0203B, 20g farm chemical emulgent, 4g ethylene glycol, 2g methyl alcohol, water supply 100g, give strong mixing and homogenize, obtain the microemulsion formulation of synergistic composition.Obtained medicament is diluted 500 times, with clear water and 1.8% abamectin emulsifiable concentrate for contrast.Do synergism experiment according to above-mentioned Experimental Method in Laboratory to white mulberry scale, toxic action data are see table 1.
Embodiment 5:
0.01g Avermectin, 25g fatty alcohol-polyoxyethylene ether, 15g cyclohexanone, 8g dimethyl sulfoxide (DMSO), No. 0203B, 20g farm chemical emulgent, 4g ethylene glycol, 2g methyl alcohol, water supply 100g, give strong mixing and homogenize, obtain the microemulsion formulation of synergistic composition.Obtained medicament is diluted 50 times, with clear water and 1.8% abamectin emulsifiable concentrate for contrast.Do synergism experiment according to above-mentioned Experimental Method in Laboratory to white mulberry scale, toxic action data are see table 1.
Embodiment 6:
0.01g Avermectin, 50g fatty alcohol-polyoxyethylene ether, 15g cyclohexanone, 8g dimethyl sulfoxide (DMSO), No. 0203B, 20g farm chemical emulgent, 4g ethylene glycol, 2g methyl alcohol, water supply 100g, give strong mixing and homogenize, obtain the microemulsion formulation of synergistic composition, medicament is diluted 50 times, with clear water and 1.8% abamectin emulsifiable concentrate for contrast.Do synergism experiment according to above-mentioned Experimental Method in Laboratory to white mulberry scale, toxic action data are see table 1.
Embodiment 7:
0.9g Avermectin, 0.9g alkoxyl trisiloxanes (Silwet408), 15g cyclohexanone, 4g dimethyl sulfoxide (DMSO), No. 0203B, 7g farm chemical emulgent, 4g ethylene glycol, 2g methyl alcohol, water supply 100g, give strong mixing and homogenize, obtain the microemulsion formulation of synergistic composition.Synergistic combination is diluted 4500 times, adopt spraying process.Do synergism experiment according to above-mentioned field trial method to white mulberry scale, toxic action data are see table 2.
Embodiment 8:
0.01g Avermectin, 25g alkoxyl trisiloxanes (Silwet408), 15g cyclohexanone, 6g dimethyl sulfoxide (DMSO), No. 0203B, 15g farm chemical emulgent, 4g ethylene glycol, 2g methyl alcohol, water supply 100g, give strong mixing and homogenize, obtain the microemulsion formulation of synergistic composition, medicament is diluted 50 times, do synergism experiment according to above-mentioned field trial method to white mulberry scale, toxic action data are see table 2.
Embodiment 9:
0.01g Avermectin, 50g alkoxyl trisiloxanes (Silwet408), 15g cyclohexanone, 8g dimethyl sulfoxide (DMSO), No. 0203B, 20g farm chemical emulgent, 4g ethylene glycol, 2g methyl alcohol, water supply 100g, give strong mixing and homogenize, obtain the microemulsion formulation of synergistic composition, medicament is diluted 50 times, do synergism experiment according to above-mentioned field trial method to white mulberry scale, toxic action data are see table 2.
Embodiment 10:
0.1g Avermectin, 25g fatty alcohol-polyoxyethylene ether, 15g cyclohexanone, 8g dimethyl sulfoxide (DMSO), No. 0203B, 20g farm chemical emulgent, 4g ethylene glycol, 2g methyl alcohol, water supply 100g, give strong mixing and homogenize, obtain the microemulsion formulation of synergistic composition, medicament is diluted 500 times, do synergism experiment according to above-mentioned field trial method to white mulberry scale, toxic action data are see table 2.
Embodiment 11:
0.01g Avermectin, 25g fatty alcohol-polyoxyethylene ether, 15g cyclohexanone, 8g dimethyl sulfoxide (DMSO), No. 0203B, 20g farm chemical emulgent, 4g ethylene glycol, 2g methyl alcohol, water supply 100g, give strong mixing and homogenize, obtain the microemulsion formulation of synergistic composition, medicament is diluted 50 times, do synergism experiment according to above-mentioned field trial method to white mulberry scale, toxic action data are see table 2.
Embodiment 12:
0.01g Avermectin, 50g fatty alcohol-polyoxyethylene ether, 15g cyclohexanone, 8g dimethyl sulfoxide (DMSO), No. 0203B, 20g farm chemical emulgent, 4g ethylene glycol, 2g methyl alcohol, water supply 100g, give strong mixing and homogenize, obtain the microemulsion formulation of synergistic composition, medicament is diluted 50 times, do synergism experiment according to above-mentioned field trial method to white mulberry scale, toxic action data are see table 2.
Table 1 is the toxic action data of indoor measurement synergetic pesticide composition to a red-spotted lizard class pest.
Table 2 is for field test synergetic pesticide composition is to the toxic action data of a red-spotted lizard class pest.
Claims (5)
1. one kind is killed the synergetic pesticide composition of a red-spotted lizard class pest, it is characterized in that, described synergetic pesticide composition with Avermectin and alkoxyl trisiloxanes Silwet408 for active component, form with carrier and auxiliary combination, the ratio of weight and number of described Avermectin and alkoxyl trisiloxanes Silwet408 is 1:5000, and described synergetic pesticide composition is microemulsion.
2. synergetic pesticide composition according to claim 1, is characterized in that, described active component sum accounts for the 0.01-99% of synergetic pesticide composition gross weight.
3. synergetic pesticide composition according to claim 1, is characterized in that, described synergetic pesticide composition is sprayed by apparatus or manually smeared a red-spotted lizard class pest of liquid control woody plant.
4. synergetic pesticide composition according to claim 3, is characterized in that, described woody plant is fruit tree or forest.
5. synergetic pesticide composition according to claim 1, is characterized in that, described a red-spotted lizard class pest is white mulberry scale, san jose scale, tells human relations ball hard a red-spotted lizard, the large ball a red-spotted lizard of jujube, Parlatoria oleae, moire a red-spotted lizard or Acer negundo a red-spotted lizard.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310158072.4A CN103250732B (en) | 2013-05-02 | 2013-05-02 | Synergistic pesticide composition for killing scale insects |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310158072.4A CN103250732B (en) | 2013-05-02 | 2013-05-02 | Synergistic pesticide composition for killing scale insects |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103250732A CN103250732A (en) | 2013-08-21 |
| CN103250732B true CN103250732B (en) | 2015-05-20 |
Family
ID=48955246
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310158072.4A Expired - Fee Related CN103250732B (en) | 2013-05-02 | 2013-05-02 | Synergistic pesticide composition for killing scale insects |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103250732B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108781932A (en) * | 2018-05-22 | 2018-11-13 | 广西昭平县古书茶业有限公司 | A kind of control method of the tea tree a red-spotted lizard class pest of tea tree |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106719622B (en) * | 2016-11-25 | 2020-10-27 | 广东省农业科学院植物保护研究所 | Pesticide synergistic decrement agent |
| CN107821428A (en) * | 2017-11-15 | 2018-03-23 | 惠州市永耐宝新材料有限公司 | A kind of composite synergistic agricultural chemicals |
| CN110754484B (en) * | 2019-09-27 | 2021-05-25 | 贵州省果树科学研究所 | Mulberry scale control method for reducing pesticide residues in dragon orchard |
| CN113349226A (en) * | 2021-05-26 | 2021-09-07 | 仲恺农业工程学院 | Application of rose oil in pest control |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101502266A (en) * | 2009-03-27 | 2009-08-12 | 郭正 | Liquid pesticide formulation containing avermectin pesticide and organosilicon surfactant and preparation method thereof |
| CN101564036A (en) * | 2009-04-08 | 2009-10-28 | 陶钧炳 | Abamectin-containing aqueous emulsion |
| CN102599175A (en) * | 2008-12-31 | 2012-07-25 | 浙江世佳科技有限公司 | Emulsifiable concentrate of propylene glycol alginate and avermectin |
-
2013
- 2013-05-02 CN CN201310158072.4A patent/CN103250732B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102599175A (en) * | 2008-12-31 | 2012-07-25 | 浙江世佳科技有限公司 | Emulsifiable concentrate of propylene glycol alginate and avermectin |
| CN101502266A (en) * | 2009-03-27 | 2009-08-12 | 郭正 | Liquid pesticide formulation containing avermectin pesticide and organosilicon surfactant and preparation method thereof |
| CN101564036A (en) * | 2009-04-08 | 2009-10-28 | 陶钧炳 | Abamectin-containing aqueous emulsion |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108781932A (en) * | 2018-05-22 | 2018-11-13 | 广西昭平县古书茶业有限公司 | A kind of control method of the tea tree a red-spotted lizard class pest of tea tree |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103250732A (en) | 2013-08-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103250732B (en) | Synergistic pesticide composition for killing scale insects | |
| CN101743970A (en) | Cyhalofop-butyl-containing pesticide composition and application thereof | |
| CN101380008A (en) | Disinsection composition with synergistic action | |
| CN103155929B (en) | Binary pesticide composition and application thereof | |
| CN106922728B (en) | A kind of suspension seed-coating agent for preventing brassicaceous vegetable phyllotreta striolata | |
| CN102907420B (en) | Insect aerosol synergist | |
| CN107711878A (en) | Killing nature herbiciding composition containing 2,4 drop dimethylamine salts and glufosinate-ammonium | |
| CN102302038B (en) | Weedicide for orchards and forest lands | |
| CN102265836A (en) | Acaricide composition containing spirodiclofen and etoxazole and application thereof | |
| CN102805102B (en) | Disinsection combination containing fosthiazate and ryanodine receptor inhibitor insecticide | |
| CN105410013A (en) | Insecticide-pesticide mixture preparation | |
| CN104996458B (en) | Composition pesticide and its application | |
| CN102228056B (en) | Pesticide composition containing sulfur-fluorine oxime ether and part of organophosphorus pesticides | |
| CN101617676B (en) | Pesticide composition | |
| CN103250713B (en) | Synergistic pesticide composition for killing gall midge insects | |
| CN105901012A (en) | Suspended seed coating prepared from pyraclostrobin, penflufen and clothianidin | |
| CN104397011B (en) | Insect-killing mite-killing agent composition with synergic effect | |
| CN108208015A (en) | A kind of agricultural chemicals suspension agent and its preparation method and application | |
| CN102613208A (en) | Composition for preventing and removing weeds in rice field | |
| CN103518773B (en) | Insecticidal composition with synergism | |
| CN102550573B (en) | Chlorantraniliprole and rotenone compound suspending agent and its preparation method | |
| CN103070190B (en) | Combination used for preventing and removing weed in paddy field | |
| CN104304253A (en) | Pesticide composition containing chlorfenapyr and picoxystrobin and its preparation and use | |
| CN105475346B (en) | A kind of Pesticidal combination | |
| CN102771494A (en) | Insecticidal composition containing Guadipyr and macrolide pesticide |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150520 |