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CN103223489B - A kind of preparation method of eccentric wheel powder metallurgy - Google Patents

A kind of preparation method of eccentric wheel powder metallurgy Download PDF

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CN103223489B
CN103223489B CN201310120611.5A CN201310120611A CN103223489B CN 103223489 B CN103223489 B CN 103223489B CN 201310120611 A CN201310120611 A CN 201310120611A CN 103223489 B CN103223489 B CN 103223489B
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eccentric wheel
weight portion
modified additive
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CN103223489A (en
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吴建平
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Guangdong Weiqiang Technology Co ltd
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Abstract

The invention discloses the preparation method of a kind of eccentric wheel powder metallurgy, it comprises the following steps: eccentric wheel is made up of the raw material of following weight percentage: the nickel of 0.2-0.4%, the molybdenum of 0.4-0.6%, 0.6-0.8% tin, the aluminium oxide powder of 0.3-0.5%, the graphite powder of 0.8-1%, the paraffin of 0.4-0.6%, the copper of 4-6%, the modified additive of 1-2%, remaining be iron;The present invention is by the modified additive added, superfines is provided in mixing raw material, this superfines can be filled between oarse-grained gap, improve the apparent density of compound, plastic of poly vinyl acetate and atoleine add in modified additive as lubricant, enhance this modified additive effect in mixing compacting, powder metallurgy structural part compact strength is greatly improved under equal pressing pressure, change raw materials particles combining form and pore shape, from root, solve the generation of crackle.

Description

A kind of preparation method of eccentric wheel powder metallurgy
Technical field
The invention mainly relates to the preparation method of a kind of eccentric wheel powder metallurgy, belong to casting field.
Background technology
Along with the economic development of China, powder metallurgy structure purposes is more and more wider.Powder metallurgy, as a kind of near-net-shape technology, has the biggest economic advantages when producing the part that the batches such as structural member are big, dimensional accuracy is high, processing charges are high.But powder metallurgy structural part exists a weakness: product is the lowest at un-sintered front compact strength, cause that crackle easily occur in shaping and handling process, and cannot find out in the fabrication process.This some application on as vehicle key position part be fatal defect, result in powder metallurgy structural part and can be only applied on medium to low-risk stressed member, range is limited by very large.
Powder metallurgy structural part intensity is mainly affected by three aspect factors: one is material composition, and two is product density, and three are whether product crackle occurs in shaping with handling process.Material composition affects manufacturing cost, and product density is very big with mould loss impact on forming bench, and crackle is mainly by pressed compact intensity effect, and is difficult to find out.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that the preparation method of a kind of eccentric wheel powder metallurgy.
The present invention is achieved by the following technical solutions:
A kind of preparation method of eccentric wheel powder metallurgy, it comprises the following steps:
(1) dispensing: described eccentric wheel is made up of the raw material of following weight percentage:
The nickel of 0.2-0.4%, the molybdenum of 0.4-0.6%, 0.6-0.8% tin, the aluminium oxide powder of 0.3-0.5%, the graphite powder of 0.8-1%, the paraffin of 0.4-0.6%, the copper of 4-6%, the modified additive of 1-2%, remaining be iron;
Described modified additive is made up of the raw material of following weight parts:
Nano zinc oxide powder 90-100, calcium hydroxide 30-40, stearic acid 30-40, cumyl peroxide 6-8, plastic of poly vinyl acetate 8-10, nano-tungsten powder 2-4, AEO 2-3, atoleine 3-4, aminopropyl triethoxysilane 0.8-1, water are appropriate;
The preparation method of described modified additive comprises the following steps:
A, by the water of the quality such as the calcium hydroxide of above-mentioned weight portion joins, agitating heating 20-30 minute at 90-110 DEG C, obtain calcium hydroxide aqueous solution;
B, the stearic acid of above-mentioned weight portion is heated to 60-70 DEG C, add the nano-tungsten powder of above-mentioned weight portion, AEO, rise high-temperature as 80-85 DEG C, constant temperature stirs 1-2 hour, it is slowly added into above-mentioned calcium hydroxide aqueous solution under agitation, continue stirring 1-2 hour after interpolation, obtain mixed liquor;
C, the nano zine oxide powder particles of above-mentioned weight portion is distributed in water, obtains the suspension containing nano zinc oxide powder;
D, the above-mentioned suspension containing nano zinc oxide powder adds the cumyl peroxide of above-mentioned weight portion, plastic of poly vinyl acetate, atoleine stir 40-50 minute under the speed of 500-600 rev/min, add the mixed liquor that the aminopropyl triethoxysilane of above-mentioned weight portion obtains with step B, high speed 1800-2000 rev/min stirs 20-30 minute, dry, grind into superfines, obtain described modified additive.
(2) compacting: put into cold stamping die after being mixed by each raw material of above-mentioned weight portion, suppresses 1-3 minute under the pressure of 800-900MPa, makes blank of colding pressing;
(3) sintering: under conditions of sintering atmosphere is vacuum, reducing atmosphere or inert atmosphere, above-mentioned blank of colding pressing is sintered under the pressure of 1-5MPa, temperature schedule is: first pre-burning 5-10 minute at 300-500 DEG C, then high-temperature is risen with the speed of 5-7 DEG C/minute, when temperature reaches 700-800 DEG C, constant temperature 15-25 minute, high-temperature is risen again with the speed of 3-5 DEG C/minute, when temperature reaches 900-1050 DEG C, constant temperature 1-2 hour, reduce temperature with the speed of 4-6 DEG C/minute the most again to cool down to normal temperature, obtain the semi-finished product of eccentric wheel;
(4) being heat-treated: at 860-880 DEG C, eccentric wheel semi-finished product are incubated 1-3 hour, quench subsequently into oil groove, oil temperature is 45-55 DEG C, sends into tempering furnace and be tempered 1-2 hour after quenching, and temperature 200-250 DEG C is incubated 1-2 hour, is then cooled to room temperature;
(5) phosphatization: pre-phosphatization: Phosphating Solution solution temperature is 90-100 DEG C, pre-phosphating time is 10-15 minute;Pickling: at room temperature with the hydrochloric acid solution pickling that concentration is 10-12% 1-3 minute;Normal temperature is washed 2-3 time;Phosphatization again: Phosphating Solution temperature is 90-100 DEG C, phosphating time is 20-30 minute;Temperature is that the water of 70-80 DEG C cleans 2-3 time;Eccentric wheel described in drying.
The invention have the advantage that
The present invention is by the modified additive added, superfines is provided in mixing raw material, this superfines can be filled between oarse-grained gap, thus improve the apparent density of compound, and this superfines be mainly composed of nano zinc oxide powder and calcium stearate, pass through silane coupler, the new modified auxiliary agent that the auxiliary agents such as cumyl peroxide obtain, every physical characteristics such as the wearability further increasing goods, wherein plastic of poly vinyl acetate and atoleine add in modified additive as lubricant, enhance this modified additive effect in mixing compacting, powder metallurgy structural part compact strength is greatly improved under equal pressing pressure, change raw materials particles combining form and pore shape, the generation of crackle is solved from root.
Detailed description of the invention
Embodiment 1
A kind of preparation method of eccentric wheel powder metallurgy, it comprises the following steps:
(1) dispensing: described eccentric wheel is made up of the raw material of following weight percentage:
The nickel of 0.4%, the molybdenum of 0.6%, 0.8% tin, the aluminium oxide powder of 0.5%, the graphite powder of 0.8%, the paraffin of 0.6%, the copper of 6%, the modified additive of 2%, remaining be iron;
Described modified additive is made up of the raw material of following weight parts:
Nano zinc oxide powder 100, calcium hydroxide 40, stearic acid 40, cumyl peroxide 8, plastic of poly vinyl acetate 10, nano-tungsten powder 4, AEO 3, atoleine 4, aminopropyl triethoxysilane 1, water are appropriate;
The preparation method of described modified additive comprises the following steps:
A, by the water of the quality such as the calcium hydroxide of above-mentioned weight portion joins, agitating heating 30 minutes at 110 DEG C, obtain calcium hydroxide aqueous solution;
B, the stearic acid of above-mentioned weight portion is heated to 70 DEG C, add the nano-tungsten powder of above-mentioned weight portion, AEO, rise high-temperature as 85 DEG C, constant temperature stirs 2 hours, it is slowly added into above-mentioned calcium hydroxide aqueous solution under agitation, continue stirring 1 hour after interpolation, obtain mixed liquor;
C, the nano zine oxide powder particles of above-mentioned weight portion is distributed in water, obtains the suspension containing nano zinc oxide powder;
D, the above-mentioned suspension containing nano zinc oxide powder adds the cumyl peroxide of above-mentioned weight portion, plastic of poly vinyl acetate, atoleine stir 50 minutes under the speed of 600 revs/min, add the mixed liquor that the aminopropyl triethoxysilane of above-mentioned weight portion obtains with step B, 2000 revs/min are stirred 30 minutes at a high speed, dry, grind into superfines, obtain described modified additive.
(2) compacting: put into cold stamping die after being mixed by each raw material of above-mentioned weight portion, suppresses 3 minutes under the pressure of 900MPa, makes blank of colding pressing;
(3) sintering: under conditions of sintering atmosphere is vacuum, reducing atmosphere or inert atmosphere, above-mentioned blank of colding pressing is sintered under the pressure of 5MPa, temperature schedule is: first pre-burning 10 minutes at 500 DEG C, then rises high-temperature, when temperature reaches 800 DEG C with the speed of 7 DEG C/minute, constant temperature 25 minutes, high-temperature, when temperature reaches 1050 DEG C, constant temperature 2 hours is risen again with the speed of 5 DEG C/minute, reduce temperature with the speed of 6 DEG C/minute the most again to cool down to normal temperature, obtain the semi-finished product of eccentric wheel;
(4) being heat-treated: at 880 DEG C, eccentric wheel semi-finished product are incubated 1 hour, quench subsequently into oil groove, oil temperature is 55 DEG C, sends into tempering furnace and be tempered 1 hour after quenching, and temperature 250 DEG C is incubated 2 hours, is then cooled to room temperature;
(5) phosphatization: pre-phosphatization: Phosphating Solution solution temperature is 100 DEG C, pre-phosphating time is 15 minutes;Pickling: at room temperature with the hydrochloric acid solution pickling that concentration is 12% 3 minutes;Normal temperature is washed 3 times;Phosphatization again: Phosphating Solution temperature is 100 DEG C, phosphating time is 30 minutes;Temperature is that the water of 80 DEG C cleans 2-3 time;Eccentric wheel described in drying.
Performance test:
Ultimate tensile strength intensity σ b (MPa): 817
Yield strength σ s (MPa): 507
Percentage elongation δ 5 (%): 160
Contraction percentage of area ψ (%): 39.

Claims (1)

1. the preparation method of an eccentric wheel powder metallurgy, it is characterised in that it comprises the following steps:
(1) dispensing: described eccentric wheel is made up of the raw material of following weight percentage: the nickel of 0.2-0.4%, the molybdenum of 0.4-0.6%, 0.6-0.8% tin, the aluminium oxide powder of 0.3-0.5%, the graphite powder of 0.8-1%, the paraffin of 0.4-0.6%, the copper of 4-6%, the modified additive of 1-2%, remaining be iron;Described modified additive is made up of the raw material of following weight parts: nano zinc oxide powder 90-100, calcium hydroxide 30-40, stearic acid 30-40, cumyl peroxide 6-8, plastic of poly vinyl acetate 8-10, nano-tungsten powder 2-4, AEO 2-3, atoleine 3-4, aminopropyl triethoxysilane 0.8-1, water are appropriate;The preparation method of described modified additive comprises the following steps: A, by the water of the quality such as the calcium hydroxide of above-mentioned weight portion joins, and agitating heating 20-30 minute at 90-110 DEG C obtains calcium hydroxide aqueous solution;B, the stearic acid of above-mentioned weight portion is heated to 60-70 DEG C, add the nano-tungsten powder of above-mentioned weight portion, AEO, rise high-temperature to 80-85 DEG C, constant temperature stirs 1-2 hour, it is slowly added into above-mentioned calcium hydroxide aqueous solution under agitation, continue stirring 1-2 hour after interpolation, obtain mixed liquor;C, the nano zine oxide powder particles of above-mentioned weight portion is distributed in water, obtains the suspension containing nano zinc oxide powder;D, the above-mentioned suspension containing nano zinc oxide powder adds the cumyl peroxide of above-mentioned weight portion, plastic of poly vinyl acetate, atoleine stir 40-50 minute under the speed of 500-600 rev/min, add the mixed liquor that the aminopropyl triethoxysilane of above-mentioned weight portion obtains with step B, high speed 1800-2000 rev/min stirs 20-30 minute, dry, grind into superfines, obtain described modified additive;
(2) compacting: put into cold stamping die after being mixed by each raw material of above-mentioned weight portion, suppresses 1-3 minute under the pressure of 800-900MPa, makes blank of colding pressing;
(3) sintering: under conditions of sintering atmosphere is vacuum, reducing atmosphere or inert atmosphere, above-mentioned blank of colding pressing is sintered under the pressure of 1-5MPa, temperature schedule is: first pre-burning 5-10 minute at 300-500 DEG C, then high-temperature is risen with the speed of 5-7 DEG C/minute, when temperature reaches 700-800 DEG C, constant temperature 15-25 minute, high-temperature is risen again with the speed of 3-5 DEG C/minute, when temperature reaches 900-1050 DEG C, constant temperature 1-2 hour, reduce temperature with the speed of 4-6 DEG C/minute the most again and be cooled to normal temperature, obtain the semi-finished product of eccentric wheel;
(4) being heat-treated: at 860-880 DEG C, eccentric wheel semi-finished product are incubated 1-3 hour, quench subsequently into oil groove, oil temperature is 45-55 DEG C, sends into tempering furnace and be tempered 1-2 hour after quenching, and temperature 200-250 DEG C is incubated 1-2 hour, is then cooled to room temperature;
(5) phosphatization: pre-phosphatization: Phosphating Solution solution temperature is 90-100 DEG C, pre-phosphating time is 10-15 minute;Pickling: at room temperature with the hydrochloric acid solution pickling that concentration is 10-12% 1-3 minute;Normal temperature is washed 2-3 time;Phosphatization again: Phosphating Solution temperature is 90-100 DEG C, phosphating time is 20-30 minute;Temperature is that the water of 70-80 DEG C cleans 2-3 time;Eccentric wheel described in drying.
CN201310120611.5A 2013-04-09 2013-04-09 A kind of preparation method of eccentric wheel powder metallurgy Active CN103223489B (en)

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CN103572162A (en) * 2013-10-10 2014-02-12 铜陵国方水暖科技有限责任公司 Powder-metallurgy slippage pump rotor and preparation method thereof
CN103602899A (en) * 2013-10-10 2014-02-26 铜陵新创流体科技有限公司 Powder metallurgy alloy material and preparation method thereof
CN103600081B (en) * 2013-10-10 2016-05-04 铜陵新创流体科技有限公司 A kind of powder-metallurgy refrigeration compressor valve sheet and preparation method thereof
CN103600073B (en) * 2013-10-10 2016-05-04 铜陵新创流体科技有限公司 A kind of powder metallurgy chain wheel and preparation method thereof
CN103600076B (en) * 2013-10-10 2016-05-04 铜陵新创流体科技有限公司 A kind of powder metallurgy automobile power steering pump stator and preparation method thereof
CN103537676A (en) * 2013-10-11 2014-01-29 芜湖市鸿坤汽车零部件有限公司 Powder metallurgy transmission gear and manufacturing method thereof
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CN110788332A (en) * 2019-11-29 2020-02-14 济南市博瀚精工机械有限公司 Powder metallurgy eccentric wheel for atomizer compression pump and preparation method thereof

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WO2002075171A1 (en) * 2001-03-16 2002-09-26 Sundram Fasteners Limited Conrod and a method of producing the same
CN102335746A (en) * 2011-09-26 2012-02-01 吕元之 Powder metallurgy sedan synchronizer gear hub and production method thereof
CN102913555A (en) * 2012-04-17 2013-02-06 向朝霞 Powder metallurgical composite oil-containing bearing and manufacturing method thereof
CN102965571A (en) * 2012-10-25 2013-03-13 安徽蓝博旺机械集团振邺机械有限公司 Powder metallurgy method for pump body of hydraulic pump

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1370645A (en) * 2000-07-07 2002-09-25 川崎制铁株式会社 Iron-base mixed powder for powder metallurgy
WO2002075171A1 (en) * 2001-03-16 2002-09-26 Sundram Fasteners Limited Conrod and a method of producing the same
CN102335746A (en) * 2011-09-26 2012-02-01 吕元之 Powder metallurgy sedan synchronizer gear hub and production method thereof
CN102913555A (en) * 2012-04-17 2013-02-06 向朝霞 Powder metallurgical composite oil-containing bearing and manufacturing method thereof
CN102965571A (en) * 2012-10-25 2013-03-13 安徽蓝博旺机械集团振邺机械有限公司 Powder metallurgy method for pump body of hydraulic pump

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