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CN103201428A - Surface sizing composition for print media in digital printing - Google Patents

Surface sizing composition for print media in digital printing Download PDF

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Publication number
CN103201428A
CN103201428A CN2010800702150A CN201080070215A CN103201428A CN 103201428 A CN103201428 A CN 103201428A CN 2010800702150 A CN2010800702150 A CN 2010800702150A CN 201080070215 A CN201080070215 A CN 201080070215A CN 103201428 A CN103201428 A CN 103201428A
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CN
China
Prior art keywords
amount
surface sizing
print media
sizing composition
paper
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Pending
Application number
CN2010800702150A
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Chinese (zh)
Inventor
周晓奇
G.A.温格科诺
D.埃德蒙森
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Hewlett Packard Development Co LP
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Hewlett Packard Development Co LP
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Application filed by Hewlett Packard Development Co LP filed Critical Hewlett Packard Development Co LP
Publication of CN103201428A publication Critical patent/CN103201428A/en
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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16—Sizing or water-repelling agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/71—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes
    • D21H17/74—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes of organic and inorganic material
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/38—Coatings with pigments characterised by the pigments
    • D21H19/385—Oxides, hydroxides or carbonates
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/38—Coatings with pigments characterised by the pigments
    • D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/64—Inorganic compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/80—Paper comprising more than one coating
    • D21H19/84—Paper comprising more than one coating on both sides of the substrate
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/22—Addition to the formed paper
    • D21H23/52—Addition to the formed paper by contacting paper with a device carrying the material
    • D21H23/56—Rolls

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Paper (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Ink Jet (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A size press (SP) surface sizing composition provides a SP surface sizing (120) for a print medium (100) that is used in a digital printing system (200). The surface sizing composition includes an aqueous mixture including a macromolecular material in an amount from about 25% to about 75% dry weight; an inorganic metallic salt in an amount from about 3% to about 20% dry weight; and an amount of inorganic pigment ranging from at least 16% to about 60% dry weight, such that a total dry weight equals about 100%.

Description

The surface sizing composition that print media in figure punch is used
Cross reference to related application
N/A。
Statement about federal sponsored research or exploitation
N/A。
Background
Printing technique can roughly be divided into two classes: analog-and digital-.Common analogue technique is that hectograph is printed, gentle version is printed, intaglio plate is printed and silk screen is printed.Ink-jet and electrophotographic printer are digital technologies the most prevailing.The advantage that figure punch is better than its analog counterpart is numeral to change printout, means that each type face can be different.In order to change the printout of printer emulation, must manufacture new one group of imaging plate or template.More cost is effective under low running length (number of pages) for the figure punch method, and large number of pages simulation is printed more economical.Print quality is that another between Method of printing is more vectorial.The simulation printed product usually has preferably image quality and also usually moves with higher print speed, but figure punch approaches quality and the print speed that simulation is printed along with the progress of printer hardware, pad-ink and print media.
From the eighties since mid-term, electrofax (EP) is printed---and often being called laser printing, is popular selection in high-quality at needs, as to seem professional type information consumer.Nowadays the business EP printer of prior art situation has the image quality be equal to the offset lithography printer.
Ink-jet printer is nowadays common and economical, even and also can obtain photograph quality under low print speed.They are used in home print, office's printing and more nearest, during business is printed.The key advantage of ink-jet technology in the business printing market is the easy convergent-divergent of print span and can realizes high print speed.
Print media used in figure punch is to print attribution, as print quality, printer durability and reliability and print speed (they are on printer manufacturer and end user and the attribute of overstating and wanting) have various impacts.The challenge of printing media manufacturer is to manufacture the printed product that can make these print attributions keep optimum state.
The accompanying drawing summary
The as detailed below of considering with reference to connection with figures is easier to understand various feature as herein described, like numerals will designate similar structural detail wherein, and wherein:
Fig. 1 shows the side view according to an example of the print media of principle as herein described.
Fig. 2 shows the block diagram according to an example of the digital printing system of principle as herein described.
Fig. 3 shows the flow chart according to an example of the method for principle manufacture surface sizing composition as herein described.
Fig. 4 shows the flow chart according to an example of the method for principle manufacture print media as herein described.
Some example has the further feature that supplements and replace graphic feature in above-mentioned accompanying drawing.Below with reference to above-mentioned accompanying drawing in detail these and other feature is described in detail.
Describe in detail
Describe in this article surface sizing composition, comprised the print media of this surface sizing composition and comprised the example of the digital printing system of this print media.In addition, the method for manufacturing this surface sizing composition and the example of manufacturing the method for this print media have been described in this article.This surface sizing composition is the aqueous mixture that comprises the preparation of macromolecular material, inorganic pigment and inorganic salts, and wherein with respect to commercially available surface sizing composition, a certain amount of inorganic pigment has replaced a certain amount of macromolecular material.This print media comprise with this surface sizing composition applying glue for figure punch based on cellulosic paper, and digital printing system comprises one of ink-jet technology, dry electrophotography (EP) and liquid EP.
This surface sizing composition also is known as size press (SP) surface sizing composition in this article.According to definition, " SP surface sizing composition " or " SP Cypres " is applied directly to or plans to be applied directly on the surface based on cellulosic paper web in the process of the online top sizing method of the size presser of using paper making equipment (being paper machine).In online top sizing method in paper-making process, the solution that will at least comprise the material (i.e. " macromolecular material ") with macromolecule by size presser is applied to paper surface.Be different from usually and add the paper coating on the paper of making to the off-line coating machine in the paper coating process according to the SP surface sizing composition of principle as herein described and the example of manufacturing the method for print media.For example, with independent coating machine, with the coating speed off-line that is less than 800 m/mins (m/min.), apply paper coating, it has every face at least 5 g/ms of (gsm) or larger dry coating weight and the viscosity that is greater than about 1000 centipoises (cP) at paper.On the contrary, according to the SP surface sizing composition of principle herein by the size presser of paper machine or equipment for example to be not less than 800 m/min. and to be less than the low coating dry weight of 5 gsm and to be less than applying online than low viscosity of about 200 cP up to the paper production speeds of 3,500 m/min., every face of paper web.In addition, be different from the example of the method for manufacturing print media the inner stuffing in paper-making process and the internal sizing further described below according to the SP surface sizing composition of principle as herein described.
This cellulose paper web can be made by any suitable wood pulp or non-wood pulp.The limiting examples of suitable pulp composition includes, but not limited to groundwood pulp, chemigroundwood pulp, chemical-mechanical slurry, hot mechanical pulp (TMP) and above-mentioned one or more combination.In some instances, this cellulose paper web comprises bleached hardwood chemistry kraft pulp.This bleached hardwood chemistry kraft pulp for example contains more than the hardwood fiber of 70 % by weight in total fiber content, and it has the fibre structure shorter than soft wood pulp (about 0.3 to about 0.6 mm length).This contributes to the good paper product that forms volume for example or sheet form than the staple fibre structure.
In addition, filler can be incorporated in paper pulp for example to the physical property with the paper product of basic controlling volume or sheet form.That the void space of filler particles fiberfill fibers network essence produce is finer and close when there is no filler, more smoothly, brighter and opaque sheet material.Filler also can significantly reduce costs, because filler is usually cheap than paper pulp itself.The example that is incorporated to the filler in paper pulp includes, but not limited to the combination of powdered whiting, winnofil, titanium dioxide, kaolin, silicate, plastic pigment, hibbsite and above-mentioned any material.Amount of filler in paper pulp can comprise nearly for example 20 % by weight.In some instances, about 0% to about 20% of the paper product that the amount of filler in paper pulp is volume or sheet form.In another example, about 5% to about 15% of the paper product that amount of filler is volume or sheet form.In some instances, if filler percentage is greater than 20 % by weight, can reduce the fiber of paper pulp to inter-fibre-bond, this can reduce deflection and the intensity of the gained paper product of volume or sheet form thereupon.
In addition, can comprise for example internal sizing.Internal sizing can improve the internal bond strength of paper pulp fiber, also can control WATER RESISTANCE liquid wetting, infiltration and the absorbability of the paper product of volume or sheet form.Can realize internal sizing processing by the wet end of papermaking, sizing agent being added in fiber furnish (or paper pulp fiber source).The limiting examples of suitable sizing agent comprises abietyl sizing agent, cerul sizing agent, cellulose-reactive sizing agent and other synthetic sizing agent and their combination or mixture.The internal sizing degree can characterize by Hercules Sizing Test (HST) value.In some instances, should there is based on cellulosic paper web the internal sizing (being soft internal sizing) of the low HST value that has 1 to 50.In some instances, the HST value is about 1 to about 10.Excessively internal sizing may affect the print quality on paper product for example, and it may cause color and the bleeding between color (color-to-color bleed) that is printed on the printing ink on paper product.
Article used herein " one " is intended to have its its ordinary meaning in patent field, i.e. " one or more ".For example " filler " typically refers to one or more fillers, and therefore " described filler " in this article refers to " described one or more fillers ".Term used herein " at least " is that exponential quantity is equal to or greater than listed numerical value.Term used herein " approximately " refer to listed numerical value can differ+or-20%, for example " about 5 " refer to 4 to 6 scope.The term used together with two numerical value " between ", for example " between about 2 to about 50 " comprise this two listed numerical value.Any number range provided herein be included in provided scope or between numerical value.Term used herein " substantially " refers to major part or almost all or all, or the amount of about 51% to 100% scope for example.Mention in this article " top ", " bottom ", " ”,“ bottom, top ", " on ", D score, " left side " or " right side " be not intended to be construed as limiting in this article.In addition, example herein only is intended to illustrate and is to discuss but not provide as restriction.
Natural or the synthetic macromolecule material that comprises about 25% amount to about 75% dry weight according to the surface sizing composition of principle as herein described in aqueous mixture; The inorganic metal salt of about 3% amount to about 20% dry weight; With the inorganic pigment that is greater than 15% amount to about 60% dry weight, so that the gross dry weight amount equals about 100%.This aqueous mixture is the surface sizing composition that size press (SP) applies in online papermaking.Compare with the top sizing of commercially available office printing paper in market, have especially following one or more according to the SP surface sizing composition of principle as herein described: lower macromolecular material content, lower salt content and higher inorganic pigment (filler) content.In some instances, with commercially available office printing paper, compare, according to the SP surface sizing composition of principle as herein described have following each: lower macromolecular material content, lower salt content and higher inorganic pigment (filler) content.
This macromolecular material is to serve as the sizing agent of SP surface sizing composition and the high molecular weight material of adhesive, as high molecular weight polymer.In some instances, this macromolecular material comprises one of synthetic polymer and natural polymer or both.Especially, according to definition, this macromolecular material is water-soluble or water dispersible, and having strong film forming ability also can be by the bonding formation pantostrat of inorganic pigment granules.In addition, according to definition, this macromolecular material is inertia to inorganic metal salt.Term used herein " film forming " refers to, in dry run, in other words when from based on cellulosic paper web, removing aqueous solvent, this large molecule can form contiguous network, or latex particle can flock together to form continuous film, or in macroscopic aspect the continuous barrier layer to aqueous solvent or moisture.Term 'inertia' used herein refers to that this macromolecular material does not interact with fixative so that causes polymer precipitation, gelling or form the solid particle of any kind, and this adversely reduces the adhesive power of macromolecular material and the spreading ability of SP surface sizing composition.
In macromolecular material, the example of available synthetic polymer comprises, but be not limited to the copolymer emulsion of polyvinyl alcohol, polyvinylpyrrolidone, acrylic latex, styrene-butadiene latex, poly latex and any above-mentioned monomer and their combination or mixture.In macromolecular material, the example of available natural polymer includes, but not limited to the combination of casein, soybean protein, polysaccharide, cellulose ether, alginates, primary starch and converted starch and any above-mentioned polymer.Starches includes, but not limited to cornstarch, farina and wheaten starch, and derivatized starch and converted starch, includes but not limited to ethylated starch, oxidized starch, anionic starch and cationic starch.For example, can use ethylated starch, as from Grain Processing Corp., Muscatine, the K96F of IA, or the derivative cornstarch of hydroxyethyl ether, as from Penford Products Co., Cedar Rapids, the Penford of IA ?280 Gum(are 2-bydroxyethyl starch ether, Hydroxyethyl Starch or ethylated starch).
In some instances, the amount of the dry weight of this macromolecular material in aqueous mixture is about 25% to about 70%, or about 30% to about 60%, or about 30% to about 55%, or about 30% to about 50%, or about 30% to about 45%, or about 35% to about 60%, or about 40% to about 60%, or about 45% to about 60%, or about 50% to about 60%, or about 55% to about 75%, or about 30% to about 55%, or about 35% to about 55%, or about 40% to about 55%, or about 45% to about 55%.In some instances, the amount of the dry weight of this macromolecular material is about 33%, or about 41%, or about 45%, or about 54%, or about 72%.In some instances, the amount of this macromolecular material equals the amount of inorganic pigment in aqueous mixture substantially.In some instances, the amount of inorganic pigment is greater than the amount of macromolecular material in aqueous mixture.
This inorganic pigment can be the inorganic white filler of any kind.The example of available inorganic pigment includes, but not limited to alumina silicate, kaolin, calcium carbonate, silica, aluminium oxide, boehmite, mica and talcum and their combination or mixture.In some instances, this inorganic pigment comprises clay or clay mixture.In some instances, this inorganic pigment comprises calcium carbonate or calcium carbonate mixture.Calcium carbonate can be one or more in powdered whiting (GCC), winnofil (PCC), modification GCC and modification PCC for example.In addition, can use other combination of any inorganic pigment as herein described.For example, this inorganic pigment can comprise the mixture of calcium carbonate and clay.In another example, this inorganic pigment can comprise two kinds of different calcium carbonate (for example GCC and PCC).In an example, can use calcium carbonate, for example, from Omyajet AG Aktiengesellschaft, the OMYAJET of Switzerland ?c440 (GCC).In another example, can use calcium carbonate, for example, from Minerals Technologies, Inc., the ALBAGLOS of NY ?s(0.6 micron PCC).In another example, can use alumino-silicate clays, for example, from INEOS Silicas, Joliet, the ZEOCROS of IL ?pF/S.
In some instances, in the inorganic pigment material of this SP surface sizing composition and wet end papermaking, above-mentioned inner stuffing used is basic identical.When basic identical, can realize cost savings and/or lower manufacture complexity when the inorganic pigment of this SP surface sizing composition and inner stuffing.For example, use one of GCC and PCC or both as the inorganic pigment in SP surface sizing composition in size press and can be by the volume lever and similarly store and supply system provide lower price as the inner stuffing in paper making wet part.
The particle that this inorganic pigment comprises filler separately.The particle mean size of the inorganic pigment granules in this SP surface sizing composition is for example about 0.1 to about 3 microns.In some instances, particle mean size is about 0.5 to about 1.5 microns.In some instances, inorganic pigment granules has by particle size distribution index (I)---according to the fineness ratio of following formula---and the size distribution of expression:
I?=?(D85/D15) 1/2
Wherein D85 is that about 85% inorganic pigment granules is less than the particle mean size in micron (m) of this value dimensionally according to distribution curve, and wherein D15 is the particle mean size that about 15% inorganic pigment granules is less than this value dimensionally.For example, particle size distribution index (I) can be about 1 to about 10.In other examples, particle size distribution index (I) can be for about 1 to about 9, about 1 to about 8, or about 1 to about 7, or about 1 to about 6, or about 1 to about 5, or about 1 to about 4, or about 1.5 to about 4.
In some instances, the amount of the dry weight of inorganic pigment in aqueous mixture is about 8% to about 60%, or about 9% to about 60%, or about 10% to about 50%, or at least 16% to about 60%, or about 20% to about 60%, or about 25% to about 50%, or about 30% to about 50%, or about 35% to about 50%, or about 40% to about 50%, or about 45% to about 50%, or about 45% to about 60%.In some instances, the amount of the dry weight of inorganic pigment is about 9%, or about 27%, or about 41%, or about 45%, or about 49% dry weight.
In some instances, this inorganic pigment comprises multiple paint filler.For example, this inorganic pigment can comprise the first paint filler, as calcium carbonate, and is different from the second paint material of the first paint filler.For example, the second paint filler can be have microcellular structure or can in paper-making process, on the surface based on cellulosic paper, in solidification process, form any organic or inorganic pigment of microcellular structure.Especially, become image receiving layer or surface at the curing microcellular structure based on cellulosic paper." image receiving layer or surface " refers to the surface of print media that is applicable to receiving from for example digital printer printing ink.The representative example of paint filler (for example being conducive to this image receiving layer) comprises calcium carbonate, zeolite, silica, talcum, aluminium oxide, aluminum trihydrate (ATH), calcium silicates, kaolin, calcined clay and any these combination or mixture.
The first paint filler and the second paint filler can provide with the ratio of the extremely about 20:1 of about 3:1.For example, the first paint filler can provide with the amount of about 24% to about 36% dry weight, and the second paint filler can provide with the amount of about 8% to about 12% dry weight.In another example, the first paint filler can provide with the amount of about 25% to about 35% dry weight, and the second paint filler can provide with the amount of about 5% to about 7% dry weight.In another example, the amount confession that the first paint filler can be carried to about 40% dry weight with about 30%, the second paint filler can provide with the amount of about 3% to about 4% dry weight.In some instances, the first paint filler is that calcium carbonate material and the second paint filler are different calcium carbonate material or alumino-silicate clays materials.
In some instances, this inorganic metal salt is the multivalent metal salt that dissolves in the metal of the leading element periodic table the 2nd of aqueous mixture of pH about 7 to about 12 or 3 families.In some instances, can use metal halide salt, for example metal chloride or metal bromide.In other examples, can use metal nitrate.The limiting examples of this inorganic metal salt comprises calcium chloride (CaCl 2), magnesium chloride (MgCl 2), aluminium chloride, beryllium chloride, calcium nitrate, magnesium nitrate, aluminum nitrate and beryllium nitrate and their combination or mixture.
In some instances, the amount of the dry weight of inorganic metal salt in aqueous mixture is about 5% to about 20%, or about 6% to about 20%, or about 7% to about 20%, or about 8% to about 20%, or about 9% to about 20%, or about 9% to about 19%, or about 9% to about 15%, or about 10% to about 20%, or about 12% to about 20%, or about 15% to about 20%, or about 17% to about 20%, or about 18% to about 20%, or about 18% to about 19%, or about 9% to about 17%, or about 10% to about 15%.In some instances, the amount of the dry weight of inorganic metal salt is 9% to 9.5%, or 18% to 18.5%, or 18.5% to 19%, or 19% to 19.5%.In some instances, univalent metal salt can replace multivalent salts or mix use with multivalent salts.But at least when replacing multivalent salts to use, many amounts of take than the amount above provided as multivalent salts provide monovalent salt to realize similar print quality (below further describe print quality), because the efficiency of monovalent salt is lower than multivalent salts.The halide salts of monovalence metal that for example, can Application standard periodic table the 1st family.
The aqueous mixture of this surface sizing composition has about 7 to about 12 pH.In some instances, the pH of this aqueous mixture is for for example about 7.5 to about 12.5, or about 8 to about 11, or about 8.5 to about 11.5, or about 9 to about 10.5, or about 9.5 to about 12.5, or about 10 to about 12.In some instances, the pH of this aqueous mixture is about 8.5 to about 12, or about 9 to about 11, or about 9.5 to about 10.5, or about 10 to about 11.
The aqueous mixture of this surface sizing composition has about 10% solid content of the target to about 25% dry weight.In some instances, take the actual solid content of dry weight as about 11% to about 23%, or about 12% to about 22%.In some instances, actual solid content is 12% to 12.5%, or 13% to 14%, or 13.5% to 14%, or 22% to 22.5%.
In addition, the aqueous mixture of this surface sizing composition has the brookfield's viscometer of using, Brookfield Engineering Laboratories, and about 10 cP that MA at room temperature records with 100 rpm axle speed are to the viscosity of about 200 cP.In some instances, this viscosity is that about 15 cP are to about 190 cP, or about 20 cP are to about 180 cP, or about 25 cP are to about 170 cP, or about 30 cP are to about 160 cP, or about 35 cP are to about 170 cP, or about 40 cP are to about 160 cP, or about 45 cP are to about 150 cP, or about 50 cP are to about 140 cP, or about 55 cP are to about 130 cP, or about 60 cP are to about 120 cP.In some instances, this viscosity is less than or equal to about 100 cP, or less than or equal to about 75 cP, or less than or equal to about 50 cP, or at about 50 cP between about 100 cP.
In some instances, also other chemical functional additive can be added in this SP surface sizing composition.These chemicals include, but not limited to fluorescent whitening agent (OBA), surfactant, levelling agent, antimicrobial and polymeric dispersant.
Show the example according to the print media of principle as herein described with side view in Fig. 1.Print media (100) comprises based on cellulosic paper (110) with at size press (SP) Cypres (120) based on cellulosic paper (110).SP Cypres (120) is the above-mentioned SP surface sizing composition of substantially removing all water (dry on surface of print media) substantially, and it uses size presser to apply online in paper-making process, then dry.SP Cypres (120) in print media (100) has the dry weight to about 3.0 gsm at print media every about 1.0 g/ms (gsm).In some instances, the dry weight of SP Cypres (120) is less than about 3.0 gsm/ faces, for example is less than about 2.8 gsm/ faces.In some instances, the dry weight of SP Cypres (120) is that about 1.2 gsm are to about 3.0 gsm/ faces, or about 1.4 gsm are to about 2.8 gsm/ faces, about 1.5 gsm are to about 2.7 gsm/ faces, or 1.7 gsm to about 2.6 gsm/ faces, or about 1.8 gsm are to about 2.5 gsm/ faces, or about 2 gsm are to about 3 gsm/ faces, or about 1.5 gsm are to about 2.5 gsm/ faces, or about 1 gsm is to about 2 gsm/ faces.
There is Hercules Sizing Test (HST) value of about 1 second to about 50 seconds based on cellulosic paper web (110).In some instances, the HST value is about 1 second to about 25 seconds, or about 1 second to about 15 seconds.There is Hercules Sizing Test (HST) value that for example is less than about 20 seconds based on cellulosic paper (110).Lower HST value means the absorption that the SP surface sizing composition improves and is penetrated into based in cellulosic paper web.In addition, lower HST value mean that improved dry EP prints and the dye-based inkjet printing in low color and the bleeding between color.For example, comprise the print media based on cellulosic paper web (110) (100) with the HST value that is greater than about 20 seconds starts to show the visible paper of spreading and sinking in of general viewers (feathering) or bleeding effect along the border between color and color with ink print the time.For example, but, when based on cellulosic paper web (110), having the HST that is less than about 20 seconds,, spread and sink in paper or bleeding effect of such on print media (100) is that general viewers is sightless.
Show the example according to the digital printing system of principle as herein described with block diagram in Fig. 2.Digital printing system (200) is the Direct-type print system, and it comprises device (210) for depositing image forming material and for directly receive the print media (220) of image forming material from precipitation equipment (210).Term " image forming material " is intended to mean printing ink or toner in this article, and can only for the terseness of discussing, be called in this article " printing ink ".The print media (220) that receives printing ink is basic identical with above-mentioned print media (100).Direct-type digital printing system (200) does not comprise the simulation printing, and for example hectograph is printed---wherein ink deposition is on middle receiving surface, and then the intermediate list face is transferred on print media.In some instances, comprise ink-jet printer (210), dry EP printer (being laser printer) (210) or liquid EP(LEP for the device (210) that deposits image forming material) printer (210).
Comprise dye-based ink and pigment based ink from the image forming material of precipitation equipment (210) deposition, comprise the color of green grass or young crops (C), pinkish red (M), yellow (Y) and black (K) and so on, they accurately mix and produce other thousands of colors with a form.In some instances, pigment based ink comprises and can be coated with or be encapsulated in by organic polymer the granules of pigments in organic polymer.This organic polymer can improve bonding between pigment and print media (220).
The example that can be present in the organic pigment in printing ink comprises, but be not limited to, perylene, phthalocyanine color (phthalocyanine green for example, phthalocyanine blue), phthalocyanine pigments (Cy3, Cy5 and Cy7), the naphthalene phthalocyanine color, nitroso pigments, monoazo pigment, disazo pigment, disazo condensation pigment, basic-dyeable fibre pigment, alkali blue pigment, acid blue pigment, phloxin pigment, quinacridone pigment, Indian yellow 1 and 3 mordant pigment, isoindolinone pigment, triazine dioxin pigment, carbazole dioxazine violet look pigment, alizarine lake pigment, vat pigment, phthaloxyamine pigment, carmine lake pigment, tetrachloroisoindolinone pigment, purple cyclic ketones pigment, thioindigo color, the mixture of anthraquinone pigment and quinophthalone pigment and two or more above-mentioned pigment and the derivative of above-mentioned pigment.
The inorganic pigment that can be present in printing ink comprises, but be not limited to metal oxide (for example titanium dioxide, iron oxide (for example red ferric oxide, yellow ferric oxide, Black Rouge and transparent ferric oxide), aluminium oxide, silica), charcoal blacks (for example furnace black), metal sulfide, metal chloride and the mixture of two or more wherein.
Show with flow chart an example manufacturing the method for surface sizing composition according to principle as herein described in Fig. 3.The method (300) of manufacturing said composition comprises the macromolecular material of about 25% amount to about 75% dry weight and inorganic pigment and hydration and forms waterborne compositions (310).For example, this macromolecular material is placed in to blending tank, and the inorganic pigment that is greater than 15% amount to about 60% dry weight is added in this tank together with this macromolecular material.In some instances, at least 16% to about 50% inorganic pigment is added in this tank to about 55% macromolecular material with about 30%.Also add water.In some instances, this macromolecular material is starch.This starch can be precooked before in adding blending tank to.For example, about 25% starch to about 75% dry weight can continue about 30 minutes with the formation solution of precooking by being heated to about 90 ℃.The starch solution of then this being precooked adds in blending tank together with water with inorganic pigment.
The method (300) of manufacturing said composition further comprises mixes the very first time (320) by this waterborne compositions.For example, this waterborne compositions at room temperature mixes (320) very first time of about 15 minutes to about 45 minutes.In some instances, the very first time is about 20 minutes to about 40 minutes, or about 25 minutes to about 35 minutes.For example, the very first time can be about 30 minutes.
The method (300) of manufacturing said composition further be included in after the very first time inorganic metal salt is added (330) in this waterborne compositions to form mixture.For example, the inorganic metal salt of starching about 3% amount to about 20% dry weight when mixing or stirring this aqueous mixture adds (330) in this waterborne compositions.For example, the multivalent salts of about 9% to about 19% amount is added to (330) in this waterborne compositions.Method (300) further comprises mixed for (340) second times to form surface sizing composition by this mixture.For example, this mixture at room temperature mixes (340) second time of about 5 minutes to about 20 minutes.In some instances, the second time was about 10 minutes to about 20 minutes, or about 10 minutes to about 15 minutes.For example, the second time can be about 10 minutes.
In the process of mixing (340) this mixture, check in mixed process and regulate pH, solid content and the viscosity of this mixture until following one or more: for example, pH is 7 to about 12, and the target solid content is about 10% to about 25%, and viscosity is that about 10 cP are to about 200 cP.In some instances, the adjusting of pH comprises interpolation NaOH (NaOH) and checks pH.In some instances, the adjusting of the adjusting of solid content and viscosity comprises and for example adds water and/or improve incorporation time and/or combined power or speed.In some instances, mix (340) this mixture until the pH of this surface sizing composition, target solid content and viscosity all in described scope.
Show with flow chart an example manufacturing the method for figure punch medium according to principle as herein described in Fig. 4.The method (400) of manufacturing print media comprises uses size presser surface sizing composition to be added to (410) in online paper-making process in based on cellulosic paper web.Especially, the SP surface sizing composition add (410) in paper web this with paper technology and integration of equipments with synchronize.It is not independent or independent application step or after the cadre (dry-end section) of papermaking or use afterwards independent equipment part in the paper drying, such as coating machine etc., applies.
The method (400) of manufacturing the figure punch medium further comprises sized paper dry (420) formation print media.In some instances, the weight of Cypres on print media is to about 3.0 gsm at every about 1.5 g/ms (gsm) of dry paper.This water-based SP surface sizing composition with every about 15 gsm to the amount of about 30 gsm wet weights add (410) in paper web for example after will sized paper dry (420) forming print media, to realize that every about 1.5 gsm are to about 3.0 gsm dry weights.By paper making equipment, use the canonical parameter of this equipment to carry out drying (420).
Definition:
The definition of term used herein and phrase below is provided, and they are not differently definition in this article.
" wet end " of papermaking refers to the one-tenth wet end (web-forming section) of paper machine, at this, merges the slurry of fiber, filler and other additive and is shaped as wet continuous fibers net.
" cadre " of papermaking in this article refers to press section and the drying section of paper machine, after both being positioned at wet end.Press section comprises " size presser ", and wherein the continuous fibers net is passed between the size press roller under pressure with expressed water.Drying section comprises heated drying cylinder, and the continuous fibers net of applying glue is further dry through this.Cadre in papermaking applies Cypres by size presser.
Embodiment
Prepare various surface sizing composition samples and assess on print media.The aqueous mixture that each sample comprises macromolecular material, inorganic metal salt and inorganic pigment according to principle as herein described.The difference of sample is to use different quantity of material and/or different inorganic pigment materials.Table 1 is listed the surface sizing composition sample of making, their composition and amount and target solid content value and actual solid content value.Unless indicate separately, umber and percentages, unless and indicate separately, temperature is room temperature.
Sample: SP-1 SP-2 SP-3 SP-4 SP-5 DP-1 DP-2
Composition: ? ? ? ? ? ? ?
Penford ?280 starch 71.75 54.13 40.77 32.69 45.35 40.77 40.77
Calcium chloride 19.28 18.81 18.45 18.27 9.30 18.45 18.45
Albaglos ? S PCC 8.97 27.06 40.77 49.04 45.35 30.58 30.58
Zeocros ?The PF/S clay ? ? ? ? ? 10.19 ?
Omyajet ? C4440 GCC ? ? ? ? ? ? 10.19
Amount to (approximately) 100.0 100.0 100.0 100.0 100.0 100.0 100.0
Target solid content (%) 12.0 12.0 12.0 12.0 22.0 13.0 13.0
Actual solid content (%) 12.4 12.6 12.4 12.4 22.3 13.7 13.8
Table 1: the top sizing sample of making.The composition of sample is listed in row, and their amount is listed in row.All amounts are (%) dry weight percentage.
Prepare the top sizing sample according to an example of the method (300) of above-mentioned manufacture surface sizing composition.Each sample in special his-and-hers watches 1, the macromolecular material of the amount that each sample in his-and-hers watches 1 is pointed out, for example Penford ?280 starch are precooked, and this starch solution is added in blending tank.The inorganic pigment of respectively estimating one's own ability in table 1 (slurry or powder type) merges and adds water with this precooked starch solution in tank.This waterborne compositions is mixed the very first time of about 30 minutes.Then add the Hydrite Chemicals respectively estimated one's own ability in table 1 in tank, Brookfield, the calcium chloride (CaCl of Wisconsin supply 2) inorganic metal salt, and mix second time of about 10 minutes with this waterborne compositions to form surface sizing composition.
Use is manufactured an example of the method (400) of figure punch medium and is manufactured the print media sample by the top sizing sample in table 1 according to principle as herein described.Specimen in various print quality tests and printer endurancing, and all carry out finely and basic identical.For example, the top sizing sample is applied to separately separately have the low HST that is less than or equal to about 5 seconds based on cellulosic paper to manufacture the print media sample.Should comprise from Glatfelter based on cellulosic paper web York, the bleached hardwood chemistry kraft pulp of PA.From Metso Corp., the metering size press machine Model Optisizer of Finland is for being applied to base paper medium by the top sizing sample.Dry sized paper in drying section immediately after size press.Drying section comprises air robot, then infrared (IR) drier, then drier hot-air tunnel drying.About 15 amounts to about 30 gsm wet weights apply composition be enough to provide on based on cellulosic paper every about 1.5 gsm to the amount of about 3.0 gsm weight to form the print media sample.Grouping regulation print media sample in table 2.For example, be the terseness of discussing, the data of the print media sample of being made by each SP-1, SP-2, SP-3 and SP-4 glueing composition are classified as EXP-1 together with result.Data and the result of print media sample SP-5 are decided to be EXP-2, and data and the result of print media sample DP-1 and DP-2 are decided to be EXP-3.
Comparative sample also is provided.Table 2 is further listed in for four kinds of comparative sample types with this print media sample comparison.The carrying capacity of each Cypres composition is indicated with the kilogram number/metric ton paper (kg/T) of composition, and what this represented that the pattern product obtain (or carrying) respectively becomes component.Use the salt ion measuring amount of ion chromatography (standard method) in said composition by ingredient standard.Comparative sample CP-1 represents commercially available paper medium, (the Staples for example in the office appliance shop for example, CA) available office printing paper, it is characterized in that comparing with the print media sample there is high macromolecular material content in its Cypres, without inorganic pigment and high inorganic salt content.Comparative sample CP-4 also represents commercially available paper medium, and also (for example Staples, CA) available office printing paper in the office appliance shop is characterized in that having high macromolecular material content in its Cypres, without inorganic pigment with without salt content.Comparative sample CP-4 serves as the control sample (" tester ") of carried out test.With the similar mode of print media sample, to prepare comparative sample CP-2 and CP-3.Sizing agent on comparative sample CP-2 with the print media sample, compare there is high macromolecular material content (starch) in its Cypres, low inorganic pigment content and high content of salt.Sizing agent on comparative sample CP-3 is compared with the print media sample has medium macromolecular material content (starch), high inorganic pigment content and high content of salt in its Cypres.The various compositions of comparative sample CP-2 and CP-3 representative Cypres as a comparison higher than threshold value with lower than the threshold value sample.
Figure 377438DEST_PATH_IMAGE002
Table 2: the print media sample of making and comparative sample and their composition separately.All amounts are the carrying capacity on paper by the kilogram number/metric ton paper of composition.
In various tests test printing dielectric sample EXP-1, EXP-2 and EXP-3 and with table 2 in comparative sample CP-1, CP-2, CP-3 and CP-4 relatively with assessment print quality performance.For example, carry out high temperature/high humidity (H/H) EP print quality (PQ) stress test at about 30 ℃ with about 80% relative humidity.This PQ stress test is exposed under relatively violent or extreme environmental conditions the print media sample in the color laser printing process.This EP print quality stress test is used from Hewlett-Packard Co., Palo Alto, and the HP color laser printer Models CP4525 of CA and CP5220 assessment toner (toner) shift defect.Missing point on the print media sample that uses visual reference evaluation EP print quality to be caused by toner transfer defect with inspection and the print area of comparative sample.Grade comprises A=zero defect; B=light defects; The apparent defect of C=consumer; D=major defect; And E=critical defect.
It (is the terseness of discussing that table 3 is summarized the print media sample, in table 3, return together, because their performances are basic identical) and comparative sample CP-1 and CP-4(representative have business paper and tester now) the print quality result of EP print quality stress test under high temperature/high humidity (H/H).
Media type Defects of vision grade The EP printer
Comparative sample, CP-1 E HP CP4525
The print media sample B HP CP4525
Comparative sample, CP-4 B HP CP4525
? ? ?
Comparative sample, CP-1 E HP CP5220
The print media sample C HP CP5220
Comparative sample, CP-4 C HP CP5220
Table 3: the summary of the laser printing quality stress test under 30 ℃ and 80%RH.Defects of vision grade: A=zero defect; B=light defects; The apparent defect of C=consumer; D=major defect; And E=critical defect.
Especially, the print media sample reveals comparison than sample CP-1 and comparative sample CP-4(tester for the colored EP type list under the H/H condition) excellent PQ.Sample CP-1 and CP-4 represent the existing paper on market.Be not intended to be confined to this reason, but comparative sample CP-1 seems the impact of the high content of salt of performance in paper delivery on laser printing, this it is believed that the electrical property that affects paper and the therefore transfer of toner, cause with do not have salt content contrast comparative sample CP-4 compare use HP CP4525 and HP CP5220 printer shift defect than colorant.In addition, although there is salt (about salt content, in Table 1 and 2) in the print media sample, the print media sample shows the performance with control sample CP-4 par.Following table 4 is also summarized the EP print quality stress test result of all comparative sample and print media sample with relational language, and the summary that following additional testing is provided.
In another example, in comparative sample and the enterprising enforcement of print media sample of table 2, with the print quality of ink-jet printer, test.Use laboratory stand ink-jet printer (TIJ) use TAPPI environmental condition printing color pigment ink on the pattern product under 23 ℃ and 50% relative humidity.Tamp the pattern in zone (solid fill areas) with the different colours ink print with the bleeding between the frontier district between assessment gamut volume, print density and color and color.The result of ink-jet PQ is provided with relational language in table 4." the best " grade refers to that substantially, without visual defects, " well " grade refers to slight visual defects, and " generally " grade refers to the visual defects of acceptable degree, and " poor " grade refers to the visual defects of unacceptable degree.With respect to the poor inkjet printing quality on the control sample CP-4 that there is no salt content, comparative sample CP-1, the CP-2 and the inkjet printing quality on CP-3 that have separately high content of salt are good.In contrast to this, compare the print media sample with intermediate salt content with comparative sample and there is best inkjet printing quality.Each print media sample performance is basic identical, is also therefore the terseness of discussing, and these samples are reported as single group in table 4.Be not intended to be confined to this reason, but this print quality performance it is believed that owing to for example comparing with comparative sample, salt medium in the print media sample exists.In addition, with respect to contrast comparative sample CP-4, the print media sample shows better inkjet printing quality and essentially identical EP print quality (stress test result).
In another example, the dusting (dusting) of assessment sample exists.For example, print each sample of about 50,000 and monitor by visualization the dust accumulated in laser printer after printing each sample with laser printer.Table 4 is summarized the result of dusting assessment.Only have inorganic pigment content and salt content all relatively high comparative sample CP-3 there is the dusting problem, this may affect for example printer capability.
Figure 294578DEST_PATH_IMAGE004
Table 4: for the comparative sample from table 2 and print media sample, the summary of using inkjet printing vs to use print quality (PQ) result, black (K) optical density (KOD) and the dusting of EP printing to exist.
In another example, carrying out black (K) optical density (KOD) on print media sample and comparative sample measures.KOD measures the black optical density of pigment ink on each print media while using the TIJ printer.By X-rite, Green Rapids, the spectrodensitometer Model 938 of MI supply measures KOD.The ANSI state A that is set to used, comparative result is with the mean value report of three measurements.The KOD measurement shows, the low macromolecular material carrying capacity in sample draws higher KOD measured value (about the starch carrying capacity, in Table 2).The KOD result also shows, with comparative sample CP-1, CP-2, CP-3 and CP-4, compares, and as shown in the black optical density by higher (KOD), print media sample (as a group) has better print quality when using the colored ink inkjet printing.Gamut volume and color saturation all estimate to follow the KOD result.
In another example, carry out the test of laser runnability relatively for dry EP, to print the carrying capacity level of the filler (being inorganic pigment) of the comparative sample of purposes and print media sample.For example, each print media sample operation of about 50,000 pages is by HP Model CP3525 laser printer.Fixing roller (fuser roll) to the CP3525 printer is not observed too early damage, to printing dielectric sample, does not observe runnability problems, includes but not limited to paperboard.They are the commercially available paper on market for this runnability result of print media sample and the comparative sample CP-1 of 50,000 pages and CP-4(, and for example operation is by identical laser printer) quite.
The robustness of many examples of the SP glueing composition of the principle of substantially equal performance identity basis this paper and print media between the print media sample in above-mentioned various tests.With the commercially available paper on market, compare, the inorganic pigment in this SP surface sizing composition is one of tip heigh material in the Cypres in the Partial Replacement size press likely, i.e. macromolecular material.In addition, reduce the inorganic metal salt content and also can reduce the cost of raw material when still keeping above-mentioned print quality level, reduce the dangerous print quality with improving in the dry EP of H/H of corrosion.Too much salt may cause in plain boiled water than highly corrosive, but for example this also life expectancy or service time of negative effect paper making equipment.Salt is moisture absorption likely, so the excess moisture that absorbs of salt also may cause the remarkable change of the electrical property of paper, and therefore as provided shown in result, the toner that may affect in print procedure shifts.As print media sample herein further confirms, because salt reduces, can significantly improve the dry EP print quality under the H/H condition.
Therefore, describe surface sizing composition, comprised the print media of this surface sizing composition and comprised the various examples of the digital printing system of this print media.The various examples of manufacturing the method for said composition and this print media have also been described.It should be understood that above-described embodiment only illustration represent the part in many specific embodiments of principle as herein described.Clearly, those skilled in the art easily design many other layouts of the scope that does not deviate from the various embodiment that stipulate as following claim.

Claims (15)

1. surface sizing composition, it comprises:
Aqueous mixture, the macromolecular material that it comprises about 25% amount to about 75% dry weight; The inorganic metal salt of about 3% amount to about 20% dry weight; The inorganic pigment of at least 16% amount to about 60% dry weight, so that the gross dry weight amount equals about 100%, described aqueous mixture is size press (SP) surface sizing composition.
2. the surface sizing composition of claim 1, the amount of wherein said macromolecular material is about 30% to about 55 % by weight, the amount of described inorganic metal salt is that about 9% amount to about 19 % by weight and described inorganic pigment is about 25% to about 50 % by weight.
3. the surface sizing composition of claim 1, the amount of wherein said macromolecular material is about 40% to about 45 % by weight, the amount of described inorganic metal salt is that about 9% amount to about 19 % by weight and described inorganic pigment is about 40% to about 50 % by weight.
4. the surface sizing composition of claim 1, the amount of wherein said macromolecular material equals the amount of described inorganic pigment substantially, and the amount of described inorganic metal salt is about 9% to about 18.5 % by weight.
5. the surface sizing composition of claim 1, the amount of wherein said macromolecular material is less than the amount of described inorganic pigment, and the amount of described inorganic metal salt is about 9% to about 19 % by weight.
6. the surface sizing composition of claim 1, wherein said inorganic pigment comprises multiple paint filler, the first paint filler is calcium carbonate, and the second paint filler is one of different calcium carbonate and clay, and the ratio of the first paint filler and the second paint filler is about 3:1 to about 20:1.
7. the surface sizing composition of claim 1, wherein said inorganic pigment has about 1 to about 10 particle size distribution index and the particle mean size of about 0.1 micron to about 3 microns.
8. the surface sizing composition of claim 1, wherein said aqueous mixture has about 12% solid content to about 22% dry weight, and about 8 to about 11 pH and about 10 centipoises (cP) are to the viscosity of about 200 cP.
9. the surface sizing composition of claim 1, wherein said macromolecular material is selected from ethylated starch, anionic starch and cationic starch, and wherein said inorganic metal salt is selected from the halide of the metal of leading element periodic table the 2nd or 3 families, and wherein said inorganic pigment is selected from one or more in clay, calcium carbonate and aluminum silicate clay.
10. manufacture the method (300) of the surface sizing composition of claim 1, described method comprises:
The inorganic pigment of merging (310) macromolecular material, described amount and water are to form waterborne compositions;
Described waterborne compositions is mixed to the very first time (320);
After the very first time, the inorganic metal salt of described amount is added (330) in described waterborne compositions to form mixture; With
Described mixture is mixed to (340) second times and with formation, have following one or more surface sizing composition: about pH of 7 to 12, about 10% to about 25% target solid content and about 10 centipoises (cP) are to the viscosity of about 200 cP.
11. play the print media (100) of seal for digital direct, described print media (100) comprises based on cellulosic paper (110) with at described size press (SP) Cypres (120) based on cellulosic paper, and described SP Cypres (120) comprises:
Macromolecular material;
Substantially be equal to or greater than the inorganic pigment of the amount of described macromolecular material amount; With
The inorganic metal salt of about 3% amount to about 20% dry weight, so that the gross dry weight amount equals about 100%,
Wherein the weight of SP Cypres (120) in print media (100) is that every about 1.5 g/ms (gsm) are to about 3 gsm.
12. claim 11 play the print media (100) of seal for digital direct, wherein saidly based on cellulosic paper (110), comprise hard wood pulp and inner stuffing and/or internal sizing, described have Hercules Sizing Test (HST) value that is less than about 20 seconds based on cellulosic paper (110).
13. manufacture the method (400) of the print media (100) of claim 11, described method comprises:
Use the online size presser of paper making equipment in paper-making process, the SP Cypres is added (410) to described based in cellulosic paper; With
Dry (420) described SP size press coated paper in the drying section of paper making equipment.
14. digital printing system (200), it comprises:
For depositing the digital printer (210) of image forming material; With
For directly receive print media (220), (100) of image forming material from digital printer (210), described print media (220), (100) comprise size press (SP) Cypres (120) on based on cellulosic paper (110), and described SP Cypres comprises:
The macromolecular material of the amount of about 25% to 75% dry weight;
The inorganic metal salt of about 3% amount to about 20% dry weight; With
The inorganic pigment of at least 16% amount to about 60% dry weight, so that the gross dry weight amount equals about 100%,
Wherein the weight of SP Cypres (120) in print media (220), (100) is that described every about 1.5 g/ms (gsm) based on cellulosic paper are to about 3 gsm.
15. the digital printing system of claim 14 (200), wherein digital printer (210) is ink-jet printer or laser printer.
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