CN103165224A - Copper plastic composite strap suitable for telecommunication cable and optical cable and preparation method of copper plastic composite strap - Google Patents
Copper plastic composite strap suitable for telecommunication cable and optical cable and preparation method of copper plastic composite strap Download PDFInfo
- Publication number
- CN103165224A CN103165224A CN2011104081911A CN201110408191A CN103165224A CN 103165224 A CN103165224 A CN 103165224A CN 2011104081911 A CN2011104081911 A CN 2011104081911A CN 201110408191 A CN201110408191 A CN 201110408191A CN 103165224 A CN103165224 A CN 103165224A
- Authority
- CN
- China
- Prior art keywords
- copper
- rolling
- compound
- plastics band
- plastic film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 148
- 239000010949 copper Substances 0.000 title claims abstract description 148
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 148
- 229920003023 plastic Polymers 0.000 title claims abstract description 81
- 239000004033 plastic Substances 0.000 title claims abstract description 81
- 239000002131 composite material Substances 0.000 title claims abstract description 33
- 230000003287 optical effect Effects 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000010410 layer Substances 0.000 claims abstract description 42
- 229920006267 polyester film Polymers 0.000 claims abstract description 34
- 238000010438 heat treatment Methods 0.000 claims abstract description 32
- 239000012790 adhesive layer Substances 0.000 claims abstract description 11
- 239000002985 plastic film Substances 0.000 claims description 97
- 229920006255 plastic film Polymers 0.000 claims description 97
- 150000001875 compounds Chemical class 0.000 claims description 77
- 238000005096 rolling process Methods 0.000 claims description 72
- 229920000877 Melamine resin Polymers 0.000 claims description 33
- 239000000853 adhesive Substances 0.000 claims description 29
- 230000001070 adhesive effect Effects 0.000 claims description 29
- 238000002485 combustion reaction Methods 0.000 claims description 25
- 239000004640 Melamine resin Substances 0.000 claims description 21
- 239000006247 magnetic powder Substances 0.000 claims description 18
- 238000000137 annealing Methods 0.000 claims description 14
- 238000013329 compounding Methods 0.000 claims description 14
- 229920002635 polyurethane Polymers 0.000 claims description 13
- 239000004814 polyurethane Substances 0.000 claims description 13
- 229920000728 polyester Polymers 0.000 claims description 12
- 229920006395 saturated elastomer Polymers 0.000 claims description 11
- 229920001897 terpolymer Polymers 0.000 claims description 11
- 239000003822 epoxy resin Substances 0.000 claims description 9
- 229920000647 polyepoxide Polymers 0.000 claims description 9
- 229920005989 resin Polymers 0.000 claims description 9
- 239000011347 resin Substances 0.000 claims description 9
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical group CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 7
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 5
- 229920001577 copolymer Polymers 0.000 claims description 5
- 238000005097 cold rolling Methods 0.000 claims description 4
- 238000010276 construction Methods 0.000 claims description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 2
- 238000007605 air drying Methods 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 claims description 2
- 238000000576 coating method Methods 0.000 claims description 2
- 230000015556 catabolic process Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 description 23
- 238000001816 cooling Methods 0.000 description 21
- 230000000694 effects Effects 0.000 description 19
- 238000004026 adhesive bonding Methods 0.000 description 14
- 238000004519 manufacturing process Methods 0.000 description 14
- 239000003292 glue Substances 0.000 description 9
- 230000007797 corrosion Effects 0.000 description 7
- 238000005260 corrosion Methods 0.000 description 7
- 239000000126 substance Substances 0.000 description 6
- 229920001038 ethylene copolymer Polymers 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 241000209094 Oryza Species 0.000 description 4
- 235000007164 Oryza sativa Nutrition 0.000 description 4
- 238000007664 blowing Methods 0.000 description 4
- 230000002950 deficient Effects 0.000 description 4
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 4
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- -1 polyethylene Polymers 0.000 description 4
- 238000010926 purge Methods 0.000 description 4
- 235000009566 rice Nutrition 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000007689 inspection Methods 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 238000011179 visual inspection Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 230000037303 wrinkles Effects 0.000 description 3
- 229920001617 Vinyon Polymers 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000012809 cooling fluid Substances 0.000 description 1
- 239000000110 cooling liquid Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
Images
Landscapes
- Laminated Bodies (AREA)
Abstract
The invention relates to the field of cable straps, in particular to a copper plastic composite strap suitable for a telecommunication cable and an optical cable and a copper plastic composite strap preparation method. The copper plastic composite strap is wrapped on the outer surface of the telecommunication cable or the optical cable. The copper plastic composite strap is provided with a red copper layer (1), an adhesive layer (2) and a polyester film layer (3) in sequence. The red copper layer (1), the adhesive layer (2) and the polyester film layer (3) are attached together through bonding and heating to form a composite structure. The tensile strength of the copper plastic composite strap is larger than or equal to 180 MPa. The breakage elongation of the copper plastic composite strap is larger than or equal to 15%. The interlaminar peeling strength between a copper strap and a plastic layer is larger than or equal to 15N/centimeter. The conductivity of the copper plastic composite strap is larger than or equal to 90% of international annealed copper standard (IACS). The breakdown phenomenon does not happen to the single-sided copper plastic composite strap 1kvd.c in one minute.
Description
Technical field
The present invention relates to the banded cable field, be specially a kind of compound copper-plastics band and preparation thereof that is applicable to telecommunication cable and optical cable.
Background technology
Compound copper-plastics band is the substitute products that cable is used pure copper strips, is one of important kind in modern copper processing material, and the application on telecommunication cable, Communication ray cable industry continues to increase.At present, the production standard of compound copper-plastics band is generally with reference to YD/T 723.4-2007, namely take pure copper strips as base material, thickness is more than 0.1mm, plastic film adopts ethylene copolymer or sealed polyethylene plastic, thickness more than 0.05mm, the tensile strength 〉=15MPa of plastic film.With the further attenuate of pure copper strips base material, and then the compound copper-plastics band gross thickness is reduced, can further reach the saving copper resource, the purpose that reduces costs.Yet after the copper strips attenuate, intensity descends, and adopts ethylene copolymer or sealed polyethylene plastic to be difficult to satisfy the bulk strength requirement of compound copper-plastics band.In addition, due to factors such as bending, scratches, plastic layer often occuring damage phenomenon in practical operation, requires plastic layer to have resistance to wear, folding resistance and tear-proof type etc.Therefore polyethylene and ethylene copolymer can not satisfy actual needs fully.And biaxially oriented polyester film has that intensity is high, good rigidly, outstanding obdurability, and its tensile strength is 10 times of low density polyethylene (LDPE); The characteristics such as fabulous resistance to wear, folding resistance, pinhole resistance and tear resistance are arranged; Simultaneously, it also possesses odorless, tasteless, colourless, nontoxic, heat-shrinkable is minimum, have good antistatic behaviour, insulating properties, good thermal endurance, low temperature resistant freezing property, good oil resistance and chemical-resistant, it belongs to polar macromolecule material and is combined closely etc. with adhesive, can satisfy ultra-thin compound copper-plastics band requirement.
Summary of the invention
The object of the present invention is to provide a kind of compound copper-plastics band and preparation thereof that is applicable to telecommunication cable and optical cable.
For achieving the above object, the technical solution used in the present invention is:
A kind of compound copper-plastics band that is applicable to telecommunication cable and optical cable, compound copper-plastics band is coated on telecommunication cable or optical cable outer surface, compound copper-plastics band is provided with red copper layer 1, adhesive layer 2 and laminated polyester film 3 successively, and red copper layer 1, adhesive layer 2 and laminated polyester film 3 form composite construction by the bonding thermal-adhering that adds.
Described adhesive layer is that resin and p-methyl benzenesulfonic acid form, described resin is by mass fraction, ethylene-methyl methacrylate methyl terpolymer 18-22%, saturated polyester 29-35%, epoxy resin 29-35%, melamine resin 4-8%, polyurethane 8-12%, the addition of p-methyl benzenesulfonic acid is resin gross mass 0.5-0.7%.In described ethylene-methyl methacrylate methyl terpolymer, the addition of methyl methacrylate is the 15-30% of copolymer total weight.
Described saturated polyester is Vyl on560,335,345,301B, 385 saturated polyesters, and its saturated polyester 335,345,301B, 385 are available from Hualun Chemical Co., Ltd., Jiangsu; Vylon560 is available from spinning (TOYOBO) in Japanese Japan; Epoxy resin 6101,634 is available from Shenyang City's applied chemistry study institute; Melamine resin is available from green source, Jiashan chemical industry Co., Ltd melamine (melamine resin refers to melamine resin also referred to as melamine formaldehyde molding compound, is called for short " MF " melamine formaldehyde resin, claims again melamine resin); Polyurethane polyurethane tpu is available from Bayer A.G (Bayer).
Be applicable to the preparation method of the compound copper-plastics band of telecommunication cable and optical cable:
1) will by the rolling one-tenth thickness of 4-roller cold rolling mill be the ultra-thin red copper layer of 0.02-0.03mm through 60-80 ℃ of preheating, stand-by;
2) adhesive is coated on laminated polyester film, and by 50-70 ℃ of preheating, stand-by;
3) with step 1) red copper layer and step 2) the laminated polyester film of coating adhesive heat under 80-120 ℃ compound, composite pressure is 50-100N.
Described step 1) adopt diameter 50-80mm working roll, the simons mill of the backing roll of diameter 260-300mm is rolling.
Described ultra-thin red copper layer is according to following preparation:
1) preform is rolling: selecting thickness is the T2 copper strips of 0.12-0.10mm, is rolling to the preform that thickness is 0.08-0.06mm, mill speed 0.1-1.5m/s;
2) softening: preform softens, and softening temperature is 600-900 ℃, and softening rate is 5-30m/min;
3) finished product is rolling: above-mentioned softening rear preform is adopted diameter 50-90mm working roll, and the hollow water-cooled simons mill of the backing roll of diameter 260-300mm is rolling;
4) softening: the finished product copper strips after rolling enters continuous annealing and softens, and softening temperature is 600-900 ℃, and softening rate is 5-30m/min.
Described step 2) with the magnetic powder brake biaxial tension of polyester film with torque 500NM, obtain the high-flatness polyester film, then adhesive evenly is coated on plastic film, the adhesive THICKNESS CONTROL is at 10-30 μ m; The polyester film that scribbles adhesive is carried out preheating in 50-70 ℃, heated-air drying, stand-by.
Described step 3) described red copper layer is carried out uncoiling with torque 500NM and then be heated to 80-120 ℃, and the polyester film that will apply adhesive is compound through the compounding machine heating, combined temp is 80-120 ℃, composite pressure is 50-100N, at last will be through the compound copper-plastics band after-combustion rolling of composite rolling, after-combustion speed 20-50m/min, compound copper-plastics band tension force is controlled at 3.5-5.5N.
Advantage of the present invention and beneficial effect are:
1, compound copper-plastics band of the present invention, have superthin structure, saved the copper material of a large amount of preciousnesses, reduced production cost.Make product instead of pure copper cable mask tape to a certain extent.
2, compound copper-plastics band employing biaxially oriented polyester film of the present invention and copper strips are compound, with reference to GB/T16958-2008, polyester film hot strength 〉=150MPa substantially exceeds the intensity of general ethylene copolymer or vinyon layer, has guaranteed the bulk strength of compound copper-plastics band after the copper strips attenuate.Because biaxially oriented polyester film has good resistance to wear, folding resistance and tear resistance etc., can improve the application property of product.
3, compound copper-plastics band of the present invention has improved the adhesive formula, at the more ripe fabulous electrical property that has, the flexing performance need not to increase in polyesters glue that rear curing processes and has the peel strength that the ethylene-methyl methacrylate methyl terpolymer component of metal adhesive has preferably further improved compound copper-plastics band.
4. product quality is high.In preparation process of the present invention, the little working roll of employing footpath, be conducive to the copper strips attenuate, reduces roll-force, and the low roll shape of roller temperature is controlled well, and the copper strips banding pattern that shuts out is smooth, size uniform; Improved but technique of traditional cooling liquid cooling, adopt hollow water-cooled roll to be rolled cooling, discharge end adds air cooling system and strengthens coolingly, has guaranteed that simultaneously the copper strip surface cleaning is dry, has avoided copper strips in the subsequent anneal process to cause the phenomenons such as variable color, corrosion because of impurity, the spot of remained on surface.
5. compound copper-plastics band tensile strength 〉=180MPa of the present invention; Elongation at break: 〉=15%; Copper strips and plastics interlaminar strength 〉=15N/cm; Conductance: 〉=90%IACS; Single-side copper-plastic compound belt 1kvd.c, punch-through does not occur in 1min.
Description of drawings
The compound copper-plastics band structural representation that Fig. 1 provides for the embodiment of the present invention; Wherein, 1. red copper layer, 2. adhesive layer, 3. laminated polyester film.
The process equipment arrangement figure of the production red copper layer that Fig. 2 provides for the embodiment of the present invention.Wherein, 1, unwinding device; 2, pinch roll I; 3, upper backup roll; 4, top working roll; 5, bottom working roll; 6, lower backing roll; 7, rear cooling device; 8, pinch roll II; 9, high-speed and continuous annealing unit; 10, jockey pulley; 11, wrap-up.
The process equipment arrangement figure of the production of copper plastic composite strip that Fig. 3 provides for the embodiment of the present invention.Wherein, 1, copper strips unwinding device; 2, lower centring roll; 3, photoelectric detector; 4, copper base band heating plate; 5, compounding machine; 6, jockey pulley; 7, wrap-up; 8, upper centring roll; 9, jockey pulley; 10, plastic film unwinding device; 11, pinch roll; 12, plastic film flattens unit; 13, automatic glue spreaders; 14, jockey pulley; 15, guide roller; 16, plastic film Heating air box.
Fig. 4 is the production technological process of compound copper-plastics band.
Embodiment
Below in conjunction with accompanying drawing, structure of the present invention is described further.
As shown in Figure 1, compound copper-plastics band of the present invention is the composite construction of red copper layer 1 and biaxially oriented laminated polyester film 3, and red copper layer 1 and laminated polyester film 3 are composited by adhesive layer 2 bonding heating.
In the present invention, red copper layer 1 is for to obtain by cold rolling, and the gross thickness of compound copper-plastics band is 0.0295～0.64mm, wherein, the thickness of red copper layer 1 is 0.02～0.2mm, and the thickness of biaxially oriented laminated polyester film 3 is 0.008～0.036mm, and adhesive layer 2 THICKNESS CONTROL are 0.0015～0.08mm.
In the present invention, T2 copper → chemical analysis → founding → first is cold rolling → in roll → form copper base band preform, its thickness is 0.12-0.10mm.After passing through again the production of ultra-thin red copper layer and compound copper-plastics band, cut, test package warehouse-in.
As shown in Figure 2, the process equipment that the present invention produces ultra-thin red copper layer mainly comprises: unwinding device, pinch roll I, upper backup roll, top working roll, bottom working roll, lower backing roll, rear cooling device, pinch roll II, high-speed and continuous annealing unit, jockey pulley, wrap-up.
Its arrangement is as follows:
Four-high mill is by upper backup roll 3, top working roll 4, and bottom working roll 5, lower backing roll 6 forms, the four-high mill feed end is arranged unwinding device 1, pinch roll I2, discharge end cloth postpone cooling device 7, pinch roll II 8, high-speed and continuous annealing unit 9, jockey pulley 10, wrap-up 11;
In this technology arrangement, top working roll 4, bottom working roll 5 is the water-cooled hollow roll, implements cooling when acting on the attenuate copper strips; Upper backup roll 3, the effect of lower backing roll 6 are to be top working roll 4, and bottom working roll 5 provides support power; The effect of unwinding device 1 is to make the copper strips uncoiling, guarantees stable unreeling; The effect of pinch roll I2 is to pinch copper strips, guarantees that copper strips has stable tension force; The effect of rear cooling device 7 is that copper strip surface is purged, and guarantees the copper strip surface cleaning when reinforcement is cooling; The effect of pinch roll II8 is to pinch copper strips to enter annealing furnace, controls copper strips tension force; The effect of high-speed and continuous annealing unit 9 is the copper strips after rolling to be carried out high temperature continuous annealing remove the copper strips internal stress; The effect of jockey pulley 10 is to control copper strips tension force, makes its stable rolling; The effect of wrap-up 11 is with the Ultrathin copper strip harvest roll coil of strip.
The technological process of production of ultra-thin red copper layer:
Preform (thickness 0.12-0.10mm) is rolling → and softening (360 ℃) → finished product (thickness 0.02-0.03mm) is rolling → softening → after-combustion rolling → check, wherein:
Preform is rolling:
Selecting thickness is the T2 copper strips of 0.12-0.10mm, is rolling to the preform that thickness is 0.08-0.06mm.
Softening:
Preform softens by continuously online annealing device, and softening temperature is 600-900 ℃, and softening rate is 5-30m/min.
Finished product is rolling:
Preform is through work roll diameter 50-90mm, and the little four-high mill of backing roll diameter 260-300mm is rolling to the finished product that thickness is 0.02-0.03mm.Working roll adopts hollow water-cooled roll, and is directly cooling to copper strips and increased air cooling system at discharge end and strengthen coolingly by working roll, purges simultaneously copper strips and the copper strip surface free from admixture adhered to keep clean.
4) softening:
Finished product copper strips after rolling enters in continuous annealer and softens, and softening temperature is 600-900 ℃, and softening rate is 5-30m/min.
5) after-combustion rolling:
After-combustion rolling after finished product is softening is tested during after-combustion, if any defective, should record rolling rice number and carry out mark.
Check:
According to GB/T11091-2005, the band presentation quality is checked; Check thickness of strip with micrometer, thickness range 0.02-0.03mm, permissible variation ± 0.0005mm.
Selection work roller diameter 50-90mm, the simons mill of backing roll diameter 260-300mm, this operation roll of mill footpath is little, mill stiffness is large, easy copper strips attenuate is arranged, the rolling machine system DC control, the operation of rolling is stable, can realize the quality requirement of the required ultra-thin copper base band of compound copper-plastics band, Ultrathin copper strip rolling thickness: be rolled to 0.02-0.03mm from 0.06-0.08mm.Improved traditional cooling fluid process for cooling in the operation of rolling, use hollow water-cooled roll cooling, having increased air cooling system at discharge end strengthens cooling, make simultaneously copper strip surface cleaning, impurity, the dirt of having avoided adhering to because of copper strip surface in subsequent anneal technique makes the quality reduction such as copper strips generation variable color etc.
As shown in Figure 3, the present invention's process equipment of producing ultra-thin compound copper-plastics band mainly comprises:
Copper strips unwinding device 1, lower centring roll 2, photoelectric detector 3, copper base band heating plate 4, compounding machine 5, jockey pulley 6, wrap-up 7, upper centring roll 8, jockey pulley 9, plastic film unwinding device 10, pinch roll 11, plastic film flattens unit 12, automatic glue spreaders 13, jockey pulley 14, guide roller 15, plastic film Heating air box 16.
Its arrangement is as follows:
Feed end at compounding machine 5 is arranged copper strips unwinding device 1, lower centring roll 2, photoelectric detector 3, copper base band heating plate 4, upper centring roll 8; Discharge end is arranged jockey pulley 6, wrap-up 7, and jockey pulley I9, plastic film unwinding device 10, pinch roll 11, plastic film flattens unit 12, automatic glue spreaders 13, jockey pulley II14, guide roller 15, plastic film Heating air box 16 are arranged in the top.
In this technology arrangement, unwinding device 1, the effect of plastic film unwinding device 10 is 1 pair of copper strips uncoiling of unwinding device, 10 pairs of plastic film uncoilings of unwinding device.Lower centring roll 2, the effect of upper centring roll 8 are centering copper strips and plastic film position, make not sideslip of copper strips and plastic film.The effect of photoelectric detector 3 is the centering situations that detect copper strips and plastic film.Jockey pulley 6, the effect of wrap-up 7 are that jockey pulley 6 is stablized composite band tension force, guarantee the steady rolling of wrap-up 7.The effect of jockey pulley I9 is to control plastic film tension force plastic film is sent into compounding machine stably.The effect of plastic film unwinding device 10 is to the plastic film uncoiling.The effect of pinch roll 11 is to pinch plastic film, guarantees that plastic film has stable tension force.The effect that plastic film flattens unit 12 is to flatten plastic film, guarantees the smooth corrugationless of plastic film.The effect of automatic glue spreaders 13 is that the plastic film gluing is guaranteed the adhesive even thickness.The effect of jockey pulley II14 is to control plastic film tension force, guarantees tension stability in plastic film gluing process.Guide roller 15, the effect of plastic film Heating air box 16 are that guide roller 15 imports 16 pairs of plastic films of plastic film Heating air box with plastic film and carries out preheating and dry up adhesive.
In the production technological process of compound copper-plastics band as shown in Figure 4:
(1) plastic film uncoiling:
The biaxially oriented polyester film frame is put on let off roll, and let off roll is connected with magnetic powder brake, magnetic powder brake torque 500NM.
(2) plastic film flattens:
Enter plastic film after the plastic film uncoiling and flatten unit, plastic film is obtained than high-flatness.
(3) film gluing:
Plastic film enters the glue spreader group after flattening, and the gluing unit evenly is coated on homemade adhesive on plastic film, and the adhesive THICKNESS CONTROL is at 10-30 μ m.
(4) preheating:
Enter the plastic film Heating air box after the plastic film gluing and carry out preheating, provide blowing hot wind to enter the plastic film Heating air box by the plastic film heating blower and make the plastic film preheating more even.The plastic film preheat temperature is 50-70 ℃.
(5) copper strips uncoiling:
The copper strips frame is put on let off roll, and let off roll is connected with magnetic powder brake, magnetic powder brake torque 500NM.
(6) tension force detects:
Utilize tension detector to carry out tension force and detect, copper strips tension force is controlled at 3.5-5.5N.
(7) preheating:
The present invention select thickness be the ultra-thin copper belt of 0.02-0.03mm as the copper base band, adopt easier copper base band heating plate to be heated to 80-120 ℃.
(8) compound:
Plastic film and copper strips are compound through the compounding machine heating, and controlling combined temp by plastic film warm-up mill in compounding machine is 80-120 ℃.
(9) rolling:
Through the compound copper-plastics band of composite rolling by composite band wrap-up after-combustion rolling, 20-50 m/min of after-combustion speed, compound copper-plastics band tension force is controlled at 3.5-5.5N.
The technological process of production of ultra-thin red copper layer:
Preform is rolling: selecting thickness is the T2 copper strips of 0.12mm, is rolling to the preform that thickness is 0.08mm, mill speed 0.8m/s.
Softening: preform softens by annealing online continuously, and softening temperature is 680 ℃, and softening rate is 15m/min.
Finished product is rolling: preform is through work roll diameter 60mm, and the little four-high mill of backing roll diameter 300mm is rolling to the finished product that thickness is 0.03mm.Working roll adopts hollow water-cooled roll, and is directly cooling to copper strips and increased air cooling system at discharge end and strengthen coolingly by working roll, purges simultaneously copper strips and the copper strip surface free from admixture adhered to keep clean.
Softening: the finished product copper strips after rolling enters continuous annealing and softens, and softening temperature is 640 ℃, and softening rate is 15m/min.
The after-combustion rolling: after-combustion rolling after finished product is softening, test during after-combustion, if any defective, should record rolling rice number and carry out mark.
Check: the band presentation quality is checked according to GB/T11091-2005; Check thickness of strip with micrometer, thickness 0.03mm, permissible variation ± 0.0005mm.
The ultra-thin red copper layer leading indicator data of above-mentioned acquisition are as follows: red copper layer thickness 0.02-0.03mm, thickness deviation be ± 0.0005mm, Vickers hardness≤65HV, conductance 〉=98%IACS.
2, the technological process of production of compound copper-plastics band:
(1) plastic film uncoiling: the biaxially oriented polyester film frame is put on let off roll, and let off roll is connected with magnetic powder brake, magnetic powder brake torque 500NM.
(2) plastic film flattens: enter plastic film after the plastic film uncoiling and flatten unit, plastic film is obtained than high-flatness.
(3) film gluing: plastic film enters the glue spreader group after flattening, and the gluing unit evenly is coated on homemade adhesive on plastic film, and the adhesive THICKNESS CONTROL is at 15 μ m.
(4) preheating: enter the plastic film Heating air box after the plastic film gluing and carry out preheating, provide blowing hot wind to enter the plastic film Heating air box by the plastic film heating blower and make the plastic film preheating more even.The plastic film preheat temperature is 70 ℃.
(5) copper belt uncoiling: above-mentioned finished product copper strips frame is put on let off roll, and let off roll is connected with magnetic powder brake, magnetic powder brake torque 500NM.
(6) tension force detects: utilize tension detector to carry out tension force and detect, copper strips tension force is controlled at 5.5N.
(7) preheating: ultra-thin copper belt adopts easier copper base band heating plate to be heated to 90 ℃ as the copper base band.
(8) compound: plastic film and above-mentioned finished product copper strips are compound through the compounding machine heating, and controlling combined temp by plastic film warm-up mill in compounding machine is 100 ℃.
(9) rolling: through the compound copper-plastics band of composite rolling by composite band wrap-up after-combustion rolling, 30 m/mins of after-combustion speed, compound copper-plastics band tension force is controlled at 5.5N.
Described biaxially oriented polyester film (inspiring confidence in many Industrial Co., Ltd.s available from Shanghai) adopts the polyethylene terephthalate biaxially oriented polyester film, adopt such plastic layer, its benefit is: with reference to GB/T16958-2008, polyester film hot strength 〉=150MPa, substantially exceed the intensity of general ethylene copolymer or vinyon layer, guaranteed the bulk strength of compound copper-plastics band after the copper strips attenuate.Because biaxially oriented polyester film has good resistance to wear, folding resistance and tear resistance etc., can improve the application property of product.
Adhesive: its main component and mass fraction are ethylene-methyl methacrylate methyl terpolymer 20%, saturated polyester 32%, and epoxy resin 32%, melamine resin 6%, polyurethane 10% adds the p-methyl benzenesulfonic acid that accounts for resin gross mass 0.6%.In described ethylene-methyl methacrylate methyl terpolymer, the addition of methyl methacrylate is that 15% described saturated polyester of copolymer total weight is 335 available from Hualun Chemical Co., Ltd., Jiangsu; Epoxy resin 6101 is available from Shenyang City's applied chemistry study institute; Melamine resin is available from green source, Jiashan chemical industry Co., Ltd melamine (melamine resin refers to melamine resin also referred to as melamine formaldehyde molding compound, is called for short " MF " melamine formaldehyde resin, claims again melamine resin); Polyurethane polyurethane tpu is available from Bayer A.G (Bayer).Have fabulous electrical property, the flexing performance need not rear curing and processes, and characteristics such as metal adhesive have preferably further improved the peel strength of compound copper-plastics band.
The end properties test, totally 13 of Interventions Requested, examination requirements is as follows:
1 visual inspection requires: should be closely compound continuously, its surface should be smooth, smooth, even, free from admixture, non-wrinkle, without piebald, without other mechanical damages, it is qualified meeting above-mentioned requirements;
2 shear strength examination requirementses: copper strips break or plastic layer and copper strips between bonding when produce destroying, the heat seal district between plastic layer should not produce failure by shear, it is qualified meeting above-mentioned requirements;
3 resistance to water examination requirementses: treatment conditions: 68 ± 1 ℃ of temperature, time 168h; The peel strength of check compound copper-plastics band after processing;
4 examination requirementses of anti-filled composite the: treatment conditions: 68 ± 1 ℃ of temperature, time 168h; Whether layering between check copper strips and plastic film after processing, not stratified is qualified;
5 corrosion resistance examination requirementses: treatment conditions: solution 0.1mol/1HCl, time 480h; Determine corrosion class after processing;
6 dielectric strength examination requirementses: treatment conditions: test voltage 1KV d.c, duration 1min; Whether breakdownly process rear inspection, do not puncture as qualified
Check data such as following table:
The technological process of production of ultra-thin red copper layer:
Preform is rolling: selecting thickness is the T2 copper strips of 0.12mm, is rolling to the preform that thickness is 0.06mm, mill speed 1.0m/s.
Softening: preform softens by annealing online continuously, and softening temperature is 750 ℃, and softening rate is 20m/min.
Finished product is rolling: preform is through work roll diameter 90mm, and the little four-high mill of backing roll diameter 300mm is rolling to the finished product that thickness is 0.03mm.Working roll adopts hollow water-cooled roll, and is directly cooling to copper strips and increased air cooling system at discharge end and strengthen coolingly by working roll, purges simultaneously copper strips and the copper strip surface free from admixture adhered to keep clean.
4) softening: the finished product copper strips after rolling enters in continuous annealing and softens, and softening temperature is 680 ℃, and softening rate is 20m/min.
5) after-combustion rolling: after-combustion rolling after finished product is softening, test during after-combustion, if any defective, should record rolling rice number and carry out mark.
Check: the band presentation quality is checked according to GB/T11091-2005; Check thickness of strip with micrometer, thickness 0.03mm, permissible variation ± 0.0005mm.
2, the technological process of production of compound copper-plastics band:
(1) plastic film uncoiling: the biaxially oriented polyester film frame is put on let off roll, and let off roll is connected with magnetic powder brake, magnetic powder brake torque 500NM.
(2) plastic film flattens: enter plastic film after the plastic film uncoiling and flatten unit, plastic film is obtained than high-flatness.
(3) film gluing: plastic film enters the glue spreader group after flattening, and the gluing unit evenly is coated on homemade adhesive on plastic film, and the adhesive THICKNESS CONTROL is at 20 μ m.
(4) preheating: enter the plastic film Heating air box after the plastic film gluing and carry out preheating, provide blowing hot wind to enter the plastic film Heating air box by the plastic film heating blower and make the plastic film preheating more even.The plastic film preheat temperature is 60 ℃.
(5) copper strips uncoiling: above-mentioned finished product copper strips frame is put on let off roll, and let off roll is connected with magnetic powder brake, magnetic powder brake torque 500NM.
(6) tension force detects: utilize tension detector to carry out tension force and detect, copper strips tension force is controlled at 4N.
(7) preheating: ultra-thin copper belt adopts easier copper base band heating plate to be heated to 85 ℃ as the copper base band.
(8) compound: plastic film and above-mentioned finished product copper strips are compound through the compounding machine heating, and controlling combined temp by plastic film warm-up mill in compounding machine is 90 ℃.
(9) rolling: through the compound copper-plastics band of composite rolling by composite band wrap-up after-combustion rolling, 30 m/mins of after-combustion speed, compound copper-plastics band tension force is controlled at 4N.
Adhesive: its main component and mass fraction are ethylene-methyl methacrylate methyl terpolymer 20%, saturated polyester 32%, and epoxy resin 32%, melamine resin 6%, polyurethane 10% adds the p-methyl benzenesulfonic acid that accounts for resin gross mass 0.6%.In described ethylene-methyl methacrylate methyl terpolymer, the addition of methyl methacrylate is that 20% described saturated polyester of copolymer total weight is 345 available from Hualun Chemical Co., Ltd., Jiangsu; Epoxy resin 6101 is available from Shenyang City's applied chemistry study institute; Melamine resin is available from green source, Jiashan chemical industry Co., Ltd melamine (melamine resin refers to melamine resin also referred to as melamine formaldehyde molding compound, is called for short " MF " melamine formaldehyde resin, claims again melamine resin); Polyurethane polyurethane tpu is available from Bayer A.G (Bayer).
The end properties test: totally 13 of Interventions Requested, examination requirements is as follows:
1 visual inspection requires: should be closely compound continuously, its surface should be smooth, smooth, even, free from admixture, non-wrinkle, without piebald, without other mechanical damages, it is qualified meeting above-mentioned requirements;
2 shear strength examination requirementses: copper strips break or plastic layer and copper strips between bonding when produce destroying, the heat seal district between plastic layer should not produce failure by shear, it is qualified meeting above-mentioned requirements;
3 resistance to water examination requirementses: treatment conditions: 68 ± 1 ℃ of temperature, time 168h; The peel strength of check compound copper-plastics band after processing;
4 examination requirementses of anti-filled composite the: treatment conditions: 68 ± 1 ℃ of temperature, time 168h; Whether layering between check copper strips and plastic film after processing, not stratified is qualified;
5 corrosion resistance examination requirementses: treatment conditions: solution 0.1mol/1HCl, time 480h; Determine corrosion class after processing;
6 dielectric strength examination requirementses: treatment conditions: test voltage 1KV d.c, duration 1min; Whether breakdownly process rear inspection, do not puncture as qualified
Check data such as following table:
The technological process of production of ultra-thin red copper layer:
Preform is rolling: selecting thickness is the T2 copper strips of 0.10mm, is rolling to the preform that thickness is 0.06mm, mill speed 1.5m/s.
Softening: preform softens by annealing online continuously, and softening temperature is 800 ℃, and softening rate is 25m/min.
Finished product is rolling: preform is through work roll diameter 90mm, and the little four-high mill of backing roll diameter 280mm is rolling to the finished product that thickness is 0.02mm.Working roll adopts hollow water-cooled roll, and is directly cooling to copper strips and increased air cooling system at discharge end and strengthen coolingly by working roll, purges simultaneously copper strips and the copper strip surface free from admixture adhered to keep clean.
Softening: the finished product copper strips after rolling enters in continuous annealer and softens, and softening temperature is 700 ℃, and softening rate is 25m/min.
The after-combustion rolling: after-combustion rolling after finished product is softening, test during after-combustion, if any defective, should record rolling rice number and carry out mark.
Check: the band presentation quality is checked according to GB/T11091-2005; Check thickness of strip with micrometer, thickness 0.02mm, permissible variation ± 0.0005mm.
2, the technological process of production of compound copper-plastics band:
(1) plastic film uncoiling: the biaxially oriented polyester film frame is put on let off roll, and let off roll is connected with magnetic powder brake, magnetic powder brake torque 500NM.
(2) plastic film flattens: enter plastic film after the plastic film uncoiling and flatten unit, plastic film is obtained than high-flatness.
(3) film gluing: plastic film enters the glue spreader group after flattening, and the gluing unit evenly is coated on homemade adhesive on plastic film, and the adhesive THICKNESS CONTROL is at 10 μ m.
(4) preheating: enter the plastic film Heating air box after the plastic film gluing and carry out preheating, provide blowing hot wind to enter the plastic film Heating air box by the plastic film heating blower and make the plastic film preheating more even.The plastic film preheat temperature is 70 ℃.
(5) copper strips uncoiling: above-mentioned finished product copper strips frame is put on let off roll, and let off roll is connected with magnetic powder brake, magnetic powder brake torque 500NM.
(6) tension force detects: utilize tension detector to carry out tension force and detect, copper strips tension force is controlled at 5.5N.
(7) preheating: ultra-thin copper belt adopts easier copper base band heating plate to be heated to 90 ℃ as the copper base band.
(8) compound: plastic film and above-mentioned finished product copper strips are compound through the compounding machine heating, and controlling combined temp by plastic film warm-up mill in compounding machine is 100 ℃.
(9) rolling: through the compound copper-plastics band of composite rolling by composite band wrap-up after-combustion rolling, 30 m/mins of after-combustion speed, compound copper-plastics band tension force is controlled at 5.5N.
Adhesive: its main component and mass fraction are ethylene-methyl methacrylate methyl terpolymer 20%, saturated polyester 32%, and epoxy resin 32%, melamine resin 6%, polyurethane 10% adds the p-methyl benzenesulfonic acid that accounts for resin gross mass 0.6%.In described ethylene-methyl methacrylate methyl terpolymer, the addition of methyl methacrylate is 30% of copolymer total weight.Described saturated polyester is that Vylon560 is available from spinning (TOYOBO) in Japanese Japan; Epoxy resin 634 is available from Shenyang City's applied chemistry study institute; Melamine resin is available from green source, Jiashan chemical industry Co., Ltd melamine (melamine resin refers to melamine resin also referred to as melamine formaldehyde molding compound, is called for short " MF " melamine formaldehyde resin, claims again melamine resin); Polyurethane polyurethane tpu is available from Bayer A.G (Bayer).
The end properties test, totally 13 of Interventions Requested, examination requirements is as follows:
1 visual inspection requires: should be closely compound continuously, its surface should be smooth, smooth, even, free from admixture, non-wrinkle, without piebald, without other mechanical damages, it is qualified meeting above-mentioned requirements;
2 shear strength examination requirementses: copper strips break or plastic layer and copper strips between bonding when produce destroying, the heat seal district between plastic layer should not produce failure by shear, it is qualified meeting above-mentioned requirements;
3 resistance to water examination requirementses: treatment conditions: 68 ± 1 ℃ of temperature, time 168h; The peel strength of check compound copper-plastics band after processing;
4 examination requirementses of anti-filled composite the: treatment conditions: 68 ± 1 ℃ of temperature, time 168h; Whether layering between check copper strips and plastic film after processing, not stratified is qualified;
5 corrosion resistance examination requirementses: treatment conditions: solution 0.1mol/1HCl, time 480h; Determine corrosion class after processing;
6 dielectric strength examination requirementses: treatment conditions: test voltage 1KV d.c, duration 1min; Whether breakdownly process rear inspection, do not puncture as qualified
Check data such as following table:
Claims (8)
1. compound copper-plastics band that is applicable to telecommunication cable and optical cable, it is characterized in that: compound copper-plastics band is coated on telecommunication cable or optical cable outer surface, compound copper-plastics band is provided with red copper layer 1, adhesive layer 2 and laminated polyester film 3 successively, and red copper layer 1, adhesive layer 2 and laminated polyester film 3 form composite construction by the bonding thermal-adhering that adds.
2. by the compound copper-plastics band that is applicable to telecommunication cable and optical cable claimed in claim 1, it is characterized in that: described adhesive layer is that resin and p-methyl benzenesulfonic acid form, described resin is by mass fraction, ethylene-methyl methacrylate methyl terpolymer 18-22%, saturated polyester 29-35%, epoxy resin 29-35%, melamine resin 4-8%, polyurethane 8-12%, the addition of p-methyl benzenesulfonic acid is resin gross mass 0.5-0.7%.
3. by the compound copper-plastics band that is applicable to telecommunication cable and optical cable claimed in claim 2, it is characterized in that: in described ethylene-methyl methacrylate methyl terpolymer, the addition of methyl methacrylate is the 15-30% of copolymer total weight.
4. preparation method who is applicable to the compound copper-plastics band of telecommunication cable and optical cable claimed in claim 1 is characterized in that:
1) will by the rolling one-tenth thickness of 4-roller cold rolling mill be the ultra-thin red copper layer of 0.02-0.03mm through 60-80 ℃ of preheating, stand-by;
2) adhesive is coated on laminated polyester film, and by 50-70 ℃ of preheating, stand-by;
3) with step 1) red copper layer and step 2) the laminated polyester film of coating adhesive heat under 80-120 ℃ compound, composite pressure is 50-100N.
5. by the preparation method who is applicable to the compound copper-plastics band of telecommunication cable and optical cable claimed in claim 4, it is characterized in that:
Described step 1) adopt diameter 50-80mm working roll, the simons mill of the backing roll of diameter 260-300mm is rolling.
6. by the described preparation method who is applicable to the compound copper-plastics band of telecommunication cable and optical cable of claim 4 or 5, it is characterized in that: described ultra-thin red copper layer is according to following preparation:
1) preform is rolling: selecting thickness is the T2 copper strips of 0.12-0.10mm, is rolling to the preform that thickness is 0.08-0.06mm, mill speed 0.1-1.5m/s;
2) softening: preform softens, and softening temperature is 600-900 ℃, and softening rate is 5-30m/min;
3) finished product is rolling: above-mentioned softening rear preform is adopted diameter 50-90mm working roll, and the hollow water-cooled simons mill of the backing roll of diameter 260-300mm is rolling;
4) softening: the finished product copper strips after rolling enters continuous annealing and softens, and softening temperature is 600-900 ℃, and softening rate is 5-30m/min.
7. by the preparation method who is applicable to the compound copper-plastics band of telecommunication cable and optical cable claimed in claim 4, it is characterized in that: described step 2) with the magnetic powder brake biaxial tension of polyester film with torque 500NM, obtain the high-flatness polyester film, then adhesive evenly is coated on plastic film, the adhesive THICKNESS CONTROL is at 10-30 μ m; The polyester film that scribbles adhesive is carried out preheating in 50-70 ℃, heated-air drying, stand-by.
8. by the preparation method who is applicable to the compound copper-plastics band of telecommunication cable and optical cable claimed in claim 4, it is characterized in that: described step 3) described red copper layer is carried out uncoiling with torque 500NM and then be heated to 80-120 ℃, and the polyester film that will apply adhesive is compound through the compounding machine heating, combined temp is 80-120 ℃, composite pressure is 50-100N, at last will be through the compound copper-plastics band after-combustion rolling of composite rolling, after-combustion speed 20-50m/min, compound copper-plastics band tension force is controlled at 3.5-5.5N.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110408191.1A CN103165224B (en) | 2011-12-09 | 2011-12-09 | Copper plastic composite strap suitable for telecommunication cable and optical cable and preparation method of copper plastic composite strap |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110408191.1A CN103165224B (en) | 2011-12-09 | 2011-12-09 | Copper plastic composite strap suitable for telecommunication cable and optical cable and preparation method of copper plastic composite strap |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103165224A true CN103165224A (en) | 2013-06-19 |
| CN103165224B CN103165224B (en) | 2015-05-20 |
Family
ID=48588229
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110408191.1A Expired - Fee Related CN103165224B (en) | 2011-12-09 | 2011-12-09 | Copper plastic composite strap suitable for telecommunication cable and optical cable and preparation method of copper plastic composite strap |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103165224B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104200892A (en) * | 2014-09-22 | 2014-12-10 | 华迅工业(苏州)有限公司 | Antistatic metal foil and plastic composited belt for symmetric data cable shielding |
| CN105437713A (en) * | 2015-12-01 | 2016-03-30 | 上海网讯新材料科技股份有限公司 | Cooling method and equipment for production of metal and plastic composite belts |
| CN106003691A (en) * | 2016-06-06 | 2016-10-12 | 深圳新澳科电缆有限公司 | Method for covering film |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1329951A (en) * | 2000-06-19 | 2002-01-09 | 东北大学 | Rolling method and apparatus for combining liquid-solid heterometals |
| JP2002216719A (en) * | 2001-01-18 | 2002-08-02 | Dainippon Printing Co Ltd | Adhesive film used at tab part of lithium battery |
| CN2527437Y (en) * | 2001-12-17 | 2002-12-25 | 周孝镛 | Copper-plastic composite belt |
| CN101786365A (en) * | 2009-11-20 | 2010-07-28 | 无锡市速达电讯材料有限公司 | Production method of single-side copper-plastic compound belt |
-
2011
- 2011-12-09 CN CN201110408191.1A patent/CN103165224B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1329951A (en) * | 2000-06-19 | 2002-01-09 | 东北大学 | Rolling method and apparatus for combining liquid-solid heterometals |
| JP2002216719A (en) * | 2001-01-18 | 2002-08-02 | Dainippon Printing Co Ltd | Adhesive film used at tab part of lithium battery |
| CN2527437Y (en) * | 2001-12-17 | 2002-12-25 | 周孝镛 | Copper-plastic composite belt |
| CN101786365A (en) * | 2009-11-20 | 2010-07-28 | 无锡市速达电讯材料有限公司 | Production method of single-side copper-plastic compound belt |
Non-Patent Citations (1)
| Title |
|---|
| 范和平等: "《柔性印刷电路用聚酯覆铜板胶粘剂的应用与制备》", 《中国胶粘剂》, no. 19993, 30 June 1999 (1999-06-30), pages 6 - 9 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104200892A (en) * | 2014-09-22 | 2014-12-10 | 华迅工业(苏州)有限公司 | Antistatic metal foil and plastic composited belt for symmetric data cable shielding |
| CN105437713A (en) * | 2015-12-01 | 2016-03-30 | 上海网讯新材料科技股份有限公司 | Cooling method and equipment for production of metal and plastic composite belts |
| CN106003691A (en) * | 2016-06-06 | 2016-10-12 | 深圳新澳科电缆有限公司 | Method for covering film |
| CN106003691B (en) * | 2016-06-06 | 2020-02-18 | 深圳新澳科电缆有限公司 | Film laminating method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103165224B (en) | 2015-05-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110379948B (en) | Dry preparation process of lithium battery flexible packaging film | |
| CN103165237B (en) | A kind of halogen-free flame retardant copper-plastic composite belt and preparation thereof | |
| SG194225A1 (en) | Process for producing a polymer coated metal substrate and a metal strip substrate provided with a polymer coating | |
| CN112563444B (en) | Asynchronous heating and rolling device, large-width ultrathin metal lithium foil, and preparation method and application thereof | |
| WO2014005537A1 (en) | Biaxially-oriented tackifying precoated film and manufacturing method therefor | |
| CN103165224B (en) | Copper plastic composite strap suitable for telecommunication cable and optical cable and preparation method of copper plastic composite strap | |
| TW201708268A (en) | Polyvinyl alcohol polymer film and method for producing same | |
| CN102560044B (en) | Copper strip surface treatment method and device | |
| JP3117724B2 (en) | Manufacturing method and manufacturing equipment for laminated metal sheet | |
| CN201336166Y (en) | Polyimide fiberglass enamelled flat wire for stator coil of 10kv high-voltage motor | |
| CN103879125B (en) | The solvent-free complex method of thermophilic digestion composite membrane, bag and set composite thereof | |
| CN109161831A (en) | Hot-dip prepares the method, system and ultra-thin lithium band of ultra-thin lithium band | |
| CN113979170A (en) | From type membrane equipment complex and from type membrane composite production line | |
| CN108425081B (en) | A kind of copper aluminium rolling casting bonding strip online annealing method | |
| CN110027302A (en) | A kind of production line and its production technology of polyester fiber composite metal plate | |
| CN109127770A (en) | Mosquito-repellent incense type dissipates greatly disk production method and system | |
| CN208827156U (en) | Lithium battery packaging film process units | |
| CN101786363A (en) | Production method of single-side low temperature aluminum-plastic compound belt | |
| CN108099337A (en) | A kind of film-covered iron high-efficient production technology | |
| CN210759689U (en) | Composite flexible package solvent-free compound machine | |
| CN201342825Y (en) | A thermal rolling extrusion equipment | |
| CN107554015A (en) | A kind of medicine and food packaging BOPP metallized films and preparation method thereof | |
| CN202543260U (en) | Processing device for surface of copper strip | |
| CN106393937A (en) | Continuous preparation equipment and process for no-woven cloth | |
| CN107804054A (en) | TPT backboards, hot-press method and the hot-press equipment of a kind of photovoltaic cell |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PP01 | Preservation of patent right |
Effective date of registration: 20151112 Granted publication date: 20150520 |
|
| RINS | Preservation of patent right or utility model and its discharge | ||
| PD01 | Discharge of preservation of patent |
Date of cancellation: 20161112 Granted publication date: 20150520 |
|
| PP01 | Preservation of patent right |
Effective date of registration: 20161112 Granted publication date: 20150520 |
|
| RINS | Preservation of patent right or utility model and its discharge | ||
| PD01 | Discharge of preservation of patent | ||
| PD01 | Discharge of preservation of patent |
Date of cancellation: 20170512 Granted publication date: 20150520 |
|
| PP01 | Preservation of patent right | ||
| PP01 | Preservation of patent right |
Effective date of registration: 20170512 Granted publication date: 20150520 |
|
| PD01 | Discharge of preservation of patent | ||
| PD01 | Discharge of preservation of patent |
Date of cancellation: 20171112 Granted publication date: 20150520 |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150520 Termination date: 20161209 |