CN103146499A - Cleaning agent for waste polyester bottle pieces - Google Patents
Cleaning agent for waste polyester bottle pieces Download PDFInfo
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- CN103146499A CN103146499A CN2013100655691A CN201310065569A CN103146499A CN 103146499 A CN103146499 A CN 103146499A CN 2013100655691 A CN2013100655691 A CN 2013100655691A CN 201310065569 A CN201310065569 A CN 201310065569A CN 103146499 A CN103146499 A CN 103146499A
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- polyoxyethylene ether
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Abstract
The invention relates to a cleaning agent for waste polyester bottle pieces in the field of cleaning agents. The cleaning agent consists of the following components in mass ratio: 96-130kg of sodium polyacrylate, 70-105kg of triethanolamine oleate, 20-40kg of sodium dodecyl benzene sulfonate, 168-200kg of fatty alcohol-polyoxyethylene ether, 30-60kg of sodium metasilicate, 20-42kg of fatty alcohol polyoxyethylene ether sodium sulfate, 35-110kg of sodium silicate and 430-475kg of pure water. The cleaning agent is strong in clearing power and easy to rinse, and can effectively reduce scales formed by calcium and magnesium ions which are attached to a waste bottle piece matrix.
Description
[technical field]
The present invention relates to the clean-out system field, especially relate to a kind of clean-out system be used to the waste polyester beverage bottle fragment after cleaning and crush.
[background technology]
known, present beverage bottle is many by PET, be that polyester material is made, when these polyester beverage bottles finishing using go out of use after, the impurity such as the caramel that useless bottle upward must have except the adhesion beverage, label glue, fructose, it also may be attached with other impurity such as animal-plant oil, dust, earth, pigment, pigment, therefore, useless beverage bottle must carry out thoroughly cleaning when smashing recycling pollution-free to ensure its clean hygiene being recovered, and then can be used for spinning POLYESTER YARNS or blowing PET bottle, yet, because the useless bottle chip detergent that uses now is all take tensio-active agent as main usually, although it is to cleaning caramel, fructose, oil slick, dust, the unstructuredness such as sebum or earth dirt can play a role, but just seemed poor effect for cleaning label glue or old grease isostructuralism dirt, it is mainly former is because want to make structural dirt by stripping down on useless bottle sheet matrix, to guarantee that not only the concentration of clean-out system in scavenging solution reaches threshold concentration, but also must make scavenging solution keep certain pH value, could provide enough activity to clean-out system like this, but, because alkali can produce saponification reaction in surface of polyester under certain pH value, also referred to as " alkali decrement ", it reacts not obvious under cold conditions, but can rise and fast reaction speed with temperature in time more than 70 ℃, and generate saponified, thereby have influence on the spinning property of the macromolecular kindliness of PET and spinning, and the waste polyester bottle chip detergent that uses does not now almost have counter-measure to this saponification reaction,
In addition, for the unstructuredness dirt, after through the cleaning of clean-out system to useless bottle sheet, although these dirts are stripped from, but the settling velocity because of it in water relatively comparatively fast causes secondary to be attached on useless bottle sheet matrix, thereby directly causes the more difficult rinsing of useless bottle sheet clean; Simultaneously, because useless bottle sheet cleaning hourly water consumption is larger, and its general use is all underground water or tap water, and the heat of at present domestic device for cleaning useless bottle sheet is washed temperature substantially all higher than 80 ℃, therefore, this very easily causes elements such as calcium, magnesium ion in underground water or tap water to be attached on useless bottle sheet matrix forming fouling; In sum, due to the reason of cleaning link, at present domestic processing to the waste polyester bottle sheet can't make impurity be removed by bottle sheet surface fully, thereby causes corresponding dirt to be brought in the polyester fondant that forms after the fusing of useless bottle sheet, and then causes spun POLYESTER YARNS quality lower.
[summary of the invention]
In order to overcome the deficiency in background technology, the invention discloses a kind of waste polyester bottle chip detergent, described clean-out system is Polyoxyethylene Lauryl Ether not only, is easy to rinsing, is attached to the fouling that forms on useless bottle sheet matrix but also can effectively reduce calcium ions and magnesium ions.
For achieving the above object, the present invention adopts following technical scheme:
A kind of waste polyester bottle chip detergent, described clean-out system is made of in mass ratio following component: 96～130 kilograms of sodium polyacrylates, 70～105 kilograms of triethanolamine oleates, 20～40 kilograms of Sodium dodecylbenzene sulfonatees, 168～200 kilograms of fatty alcohol-polyoxyethylene ether, 30～60 kilograms of Starsos, 20～42 kilograms of polyoxyethylenated alcohol sodium sulfate, 35～110 kilograms of water glass, 430～475 kilograms of pure water.
Described waste polyester bottle chip detergent, described clean-out system is made of in mass ratio following component: 106 kilograms of sodium polyacrylates, 86 kilograms of triethanolamine oleates, 29 kilograms of Sodium dodecylbenzene sulfonatees, 186 kilograms of fatty alcohol-polyoxyethylene ether, 45 kilograms of Starsos, 30 kilograms of polyoxyethylenated alcohol sodium sulfate, 50 kilograms of water glass, 468 kilograms of pure water.
Described waste polyester bottle chip detergent, described clean-out system is made by following flow process by above-mentioned component: sodium polyacrylate is added in triethanolamine oleate airtight stirring 90～100min under 80～90 ℃; When solution temperature is down to 70～80 ℃, keeps temperature and add Starso, water glass after stirring, then stirring 30～35min; When temperature is down to 60～70 ℃, progressively add polyoxyethylenated alcohol sodium sulfate, Sodium dodecylbenzene sulfonate, fatty alcohol-polyoxyethylene ether under whipped state, add pure water to be finished product after stirring 30～40min.
Owing to adopting technical scheme as above, the present invention has following beneficial effect:
Waste polyester bottle chip detergent of the present invention is applicable to unstructuredness dirt and structural dirt on useless bottle sheet are cleaned, it utilizes triethanolamine oleate that alkali saponification reaction speed to surface of polyester at temperature more than 85 ℃ is reduced greatly, utilize Sodium dodecylbenzene sulfonate and fatty alcohol-polyoxyethylene ether that tensio-active agent is attached on carrier, and infiltrate the dirt internal direct to useless bottle sheet matrix, make the unstructuredness dirt be stripped from, make structural dirt be in relaxed state, thereby reach the purpose under being easy to be stripped from the alkaline environment of 85 ℃; In addition, can reduce due to sodium polyacrylate the settling velocity of dirt in scavenging solution that strips down, water glass, Starso and polyoxyethylenated alcohol sodium sulfate can make the fouling body of the elements such as calcium in underground water or tap water, magnesium ion be suspended in water, therefore, described clean-out system is strong detergency not only, be easy to rinsing, but also incrustation scale is attached on useless bottle sheet matrix.
[embodiment]
Can explain in more detail the present invention by the following examples, disclose purpose of the present invention and be intended to protect all changes and improvements in the scope of the invention, the present invention is not limited to the following examples;
Described waste polyester bottle chip detergent is made of in mass ratio following component: 96～130 kilograms of sodium polyacrylates, 70～105 kilograms of triethanolamine oleates, 20～40 kilograms of Sodium dodecylbenzene sulfonatees, 168～200 kilograms of fatty alcohol-polyoxyethylene ether, 30～60 kilograms of Starsos, 20～42 kilograms of polyoxyethylenated alcohol sodium sulfate, 35～110 kilograms of water glass, 430～475 kilograms of pure water; As required, can form in mass ratio described clean-out system by following component: 106 kilograms of sodium polyacrylates, 86 kilograms of triethanolamine oleates, 29 kilograms of Sodium dodecylbenzene sulfonatees, 186 kilograms of fatty alcohol-polyoxyethylene ether, 45 kilograms of Starsos, 30 kilograms of polyoxyethylenated alcohol sodium sulfate, 50 kilograms of water glass, 468 kilograms of pure water;
Described waste polyester bottle chip detergent is made by following flow process by above-mentioned component: sodium polyacrylate is added in triethanolamine oleate airtight stirring 90～100min under 80～90 ℃; When solution temperature is down to 70～80 ℃, keeps temperature and add Starso, water glass after stirring, then stirring 30～35min; When temperature is down to 60～70 ℃, progressively add polyoxyethylenated alcohol sodium sulfate, Sodium dodecylbenzene sulfonate, fatty alcohol-polyoxyethylene ether under whipped state, add pure water to be finished product after stirring 30～40min.
Part not in the detailed description of the invention is prior art, therefore the present invention is not described in detail.
Claims (3)
1. waste polyester bottle chip detergent, it is characterized in that: described clean-out system is made of in mass ratio following component: 96～130 kilograms of sodium polyacrylates, 70～105 kilograms of triethanolamine oleates, 20～40 kilograms of Sodium dodecylbenzene sulfonatees, 168～200 kilograms of fatty alcohol-polyoxyethylene ether, 30～60 kilograms of Starsos, 20～42 kilograms of polyoxyethylenated alcohol sodium sulfate, 35～110 kilograms of water glass, 430～475 kilograms of pure water.
2. waste polyester bottle chip detergent according to claim 1, it is characterized in that: described clean-out system is made of in mass ratio following component: 106 kilograms of sodium polyacrylates, 86 kilograms of triethanolamine oleates, 29 kilograms of Sodium dodecylbenzene sulfonatees, 186 kilograms of fatty alcohol-polyoxyethylene ether, 45 kilograms of Starsos, 30 kilograms of polyoxyethylenated alcohol sodium sulfate, 50 kilograms of water glass, 468 kilograms of pure water.
3. waste polyester bottle chip detergent according to claim 1 and 2, it is characterized in that: described clean-out system is made by following flow process by above-mentioned component: sodium polyacrylate is added in triethanolamine oleate airtight stirring 90～100min under 80～90 ℃; When solution temperature is down to 70～80 ℃, keeps temperature and add Starso, water glass after stirring, then stirring 30～35min; When temperature is down to 60～70 ℃, progressively add polyoxyethylenated alcohol sodium sulfate, Sodium dodecylbenzene sulfonate, fatty alcohol-polyoxyethylene ether under whipped state, add pure water to be finished product after stirring 30～40min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013100655691A CN103146499A (en) | 2013-03-01 | 2013-03-01 | Cleaning agent for waste polyester bottle pieces |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013100655691A CN103146499A (en) | 2013-03-01 | 2013-03-01 | Cleaning agent for waste polyester bottle pieces |
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| Publication Number | Publication Date |
|---|---|
| CN103146499A true CN103146499A (en) | 2013-06-12 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2013100655691A Pending CN103146499A (en) | 2013-03-01 | 2013-03-01 | Cleaning agent for waste polyester bottle pieces |
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| CN (1) | CN103146499A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103421618A (en) * | 2013-07-24 | 2013-12-04 | 洛阳市柯莱尔清洗材料有限公司 | Scrap cleaning agent for edible oil packaging container |
| CN104498198A (en) * | 2015-01-14 | 2015-04-08 | 上海承瑶环保科技有限公司 | PET (polyethylene terephthalate) bottle chip recycling treatment rinsing agent |
| CN105800908A (en) * | 2016-05-24 | 2016-07-27 | 成都科衡环保技术有限公司 | Composite treatment agent for waste vegetable-oil-based mud and preparation method thereof |
| CN107829103A (en) * | 2017-11-15 | 2018-03-23 | 苏州锐耐洁电子科技新材料有限公司 | A kind of stainless steel welds spot cleaning agent |
| CN113416613A (en) * | 2021-06-18 | 2021-09-21 | 江苏斯尔邦石化有限公司 | Recovered polyester PET bottle flake cleaning agent and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1079506A (en) * | 1992-06-05 | 1993-12-15 | 湖北省沙市市日用化工总厂 | Industrial bottle-washing detergent |
| CN1114680A (en) * | 1994-07-05 | 1996-01-10 | 李连桂 | Liquid detergent for washing bottle |
| CN1198469A (en) * | 1998-05-20 | 1998-11-11 | 重庆药用包装容器厂 | High-effect detergent for cleaning beverage bottle |
| CN1242039A (en) * | 1996-11-15 | 2000-01-19 | 埃科莱布有限公司 | Cleaning method for polyethylene terephtalate containers |
| WO2004027001A1 (en) * | 2002-09-18 | 2004-04-01 | Ecolab Inc. | Additive for use in bottle washing compositions additive |
| CN102115696A (en) * | 2010-01-05 | 2011-07-06 | 哈尔滨理工大学 | Non-phosphate liquid detergent and preparation method thereof |
-
2013
- 2013-03-01 CN CN2013100655691A patent/CN103146499A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1079506A (en) * | 1992-06-05 | 1993-12-15 | 湖北省沙市市日用化工总厂 | Industrial bottle-washing detergent |
| CN1114680A (en) * | 1994-07-05 | 1996-01-10 | 李连桂 | Liquid detergent for washing bottle |
| CN1242039A (en) * | 1996-11-15 | 2000-01-19 | 埃科莱布有限公司 | Cleaning method for polyethylene terephtalate containers |
| CN1198469A (en) * | 1998-05-20 | 1998-11-11 | 重庆药用包装容器厂 | High-effect detergent for cleaning beverage bottle |
| WO2004027001A1 (en) * | 2002-09-18 | 2004-04-01 | Ecolab Inc. | Additive for use in bottle washing compositions additive |
| CN102115696A (en) * | 2010-01-05 | 2011-07-06 | 哈尔滨理工大学 | Non-phosphate liquid detergent and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103421618A (en) * | 2013-07-24 | 2013-12-04 | 洛阳市柯莱尔清洗材料有限公司 | Scrap cleaning agent for edible oil packaging container |
| CN104498198A (en) * | 2015-01-14 | 2015-04-08 | 上海承瑶环保科技有限公司 | PET (polyethylene terephthalate) bottle chip recycling treatment rinsing agent |
| CN105800908A (en) * | 2016-05-24 | 2016-07-27 | 成都科衡环保技术有限公司 | Composite treatment agent for waste vegetable-oil-based mud and preparation method thereof |
| CN107829103A (en) * | 2017-11-15 | 2018-03-23 | 苏州锐耐洁电子科技新材料有限公司 | A kind of stainless steel welds spot cleaning agent |
| CN113416613A (en) * | 2021-06-18 | 2021-09-21 | 江苏斯尔邦石化有限公司 | Recovered polyester PET bottle flake cleaning agent and preparation method thereof |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20130612 |