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CN103131326A - Preparation method of anti-radiation paint - Google Patents

Preparation method of anti-radiation paint Download PDF

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Publication number
CN103131326A
CN103131326A CN2013100563702A CN201310056370A CN103131326A CN 103131326 A CN103131326 A CN 103131326A CN 2013100563702 A CN2013100563702 A CN 2013100563702A CN 201310056370 A CN201310056370 A CN 201310056370A CN 103131326 A CN103131326 A CN 103131326A
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China
Prior art keywords
powder
coating
paint
preparation
titanium dioxide
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CN2013100563702A
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CN103131326B (en
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王创标
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GUANGDONG BIAOPAI CHEMICAL TECHNOLOGY Co Ltd
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GUANGDONG BIAOPAI CHEMICAL TECHNOLOGY Co Ltd
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Publication of CN103131326A publication Critical patent/CN103131326A/en
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Abstract

The invention relates to the field of anti-radiation material preparation, and specifically relates to a preparation method of an anti-radiation paint. The method comprises the steps that: talc powder, lime powder, porous starch, titanium dioxide, quartz powder, barite powder, epoxy-modified silicone resin powder, a sodium polycarboxylate dispersant, a thickening agent, a defoaming agent, a coupling agent, and water are mixed; the mixture is stirred under a temperature of 80-90 DEG C; the mixture is cooled, a styrene-acrylic emulsion is added; and the mixture is sufficiently mixed by stirring. The paint preparation method provided by the invention is simple and safe, and has the advantages of low cost, no toxicity, stable performance, easy transportation, and easy storage. When a thickness of a coated layer reaches 12mm, a lead equivalent is 1.53mmpb. The paint has high resistances against X and gamma rays, and provides a good shielding and protecting function for building walls.

Description

A kind of collocation method of radiation shielding coating
Technical field
The invention belongs to the antiradiation material preparation field, be specifically related to a kind of collocation method of radiation shielding coating.Background technology
Along with the development of society, more and more modernization, radiotechnology such as national defence, medical science, industry, agricultural etc. in a lot of fields is widely used.The application one side science and technology of radiotechnology and the embodiment of Economic development, and radiation can be to people's the healthy infringement that causes in various degree on the other hand, especially X and gamma-rays, be to be employed maximum ionizing rayss, is also the greatest irradiation source of jeopardizing HUMAN HEALTH.It all has very strong penetration power, can pass the construction wall of general thickness.One of method that prevents radiation is that body of wall is thickeied, but can waste building cost like this, ties up the space, is optimal approach and construction wall is used radiation shielding coating.Have at present employing stereotype, barium cement layer or composite protective plate to protect both at home and abroad, but all there is defective in various degree in these materials, leaks, easily chap, easily come off as bad adhesion, easy seam etc.Existing radiation shielding coating, filling anti-radiation material contain the harmful toxic matter that exceeds standard mostly, as formaldehyde, volatile organic compounds, lead etc.
Summary of the invention
The embodiment of the present invention provides a kind of collocation method of radiation shielding coating, is intended to solve the problem that existing radiation shielding coating, filling anti-radiation material contain the harmful toxic matter that exceeds standard mostly.
The embodiment of the present invention is achieved in that a kind of collocation method of radiation shielding coating, and described method comprises the steps:
Talcum powder, lime powder, porous-starch, titanium dioxide, silica powder, ground barium sulfate, epoxy modified silicone resin powder and poly carboxylic acid sodium dispersion agent, thickening material, defoamer, coupling agent are added water to be mixed;
Described mixture is stirred at the temperature of 80-90 ℃, add benzene emulsion after cooling and fully mix thoroughly.
Embodiment of the present invention coating preparation technique is simple, and cost is low, safety non-toxic, stable performance is easy to transportation and stores, when smear layer thickness reaches 12mm, protective value is 1.53mmpb, and X, gamma-rays are had very strong resistibility, and building masonry wall is also had good shielding protection function.
Description of drawings
Fig. 1 represents the realization flow figure of a kind of radiation shielding coating collocation method that the embodiment of the present invention provides.
Embodiment
In order to make purpose of the present invention, technical scheme and advantage clearer, below in conjunction with drawings and Examples, the present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, is not intended to limit the present invention.
Fig. 1 shows the realization flow of a kind of radiation shielding coating collocation method that the embodiment of the present invention provides, and details are as follows:
In step S101, talcum powder, lime powder, porous-starch, titanium dioxide, silica powder, ground barium sulfate, epoxy modified silicone resin powder and poly carboxylic acid sodium dispersion agent, thickening material, defoamer, coupling agent are added water mix;
In embodiments of the present invention, the performance of main raw material is as follows:
1, epoxy modified silicone resin: epoxy modified silicone resin integrates epoxy resin and silicone resin good characteristic, be used widely because of its performance such as thermostability, non-corrosibility, electrical insulating property, resistant of high or low temperature, anti-corona, radiation hardness, humidity and resistant to chemical media with good mechanical property and excellence, become and use one of maximum, that range of application is the widest Special Resin kind in speciality coating;
2, porous-starch: having another name called micropore starch, is a kind of novel modified starch, and it is to have the enzyme of living amylase activity at the cellular product of porousness that forms lower than acting on living starch under gelatinization point.The micropore starch surface is covered with the aperture that diameter is 1 about μ m, aperture by the surface to the center deeply, the volume in hole accounts for 50% left and right of particle volume.With natural living starch through the outer reason of hydrolysis after, form aperture on its material surface, and extend to granule interior always, be a kind of hollow particle of similar hornet's nest shape, can the various materials of splendid attire in wherein, have good adsorptivity;
3, ground barium sulfate: have another name called native sulfate of barium, product is mainly used in the weighting agent of oil and gas well drilling mud, produces zinc sulfide white or is used for the industries such as medical science, nuclear industry, car brakeing material, strap, high-grade paint, hospital's radioprotective Gravity Wall as the screener of X ray.
4, titanium dioxide: titanium dioxide (titanium dioxide) stable chemical nature does not react with most of material in the ordinary course of things.At occurring in nature titanium dioxide, three kinds of crystallizations are arranged: plate titanium type, sharp titanium and rutile-type.Plate titanium type is unsettled crystal formation, be worth without industrial utilization, anatase titanium dioxide is called for short the A type, be called for short the R type with rutile-type, all has stable lattice, be important white pigment and porcelain glaze, with other white pigments, superior whiteness, tinting strength, opacifying power, weathering resistance, thermotolerance and chemical stability arranged relatively, particularly there is no toxicity.Titanium dioxide is considered at present the best a kind of white pigment of performance in the world, is widely used in the industry such as coating, plastics, papermaking, printing-ink, chemical fibre, rubber, makeup.
5, talcum powder: main component is the moisture Magnesium Silicate q-agent of talcum, and talcum belongs to oblique system.Crystal is the sheet of false six sides or rhombus, and is accidental.Be generally fine and close bulk, foliated lamellar, radial, fibrous agrregate.Water white transparency or white, but present even light red of light green, pale yellow, shallow palm fibre because containing a small amount of impurity; Be pearliness on cleavage surface.Hardness l, proportion 2.7~2.8.Be used for rubber, plastics, paint, etc. chemical industry as strengthening the upgrading weighting agent.Characteristics: increase the stable of shape of product, increase tensile strength, shearing resistance, flexing intensity, pressure intensity reduces distortion, the extension rate, thermal expansivity, whiteness is high, the dispersed characteristics such as strong of epigranular.
6, lime powder (calcium carbonate): calcium carbonate can be used as white pigment in coating, plays a kind of skeleton function, and calcium carbonate can be used as pigment extender in coatings industry.Because the calcium carbonate color is white, relative latex in coating, the solvent price is all cheap, and particle is thin, can be in coating Uniform Dispersion, so be a large amount of pigment extenders that use.Due to the raising of environmental consciousness, coating use coating in a large number aspect building, because calcium carbonate is that white is hydrophilic again, price is cheap again, so obtain application.Inserting of calcium carbonate can strengthen priming paint to deposition and the perviousness of substrate surface.Putty is to fill and lead up basal plane in coating, it is the middle layer of whole coating, no matter any putty all needs to add a large amount of fillers, filler body in putty is water-ground limestone, add on a small quantity again some lithopones and prevent that to increase viscosity enamelled coating is loose, suitably add precipitated chalk simultaneously so that polishing after doing.
7, silica powder: claim again silicon powder.Silica powder is a kind of mineral of hard, wear-resisting, stable chemical performance, and its essential mineral composition is quartzy, and its main chemical compositions is SiO 2The color of quartz sand is oyster white or colourless translucent, hardness 7, and property is crisp without cleavage, conchoidal fracture, oily luster, density are 2.65, tap density (the 20-200 order is 1.5), its chemistry, calorifics and mechanical property have obvious anisotropy, be insoluble to acid, be dissolved in NaOH, the KOH aqueous solution in time more than 160 ℃, 1650 ℃ of fusing points.The quartzite that goes out from mining is after processing, and the general product of granularity on 120 mesh sieves claims quartz sand.The product of crossing 120 mesh sieves is called silica powder.Quartzite is used for coating, can improve the weathering resistance of coating.
8, benzene emulsion: benzene emulsion (cinnamic acrylic ester emulsion) is to be got through emulsion copolymerization by vinylbenzene and acrylate monomer.Benzene emulsion is the more system of research in letex polymerization, is also that the world today has one of ten large non-crosslinked type emulsions of essential industry using value.Benzene emulsion has purposes very widely as the important middle Chemicals of a class, and is existing main as building coating, metallic surface latex coating, floor coating, paper tackiness agent, tackiness agent etc.
In step S102, mixture is stirred at the temperature of 80-90 ℃, add benzene emulsion after cooling and fully mix thoroughly.
Embodiment two
In embodiments of the present invention, get ready talcum powder 1Kg, lime powder 1Kg, porous-starch 3Kg, titanium dioxide o.6Kg, silica powder 1.5Kg, ground barium sulfate 3Kg, epoxy modified silicone resin powder 3.5Kg, poly carboxylic acid sodium dispersion agent 0.03Kg, thickening material 0.05Kg, defoamer 0.02Kg, coupling agent 0.1Kg, water 7Kg, all raw materials are mixed, stirred 10 minutes at 80 ℃ of temperature, cooling, add benzene emulsion 1Kg to stir, obtain the environmental protection radiation shielding coating.
Embodiment three
In embodiments of the present invention, get talcum powder 0.8Kg, lime powder 1.2Kg, porous-starch 4Kg, titanium dioxide 0.5Kg, silica powder 1.5Kg, ground barium sulfate 3Kg, epoxy modified silicone resin powder 4Kg, poly carboxylic acid sodium dispersion agent 0.05Kg, thickening material 0.08Kg, defoamer 0.03Kg, coupling agent 0.08Kg ready; Water 6Kg mixes all raw materials, stirs 10 minutes at 80 ℃ of temperature, and is cooling, adds benzene emulsion 1.2Kg to stir, and obtains the environmental protection radiation shielding coating.
Embodiment of the present invention coating preparation technique is simple, and cost is low, safety non-toxic, stable performance is easy to transportation and stores, when smear layer thickness reaches 12mm, protective value is 1.53mmpb, and X, gamma-rays are had very strong resistibility, and building masonry wall is also had good shielding protection function.
The above is only the preferred embodiment of the present invention; should be pointed out that for those skilled in the art, under the prerequisite that does not break away from the principle of the invention; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.

Claims (3)

1. the collocation method of a radiation shielding coating, is characterized in that, said method comprising the steps of:
Talcum powder, lime powder, porous-starch, titanium dioxide, silica powder, ground barium sulfate, epoxy modified silicone resin powder and poly carboxylic acid sodium dispersion agent, thickening material, defoamer, coupling agent are added water to be mixed;
Described mixture is stirred at the temperature of 80-90 ℃, add benzene emulsion after cooling and fully mix thoroughly.
2. the method for claim 1, it is characterized in that, the main combination raw materials of described coating umber by weight ratio is talcum powder 6-10, lime powder 10-15, porous-starch 30-43, titanium dioxide 4-7, silica powder 12-20, ground barium sulfate 25-33, epoxy modified silicone resin powder 32-42, benzene emulsion 10-12, poly carboxylic acid sodium dispersion agent 0.3-1, thickening material 0.2-0.8, defoamer 0.1-0.5, coupling agent 0.7-1.5.
3. method as claimed in claim 2, is characterized in that, the described amount that adds entry accounts for the 1/3-1/2 of coating weight.
CN201310056370.2A 2013-02-22 2013-02-22 A kind of collocation method of radiation shielding coating Expired - Fee Related CN103131326B (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103525153A (en) * 2013-10-09 2014-01-22 三棵树涂料股份有限公司 Radiation-proof putty powder and preparation method thereof
CN103555071A (en) * 2013-10-30 2014-02-05 张洪男 Radiation-proof coating and preparation method thereof
CN105440940A (en) * 2015-12-25 2016-03-30 惠州中铼环保科技有限公司 Water-based paint for exterior wall of balcony
CN106283676A (en) * 2016-08-17 2017-01-04 颍上县亿达帐蓬有限公司 A kind of UV resistance, radioprotective canvas tent fabric and preparation method thereof
CN106892626A (en) * 2017-04-20 2017-06-27 荣延洲 A kind of thermal insulation coatings of utilization hollow glass micropearl and preparation method thereof
CN111532538A (en) * 2020-05-07 2020-08-14 王有为 Anti-radiation anti-ultraviolet wear-resistant packaging box and preparation method thereof
CN115707747A (en) * 2022-11-29 2023-02-21 广西标牌化学科技有限公司 Waterproof slurry with strong adhesive force and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100092686A1 (en) * 2007-04-27 2010-04-15 Nora Laryea Method for the production of a coating material
CN102321410A (en) * 2011-07-27 2012-01-18 甘肃圣邦新材料有限公司 Composite modified starch environmentally-friendly interior wall coating and preparation method thereof
CN102391779A (en) * 2011-09-29 2012-03-28 资阳赛特化工有限公司 Metal base material corrosion-resistant coating and preparation method thereof
CN102585697A (en) * 2012-02-21 2012-07-18 广州秀珀化工股份有限公司 Nuclear radiation-resistant coating and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100092686A1 (en) * 2007-04-27 2010-04-15 Nora Laryea Method for the production of a coating material
CN102321410A (en) * 2011-07-27 2012-01-18 甘肃圣邦新材料有限公司 Composite modified starch environmentally-friendly interior wall coating and preparation method thereof
CN102391779A (en) * 2011-09-29 2012-03-28 资阳赛特化工有限公司 Metal base material corrosion-resistant coating and preparation method thereof
CN102585697A (en) * 2012-02-21 2012-07-18 广州秀珀化工股份有限公司 Nuclear radiation-resistant coating and preparation method thereof

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103525153A (en) * 2013-10-09 2014-01-22 三棵树涂料股份有限公司 Radiation-proof putty powder and preparation method thereof
CN103525153B (en) * 2013-10-09 2016-01-20 三棵树涂料股份有限公司 Radiation-proof putty powder and preparation method thereof
CN103555071A (en) * 2013-10-30 2014-02-05 张洪男 Radiation-proof coating and preparation method thereof
CN105440940A (en) * 2015-12-25 2016-03-30 惠州中铼环保科技有限公司 Water-based paint for exterior wall of balcony
CN106283676A (en) * 2016-08-17 2017-01-04 颍上县亿达帐蓬有限公司 A kind of UV resistance, radioprotective canvas tent fabric and preparation method thereof
CN106892626A (en) * 2017-04-20 2017-06-27 荣延洲 A kind of thermal insulation coatings of utilization hollow glass micropearl and preparation method thereof
CN111532538A (en) * 2020-05-07 2020-08-14 王有为 Anti-radiation anti-ultraviolet wear-resistant packaging box and preparation method thereof
CN111532538B (en) * 2020-05-07 2021-08-20 王有为 Anti-radiation anti-ultraviolet wear-resistant packaging box and preparation method thereof
CN115707747A (en) * 2022-11-29 2023-02-21 广西标牌化学科技有限公司 Waterproof slurry with strong adhesive force and preparation method thereof

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